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lyondellbasell.com

Catalloy TPO ResinsAmazing Then, Amazing Now

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LyondellBasell: Shaping Tomorrow

LyondellBasell is the world’s third-largest independent chemical company.Our vertically integrated facilities, broad product portfolio, manufacturingexibility, superior technology base and reputation for operationalexcellence enable us to deliver exceptional value to our customers acrossthe petrochemical chain – from rening to advanced product applications.

Essential Ingredients

We manufacture products and develop technologies that improve the

quality of life for people around the world. Our products are the basicbuilding blocks used to manufacture countless everyday goods suchas personal care products, fresh food packaging, lightweight plastics,high-strength construction materials, automotive components, biofuels,durable textiles, medical applications and many others. With the help ofLyondellBasell materials, thousands of products are made safer, stronger,more affordable and more reliable.

Experience and Long-term Commitment

The pioneering work of Karl Ziegler and Giulio Natta continues to shape

and improve our lives. While working with LyondellBasell predecessorcompanies, these two fathers of modern polyolens changed the worldwith their discoveries. Their achievement was recognized with the NobelPrize in Chemistry in 1969. At LyondellBasell, their legacy of innovationlives on. Catalloy process technology, for example, was invented in the1990’s in Ferrara, Italy and was seen as a break through innovation. Thisprocess today produces a full range of advanced polypropylene productsincluding in-reactor thermoplastic polyolens. Since its introduction nearly25 years ago, LyondellBasell Catalloy process technology has introducedmany new and innovative grades, many still considered benchmarksin popular applications. Amazing then and amazing now - we are atechnology-driven company powered by innovative thinkers. Watch asCatalloy process resins shape the face of tomorrow.

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Thermoplastic Polyolens (TPO) from theCatalloy process

LyondellBasell’s proprietary Catalloy technology combines the advantagesof polyolens with those of elastomers. Their wide range of highly balancedand tailor-made properties makes these materials unique. Catalloy TPOresins can also be recycled to guarantee full sustainability throughout its lifecycle – and beyond.

Catalloy is a multi-stage gas phasepolymerization process, not just a resin or aproduct name. This process produces materialsover a much wider property spectrum and witha high degree of consistency.

From the Catalloy process, LyondellBasellproduces an innovative family of thermoplasticpolyolens (TPO). Using a series of independentgas-phase reactors with independentcomposition and sophisticated catalysts, theCatalloy process produces ex-reactor polymeralloy using multiple monomer inputs.

These advanced polyolens are used by ourcustomers as base materials, raw materials incompounds or as polymer modiers. Catalloy TPO resins can be formulated to meet speciccustomer requirements and can deliveradditional value in use, through:

Note: Schematic overview of Catalloy unique processtechnology. Independent uidized bed reactors withmulti monomer capability exploiting spherical Ziegler-Natta high mileage catalyst with controlled porosity.

1. Cost performance - offers replacement forhigher priced exible polymers or engineeringresins with more cost efcient polyolens.

2. Differentiation - brings cost benets alongthe value chain and enables differentiation inend-use applications versus commonly usedcommodity materials.

3. Properties modication - modies andenhances the properties of other polyolensused in blown and cast lms, textile,calendaring and extrusion thermoforming.They can also be injection molded,compression molded and used as buildingblocks for technical compounds.

In a comparison Catalloy with a standardpolypropylene (PP), the Catalloy TPO resinscovers a signicantly broader range from verysoft, without the use of plasticizers, to more

rigid properties. Along with other characteristicssuch as impact resistance, dimensional stability,aesthetic and optics; the Catalloy process resinsmeet the requirements of many applicationelds.

Catalloy process resins are sold as easy-to-blend and easy-to-store pellets. With fourmanufacturing sites in Europe and NorthAmerica, Catalloy sales and support teams havea global reach to serve customers worldwide.

EthylenePropylene1-Butene

Propylene

Prepolymerisation Polymerisation Finishing

EthylenePropylene1-Butene

EthylenePropylene1-Butene

Gas PhaseReactor 2

Gas PhaseReactor 1

Gas PhaseReactor 3

ControlledPorosityCatalyst

Activation

S t e am er

Dr y er

CAT... ...ALLOY

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Adex, Hifax, Softell and Adsyl : UniqueStructures

Unlike conventional TPOs that are merely mechanical blends of elastomersor plastomers in a polypropylene matrix, LyondellBasell TPO is an alloy ofrubber and polypropylene produced simultaneously in the polymerizationreactors. It creates a much better dispersion of the rubber in the material,which has a direct effect on the processing consistency and end-useproperties.

As opposed to elastomers or plastomers, theCatalloy TPO resins do not necessarily requireadditional off-line blending with polypropylene,thus minimizing the complexity sometimes seenwhen handling these materials and managingthe ensuing risk of inconsistencies in blends atthe end-users.

Manufactured using LyondellBasell’s proprietaryCatalloy process technology, the Catalloy TPOresin product families – Hifax, Adex and Softell - enable the control of key properties such as:

• Low specic gravity• Stiffness and impact balance

• Thermal resistance

• Low-temperature exibility

• Optical properties

• Dimensional stability

• Softness

• Compatibility with polyolens

• Easy processing

Note: Transmission Electron micrographs (TEM) of Hifax CA10A and a mechanically compounded grade.The uniform dispersion of the amorphous rubber phase (dark areas) in the Hifax material, which yields moreconsistent processing and end-use properties.

Ethylene Propylene Rubber Blend Hifax CA10A

10MPa

SBS, TPV,PolyolensElastomers

Catalloy Conventional

Polypropylene

High Crystallinity

PP

Softell, Hifax, Adex Moplen

PP Copolymer PP RandomCopolymer

PP Homopolymer

Adstif

20MPa 800MPa 1400MPa 2400MPa

Flexural Modules

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Note: Hifax , Adex and Softell versus other polymers comparing three key properties:

THREE KEY PROPERTIES

Catalloy resins are split into 4 product families:

HIFAX–Outstanding impact forindustrial and exterior automotiveapplications.

ADSYL– Low seal initiation temperatureresins.

SOFTELL–New generation for industrialand consumer applications. Softness,exibility and soft touch.

ADFLEX–Very soft, exible polyolens.

Grades with an outstanding balance ofmechanical performance, processabilityand aesthetics. Utilized by customers inbuilding and construction applications(e.g. single ply roong), industrialapplications (e.g. wire and cable) andautomotive applications (e.g. interior andexterior parts).

Through different co-monomercompositions, Adsyl grades offerthe marketing leading range of sealinitiation temperatures combined withrelatively high melting temperatures. Theresulting favorable balance of thermaland mechanical properties outperformsstandard polypropylene and polyethylene,making Adsyl low sealing temperatureresins the materials of choice for bi-oriented polypropylene lms (BOPP) as wellas for cast and blown lms.

Combining toughness with exibility,customers select these resins due to theirresistance and elasticity. Softell resinsprovide an enhanced soft-touch feeland slip resistant grip used in electricalappliances and tools. Additional benetsinclude the ability to bond well with otherpolyolens and additives and the capacityto effectively incorporate llers.

Our Adex family are very soft and exibleTPO resins used by a wide number of ourcustomers in applications such as specialitylms, as a blending partner to improveimpact performance, extrusion coating,bitumen modication and consumerapplications. In addition to enhancedexibility, the Adex resins exhibit excellentimpact performance at low temperatures,outstanding haptic properties and softtouch.

THERMOPLASTICHIGH TEMPERATURE RESISTANCE

FLEXIBLE

EPDM

(XL)PE

PP

TPVsTPEs

PVC ADFLEX

HIFAXSOFTELL

Also manufactured with the Catalloy processtechnology is the Adsyl product family for thepackaging industry, which require low sealinitiation temperatures (SIT), no stickiness,high clarity and additionally provide specicfunctional properties to the lm surface.

AllCatalloy resins can be easily shipped inbulk containers and stored in silos, makingit an easy-to-handle product compare toconventional grades.

The Catalloy TPO resin product families – Hifax , Adex and Softell – improve the processabilityin injection molding, sheet extrusion,thermoforming and blow molding operations.They enable the replacement of higher pricedexible polymers or engineering resins withmore cost efcient polyolens. Additionallythey can be used to modify properties ofother polymers used in technical compounds,extrusion, injection molding and other blendedapplications. The thermoplastic Catalloy resinsoffer very attractive properties includingexibility, high thermal resistance, haptics andprocessing.

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Catalloy in Soft and Rigid TechnicalCompounds

LyondellBasell Catalloy TPO resins are used in many types of compoundsand produced for a wide variety of applications. Whether a rigid, softcompound or a masterbatch, Catalloy enables customers to meetchallenging requirements on performance, cost, recyclability andprocessability.

Soft Compounds

Hifax , Adex and Softell resins are selected bycustomers for use in the formulation of softcompounds for a wide range of applications,as well as elastomer modication. These gradesare well-known in the automotive industryfor their very good impact resistance at lowtemperatures, good haptics, controllablegloss, ow-mark-free surfaces and controlleddimensional stability.

Impact modication

Thermal resistance

Compatible with polyolens(PE/PP)

Durability

Soft-touch enhancements

Low-Gloss

Improved tensile properties

Improved processability

High ller loading

Recyclable

Cost reductionLow voc

Weight reduction

Automotive:• Dashboard TPO

skins• Door panel and

armrest• Floor mat Flexible proles:• Flexible proles• Flexible hoses and

pipes• Roong

Foam sheet:• High thermal

resistant soft foam

Consumer andTextile:• High impact

container lids• Soft touch textile

and carpet• Articial grass

The Catalloy process resins exhibit very goodcompatibility with many TPEs (ThermoplasticElastomers). Due to their relatively high meltingtemperature (up to 163 °C), softness and verygood processability, these versatile, cost-effective resins are extensively used to improvethermal resistance, surface aesthetics andrheology.

Wire and Cable:• Industrial cable

insulationand jacketing,

compounds• Automotive T3class cable

Film:• Soft touch, puncture

resistant andtransparent lms

TYPICAL APPLICATIONSKEY FEATURES

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Low density

Compatibility with widerange of polyolens

High ller loading

Low Tm carrier

Porous carrier for liquidadditives

Easy processing

Softness

Recyclable

Excellent impact resistance/ stiffness balance

Improved impact at lowtemperatureDurability

Mold shrinkage adjustment

Gloss modication andaesthetics

Improved soft-touchperformance

Compatibility with widerange of polyolensHigh melt strength

Recyclable

Wire and cable

Flame retardantmaterials

Pigments andadditives

Natural bers

Automotive interior:

• Glove box

• Side covers

• Central console

Rigid Compounds

Hifax , Adex and Softell grades are usedin the manufacturing of rigid compoundswith low warpage (glass and natural bersand reinforced compounds), improved heat

resistance, high aesthetic (lled grades,automotive interior parts), durability (UVresistance) and also to control the shrinkageof the nished product (e.g. appliances,automotive, tools).

Carrier, Masterbatches and HyperlledSystems

Special Catalloy process resins available inpowder form have been successfully used inmasterbatches and concentrates as a carrierfor liquid additives such as peroxides which arephysically absorbed into the mixture throughsimple dry-blending.

The opportunity to custom tailor theseadvanced polyolens is particularlyadvantageous to converters who are producingmaterials where tight tolerances are required.

Catalloy resins open up new opportunities forthe compounder, enabling him to developdifferentiated performance products, whileusing a cost-effective Catalloy grade as analternative to previously used commodity resins.

Automotive exterior:

• Side rails

• Tailgate covers

• Side cladding

• Bumper

Consumer goods:

• Tooling

• Body care items

TYPICAL APPLICATIONS

TYPICAL APPLICATIONS

KEY FEATURES

KEY FEATURES

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Catalloy : Utilized in a widerange of market segments

The Hifax , Adex , Softell and Adsyl familiesof reactor-made polyolens produced byLyondellBasell’s proprietary Catalloy technologyhave become industry benchmarks. Thesegrades offer optimum, well-balanced propertiesand performance characteristics for durable

applications in building and construction, butalso applications including automotive (interiorand exterior), consumer products, packaging,electrical appliances, toys, sporting goods. Learnmore about the wide range of market segmentssupplied with Catalloy resins.

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Automotive

Interior Applications – Controllable gloss,good aesthetics and low CLTE are typicalrequirements for components found in theinterior compartment. Using compounds basedon Hifax and Softell resins, console, pillar trim,interior ooring, soft grips and TPO skins fordashboard and door panels are produced.

Exterior Applications – Due to their speciallydesigned compositions, Hifax and Softell resins are well-known in the industry for theirexcellent impact resistance at low temperatures,

ow-mark free surfaces and low shrinkage inapplications such as bumpers, side cladding andfront grills.

Textile and Carpets

Due to the very low exural modulus, ourcustomers have found signicant advantagesin combining Adex grades with standard PP

to soften yarns and laments used in textileapplications increasing the end user’s comfort.

Packaging

Flexible Packaging – Adsyl products with alow seal-initiation temperature and excellenthot tack strength for higher speed form-ll-sealpackaging are used for exible food packaging.In co-extruded BOPP, cast lm, and doublebubble applications, Adsyl is used as skin layermaterial.

Rigid Packaging – Hifax and Adex gradesare used in the manufacture of rigid moldedgoods. They can be used alone or blended withother polymers to improve heat resistance,

clarity, durability and elastic recovery of thenished product.

Industrial packaging – IncorporatingCatalloy TPO resins with other polyolenresins into a lm structure, the resulting highperformance lms can be tailor made to meetspecic requirements: puncture resistanceat low temperature, excellent tear resistance,high stretching ratio, increased strength andexcellent processability. Typical applicationsinclude stretch hoods, heavy duty bags, non-fusion shrink hoods or IBC liners.

Electrical Appliances

The Hifax and Softell resins are known for theircontribution to the aesthetic value and qualityof thermal resistant compounds. The Catalloy TPO portfolio offers a wide range of propertiesthat meet our customers’ requirements.Each offers new opportunities to developsophisticated compounds used for productionof large parts with optimum dimensionalstability, good processing, and low warpage.

Building, Construction and Infrastructure

Single Ply Roong – Waterproongmembranes produced using Catalloy thermoplastic polyolens are recognized in theindustry as tough, versatile materials, combiningease of installation, durability and long servicelife. For more than 20 years, LyondellBasell’sthermoplastic polyolens have been speciedby customers for waterproong membranes.

Geomembranes – Catalloy TPO resins areused in geomembrane applications becauseof their unique combination of durability,

exibility, barrier properties, thermal resistance,dimensional stability, plasticizer-free design andenvironmental resistance.

Bitumen Modication for roong and paving – Catalloy TPO resins are used as additives forbitumen modication with proven long-termperformance. Key features of the resins forthese applications are temperature resistancefrom very low to elevated levels improving thecold bending property of bitumen even afterthermal and UV aging.

Wire and Cable – The unique balance of hightemperature performance and exibility offered

by Hifax and Softell grades is widely recognizedby producers of compounds for wire and cableapplications. Product exibility and toughnessare maintained even when highly loaded withmineral llers, such as in non-halogenated,ame-retardant versions.

Soft Sheets and Proles – Catalloy processtechnology offers products suitable for theextrusion, calendering and extrusion blowmolding of very soft lm and sheet as wellas for injection molded parts. It combinesoutstanding low stiffness, excellent lowhardness and very good impact resistance. Oneof the typical applications are soft proles forwindows.

Interior and Exterior Pipes – Hifax and Softell resins can be used as cost saving material forthe production of exible pipe connection ring(compound or co-extrusion). Catalloy resins arealso used for producing liners for ‘cured in placepipe’ rehabilitation projects.

Consumer Goods

Achieve higher performance by utilizingreactor-grade Adex, Hifax or Softell resins inblends with other polyolens. Modicationwith these specialized resins can enhancethe cold-temperature impact performance oftransparent applications while retaining clarity.They also offer an attractive haptic and softtouch surface.

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LyondellBasell: Your Preferred Global Supplier

Bayport, TX

Lake Charles, LA

Moerdijk, NE

Ferrara, IT

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Rotterdam

Stationsplein 453013 AK RotterdamNetherlands

Tel: +31 10 275 5500

Houston

LyondellBasell Tower, Ste. 3001221 McKinney StreetHouston, TX 77010P.O. Box 3646 (77253-3646)USA

Tel: +1 713 309 7200

Hong Kong

Basell Asia Pacic Ltd.12/F Caroline CenterLee Gardens Two, 28 Yun PingRoad CAUSEWAY BAYHong Kong

Tel: +852 2882 2668

Before using a product so ld by one of the LyondellBasell family of companies, users should make their own independent determination that the product is suitable for the intendeduse and can be used safely and legally. SELLER MAKES NO WARRANTY; EXPRESS OR IMPLIED (INCLUDING ANY WARRANTY OF MERCHANTABILITY OR FITNESS FOR A PARTICULARPURPOSE) OTHER THAN AS SEPARATELY AGREED BETWEEN THE PARTIES IN WRITING. This product may not be used in the manufacture of any US FDA Class III Medical Device orHealth Canada Class IV Medical Device and may not be used in the manufacture of any US FDA Class II Medical Device or Health Canada Class II or Class III Medical Device without theprior written approval by Seller of each specic product or application. Users should review the applicable Material Safety Data Sheet before handling the product.

Adex, Adsyl, Catalloy, Hifax and Softell are trademarks owned or used b y one of the LyondellBasell family of companies and are registered in the U.S. Patent and Trademark Ofce.

LyondellBasell Industries Holdings, B.V. 2013

LB 13 007 e 10/13