celstrancompositespresentation-110419102406-phpapp01

7/27/2019 celstrancompositespresentation-110419102406-phpapp01

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Celstran

Thermoplastic CompositesThe Material of Great Inventions

Daniel Grauer

David Almond


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Ticona a global company with

proximity to local customers

Leading global supplier of engineering polymers

Sales: 1.109 bill. US dollars (2010)

Globally positioned with regional subsidiaries or dealer networks

Approx. 1630 employees ensure success of the company

Excellent technical services

Broad expertise in application development

Responsible Care (Environment, Health and Safety), ISO 14001

Quality management certifications

(ISO 9001, ISO/TS 16949, VDA 6.3)


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Global network strong global presence

Wilmington,

North Carolina

(Fortron Industries) *

Shelby, North Carolina

Winona, Minnesota

Bishop, Texas

Florence, Kentucky

Suzano, Brazil

Kelsterbach, Germany

Oberhausen, Germany

Production and

compounding plants

Sales offices

Nanton

Nanjin


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Celstran

Thermoplastic Composites


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CelstranCFRTP

Evolution

Short fiber granule

fiber length

= 0.20.4 mm

Wire-coated or

co-mingled fibers

Fully impregnated

long fiber granule

fiber length

= 1125 mm

Ful

co

re

Step 1 Step 2 Step 3


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CelstranCFRTP

Our Strengths

Ticona is a world leader in thermoplastic fiber

impregnation technology

Ticona is a world leader in thermoplastic resin

technology

Ticona has brand equity in engineering

materials markets

Our strengths are our resin fiber range, our

size and experience in engineeringthermoplastics, and our impregnation quality

Celstran

C = Continuous

F = Fiber

R = Reinforced

T = Thermo-P = plastic


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Celstran

Why CFRTP?

CFRTPs can extend the range of physicalproperties attainable with reinforced thermoplasticmaterials by up to an order of magnitude.

Extend the range of CFRTPs commerciallyavailable to include most significant resins, fibersand additives.

Improve the range of useful, economicalfabrication methods.

Combination of easy processing of TPs with

performance of composite materials.

Pros

Consolidation and fabrication methods

established relative to traditional therm

thermoset processing.

Range of commercially available mater

been relatively limited.

Polyolefins-GF or PEEK-CF

Cons


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CelstranCFRTP

and Ticona

Best fiber

impregnationUltimate

resin/fiber

range

Ability for

customizedproductsHelp customers

to develop their

new products

Large projects

confidence

Outstanding

mechanical/thermal

performance


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Celstran

Broad Portfolio

Resins Fibers Additives

PEEK ABS Carbon Fiber Custom Color

PEI PPO Aramid UV Stabilization

PAA/PPA TPU S-Glass Heat Stabilization

PA (6,66,46,12) POM E-Glass Impact Enhanceme

PPS PEHD ECR-Glass Surface Appearance

PBT/PET TPE/TPO/TPV Stainless Steel Flow Enhancement

PC PP Paint Adhesion

PCABS Conductive Particle

Low Emission

Lubricity/WearEnhancement


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Celstran

Broad Possibilities

Glass-fiber tapes:

12 mm (slit tape)

20 mm (slit tape)

25 mm (slit tape) 50 mm (slit tape)

152 mm (6)

178 mm (7)

203 mm (8)

Custom

Carbon-fiber t

12 mm (slit ta

20 mm (slit ta

25 mm (slit ta 50 mm (slit ta

152 mm (6)

Custom

Undirectional fiber-reinforced tapes

( 1112 mm)

1 ( 25 mm) Custom

Pellets


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Celstran

Fiber Impregnation

Fully impregnated

long fiber granule

Fully impregnated

continuous fiber-

reinforced tape

Celstran

Impregnation

Process

Very GoodProperties for New

Applications

Transfer from pellet knowledge into CFRTPs

Impregnation ofEach Filament


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Celstran

Benefits of Thermoplastic Composites

1. Take advantage of the full strength of thereinforcing fibers

2. Extend LFRTP mechanical specific properties byup to an order of magnitude

3. Safe, efficient, environmentally friendly

4. Modern design

5. For a wide range of different market segments

6. New applications for Celstran

7. All the well-known benefits of th

Post-processable

High-toughness

Light-weight

Recyclable

Environmental resistance

Rapid processing

Indefinite shelf life Large range of fibers and m


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CelstranCFRTPs

Tensile Modulus

0

20

40

60

80

100

120

[GPa]

HDPE-GF70

PP-GF70

PBT-G

F55

POM-GF60

POM-CF50

PA6-C

F60

PA6-GF60

PAA-CF50

TPU-GF70

TPU-CF50

TPU-AF60

PPS-G

F50

PPS-CF50

PEEK-CF50

PEI-GF50

ABS-G

F50

ABS-G

F60

PA66-C

F50

PA66-C

F58

PA66-C

F62

Products


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CelstranCFRTPs

Tensile Strength

0

500

1000

1500

2000

2500

[MPa]

HDPE-G

F70

PP-GF70

PBT-GF55

POM-GF60

POM-CF50

PA6-CF60

PA6-GF60

PAA-CF50

TPU-GF70

TPU-CF50

TPU-AF60

PPS-GF50

PPS-CF50

PEEK-CF50

PEI-GF50

ABS-GF50

ABS-GF60

PA66-CF50

PA66-CF58

PA66-CF62

Products


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Celstran

Tg of Different Polymers

100

50

0

50

100

150

200250

Tg

[C]

POM TPU PE PP PA6 PBT PA66 PPS PPA PEI P

Polymers


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Celstran

Thermal key points of different polymers

100

50

0

50

100

150

200

250

300

350

Temp.

inC

POM HDPE PP PA 6 PBT PA 66 PPS PEI

Polymers

Tg Tm Ts


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Celstran

Comparison of Density

0

0.5

1

1.5

2

2.5

3

3.5

4

Polymers

Density[g/cm

3]


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Celstran


Density vs.Strength of Various Materials

P O M - G F 6 0

E p o x y - C F 6 1

P P - G F 7 0

P O M - C F 5 0

P B T - G F 5 5P P S - G F 5 0

P P S - C F 5 0P E E K - C F 5 0

E p o x y - G F 4 5

A l u m i n u m a l l o y , 6 0 6 1 - T 6

A l a ll o y 2 0 2 4 - T 3

S t e e l

C a s t I r o n

0

2 0 04 0 0

6 0 0

8 0 0

1 0 0 0

1 2 0 0

1 4 0 0

1 6 0 0

1800

2 0 0 0

1 2 3 4 5 6 7

Density [g/cm3]

Tensilestrength[MPa]


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Celstran

What are the Target Markets?

Sport/

Leisure

Energy

TransportaBuilding/

Construction

Aircraft

Celstran


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Celstran

CFR-TP processing

Automated tape lay-up/consolidation

Winding

Tape placement

Press consolidation

Double belt press

Press consolidation

Continuous press consolidation

Fluid heat transfer under vacuum (Quickstep)

Partial reinforcement

Injection molding incorporation

Compression molding incorporation

Extrusion incorporation

Sandwich structures


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Thank you very much

for your attentionTicona GmbH

Daniel Grauer

Product Management Celstran EU

Professor-Staudinger-Strasse

D-65451 Kelsterbach Germany

www.ticona.com


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2323

Backup


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Weight Reduction Why?


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Wet winding

Injection/Infusion of resin(dry winding/dry laying)

Hand-laminating of wave

SMC

Pultrusion

Thermosets

TWINTEX

Organoblech

Dry winding (pipes)

Consolidation by heating in a cen(discontinuous process, developeDarmstadt)

Consolidation by heating and enla(continuous process, developed a

Darmstadt) Pultrusion

Thermoplastics

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Celstran

Thermosets vs. Thermoplastics

Alternative technologies (instead of tapes)

C l t


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Celstran


Emission

Exact mixture

Hazardous waste

Thermosets

Pressure, temperature and speed

consolidation point have to be coo

controlled and documented

Trapped air can normally not be e

by vacuum

Thermoplastics

Critical points in process

C l t


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Celstran


No chance to invert the crosslinking reaction

Thermosets

Melting after molding possible

No system to recycle long fibers but ma

fibers

Producing short fiber-reinforced recycla

Thermoplastics

Recycling

C l t


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Celstran


Has to be molded in one step

Post-processing: Only machining processing possible

Winding: Only geodetic ways

Exothermic reaction

Thermosets

Elastic Thermo-deformable Very good surface roughness by centrifugal te High impact resistance High elongation at fracture Good buckling and upsetting performance Creep

In endless fiber-reinforced materials, the by the fibers. So the creep is not as impoother thermoplastic parts.

In contrast to thermosets, there is creep.

Thermoplastics

Characteristics

Celstran


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Celstran


Limited storage time for prepregs

Dust masks are necessary because of emission

Material is liquid, so every tool or work surface has

to be cleaned extensively

Low viscosity (easy fiber impregnation)

Thermosets

Unlimited storage time

Prepregs have to be heated to be as f le

the thermoset prepregs or dry fibers

Hand-lamination is impossible

High viscosity

Thermoplastics

Handling

Celstran


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Celstran


Much hand work

Hand-lamination

Resin injection/infusion

Long cycle time because of hardening

State of the art

Thermosets

Fiber and tape placement of thermopla

new technologies

New processes have to be develo

Fewer steps to get a finished prod

Less experience in processing

Thermoplastics

Cost of processing and machine acquisition

Celstran


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Celstran


Chemical crosslinking reaction for partmanufacture

Irreversible

Storage in freezer for preforms

Limited shelf time

Part assembly

Conventionalnuts, bolts, screws

Smell/odor

Thermosets

Part manufacture by physical phase trasolid-liquid-solid

Wide range of different polymers

PP to PEEK

Repeatable

Unlimited storage at room temperature

Part assembly

Conventionalnuts, bolts, screws

Welding Environmentally friendly

Thermoplastics

Celstran


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Celstran

Granule/Tape Cross Section

Transfer experience from pellets into tapes

Pellet Tape

Celstran Fiber/Matrix


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CelstranFiber/Matrix

Adhesion in REM

Celstrangood adhesion Bad adhesion (fiber pullout)

Celstran


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Celstran


Density vs. Modulus of Various Materials

P O M - G F 6 0

E p o x y - C F 6 1

P P - G F 7 0

P O M - C F 5 0

P B T - G F 5 5 P P S - G F 5 0

P P S - C F 5 0P E E K - C F 5 0

E p o x y - G F 4 5A l u m i n u m a l l o

A l a l l o

0

2 0

4 0

6 0

8 0

1 0 0

1 2 0

1 4 0

1 6 0

1 1 . 2 1 . 4 1 . 6 1 . 8 2 2 . 2 2 . 4 2 . 6

Density [g/cm3

]

Tensilemodulus[GPA]

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