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Inte grate d M .Sc. and 2 ye ar M . Sc. Curr icula

Depa r tm ent of Chem ist ry

Indian Inst i tut e o f Techn ology Bom bay

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CURRICULUM FOR 5 YEAR INTEGRATED M .Sc. PROGRAM M E

First year : First Sem ester

Code Na m e L T P C

CH 103 Chem istry -I 2.0 1.0 0.0 6.0CS 101 Com put er program m ing and ut i l izat ion 2.0 1.0 0.0 6.0

M A 105 Calculus 3.0 1.0 0.0 8.0

HS 101 Econ om ics 2.0 1.0 0.0 6.0

CH 117 Chem istr y Lab 0.0 0.0 3.0 3.0

M E 113 W orkshop pract ice 0.5 0.0 3.0 4.0

9.5 4.0 6.0 33.0

Cont act hou rs: 19.5

Credits: 33.0

First ye ar : Secon d Sem ester

Code Na m e L T P C

CH 104 Chem istry -II (DIC) 2.0 1.0 0.0 6.0

PH 105 Physics-II (M od ern Physics) 2.0 1.0 0.0 6.0

M A 10 6

M A 10 8

Linear algebra (half semester )

Ordinary d i f ferent ia l equat ion s(half semester )

3.0 1.0 0.0 8.0

IC 102 Data analysis and inter pret at io n 2.0 1.0 0.0 6.0PH 117 Physics Lab 0.0 0.0 3.0 3.0

M E 118 Engineering graphics and draw ing 1.0 0.0 3.0 5.0

10.0 4.0 6.0 34.0

Cont act hou rs: 20.0

Credits: 34.0

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Second year : First Sem ester

Code Na m e L T P C

CH 211 Physical Chem istry - I 2.0 1.0 0.0 6.0

CH 221 Organic Chem istr y - I 2.0 1.0 0.0 6.0

BT 251 M olecular Cell Biology 2.0 1.0 0.0 6.0EE 101 Int roduct ion to e lectr ica l and e lectron ic

circuits3.0 1.0 0.0 8.0

CH 206 Inor ganic Chem istr y Lab -I 1.0 0.0 3.0 4.0

IC 211 Exper iment at ion and m easurem ents lab 0.0 0.5 3.0 4.0

10.0 4.5 6.0 34.0

Cont act hou rs: 20.5

Credits: 34.0

Second y ear : Second Sem ester

Code Na m e L T P C

CH 222 Organic Chem istry - II 2.0 1.0 0.0 6.0CH 210 Inorganic Chem istr y - I 2.0 1.0 0.0 6.0

CL 152 Intr odu ction to Chem ical Engineerin g 2.0 1.0 0.0 6.0

PH 103 Electr ici ty and M agnetism 2.0 1.0 0.0 6.0

ES 20 0/HS200

Enviro nm ent al science and engineer ing/Environm enta l s tud ies

(Half-sem ester courses)

3.03.0

0.00.0

0.00.0

3.03.0

CH 215 Physical Chem istry Lab - I 0.0 0.0 4.0 4.0

14.0 4.0 4.0 34.0

Cont act hou rs: 22.0

Credits: 34.0

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Third yea r : First Sem ester

Code Na m e L T P C

CH 423 Organic Chem istry -III 2.0 1.0 0.0 6.0

CH 427 Chem ical and Stat ist ical Therm odyn am ics 2.0 1.0 0.0 6.0

PH 201 Opt ics 2.0 1.0 0.0 6.0IE1 Instit ut e Electiv e fro m HSS 3.0 0.0 0.0 6.0CH 317 Organic Chem istry Lab - I 0.0 0.0 4.0 4 .0

EP 215 Electr on ics Lab - I 0.0 0.0 3.0 3.0

9.0 3.0 7.0 31.0

Cont act hou rs: 19.0

Credits: 31.0

Third yea r : Second Sem ester

Code Na m e L T P C

CH 416 Physical Organic Chem istry 2.0 1.0 0.0 6.0

CH 426 Rat e Processes 2.0 1.0 0.0 6.0CH 429 M odern M ethod s of Analysis 2.0 1.0 0.0 6.0

IE 2 Inst i tut e Elect ive from HSS 3.0 0.0 0.0 6.0

CH 316 Inorganic Chem istr y Lab - I I 0.0 0.0 4.0 4.0

CH 318 Organic Chem istry Lab - II 0.0 0.0 4.0 4.0

9.0 3.0 8.0 32.0

Cont act hou rs: 20.0

Credits: 32.0

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Fourth year : First Sem ester

Code Na m e L T P C

CH 425 Chem ical Bond and M olecular Geomet ry 2.0 1.0 0.0 6.0

CH 438 Chem istry of M ain Group Element s 2.0 1.0 0.0 6.0

CH 507 M et hod s in Organic Synt hesis 2.0 1.0 0.0 6.0CH 433 Physical Chem istry Lab - II 0.0 0.0 4.0 4.0CH 419 Separ atio n Techniq ues Lab 0.0 0.0 4.0 4.0

8.0 4.0 8.0 32.0

Cont act hou rs: 20.0

Credits: 32.0

Fourt h yea r : Second Seme ster

Code Na m e L T P C

CH 402 Therm al and Photo chem ical Reactions 2.0 1.0 0.0 6.0

CH 437 Chem istr y of Transit io n Elem ent s 2.0 1.0 0.0 6.0

CH 432 Inor ganic Chem istry Lab - III 0.0 0.0 4.0 4.0

CH 434 Physical Chem istry Lab - III 0.0 0.0 4.0 4.0

CH 442 M olecular Spectr oscopy 2.0 1.0 0.0 6.0CH 418 Organic Chem istry Lab - III 0.0 0.0 4.0 4.0

6.0 3.0 12.0 30.0

Cont act hou rs: 21.0

Credits: 30.0

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Fifth year : First Sem ester

Code Na m e L T P C

CH 557 Topics in Chem istr y 2.0 1.0 0.0 6.0

CH 547 Organom et al l ic Chem istr y 2.0 1.0 0.0 6.0CH 521 Inter pret at ive M olecular Spect roscopy 2.0 0.0 0.0 4.0IE 4 Inst i tut e Elect ive- fro m HSS or any

depar tm ent o t her than Chemis t ry

2.0 1.0 0.0 6.0

CH 593 Project 0.0 1.0 10.0 12.0

8.0 4.0 10.0 34.0

Cont act hou rs: 22.0

Credits: 34.0

Fifth y ear : Second Sem ester

Code Na m e L T P C

CH EL1 Elect ive-I 2.0 1.0 0.0 6.0CH EL2 Elect ive-II 2.0 1.0 0.0 6.0

CH EL3 Elect ive-III 2.0 1.0 0.0 6.0

CH 594 Project 0.0 1.0 16.00 18.0

6.0 4.0 16 36.0

Cont act hou rs: 26.0

Credits: 36.0

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Dep artm enta l e lectives I to I I I

Physical Chemistry

CH 559 Solid Stat e Chem istr y and its Applicat ion sCH 550 Electrochem istr yCH 552 Inter facial Phenom ena

CH 560 Quantum Chem istry

CH 576 Stat ist ical M echanics

CH 584 Biophysical Chem istr y

CH 586 Structu re and Proper t ies of M ater ia ls

CH 504 Com put at ion al Chem istr y

Organ ic Chem istry

CH-504 Com put at ion al Chem istr y

CH-556 Polym er Sciences

CH-528 Natu ral Product s

CH-540 Drugs and Biological ly act ive com pou nds

CH 510 Heter ocycl ic chem istr y

CH 546 Int roduct io n to Biomolecules

Inorgan ic Chem istry

CH-502 Synt hesis and Character izat ion of Inorganic Com pou nds.CH-522 Chem istry of Coord inat ion Com poun ds

CH-524 Bioinorganic Chem istr y

CH-574 Topics in Inorganic Chem istr y-I

CH-578 Topics in Inorganic Chem istr y-I I

CH-582 Inorganic Phot ochem istr y

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HS AN D IN STITU TE ELECTIVES

The student is al lowed to take any course as an Inst i tute Elect ive provided that i t is not

of fered by h is /her own Depar tment as a compulsory course or as a Depar tmenta l

Elect ive. This is in addi t ion to the courses expl ic it ly l isted below under t he Inst i t u te

Elect ive heading. How ever the consent of the Inst ructor and h is /h er facul ty adviser w i l lbe necessary. The inform atio n abo ut ot her courses is available on the Inst i t ut eshome / w eb page .

HS Electives - Aut um n Sem ester

HS 423 Trends in Twent ie th Centur y Drama

HS 425 St ress and Cop ing

HS 427 Essent ials of Gandh ian Polit ical Econ om y

HS 429 Sociolo gy of Science

HS 433 M an, Environm ent and SocietyHS 443 Philosophy and Histo ry of Science

HS 463 Int roduct io n to Ar t and Aesthet ics

HS 467 Indian Philosoph y

HS 475 Perspectives on Econom ic Developm ent

HS 477 Principles of M anagem ent

HS 481 Psychology in Executives Self M anagem ent

HS 483 Int roduct io n to Logics and the ir Autom at ionHS 485 M anagem ent of Hum an Resources in Organizat ions

HS 487 Planning and Econom ic Policies in India

HS 489 St ate , Polity and Societ y

HS 491 Cont em porary Urb an India: Sociological Perspective

Insti tute Electives - Autu m n Sem ester

CE 466 Com put at ional M echanics : An In t rodu ct ion

EE 663 Thin Fi lm Com po nent s and CircuitsEN 402 Intr odu ction to Energy Engineering

ES 400 Enviro nm ent al Science and Engineering

HS 422 Intr odu ction to Classic English Lite ratu re

HS 424 Und erstanding Sciencd and Techn ology t hrou gh Literatu re

HS 426 Theory and Policy of M anagerial FinanceHS 428 Futu res St ud ies

HS 432 An Int rodu ct ion to the Socio logy of Rura l Developm ent

HS 440 Industr ial Econom icsHS 442 Logic and Found at ions of M athem at ics

HS 457 M anagerial Econom ics

HS 462 App lied Social Psycho logy

HS 464 Science, t echn olo gy and Societ y

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HS 466 Intr odu ction to Linguist ics

HS 468 Philosophy of Religion

HS 478 Indu strial Sociolo gy

HS 480 An Organizatio nal Psychology Appr oach t o Engg. M anagem ent

HS 484 Inter nat ional Finance and M onet ary System

HS 486 Theory of Set s and M ult isetsHS 490 Organizat ional Behaviour and Imp l icat ions for M anagem entHS 492 M anagem ent by Values

IM 610 M anager ia l Econom ics

IM 622 M anufactur ing Strat egies

M E 474 Investm ent Analysis and Secur i t ies M arkets

M S 400 M odern Concepts in M ater ia ls Science

M T 604 Corro sion Process and Cont rol

PH 400 Lasers

PH 426 Astr o Physics

SC 400 Intr odu ction to System sSC 404 M eth ods for System s Analysis I I

HS Electives/ Institut e Electives - Spring Sem ester

BM 402 Neurophysio logy and M otor Cont ro l

CE 466 Com put at ional M echanics : An In t rodu ct ion

EN 402 Intr odu ction to Energy EngineeringES 400 Enviro nm ent al Science and Engineering

ES 402 Terrest rial Biosphe re : Physical and Sosiet al Issues

HS 424 Und erstanding Science and Techno logy th rou gh Liter atur e

HS 426 Theory and Policy of M anagerial FinanceHS 432 An Int rodu ct ion to the Socio logy of Rura l Developm ent

HS 440 Industr ial Econom ics

HS 442 Logic and Found at ions of M athem at ics

HS 457 M anagerial Econom ics

HS 464 Science, Techno logy and Societ yHS 466 Intr odu ction to Linguist ics

HS 468 Philosophy of Religion

HS 474 Investm ent Analysis and Securit ies M arkets

HS 478 Indu strial Sociolo gy

HS 480 An Organizatio nal Psychology Appr oach t o Engg. M anagem entHS 482 Com m unicatio n Skil ls

HS 484 Inter nat ional Finance and M onet ary System

HS 486 Theory of Set s and M ult isetsHS 490 Organizat ional Behaviour and Imp l icat ions for M anagem ent

HS 492 M anagem ent by Values

HS 494 W om en in Third W or ld Developm ent

M A 406 General Topo logy

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M E 462 Appropr iate Technology

M E 474 Investm ent Analysis and Secur i t ies M arkets

M E 478 M anagem ent Pr inc ip les and Pract ice

M S 400 M odern Concepts in M ater ia ls Science

M T 604 Corro sion Process and Cont rol

PH 400 LasersPH 426 Astr o PhysicsSC 400 Intr odu ction to System s

SC 404 M eth ods for System s Analysis I I

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CURRICULUM FOR 2 YEAR M .Sc. PROGRAM M E

First year : First Sem ester

Code Na m e L T P CCH 423 Organic Chem istry -III 2.0 1.0 0.0 6.0

CH 425 Chem ical Bond and M olecular Geomet ry 2.0 1.0 0.0 6.0

CH 427 Chem ical and Stat ist ical Therm odyn am ics 2.0 1.0 0.0 6.0

CH 438 Chem istry of M ain Group Element s 2.0 1.0 0.0 6.0

CH 419 Separ atio n Techniq ues Lab 0.0 0.0 4.0 4.0

CH 433 Physical Chem istry Lab - II 0.0 0.0 4.0 4.0

CH 481 Com put ers in Chem istr y 1.0 0.0 2.0 4.0

9.0 4.0 10.0 36.0

Cont act hou rs: 23.0

Credits: 36.0

First ye ar : Secon d Sem ester

Code Na m e L T P C

CH 402 Therm al and Photo chem ical reaction s 2.0 1.0 0.0 6.0

CH 416 Physical Organic Chem istry 2.0 1.0 0.0 6.0

CH 426 Rat e Processes 2.0 1.0 0.0 6.0

CH 429 M odern M ethod s of Analysis 2.0 1.0 0.0 6.0CH 437 Chem istr y of Transit io n Elem ent s 2.0 1.0 0.0 6.0CH 418 Organic Chem istry Lab - III 0.0 0.0 4.0 4.0

CH 432 Inor ganic Chem istry Lab - III 0.0 0.0 4.0 4.0

CH 434 Physical Chem istry Lab-III 0.0 0.0 4.0 4.0

CH 442 M olecular Spectr oscopy 2.0 1.0 0.0 6.0

16.0 5.0 12.0 48.0

Cont act hou rs: 33.0

Credits: 48.0

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Second year : First Sem ester

Code Na m e L T P C

CH 507 M eth ods in Organic Synt hesis 2.0 1.0 0.0 6.0

CH 521 Inter pret at ive M olecular Spect roscopy 2.0 1.0 0.0 6.0CH 547 Organom et al l ic Chem istr y 2.0 1.0 0.0 6.0ES 20 0/

HS 200

Enviro nm ent al science and engineering/

Environm enta l s tud ies

(Half-sem ester courses)

3.0

3.0

0.0

0.0

0.0

0.0

3.0

3.0

CH 593 Project - - - 12.0

8.0 4.0 0 34.0

Cont act hou rs: 12.0

Credits: 36.0

Second y ear : Second Sem ester

Code Na m e L T P CCH EL1 Elect ive-I 2.0 1.0 0.0 6.0

CH EL2 Elect ive-II 2.0 1.0 0.0 6.0

CH EL3 Elect ive-III 2.0 1.0 0.0 6.0

CH 594 Project 0.0 0.0 18.0 18.0

6.0 3.0 18.0 36.0

Cont act hou rs: 27.0

Credits: 36.0

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Electives I to I I I from the fol low ing :

Physical Chemistry

CH 504 Com put at ion al Chem istr yCH 550 Electrochem istr yCH 552 Inter facial Phenom ena

CH 559 Solid Stat e Chem istr y and its Applicat ion s

CH 560 Quantum Chem istry

CH 576 Stat ist ical M echanics

CH 584 Biophysical Chem istr y

CH 586 Structu re and Proper t ies of M ater ia ls

Organ ic Chem istry

CH-504 Com put at ion al Chem istr y

CH 510 Heter ocycl ic chem istr y

CH-528 Natu ral Product s

CH-540 Drugs and Biological ly act ive com pou nds

CH 546 Int roduct io n to Biomolecules

CH-556 Polym er Sciences

Inorgan ic Chem istry

CH-502 Synt hesis and Character izat ion of Inorganic Com pou nds.CH-522 Chem istry of Coord inat ion Com poun ds

CH-524 Bioinorganic Chem istr y

CH-574 Topics in Inorganic Chem istr y-I

CH-578 Topics in Inorganic Chem istr y-I I

CH-582 Inorganic Phot ochem istr y

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Chem istry M inor Program

M inor in Chem istry (For the BTech and DD , Total 30 Extra Credits)

1. CH 104 (Chem istr y II)2 . CH 211 (Physical Chem istry I)3. CH 210 (Inor ganic Chem istr y I)4. CH 221(Organic Chem istr y I)5. CH 4XX (Any 400 level course for w hich prer equ isites are m et)6. CH 4YZ (A second 400 level course for w hich pr erequ isites are m et)

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DEPARTM EN TAL COU RSES

PREPARATO RY CO U RSES

CH 001 : Preparato ry Chem istry I 3 2 0Genera l introduction:Form ula, sto ich iom etry, m olar i ty , mola l i ty , norm al ity , appl icat ions

of th ese concept s.Gases: Boyle's law, Charles' law, PV=nRT and applicat ions : Dalton's law of part ialpressure, Graham's law of dif fusion, kinetic theory of gases (physical concept) and

applicat ions in prob lem s solving.Chemical Equil ibrium - Ionic Equil ibrium: Law of mass act ion, reversible reaction,

equi l ibr ium constant for homogeneous annd heterogeneous react ions, e f fect o f

pressure, vo lum e and concentrat ion of reactants and prod ucts on equi l ibr ium , ef fect o f

temperature on equil ibr ium constant. Dissociat ion constants of acids and bases,

comm on ion ef fect , ion isat ion constant o f w ater , pH, buf fer so lut ions and hydro lys is of

salts. Solubil i t y prod uct and it s applicat ion t o chem ical analysis. Determ ination of Ka, Kb,

Kw and Ksp by conductance m easurem ents. Col l igat ive prop er t ies, f ract ional d ist i l lat ion,phase diagrams.Thermodynamics: First law of thermodynamics, revers ib le work, i r revers ib le work,

isothermal and adiabat ic , thermochemistry, Hess 's law, bond energy. The entropy

concept .Chemical Kinetics:Rate expression, order and molecular ity, f irst order reaction, half l i fe

period , radioactive carbon datin g, Arrh enius equatio n act ivat ion ener gy and catalysis.Electrochemistry: Faraday's laws of electrolysis, galvanic cel ls, electrode potential andelectrod e reactions of sim ple electrode pr ocesses.Atomic Structure and Periodic classifications: Spectra of H-atom, Bohr 's model o f H-

atom , wave nat ure of e lect ron , a tom ic orb i ta ls, shapes of s,p, and d o rb i ta ls, quantum

numbers, Pauli Pr inciple, Hund's Rule, electronic configurat ion of elements uptoKrypton , per iod ic classif icat ion o f elem ent s. Solids.

Texts/ References

G. M . Bar row, Physical Chem istr y, 5 t h edi t ion, Tata M cGraw-Hi l l , New Delh i , 1992

S. H. M aron and C. F.Prut to n, Principles of Physical Chem istr y, 4 th Edi t ion, Oxford & IBH,New Delh i, 1972.

CH 002 : Preparato ry Chem istry I I 3 2 0

Inorgan ic Chem istryPeriodicity in Properties: Ion izat ion potent ia l , e lect ron af f in i ty , ion ic rad i i and

electronegativity. Chemical Bonding: Ionic sol ids, Born-Haber cycle, covalent bonds,d ipole moment, resonance, hybr id izat ion, geometry and shape of s imple molecules.

Coord inate Bond, Hydrogen bon d.

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Chemistry of p-block and d-block elements: Halogens; Periodicity of propert ies,

preparat ion and uses of halogens and hydrogen halides. Oxides and oxyacids of

chlor ine.

In t roduct ion to t ransi t ion e lements; ox ides and oxyacids of su lphur , n i t rogen and

phosphorus.

Isolat ion o f M etals; Extract ion of M g, Al, Zn, Cu and Fe.Preparat ion and Proper t ies of chemical compounds of industr ia l impor tance : Caust icsoda, sodium carbonate, b leaching pow der , superpho sphate, gypsum alum , a lum in ium ,

chlor ide. Copper su lphate,si lver n i t ra te, am m onia and amm onium sulphate.

Organ ic Chem istry

Classi f icat ion and nomeclature of compounds. Empir ica l and molecular formula

determination, isomerism. Electronic effects, resonance and inductive effects. Acidity of

carboxyl ic acids and phen ols, basicity of am ines.

Covalent bond, types of hybr id izat ion in carbon com poun ds. Hetero lysis and hom olysis

of covalent bonds - nucleophiles and electrophiles. Reactions of alkanes, alkenes and

alkynes.Character ist ic reaction s of com m on fun ctional groups like alcoho ls, aldehydes, ket ones,

acids, ester s and am ines.

Di f ference between a l iphat ic annd aromat ic compouds. Benzene and e lectrophi l ic

subst i tu t ion.

Text / References

R. T. M orr ison an d R. N. Boyd , Organ ic Chem istr y, 6 t h edit ion, Pearson Com ., 1992P. Volhardt and N . Schor e, Organ ic Chem ist ry : St r ucture and Funct ion, 5 t h edi t ion, W. H

Freem an & Co, 2006

J. D. Lee , Con cise Ino rga nic Chem istr y, 4 t h edit ion , ELBS, 199 1.

F. A. Cot t on , G. Wilkin son, P. G. Gans, Basic Inorga nic Chem istr y, 2n d edi t ion, John W i ley& Sons, 1987.

CH-011 : Preparato ry Chem istry Laborat ory I 0 0 3

Practical exercises :

Exper iment s re la ted t o -1. Acid-base t i t rat ion .

2. Redox t i t ra t ion

3. Chem ical Equ il ibr ium

4. Ionic Equil ibr ium

5. Solub il i ty Prod uct6. Chem ical kinet ics

7. Electrochem istr y

CH-012 : Preparato ry Chem istry Laborat ory I I 0 0 3

1.Quali tat ive analysis of an ions and catio ns.

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2. Detect ion o f elem ent s- N, S, halogens

3. Separat ion and pu r i f icat ion m etho ds.

4 . M e l t ing po in t and bo i ling po in t de te rmina t ion .

CH 103 Chem istry - I 2 1 0 6

Schrodinger equat ion (or ig in of quant izat ion) , Born in terpretat ion of wave funct ion,

Hydrogen atom: solution to -par t , M O theory: a tom ic and m olecular orb i ta ls,

Structure, bonding and energy levels of diatomic molecules. Examples N2, O2, CO and

HF, Configurat ion, molecular chiral i ty and isomerism, Conformation of alkanes and

cycloalkanes, Reactivity of carbonyl group (addit ion reactions, reactions due to acidic

proton, addi t ion-e l iminat ion react ions and react iv i ty o f ac id hal ide, ester and amide) ,

Funct ional group in terconvers ions involv ing oxidat ion and reduct ion, Per iod ic

proper t ies: t rends in s ize, e lect ron af f in i ty , ion izat ion potent ia l and e lectronegat iv i ty ,

Use of El l ingham diagram and th erm odynam ics in t he extract ion of e lem ents, Transi t ionmeta l chemistry: inorganic complexes, bonding theor ies, magnet ism, bonding aspects

and st ructura l d is tor t ion, Bio inorganic chemistry: s torage and t ranspor t prote ins,

Cata lysis: hydrogenat ion, hydr oform ylat ion and o lef in m etath esis.

Text / References

P. Atkin s and J. de Paula, Atk ins Physical Chem istr y, Oxford University Press, 8t h edi t ion,

2006.I. N. Levin e, Physical Chemistry, 5 t h edi t ion, Tata M cGraw-Hi l l , New Delh i , 2002.

D. A. M cQuarr ie and J.D. Sim on , Physical Chem ist ry - a m olecular a ppro ach, Viva Books

Pvt. Lt d. (1998).

P. Volhardt and N . Schore, Organ ic Chem ist r y : St r ucture and Funct ion, 5 t h Edit ion, W . HFreem an & Co, 2006

T. W. G. Solomons, C. B. Fryhle, Organ ic Chem ist ry , 9 t h Edit ion, Wilely India Pvt. Ltd.,

2009

R. T. M orr ison an d R. N. Boyd , Organ ic Chem istr y, 6 t h edit ion, Pearson Com ., 1992

L. G. Wad e , Organ ic Chem istr y, Pearson Education 6 t h edi t ion, 2006.M . J. Sienko and R. A. Plane, Chem ical Principles an d App licat ions, M cGraw Hi l l, 1980.

J. D. Lee, Con cise Ino rga nic Chem istr y, 4t h Edit ion , ELBS, 1991 .

D. D. Ebb ing, General Chemistry, Houghton M if f in Co. , 1984.

CH 104 Chem istry- I I 2 1 0 6

Chemical potential, Fugacit ies, act ivit ies, equil ibr ium constant, standard potential,

Nernst equation, cel l potential, concentrat ion cel ls and applicat ions, Chemical kinet ics:steady state approximation, col l is ion theory, Reaction mechanisms, energies and

kinetics, Reaction types (nucleophil ic, electrophil ic, free radical reactions,

polym er izat ion react ion s involv ing a liphat ic and arom at ic substrates) , M olecular

rearrangements Synthetic polymers and proteins, VSEPR theory, structure of boranes

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and carboranes and electron count ing, Inorganic r ings, M etal carbonyls (synthesis,

st ructu re, bonding and react iv ity) , Organom eta l l ic reagents, M agnet ism and

superconduct iv i ty , Bio inorganic chemistry, act ivat ion and f ixat ion of iner t m olecules.

Text / References

P. Atkin s and J. de Paula, Atk ins Physical Chem istr y, Oxford University Press, 8t h edi t ion,2006.G. M . Bar row, Physical Chem istr y, 5 t h edi t ion, Tata M cGraw-Hi l l , New Delh i , 1992.

D. A. M cQuarr ie and J. D. Sim on , Physical Chem ist ry - a m olecular appr oach, Viva Boo ks

Pvt. Ltd. ( 1998 ).

P. Volhardt and N . Schore, Organ ic Chem ist r y : St r ucture and Funct ion, 5 t h Edit ion, W . H

Freem an & Co, 2006

T. W. G. Solomons, C. B. Fryhle, Organ ic Chem ist ry , 9 t h Edit ion, Wilely India Pvt. Ltd.,

2009

R. T. M orr ison an d R. N. Boyd , Organ ic Chem istr y, 6 t h edit ion, Pearson Com ., 1992

L. G. W ade, Organic Chemistry, Pearson Education 6

t h

edi t ion, 2006.M . J. Sienko and R. A. Plane, Chem ical Principles an d App licat ions, M cGraw Hi l l, 1980.

J. D. Lee, Con cise Ino rga nic Chem istr y, 4 t h edit ion , ELBS, 1991 .

D. D. Ebb ing, General Chemistry, Houghton M if f in Co. , 1984.

CH 117: Chem istry Lab - I 0 0 3 3

Experiments i l lustrat ing the concepts of 1) galvanic cel ls, (2) thermochemistry, (3)

chemical k inet ics, (4) equi l ibr ium constant , (5) analysis by oxidat ion reduct ion t i t ra t ion.

CH 206 Principles of Chem ical Ana lysis, Inorgan ic Chem istry Lab-I 1 0 3 4

Basic concept s of q uant itat ive analysis, m eth ods of samplin g, erro rs in chem ical analysis

of data, genera l theory of neutra l isat ion, redox, precip i ta t ion and complexometr ic

t i t ra t ions. Solubi l i ty product and precip i ta t ion, organic precip i tants and extractants. Abr ie f survey of separat ion m etho ds: so lvent extract ion and chrom atography.

Inorganic Sem i-micro quali t at ive analysis involv ing 4 radicals. Volum etr ic analysis

involv ing redox, precip i ta t ion and com plexom etr ic t i t ra t ions. Gravimet r ic est im at ion of

m et als. Analysis of al loys and m inerals.

Text / References

D. A. Skoog, D. M . W est and F. J. Holler, Analyt ical Chemist ry : An int roduct ion, 6 t h

edit io n, Saund ers College Publisher, 1994.G. H. Jeff ery, J. Bassett , J. M end ham and R. C. Denn y, Vogel s Text boo k of Quant i tat ive

Chem ical Ana lysis, 5 t h edit ion , ELBS, 199 1.

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CH 210 Inorganic Chem istry I 2 1 0 6

In t roductory survey of t ransi t ion e lements wi th reference to e lectronic conf igurat ion,

oxidat ion states, comp lex comp ound s. In t roduct ory concepts of m olecular sym m etry.

Spectra l and m agnet ic proper t ies. In t roduct ion t o theor ies of met a l- ligand bond ing and

stereochemistry. Chemistry of t i tan ium, vanadium, chromium, manganese sub-groupelements, i ron, cobal t , n ickel , p la t inum meta ls, copper and z inc sub-group e lements,group II I , IV, V, VI, VII and rare gases with reference to isolat ion, propert ies, uses and

impor tan t comp ounds.

Texts/ References

F. A. Cot to n and G. W ilkinson, Basic Ino rga nic Chem istr y, W iley Easter , 1978.

M . J. Sienko and R .A. Plane, Chem ical Principles and Proper t ies, M cGraw Hi l l, 1975.

J. D. Lee, Con cise Ino rga nic Chem istr y, Van No strand Reinhold, 1977.

CH 211 Physical Chem istry-I 2 1 0 6

Thermodynamic functions; Part ial molar quantit ies; Phase rule, phase equil ibr ia and

applicat ions; Non-ideal solut ions; M ixing and excess funct ions; Chem ical equil ibr ia.

Electrochemistry of solut ions: Ion-solvent interact ions; ion- ion interact ions; ionic

m igrat ion and d i f fus ion.

Text / References

L. I . Antrapo v, Theoret ical Electrochemistry, M ir Publishers, 1972.

J. OM . Bockris and A. K. N. Reddy, M odern Elect r ochem ist ry , Vol . 1 , 2 nd edi t ion, Plenum

Press, 1998.P. Atkin s and J. de Paula, Atkin s Physical Chem istr y, 8 t h edit ion, Oxford University Press,

2006.

G. W. Castellan, Physical Chemistry, 3 r d edi t ion, Addison - W esley/Narosa Publ ish ing

House, 1993.

G. N. Lew is and M . Randall , Thermodynamics , (Revised by K. S. Pitzer and L. Brewer),

In ternat ional Stud ents Edi t ion, M cGraw Hi l l , 1961.

CH 215 Physical Chem istry Lab -I 0 0 4 4

Potent iom etry, Electr ode pot ent ia ls, act iv i ty coef f icient , t i t ra t ion/ s, so lubi l i ty

produ ct .Condut om etry, t i t ra t ion/ s, d issociat ion of w eak acid as a funct ion of

concentrat ion. Ion izat ion constant by spectropho tom etry, enzyme k inet ics, use of

imm obi l ized enzym e e lectrode, adsorpt ion isoth em , M .O. m ethod s in chem istry .

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CH 221 Organic Chem istry- I 2 1 0 6

System at ic stud y of s t ructure, proper t ies and chem istr y of h ydrocarbons wi th em phasis

on t heoret ica l , s tereochem ical and m echanist ic concepts.

Text / References

P. Volhardt and N . Schore, Organ ic Chem ist r y : St r ucture and Funct ion, 5 t h Edit ion, W . HFreem an & Co, 2006 T. W. G. Solomons, C. B. Fryhle, Organ ic Chem ist ry , 9 t h Edit ion, Wilely India Pvt. Ltd.,

2009

R. T. M orr ison an d R. N. Boyd , Organ ic Chem istr y, 6 t h edit ion, Pearson Com ., 1992

CH 222 Organic Chem istry - I I 2 1 0 6

Prerequ isite : CH 221

Chem istry of heterofu nct ional organic com pound s. System at ic Stud y of st ructu re,

proper t ies and chemistry of heterofu nct ional organic comp ound s w i th emp hasis ontheoret ica l , stereochem ical and m echanist ic concepts.

Text / Reference

J. Clayden, S. Warren, N. Greeves, P. Wothers, Organic Chemistry, 1st Edit ion, Oxford

Univ ersit y Press, 200 0

P. Volhardt and N . Schore, Organ ic Chem ist r y : St r ucture and Funct ion, 5 t h Edit ion, W . H

Freem an & Co., 2006 T. W. G. Solomons, C. B. Fryhle, Organ ic Chem ist ry , 9 t h Edit ion, Wilely India Pvt. Ltd.,

2009

R. T. M orr ison an d R. N. Boyd , Organ ic Chem istr y, 6 t h Ed, Pearson Com ., 1992

CH 316 Inor ganic Chem istry Lab -I I 0 0 4 4

Complex mater ial analyses: minerals/ al loys. Quantitat ive est imations using

conductom etry and spectropho tom etry. Est im at ion of iron in i ron ore. Est im at ion ofm ixtur e of m etal ions by EDTA t i trat ions. Karl-Fischer Titrat io n.

CH 317 Organ ic Chem istry Lab -I 0 0 4 4

Determ inat ion of physica l constants, pur i f i -cat ion of so l ids and l iqu ids and m ethod s of

checking the ir pur i t y . Separat ion of enant iom ers and measurement s of opt ica l ro t at ion.

Studies of electrophil ic/nucleophil ic substi tut ion reactions, redox reactions.

Texts/ References

R. M . Rob ert s, J. C. Gilbert , L. B. Rod ew ard an d A. S. W ingro ve, M odern Exper im enta l

Organ ic Chem ist r y , Holf-Saund ers Intn l. Edn ., 4 t h edi t ion, 1985.

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CH 318 Organ ic Chem istry Lab -I I 0 0 4 4

Qualitat ive analysis of organic compounds. Chemical separat ion of binary mixtures and

th eir quali t at ive analysis.

Texts/ ReferencesR. L. Shriner, R. C. Fuson and D.Y. Curtin, Systemat ic Ident i f icat ion of Organic Com poun ds, a lab. manu al , 6 t h edi t ion W i ley, New York.

CH 402 Therm al and Photochem ical Reactions 2 1 0 6

Investigat ions of reaction mechanisms. Operational cr i ter ia for evaluation of

concer tedness in pot ent ia l per icycl ic react ions. Photochem ical act ivat ion and pot ent ia l

energy sur faces. Geom etry, d ipo le m om ents, acid-base and redox p roper t ies of excited

states. Uni- and bimolecular deactivat ions. Quenching mechanisms. Electronic energytransfer mechanisms. Corre lat ion ru les and symmetry conservat ion. In t ramolecular

( isomerizat ions, rearrangements and dissociat ion) and intermolecular (addit ions)

photochemical processes. Electrocycl ic reactions- Frontier orbital, orbital and state

corre lat ion d iagrams, conservat ion of orb i t a l sym m etr ies, and arom at ic t ransit ion state

approaches to electrocycl ic processes. Woodward-Hoffmann rules. Thermal and

pho to chem ical electro cycl ic pro ceses. Electro cyclic reactions of cat ions, anions, radicals

and radicals ions, M etal catalysis. Cycloaddit io n reaction s. FM O, orbit al and stat ecorrelat ion diagrams, and aromatic transit ion state approaches. Various [2+2] [4+2]

cycloaddit ion reactions. Reactivity and regioselect ivity in Diels-Alder reactions,

M ul t icomp onent cycloaddi t ions. Alder Ene React ion . Photochem ical cycloaddi t ions.

Transit io n m etal-catalyzed cycloaddit ions. General ized PM O theor y for reactivity,regioselect ivity and perselect ivity in cycloaddit ion. 1,3-Dipolar cycloaddit ions.

Chelet ropic react ions. Sigmatropic react ions-Appl icat ion of symmetry conservat ion

rules, arom atic transit ion stat e and FM O approaches. Various [1,3], [1,5], [1,7], [3,3] and

[5,5] shif ts. Fluxional M olecules. Sigmat ropic rearrangem ent s of charged system s, [3,2]

sigmatropic shif ts Ylide rearrangements, Dyotropic reactions. Photo-reactions ofnitrobenzyl, azo and diazo compounds, diazir ines and azides, caged compounds.

Chem i luminescent react ions. Singlet oxygen m ediated phot oreact ions.

Text / References

R. B. Woodward and R. Hof fmann, The Conservat ion of Orbi tal Symmetry, AcademicPress, New York , 1971.

M . J. S. Dew ar and R. C. Doughert y, The PM O Theory of Orga nic Chem ist ry , Plenum

Press, New York , 1975.T. L. Gilchrist and R. C. Storr, Organic React ions and Orbi tal Symmetry, 2n d ed i t ion ,

Cam bridge U niversity Press, Cam brid ge, 1979.

R. P. W ayne , Principles and Applicat ions of Photochemistry, Oxford Science Publications,

Oxford U niversity Press, Oxford , 1988.

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A. Gilbert and J. Baggot , Essent ials of M olecular Phot ochem istr y, Blackwell Scientific

Publicat ion s, Oxford & Bosto n, 1991.

M . Klessinger and J. M ichl, Exci ted Sta tes and Photo chemist ry of Organ ic M olecules, VCH

Publishers, Inc., New York , 1994 .

I. Flem ing, Pericyclic Reactions, Oxford U niversity Press, Oxford, 1998.

A. Rauk , Orbi tal Interact ion Theory of Organic Chem ist ry , 2 nd edit ion, Wiley Interscience,New York, 2001.S. Sankar am an, Pericycl ic Reactio ns- A Textb oo k, W iley-VCH, Weinh eim , 2005.

H. M askill (Ed.), The Invest igat ions of Orga nic React ions and Their M echanism s,

Blackw ell Pub lishing Ltd. Oxford , 2006.

N. J. Turro, J. C. Scaiano and V. Ramamurthy, Princ iples of M olecular Phot ochemist ry ,

University Science Books, 2008.

CH 416 Physical Organic Chem istry 2 1 0 6

M odern th eory of organic st ructures and bondin g. Sym m etry-adapted orb i t a ls.

Per turbat ion theory and orb i ta l mix ing ru les. Bui ldup approach to large molecular

structures. Bonding and structure of reactive intermediates: Carbocations, carbanions,

and carbenes. Relat ion between structure and energetics. Solut ions and forces of

molecular recognit ion. Bronsted acid-base chemistry. Lewis acids/bases, electrophiles

and nucleophiles. Reactivity, kinet ics, and mechanisms. Energy surfaces and transit ion

states. Hammond Postu late. Isotope ef fects. Hammet p lot . Ster ic and polar e f fects.Em pir ical scales of solvent eff ect. pH and Bronst ed relat ion ship. M echanism and

catalysis of proton transfer. General pr inciples of catalysis. Enzyme-catalyt ic effect and

concept of transit ion-state stabi l izat ion. Investigat ion of organic reaction mechanisms

by physical organic approach. Examples i l lustrat ing applicat ion to investigat ion ofelectrop hil ic/ nucleop hil ic reaction s, and enzym e-catalyzed reactio ns.

Text / References

E. V. Anslyn an d D. A. Dou ghert y, M odern Organ ic Chem ist ry , Univer sity Science, 2005.

A. Pross, Theory an d Physical Principles of Org anic Reactivi t y, Joh n W iley, 1995.A. Rauk, Orbi ta l Interact ion Theory of Orga nic Chem ist ry , John W iley, 1994.

T. H.Lowry and K. H.Richardson, M echanism s and Theory in Organic Chem ist ry , Harper

and Row , 1976.

CH 418 Organ ic Chem istry Lab I I I 0 0 4 4

Chemical separat ion of ternary organic mixtures and character izat ion of thecomponents. Simple one or two step prepara- t ions involv ing d i f ferent techniques.

Iso lat ion of natura l produ cts.

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CH 419 Separat ion Techniques Lab 0 0 4 4

Separatio n by Soxhlet and liquid - l iquid extract ion. Cation and anion exchange

chrom atography, co lumn , th in layer and paper chrom atography, gas- liqu id and gel

perm eat ion chrom atography. Fract ional d ist i l lat ion.

Texts/ ReferencesB. L. Karger, L. R. Snyder and C. Horvath, An Int r oduct ion to Separat ion Science, John

W iley and Son s, Inc., 1973.

J. A. Dea n, Chem ical Separa t ion M ethods, Van Nostr and Reinho ld, 1970.

D. J. Past o an d C. R. Joh nson , Organ ic Str ucture Determ inat ion, Prent ice Hall, 196 9.

CH 423 Organic Chem istry- I I I 2 1 0 6

A reappraisal of str uctu re, stereochem ical pr in ciples, pro pert ies and reactivit y inorganic com pou nds. Stu dy of the fo l low ing classes of reactions, nucleoph il ic

substi t ut ions, el im inatio ns, electro ph il ic addit ions, electrop hil ic and nu cleophil ic

subst i tu t ion in arom at ic comp ounds, nucleophi l ic addi t ion, ha logenat ion, and a lky lat ion

of carbon yl com po un ds. Reactions involving enam ines, ester enolates and act ive

methylenes.

Chem istr y of conjugate d dienes, enon es. Pericyclic reaction s, FM O th eory.

Phot ochemical react ion s. Al iphat ic and arom at ic n i t ro and amino comp ound s.Oxidat ion and reduct ion react ions.

Texts/ References

J. Clayden, S. Warren, N. Greeves, P. Wothers, Organic Chemistry, 1st Edit ion, OxfordUniv ersit y Press, 200 0

F. J. Carey and R. J. Sundburg, Advanced Organ ic Chem ist ry , Part A and Part B, 5 t h Ed.,

Springer, 2007

J. M arch, Advanced Org anic Chem ist ry , 3 r d edi t ion, M cGraw Hi l l ,1991.

S. H. Pin e, Organ ic Chem ist ry , 5 t h edi t ion, M cGraw Hi l l, 1987.

CH 425 Chem ica l Bond and M olecular Geom etry 2 1 0 6

Postu lates of quant um m echanics; herm it ian operators; com plete set . Der ivat ion of t heuncer ta in ty re la t ions. Exact ly so lvable problems, orb i ta l angular momentum, and the

hydrogen atom. Spin, spin orbitals, and character ist ics of a many-electron wave

func t ion .Var ia t ion t heorem , var iat ion m ethod , the l inear var iat ion m ethod , and the non -crossing

rule. Applicat ions: M any-electron atom s, self-consisten t f ield, atom ic orb itals, Slater

Type Orbit als, Slater exponen ts and the periodi c pro pert ies of elem ent s; LCAO-M O,

Hckel orb i ta ls; Born-Oppenheim er appro ximat io n, Potent ia l energy sur face, Hel lman-

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Feynman theorem; Hydrogen molecule ion, Hydrogen molecule; Qual i ta t ive molecular

orb i ta ls for h om o- and h etero-nuclear d ia tom ics, isoelectro nic pr inc ip le , hybr id orb i ta ls,

and W alsh m olecular orb i t a l d iagram.

Time- independent per turbat ion theory - Rayle igh-Schrdinger formulat ion.

Applicat ions: Zeeman effect, Stark effect, crystal f ield spl i t t ing, and simple l igand f ield

t rea tments .The valence bond t reatm ent of hydr ogen mo lecule; Resonance; Polar i ty and d ipolem om ent; Electron egat iv i ty ; Valence-bond w ave funct ions for p o lyatom ic m olecules.

Texts/ References

R. M cWeeny, Coulsons Valence, Oxford Un iversity Press, 1979.

D. A. M cQuarr ie , Quantum Chemist ry , Oxford Univ ersity Press, 1983.

I. R. Levine , Quantum Chemist ry , Prent ice Hall India (Ltd ), 1995.

S. N. Dat t a, Lectu res on Chem ical Bonding and Qua ntu m Chem ist ry , Pr ism Books, 1998.

CH 426 Rate Processes 2 1 0 6

Rates of chem ical react ions, ra te expressions. M ethod s of determ in ing rates and ord ers

of reaction s. Com plex reaction s. Coll ison and transit ion stat e th eories of chem ical

reaction rates. Potent ial energy surfaces and reactio n dynam ics. Applicat io n to

unim olecular and bim olecular reaction s. Hom ogeneou s catalysis, chain reaction s.

Photo chem ical reaction s. Fast reaction s. Dif fusion in sol ids, l iquids and solut ions.Chem ical osci l lat ion s and non linear dynam ics.

Texts/ References

K. A. Connors, Chem ical Kinet ics : A Stu dy of Reaction Rates in Solut ion, V.C.H.Publicat ion s 1990.

J. I. Steinfeld, J. S. Francisco and W.L. Hase, Chem ical Kinet ics an d Dynam ics, Prentice

Hall 1989.

K. J. Laidler, Chem ical Kinet ics, 3 r d edi t ion, Harper and Row , 1987.

R. D. Levin e and R. B. Bern stein , M olecular React ion Dynam ics and Chem ical React iv ity ,Oxford Univer sity Press, 1987.

J. W . M oore and R. G. Pearson, Kinet ics and M echanism s, Joh n W iley and Sons, 1981.

CH 427 Chem ical and Stat ist ical Therm odynam ics 2 1 0 6

Appl icat ions of thermodynamic funct ions; par t ia l molar quant i t ies; non ideal i ty and

activit ies; chem ical equil ibr ia. Ensem bles, M B, BE and FD distr ibut ions; Part i t io nfunct ions and the ir re la t ionships to t herm odynam ic funct ion s and equi l ibr ium constant ;

Vir ia l coef f ic ients; Lat t ice M odels; In t ro duct ion to non-equi l ibr ium therm odynam ics;

Onsager`s reciprocit y relat ions.

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Text / References

P. Atkin s and J. de Paula, Atk ins Physical Chem istr y, 8 t h edit ion, Oxford U niversity Press,

2006.

K. S. Forland, T. Forland and S.K. Ratkje, I rreversible Therm od ynam ics, Theory an d

Appl icat ions, John W iley,1988.

G. W. Cast ellan, Physical Chemistry, 3 r d edit ion , Narosa Publishing House, 1985R. S. Ber ry , S. A. Rice an d J. Ross, Physical Chem ist ry, John W iley, 1980.F. T. W all, Chem ical Therm odyna m ics, W . H. Freem an and Co., 1965.

G. N. Lew is, M . Randall, K.S. Pit zer and L. Brew er, Thermodynamics , M cGraw Hi l l , 1961.

T. L. Hil l, Sta t ist ical Thermo dynam ics, Addison W esley, 1960.

D. A. M cQuarr ie and J. D. Sim on , Physical Chem ist ry - a m olecular appr oach, Viva Boo ks

Pvt. Ltd . ( 1998 )

CH 429 M odern M ethods of Ana lysis 2 1 0 6

Evaluation of r el iabi l i ty of an alyt ical data and stat ist ics in chem ical analysis. Expression

of results to signif icant f igures. Sam pling and preparat ion of sam ple for

analysis. In t ro duct ion t o op t ica l met hods, u l t rav io le t , v isib le , in f rared spectrophot om etry

and f luor imetry. Atomic absorpt ion and f lame emission spectroscopy. Scat ter ing of

radiat ion, nephelom etry, turb id im etry and Ram an Spectroscopy. Electroanalyt ical

m etho ds such as vo l tam m etry, po larography, am perom etry, conductom etry and h igh

frequency t i t ra t ions. Thermogravimetry and d i f ferent ia l thermal analys is . In t roduct ionto in terphase separat ions wi th specia l re ference to chromatography. Gas

chrom atograp hy and HPLC.

Text ReferencesG .W . Ew ing, Instrum ent al m eth ods of chem ical analysis, 5th Edit ion, M cGraw -Hil l ,

1985.

H. H.Wil lard, L. L.M err i t , J. A. Dean and F. A. Sett le, Instru m ent al M eth ods of A nalysis,

6th Edit ion, Van Nostr and Reinho ld, 1980.

H. A. Lait inen and W . A. Harr is, Chem ical Analysis, 2nd Edit ion M cGraw -Hil l , 1975.

CH 432 Inor ganic Chem istry Lab I I I 0 0 4 4

Complexometr ic t i t ra t ions by masking and demasking react ions. Est imat ions bynephelometry, f luor imetry,s imul taneous spectrophotometry, a tomic absorpt ion

sepectroscopy. Determ inat ion of com posit ion of com plexes in so lut ion. Synth esis and

character izat ion of t ransi t ion m eta l com plexes ( inc lud ing organom eta l l ic com poun ds)and the ir stud y by spectra l , m agnet ic and therm al m ethod s.

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CH 433 Physical Chem istry Lab I I 0 0 4 4

Phase equil ibr ia, viscosity and molecular weight of polymers, surface tension, reaction

kinet ics ( ra tes, order of react ion, in f luence of ion ic s t rength) , use of thermocouples,

t ransit ion t em perature determ inat ions, se l f generated exper iment .

CH 434 Physical Chem istry Lab I I I 0 0 4 4

Determ inat ion of the fo l low ing physical quant i t ies : par t ia l m ola l vo lum es, d ipo le

m om ents, act iv i t ies by f reezing point , quantu m yie lds, heats of vapor isat ion and

depressions of freezing poin ts of solut ions, velocity constant and act ivat ion energy.

Electro des wi t h d i f ferent substrates for H2 evolut ion, photoelectrochemical solar cel ls.

Vacuum m easurem ent. IR spectrum of HCl, Use of M .O. theory, so lut ion of Schrodinger

equat ion for po lyatom ics.

CH 437 Chem istry of Transit ion Elem ent s 2 1 0 6

General chem istry of t he t ransit ion e lem ents, lanthanides and act in ides inc lud ing

atom ic nucle i and nuclear react ions, coord inat ion chem istry inc lud ing theor ies of m eta l-

l igand bond ing, spectra l and m agnet ic proper t ies, organom eta l l ic comp ounds of

t ransit ion e lement s, ro le of t ransi t ion m eta l ions in b io log ica l processes.

Texts/ References

F. A. Cot to n, G. W ilkinson, C. A. M uri l lo and M . Bochm ann , Advanced Inorganic

Chemistry, W iley Easter n, John W iley, 6 t h edi t ion, 1999.

J. E. Huheey, E. Keiter and R. Keiter, Inorganic Chemistry, 4 t h edit ion, Harper Coll insCollege Publisher , 1993.

D. Banerjea, Inor ga nic Chem istr y Principles, Books Synd icate Pvt . Lt d., 2000

N. N. Greenw ood and E. A. Earnshaw , Chem ist ry of Element s, Pergam on Press, 1989

CH 438 Chem istry of M a in Group Elements 2 1 0 6

Chem istry of non- t ransi t ion e lem ents, stereochem istry and bonding in non- t ransit ion

elem ent s and com pou nd s. Solvent s, solut io ns, acids and bases, br ief r eview of ino rganic

chains, r ings and cages, organometal l ic compounds of non-transit ion elements, role ofnon -transit ion elem ent s in bio logical pro cesses.

Texts/ ReferencesF. A. Cot t on, G. W ilkinson, C. A. M uri l lo and M . Bochm ann, Advanced Inorganic

Chemistry, John W iley, 6 t h edi t ion, John W i ley, 1999.

C. Elschen br oich and A. Salzer, Organometa l l i cs , 2 nd edit ion, W iley VCH, 1992.

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D. F. Shriver, P. W. Atkins and C. H. Langford, Inorga nic Chem ist r y , Oxford University

Press, 3 r d edi t ion, 1999.

CH 481: Chem istry and Com put ers 2 0 2 6

Numerical computing using a high level language l ike FORTRAN/C: Programmingprinciples using loops, arrays and functions; use of l ibrar ies; Numerical methods:

t runcat ion and round of f er rors; roots; in terpolat ion; d i f ferent ia t ion and in tegrat ion;

l inear equat ions, matr ix operat ions; curve f i t t ing; ODEs; opt imizat ion; Appl icat ion of

num er ica l m etho ds to chem ical problem s.

Text / References

S. J. Chapman, Fort ran 90/95 for Sc ient is ts and Engineers, 2 nd edi t ion, M cGraw-Hi l l ,

2003.

W . E. M ayo and M . Cw iakala, Programming with FORTRAN 77, Schaums Outl ine Series,M cGraw Hi ll , 1995.

A. Kelly and I. Pohl, A book on C4 t h edit ion, Addison-Wesley, 1999.

S. C. Chapra and P. Canale, Num erical M etho ds for Engineers4 t h edi t ion, Tata M cGraw -

Hil l , 2002.

R. J. Schilling and S. L. Harris, Appl ied Num erical M ethod s for Engineers: Using M ATLAB

and C , Brooks/Cole Publ ish ing Com pany , 2000.

J. H. M athew s, Num erical M ethods for M ath ema t ics, Sc ience, and Engineering 2nd edit io n, Prent ice Hall of India, 2001.

CH 502 Synthe sis and character izat ion of Inorganic Com pou nds. 2 1 0 6

Preparat ive chemistry of compounds of main group and t ransi t ion e lements inc lud ing

inorganic chains, r ings, cages, cluster s, halogen and rare gas com po und s. Experim ent al

problems encountered in the synthesis, iso lat ion, pur i f icat ion, character izat ion and

ident if icat ion of inorganic com po und s. Physical m eth ods for character izat ion , PES,EXAFS, M ossbauer spectr oscopy, magnet ic susceptibi l i t y and cycl ic volt am m etr y.

Text / References

R. S. Dr ago, Physical M etho ds for Chemists , Saund ers, 1992.R. J. Angelias, Synthesis and Techniques in Inorganic Chemistry, 2 nd edit ion, Saunders,

1977.

G. Pass and H. Sutchliffe, Pract ical Inor ga nic Chem istr y: Prepara t io n, Reactio ns an dI nst rum enta l M e thods , 2 n d edit ion, Chapm an and Hall , 1974.

W. L. Jolly, The Synth esis and Character izat ion o f Inorganic Com pound s, Prent ice Hall ,

1970.

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CH 504 Com puta tional Chem istry 1 0 4 6

A br ie f out l ine of molecular mechanics, semi-empir ica l approximat ions, ab in i t io

methods, basis sets and Z-matr ix ; Appl icat ion of these computat ional methods for

predict ion of s t ructura l and e lectronic proper t ies of molecules by using standardprogram s; FM Os in organic chem istr y, crystal and l igand f ield calculat ions, com put at ionof potential energy surfaces. Conformational analysis by molecular mechanics;

Dynamical and st ructura l s tud ies of molecules using molecular dynamics s imulat ions;

M ont e Car lo sim ulat ions of m olecules.

Texts/ References:

C. J. Cram er , Essent ials of Com put at ion al Chem ist ry : Theories and M odels , Joh n W iley &

Son s, 2002.

D. Young, Computat ional Chemist ry : A pract ical Guide for apply ing Techniques to Real

W or ld Prob lems, Wiley Int erscience, 2001.A. R. Leach , M olecular M odel l ing: Pr inc iples and Appl icat ions, Pearson Educatio n, 2001.

J. B. Foresman, A. Frisch, Explor ing Chem ist r y w i th Elect ronic Str ucture M ethod s.

Gaussian In c., 1996.

M . P. Allen and D. J. Tildesley, Com put er Simu lat ions of Liquids, Oxfor d, 1987

A review o f var ious synt het ic m eth ods in organic chem istr y: Form at ion of C-C, C=C, CC

bonds and various r ings (namely 3, 4, 5, 6, 7 and 8-membered r ing) with special

emphasis on ut i l i ty of several types of organometal l ic reagents. Selected syntheses ofnatura l and unnatura l products having these r ing systems. A concise in t roduct ion to

various aspects of asymmetr ic synthesis fol lowed by detai led discussion on resolut ion,

chiral auxi l iar ies, chiral l igands, chiral catalysts, and organocatalysts with specif ic

examples. A br ief discussion on biosynthesis and biomimetic synthesis with selectedexamples from monoterpenes, sesquiterpenes, diterpenes, steroids, and alkaloids.

In t roduct ion of domino and tandem react ion concepts wi th a deta i led d iscussion on

selected exam ples.

Texts/ References:

G. S. Zw eifel and M . H. Nantz, M odern Or ganic Synth esis-An Int ro duct ion, W. H.

Freem an and Comp any, 2006

F. A. Carey, R. Sundberg, Advanced Organic Chemistry, Part B, 5 t h edit ion, Plenum Press,

2007. R. O. C. Nor m an and J. M . Coxon Principles of Organic Synthesis 3 r d edit ion, Nelson

Thornes, 2005.

M . B. Sm ith and J. M arch, M archs Advanced Org anic Chem ist ry , 5 t h edi t ion, W i ley, 2001.

B. M . Trost and I. Flem ing, Com preh ensive Orga nic Synt hesis, Pergam on Press, 199 2

CH 507 M etho ds in Organic Synthe sis 2 1 0 6

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CH-5 08 Bioorganic chem istry 2 1 0 6

General com par ision of organic react ions carr ied out in laboratory and organic

reactions observed in biological system s. Natu re of biom olecular int eract ion s, ph ysical

concepts. Ster eospecif ici ty and rate enhancem ent in enzym e catalysed reactions.

Discussion on no n-availabi l ity of electrop hil ic sites in enzym es and th eir presence in co-enzym es. Follow ing reaction s w il l be discussed (comp aring th e usual m echanism t oenzyme catalysed mechanism) : hydrolysis of esters, amides, phosphoesters, etc. C-C

and C=C bond fo rm at ion, ox idat ion,reduct ion and decarboxylat ion. Rem ote

functionalisat ion cycl isat ion reactions. Biomimetic reactions. Hydrophobicity,organized

assemb lies. Supram olecular str uctu re, dru g design.

Text / References

Bioorg an ic Chem istr y Fron t iers Vol.2, Ed. H. Dugas, Spr inger- Verlag, pp.1 -252, 199 0.

H .Dugas, Bioorg anic Chem ist ry . A Chem ical approach to enzym e act ion, 2nd Edn.,

Springer-Verlag, 1989.D. E.M etzler, Biochem istr y-The Chem ical Reactio ns of a Living Cell , Academ ic Press,

1977.

E. E. Tam len , Bioorgan ic Chem ist ry , Academ ic Press, 1977.

CH 510 H ete rocyclic chem istry 2 1 0 6

In t roduct ion t o heterocyclics and the ir im por t ance. Nom enclature of r ing system s,

st ructu re, react iv i ty and synth esis of reduced th ree, fou r , f ive and six m em bered

oxygen, n i t rogen and sulphur heterocycl ics; aromat ic heterocycl ics, 5-membered, 6-

m em bered and polyhetero r ing system s - indole, azoles and d iazines. Const i tu t ion andconfigurat ion of sim ple sugars, chem ical reaction s of m ono saccharides and th eir cyclic

anomers.

Texts/ References

R. K. Bansal, Heter ocyclic Chem istr y, Synt hesis, Reactio ns an d M echanisms, Wi leyEastern Lt d., 1990.

J. A. J. Jou le an d G. F. Sm it h , Hetero cycl ic Chem istr y, ELBS, 2 nd edi t ion, 1982.

F.G. Riddell, The Confo rm at iona l Analy is of Heterocycl ic Com pound s, Academic Press,

1980.

L.A. Paquet te, Principles of M od ern Heter ocycl ic Chem istr y, W .B. Benjam in, Inc., 1978.B.M . Acheson, An Int roduct ion to the Chemist ry of Heterocyc l ic Compounds,

Interscience, 2 nd edi t ion 1975.

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CH 521 Interp retat ive M olecular Spectroscopy 2 1 0 6

M ass spectrom etry, the product ion and analysis of posit ive ions, m olecular ions,

appl icat ion of isoto pic abundance m easurem ents, f ragment at ion m odes and

rearrangem ent of ions. M ass spectra of cert ain chem ical classes. Electron ic

spectroscopy (UV-visible,f luorescence and phosphorescence):Simple chromophoricgroups, conjugat ed and arom atic system s. Character ist ic absorpt ion of organic andinorganic compounds. Infrared spectroscopy:Character ist ic group frequencies of organic

and inorganic molecules. Nuclear magnetic resonance spectroscopy of compounds

conta in ing 1H, 13 C,19 F and 31 P nucle i . Ident i f icat io n of organic and inorganic comp ounds

using comb inat ion of spectra l data.

Text / References

R. S. Dr ago, Physical M etho ds for Chemists , W. B. Saund ers,1992.

R. M . Silverst ein, C. G. Bassler and T. C. M or ril, Spectropho tom etr ic Ident i f icat ion of

Organ ic Com pound s, 5

t h

edi t ion,W i ley, 1991.D. H. Wil l iams and I. Fleming, Spectro scopic M eth ods in Orga nic Chem istr y, 3 r d edi t ion,

M cGraw Hi ll , 1980.

W . Kemp, Orga nic Spectr oscopy, ELBS, 19 79 .

W. L. Jolly, The synthesis and character izat ion of inorganic compounds, Prentice-Hall,

1970.

CH 522 Chem istry of Coordinat ion com pou nds 2 1 0 6

Classif icat ion of l igands by donor atoms, stabi l i ty, reactivity, bond types, geometry and

coord inat ion com poun ds. Kinet ics and mechanism of react ions of t ransit ion met a lcom plexes : substi t ut ion reaction s, electro n tra nsfer redox pro cesses, acid base and

re lated p rocesses. Inorganic photo chemistry of coord inat ion com pound s.

Text / References

F. A.Cot to n ,G. Wilkinson, C. A. M uri l lo and M . Bochm ann, Advanced Inorganic Chemistry, 6 t h edi t ion, W i ley, 1999

J. E. Huheey, E. Keiter and R. Keiter , Inorganic Chemistry, 4 t h edit ion, Harper Coll ins

College Publisher , 1993.

R. G. Wilkins, Kinet ics and React ion M echan ism of Transit ion M etal comp lexes, 2nd

revised edit ion , VCH, New York, 1991.F. Basolo an d R.G. Pearson, M echanism of Inorga nic React ions, 2nd Edi t ion, W i ley, 1967.

CH-523 M olecular Spectroscopy 2 1 0 6

In t roduct ion to spectra l energy domains and measurement of spectra, Impl icat ions of

discrete energy levels, Populat ion of States Boltzman Distr ibut ion, Interact ion of

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radiat ion wi th mat ter , or ig in of l inewidths in molecular spectra, Transi t ion d ipo le

m om ent and Ferm i's Golden Rule, Einsteins Coeff icient s, Lasers and M asers;

Rotat ional (M icrowave) spectroscopy, M olecular v ibrat ions - In f rared spectroscopy,

Norm al m ode analysis, Ram an Scatt er ing, Select ion Rules from Group Theo ry, M olecular

electron ic spectra, Phot oph ysical pro cesses, Non-Linear Spectro scopy, Nu clear M agnetic

Resonance, Relaxation t im es, FT-NM R, spin-spin coup ling, ESR, Nu clear Quad rup olarResonance.

Text / References

J. L. M cHale, M olecular Spectroscopy, Pearson Educat ion, 1999.

M . Hol las, M odern Spectroscopy,W iley; 4 t h edi t ion, 2004.

F. A. Cotton, Chemical Appl icat ions of Group Theory, 3 r d edit ion, Wiley-Interscience,

1990.

D. C. Harr is, M . D. Berto lucci, Sym m etry and Spectroscopy, Dover, 1990.

C. M . Banw ell, E. M . M cCash, Fund am entals of M olecular Spectroscopy, Tata M cGraw

Hil l , 1983G. M . Bar row, M olecular Spectroscopy, M cGraw Hi ll , 1962

J. I. Steinfeld, M olecules and Radiat ion: An In t roduc t ion to M odern M olecu lar

Spectroscopy, 2 n d edi t ion, Dover , 2005.

J. D. Grayb eal, M olecular Spectroscopy, M cGraw Hi l l 1993.

D. A. M cQuarr ie and J. D. Sim on , Physical Chem ist ry - a m olecular appr oach, Viva Boo ks

Pvt. Ltd . 1998.

CH-5 24 Bioinorganic Chem istry 2 1 0 6

Chemical make up and essential inorganic elements of organisms. Chemistry aspects ofmetal complexes. Spectral, biochemical and biological methods used in bioinorganic

chemistry. Bio inorganic chemistry of Na+, K+, M g2+ and Ca2+ . Role of metal ions in

biology: Prot eins and enzym es of V, M n, Fe, Co, Ni, Cu, Zn and M o. Str uct ural and

funct ional mod els. Transpor t and storage of met a l ions. Carcinogenici ty o f chrom ium .

Selenium in biology.

Text / References

S. J. Lipp ard and J. M . Berg, Principles of bioinorganic chemistry, University Science

Books, M il l Valley, 1994.

I. Bertin i, H. B. Gray, S. J. Lipp ard and J. S. Valent im e, Bioinorg anic Chem ist ry , Univ. Sci.Books, M il l Valley, 1994.

J. A.Cow an, Inorgan ic Biochemist ry , VCH Publ ishers, 1993.

J. Reedij k, Bioorg an ic Cat lysis, M arcel Dekker,Inc.(Ed.), 1993.R. W.Hay , Bioinorg anic Chem ist ry , El l is Hollwo od ,Ltd .1984.

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CH 528 Na tural Products 2 1 0 6

Terpenoids : Classif icat ion, structu re, chem istr y and biogenesis of som e im port ant

m ono; sesqui ,d i , and t r i ter p enes.

Steroids : Ster ols and bi le acids, estr ogens, andro gens, gesto gens and adren ocort ical

horm ones. Horm on e pro du ction. Cardiac glycosides. Ster oidal t r i ter pen es; biogenesis ofstero ids and corre lat ion w i th t erpenoids.Alkaloids : Character ist ic reactions, general m eth ods of degradatio n, struct ure and

chemistry of som e w el l -know n a lkalo ids.

Natural Pigments: Flavones, f lavanones, isof lavones, xanthones, quinones, pter ins,

ch lorop hyl l and haem in.

Carbohydrates: Stereochem istry, react ion and conform at ion of m onosacchar ides, deoxy

and am inosugars, hexonic acid and vitam in C, disaccharides, polysaccharides, inosito l;

gan- gliosides and o th er glycosides. Chem istr y of vitam ins A,B,C and E.

Text / ReferencesI. L. Finar , Orga nic Chem istr y, Vol .2, 5 t h edit ion , ELBS, 1975.

K. Nakanishi, T. Goto, S.Ito, S. Najori and S. Nozoe, Nat ural prod ucts Chem ist ry , Vol. 1

and 2 , Academ ic Press, 1974 .

A. A. Newm an, Chem istr y of Terpen es an d Terpen oids, Academ ic Press, 1972 .

S. W . Pellet ier, Chem ist r y of t he Alkaloids, Van No strand Reinho ld, 1970.

C. W.Shoppee, Chem ist r y of th e Steroids, 2 n d edi t ion, But ter w or th s, 1964.

R. D. Gut hr ie and J. Honeym an , An Int ro duct ion t o th e Chem ist r y of Carbo hydrat res, 3 r d edit io n, Clarend on Press, 1968.

T. A. Geissm an, Chem ist ry o f Flavonoid Com pou nds, Pergam om n Press, 1962.

CH 54 0 D rugs and Biologically Active Com pou nds 2 1 0 6

Drug recepto r in teract ion s. Approaches to drug design. Drug m etabol ism . A few drugs

from each of the fo l low ing groups wi l l be d iscussed.

Analgesics, antidepressants, antipsdychotics, anti inf lammatory agents, cardiovascularagents, diuret ics, ant ibacter ials, ant ibio t ics, antivirals, ant im alar ials, ant iam oebics, drugs

for neoplastic diseases.

Vitamins : A, B1, B2, B6 niacin, fol ic acid, dantothenic acid, biot in, B12,C,D,E and K.

Horm ones : Thyro id horm ones and ant i t hyro id drugs. Stero id horm ones and som e

imp or tant stero ida l drugs.

Texts/ References

A. Burger, M edicinal Chem ist ry , 4 t h edit ion, W iley Inte rscience, 1981.R. F. Doerge, Ed., W ilson and Gisvelds Text Book o f Org anic M edicinal and

Pharm aceut ical chem ist ry , 8 t h edit ion , J. B. Lippin cot t Co., 1982.

D. Lednicer and L. A. M itscher, The Organic Chem istr y of Drug Synt hesis, W iley

Inter science, 1977.

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O. L. Salerini, Nat ural and Synthet ic Organ ic M edicinal Com poun ds, C. V. M osby Co.,

1976.

CH 546 Introd uction to Biom olecules 2 1 0 6

M olecular log ic of l iv ing m atter . Or ig in of b iom olecules. Cel l st ructu re. Am ino acidsstructure, funct ional group proper t ies and react ions. Prote in st ructure, conformat ion

and biomolecular interact ions. Sugar-polysaccharides, structure and functions.

Nucleotides, nucleic acids structure and function, DNA organisation, repl icat ion,

transcr ipt ion, r ibosomes, gentic code and protein synthesis. Enzymes-categorizat ion,

catalysis, kinet ics-single substrate enzyme catalyzed reactions, inhibit ion. Lipids-

st ructure and prop- er t ies of d i f ferent c lasses of l ip ids. Biomembrane organisat ion-

m em brane lip ids. M em brane bound prot e ins-st ructu re, proper t ies and t ranspor t

phenomena. Bioenergetics-basic pr inciples, glycolyt ic pathways, Kreb's cycle, oxidative

pho sphorylat ion, coupled p rocesses. Photo synthesis.

Texts/ References

J. M . Berg, J. L. Tym oczko , L. St ry er, Biochemistry, International Edit ion, W. H. Freeman

and Com pany, 2006.

A. Lehninger, D. L. Nelson, M . M . Cox, Principles of Biochemistry, 5 t h edi t ion, W. H.

Freem an and Comp any, 2008.

G. M . Blackburn, M . J. Gait, D. Loakes, D. M . W il l iam s, Nucleic Acid in Chemistry andBiology, 3 r d ed itio n, RSC Publishin g, Lon do n 200 6.

V. Voet and J. G. Voet, Biochemist ry , John W iley, New York , 2004.

R. J. Sim on d , Chem ist ry of Biomo lecules, Royal Society of Chem istr y, U.K. Lon don , 1992.

CH-547 Organom etal l ic Chem istry 2 1 0 6

Histor ica l background, factors contro l l ing met a l-carbon bond form at ion, met hods of M -

C bond form at ion, com parat ive survey of st ru cture and bond ing of m eta l alky ls andaryls,com plexes w ith p acids, CO and related l igands, com plexes w ith olef in s,

acety lenes and re lated unsaturated molecules, cata ly t ic proper t ies of mononuclear

compounds, s tereochemical non-r ig id i ty in organometa l l ic compounds, boranes,

carboranes and m etal locarbo ranes, bim etal l ic and cluster com plexes, structu re and

applicat ions in catalysis, app licat ion s of organom etal l ic com pou nds in organic synt hesis,enant ioselect ive synth esis v ia organom eta l l ic comp ound s, imp or tance of

organomet a l lic com poun ds in cer ta in b io log ica l system s.

Text / re ferences

G. O. Spessard, G. L. M iessler, Organ om etal l ic Chem ist r y , Prent ice Hall , 1997.

C. Elsehenb ro ich an d A. Salzer, Organ om etal l ic Chem ist ry , 2 n d edit ion, W iley VCH, 1992.

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F. A. Cot t on, G. Wi lk inson, C. A. M ur i l lo and M . Bochm ann, Advanced Inorganic

Chemistry, 6 t h edi t ion, W i ley, 1999.

N. N. Greenwo od and A. Earnshaw , Chem ist ry o f t he Element s, 1 st edi t ion, Pergamo n,

1985.

B. F. G. Joh nso n, Transi t ion M etal Clusters, Wiley, 1980.

G. Wilkinson, F. G. A. Stone and E. Abel, Comprehensive Organometal l ic chemist ry ,Pergamon, 1980.

CH 550 Electro chem istry 2 1 0 6

Nernst eq uatio n. Origin of EM F of a galvanic cel l . Polar izable and n on -polar izable

electrod es, the e lectrocapi llary curve, nu l l po int o f m eta ls and i ts determ inat ion.

Therm odynam ics of e lect r ica l double layer , Lipm ann equat ion, m easurem ent of sur face

excess. M odels for t he electr ical dou ble layer. Electrod e kinetics. The concept o f over

pot ent ia l . Electrochem ical react ion s under m ass t ransfer cont ro l , chronopot ent iom etry,vo l tammetry and polarography. Electrochemical react ions under charge t ransfer

contro l , genera l ized But ler Volmer equat ion, determinat ion of k inet ic parameters.

M echanism and e lectrocata lysis of hydr ogen and oxygen evolut ion react ions.

Text / References

D. I . Antro pov, Theoret ical Electrochemistry, M ir Publishers, 1972.

J. Koryt a, J. Dvo rak, V. Boh ackova, Electrochemistry, M ethuen & Co. Ltd. , 1970.

J. OM . Bockris and A. K. N. Reddy, M odern Elect ro chemist ry , Vol .1 and 2, Plenu m Press,

1998.

CH 552 Interfacia l Phenom ena 2 1 0 6

Adsorpt ion isot herm s: Langm uir, BET, Frum kin, Tem kin and Freund lich. Adsorpt ion on

poro us sol ids. Chem isorpt ion of gases on m etals and sem icondu ctors. Kinet ics of

adsorpt io n pro cesses, het erogeneo us catalysis. Catalysis by m et als, semicondu ctor s

and sol id acids. Character izat ion of sol id surface struct ure and com posit ion using

elect ron m icroscopy , FEM , XPS, Auger, M ossbauer , SIM S, ISS and LEED.

Text / References

D. K. Chakr abart y, Adsorpt ion a nd catalysis by sol ids, W iley Easter n, 1990.F. P. Kane an d G. B. Larrab ee (Eds.), Characterisat ion of sol id surfaces, Plenum , 1978.

A. W. Adamson, Physical Chem istry o f Sur fa ces, 3r d edi t ion, W iley Inter science, 1976.

A. Clark, The Theory of Adsorpt ion a nd Cat alysis , Academic Press, 1970.

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CH 556 : Polym er Science 2 1 0 6

In t roduct ion and appl icat ions of po lymers, molecular weight d is t r ibut ions, var ious

experimental methods (GPC/SEC, solut ion viscosity, VPO, l ight scatter ing) to determine

re lat ive and absolute molecular weight d is t r ibut ions, chain growth and step growth

mechanisms and kinetics, ionic polymerizat ion, l iv ing polymerizat ion, stereochemistry ofpolymers, f ree radica l copolymer izat ion ( random, b lock, a l ternate and graf tcopolymers) , k inet ics and m echanisms of f ree radica l copolym er izat ion, po lymer izat ion

condi t ions and polymer react ions, thermal , mechanica l and so lut ion proper t ies of

polym ers, therm oplast ics, therm osets and e lastom ers, conduct ing polym ers, branched

polym ers (star , dend r i t ic and hyperb ranched polym ers) .

Text / References

G. Odian, Principle of Polymerizat ion3 r d edit ion, John W iley, 1991

P. J. Flor y, Principles of Polymer Chem isty, Cor nell U niver sity Press, 1953

M . Chanda, Advanced polym er chemist ry : a pr oblem solv ing guide, M arcel Dekker, 2000F. W . Billm eyer Jr., Textb oo k of Polym er Science3 rd edit ion, Joh n W iley, 1991

CH 557 Topics in Chem istry 3 0 0 6

Structure of sol ids, surfaces, interfaces and soft matter, electronic structures, structure

and proper t ies of nanocrysta ls . In t roduct ion to polymers; physica l proper t ies ofpolymers; classif icat ion of polymers based on kinetics and methods to character ize

polym ers. Str uctu ral Ino rganic Chem istr y: Basic aspects of single crystal X-ray

di f f ract ion, m eth ods of st ructu re determ inat ion and in terpret at ion of st ructu res.

Hom ogeneou s catalysis: M et al ions in organic tr ansform ation , basic pr in ciples,act ivat ion energy, essential steps in catalysis, catalyt ic transformation to useful organic

compounds.

Text / References

P. A. Cox, Electron ic Str uctu re and Chem istr y of Sol ids, Oxford Univer sity Press, 1991.G. Odian, Principle of Polymerizat ion3 r d edit ion, John W iley, 1991

P. J. Flor y, Principles of Polymer Chem isty, Cor nell U niver sity Press, 1953

M . Chanda, Advanced polym er chemist ry : a p roblem solv ing g uide, M arcel Dekker, 2000

F. W . Billme yer Jr., Textb oo k of Polym er Science3 rd edit ion, Joh n W iley, 1991

G.H. Stout and L.H. Jensen, X-ray Stru cture Determ inat ion: A Pract ical Guide, 2

nd

edit io n, John W iley, 1989.

Ch. Elschen br oich , Organometa l l i cs , 3 r d edi t ion, W i ley-VCH: W einheim, 2006.

P.W . van Leeuw en, Hom ogeneous Cat alysis: Und ersta nding th e art , Kluw er, 2005.

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CH 559 Solid Stat e Chem istry and Its App licat ions 2 1 0 6

Diffract ion techniques and the structure of sol ids; analysis of dif fract ion data. Crystal

defects, nonstoichimetry and sol id solut ions. Structure of sol id electrolytes, zeoli tes,

conduct ing polym ers and surf aces. Solid state tr ansform atio ns and reactions.

Electronic structure of sol ids: Fermi level, Bloch orbitals, energy bands, Bri l louin zone.Electr ic and magnetic propert ies of sol ids: insulators, semiconductors, conductors and

Fermi surfaces; superconductivity; polar izat ion, refract ive index, dielectr ics and

ferroelectr ics; d iamagnet ism and paramagnet ism ; fer rom agnet ism , fer r imagnet ism and

ant i fer rom agnet ism . M olecular m eta ls, phosphors and sol id s tate lasers.

Texts/ References

C. Kit t el, Int rod uct ion to Solid Sta te Physics, 6 t h edi t ion, W i ley, 1991.

A. R. W est, Solid Sta te Chem istr y and I t s App licat ions, Wiley, 1989.

P. A. Cox, Electron ic Str uctu re and Chem istr y of Sol ids, Oxford Univer sity Press, 1991.A. W. Adamson, Physical Chem istr y of Surf aces, Wiley, 1990.

H. V. Keer, Principles of th e Solid Sta te, W iley Easter n, 1993.

D. K. Chakr abart y, Solid Sta te Chem istr y, New Age Int ernat ional , 1996.

A. Zangw il l , Physics at Sur fa ces, Oxford Univer sity Press, 1988.

CH 560 Quantu m Chem istry 2 1 0 6

M atr ix form ulat ion of quantum m echanics: t ransform at ion, representat ions, pro ject ion

operators, equat ions of m ot ion . Operator form al ism : Vir ia l theorem , norm al operator s,

Dirac 's m ethod of so lut ion of harm onic osci l la tor problem . Angular mom entum : ladderoperator technique, so lut ions, d i f ferent ia l equat ion m etho ds, sp in, addi t ion of angular

momenta. Expl ic i t der ivat ion of Har t ree and Har t ree-Fock equat ions, Roothaan

equations, basis sets - STO and GTO, calculat ion of integrals, semiempir ical methods.

Conf igurat ion in teract ion. Tunnel e f fect : square barr ier , WKB approximat ion, e lect ron

and proto n t ransfer . M any-body t reatm ents: corre lat ion energy, N-dependence,d iagramm at ic representat ions and l inked c luster t heorem .

Texts/ References

I. R. Levine , Quantum Chemist ry , Pren t ice Hall India (Lt d.), 1995.

A. Szabo and N. S. Ostlu nd , M odern Quantum Chemist ry , M cGraw-Hi l l , 1989.J. Goodisman, Contem porary Quant um Chemist ry , Plenum , 1977.

F. L. Pilar , Element ary Quantum Chem ist ry , M cGraw -Hil l, 1968.

S. N. Dat t a, Lectu res on Chem ical Bonding and Qua ntu m Chem ist ry , Pr ism Books, 1998.

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CH-5 74 Topics in Inorgan ic Chem istry-I 2 1 0 6

Electro n t ransfer proper t ies of met a l comp lexes. M olecular recogni t ion. Asym m etr ic

catalysis. Phosphorus compounds as l igands. Cluster chemistry. Bio- inorganic reaction

mechanisms.

Text / ReferencesW . L. Jol ly, M odern Inorganic Chem ist ry , M cGraw , Hil l Co., 1984.

R. W . Hay, Bioinorg anic Chem ist ry , Wiley, 1984.

M . Day and J. Selbin , Theoret ical Inorganic Chemistry, 2 n d edi t ion, Von. Nostrand, 1980.

H. J. Eme leus and J. J. An der son, M odern Aspects of Inor ganic Chem ist ry , Von. Nostrand,

1962.

CH-5 76 Stat istical M echanics 2 1 0 6

Ensem bles and Aver ages, equivalence of Ensem bles, classical Lim it. M ont e Carlo and

M olecular Dyamics sim ulat ions. Dist r ibut ion funct ions at equi l ibr ium. In tegra l equat ion

m etho ds. Per turbat ion theory. Densi ty funct ional m ethod s. M olecular f lu ids. Est imat ion

of therm odynam ic funct ions. Non-equi l ibr ium m ethod s. Linear response theory.

Pro ject ion operator m ethod . Stochast ic processes and Brown ian m ot ion . Selected

appl icat ions to problem s in chem ical dynamics, re laxat ion processes and neutro n

di f f ract ion.

Texts/ References

M . P.Allen and D. J. Tildesley, Com put er Simu lat ion in Liquids, Oxford University Press,

1987.J. P. Hansen and I. R. M cDonald , Theory o f Liquids, 2nd edit ion, Academ ic Press,1986.

D. Chand ler , Sta t ist ical M echan ics, Oxford U niversity Press, 1985.

H. L. Fr iedm an, A Cou rse in Sta t ist ical M echanics, Prentice Hall ,1983.

L. D. Landau, E. M . Lifshit z and L.P. Pitaevskii, Statistical Physics Parts I and II, Pergam on

Press, 198 0D. A. M cQuarr ie , Stat ist ical M echanics, Harper and Row,1974.

CH-5 78 Topics in Inorganic Chem istry - I I 2 1 0 6

Basic aspects of single crystal dif fract i on. M olecular m etals. Inorganic r ings. Transit ion

m eta l chemistry of m acrocycles. M eta l ions in m edic ine. Flux ional m olecules.

Text / References

J. E. Hu he ey, Inorga nic Chem ist ry , 4 t h edit ion, Harper Coll ins College Publisher, 1993.

G. H. Stout and L. H. Jensen, X-ray Stru cture Determ inat ion : A Pract ical guide, 2nd

edit io n, John W iley, 1989.

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38

J. P. Ferrar o an d J. M . W illiam s : Int ro duct ion to synth et ic elect r ical conductors,

Academ ic Press, 1987 .

B. Sark ar (Ed.), Biological Aspects of M eta ls relat ed Diseases, Raven Press, 1983 .

G. A.M elson (Ed.), Coord inat ion Chem ist ry of M acrocycl ic Com pou nds, Plenum Press,

1979.

D. E. C. Cor br idge , The Stru ctural Chem ist r y of Phosphorus, Elsevier, 1974.

CH 582 Inorganic Photochem istry 2 1 0 6

In t roduct ion to inorganic phot ochem istry. Phot ochemical laws and phot ochem ical

kinet ics. Photo physical pro cesses. The electron ic absorpt ion spectra of ino rganic

com pou nds. Character ist ics of th e electron ical ly excite d states of inorganic

comp ounds. Phot oelectochem istry of excicted state redox react ions.

Photosensi t izat ion. Photochemical react ions; subst i tu t ion, decomposi t ion and

fragment at ion, rearrangem ent, and redox react ions. Select ive inorganic phot ochem istryusing laser beam s. Inorganic pho to chem istr y in biological pro cesses and their m odel

studies.

Text / References

G. L.Geof f rey and M . S. W r ighton, Organometal l ic Photochemist ry , Academ ic Press,

1979.

K. K. Rohat agi-M ukher jee, Funda m enta ls of Phot ochemist ry , W iley Easter n, 1978.M . S. Wr igh ton , Inorgan ic and Organ om etal l ic Phot ochemist ry , ACS Pub. ,197 8.

V. Balzani an d V. Carasiti, Photochemist ry of Co-ordinat ion compounds, Academ ic Press,

1970.

CH-5 84 Biophysical Chem istry 2 1 0 6

St ructure of water . Bio log ica l re levance of chemical potent ia l . Hydrophobic and

hydro ph il ic int eract ion s in biological system s. Protein-Solvent Int eract ion s - pref erent ialbind ing, hydr at ion and exclusion. Prot ein struct ure, stabi l i ty, foldin g, unf olding and

their s tud ies w i th spectroscopic and ca lor im etr ic met hods. Prote in-Ligand Binding.

Str uctu re-Fun ction re lat ion ships. Equ il ibr ia across m em branes.

Text / ReferencesR. B. Gregory , ed., Prot ein-Solvent Interact ion s, M arcel Dekker,Inc., 1995.

B. T. Nall and K. A. Dill, ed., Confo rm at ions and Forces in Prot ein Folding, American

Associat ion for the Advancemen t of Science, 19 91.C. Branden and J. Tooze, Int roduct ion to Protein Structure, Garland Publishing, Inc.,

1991.

J. Wyman and S. J. Gill, Binding and Linkag e : Funct iona l Chem ist ry of Biolog ical

M acromolecu les , Un iversit y Sciences Book s, 1990 .

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C. R. Cantor and P. R. Schimmel, Biophysical Chem istr y, Part I II , W.H.Freeman and Co.,

1980.

CH 586 Structure and Propert ies of M ater ia ls 2 1 0 6

Common st ructure of e lements and compounds. Bonding in so l ids. Structuredetermination by X-ray dif fract ion methods. Dif fusion in sol ids. Electr ical, magnetic,

opt ica l , d ie lect r ic and therm al proper t ies of so l ids.

Text / References

H. V. Keer, Principles of th e Solid Sta te, W iley Easter n Ltd ., 1993.

C. Kit t el , Int rod uct ion to Solid Sta te Physics, John W iley & Son s, 1991.

A. R. W est, Solid Sta te Chem istr y and I t s App licat ions, John W iley & Sons, 1989.

A. F. Wells, Stru ctural Inorga nic Chem ist ry , Claren do n Press, 1 986.

L. V. Azaroff , Element s of X-ray Crysta l lograph y, M cGraw -Hil l , 1968.

CH 588 Organ ic Synt hesis 2 1 0 6

Concepts of symmetr izat ion, umpolung, select ivity and specif ici ty (stereo, regio and

chemo). Ant i thet ic and m etath et ic approaches. Select ive in t rodu ct ion and manipu lat ion

of fun ct ional groups. Select iv i ty in funct ional groups react ions, act ivat ion, prot ect ionand b locking of groups. C-C bond form ing react ions-cyanohydr in form at ion,

organomet a l lic addi t ions, W it t ig and re lated react ions, ha lomet hane addi t ion,

nucleophil ic substi tut ion, Aldol condensation, enolate alkyla- t ion, Fr iedel-Crafts

reaction , M ichael reaction , Claisen conden satio n, Cope and Claisen rearrangem ent s,in ter - and in t ra m olecular Die l 's-Alder react ions, Barb ier W ei land degradat ion ,

Dieckm ann and acylo in cond ensat ions, d i rected a ldo l condensat ion, conjugate addi t io n

and annulat ion reactions. Photochemical synthesis. Applicat ions of the above

m etho dologies in the synthesis of key syntho nes and othe r m olecules.

Text / References

S. W arren , Designin g Or ga nic Synt hesis, Joh n W iley and Sons, 1980.

W . Carut hers, Som e M etho ds of Organ ic Synthesis , Cam brid ge Univer sity Press, 1978.

H. O. House, M odern Synth et ic React ions, 2nd Ed., W.A.Benjam in 1972.

R.O.C. Norman, Principles of Org anic Synt hesis, 2nd Edn. , M ethuen and Co. Ltd. , 1972.

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