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Publ ic Interest Energy Research (PIER) ProgramFINAL PROJECT REPORT
ADVANCEDLASERIGNITIONSYSTEMINTEGRATEDARICESYSTEMFORDISTRIBUTEDGENERATIONINCALIFORNIA
MAY 2012
CEC 500 2012 043
Preparedfor: CaliforniaEnergyCommissionPreparedby: ArgonneNationalLaboratory
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Prepared by:
Primary Author(s):Sreenath GuptaRaj Sekar
Argonne National LaboratoryArgonne, IL, 60439
Contract Number: 500-02-022
Prepared for :
California Energy Commission
Avtar Bining, Ph.D.Project Manager
Mike GravelyOffice ManagerEnergy Systems Research Office
Laurie ten HopeDeputy DirectorRESEARCH AND DEVELOPMENT DIVISION
Robert P. OglesbyExecutive Director
DISCLAIMER
This report was prepared as the result of work sponsored by the California Energy Commission. It
does not necessarily represent the views of the Energy Commission, its employees or the State ofCalifornia. The Energy Commission, the State of California, its employees, contractors andsubcontractors make no warrant, express or implied, and assume no legal liability for the informationin this report; nor does any party represent that the uses of this information will not infringe uponprivately owned rights. This report has not been approved or disapproved by the California EnergyCommission nor has the California Energy Commission passed upon the accuracy or adequacy ofthe information in this report.
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i
Acknowledgments
TheauthorsthanktheCaliforniaEnergyCommissionforthefunding,supportandguidance
forthisproject.TheauthorswouldalsoliketothankMr.RonFiskum,TechnologyManager
oftheAdvancedReciprocatingEngineSystemsProgramattheUnitedStatesDepartmentof
Energyforcofundingthisproject.Wealsorecordourappreciationfortheinteractionwith
AdvancedLaserIgnitionSystemConsortiumpartners.
Pleasecitethisreportasfollows:
Gupta,Sreenath,andRajSekar(ArgonneNationalLaboratory).2008.AdvancedLaserIgnitionSystemIntegratedARICESystemforDistributedGenerationinCalifornia.CaliforniaEnergy
Commission,PIEREnvironmentallyPreferredAdvancedGenerationProgram.CEC500
2012043.
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Preface
TheCaliforniaEnergyCommissionsPublicInterestEnergyResearch(PIER)Program
supportspublicinterestenergyresearchanddevelopmentthatwillhelpimprovethe
qualityoflifeinCaliforniabybringingenvironmentallysafe,affordable,andreliableenergy
servicesandproductstothemarketplace.
ThePIERProgramconductspublicinterestresearch,development,anddemonstration
(RD&D)projectstobenefitCalifornia.
ThePIERProgramstrivestoconductthemostpromisingpublicinterestenergyresearchby
partneringwithRD&Dentities,includingindividuals,businesses,utilities,andpublicor
privateresearchinstitutions.
PIERfundingeffortsarefocusedonthefollowingRD&Dprogramareas:
BuildingsEndUseEnergyEfficiency
EnergyInnovationsSmallGrants
EnergyRelatedEnvironmentalResearch
EnergySystemsIntegration
EnvironmentallyPreferredAdvancedGeneration
Industrial/Agricultural/WaterEndUseEnergyEfficiency
RenewableEnergyTechnologies
Transportation
AdvancedLaserIgnitionIntegratedARICESystemforDistributedGenerationinCaliforniaisthe
finalreportfortheAdvancedLaserIgnitionIntegratedAdvancedReciprocatingInternal
CombustionEngine(ARICE)SystemforDistributedGenerationinCaliforniaproject
Contractnumber50002022conductedbyArgonneNationalLaboratory.Theinformation
fromthisprojectcontributestoPIERsEnvironmentallyPreferredAdvancedGeneration
Program.
FormoreinformationaboutthePIERProgram,pleasevisittheEnergyCommissions
websiteatwww.energy.ca.gov/research/orcontacttheEnergyCommissionat9166544878.
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Table of Contents
Preface:................................................................................................................................................ iii
Abstract............................................................................................................................................. xiii
ExecutiveSummary............................................................................................................................ 1
1.0 Introduction............................................................................................................................. 5
1.0 Introduction............................................................................................................................. 5
1.1. Background................................................................................................................ 5
1.2. FundamentalsofIgnition......................................................................................... 8
1.3. WhyLaserIgnition?.................................................................................................. 9
1.4. ALISConsortium..................................................................................................... 10
1.5. GoalsandObjectives............................................................................................... 11
2.0 (Task2.2)NaturalGasAirIgnitionExperimentalStudy............................................... 13
2.1. RationaleforTask2.2.............................................................................................. 13
2.2. ExperimentalSetup................................................................................................. 14
2.2.1. Rapidcompressionmachine.................................................................................. 14
2.2.2. Laserignitionsystem.............................................................................................. 17
2.2.3.
Conventionalignitionsystem................................................................................ 17
2.2.4. Operationalprocedure............................................................................................ 18
2.3. ResultsandDiscussion........................................................................................... 19
2.3.1. TestMatrix................................................................................................................ 19
2.3.2. IgnitionLimits.......................................................................................................... 20
2.3.5. ConclusionsforTask2.2......................................................................................... 24
3.0 (Task2.3)DesignofALISComponents............................................................................ 25
3.1. GoalsandObjectivesofTask2.3........................................................................... 25
3.2. LaserSystem............................................................................................................ 28
3.3. LaserPlugs............................................................................................................... 31
3.4. HighPowerOpticalMultiplexer.......................................................................... 34
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3.4.1. ElectroOpticModulator(PockelsCell)............................................................... 34
3.4.2. RotatingMirror........................................................................................................ 35
3.4.3. Flipflop.................................................................................................................... 37
3.5.
FiberOpticDelivery............................................................................................... 38
3.5.1. Solidcorefibers........................................................................................................ 39
3.5.2. HollowGlassWaveguides(HGWs)..................................................................... 41
3.5.3. Advancedaircorefibers........................................................................................ 42
3.6. ElectronicInterface.................................................................................................. 43
3.7. ResultsandConclusionsforTask2.3................................................................... 44
4.0 (Task2.4)SingleCylinderLaserIgnitionStudies............................................................ 47
4.1.
StatementofWorkforTask2.4............................................................................. 47
4.2. ExperimentalSetup................................................................................................. 48
4.2.1. SingleCylinderEngine........................................................................................... 48
4.2.2. OpenPathLaserIgnitionSetup............................................................................ 50
4.2.3. Fibercoupledlaserignitionsetup........................................................................ 52
4.3. TestMatrix................................................................................................................ 54
4.4. ResultsandDiscussionforTask2.4...................................................................... 56
4.4.1. FullLoadComparison(15barBMEP).................................................................. 58
4.4.2. PartLoadComparison(10barBMEP)................................................................. 62
4.4.3. FiberCoupledLaserIgnitionResults................................................................... 64
4.5. ConclusionsforTask2.4......................................................................................... 65
5.0 (Task2.5)IntegrateALISandRefineforPerformanceonaMultiCylinderEngine..67
5.1. EngineandNaturalGasFuelingSystemInstallation........................................ 67
5.1.1.
Multicylinderengine............................................................................................. 67
5.1.2. NaturalGasFuelingsystem................................................................................... 68
5.2. ALISIntegration...................................................................................................... 69
5.2.1. Mechanicalintegration........................................................................................... 70
5.2.2. ElectronicIntegration.............................................................................................. 72
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5.2.3. ALIStesting.............................................................................................................. 75
6.0 (Task2.6)PerformanceTestingofIntegratedALISARICESystem............................. 79
6.1. StatementofWorkforTask2.6............................................................................. 79
6.2.
MultiCylinderEngineTests.................................................................................. 79
7.0 (Task2.7)EconomicEvaluationforFeasibility................................................................ 81
8.0 SummaryandConclusions................................................................................................. 83
9.0 References.............................................................................................................................. 85
10.0 GLOSSARY............................................................................................................................ 87
APPENDIXA:AdvancedLaserIgnitionSystem(ALIS)Consortium
APPENDIXB:FutureHighPowerOpticalMultiplexingTechnologies
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List of Figures
Page
Figure1.ComparisonofMaintenanceCostsforRichBurnandLeanBurnEngines...............6
Figure2.OperationalRegionofaTypicalLeanBurnEngine.(Courtesy:SwRI)...................... 7
Figure3.IgnitionLimitsofaTypicalFuelairSystem................................................................... 8
Figure4.SchematicofaCapacitanceDischargeIgnition(CDI)System..................................... 9
Figure5.ALISDevelopmentConsortium..................................................................................... 11
Figure6.IgnitionLimitsofMethaneairMixturesEstablishedinaStaticChamber.Initial
MixtureTemperature~22C.............................................................................................. 14
Figure7.SchematicoftheRapidCompressionMachine............................................................ 16
Figure8.APictureofArgonnesRapidCompressionMachine................................................. 16
Figure9.SchematicoftheOpticalArrangementintheLaserIgnitionSystem........................ 17
Figure10.ConventionalIgnitionSystemCart.............................................................................. 18
Figure11.TypicalPressureTracesfromRCMOperation;P1=1bar,=0.7........................... 20
Figure12.MeasuredversusCalculatedPeakCombustionPressuresforVariousMethaneair
Mixtures,1.0
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Figure24.PhotographofaPockelsCellBasedTwoChannelMultiplexer.............................. 35
Figure25.SchematicofaRotatingMirrorMultiplexer............................................................... 36
Figure26.PhotographofArgonnesRotatingMirrorMultiplexer............................................ 36
Figure27.SchematicofaFlipFlopMultiplexer........................................................................... 37Figure28.(a)SchematicofSetuptoMeasuretheTimeResponseoftheFlipFlop(b)A
TypicalDetectorResponseCurve...................................................................................... 37
Figure29.SchematicofLaserRefocusingSchemeattheDistalEndoftheOpticalFiber......39
Figure30.FiberFaceLaserIntensityDistributionProfilesforanInjectionSchemeUsing(a)
PlanoConvexLens,(b)CombinationofAxiconandPlanoConvexLens................... 40
Figure31.TheRefractiveIndexDistributioninTwoSolidCoreFibers:(a)StepIndexFiber,
and(b)GradientIndexFiber.............................................................................................. 41
Figure32.(a)SchematicoftheCrossSectionofaHollowGlassWaveguide(HGW),and(b)APhotographShowingSparkGenerationUsingHGWintheLab.............................. 42
Figure33.(a)SchematicoftheCrossSectionofaMultiLayerHollowGlassWaveguide,and
(b)PhotographofanAirCorePhotonicBandgapFiber................................................ 43
Figure34.SchematicDiagramoftheElectronicInterface........................................................... 44
Figure35.SchematicoftheControlSchemeoftheBSCRESingleCylinderEngineUsing
SwRIsRPECS...................................................................................................................... 49
Figure36.PhotographShowingtheInstalledLaserPlugintheCombustionChamber........51
Figure37.SetupfortheOpenPathLaserIgnitionTestsonaLargeBore,SingleCylinder
BombardierBSCRE04Engine............................................................................................ 51
Figure38.LayoutoftheFiberCoupledLaserIgnitionSystem.................................................. 52
Figure39.FiberCoupledLaserIgnitionSystemasMountedontheBombardierBSCRE04
Engine..................................................................................................................................... 53
Figure40.ArbitraryCylinderPressureandHeatReleaseComparisontoClarify
NomenclatureofCombustionParameters....................................................................... 57
Figure41.COVofIMEPversusEquivalenceRatio(EQR)ataBMEPof15bar...................... 58
Figure42.CombustionStabilitywithConventionalSparkIgnitionataBMEPof15bar......59
Figure43.CombustionStabilitywithLaserIgnitionataBMEPof15bar................................ 59
Figure44.BSNOXBrakeThermalEfficiencyTradeoffataBMEPof15bar............................. 61
Figure45.CylinderPressureComparison..................................................................................... 61
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Figure46.CylinderPressureandHeatReleaseComparison..................................................... 62
Figure47.COVofIMEPversusEquivalenceRatioataBMEPof10bar.................................. 63
Figure48.BSNOXBrakeThermalEfficiencyTradeoffataBMEPof10bar............................ 63
Figure49.AComparisonofBurnDurationsforDifferentModesofIgnition......................... 64Figure50.APhotographoftheCumminsQSK19GEngineinoneoftheEngineTestCellsat
ArgonneNationalLaboratory............................................................................................ 68
Figure51.ASchematicoftheIntegratedALIS............................................................................. 70
Figure52.AschematicoftheIntegratedALISShownInstalledonOneCylinderofaMulti
CylinderEngine.................................................................................................................... 71
Figure53.PictureoftheALISAssemblyMountedonArgonnesQSK19GEngine(Top
View).LaserHeadontheRightisnotShown................................................................. 72
Figure54.(a)SchematicRepresentationoftheuseofElectronicInterfaceina6cylinderEngine,(b)SchematicRepresentationoftheuseofElectronicInterfaceforLabScale
Testing.................................................................................................................................... 73
Figure55.FunctionalRepresentationoftheElectronicInterface............................................... 74
Figure56.TimingDiagramfor1800rpmOperation,redPulsesTriggerLaserPowerSupply
#1WhileBluePulsesTriggerLaserPowerSupply#2................................................... 74
Figure57.Pictureofthe6ChannelALISAssemblyontheTestrig(TopView).AlsoShown
aretheLaser,BNC565PulserandtheElectronicInterface.LaserPlugsarenot
Visible..................................................................................................................................... 75
Figure58.PictureofMisfireDetectionSystem............................................................................. 76
Figure59.DataFromoneoftheLongTermDurabilityTests.................................................... 77
FigureB1.(a)PhotographofaGalvanometerBasedSystem.Courtesy:Cambridge
Technology,Inc.(b)UseofGalvanometerforLaserScanning[28]................................ 1
FigureB2.PhotographofaPiezoBasedLaserScanner.Courtesy:PhysiqueInstrumente......2
FigureB3.(a)PhotographofaMEMSBasedMirrorArray,and(b)TexasInstruments
DigitalMirrorDevice............................................................................................................. 2
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List of Tables
Page
Table1.Performancetargetsforadvancedreciprocatinginternalcombustionengines..........5
Table2.PerformanceRequirementsofanAdvancedIgnitionSystem(Courtesy:Caterpillar,
CumminsandWaukesha).................................................................................................. 28
Table3.PerformanceSpecificationsofSomeCommerciallyAvailablePulsedDPSSL..........31
Table4.HollowGlassWaveguidesTestedforHighPowerLaserTransmission.................... 41
Table5.SpecificationsofSwRIsBSCREEngine.......................................................................... 50
Table6.TestMatrixforSingleCylinderLaserIgnitionStudies................................................. 55
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Abstract
TheprimarygoalofthisprojectwastodevelopandtestanAdvancedLaserIgnitionSystem
(ALIS)forimprovingefficiencyandreducingengineoutemissionsofoxidesofnitrogen
(NOx)fromnaturalgasfueledreciprocatingenginescommonlyusedfordistributed
generationinCalifornia.Thespecificobjectiveoftheprojectwastodesign,developanddemonstrateanintegratedALISonamulticylindernaturalgasfueledreciprocatingengine
meetingorexceedingCaliforniasDistributedGenerationEmissionsStandards.
Leanoperationhasbeenthepreferredmodeofoperationfornaturalgasfueled
reciprocatingenginesasitallowslowNOxemissionsandhighoverallefficiency.Laser
ignitionappearspromisingasitachievesignitionathighpressuresandunderlean
conditionsrelativelyeasily.Lasersarebecominglessexpensiveandmorecompactthan
beforeandareattractivemeansofignitionforengines.
Initially,thebasicdesignrequirementsforlaserignitionundertypicalincylinderconditions
(temperaturenear500degreesCelsius,pressureunder77bar)wereestablished.Throughfundamentalignitionstudiesperformedinarapidcompressionmachine,thecharacteristics
oflaserignitionandconventionalsparkignitiononmethaneairmixtureswerecompared.
Therapidcompressionmachinestudiesdemonstratedsignificantdifferencesbetweenthe
combustionprocessesassociatedwithlaserignitionandconventionalsparkignition.
Subsequenttestsonalargeboresinglecylinderengineshowedthatlaserignitioncould
potentiallyreduceNOxemissionsupto70percent.Alternately,foragivenNOxemissions
level,laserignitioncanenhanceenginefuelconversionefficiencyby3percentagepoints.
VariouscomponentsrequiredforALISweredeveloped.Afreespacelasertransmission
designapproachwasusedduetononavailabilityofsuitablefiberoptics.Thesuccessfully
developedcomponentswereintegratedandoptimizedforusewithamulticylinderengine.TheintegratedALISwastestedforanextendedperiodoftimeinthelaboratorytoprove
systemreliability.AbriefenginetestwithALISwasattemptedinatestcellatCummins
EngineCompanyandthesystemintegrationissueswereidentified.Futureworkisexpected
tosuccessfullydemonstratetheperformanceandemissionsbenefitsofAdvancedLaser
IgnitionSystemoperationinamulticylindernaturalgasfueledreciprocatingengine
suitablefordistributedgenerationapplicationsinCalifornia.
Keywords: Emissions,Engine,Ignition,Laser,Spark
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Executive Summary
Introduction
Withelectricgridinfrastructurecapabilitieslaggingbehindtheeverincreasingpower
demandsinCalifornia,DistributedPowerGenerationhascomeintovogue.Mostofsuchinstallationsarenaturalgasfueledinternalcombustionengineswitheitherrichburn
(equivalenceratio,~1.0)orleanburn(
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Approach
Theprojectcommencedwithanexhaustivesurveyoftheignitionliterature.Followingthis
literaturereview,fundamentalignitiontestswereperformedonaRapidCompression
Machinetocompareconventionalsparkignitionandlaserignition.
AninitialsurveyofpossibleAdvancedLaserIgnitionSystemschemeswasperformedand
twopromisingconfigurationswereidentified:(i)thelaserpercylinderconcept,and(ii)the
multiplexedlaserconcept,whereintheoutputofasinglelaserisdistributedovervarious
cylinders.Thelatterconceptwaschosenasitpromisedlowcostandsimplicityofthermal
management.However,thisconceptrequiredthedevelopmentofthreemaincomponents,
namely,laserplugs,multiplexersandfiberopticbeamdelivery.Forbreakdowntooccurin
gases,therequiredlaserfluencyatthefocalpointisoftheorderof1012WattsperSquare
Centimeter(W/cm2).Toachievesuchpeakfluencies,highpowerlaserpulseswithpeak
powerofseveralmegawatts(MW)arerequired.Therefore,themaincomponentsofthe
AdvancedLaserIgnitionSystemmustbedesignedtowithstandsuchhighpowerlevels.
Guidancewasderivedinthedevelopmentofthesecomponentsthrough(i)datafromfundamentalignitionstudiesconductedontheRapidCompressionMachine,and(ii)
requirementsoftheadvancedignitionsystemasspecifiedbyenginemanufacturers.Specific
detailsofthehighpowercomponentsconsideredinthepresentprojectaredescribedbelow:
LaserPlugs:Atwolensdesignthatsuccessfullymeetsthephysicalandfunctional
requirementsofalaserplugwasdeveloped.Adaptationofthisdesignforvariousengine
geometriesispossible.
Multiplexers:Threeschemesthatdistributetheoutputofasinglelaseramongvarious
cylinderswerepursued:(i)anelectroopticswitch,(ii)arotatingmirrorscheme,and(iii)a
flipflopswitch.Thefirsttwoschemesfellshortoftherequirementseitherduetohighcostortheinabilitytoprovideignitiontimingvariationsinindividualcylinders.Theflipflop
scheme,however,provedeffectiveinallrespects.
FiberOpticBeamDelivery:Throughtestsandanalysesitwasdeterminedthatthefiber
opticdeliveryrequirementsare(i)lowdivergenceatdistalend,(ii)highpowerlaser
transmission,and(iii)preservationofmodequality.Initialtestsperformedusingsolidcore
fibersshowedthattheyarelimitedbythematerialdamagethreshold.Subsequenttests
performedusingHollowGlassWaveguidesshowedthattheyarelimitedbymodeshifts
introducedbybendingoftheopticalfibers.Whilephotonicbandgapfibersappear
promising,theyarenotreadilyavailablefortestsandtheirdevelopmentisexpectedtobe
expensive.
ElectronicInterface:AnelectronicinterfaceisrequiredfortheAdvancedLaserIgnition
SystemtocommunicatewiththeElectronicControlUnitofanengineforignitiontiming
coordination.InconsultationwithArgonnesindustrialpartner,Altronic,Inc.,thetiming
modulesfromexistingignitionsystemsweremodifiedforthepresentpurpose.
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Inparallel,thebenefitsoflaserignitionweredemonstratedinasinglecylinderresearch
engine.Forthispurpose,a9.5inchbore,11literdisplacementBombardiersinglecylinder
engineatSouthwestResearchInstitutewasused.Testswereperformedcomparing
conventionalcapacitancedischargesparkignition,freespacelaserignition,andfiber
coupledlaserignition.
Theenginewasoperatedat10barand15barBrakeMeanEffectivePressure(BMEP)at900
revolutionsperminute(rpm).Sweepsoffuelairequivalenceratio(from0.5to0.65)and
ignitiontiming(from25degreesBeforeTopDeadCenter,to8degreesAfterTopDead
Center)wereperformedwhileadjustingtheairboosttokeepthemeanpowerconstant.
Results
Reviewofpreviouslypublishedignitionliteratureshowedsignificantspreadindata
concerningthecombustionbehaviorofnaturalgasairmixtureswithlaserignition.
Subsequently,intheRapidCompressionMachinestudies,methaneairmixturesunder
typicalincylinderconditions(temperature~500degreesCelsius,pressure
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Inviewoftheaforementionedbenefitsoflaserignition,effortsweredirectedatdeveloping
anintegratedAdvancedLaserIgnitionSystem.Previouslydevelopedcomponentswere
integratedintoasinglesystemwhilerelyingonafreespacelaserbeamdelivery.Tests
conductedinalaboratoryenvironmentshowedtheintegratedsystemtohavetherequired
timeresponseandperformance.
Conclusions
Inconclusion,theprojecttitledAdvancedLaserIgnitionIntegratedARICESystemfor
DistributedGenerationinCaliforniaproducedimportantresultsofpracticalsignificance
towardthedevelopmentofanadvancedlaserignitionsystemforreciprocatingengines.
FundamentalRapidCompressionMachinestudiesclearlyshowedthepotentialbenefitsof
laserignitioncomparedtoconventionalsparkignition:(i)Laserignitionextendedthelean
operatinglimitofmethaneairmixturestotheleanflammabilitylimit(ll=0.5),and(ii)Combustionrateswereacceleratedwithlaserignition.
SinglecylinderengineexperimentsperformedwithlaserignitionrealizedthepotentialbenefitsevidencedintheRapidCompressionMachinestudies.Comparedtoconventional
sparkignition,laserignitionextendedtheleanmisfirelimitbyabout10percentatBMEPsof
10and15bar,increasedoverallburnrates,andimprovedcombustionstabilityatalltest
points.Mostimportantly,laserignitionshowedareductionofbrakespecificNOx(BSNOx)
emissionsby~70percentatconstantengineefficiencyoralternately,anincreaseinbrake
thermalefficienciesofupto3percentagepoints,whilemaintainingBSNOxemissions
constant.
Thisprojectwasasuccessattheresearchlevel,whereforthefirsttimeamulticylinder
enginedesignoflaserignitionsystemwasshowntoworkeffectivelyinthelaboratory.Itis
recommendedthataseparatematerialsresearchprojectbeundertakentodevelopfiber
opticlaserenergydeliverysystemsuitableforengineconditions.Thefinalstep,toestablish
thetechnicalviabilityoftheAdvancedLaserIgnitionSystemconcept,isperformingaseries
ofmulticylinderengineteststodocumenttheefficiencyandemissionsbenefitsofthelaser
ignitionsystem.
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1.0 Introduction
1.1. Background
ReciprocatingInternalCombustionEnginearecommonlyusedforDistributedGeneration
(DG)andCombinedHeatandPower(CHP)applications.AsshowninTable1,accordingtotheCaliforniaEnergyCommissionsAdvancedReciprocatingInternalCombustionEngine
(ARICE)program,theperformanceandemissiontargetssetforstationaryreciprocating
enginesbyyear2010arebrakethermalefficiencygreaterthan44%andbrakespecific
nitrogenoxideemissionslessthan0.01gramsperbrakehorsepowerhour(g/bhphr).
Table 1. Performance Targets for Advanced Reciprocating Internal Combustion Engines
Parameter 2007 2008 2009 2010Efficiency
Brake Thermal Efficiency 35% 38% 40% 44%Fuel-to-Electric Efficiency*** 32% 34% 38% 42%
Overall Efficiency (CHP) 85% 85% 85% 85%Emissions shaft power (g/bhp-hr)
Oxides of Nitrogen (NOx)
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Primarily,therearethreetechnicalapproachestomeetCaliforniasDGemissionsand
performancetargetsspecifiedinTable1:Richburn(equivalenceration[]greaterthan1.0)operationwithexhaustgasrecirculation(EGR)anduseofthreewaycatalyst,Low
temperaturecombustionstrategiessuchasHomogenousChargeCompressionIgnition
(HCCI),andLeanburnoperation(~0.60.7).
Richburnengineoperation(~1.0),usuallyentailstheuseofanexhaustgasoxygensensoralongwithanadvancedenginecontroller.Thecontrolleroscillatesthecombustion
equivalenceratiobetween0.95and1.05therebyenablingtheoxidationandreduction
processesinthethreewaycatalyst.EGRhelpskeepthecombustiontemperatureslowand
theoverallefficiencyhigh.However,suchastrategyintroducescorrosivecombustion
byproductsandothercontaminantsbackintotheenginewhichcompromiseshardwarelife
andlubricantquality.Suchastrategycouldprovetobeverycompetitivewithefficienciesas
highas38%andverylowemissions.However,asshowninFigure1,effortsbyGeneral
ElectricJenbacherspreadover1.3millionrunninghourson17differentengineshave
shownthatenginemaintenancecostsincreaseby42%.
Figure 1. Comparison of Maintenance Costs for Rich-Burn and Lean-Burn Engines.
HCCIandothersimilarstrategiesrelyonextremelyleanfuelairmixtures(
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timingcontroland(iii)startabilityarereportedtobeaproblem.Inlightofsuchissues,the
leanburntechnologyappearsverypromising.
Leanburnoperation(~0.60.7),hasremainedtheprimarychoiceofthegasengineindustry.Inthisstrategy,air,farinexcessofthatrequiredforcompletecombustionofthe
fuel,isinductedintothecylinderduringeachcombustioncycle.Tooffsettheenergydensity,intakeairboostisemployedwiththeuseofaturbocharger.Theresultinglow
combustiontemperaturesandhighincylinderpressuresensureverylowNOxemissions
(~0.5gramsperkilowatthour[g/kWh]or0.37g/bhphr)whilesimultaneouslyachieving
highfuelconversionefficiencies(~38%).Usuallyanaftertreatmentsystemisnotusedwith
leanburnengines.
Figure2showsthetypicaloperationofaleanburnengine.Theseenginesareoperatedat
theintersectionofknock(autoignition)limitandmisfire(leanignition)limit,soastoattain
maximumefficiencyandsimultaneouslylowNOxemissions.Boostlimitandpreturbine
limitareimposedbytheturbochargerconstruction.Also,asthesparktimingisadvanced,
combustionstartsearlyinthecompressionstrokeandtheknocklimitisencountered.Ontheotherhand,assparktimingisretarded,thegasdensityatthetimeofignitiontendstobe
higherresultinginmisfire.Byextendingthemisfirelimitthroughjudiciouschoiceofan
ignitionsystem,substantialbenefitsinefficiencyandemissionscanbeachieved.
0
10
20
30
40
50
60
6.5 7 7.5 8 8.5 9 9.5 10
Dry Exhaust Gas Oxygen Mole Fraction (%)
SparkTiming(deg
BTDC)
KnockLimi
t
KnockLim
it
MisfireLim
itMisfi
reLimit
BoostL
imit
BoostL
imit
Pre-TurbinePre-Turbine
LimitLimit
DesiredCa
libration
DesiredCa
libration
MaxMax
BTEBTE
The shape of this windowThe shape of this window
is combustion chamber &is combustion chamber &
ignition system dependentignition system dependent
Figure 2. Operational Region of a Typical Lean-Burn Engine. (Courtesy: SwRI)
Figure2,recastincombustionterminology,isshowninFigure3.Thisrepresentsthe
ignitionlimitsofatypicalfuelairsystemfor0.51.0.Forrichmixtures,selfignitionoccursaboveacertainpressuretherebydefiningtheselfignitionlimit.Alsoforagiven
modeofignition,aleanlimitexists(ll)formixturesleanerthanwhich(
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cannotbeachieved.Formethaneairmixturesllis5.01%.ForachievingmaximumcombustionefficiencyandlowNOxemissions,leanburnenginesareoperatedatthe
intersectionofleanignitionlimitandtheselfignitionlimit.Betterperformancecanbe
achievedbyextendingtheleanignitionlimitbychoosinganadvancedignitionsystem.
Equivalence Ratio,
0.40.50.60.70.80.91.0
Pressure(au.)
1
2
3
4
NonFlamableRegion
Self-ignitionlimit
LeanIgnitionLimit
IgnitableMixture
Lean-burn engine Operation
Figure 3. Ignition Limits of a Typical Fuel-Air System.
1.2. Fundamentals of Ignition
Inatypicalsparkplug,successfulsparkingisachievedwhenthepotentialdropacrossthe
sparkgapexceedsthedielectricbreakdownthresholdoftypicalgases.Thesparking
potentialacrosstheelectrodesisgivenbyPaschenslaw:
( )dpfVb ,= (1)
where,pisthepressureofthegasanddisthesparkgap.Thebreakdownvoltage,Vb,
exhibitsalineardependenceontheproductpd.Theelectrodeshapeandmaterialarealso
foundtohavesignificantinfluenceonthesparkignitionprocess[1].Oncegasbreakdown
occursandaplasmakernelisestablished,energytransferoccursmainlythroughdiffusion
onthesurfacetothesurroundinggas.Whethersuchadiffusionprocessresultsina
successfulcombustionflamefrontdependsuponthekernelenergyexceedingMinimum
IgnitionEnergy(MIE),thekernelsizeexceedingacertainsize,turbulenceandgasspeed[2].
Inpractice,factorsinfluencingsuccessfulsparkcreationfaroutweighthoseinfluencingits
transformationintoaflamefront,anditisnormallyassumedthatonceasparkiscreatedthe
mixtureissuccessfullyburned.
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1.3. Why Laser Ignition?
Inpresentturbochargedoftheleanburnnaturalgasengines,CapacitanceDischarge
Ignition(CDI)systemsareusedasschematicallyshowninFigure4.Thoughthesesystems
areratedat100150millijoules(mJ)perstrike,afterthermallossestypically4060mJis
transmittedtothesparkkernelatratesofvoltageriseof500Voltspermillisecond(V/s).In
CDIsystems,energystoredinahighvoltagecapacitor(at~175VoltsDirectCurrent(VDC)
isdischargedthroughahighvoltagecoilresultinginvoltagesinexcessof28kilovoltsdirect
current(kVDC)acrossthesparkpluggaps.
HVCoil
SparkPlugs
DCSource
ElectronicDistributor
CapacitorCircuit
Figure 4. Schematic of a Capacitance Discharge Ignition (CDI) System.
Withapushtowardsleanengineoperation,withaconcomitantrequirementtomaintain
enginespecificpower,theintakeairpressureisincreased.Leanoperationalongwithhigh
intakeairpressureresultsinveryhighchargedensitiesatthetimeofignition.Suchhighgas
densitiesnecessitatesparkgapvoltagesinexcessof40kilovolts(kV)thatcannotbe
achievedusingcurrentCDIsystems.Thisoftenleadstoincreasedmisfiringwithsubsequent
lossoffuelefficiencyandincreasedunburnedhydrocarbon(UHC)emissions.HigherUHC
emissionsareessentiallyvolatileorganiccompounds(VOC),whicharecurrentlyregulated
inCalifornia.Toaddresstheseproblems,variousresearchorganizationshavebeenexploringalternatewaystoachieveignition[36].Amongthesealternatemethods,laser
ignitionprovesattractiveasitoffersthefollowingperformancebenefits:
Successfulignitionofmixturesathighpressuresensuresreducedoccurrenceof
misfire,andconsequentlyimprovedfuelefficiencyandlowerUHCemissions,
Potentiallylowermaintenanceastherequirementtomaintainareasonablesparkgap
iseliminated,
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Extensionofleanoperatinglimits,therebyenablinglowerNOxemissions,
Shorterignitiondelaysandenhancedcombustionrates,whichallowretarded
timingstherebyreducingNOxemissions,and
Locationofignitionkernelawayfromthewalls,therebyenhancingoverallefficiency
duetoreducedheatlosstothecylinderhead.Withsuchpotentialbenefits,anattempttouselaserignitionforreciprocatingengineswas
madebyDaleandSmyasearlyas1974[7].However,thesizeandcostoflasersystemsat
thattimeweretoolargetoreducelaserignitiontopractice.Overthelasttwodecades,on
accountofthedevelopmentsinelectroopticsystems,thereisarenewedinterestinlaser
ignitionforreciprocatingengines.Thepresenteffortaimedto(i)determinethebenefitsthat
accruewiththeuseoflaserignition,and(ii)developandintegratesystemstoreducelaser
ignitiontopracticeoncommercialmulticylinderengines.Thiswascarriedoutintechnical
tasks,Tasks2.12.6,asdescribedbelow.
AspartofTask2.2,fundamentalignitionstudieswereperformedinaRapidCompression
Machine(RCM)tocomparethecharacteristicsoflaserignitionandconventionalsparkignitiononmethaneairmixtures.TheRCMstudiesdemonstratedsignificantdifferences
betweenthecombustionprocessesassociatedwithlaserignitionandconventionalspark
ignition.InTask2.4,thepracticalimplicationsofthealteredcombustionbehaviorwithlaser
ignitionweredeterminedthroughexperimentsonasinglecylinderresearchengine.Ina
paralleltask(Task2.3),variouscomponentsrequiredforanAdvancedLaserIgnition
System(ALIS)weredeveloped.InTask2.5,thesuccessfulcomponentsdevelopedinTask
2.3wereintegratedintoasinglesystemandoptimizedforusewithamulticylinderengine.
Task2.6,fieldtestingforperformance,isstillanongoingeffort.AbrieftestingonaQSK
19G6cylinderengineatCumminsTechnicalCenterwascarriedout.Theprogressmadein
individualtasksisgivenhenceforth.Thisisconcludedwithasummaryoftheoverallproject.
1.4. ALIS Consortium
AttheinitiativeoftheUnitedStatesDepartmentofEnergy(U.S.DOE)Advanced
ReciprocatingEngineSystems(ARES)programmanager,Mr.RonaldFiskum,andthe
EnergyCommissionsARICEprogrammanager,Dr.AvtarBining,anALISconsortiumwas
formed.AsshowninFigure5,thisconsortiumcomprisedArgonneNationalLaboratory
(ANL),ColoradoStateUniversity(CSU),NationalEnergyTechnologyLaboratory(NETL)
andSouthwestResearchInstitute(SwRI)astechnicalpartners.Oversightfortheprogram
wasprovidedbyindustrialpartnersCaterpillar,Cummins,WaukeshaandAltronicInc.
aswellasthefundingagenciesU.S.DOEDistributedEnergyProgramandCalifornia
EnergyCommissionsARICEProgram.Researchideasandprogresswerediscussedand
sharedthroughregulartechnicalmeetings.Additionally,therewasenoughinteraction
amongparticipantsthroughsidebarmeetingsheldatvariousconferencesites.Asummary
ofconsortiumactivitiesandalistofpublicationsareprovidedinAppendixA.
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Figure 5. ALIS Development Consortium
1.5. Goals and Objectives
Laserignitioncanovercometheignitionproblemsinleanburnnaturalgasenginesand
furtherhasthepotentialtoimproveengineefficiencyandloweremissions.Theoverall
benefitsduetolaserignitioncanbesummarizedas:
1. Improvedoverallefficiency,
2. Reducedfuelconsumption,3. LowerNOxandunburnedhydrocarbon(UHC)emissions,
4. Enhancedpowerdensity,and
5. Reducedoverallmaintenancerequirements.
Theseperformanceimprovementstranslatetoimprovingtheenergycost/valueofCalifornias
electricity.Simultaneously,byloweringNOxandUHCemissions,theenvironmentalandpublic
healthcosts/riskofCaliforniaselectricityarereduced.
TheoverallgoalsoftheproposedALISsystemare:
1.
MeetorexceedthecurrentandfutureCaliforniaemissionsrequirementsandhaveotherdesirableenvironmentalattributes.
2. Improvefueltoelectricityconversionefficiency.
3. Lowercapitalcosts,installationcosts,operationandmaintenancecost,andlifecycle
costs.
4. Enhancereliability,maintainability,durabilityandusability.
5. Possessmultifuelusecapabilities,suchaswithsewergas,landfillgasetc.
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Ingeneral,theproposedALISsystemisexpectedtoleadtotheadoptionanduseof
improvedARICEtechnologieswithinCalifornia.
Technical and economic/cost performance objectives
TheoveralltechnicalgoalofthisprojectwastodevelopaCommercial/ProductionReady
ALISintegratedARICEfordistributedgeneration(DG)inCaliforniabymeetingorexceedingYear2007PerformanceTargetsofARICE(cf.Table1.).
Thespecifictechnicalobjectivesoftheprojectwere:
1. Completionofexperimentalstudiestodeterminecomponentdesignspecifications.
2. Developmentofviablecomponentsforhighpowerlasertransmissionandtheir
integrationintoanALIS.
3. SuccessfulintegrationanddevelopmentofALISthatachievesthetechnical
requirementsspecifiedbytheindustry.
4. PerformanceevaluationofanintegratedALISARICEsystemonamulticylinderengine.
5. DemonstrationoftheintegratedALISARICEsysteminmeetingorexceeding2007
ARICEperformancetargets.
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2.0 (Task 2.2) Natural Gas-Air Ignition Experimental Study
2.1. Rationale for Task 2.2
Withtherenewedinterestinlaserignition,therehavebeenquiteafewpaststudies
evaluatinglaserbasedignitioninstaticchambers[8,9].AsshowninFigure6,suchstudieshaveshownthatlasersenableignitionofmixturesatpressureshigherthanthosethatcanbe
ignitedbyconventionalcoilbasedCapacitanceDischargeIgnition(CDI)systems.However,
nosignificantextensionofleanignitionlimitwasfoundwithlaserignition.Thelean
ignitionlimitsforbothmodesofignitionappearedtocoincideat equalto0.67.
Similarly,throughtestsperformedonRicardoProteussinglecylinderengineequivalent
ration,McMillianetal.[10]reportextensionofleanignitiontoequivalentto0.51with
Kopeceketal.[11]reportingthesametoequivalentto0.42(useablerangeequivalentto
0.46).Withmostoftheleanburnenginesoperatedclosetotheintersectionofleanignition
limitandselfignitionlimit,suchaspreadindatawarrantsasystematicstudyunderin
cylinderlikeconditions.Toattainthisgoal,oneneedstoperformignitiontestsinaRapidCompressionMachine(RCM)thatsimulatestypicalnaturalgasengineconditions.Asmost
oftheleanburnenginesareoperatedclosetotheintersectionofignitionlimitandknock
limit,theselfignitionlimitneedstobedeterminedaswell.Also,mappingoftheminimum
laserenergiesrequiredforsuccessfulignitionunderdifferentmixtureconditionswould
assistinthedevelopmentofALIS.
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Figure 6. Ignition Limits of Methane-Air Mixtures Established in a Static Chamber(Initial Mixture Temperature ~ 22 C).
2.2. Experimental Setup
2.2.1. Rapid Compress ion Machine
Asmostofthecurrentstationarypowergenerationenginesareoperatedatspeedslessthan
1800rpm,therapidcompressionmachine(RCM)wasdesignedwithcompressiontimeless
than17milliseconds.Overallthesystemwasdesignedtowithstandconditionsattheendof
combustionof362barand3,000Kelvin(K).Also,withthecompressionratio(CR)oftypical
gasenginesbeing12.5,theRCMwasdesignedforaCR=12.
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ThedesignconceptthatwasusedbyArgonneisanimprovementovertheonedeveloped
byMassachusettsInstituteofTechnology(MIT)[12].AschematicoftheRCMisshownin
Figure7.ApictureofthesystemisshowninFigure8.ThisRCMconsistsoftwopistons
which,whenreleased,traveltowardseachotherwithextremelysmallresultantvibration.
EachsideoftheRCMconsistsofthreeseparatechamberseachcarryingapiston.Allthe
threepistonsaremountedontothesamecentralTitaniumshaftthatforcestheirmovementinunison.Theoutermostchamberisapneumaticchambercarryinga6inchdiameter
aluminumpiston.Theinnermostisacompressionchamberwhereina2.5inchdiameter
aluminumpistoncompressestheexperimentalgasesintothecentralignitionchamber.In
themiddleisahydraulicchamberthatcontainshydraulicoilpressurizedto165bar.Special
designfeatureswithinthehydraulicchamberallowedholdingthepistonintheretracted
positioneventhoughpressurizedairat20.7barwaspresentinthepneumaticchamber.The
samedesignfeaturesallowedreleaseofthepistonsynchronizedwithanexternalsparking
event.Similaradditionalfeaturesinthehydraulicchamberallowedholdingthepistonin
thecompressedpositiontherebyavoidingthepistonbounceatthecommencementof
combustion.VariousportsonthecompressionchambersallowedfillingtheRCMwithdrycompressedairand99.99%puremethane.Fineorificesinthegaslinesalongwithahigh
resolutionpressuretransducerallowedestablishingmixturesoftherequiredpressuresand
equivalenceratiosaccurately.Aportonthecombustionchamberallowedignitionwitha
conventionalsparkplug(18mmthread,Jstyle)poweredbytheAltronicPM1(CDI)
ignitionsystem.Asecondportalloweddirectingandfocusingalaser(focallength13mm)
toachieveignition.AthirdportcarryingaKistler4073A500pressuretransducerallowed
recordingthepressuretraces.Afourthportcarriedanexhaustvalve.Atotalof22
pneumaticallydrivensolenoidvalvesinterfacedtoacomputerallowedremoteoperationof
theRCM.AcomputerprogramwritteninNationalInstruments(NI)LabviewdrivingNI
FieldPointsystemallowedautomationoftheprocesses.
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Figure 7. Schematic of the Rapid Compression Machine.
Figure 8. A Picture of Argonnes Rapid Compression Machine.
Photo Credit: Argonne National Laboratory
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2.2.2. Laser Ignition System
ThelaserignitionsystemisschematicallyshowninFigure9.Thebeamoutputofa
frequencydoubledNeodymium:YttriumAluminumGarnet(Nd:YAG)laser(Spectra
PhysicsGCR170)wasroutedthroughacombinationofhalfwaveplateandpolarizerto
varythelaserpower.Abeamsplitterandapowermeterallowedmonitoringofthelaserpower.Afastshutterwith3millisecondtimeresponseallowedincidenceofasinglepulse
fromthelaserpulsetrain.AllofthetimingwascontrolledbytheNIFieldPointsystem.
To RCM FastShutter
Iris
Laser powerHead & Meter
532 nm
GCR170Nd:YAGLaser
BeamDump
1064 nm
Protective Enclosure 2
BeamDump
1/2 wavplateGlan Taylor
PolarizerT70/R30 Mirror
Protective Enclosure 1
Figure 9. Schematic of the Optical Arrangement in the Laser Ignition System.
2.2.3. Conventional Ignition System
ACDIsystem,modifiedforthepresenttests,wassuppliedbyAltronic,Inc.Thissystem,
whenactivatedremotelybya5volt(V)pulsesuppliesignitionenergytothesparkplug
placedonthewallofthecombustionchamber.Thearrangementwassuchthatthespark
wassupplied30msfollowingtheendofpistonstroke.Suchadelaywasnecessarytoallow
thelockingmechanismtoengagecompletelybeforetheinitiationofcombustion.Figure10
showsapictureofthisignitionsystem.
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Figure 10. Conventional Ignition System Cart.
Photo Credit: Argonne National Laboratory
2.2.4. Operational Procedure
Inatypicalexperiment,theRCMpistonswereretractedandheldintheretractedposition.
Subsequently,agasmixtureoftherequiredequivalenceratioandinitialpressure,P1,was
establishedinthecompressionchambers.Afterallowing5minutesforthegasestomix,the
pneumaticchamberswerepressurizedwithcompressedairat20.7barsuppliedbya150
Literairtank.Thepistonswerereleasedbyactivatingtheappropriatevalvesequencing.A
photodetectorsensingthepistonpositionprovidedthenecessarysignalforsequencingthe
laserpulseortheconventionalignitionspark.Toallowforlockingofthepistonsinthe
compressedpositionandtherebyavoidapistonbouncebackatthecommencementof
combustion,ignitionwasinitiated30msfollowingtheendofcompressionstroke.Also,one
secondfollowingtheendofcompressionstroke,theexhaustvalvewasopened.
Subsequently,thepistonswereretractedandthecompressionandcombustionchambers
werepurgedtoprepareforthenextexperimentalrun.Atypicaltestrunrequired20to30
minutesforexecution.
Oscillosco e
Sparkplugs
Ignition
coils
Electronic
control
24VDCpower
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2.3. Results and Discussion
2.3.1. Test Matrix
Withtheabovesetup,testswereperformedwhilevaryingtheinitialpressureofthe
mixture,P1,andtheequivalenceratio,.ThemixturesestablishedintheRCMwerelimited
to1.0>>0.4,3.0>P1>1.0barandinitialtemperature,T1=298K.AtypicalpressuretraceobtainedduringonesuchtestrunisshowninFigure11.AsshowninFigure11,whenthe
pistonsarereleased,thegaseousmixtureisisentropicallycompressedtoP2.Astheignition
(sparking)eventissequenced20to30msfollowingendofcompression,thereisasmall
pressuredropresultingfromheattransfertothecombustionchamberwalls,(P2P2).
Followinganignitiondelayaftertheincidenceofspark,thepressurerisessteeplytoP3due
tocombustion.Subsequentpressuredropisprimarilyduetocondensationofwatervapor
andheattransfertowallsofthechamber.
Fromthermodynamics,onehastherelations
( )
CRPP 12 = (2)
and
( )( )112= CRTT (3)
where,CRisthecompressionratioandistheratioofspecificheatatconstantpressure(Cp)tospecificheatatconstantvolume(Cv),whichequals1.4forair.
AregressionanalysisperformedonthemeasuredvaluesofP2assumingas1.4showedthatthecompressionratioforthepresentRCMis10.0asopposedto12.0thatitwas
originallydesignedfor.Withthisadjustedcompressionratio,calculationswereperformed
assumingadiabaticcombustionbyusingNationalAeronauticsandSpaceAdministration(NASA)ChemicalEquilibriumforApplications(CEA2)program.Fromsuchcalculations,as
showninFigure12,itwasobservedthatthemeasuredP3valueswereonanaverage83%of
thecalculatedP3values,withleanermixturesexhibitinglowervalues.Also,itoughttobe
notedthatinthepresenttests,forallmixtureconditions,thetemperatureatthetimeof
ignition,T2wasabout765K(perEquation3).
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Time (ms)
-50 0 50 100 150 200 250 300
Pressure(Bar)
0
10
20
30
40
50
60
70
trial 1trial 2
trial 3P2
P1
P3
Ignition
IsentropicCompression
Pr. risedue to
combustion
Pr. drop due to watercondensation and heat transfer
Pr. dropdue toheat transferP2'
Figure 11. Typical Pressure Traces from RCM Operation; P1 = 1 bar, = 0.7
P3 Calculated (Bar)
0 50 100 150 200 250 300
P3
Measur
ed(Bar)
0
50
100
150
200
250
300
Figure 12. Measured Versus Calculated Peak Combustion Pressures for
Various Methane-Air Mixtures, 1.0 < P1
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betweenthemaximumpulseenergyofabout75mJandminimumpulseenergyof5mJ.
Witheachtestthewindowwithinwhichthethresholdenergywaspresentwashalveduntil
thefinalthresholdvaluewasdeterminedwithinanaccuracyof2.25mJ/pulse.
Theignitionboundariesdeterminedthroughsuchtestsexpressedasafunctionofpressure
atthetimeofignition,P2,areshowninFigure13.ItisprominentlynoticedthatselfignitiondominatesformixtureswithP2greaterthan63bar.Also,itisnoticedthattheleanignition
limitwhileusingtheCDIsystemisat0.6.Ontheotherhand,byusinglaserignitionthis
couldbeextendedallthewaytotheflammabilitylimitofofabout0.5.Suchextensionsare
ofsignificanceasthecurrentleanburnenginesareoperatedattheintersectionofself
ignitionlimitsandleanignitionlimits.
Followingsuchobservations,wearenotsureoftheclaimsmadebyresearchersatGE
Jenbacherwhoreportextensionofleanignitiontoof0.417byusingalaser.
Figure 13. Ignition Boundaries Determined by Using an RCM.
2.3.3. Minimum Required Energy Scans
Fortheignitionboundariesestablishedabove,MinimumRequiredEnergy(MRE)valuesfor
successfullaserignitionweredeterminedforvariousmixtureconditions.Values
determinedforalensfocallength,fof13millimetersandlaserbeamqualityofM25areshowninFigure14.Itisobservedthatexceptforof1.0,MREvaluesdecreasedwith
increaseinpressurefinallyresultinginselfignition.ThevaluesalongacrosssectionofP2of
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37.7barareshowninFigure15.Foravariationoftheequivalenceratio,itisnoticedthata
minimaexistsatof0.85forthesemethaneairmixtures.Alsoitisnoticedthatthereisa
sharpriseintheMREvaluesformixturesleanerthanof0.7.Suchatrendwasalsonoticed
atotherpressures.
P2
(Bar abs.)
20 30 40 50 60 70
M
RE(mJ/pulse)
0
20
40
60
80
100
= 1.0 = 0.7 = 0.65 = 0.6 = 0.55 = 0.5
Figure 14. Minimum Required Laser Energies (MRE) for a Lens Focal Length f = 13 mm and
Laser Beam Quality of M2 5.
0.50.60.70.80.91.0
MRE(mJ/pulse)
20
30
40
50
60
70
Figure 15. Minimum Required Laser Energies for P2 37.7 bar.
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2.3.4. Ignition Delays and Rates of Pressure Rise
Leannaturalgasairmixturesarecharacterizedbyslowflamevelocitiesandlongerignition
delaysthatareofconcernforleanburnengineoperation.Previousstudiesin1cylinder
engines[10,13]haveshownthatlaserignitionresultsinsmallerignitiondelaysandfaster
combustion.AsshowninFigure16,similartestsperformedintheRCMshowedthatignitiondelayincreasedwithleanoperationforbothCDIignitionaswellaslaserignition.
However,thebenefitsintermsofsmallerignitiondelayswereonlypronouncedunderlean
conditionsandatof1.0.
SimilarcomparisonoftherateofpressureriseisshowninFigure17.Againitwasfound
thatfastercombustionratesoccurforleanoperationandforof1.0bytheuseoflaser
ignition.Thereversaloftrendsfor0.75
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2.3.5. Conclusions for Task 2.2
ThroughignitiontestsconductedinaRapidCompressionMachinethatsimulatedin
cylinderconditionsofaleanburnnaturalgasengine,itwasobservedthatlaserignition
extendstheleanoperatinglimitofmethaneairmixturestotheflammabilitylimit(of0.5)
whereasconventionalCDIignitiononanaverageislimitedtomixturesricherthanof0.6.
MinimumRequiredEnergiesforsuccessfullaserignitionexhibitedasharpincrease
followedbyaplateauregionformethaneairmixturesleanerthanof0.7.Suchatrend
showsthatalaserignitionsystemdevelopedtooperateatof0.65willsuccessfullyoperate
underallotherpossibleoperatingconditions.
Toreapthetruebenefitsoflaserignition,therequiredhardwarecomponentsfortheALIS
needtobedeveloped.ThiswaspursuednextinTask2.3.
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3.0 (Task 2.3) Design of ALIS Components
Fromaninitialsurveyofpossibleconfigurationsforalaserbasedignitionsystem,two
promisingconceptswereidentified:(i)Thelaserpercylinderconcept,and(ii)The
multiplexedlaserconcept.
InthelaserpercylinderconceptschematicallyshowninFigure18,aminiaturelaserisbuilt
directlyoverthecylinderhead.Thecostofsuchaconfigurationislikelytobeveryhigh,as
asinglelaserisrequiredforeachcylinder.Also,thermalmanagementinthelasersystem
becomesanissueasthecylinderheadtemperaturescouldbeashighas130oCelsius(C).
However,thisconfigurationdoesnotrequiretheuseofahighpowerdeliverysystem(e.g.,
afiber).AspartoftheALISconsortium,NationalEnergyTechnologyLaboratory(NETL)
haspursuedthedevelopmentofalaserpercylinderignitionsystem,detailsofwhichare
providedinReference[14].
Alternately,asshowninFigure19,theoutputofasinglelasercanbedistributedamongthevariouscylindersofamulticylinderengine.ThiswasprimarilypursuedbyArgonne
NationalLaboratory.Thisconfigurationbenefitsfromthecostsavingsthatresultfromthe
useofasinglelaseraslasersarethemostexpensivecomponentsofALIS.Also,thelaser
systemisisolatedfromtheheatandvibrationoftheengine.However,thissystemrequires
thedevelopmentofassociatedhighpowercomponentsincludinglaserplugs,optical
multiplexerandfiberdeliverysystem.
OutsidetheconsortiumGEJenbacher,andAVLarepursuingbothlaserpercylinderand
multiplexedlaserapproachesoracombinationapproachofthetwo[11].
3.1. Goals and Objectives of Task 2.3
ThegoalofTask2.3wastodevelopvarioushardwarerequiredforALIS,accordingtothe
specificationsdeterminedthroughtestsinearliertask,Task2.2.Thisentailsselectionof
somecandidatetechnologiesandtestingthemforperformance.Thesuccessfulcandidates
weresortedfurthertomeettheprojectobjectives.
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Figure 18. Schematic of the Laser-Per-Cylinder Concept.
Laserplugs
Laser Multiplexer
fiber optic delivery
ElectronicInterface
EngineECU
Natural Gas Multi-cylinder Engine
Figure 19. Schematic of the Multiplexed Laser Concept.
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Thespecificobjectivesofthistaskaredescribedbelow:
1. Designanddeveloplaserplugswiththefollowingspecifications.
i. Havethesamethreadsizeasaconventionalsparkplug,i.e.,M18x1.5,
ii. Providepressuresealingto3,000poundspersquareinch(psi).
iii. Withstandtemperaturesashighas2,400C.
iv. Minimizefirstandsecondsurfacereflections.
v. Minimizeoveralllaserenergyrequirements.
vi. Providesufficientreliabilitywhiletransmittinglaserenergiesofabout60mJ
perpulse.
vii. Beselfcleaningofanydeposits.
viii. Facilitatecouplingtofiberoptictransmission.
2. Developfiberopticsystemsthatareabletotransmittherequiredlaserenergiesfor
ALISoperation.Intheprocess,evaluatetheperformanceofthefollowingtechnologies,amongothers,fortransmissivity,flexibility,andeaseofconnectivity.
i. Conventionalsilicacoreof1to2millimeter(s)diameterfiberswith
appropriatecladding.
ii. Fiberswithtaperedends.
iii. Hollowfibersystems.
3. Developanopticalmultiplexercapableofdistributingthelaseroutputamong
variouscylindersofanaturalgasengine,whileminimizingtransmissionlossesand
facilitatingtherequiredignitiontimingadvanceorretard.Thiscanbeperformedby
evaluatingthefollowingcandidatetechnologiesamongothers.
i. Fiberoptictelecommunicationmultiplexer.
ii. Rotatinggratingtypeindexingsystem.
4. Developorselectalasersystemthatcan
i. Providetherequiredlaserenergies.
ii. Operatewithminimalmaintenance.
iii. Haveasmallfootprint.
iv. Providetheaforementionedfeaturesatalowcost.
5. DevelopanelectronicinterfaceincollaborationwithAltronic,Inc.,whichintegrates
thefunctionsoflaserhead,ElectronicControlUnit(ECU),andindexerintoone
singleunit.Thiselectronicinterfaceshouldenhanceeaseofinstallation,improve
durability,satisfythesafetyrequirementsofnaturalgasengines,haveasmall
footprint,belightweight,andfacilitatemanufacturinginlargequantities.
InadditiontothedatagatheredintheearlierTask2.2,guidanceindesignwasalsoderived
fromperformancerequirementsoftheignitionsystemasspecifiedbyengine
manufacturers,asgiveninTable2.
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Table 2. Performance Requirements of an Advanced Ignition System (Courtesy: Caterpillar,Cummins and Waukesha )
1 Cost (current dollars) Value Units
- First Cost (add $1/kWe for CSA requirement) 4.00 $ / kWe- Life Cycle Cost (including system replacement at major) 0.25 $ / MWe-h
2 Performance
-Maximum ignition pressure (peak cylinder pressure) 220 bar
-Minimum air/fuel ratio 0.9 -
-Maximum air/fuel ratio (with swirl) 2.5 -
-Minimum methane number (hydrogen capable) 0 -
- Maximum methane number (landfill capable) 140 -
- Ignition timing repeatability (non-mechanical) 0.08 CA
- Ignition timing accuracy (non-mechanical) 0.08 CA
- COV (ARES steady state, 0.5 g/bhp-hr NOx, 25 bar BMEP)
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havewavelengthsof1064nanometers(nm),532nmor266nm.Thefocalspotdiameterofa
collimatedlaserbeamfocusedbyalensisgivenby[15]
==D
f
M
Ww oo
4 (4)
where,
wo=focalspotdiameterforidealGaussianmodelaser(microns),
Wo=focalspotdiameterforatypicalmultimodelaser(microns),
M=isthemodequality,
=laserwavelength(microns),
f=lensfocallength(cm),and
D=laserbeamdiameter(cm).
AsevidentfromEquation4,smallerwavelengthsresultinsmallerfocalspotdiameters.Asa
result,theuseofsmallerwavelengthsisdesirabletoachievealaserfluxdensityofabout
1012Wattspersquarecentimeter(W/cm2),whichisrequiredforsparking.Withtheharmonic
generationprocessbeingatbest50%efficient,theoreticallyspeaking,afactoroftwo
advantageisachievedbygoingtoahigherharmonic.However,acompromiseisnecessary
asthesystemcomplexityincreases.Forthepresentpurpose,awavelengthof532nmwas
chosen.
Fromafunctionalstandpoint,itwasidentifiedthatthelaserneedstohavethefollowing
operationalcharacteristics:
Wavelength=532or1064nm,
pulsewidth
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mitigatedinthecaseofdisklasersandfiberslasersduetothelargesurfaceareatovolume
ratioofthelasingmedia.Onaccountoftherapidadvancementsinfiberlasertechnology,it
isexpectedthatdisklaserswouldbecomeobsoleteinthenearfuture[16].However,asof
2005,bothfiberlasersanddisklaserswerecostprohibitiveforthecurrentapplication.
Figure 20. A Commercially-Available Diode Pumped Solid State Laser (DPSSL)Model: Centurion, Manufacturer: Big Sky Laser, Inc., 100 Hz, 45mJ/pulse.
Photo Credit: Argonne National Laboratory
DiodePumpedSolidStateLasers(DPSSL),ontheotherhand,areideallysuitedforthe
presentpurpose.Withthecostoflaserdiodescontinuallydecreasingandtheirpower
continuallyincreasing,DPSSLareanticipatedtomakemanynewapplicationspossible.
Mostattractivetothecurrentapplicationisthefactthattheonlycomponentthatrequires
maintenance,thelaserdiode,hasalifetimegreaterthan109shots,whichforatypicalARICE
enginecantranslateto2.5years.AnexampleofacommerciallyavailableDPSSLisshownin
Figure20.TheperformancedataofDPSSLfromthreedifferentmanufacturersistabulated
inTable3below.TheMK88lasersystemfromKigre,hasthesmallestfootprintandhas
alreadybeenshowntoachievesparkinginthelabusinga13millimeter(mm)focallength
lens.However,therepetitionrateofthislasermakesitsuitableonlyforthelaserper
cylinderapplicationshowninFigure18.Ontheotherhand,thesystemsfromBigSkylaser
andJMARaresuitableforthepresentapplication.
Table3providesasnapshotoftheDPSSLtechnologyavailableasof2005.Thistechnologyis
makingrapidprogresswithaveryfavorablecostandperformancetrajectoryamenableto
thelaserignitionapplication.Basedontheseconsiderations,itwasdecidedtopostponethe
selectionofaspecificlaserforthepresentapplication.Consequently,allofthe
demonstrationsinthepresentprojectareperformedusingcompactNd:YAGlasersthatare
alreadyavailableatArgonneNationalLaboratory.Exceptforlongevityofthepumpsource,
theperformanceoftheselaserswillmimicthatofDPSSLinallotherrespects
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Table 3. Performance Specifications of Some Commercially-Available Pulsed DPSSL
Specification
Manufacturer
Kigre Big Sky Laser JMARModel number MK-88 Centurion Britelight-24
Wavelength ( m) 1.54 1.064 1.064
Energy/pulse (mJ/pulse) 3-5 45 80
Pulse width (ns) 7 7 7
Repetition rate (Hz) 0 20 100 300
Beam quality (M2) 1.1 * 109 >1010
Beam diameter (mm) 0.8 3 8
Laser head size (W x D x L) 0.85 2 3 5 3 9 18 30 12
Laser Power Supply size 10 5 3.5 * 19 rack 38 high
* Informationnotavailable
3.3. Laser Plugs
Laserplugsareelementsthatintroduceanopticalwindowsothatlaserradiationcanbe
focusedtocreateasparkinsidethecylinder.Additionalrequirementsfortheirperformance
aregivenbelow:Footprintsimilartothatofstandard18mmsparkplug[17],Pressure
rating~300bar,Temperaturerating~3,000Konelementsexposedtocombustion,and
shouldbeselfcleaningofcarbonandoildeposits.
Afteracoupleofiterations,atwolensdesignwasfoundtobeappropriateforALIS.As
showninFigure21,theoutputofafiberopticcableiscollimatedusingaplanoconvexlens.
Thecollimatedoutputisrefocusedinsidethecylinderusingasapphirelensof13mmback
focallength.Suchanarrangementallowedrefocusingtoaspotsizeof240micrometers
(m).RaytracingiterationsperformedusingZEMAXsoftwareshowedthattheuseof
multielementlensesdoesnotreducethefinalspotsizeanyfurther.
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Figure 21. Ray Propagation Scheme Inside a Laser Plug.
InthearrangementshowninFigure21,thethicknessoftheplanoconvexsapphirelenswas
chosentowithstandpressuresupto300bar.Withsuchathicklens,itisveryimportantthat
thecurvedsideofthelensbepointedtowardsthelasersoastoavoidinternalreflections
thatwillleadtointernalcrackingofthelens.Suchalenswasalsofoundtowithstand
typicalincylindercombustiontemperatures.
ThephysicalarrangementoftheaforementionedlensconfigurationisshowninFigure22.
Asnoticedinthisarrangement,thelaserplugconsistedofatoppartandabottompart
separatedbyanaluminumspacer.Thebottompartcarriedthenecessaryexternalthreadsto
fastentheentirelaserplugassemblyintothecylinderhead.Acoppercrushgasketinthe
bottompartprovidedthenecessarysealingtopreventleakageofcombustiongasesbeyond
thesapphirelens.Thetoppartcarriedalenstube,whichinturn,housedthecollimating
planoconvexlens.Afiberopticconnector(SMAtype)separatedfromthecollimatinglens
allowedcouplingoftheincominglaserradiation.
Throughtestsperformedbyincorporatingthislaserplugina4kilowatts(kW)naturalgas
engine,itwasobservedthatthelaserfluxdensityontheexitfaceofthesapphirelenswas
critical.Atlowlaserfluxdensitiesdistinctcarbondepositswerevisibleonthelens.Abovea
certainthreshold,thelaserradiationablatedsuchdepositsandthelenswasfoundtobeselfcleaning.Cautionneedstobeexercisedtokeepthelaserfluxdensitieswellbelowthe
materialdamagethresholdof5gigawattspersquarecentimeter(GW/cm2).Similarlaser
ignitiontestswereperformedbyGEJenbacherandtheydemonstratedsatisfactory
performanceofthelensarrangementforover5000hoursofoperation[9].
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Figure 22. Schematic of a Two-Lens Laser Plug.
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3.4. High-Power Optical Multiplexer
Theopticalmultiplexerperformsafunctionsimilartotheconventionalignitionsystem:It
distributestheoutputofapulsedlaseramongvariouslaserplugsinstalledindifferent
enginecylinders.Thefunctionalrequirementsofsuchahighpoweropticalmultiplexerare
listedbelow:
Ignitiontimingvariationof048crankangle(CA)beforetopdeadcenter(BTDC).
Lasertriggerpulsegeneration.
Individualcylinderignitiontimingvariationof6CA.
Additionally,thesystemneedstobeoflowcostandmustconformtothedurabilitytargets
oftheoverallsystemof80,000hours.
Asurveywasperformedtoevaluatepotentialtechnologiesthatconformtothe
aforementionedrequirementsandthefollowingthreewereidentified:(i)Electrooptic
switches,(ii)Rotatingmirrorsystems,and(iii)Flipflopsystems.Theresultsfromtheperformanceevaluationofprototypesofthesesystemsarediscussedbelow.Itoughttobe
notedthatthesystemdesignsconsideredbelowconformtoa6cylinder,1800rpm,4stroke
engine.Thesecanbeextendedtoengineswithmorenumberofcylinders,ifnecessary.
3.4.1. Electro-Optic Modulator (Pockels Cell)
APockelscellactsasanelectroopticswitchbecauseitrotatesthepolarizationofthelaser
lightby90degreeswhenactivated.AsshowninFigure23,apolarizingbeamsplittercan
directthebeamonewayortheotherbasedonthepolarizationstateofthelaserbeam
incidentonitfromthePockelscell.AlineararrayofsuchPockelscellbeamsplitter
combinationscanbeusedforthepresentmultiplexingpurpose.Forevaluation,atwochannelsystemwasfabricatedatANLanditdemonstratedtherequiredperformance(see
Figure24).
Figure 23. Schematic of a Pockels Cell-Based Multiplexer [18].
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Figure 24. Photograph of a Pockels Cell-Based Two-Channel Multiplexer.
Photo Credit: Argonne National Laboratory
Thisschemefacilitatesmanipulationofthelaserbeamwithouthavinganymechanical
movementofthecomponents.However,thenumberofrequiredopticalsurfacesincreases
withthenumberofenginecylindersandeventuallybecomestoounwieldy.Additionally
voltagesashighas5kVarerequiredforactivatingthePockelscell.Underthepresent
marketconditions,itwasestimatedthatthecostassociatedwiththisschemeamountsto
about$2,000percylinder,whichisconsideredtobetoohigh.
3.4.2. Rotating Mirror
Thisschemeisbasedonthetraditionalmechanicaldistributorsystemofthe1980s.As
showninFigure25,amirror,placedat45degreestotheincominglaserbeam,isrotated
synchronouslywiththecamshaft.Asaresult,thebeamisrotatedat90degreesaboutan
axiscoincidentwiththeincominglaserbeam.Laserfiringattheappropriatecrankangleis
facilitatedbyatimingdiskfittedontheshaft.Adifferentialgearsystemallowsignition
timingvariationbyintroducingaphaseshiftbetweenthemirrorandthecamshaft.Allof
thecomponentsrequiredforthissystemaresimple,costeffective,andoffertherequired
durability.Therefore,aprototypesystemwasdesignedandassembled.Aphotographofthe
systemisshowninFigure26.Testsperformedinthelabusingasmallelectricalmotorfordrivingthesystemshowedthatithastherequiredperformance.Throughsuchtrialsitalso
becameevidentthatsignificantperformanceadvantagescanbegainedbyusingamirror
inclinedatangles
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gasengines.Therotatingmirrorsystemdoesnotallowthisflexibility.Therefore,
developmentoftheflipflopmultiplexingschemewaspursued.
Figure 25. Schematic of a Rotating Mirror Multiplexer.
Figure 26. Photograph of Argonnes Rotating Mirror Multiplexer.
Photo Credit: Argonne National Laboratory
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3.4.3. Flip-flop
Aflipflopmultiplexerconsistsofalineararrayofmirrors.Anindividualmirror,when
activated,movesintothepathofthelaserbeamanddeflectsitintotherespectivefiber
injectionport.Thissystem,schematicallyshowninFigure27,facilitatestimingvariationof
individualcylinders.Totesttheperformanceoftheflipflopsystem,arotaryactuator(Model6EM)wasobtainedfromtheLedexDivisionofSaiaBurgess,anautomotiveparts
supplier.Thisactuator,whenactivated,rotatesitsshaftby22.5andmovesthemirrorinto
oroutofthepathofthebeam.Ina4stroke,1800rpm,6cylinderenginethetargetresponse
timeforsuchasystemis11ms.Thetimeresponseofaonechannelsystemwasmeasured
usingthearrangementshowninFigure28(a).AsnoticedinFigure28(b),thesystemshows
verylittlebounceandinaddition,exhibitsatimeresponseoflessthan7ms.Subsequently,
effortswereundertakentodevelopasixchannelsystemforusewitha6cylinderengine.
Asmentionedpreviously,withadvancesinactuatorsandmicroelectromechanicalsystems
(MEMS)technologymanyothermultiplexingschemes,otherthanthosediscussedabove,
arepossible.SomeofthesearediscussedinAppendixB.Thefinalchoiceislikelytobedictatedbydurabilityandthecostofthesesystems.
Figure 27. Schematic of a Flip-Flop Multiplexer.
Time (ms)
0 5 10 15 20
N
ormalizedDetectorResponse
-0.2
0.0
0.2
0.4
0.6
0.8
1.0
1.2
(a) (b)
Figure 28. (a): Schematic of Setup to Measure the Time Response of the Flip-Flop(b): A Typical Detector Response Curve.
Fiber couplingassembly
Mirror
Laser beam
Lens
Diode
LaserDeactivated
Activated
5 mm high Laser Sheet
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3.5. Fiber-Optic Delivery
AspartofthecurrentALISscheme,itwasenvisionedthatthepulsedoutputofalaserwill
betransmittedviaopticalfiberstolaserplugsinstalledinindividualcylinders.The
functionalrequirementsspecifiedbyenginemanufacturersfortheopticalfiberstobeused
inamulticylinderenginearegivenbelow:
Length>3m.
Atleastone90obendwitharadiusofcurvature130C.
Additionally,toachievesparkingatthedistalendofthefiber,alaserfluxdensityof1012
W/cm2isnecessarywhenrefocused.
ForagivenfiberandatwolenssystemshowninFigure29,theLagrangeinvariantyields
se NAsNAa = (5)
Asaresult,thelaserfluxdensityatthefocalspot=2s
llaser (6)
where,
a = corediameterofthefiber(microns)
s = focalspotsize(microns)
NAe = numericalapertureatthefiberexithalfconeangleatfiberexit
NAs
= numericalapertureatthefocalspot
Ilaser = intensityoflaser(Watts).
CombiningEquations5and6,thefollowingequationisobtained:
Laserfluxdensityatthefocalspot
2
2
e
slaser
NA
NA
a
l (7)
InEquation7,thefirsttermisdeterminedbythefibercorematerialdamagethreshold.In
thesecondterm,NAsisdeterminedbythespaceavailableforthelaserplug.Forfibersof
shortlengths(~3m)thenumericalapertureatinjectionendisapproximatelyequaltothat
atthefiberexit,i.e.,NAiNAe;inotherwords,theexitconeangleisdeterminedbytheinjectionschemeused.Hencethelaserfluxdensitycanbemaximizedbymakingajudicious
choiceofboththeopticalfiberandtheinjectionscheme.
However,inderivingEquation7ithasbeenassumedthatthefiberismodepreserving.For
thepresentcasewheretransmissionofhighlaserpowerisrequired,theuseofmultimode
fibersisrequired.Asisusuallythecase,withtheintroductionofhigherordermodesthe
energyisnotequallydistributedandisskewedtowardsthehigherordermodes.These
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aspectsofactualphysicalbehaviorarenotcapturedbyEquation7.Nevertheless,this
equationprovidesanacceptablebasisthatassistsinthechoiceoftheopticalfiberandthe
injectionscheme.
Withtheinsightprovidedintheaforementionedarguments,differenttypesoffiberswere
obtainedandtestedforsparkinginthelaboratory.Theresultsofsucheffortsarediscussedbelow.
aNAe NAs
R
s
Figure 29. Schematic of Laser Refocusing Scheme at the Distal End of the Optical Fiber.
3.5.1. Solid Core Fibers
Largelydrivenbyadvancesinthetelecomindustry,therehavebeenrapiddevelopmentsin
solidcorefibertechnologyoverthepasttwodecades.Currently,stepindex(seeFigure
31(a))solidcorefiberswith1mmcorediameterandadamagethresholdof5GW/cm2are
readilyavailable.Initialeffortstoinjectsuchfiberslimitedthemaximumlaserenergy
transmissionto8mJperpulse.Theprimarymodeoffailureinsuchfiberswasmaterialdamageattheentranceendofthefiber.Analysisshowedthatsignificantgainsintermsof
transmittedlaserenergycouldbeobtainedbyensuringthatthelaserbeamcrosssection
profileisincidentonthefaceofthefiberasuniformlyaspossible.Forinstance,asshownin
Figure30(a),thebeamcrosssectionincidentonthefiberfacewiththeuseofasimpleplano
convexlenshadaPeaktoAverage(P/A)ratioof15.6.However,aprofilethatdistributed
theenergymoreevenlyonthefiberfacewasachievedusinganappropriateaxiconlens
combination(seeFigure30(b)).TheP/Aratioinsuchacasewas3.9andtransmittedlaser
energywasashighas30mJ/pulse.
Nevertheless,suchadvancedinjectionschemesintroducehigherordermodesandthe
qualityofthebeamexitingthefiberdegrades.Despitethebesteffortstocountertheseeffects,thetradeoffbetweenthemaximumtransmittablelaserenergyandthegenerationof
higherordermodesproveddifficulttoovercomeandsparkingcouldnotbeachieved.In
thisrespect,thegradientindexfibershowninFigure31(b)appearedpromisingasithad
bettercapabilitytopreservebeamquality.Initialtrialsinthelabshowedthatthesefibers
sufferfromlowmaterialdamagethreshold.Ultimately,itwasdecidedtodirectthepresent
efforttowardstrategieswithhollowcorefibers.
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With Axicon
(P/A) = 3.9
Max. Transmitted 27 mJ/p
Axicon
Simple Plano-convex lens
(P/A) = 15.6
Max. Transmitted 8 mJ/p
With Axicon
(P/A) = 3.9
Max. Transmitted 27 mJ/p
With Axicon
(P/A) = 3.9
Max. Transmitted 27 mJ/p
Axicon
Simple Plano-convex lens
(P/A) = 15.6
Max. Transmitted 8 mJ/p
AxiconAxicon
Simple Plano-convex lens
(P/A) = 15.6
Max. Transmitted 8 mJ/p
Simple Plano-convex lens
(P/A) = 15.6
Max. Transmitted 8 mJ/p
(a) (b)
Figure 30. Fiber Face Laser Intensity Distribution Profiles for an Injection Scheme Using(a): Plano-Convex Lens, (b): Combination of Axicon and Plano-Convex Lens.
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n
n
(a) (b)
Figure 31. The Refractive Index Distribution in Two Solid Core Fibers: (a) Step-Index Fiber, and(b) Gradient-Index Fiber.
3.5.2. Hollow Glass Waveguides (HGWs)HollowGlassWaveguides(HGW)havethestructureillustratedinFigure32(a).Theyare
essentiallyglasscapillarytubescoatedontheinsidewithsilverandareflectivityenhancing
dielectric.ThemodeoftransmissionthroughHGWsisfirstsurfacereflectionwhiletotal
internalreflectionisthemodeoftransmissioninsolidcorefibers.Asaresultofthe
transmissioninairthedamagethresholdofthesefibersis40timeslarger,i.e.,200GW/cm2.Also,HGWstendtopreservethemodequalityandexitthebeamatalowcone
angle,bothcharacteristicsrenderingthemideallysuitedforsparkgeneration.However,
thesefiberstendtohavehighertransmissionlossescomparedtosolidcorefibers.
Additionally,theyexhibitcertainuniquecharacteristics:
Transmissionlosses(corediameter)3.
Bendinglosses(bendradius)1.
Initialevaluationsinthelabshowedthatthe700mcoreHGWswereideallysuitedastheyofferedthebestcompromisebetweenflexibilityandtransmission.Subsequently,700mcoreHGWswereobtainedfromthreedifferentsourcesandtestedinthelaboratory.Their
characteristicsareasgivenbelowinTable4.
Table 4. Hollow Glass Waveguides Tested for High-Power Laser Transmission
Source CoatingOptimized for
Wavelength
Polymicro Technologies Proprietary 3.2 m
Rutgers University Ag/CdS 0.532 m
Tohoku University Ag/ COP 0.532 m
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QuartzAir core
Silver Dielectric
(a) (b)
Figure 32. (a) Schematic of the Cross-Section of a Hollow Glass Waveguide (HGW), and (b) APhotograph Showing Spark Generation Using HGW in the Lab.
Photo Credit: Argonne National Laboratory
SparkingwasachievedinthelaboratorywithallthreefibersshowninTable4.Inallthree
cases,theinjectionwasperformedwithlensesoffocallengthgreaterthan250mminto
fiberstypically12meterslong.However,thefibersfromTohokuUniversity[19]offeredthe
lowesttransmissionlosses(seeFigure32(b)).Subsequently,afibercoupledlasersystem
wasdevelopedusingthesefibersandtheoperationofasinglecylinderenginewas
demonstrated[18,20].However,thedownsidewiththesefiberswasthattheywerevery
bendsensitive;forbends>45,sparkingwasseverelyaffected[18,21].Consequently
advancedfibersthatarerelativelybendinsensitivearedesirable,whileretainingthe
favorablecharacteristicsoftheHGWfibersfromTohokuUniversity.
3.5.3. Advanced Air-Core Fibers
Forfutureonenginelaserignitionapplications,twokindsofadvancedfibertechnologies
appearpromising:(i)multilayerhollowglasswaveguides,and(ii)hollowcorephotonic
bandgapfibers.TheseareschematicallyshowninFigures33(a)and33(b).Bothrelyon
multiplereflectionstoconfinelighttothecentralaircore,andmostimportantlybothfibers
arebendinsensitive.Manufacturingprocessesofbothkindsoffibersareveryinvolvedand
thosethatarecommerciallyavailablewithcorediameters
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Several layers ofDielectric coatings
Air core
(a) (b)
Figure 33. (a) Schematic of the Cross-Section of a Multi-Layer Hollow Glass Waveguide, and(b) Photograph of an Air-Core Photonic Bandgap Fiber
3.6. Electronic Interface
Innaturalgasfueledstationaryengines,theElectronicControlUnit(ECU)performstwo
primaryfunctions:(i)providingignitionwithfeedbackfromatimingdisk,and(ii)speed
controlwithfeedbackfromagovernor.Inmostofthegasfueledengines,thesefunctions
areperformedbytwoseparateunits.Earlierinthereport,asshowninFigure19,itwas
envisionedthatanelectronicinterfacewouldberequiredfortheALIStocommunicatewith
theignitioncontrolpartofECUforignitiontimingcoordination.InconsultationwithArgonnesindustrialpartner,Altronic,Inc.,anelectronicinterfacewasdevelopedthat
utilizescommerciallyavailableconventionalignitionsystems.
Onesuchsystemtodriveaflipflopmultiplexerandalaserisschematicallyshownin
Figure34.Thepositionofatimingdiskmountedonthecrankshaftissensedbyamagnetic
pickup.ThesignalfromthemagneticpickupisprocessedbytheECU/Conventional
ignitionsystemtoprovidea165VDCpulsethatisusuallyfedtotheprimarysideofthe
ignitioncoil.Inthepresentelectronicinterfacesuchasignalisusedtogeneratea24VDC
pulseusingaresistorstepdowncircuit(representedasaboxinFigure34).The24VDCsignal,inturn,isusedtodriveacorrespondingrotaryactuator.Theendofstrokeofthe
rotaryactuatorissensedbyanopticalsensorandatriggersignalisprovidedtothelaser
afterroutingitthroughanORgate.Insuchasystem,theindividualcylinderignitiontiming
variationisprovidedbytheECU/conventionalignitionsystem.Onesuchsystemwas
successfullysimulatedandtestedatArgonneusingAltronic,Inc.sCD200system.
Howeverthebasicdesignofthesystemisnotspecifictoaparticularmodelor
manufacturer.
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RotaryActuator
opticalsensor
1 2 3 4 5 6
ECU/Conv.
Ign Sys
Laser
ORGate
165 VDC7 ns pulse
primary
24 VDC8 s wide pulse
5 VDC TTL
Mag.Pickup
TimingDisk
Electronic Interface
Mirror
Figure 34. Schematic Diagram of the Electronic Interface
3.7. Results and Conclusions for Task 2.3
FromaninitialsurveyofseveralpossibleALISschemes,twopromisingconfigurationswere
identified:(i)thelaserpercylinderconcept,and(ii)themultiplexedlaserconcept,wherein
theoutputofasinglelaserisdistributedovervariouscylinders.Thelatterconceptwas
chosenasitpromisedlowcostandsimplicityofthermalmanagement.However,this
conceptrequiredthedevelopmentofthreehighpowercomponents,namely,laserplugs,
multiplexersandfiberopticbeamdelivery.Guidancewasderivedinthedevelopmentof
suchcomponentsthrough(i)datafromfundamentalstudiesconductedinanearliertask(Task2.2),and(ii)requirementsoftheadvancedignitionsystemasspecifiedbyengine
manufacturers.Specificdetailsofthehighpowercomponentsconsideredinthepresenttask
aredescribedbelow:
LaserPlugs:Atwolensdesignthatsuccessfullymeetsthephysicalandfunctional
requirementsofalaserplugwaseasilyachieved.Adaptationofthisdesignforvarious
enginegeometriescanbeeasilyachieved.
Multiplexers:Threeschemesthatdistributetheoutputofasinglelaseramongvarious
cylinderswerepursued:(i)anelectroopticswitch,(ii)arotatingmirrorscheme,and(iii)a
flipflopswitch.Thefirsttwoschemesfellshortoftherequirementseitherduetohighcost
ortheinabilitytoprovideignitiontimingvariationsinindividualcylinders.Theflipflop
scheme,however,provedeffectiveinallrespects.
HighPowerFiberOpticBeamDelivery:Throughtestsandanalysesitwasdeterminedthat
thefiberopticdeliveryrequirementsare(i)lowdivergenceatdistalend,(ii)highpower
lasertransmission,and(iii)preservationofmodequality.Initialtestsperformedusingsolid
corefibersshowedthattheyarelimitedbythematerialdamagethreshold.Subsequenttests
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performedusingHollowGlassWaveguidesshowedthattheyarelimitedbymodeshifts
introducedbybendingoftheopticalfibers.Whilephotonicbandgapfibersappear
promising,theyarenotreadilyavailablefortestsandtheirdevelopmentisexpectedtobe
expensive.
ElectronicInterface:AnelectronicinterfaceisrequiredfortheALIStocommunicatewiththeECUofanengineforignitiontimingcoordination.InconsultationwithArgonnes
industrialpartner,Altronic,Inc.,thetimingmodulesfromexistingignitionsystemswere
adaptedforthepresentpurposeeasily.
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4.0 (Task 2.4) Single-Cylinder Laser Ignition Studies
EarliertestsperformedinanRCM,inTask2.2,showedthatlaserignitionextendsthelean
ignitionlimitallthewaytotheleanflammabilitylimit(=0.5)fornaturalgasairmixtures.
Additionally,itwasfoundthatforleanoperationlaserignitionacceleratestherateof
combustion.Theobjectiveofthepresenttask(Task2.4)istodeterminetheimpactofsuch
alteredcombustionbehavioronthetradeoffbetweenbrakethermalefficiencyandNOx
emissionsinanaturalgasfueledengine.
4.1. Statement of Work for Task 2.4
Thegoalofthistaskwastoperformlaserignitiontestsonsinglecylindernaturalgas
enginesoftwosizeclassessoastoevaluatetheeffectsofignitiontiming,equivalenceratio
andintakeairpressureonemissionsandperformance.Thefollowingactionswereplanned
tobeperformedinthistask:
Prepareatestplanforoptimizingignitiontiming,efficiencyandNOxemissions
whileavoidingknockinordertodeterminetheperformancebenefitsbytheuseof
laserignition.Also,advantagesbytheuseofmultipointignitioningasengines
needstobedetermined.SuchtestsaretobeperformedbyNETLonaRicardo
Proteusengine.
PerformthetestsontheRicardoProteusenginepertheapprovedtestplan.
Prepareasimilartestplanforimplementationonalargeboreenginetodetermine
theperformancebenefitsbytheuseoflaserignition.Suchtestsaretobeperformed
bySwRIonaCAT3401engine.
PerformthetestsonCAT3401pertheapprovedtestplan.
Inatypicalreciprocatingenginechemicalenergyduringcombustionisconvertedto
mechanicalworkonthepiston.Thenetshaftpowerisaresultofsuchworkperformedon
thepistonslessthemechanicallosses.Whilethemechanicallossesoriginateatvarious
pointsofaworkingengine,themostsignificantofthem(upto50%)