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CEMENTING PRODUCTS AND ADDITIVES (March 1999) The 1999 Cementing Supplement is a comprehensive listing of cementing products and additives available from mayor suppliers. This most recent update now comprises seven companies, including two companies new to the listing. American Fracmaster Ltd. Is the U.S. affiliate of Fracmaster in Calgary, Canada. The firms have separate but complementary products lines. Argentinas’ s San Antonio is listed in Cementing this year for the first time as well. HOW TO USE THIS REFERENCE Listings reflect available cement additives from seven service companies. Products are grouped into functional categories. Some products are unique to a company, and many are protected by patent rights or other legal means. They may be chemically similar, but not identical, and provide comparable performance in cement slurry formulations. Exact equivalence is not implied. Where applicable, products are subdivided into groups having similar performance within each functional category. Performance groups have been subdivided to reflect significant differences in chemical nature of additives and emphasize uniqueness within each company’ s product line. What can not be reflected are differences in product performance with different cements, or performance variations resulting from different sources of the same material around the world. Materials should be tested according to accepted procedures to ensure that performance requirements are met. Also, users are cautioned that it is generally not possible or prudent to make “translations” of cement formulations between service companies based solely on additive descriptions. Products are grouped in 15 functional categories: • Basic cements • Accelerators and salts • Extenders and density-reducing additives • Free water control and solids suspending agents • Dispersants • Bond improving and expanding additives • Fluid-loss control additives • Silica to reduce or prevent high temperature strength retrogression • Retarders • Anti-gas migration agents • Anti-foam and defoaming agents • Density increasing or weighting agents • Additives and mixtures to reduce or prevent lost circulation • Spacers and chemical washes or preflushes • Specialty cement blends Temperature has a significant effect on many cementing additives and is the single most important variable affecting cement hydration. This is particularly for retarders, but also applies to fluid loss control additives, anti-gas migration, expanding and other agents. Salt tolerance is particularly important in fluid loss control additive selection. When applicable, this reference
includes temperature ranges groupings, salt tolerance and other variables critical to additive performance. Temperature and salt tolerance are broad groupings and actual performance may vary somewhat depending on cement, other additives in formulations and well conditions. Important note. Fluid loss control additives are listed according to maximum temperature and salt tolerance for that product. For example, if an additive is shown to be effective up at about 250 °F in the presence of over 18% salt (by weight of mix water), it is very likely that this product is also effective at higher temperatures with lower salt concentrations. There are several examples of this in the table. Finally, if a company does not have an equivalent to a competitor’s product listing, it does not mean that the company can not come up with a cement formulation that achieves similar performance. Our recommendation is to call the company, describe the application or problem and let them work on a solution. Even though additive technology has advanced, it is still best applied with a measure of experience.
BASIC CEMENTS
Material Description American
Fracmaster Ltd
BJ Services Dowell Fracmaster Halliburton Nowsco Canada
San Antonio
API Class A, B and ASTM Type I or II cements A A, B Type I, II A, B Type I, II Normal
Portland Standard A, B Type I, II A, B
API Class G or H H G, H G, H G, H Premium G, H G, H Portland cement
API Class C and ASTM type III C C, Type III C, Type III C Premium Plus C, Type III
High aluminate cement Calcium aluminate cement Fondu Lumnite, Ciment Fondu
Lumnite, Ciment Fondu Fondu Ciment
Fondu Ciment Fondu
Ciment Fondu
Commercial lightweight cements TXI lightweight or equivalent TXI
Lightweight TXI
Lightweight TXI
Lightweight TXI
Lightweight TXI
Lightweight TXI
Lightweight Lightweight
Commercial expanding cements
Chem Comp, ASTM type K or similar
Microfine Portland cement MC-300 or equivalent Available
on request MC-300 Microfine cement
Channelmaster
Micromatrix cement
Microfine Portland cement and microfine blast furnace slag blend
MC-500 or equivalent Available on request MC-500 Microfine
cement Channelma
ster CS Matrix
cement Microcem
1000
High fineness cement Cements ground finer than normal but not as microfine cements
Fine Grind Class C cement
Blast furnace slag (BFS) Ground, granulated or pelletized blast furnace slag Blast Furnace
Slag cement Blast Furnace Slag (D930) Slag
cement Slag-10, 20,
30, 40
Microfine blast furnace slag MC-100 or equivalent
Blend of Portland cement and blast furnace slag
Blend to improve poor quality Portland cements and improve additive response
Slagment
Storable liquid cement slurry
Water-based liquid cement slurry Liquid stone
Acid soluble cement Non-Portland inorganic cement soluble in acid Magne Plus Acid soluble
cement Available
on request Acid soluble
cement Magna cement
Synthetic resin cement Epoxi resin cement Synthetic cement EPSEAL,
Stratalock
ACCELERATORS AND SALTS
Material Description Product Form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Sodium chloride (salt)
Reduces thickening time of cement at concentrations between 1% and 10% by weight in the mix water
Granular Salt A-5 or salt or Sodium Chloride D44 Salt Salt Cement
Grade salt Salt
Solid CaCl2 A-7 or CaCl2 S1 CaCl2 Calcium Chloride
Calcium Chloride
Calcium Chloride
Calcium Chloride
Accelerator. Reduces thickening time of cement. Typically used at 1% to 3% by weight of cement
Liquid CaCl2-L A-7L or CaCl2-L D77 CaCl2-L Calcium Chloride Liquid
Calcium Chloride Liquid
Powder or Beads
Sodium Metasilicate
A-2, Sodium Metasilicate,
Diacel A D79, Diacel A TXC-1 Econolite,
Diacel A EXC Sodium
Metasilicate Diacel A Sodium silicate
Accelerator. Reduces thickening time of cement. Increases slurry viscosity Liquid Liquid sodium
silicate A-3L or Sodium
Silicate D75 EXT-100 Liquid Econolite EXC-L
SE-1L Sodium silicate
Calcium sulfate hemihydrate or gypsum
Accelerator. Reduces thickening time of cement. Often used to create thixtropic cement slurries
Powder Gypsum A-10 or Gypsum D53 Ultracal 60 Cal-Seal, EA-2
Gyp-Cem, Quik Gyp Gypsum
Potassium chloride KCl Granular KCl
A-9 or Potassium Chloride
M117 KCl KCl KCl KCl
Ammonium chloride NH4Cl Granular Available on
request Available on
request Available on
request Available
on request Available
on request Available
on request NH4Cl
Proprietary accelerator AEF-100L,
T-40L CA-3 CA-4
EXTENDERS AND DENSITY-REDUCING ADDITIVES Material Description Product
Form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Bentonite Naturally colloidal clay Powder Bentonite Bentonite D20 Bentonite Gel Bentonite Bentonite
Attapulgite Naturally colloidal clay Powder Salt Gel Attapulgite D128 Salt gel Attapulgite Salt Gel Sepiolite Attapilgite
Type F flyash
Pozzolanic material product of burning coal. Lower in lime content than type C
Powder Pozzolan Flyash D35 Pozzolan Pozmix A NowPoz Pozzolan
Type C, flyash Pozzolanic material product of burning coal Powder Flyash D132 Calss C
Flyash NowPoz
Microfine flyash For use with microfine cements Powder Microflyash
Natural pozzolan
Siliceous material produced from volcanic activity
Powder Pozzolan D61 Pozzolan
Diatomaceous earth
Lightweight, friable siliceous material derived from diatom remains
Powder Granular Diacel D Diacel D D56 Diacel D D.E. Diacel D
Perlite/expand perlite
Volcanic glass, spherelitic and hollow
Granules Beads Perlite Perlite D72 Perlite Perlite Perlite
Powder Fumed Silica
BA-58 CSE D154 FS-1 Silicalite Microsil-10P
Microsil-22P Microsilica Fumed silica (dry)
High surface area, amorphous silica Liquid
Suspension On request BA-58L LW-8L D155 FS-101
Liquid silicalite,
Microblock Microsil-15L
Glass microspheres Scotchlite or similar Small beads On request LW-7-2,
LW-7-4 On
request Galss Spheres
Nowspheres 2000 Esfelite
Pozzolan microspheres
Spherulitic, expanded pozzolanic material produce from burning coal
Powder-like Small beads C Spheres LW-6 D124 Ceramic
Spheres Spherelite Nowspheres 7000
Powder or beads
Sodium Metasilicate
Thrifty Mix, Diacel A, Sodium
Metasilicate
D79, Diacel A TXC-1 Econolite,
Diacel A EXC SE-15
Sodium silicate
Liquid Liquid sodium silicate
Thrifty Mix-L, Sodium Silicate
Liquid D75 EXT-100 Liquid
Econilite EXC-L
Solid T-40 Black-Lite Versaset D-20 Proprietary extender
Liquid BJ Blue D111 GasCon 469 Versaset L
FREE WATER CONTROL AND SOLIDS SUSPENDING AGENTS
Application Product type Product Form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Dry powders, granules, beads, etc
Sodium metasilicate,
Diacel A
A-2 or sodium metasilicate,
Diacel A, T-40, FWC-47, ASA-
301
D79, Diacel A,
D153 TXC-1
Econolite, Diacel A, VersaSet,
FWCA, Suspend HT,
SA-541
FW-1, EXC
Sodium metasilicate,
Diacel A, SE 18
Polymers, sodium silicates, biopolymers, proprietary chemicals
Liquid Liquid
Sodium Silicate
A-3L or sodium silicate, T-40L,
FWC-47L, ASA-301L, BJ Blue
D75, D162 EXT-100
Liquid Econolite,
VersaSet L, VersaSet LXP, GasCon 469
FW-2, EXC-L SE IL
Powder Bentonite, Attapulsite
Bentonite, attapulgite, BA-58, CSE, BA-90
D20, D128, D154
Bentonite, FS-1, TXC-1,
Salt gel, FWC-3
Gel, Attapulgite, Silicalite,
Compacted silicalite,
Microblock
Bentonite, Attapulgite,
Microsil 10P, Microsil 22P
Microsilica, Bentonite
Free water control and solids suspension
Bentonite, attapulgite, fumed silica, etc. See also: Extenders and density reducing agents Liquid Available on
request BA-58L,
Microblock D155 FS-101, EXT-100
Liquid silicalite, Microblock Microsil 15L SE IL
DISPERSANTS
Application Product type Product Form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder Available on request CD-31 D65 FRC-3 CFR-2 T-10
1W, 3W, FT-4,
Granular Powder, FT4-L
Polynapthalene sulfonate (PNS) type. Example products: Lomar-D, Daxad-19 or equivalent Liquid Available on
request
CD-31L, CD-31NL, CD-31LS
D80 FRC-100 CFR-2L T-10L
Powder FMD-1300 CD-33 CFR-3
Liquid CFR-3L Proprietary, non-PNS, non-lignosulfonate
Liquid D145A
Powder CD-32 Proprietary
Liquid
General Application
Proprietary: for use above about 200 F circulating temperature
Powder FMD-1300 D121
Citric acid, citrate salt or similar
Powder Granular
FM-MTB 1500 XR-2 D45 FRC-2 FE-2 T-11
Powder FM-MTB 1600 CD-33 D65A CFR-3
Dispersant for salt-saturated slurries
Polimetric materials (not citric acid, citrate salt, etc) Liquid D80A,
D604AM CFR-3L
Powder CD-32 CFR-2 Dispersant with non-setting or anti-setting characteristics for easily dispersed cements
Liquid CD-33L D604AM CFR-2L
BOND IMPROVING AND EXPANDING ADDITIVES
Application Product type Product Form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Latex: Styrene/butadiene copolymer
Liquid LAC-1 BA-86L D600, D134 Latex-1 Latex 2000
Powder LAC-1P BA-10, BA-56,
BH-56HT, FLAG-56
LAP-1,
FloBlock 210, Halad 447
Latex: Acrylic or equivalent Liquid BA-10L LA-2 NL-2 NL-2
Powder Fumed silica BA-58, CSE, BA-90 D154 FS-1
Silicalite, Compacted
silicalite
Microsil 10P, Microsil 22P
Fumed silica
Liquid Available on request BA-58L D155 FS-101 Liquid silicalite,
Microblock Microsil 15L
Fumed silica/flyash blend Powder Nowlite BA-91 Silicalite blend Nowlite Nowlite
Powder D65A
Improve cement bonding to surfaces: Non-expanding additives
Improve bonding to salt formations
Liquid D80A,
D604AM, D604M
Calcium sulfate hemihydrate or gypsum
Powder Gypsum A-10 or Gypsum D53 Ultracal 60 Cal-Seal, EA-2 Gyp-Cem,
Quik Gyp
Pwder Available on request EC-1, EC-2
Microbond, Microbond M, Microbond HT
Metal oxide
Liquid
Powder Available on request BA-29, BA-61 CPC-1 Super CBL SPC-12000
Expanding agents, may also improve bonding
Gas-generating agents: Aluminum powder or similar Liquid Available on
requesr Gas-Check,
Inhibited Gas- Check
Powder BA-92, BA-100, MPA-1, MPA-2 Bondmaster
Other materials Proprietary Liquid BA-100L
FLUID-LOSS CONTROL ADDITIVES
Appication Circulating temperature range
Compatibility with salt (NaCl):
Salt concentration and temperature
limitations
Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder FM-FL-1200 FL-62, BA-10 D127, D156
FLC-1, FLC-5 LAP-1 D-25 LTX Use in fresh water
or with less than 5% salt by weight Liquid BA-10L,
FL-45LS/LN UniflexL FLC-100 LA-2 LTXL
Powder UniflexS D19, D30 D19,D30 Use up to 10% salt
by weight Liquid UniflexL LD-30 FC-19, FC-22,
Sarf-100
Powder FM-HTFL-1270 FL-33, FL-63 D146,
UniflexS FLC-7 Halad 322,
344,413,567, Gas Stop HT
D-24, NFL-2
Low temperature when little or no retarding effect is desired
60 °F to 120 °F
Use up to 18% salt by weight
Liquid FL-33L, FL-63L UniflexL FLC-107
Halad 322L, 322LXP,
344LXP, 413L, 361A, 600LE
LD-18, LD-24 LTX
Powder FM-FL-1200 FL-62, BA-10 UniflexS FLC-1,7,4,8 LAP-1, Halad 447, GasStop
HT
NFL-2, NFL-3, D-33
LTXL Only for fresh water
Liquid BA-10L UniflexL FLC-100 LA-2
Powder UniflexS GasStop HT Use up to 10% salt by weight Liquid FL-45LN,
FL-45LS D300,
UniflexL Halad-10L
Powder FL-52, FL-25 D60, UniflexS Halad 9, 332,
413, 567 NFL-2 Use up to 18% salt
by weight Liquid UniflexL
Halad 9L, 9LXP, 322L,
322LXP LD-18
Powder FM-HTFL-1270 FL-33, FL-63 D59,
UniflexS FLC4, 7, 8 D-24 Sarf 3, FC-22, FC-2
General application
80 °F to 200 °F
Use over 18% salt by weight
Liquid FL-33L, FL-63L UniflexL FLC-107 LD-24
FLUID-LOSS CONTROL ADDITIVES (CONT. 1)
Appication Circulating temperature range
Compatibility with salt (NaCl):
Salt concentration and temperature
limitations
Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder FM-HTFL-1250 FL-62 UniflexS
GasStop HT, Halad 413,
567 D-30 Sarf 2
Only for fresh water
Liquid BA-10L UniflexL LD-30 LD-30
Powder UniflexS GasStop HT, Halad 413,
567 FC-9 Use up to 10% salt
by weight Liquid UniflexL
Powder FM-HTFL-1270 FL-52, FL-25 D160,
UniflexS Halad 22A, 344 FC-22
Use up to 18% salt by weight
Liquid D603, D159,
UniflexL Halad 22AL,
22ALXP
Powder FM-HTFL-1270
FL-32, FL-33, FL-63
D65A, UniflexS
General application
Effective up to 250 °F
Use over 18% salt by weight
Liquid FL-32L, FL-33L, FL-63L
D80A, D604AM UniflexL
Powder FM-HTFL-1250/1270 UniflexS GasStopHT,
Halad 413 Diacel, LWL Only for fresh water
Liquid UniflexL
Powder FM-HTFL-1270 UniflexS Use up to 10% salt
by weight Liquid UniflexL
Powder FM-HTFL-1270 FL-52, FL-25 UniflexS FLC-7
Halad-14, GasStop HT,
Halad 413 D-24 Use up to 18% salt
by weight Liquid UniflexL FLC-107 Halad-14LXP,
Halad 600LE LD-24
Powder FL-32, FL-33, FL-63 UniflexS GasStop HT,
Halad 413
General application
Effective up to 300 °F
Use over 18% salt by weight Liquid FL-32L, FL-33L,
FL-63L UniflexL
FLUID-LOSS CONTROL ADDITIVES (CONT. 2)
Appication Circulating temperature range
Compatibility with salt (NaCl):
Salt concentration and temperature
limitations
Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder FM-HTFL-1250
UniflexS FLC-7 GastStop HT, Halad 413
Only for fresh water
Liquid UniflexL FLC-107
Powder FM-HTFL-1270 UniflexS GasStop HT,
Halad 413 Up to 10% salt by weight
Liquid UniflexL
Powder FM-HTFL-1270
UniflexS GasStop HT, Halad 413
D-28 Up to 18% salt by
weight Liquid FM-HTFL-
1270 D73,
D73.1,D158, UniflexL
LD-28
Powder FM-HTFL-
1270, Diacel LWL
FL-33, FL-63, FL-32
D8, Diacel LWL,D143,
UniflexS
Halad 413, 100A, Diacel
LWL, Gas Stop HT
Diacel LWL
General application
Efective over 300 °F
Over 18% salt by weight
Liquid FL-33L,FL63L FL-32L
D158, UniflexL
Halad-413L, 361A, 600LE
General and special application Latex: Styrene/ butadiene copolymer
From 100 °F to 400 ° F depending upon product and stabilizers
Recommended for fresh water. May be used up to 18% salt
by weight
Liquid LAC-1 BA-86L D600, D134, UniflexL
Latex-1 Latex 2000
Powder UniflexS LAP-1, Halad 447
General and special application Latex: Acrilic
Up to 200/250 °F
Recommended for fresh water
Liquid UniflexL LA-2
Powder FL-52 D112,D156 UniflexS
FLC-4, FLC-7, FLC-8
D23, D24 NFL-2
Fluid loss control in highly extended or low density slurries
Variable limits Variable limits
Liquid BL Blue D159,D300 UniflexL
FLC-100 LD-24
Powder UniflexS
Fluid loss control in blast furnace slag slurries (containing no Portland cement)
Variable limits Variable limits
Liquid UniflexL
FLUID-LOSS CONTROL ADDITIVES (CONT. 3)
Appication Circulating temperature range
Compatibility with salt (NaCl):
Salt concentration and temperature
limitations
Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Stabilizer for latex in the presence of salt or at high temperature
Liquid LS-1, LS-2 D135, UniflexL Stabilizer 434B,
Stabilizer 434C
Stabilizer for latex in low density slurries
Liquid CD-32, CD-33 D138, UniflexL Stabilizer 434B,
Stabilizer 434C
Fluid loss aid Up to 200 °F Powder D136, UniflexS FLC-2
Fluid loss aid Over 200 °F Powder D121, UniflexS FLC-2
SILICA TO REDUCE OR PREVENT HIGH TEMPERATURE STRENGTH RETROGRESSION Material Product type Product
form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Sand
Crystalline silica approximately 100 mesh. SG 2.65 nominal
Granular solid FM-SR-1150 S-8C D30 SFA-100 SSA-2 L-10 SF-100
Silica flour
Cristalline silica approximately 200 mesh or finer SG 2.65 nominal
Fine Powder FM-SR-1100 S-8 D66 SFA-200 SSA-1 SFA-200,
SFA-325 SF-200, SF-225
Microfine silica: For use with microfine cements
Crystalline silica SG 2.65 nominal
Fine Powder
Available on request FS-1 Microsand
RETARDERS Appication
Circulating temperature range
Product type Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder FM-R-1400 R-3 D13 CR-1 HR-4, HR-7 R-6 SR-2 Low temperature Up 180 °F
Lignosulfonate, mofified lignosulfonate Liquid R-21L D81 CR-100 HR-4L, HR-7L R-6L
Powder R-3, R-11 D800 CR-2 HR-5 SR-6 Mid-range, moderate temperature
125 to 225 °F Lignosulfonate. Modified lignosulfonate blend Liquid FM-R-4 R-10L, R-12,
R-21L D801 CR-102 HR-6L R-40L SR6-1
Powder FM-R-22 CR-5 Diacel LWL
Moderate to hight temperature
175 to 300 °F Organic acid or organic acid salt blend Liquid D110 CR-105
Powder Diacel LWL R-6 or Diacel LWL D8 CMHEC Diacel LWL Diacel
LWL SR-12 Moderate to hight temperature
175 to 300 °F
Diacel LWL (carboxymethyl hydroxyethyl cellulose) Liquid
Powder FM-R-1400 R-8 D28 CR-5 HR-12, HR-15 R-55 SR-10 Hight temperature Over 225 °F Modified
lignosulfonate blend Liquid R-8L D150 CR-105 HR-12L, HR-13L R-55L
Powder CR-5, CR-3 HR-20 R-57 Hight temperature Over 300 °F
Blend of lignosulfonate or modified lignosulfonate with borax or borate salt
Liquid
Retarder aid for lignosulfonates Borax/borate salt Powder Borax R-9 or sodium
borate D93 CR-3 Component R R-35
Retarder aid for lignosulfonates Non-borax/norate
salt Powder D121 HR-25
Powder SR-30 SCR-100 Synthetic retarder Up to 250 °F
Proprietary, synthesized polymer or copolymer. Non- lignosulfonate
Liquid R-14L, R-15LS, R-20L SCR-100L
Powder SR-30 HR-25 Synthetic retarder Up to 425 °F
Liquid HR-25L
Powder SR-30 D161 SCR-100 Retarder for improved compressive strength in long cement columns
Helps early compressive strength where significant temperature differential exists
Liquid D110 SCR-100L
RETARDERS (CONT.)
Appication Circulating temperature range
Product type Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder Retarder for microfine cements
Liquid MMCR
Thixotropic cement retarder
For slurries containing calcium sulfate hemihydrate or gypsum
Powder R-18, SR-30 D74 CR-4
Powder R-7 FRC-2 Sodium citrate R-15 Permafrost cement retarder
Citric acid or citrate salt or similar, non-lignosulfonate Liquid
Powder D13 CR-1 HR-4 R-7 Permafrost Lignosulfonate
Liquid D81 CR-100 HR-4L
ANTI-GAS MIGRATION AGENTS General mechanism of action Product type Product
form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Fluid loss control only See: fluid loss control additives
Powder BA-56, BA-56HT, BA-100, FLAG-56 GasblockLT Polymeric blends:
(Non-Latex) Liquid BA-100L, FL-45LS LN, BJ Blue
Latex: Styrene/butadiede copolymer or similar
Liquid LAC-1 BA-86L D600, D134 Latex-1 Latex 2000
Powder BA-10 LAP-1, Halad-447
Latex: Acrylic Liquid BA-10L LA-2
Powder Fumed silica BA-58, CSE, BA-90 D154 FS-1
Silicalite, compacted
silicalite
Microsil10P Microsil 22P
Fumed silica
Liquid On request BA-58L D155 FS-101 Liquid
silicalite, Microblock
Microsil 15L
Powder
Matrix flow restriction/blocking
Fumed silica/polymer blends Liquid Calcium sulfate hemihydrate or gypsum
Powder Gypsum A-10 or gypsum D53 Ultracal 60 Cal-seal, EA-2 Gyp-cem
Powder Cross-linked or complexed polymeric materials Liquid Thix Set 31
Powder On request BA-46 Telmaster, Thixmaster, FastMaser2
Thix-Set A, VersaSet
Thix-Mix, Thix-O-Gel,
Thermal Thix-Mix
Gel strength modification: Thixotropic additives/slurries
Other
Liquid BA-46L Versaset L, VersaSet
LXP
Powder D65A GasStop, GasStop HT Gel-strength
modification: Delayed gelling
Proprietary polymeric additives
Liquid D604AM GasStop L, GasStop
LXP
ANTI-GAS MIGRATION AGENTS (CONT.) General mechanism of action Product type Product
form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Powder On request BA-29, BA-61 CPC-1 Super CBL SPC-12000 Alteration of cement slurry compressibility: Gas-generating agents
Aluminum powder or similar Liquid
Gas-check, Inhibited Gas-
Check
Alteration of cement slurry compressibility: Foamed cement
Foamed cement Foamed cement Foamed
cement Foamed cement
Foamed cement
Foamed cement
Supplemental agents for gas migration control
Stabilizer for Latex in the presence of salt or at high temperature
LS-1, LS-2 D135 Stabilizer 434B, Stabilizer 434C
Supplemental agents for gas migration control
Stabilizer for Latex in low-density slurries CD-32, CD-33 D138 Stabilizer 434B,
Stabilizer 434C CF-1
ANTI-FOAM AND DEFOAMING AGENTS General mechanism of action Product type Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Dry-powders, granules,
beads, etc. FM-AF-P FP-11 D46 DEF-3 D-Air 1 Prevent or decrease
foaming during mixing
High molecular weight alcohols, polyalcohols, silicones, etc. Liquid FM-AF-L
FP-6L, FP-9L, FP-12L, FP-10L,
AFA-3
D47, M45, D144
DEF-1, DEF-5
D-Air 2, D-Air 3, NF-3, NF-4, NF-6,
NF-7
AFA-2, AFA-3
DENSITY INCREASING OR WEIGHTING AGENTS
Material Product type Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Sand
Cirstalline silica approximately 40-70, 20-40 mesh or similar coarse material SG 2.65 nominal
Granular solid Sand Sand Sand Sand Sand Sand
Sand
Crystalline silica approximately 100 mesh SG 2.65 nominal
Granular solid FM-SR-1150 S-8C D30 SFA-100 SSA-2 L-10
Silica flour
Crystalline silica approximately 200 mesh or finer SG 2.65 nominal
Fine powder FM-SR-1100 S-8 D66 SFA-200 SSA-1 SFA-200,
SFA-325
Microfine silica: For use with microfine cements
Crystalline silica SG 2.65 nominal
Fine powder Microsand
Ilmenite Iron Titanium oxide SG 4.4 – 4.5 nominal Powder Ilmenite Ilmenite Ilmenite Ilmenite
Hematite Iron oxide SG 5 – 5.2 nominal Powder Hematite Hematite D76 Hematite Hi-Dense 3,
Hi-Dense 4 Hematite
Barite Barium sulfate SG 4.2 nominal
Fine powder Barite Barite D31 Barite Barite Barite
Manganese oxides SG 4.6 – 4.9 nominal Fine powder W-10 D157 Micromax
Microfine weighting agents for use with microfine cements
SG 4.9 Fine powder D157 Micromax
Calcium carbonate for use in spacers SG 2.75 Granular
solid D151
ADDITIVES AND MIXTURES TO REDUCE OR PREVENT LOST CIRCULATION
Material Description Product form
American Fracmaster
Ltd BJ Services Dowell Fracmaster Halliburton Nowsco
Canada San
Antonio
Cements SEE: Basic cements Slurries
Thixotropic cement slurries: Aqueous
Slurries Available custom blend
Sure Fill, Sure Plug, Thixofill, Thixofume,
Gypsum cement, BJ Thixo
RFC Thixmaster, Telmaster, Plugmaster
Thix-Set, Thix-Set 31,
Thixlite 373, Cal-Seal cement, VersaSet
Thix-Mix, Thix-O-Gel,
Thermal Thix-Mix, Rapid Gel
SPC, Rapid Set
Foamed cement Slurries Foamed cement
Foamed cement Foamed cement
Foamed cement
Foamed cement
Foamed cement
Non-aqueous slurries
Diesel oil cements, diesel oil bentonite cements, gunk squeeze, etc. Made with regular grind cements
Slurries Diesel cement
Diesel oil cement, Visqueeze Mark II, Diesel oil/bentonite,
Zone check
Polymer Plug, SOS
Diesel cement systems
BDO, BDOC, DOC, Flex-
plug
Diesel Gel, Diesel cement
Non-aqueous cement slurries
Made with microfine cements
Slurries MOC-1
Reactive washes, polymer solutions
Sodium silicate solutions, complexed sodium silicate solutions, polymer solutions
Liquid mixtures Custom Flush
Flo-guard L, Stop Block, SAF Mark III,
Siljel V
Zonelock, Permablock
Gel Seal, Masterflush, Mastersweep
Superflush Thixseal
Sand Graded and sized to meet needs
Granular Sand Sand Sand Sand Sand Sand
Mica Flake/ Powder Mica Mica Mica Mica Mica
Cellophane flake Flake Celloflake Celloflake D29 Celloflake Flocele Celloflake
Gilsonite Granular Gilsonite Gilsonite D24 Gilsonite Gilsonite Gilsonite
Ground coal Granular Kol seal D42 Kollite NLC-1
Walnut plugs Tuf plug or equivalent Granular On request Nut plug Tuf Plug
Perlite Beads On request Perlite D72 Perlite Perlite Fibers: Nylon, Polypropinele, cellulose, etc.
Fibrous/ poeder
On request LCM-2 Tuf additive No. 2
Wood chips Granular/ Flake
On request Wood chips Wood chips Wood chips Wood chips
Polyester, rubber, Granular Flex Seal, Hi-Seal,
Mud save F, Mud save M
D130 On request Granulite TR 1/4
Kwik seal Granular Kwik Seal
Proprietary Acid soluble, expanding bridging agenbt Flakes Cuttings K Perfect seal
SPACERS AND CHEMICAL WASHES/PREFLUSHES
Spacer or wash type Description American
Fracmaster Ltd
BJ Services Dowell Fracmaster Halliburton Nowsco Canada
San Antonio
Reactive – containing sodium silicate or similar reactive materials
Chekmaster Flowcheck, Flo Guard
Zonelock, Zonelock SC Gel Seal Super flush Thix-Seal
Flush
Aqueous – containing surfactants and solvents. No fluid loss control
Chemwash-1 Mud clean, MRS-2
CW-7, CW-8, CW-8ES
Masterflush W Mud Flush Nowflush 6,
Nowflush 7
Aqueous – containing surfactants and solvents. Contains agents to reduce fluid loss to formations
Mud sweep, Ultraflush II
CW-100, CW-101 Alpha
Preflush
Chemical washes (Not weighted with solid weighting agents)
Non-aqueous – blend or surfactants, solvents, etc in hydrocarbon carrier fluid
Masterflush O
N-Ver-Sperse O
Chemical washes recommended for wells drilled with OBM
Chemwash D CW-8,
CW-8ES, CW-101
Masterflush O
N-Ver-Sperse O, Alpha Preflush
Nowflush 6, Nowflush 7
Chemical washes design for mixability at sub-zero temperatures
Aqueous formulations containing a freeze point depressant
Formulated for turbulent flow at low pump rates FOMS-300
MCS-2, MCS-3 MCS-4, MCS-5
Ultraflush II, Turbo Flo 3
Mudpush XT Mudpush XTO Mudpush XS
Mudpush XSO
Dual Spacer, SD Spacer, Spacer 500
Nowsweep W
Formulated for laminar flow Weighted mud
sweep Mudpush XL
Mudpush XLO Mastersweep
W Tuned Spacer Supersweep
Spacers – Aqueous, weighted
Flow regime not specified MudpushWHT Alpha spacer
Water continuous phase APS-1 Mudpush XEO
Oil continuous phase FOMS-100 OB-1, RSB SAM-4 Spacers – Emulsion, weighted
Solvent continuous phase Turbo-Solvent
Spacers – Recommended in wells drilled with OBM
FOMS-200 MCS-3, MCS-4
RSB, Turbo-Solvent
Mudpush XLO Mudpush XTO Mudpush XEO
Mastersweep O
Dual Spacer, Alpha spacer,
SAM-4, Tuned spacer
Nowflush 6, Nowflush 7
Spacers – Formulations compatible with high salt concentrations
Mudpush XS Dual spacer, Dual spacer
E
Spacers – Fluids containing blast furnace slag for use with Slag-Mix and slag cement
OMR-2
SPECIALTY CEMENT BLENDS
General formulation Specific formulation American
Fracmaster Ltd
BJ Services Dowell Fracmaster Halliburton Nowsco Canada
San Antonio
Blends of Portland cement with commercial lightweight cements such us TXI Lightweight
(1) Thriftmaster, Thriftmaster
LT Tru-Lite R,
Tru-Lite HS
Ratio of flyash: cement at 15:85 with bentonite up to 8%
15:85:8 FAC (2) (Flyash cement) (1) Nowlite 2
Ratio of flyash: cement at 35:65 with bentonite up to 6%
AFL-Lite FAC (2) (1) Halliburton Light cement Nowlite 1
Ratio of flyash: cement at 50:50 with bentonite up to 4%
50:50:4 FAC (2) (1) Fillmaster Halliburton Pozment A Nowlite 3
Blends of Portland cement, Flyash and Gel (Bentonite)
Other ratios FAC (2), Econofill (1)
Blends of cement. Flyash and silica fume On request WMC-1,
WMC-1B
Blends containing cement, silica fume and pozzolan microspheres
FM-Lite HILITE My-T-Lite 1200 Nowlite 1200
Blends of containing lightweight pozzolan microspheres
On request Cenolite LITEFILL Litemaster, Litemaster 2
SpheraLite Cement
Blends containing lightweight glass beads Lite Set
Blends of cement, flyash, lime and silica for high temperature applications
On request
HTLD (High temperature Low Density
Cement)
Low density cement blend with superior compressive strength (10.5 to 12.5 ppg)
Proprietary blend LiteCRETE On request
High density cement blend with superior mixing and rheological properties (17.5 to 24 ppg)
Proprietary blend LW-6/MPA-1, Portland Blend LiteCRETE On request
Expanding cements containing calcium sulfate hemihydrate or similar
Self Stress Cement Bondmaster On request Expand-O-Mix
SPECIALTY CEMENT BLENDS (CONT. 1)
General formulation Specific formulation American
Fracmaster Ltd
BJ Services Dowell Fracmaster Halliburton Nowsco Canada
San Antonio
Expanding cements containing metal oxide expanding agents
Expanding cement containing gas generating agents
Rapid Gel SPC
Containing calcium sulfate hemihydrate or gypsum
Sure Fill RFC
(Regulated fill-up cement
Thixmaster On request Thix-Mix
Crosslinked polymer complexes Thix-Set 31
Thixotropic cements
Proprietary additives Thixofil Versaset BVC-30
Permafrost cement Cold Set Arcticset cement Permafrost
cement Polarset Cement
Cements to improve bonding
Containing polymeric additives such us latex, polyvinyl alcohol, etc.
Wellbond Service Telmaster Latex
Cement
Salt containing or salt saturated cements
Salt Saturated Cement
Cements to improve bonding to salt formations Proprietary additives to
improve bonding to salt formations
Saltbond cement On request
Carbon dioxide resistant cements CO2 resistant
cement Flexcem, Thermalock
Acid resistant cement Portland cements with additives to reduce acid solubility
Flexcem, Epseal
Synthetic resin cement Epoxy resin cement Synthetic cement Epseal,
Atratalock
Acid soluble cement Non-Portland inorganic cement completely soluble in acid
Magne Plus Acid soluble cement On request Acid soluble
cement
Storable liquid cement Water-based liquid cement slurry Liquid Stone
SPECIALTY CEMENT BLENDS (CONT. 2)
General formulation Specific formulation American
Fracmaster Ltd
BJ Services Dowell Fracmaster Halliburton Nowsco Canada
San Antonio
Fiber cement
Cement containing fibers to increase resistance to mechanical shock and tensile stress
Fiber cement On request On request On request
Deepwater cement
Blend for cold temperature of deep water drilling where shallow water flow zones are a problem
Deep Set RAS Flow Stop I, Flow Stop
4000
(1) No compositional name used. Blends are referred to by their actual composition (35:65:6, 50:50:2, etc). (2) Flyash cement or FAC is used to describe all blends of flyash and cement. The ratio is specific for the appication.