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Carbohydrates

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Page 1: Carbohydrates

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• Carbohydrate Molecules

Carbohydrates

Polymers > Carbohydrates

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Page 5: Carbohydrates

• Monosaccharides are simple sugars made up of three to seven carbons, and

they can exist as a linear chain or as ring-shaped molecules.

• Glucose, galactose, and fructose are monosaccharide isomers, which means

they all have the same chemical formula but differ structurally and chemically.

• Disaccharides form when two monosaccharides undergo a dehydration reaction

(a condensation reaction); they are held together by a covalent bond.

• Sucrose (table sugar) is the most common disaccharide, which is composed of

the monomers glucose and fructose.

• A polysaccharide is a long chain of monosaccharides linked by glycosidic bonds;

the chain may be branched or unbranched and can contain many types of

monosaccharides.

Carbohydrate Molecules

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Monosaccharides

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Polymers > Carbohydrates

Page 6: Carbohydrates

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Appendix

Page 7: Carbohydrates

Key terms

• biopolymer Any macromolecule of a living organism that is formed from the polymerization of smaller entities; a polymer that occurs in a living organism or results from life.

• dehydration reaction A chemical reaction in which two molecules are covalently linked in a reaction that generates H2O as a second product.

• isomer Any of two or more compounds with the same molecular formula but with different structure.

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Polymers

Page 8: Carbohydrates

DisaccharidesSucrose is formed when a monomer of glucose and a monomer of fructose are joined in a dehydration reaction to form a glycosidic bond. In the process, a water molecule is lost. By convention, the carbon atoms in a monosaccharide are numbered from the terminal carbon closest to the carbonyl group. In sucrose, a glycosidic linkage is formed between carbon 1 in glucose and carbon 2 in fructose.

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Polymers

Page 9: Carbohydrates

MonosaccharidesMonosaccharides are classified based on the position of their carbonyl group and the number of carbons in the backbone. Aldoses have a carbonyl group (indicated in green) at the end of the carbon chain, and ketoses have a carbonyl group in the middle of the carbon chain. Trioses, pentoses, and hexoses have three, five, and six carbon backbones, respectively.

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Polymers

Page 10: Carbohydrates

PolysaccharidesIn cellulose, glucose monomers are linked in unbranched chains by β 1-4 glycosidic linkages. Because of the way the glucose subunits are joined, every glucose monomer is flipped relative to the next one resulting in a linear, fibrous structure.

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Polymers

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Polymers

Which of the following describe disaccharides?

A) Lactose, maltose, and sucrose are the result of bonded monosaccharides after a dehydration reaction.

B) Glucose, galactose, and fructose are isomers with more than one asymmetric carbon.

C) They are a long chain of monosaccharides linked by glycosidic bonds.

D) Cellulose is the result of two monosaccharides that have undergone a condensation reaction.

Page 12: Carbohydrates

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Polymers

Which of the following describe disaccharides?

A) Lactose, maltose, and sucrose are the result of bonded monosaccharides after a dehydration reaction.

B) Glucose, galactose, and fructose are isomers with more than one asymmetric carbon.

C) They are a long chain of monosaccharides linked by glycosidic bonds.

D) Cellulose is the result of two monosaccharides that have undergone a condensation reaction.

Page 13: Carbohydrates

Attribution

• Connexions. "Carbohydrates." CC BY 3.0 http://cnx.org/content/m44400/latest/?collection=col11448/latest

• Wiktionary. "biopolymer." CC BY-SA 3.0 http://en.wiktionary.org/wiki/biopolymer

• Wiktionary. "dehydration reaction." CC BY-SA 3.0 http://en.wiktionary.org/wiki/dehydration+reaction

• Wiktionary. "isomer." CC BY-SA 3.0 http://en.wiktionary.org/wiki/isomer

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Polymers


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