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Cement Additives - Cross Reference

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CEMENTING PRODUCTS AND ADDITIVES (March 1999) The 1999 Cementing Supplement is a comprehensive listing of cementing products and additives available from mayor suppliers. This most recent update now comprises seven companies, including two companies new to the listing. American Fracmaster Ltd. Is the U.S. affiliate of Fracmaster in Calgary, Canada. The firms have separate but complementary products lines. Argentinas’ s San Antonio is listed in Cementing this year for the first time as well. HOW TO USE THIS REFERENCE Listings reflect available cement additives from seven service companies. Products are grouped into functional categories. Some products are unique to a company, and many are protected by patent rights or other legal means. They may be chemically similar, but not identical, and provide comparable performance in cement slurry formulations. Exact equivalence is not implied. Where applicable, products are subdivided into groups having similar performance within each functional category. Performance groups have been subdivided to reflect significant differences in chemical nature of additives and emphasize uniqueness within each company’ s product line. What can not be reflected are differences in product performance with different cements, or performance variations resulting from different sources of the same material around the world. Materials should be tested according to accepted procedures to ensure that performance requirements are met. Also, users are cautioned that it is generally not possible or prudent to make “translations” of cement formulations between service companies based solely on additive descriptions. Products are grouped in 15 functional categories: Basic cements Accelerators and salts Extenders and density-reducing additives Free water control and solids suspending agents Dispersants Bond improving and expanding additives Fluid-loss control additives Silica to reduce or prevent high temperature strength retrogression Retarders Anti-gas migration agents Anti-foam and defoaming agents Density increasing or weighting agents Additives and mixtures to reduce or prevent lost circulation Spacers and chemical washes or preflushes Specialty cement blends Temperature has a significant effect on many cementing additives and is the single most important variable affecting cement hydration. This is particularly for retarders, but also applies to fluid loss control additives, anti-gas migration, expanding and other agents. Salt tolerance is particularly important in fluid loss control additive selection. When applicable, this reference
Transcript

CEMENTING PRODUCTS AND ADDITIVES (March 1999) The 1999 Cementing Supplement is a comprehensive listing of cementing products and additives available from mayor suppliers. This most recent update now comprises seven companies, including two companies new to the listing. American Fracmaster Ltd. Is the U.S. affiliate of Fracmaster in Calgary, Canada. The firms have separate but complementary products lines. Argentinas’ s San Antonio is listed in Cementing this year for the first time as well. HOW TO USE THIS REFERENCE Listings reflect available cement additives from seven service companies. Products are grouped into functional categories. Some products are unique to a company, and many are protected by patent rights or other legal means. They may be chemically similar, but not identical, and provide comparable performance in cement slurry formulations. Exact equivalence is not implied. Where applicable, products are subdivided into groups having similar performance within each functional category. Performance groups have been subdivided to reflect significant differences in chemical nature of additives and emphasize uniqueness within each company’ s product line. What can not be reflected are differences in product performance with different cements, or performance variations resulting from different sources of the same material around the world. Materials should be tested according to accepted procedures to ensure that performance requirements are met. Also, users are cautioned that it is generally not possible or prudent to make “translations” of cement formulations between service companies based solely on additive descriptions. Products are grouped in 15 functional categories: • Basic cements • Accelerators and salts • Extenders and density-reducing additives • Free water control and solids suspending agents • Dispersants • Bond improving and expanding additives • Fluid-loss control additives • Silica to reduce or prevent high temperature strength retrogression • Retarders • Anti-gas migration agents • Anti-foam and defoaming agents • Density increasing or weighting agents • Additives and mixtures to reduce or prevent lost circulation • Spacers and chemical washes or preflushes • Specialty cement blends Temperature has a significant effect on many cementing additives and is the single most important variable affecting cement hydration. This is particularly for retarders, but also applies to fluid loss control additives, anti-gas migration, expanding and other agents. Salt tolerance is particularly important in fluid loss control additive selection. When applicable, this reference

includes temperature ranges groupings, salt tolerance and other variables critical to additive performance. Temperature and salt tolerance are broad groupings and actual performance may vary somewhat depending on cement, other additives in formulations and well conditions. Important note. Fluid loss control additives are listed according to maximum temperature and salt tolerance for that product. For example, if an additive is shown to be effective up at about 250 °F in the presence of over 18% salt (by weight of mix water), it is very likely that this product is also effective at higher temperatures with lower salt concentrations. There are several examples of this in the table. Finally, if a company does not have an equivalent to a competitor’s product listing, it does not mean that the company can not come up with a cement formulation that achieves similar performance. Our recommendation is to call the company, describe the application or problem and let them work on a solution. Even though additive technology has advanced, it is still best applied with a measure of experience.

BASIC CEMENTS

Material Description American

Fracmaster Ltd

BJ Services Dowell Fracmaster Halliburton Nowsco Canada

San Antonio

API Class A, B and ASTM Type I or II cements A A, B Type I, II A, B Type I, II Normal

Portland Standard A, B Type I, II A, B

API Class G or H H G, H G, H G, H Premium G, H G, H Portland cement

API Class C and ASTM type III C C, Type III C, Type III C Premium Plus C, Type III

High aluminate cement Calcium aluminate cement Fondu Lumnite, Ciment Fondu

Lumnite, Ciment Fondu Fondu Ciment

Fondu Ciment Fondu

Ciment Fondu

Commercial lightweight cements TXI lightweight or equivalent TXI

Lightweight TXI

Lightweight TXI

Lightweight TXI

Lightweight TXI

Lightweight TXI

Lightweight Lightweight

Commercial expanding cements

Chem Comp, ASTM type K or similar

Microfine Portland cement MC-300 or equivalent Available

on request MC-300 Microfine cement

Channelmaster

Micromatrix cement

Microfine Portland cement and microfine blast furnace slag blend

MC-500 or equivalent Available on request MC-500 Microfine

cement Channelma

ster CS Matrix

cement Microcem

1000

High fineness cement Cements ground finer than normal but not as microfine cements

Fine Grind Class C cement

Blast furnace slag (BFS) Ground, granulated or pelletized blast furnace slag Blast Furnace

Slag cement Blast Furnace Slag (D930) Slag

cement Slag-10, 20,

30, 40

Microfine blast furnace slag MC-100 or equivalent

Blend of Portland cement and blast furnace slag

Blend to improve poor quality Portland cements and improve additive response

Slagment

Storable liquid cement slurry

Water-based liquid cement slurry Liquid stone

Acid soluble cement Non-Portland inorganic cement soluble in acid Magne Plus Acid soluble

cement Available

on request Acid soluble

cement Magna cement

Synthetic resin cement Epoxi resin cement Synthetic cement EPSEAL,

Stratalock

ACCELERATORS AND SALTS

Material Description Product Form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Sodium chloride (salt)

Reduces thickening time of cement at concentrations between 1% and 10% by weight in the mix water

Granular Salt A-5 or salt or Sodium Chloride D44 Salt Salt Cement

Grade salt Salt

Solid CaCl2 A-7 or CaCl2 S1 CaCl2 Calcium Chloride

Calcium Chloride

Calcium Chloride

Calcium Chloride

Accelerator. Reduces thickening time of cement. Typically used at 1% to 3% by weight of cement

Liquid CaCl2-L A-7L or CaCl2-L D77 CaCl2-L Calcium Chloride Liquid

Calcium Chloride Liquid

Powder or Beads

Sodium Metasilicate

A-2, Sodium Metasilicate,

Diacel A D79, Diacel A TXC-1 Econolite,

Diacel A EXC Sodium

Metasilicate Diacel A Sodium silicate

Accelerator. Reduces thickening time of cement. Increases slurry viscosity Liquid Liquid sodium

silicate A-3L or Sodium

Silicate D75 EXT-100 Liquid Econolite EXC-L

SE-1L Sodium silicate

Calcium sulfate hemihydrate or gypsum

Accelerator. Reduces thickening time of cement. Often used to create thixtropic cement slurries

Powder Gypsum A-10 or Gypsum D53 Ultracal 60 Cal-Seal, EA-2

Gyp-Cem, Quik Gyp Gypsum

Potassium chloride KCl Granular KCl

A-9 or Potassium Chloride

M117 KCl KCl KCl KCl

Ammonium chloride NH4Cl Granular Available on

request Available on

request Available on

request Available

on request Available

on request Available

on request NH4Cl

Proprietary accelerator AEF-100L,

T-40L CA-3 CA-4

EXTENDERS AND DENSITY-REDUCING ADDITIVES Material Description Product

Form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Bentonite Naturally colloidal clay Powder Bentonite Bentonite D20 Bentonite Gel Bentonite Bentonite

Attapulgite Naturally colloidal clay Powder Salt Gel Attapulgite D128 Salt gel Attapulgite Salt Gel Sepiolite Attapilgite

Type F flyash

Pozzolanic material product of burning coal. Lower in lime content than type C

Powder Pozzolan Flyash D35 Pozzolan Pozmix A NowPoz Pozzolan

Type C, flyash Pozzolanic material product of burning coal Powder Flyash D132 Calss C

Flyash NowPoz

Microfine flyash For use with microfine cements Powder Microflyash

Natural pozzolan

Siliceous material produced from volcanic activity

Powder Pozzolan D61 Pozzolan

Diatomaceous earth

Lightweight, friable siliceous material derived from diatom remains

Powder Granular Diacel D Diacel D D56 Diacel D D.E. Diacel D

Perlite/expand perlite

Volcanic glass, spherelitic and hollow

Granules Beads Perlite Perlite D72 Perlite Perlite Perlite

Powder Fumed Silica

BA-58 CSE D154 FS-1 Silicalite Microsil-10P

Microsil-22P Microsilica Fumed silica (dry)

High surface area, amorphous silica Liquid

Suspension On request BA-58L LW-8L D155 FS-101

Liquid silicalite,

Microblock Microsil-15L

Glass microspheres Scotchlite or similar Small beads On request LW-7-2,

LW-7-4 On

request Galss Spheres

Nowspheres 2000 Esfelite

Pozzolan microspheres

Spherulitic, expanded pozzolanic material produce from burning coal

Powder-like Small beads C Spheres LW-6 D124 Ceramic

Spheres Spherelite Nowspheres 7000

Powder or beads

Sodium Metasilicate

Thrifty Mix, Diacel A, Sodium

Metasilicate

D79, Diacel A TXC-1 Econolite,

Diacel A EXC SE-15

Sodium silicate

Liquid Liquid sodium silicate

Thrifty Mix-L, Sodium Silicate

Liquid D75 EXT-100 Liquid

Econilite EXC-L

Solid T-40 Black-Lite Versaset D-20 Proprietary extender

Liquid BJ Blue D111 GasCon 469 Versaset L

FREE WATER CONTROL AND SOLIDS SUSPENDING AGENTS

Application Product type Product Form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Dry powders, granules, beads, etc

Sodium metasilicate,

Diacel A

A-2 or sodium metasilicate,

Diacel A, T-40, FWC-47, ASA-

301

D79, Diacel A,

D153 TXC-1

Econolite, Diacel A, VersaSet,

FWCA, Suspend HT,

SA-541

FW-1, EXC

Sodium metasilicate,

Diacel A, SE 18

Polymers, sodium silicates, biopolymers, proprietary chemicals

Liquid Liquid

Sodium Silicate

A-3L or sodium silicate, T-40L,

FWC-47L, ASA-301L, BJ Blue

D75, D162 EXT-100

Liquid Econolite,

VersaSet L, VersaSet LXP, GasCon 469

FW-2, EXC-L SE IL

Powder Bentonite, Attapulsite

Bentonite, attapulgite, BA-58, CSE, BA-90

D20, D128, D154

Bentonite, FS-1, TXC-1,

Salt gel, FWC-3

Gel, Attapulgite, Silicalite,

Compacted silicalite,

Microblock

Bentonite, Attapulgite,

Microsil 10P, Microsil 22P

Microsilica, Bentonite

Free water control and solids suspension

Bentonite, attapulgite, fumed silica, etc. See also: Extenders and density reducing agents Liquid Available on

request BA-58L,

Microblock D155 FS-101, EXT-100

Liquid silicalite, Microblock Microsil 15L SE IL

DISPERSANTS

Application Product type Product Form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder Available on request CD-31 D65 FRC-3 CFR-2 T-10

1W, 3W, FT-4,

Granular Powder, FT4-L

Polynapthalene sulfonate (PNS) type. Example products: Lomar-D, Daxad-19 or equivalent Liquid Available on

request

CD-31L, CD-31NL, CD-31LS

D80 FRC-100 CFR-2L T-10L

Powder FMD-1300 CD-33 CFR-3

Liquid CFR-3L Proprietary, non-PNS, non-lignosulfonate

Liquid D145A

Powder CD-32 Proprietary

Liquid

General Application

Proprietary: for use above about 200 F circulating temperature

Powder FMD-1300 D121

Citric acid, citrate salt or similar

Powder Granular

FM-MTB 1500 XR-2 D45 FRC-2 FE-2 T-11

Powder FM-MTB 1600 CD-33 D65A CFR-3

Dispersant for salt-saturated slurries

Polimetric materials (not citric acid, citrate salt, etc) Liquid D80A,

D604AM CFR-3L

Powder CD-32 CFR-2 Dispersant with non-setting or anti-setting characteristics for easily dispersed cements

Liquid CD-33L D604AM CFR-2L

BOND IMPROVING AND EXPANDING ADDITIVES

Application Product type Product Form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Latex: Styrene/butadiene copolymer

Liquid LAC-1 BA-86L D600, D134 Latex-1 Latex 2000

Powder LAC-1P BA-10, BA-56,

BH-56HT, FLAG-56

LAP-1,

FloBlock 210, Halad 447

Latex: Acrylic or equivalent Liquid BA-10L LA-2 NL-2 NL-2

Powder Fumed silica BA-58, CSE, BA-90 D154 FS-1

Silicalite, Compacted

silicalite

Microsil 10P, Microsil 22P

Fumed silica

Liquid Available on request BA-58L D155 FS-101 Liquid silicalite,

Microblock Microsil 15L

Fumed silica/flyash blend Powder Nowlite BA-91 Silicalite blend Nowlite Nowlite

Powder D65A

Improve cement bonding to surfaces: Non-expanding additives

Improve bonding to salt formations

Liquid D80A,

D604AM, D604M

Calcium sulfate hemihydrate or gypsum

Powder Gypsum A-10 or Gypsum D53 Ultracal 60 Cal-Seal, EA-2 Gyp-Cem,

Quik Gyp

Pwder Available on request EC-1, EC-2

Microbond, Microbond M, Microbond HT

Metal oxide

Liquid

Powder Available on request BA-29, BA-61 CPC-1 Super CBL SPC-12000

Expanding agents, may also improve bonding

Gas-generating agents: Aluminum powder or similar Liquid Available on

requesr Gas-Check,

Inhibited Gas- Check

Powder BA-92, BA-100, MPA-1, MPA-2 Bondmaster

Other materials Proprietary Liquid BA-100L

FLUID-LOSS CONTROL ADDITIVES

Appication Circulating temperature range

Compatibility with salt (NaCl):

Salt concentration and temperature

limitations

Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder FM-FL-1200 FL-62, BA-10 D127, D156

FLC-1, FLC-5 LAP-1 D-25 LTX Use in fresh water

or with less than 5% salt by weight Liquid BA-10L,

FL-45LS/LN UniflexL FLC-100 LA-2 LTXL

Powder UniflexS D19, D30 D19,D30 Use up to 10% salt

by weight Liquid UniflexL LD-30 FC-19, FC-22,

Sarf-100

Powder FM-HTFL-1270 FL-33, FL-63 D146,

UniflexS FLC-7 Halad 322,

344,413,567, Gas Stop HT

D-24, NFL-2

Low temperature when little or no retarding effect is desired

60 °F to 120 °F

Use up to 18% salt by weight

Liquid FL-33L, FL-63L UniflexL FLC-107

Halad 322L, 322LXP,

344LXP, 413L, 361A, 600LE

LD-18, LD-24 LTX

Powder FM-FL-1200 FL-62, BA-10 UniflexS FLC-1,7,4,8 LAP-1, Halad 447, GasStop

HT

NFL-2, NFL-3, D-33

LTXL Only for fresh water

Liquid BA-10L UniflexL FLC-100 LA-2

Powder UniflexS GasStop HT Use up to 10% salt by weight Liquid FL-45LN,

FL-45LS D300,

UniflexL Halad-10L

Powder FL-52, FL-25 D60, UniflexS Halad 9, 332,

413, 567 NFL-2 Use up to 18% salt

by weight Liquid UniflexL

Halad 9L, 9LXP, 322L,

322LXP LD-18

Powder FM-HTFL-1270 FL-33, FL-63 D59,

UniflexS FLC4, 7, 8 D-24 Sarf 3, FC-22, FC-2

General application

80 °F to 200 °F

Use over 18% salt by weight

Liquid FL-33L, FL-63L UniflexL FLC-107 LD-24

FLUID-LOSS CONTROL ADDITIVES (CONT. 1)

Appication Circulating temperature range

Compatibility with salt (NaCl):

Salt concentration and temperature

limitations

Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder FM-HTFL-1250 FL-62 UniflexS

GasStop HT, Halad 413,

567 D-30 Sarf 2

Only for fresh water

Liquid BA-10L UniflexL LD-30 LD-30

Powder UniflexS GasStop HT, Halad 413,

567 FC-9 Use up to 10% salt

by weight Liquid UniflexL

Powder FM-HTFL-1270 FL-52, FL-25 D160,

UniflexS Halad 22A, 344 FC-22

Use up to 18% salt by weight

Liquid D603, D159,

UniflexL Halad 22AL,

22ALXP

Powder FM-HTFL-1270

FL-32, FL-33, FL-63

D65A, UniflexS

General application

Effective up to 250 °F

Use over 18% salt by weight

Liquid FL-32L, FL-33L, FL-63L

D80A, D604AM UniflexL

Powder FM-HTFL-1250/1270 UniflexS GasStopHT,

Halad 413 Diacel, LWL Only for fresh water

Liquid UniflexL

Powder FM-HTFL-1270 UniflexS Use up to 10% salt

by weight Liquid UniflexL

Powder FM-HTFL-1270 FL-52, FL-25 UniflexS FLC-7

Halad-14, GasStop HT,

Halad 413 D-24 Use up to 18% salt

by weight Liquid UniflexL FLC-107 Halad-14LXP,

Halad 600LE LD-24

Powder FL-32, FL-33, FL-63 UniflexS GasStop HT,

Halad 413

General application

Effective up to 300 °F

Use over 18% salt by weight Liquid FL-32L, FL-33L,

FL-63L UniflexL

FLUID-LOSS CONTROL ADDITIVES (CONT. 2)

Appication Circulating temperature range

Compatibility with salt (NaCl):

Salt concentration and temperature

limitations

Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder FM-HTFL-1250

UniflexS FLC-7 GastStop HT, Halad 413

Only for fresh water

Liquid UniflexL FLC-107

Powder FM-HTFL-1270 UniflexS GasStop HT,

Halad 413 Up to 10% salt by weight

Liquid UniflexL

Powder FM-HTFL-1270

UniflexS GasStop HT, Halad 413

D-28 Up to 18% salt by

weight Liquid FM-HTFL-

1270 D73,

D73.1,D158, UniflexL

LD-28

Powder FM-HTFL-

1270, Diacel LWL

FL-33, FL-63, FL-32

D8, Diacel LWL,D143,

UniflexS

Halad 413, 100A, Diacel

LWL, Gas Stop HT

Diacel LWL

General application

Efective over 300 °F

Over 18% salt by weight

Liquid FL-33L,FL63L FL-32L

D158, UniflexL

Halad-413L, 361A, 600LE

General and special application Latex: Styrene/ butadiene copolymer

From 100 °F to 400 ° F depending upon product and stabilizers

Recommended for fresh water. May be used up to 18% salt

by weight

Liquid LAC-1 BA-86L D600, D134, UniflexL

Latex-1 Latex 2000

Powder UniflexS LAP-1, Halad 447

General and special application Latex: Acrilic

Up to 200/250 °F

Recommended for fresh water

Liquid UniflexL LA-2

Powder FL-52 D112,D156 UniflexS

FLC-4, FLC-7, FLC-8

D23, D24 NFL-2

Fluid loss control in highly extended or low density slurries

Variable limits Variable limits

Liquid BL Blue D159,D300 UniflexL

FLC-100 LD-24

Powder UniflexS

Fluid loss control in blast furnace slag slurries (containing no Portland cement)

Variable limits Variable limits

Liquid UniflexL

FLUID-LOSS CONTROL ADDITIVES (CONT. 3)

Appication Circulating temperature range

Compatibility with salt (NaCl):

Salt concentration and temperature

limitations

Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Stabilizer for latex in the presence of salt or at high temperature

Liquid LS-1, LS-2 D135, UniflexL Stabilizer 434B,

Stabilizer 434C

Stabilizer for latex in low density slurries

Liquid CD-32, CD-33 D138, UniflexL Stabilizer 434B,

Stabilizer 434C

Fluid loss aid Up to 200 °F Powder D136, UniflexS FLC-2

Fluid loss aid Over 200 °F Powder D121, UniflexS FLC-2

SILICA TO REDUCE OR PREVENT HIGH TEMPERATURE STRENGTH RETROGRESSION Material Product type Product

form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Sand

Crystalline silica approximately 100 mesh. SG 2.65 nominal

Granular solid FM-SR-1150 S-8C D30 SFA-100 SSA-2 L-10 SF-100

Silica flour

Cristalline silica approximately 200 mesh or finer SG 2.65 nominal

Fine Powder FM-SR-1100 S-8 D66 SFA-200 SSA-1 SFA-200,

SFA-325 SF-200, SF-225

Microfine silica: For use with microfine cements

Crystalline silica SG 2.65 nominal

Fine Powder

Available on request FS-1 Microsand

RETARDERS Appication

Circulating temperature range

Product type Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder FM-R-1400 R-3 D13 CR-1 HR-4, HR-7 R-6 SR-2 Low temperature Up 180 °F

Lignosulfonate, mofified lignosulfonate Liquid R-21L D81 CR-100 HR-4L, HR-7L R-6L

Powder R-3, R-11 D800 CR-2 HR-5 SR-6 Mid-range, moderate temperature

125 to 225 °F Lignosulfonate. Modified lignosulfonate blend Liquid FM-R-4 R-10L, R-12,

R-21L D801 CR-102 HR-6L R-40L SR6-1

Powder FM-R-22 CR-5 Diacel LWL

Moderate to hight temperature

175 to 300 °F Organic acid or organic acid salt blend Liquid D110 CR-105

Powder Diacel LWL R-6 or Diacel LWL D8 CMHEC Diacel LWL Diacel

LWL SR-12 Moderate to hight temperature

175 to 300 °F

Diacel LWL (carboxymethyl hydroxyethyl cellulose) Liquid

Powder FM-R-1400 R-8 D28 CR-5 HR-12, HR-15 R-55 SR-10 Hight temperature Over 225 °F Modified

lignosulfonate blend Liquid R-8L D150 CR-105 HR-12L, HR-13L R-55L

Powder CR-5, CR-3 HR-20 R-57 Hight temperature Over 300 °F

Blend of lignosulfonate or modified lignosulfonate with borax or borate salt

Liquid

Retarder aid for lignosulfonates Borax/borate salt Powder Borax R-9 or sodium

borate D93 CR-3 Component R R-35

Retarder aid for lignosulfonates Non-borax/norate

salt Powder D121 HR-25

Powder SR-30 SCR-100 Synthetic retarder Up to 250 °F

Proprietary, synthesized polymer or copolymer. Non- lignosulfonate

Liquid R-14L, R-15LS, R-20L SCR-100L

Powder SR-30 HR-25 Synthetic retarder Up to 425 °F

Liquid HR-25L

Powder SR-30 D161 SCR-100 Retarder for improved compressive strength in long cement columns

Helps early compressive strength where significant temperature differential exists

Liquid D110 SCR-100L

RETARDERS (CONT.)

Appication Circulating temperature range

Product type Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder Retarder for microfine cements

Liquid MMCR

Thixotropic cement retarder

For slurries containing calcium sulfate hemihydrate or gypsum

Powder R-18, SR-30 D74 CR-4

Powder R-7 FRC-2 Sodium citrate R-15 Permafrost cement retarder

Citric acid or citrate salt or similar, non-lignosulfonate Liquid

Powder D13 CR-1 HR-4 R-7 Permafrost Lignosulfonate

Liquid D81 CR-100 HR-4L

ANTI-GAS MIGRATION AGENTS General mechanism of action Product type Product

form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Fluid loss control only See: fluid loss control additives

Powder BA-56, BA-56HT, BA-100, FLAG-56 GasblockLT Polymeric blends:

(Non-Latex) Liquid BA-100L, FL-45LS LN, BJ Blue

Latex: Styrene/butadiede copolymer or similar

Liquid LAC-1 BA-86L D600, D134 Latex-1 Latex 2000

Powder BA-10 LAP-1, Halad-447

Latex: Acrylic Liquid BA-10L LA-2

Powder Fumed silica BA-58, CSE, BA-90 D154 FS-1

Silicalite, compacted

silicalite

Microsil10P Microsil 22P

Fumed silica

Liquid On request BA-58L D155 FS-101 Liquid

silicalite, Microblock

Microsil 15L

Powder

Matrix flow restriction/blocking

Fumed silica/polymer blends Liquid Calcium sulfate hemihydrate or gypsum

Powder Gypsum A-10 or gypsum D53 Ultracal 60 Cal-seal, EA-2 Gyp-cem

Powder Cross-linked or complexed polymeric materials Liquid Thix Set 31

Powder On request BA-46 Telmaster, Thixmaster, FastMaser2

Thix-Set A, VersaSet

Thix-Mix, Thix-O-Gel,

Thermal Thix-Mix

Gel strength modification: Thixotropic additives/slurries

Other

Liquid BA-46L Versaset L, VersaSet

LXP

Powder D65A GasStop, GasStop HT Gel-strength

modification: Delayed gelling

Proprietary polymeric additives

Liquid D604AM GasStop L, GasStop

LXP

ANTI-GAS MIGRATION AGENTS (CONT.) General mechanism of action Product type Product

form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Powder On request BA-29, BA-61 CPC-1 Super CBL SPC-12000 Alteration of cement slurry compressibility: Gas-generating agents

Aluminum powder or similar Liquid

Gas-check, Inhibited Gas-

Check

Alteration of cement slurry compressibility: Foamed cement

Foamed cement Foamed cement Foamed

cement Foamed cement

Foamed cement

Foamed cement

Supplemental agents for gas migration control

Stabilizer for Latex in the presence of salt or at high temperature

LS-1, LS-2 D135 Stabilizer 434B, Stabilizer 434C

Supplemental agents for gas migration control

Stabilizer for Latex in low-density slurries CD-32, CD-33 D138 Stabilizer 434B,

Stabilizer 434C CF-1

ANTI-FOAM AND DEFOAMING AGENTS General mechanism of action Product type Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Dry-powders, granules,

beads, etc. FM-AF-P FP-11 D46 DEF-3 D-Air 1 Prevent or decrease

foaming during mixing

High molecular weight alcohols, polyalcohols, silicones, etc. Liquid FM-AF-L

FP-6L, FP-9L, FP-12L, FP-10L,

AFA-3

D47, M45, D144

DEF-1, DEF-5

D-Air 2, D-Air 3, NF-3, NF-4, NF-6,

NF-7

AFA-2, AFA-3

DENSITY INCREASING OR WEIGHTING AGENTS

Material Product type Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Sand

Cirstalline silica approximately 40-70, 20-40 mesh or similar coarse material SG 2.65 nominal

Granular solid Sand Sand Sand Sand Sand Sand

Sand

Crystalline silica approximately 100 mesh SG 2.65 nominal

Granular solid FM-SR-1150 S-8C D30 SFA-100 SSA-2 L-10

Silica flour

Crystalline silica approximately 200 mesh or finer SG 2.65 nominal

Fine powder FM-SR-1100 S-8 D66 SFA-200 SSA-1 SFA-200,

SFA-325

Microfine silica: For use with microfine cements

Crystalline silica SG 2.65 nominal

Fine powder Microsand

Ilmenite Iron Titanium oxide SG 4.4 – 4.5 nominal Powder Ilmenite Ilmenite Ilmenite Ilmenite

Hematite Iron oxide SG 5 – 5.2 nominal Powder Hematite Hematite D76 Hematite Hi-Dense 3,

Hi-Dense 4 Hematite

Barite Barium sulfate SG 4.2 nominal

Fine powder Barite Barite D31 Barite Barite Barite

Manganese oxides SG 4.6 – 4.9 nominal Fine powder W-10 D157 Micromax

Microfine weighting agents for use with microfine cements

SG 4.9 Fine powder D157 Micromax

Calcium carbonate for use in spacers SG 2.75 Granular

solid D151

ADDITIVES AND MIXTURES TO REDUCE OR PREVENT LOST CIRCULATION

Material Description Product form

American Fracmaster

Ltd BJ Services Dowell Fracmaster Halliburton Nowsco

Canada San

Antonio

Cements SEE: Basic cements Slurries

Thixotropic cement slurries: Aqueous

Slurries Available custom blend

Sure Fill, Sure Plug, Thixofill, Thixofume,

Gypsum cement, BJ Thixo

RFC Thixmaster, Telmaster, Plugmaster

Thix-Set, Thix-Set 31,

Thixlite 373, Cal-Seal cement, VersaSet

Thix-Mix, Thix-O-Gel,

Thermal Thix-Mix, Rapid Gel

SPC, Rapid Set

Foamed cement Slurries Foamed cement

Foamed cement Foamed cement

Foamed cement

Foamed cement

Foamed cement

Non-aqueous slurries

Diesel oil cements, diesel oil bentonite cements, gunk squeeze, etc. Made with regular grind cements

Slurries Diesel cement

Diesel oil cement, Visqueeze Mark II, Diesel oil/bentonite,

Zone check

Polymer Plug, SOS

Diesel cement systems

BDO, BDOC, DOC, Flex-

plug

Diesel Gel, Diesel cement

Non-aqueous cement slurries

Made with microfine cements

Slurries MOC-1

Reactive washes, polymer solutions

Sodium silicate solutions, complexed sodium silicate solutions, polymer solutions

Liquid mixtures Custom Flush

Flo-guard L, Stop Block, SAF Mark III,

Siljel V

Zonelock, Permablock

Gel Seal, Masterflush, Mastersweep

Superflush Thixseal

Sand Graded and sized to meet needs

Granular Sand Sand Sand Sand Sand Sand

Mica Flake/ Powder Mica Mica Mica Mica Mica

Cellophane flake Flake Celloflake Celloflake D29 Celloflake Flocele Celloflake

Gilsonite Granular Gilsonite Gilsonite D24 Gilsonite Gilsonite Gilsonite

Ground coal Granular Kol seal D42 Kollite NLC-1

Walnut plugs Tuf plug or equivalent Granular On request Nut plug Tuf Plug

Perlite Beads On request Perlite D72 Perlite Perlite Fibers: Nylon, Polypropinele, cellulose, etc.

Fibrous/ poeder

On request LCM-2 Tuf additive No. 2

Wood chips Granular/ Flake

On request Wood chips Wood chips Wood chips Wood chips

Polyester, rubber, Granular Flex Seal, Hi-Seal,

Mud save F, Mud save M

D130 On request Granulite TR 1/4

Kwik seal Granular Kwik Seal

Proprietary Acid soluble, expanding bridging agenbt Flakes Cuttings K Perfect seal

SPACERS AND CHEMICAL WASHES/PREFLUSHES

Spacer or wash type Description American

Fracmaster Ltd

BJ Services Dowell Fracmaster Halliburton Nowsco Canada

San Antonio

Reactive – containing sodium silicate or similar reactive materials

Chekmaster Flowcheck, Flo Guard

Zonelock, Zonelock SC Gel Seal Super flush Thix-Seal

Flush

Aqueous – containing surfactants and solvents. No fluid loss control

Chemwash-1 Mud clean, MRS-2

CW-7, CW-8, CW-8ES

Masterflush W Mud Flush Nowflush 6,

Nowflush 7

Aqueous – containing surfactants and solvents. Contains agents to reduce fluid loss to formations

Mud sweep, Ultraflush II

CW-100, CW-101 Alpha

Preflush

Chemical washes (Not weighted with solid weighting agents)

Non-aqueous – blend or surfactants, solvents, etc in hydrocarbon carrier fluid

Masterflush O

N-Ver-Sperse O

Chemical washes recommended for wells drilled with OBM

Chemwash D CW-8,

CW-8ES, CW-101

Masterflush O

N-Ver-Sperse O, Alpha Preflush

Nowflush 6, Nowflush 7

Chemical washes design for mixability at sub-zero temperatures

Aqueous formulations containing a freeze point depressant

Formulated for turbulent flow at low pump rates FOMS-300

MCS-2, MCS-3 MCS-4, MCS-5

Ultraflush II, Turbo Flo 3

Mudpush XT Mudpush XTO Mudpush XS

Mudpush XSO

Dual Spacer, SD Spacer, Spacer 500

Nowsweep W

Formulated for laminar flow Weighted mud

sweep Mudpush XL

Mudpush XLO Mastersweep

W Tuned Spacer Supersweep

Spacers – Aqueous, weighted

Flow regime not specified MudpushWHT Alpha spacer

Water continuous phase APS-1 Mudpush XEO

Oil continuous phase FOMS-100 OB-1, RSB SAM-4 Spacers – Emulsion, weighted

Solvent continuous phase Turbo-Solvent

Spacers – Recommended in wells drilled with OBM

FOMS-200 MCS-3, MCS-4

RSB, Turbo-Solvent

Mudpush XLO Mudpush XTO Mudpush XEO

Mastersweep O

Dual Spacer, Alpha spacer,

SAM-4, Tuned spacer

Nowflush 6, Nowflush 7

Spacers – Formulations compatible with high salt concentrations

Mudpush XS Dual spacer, Dual spacer

E

Spacers – Fluids containing blast furnace slag for use with Slag-Mix and slag cement

OMR-2

SPECIALTY CEMENT BLENDS

General formulation Specific formulation American

Fracmaster Ltd

BJ Services Dowell Fracmaster Halliburton Nowsco Canada

San Antonio

Blends of Portland cement with commercial lightweight cements such us TXI Lightweight

(1) Thriftmaster, Thriftmaster

LT Tru-Lite R,

Tru-Lite HS

Ratio of flyash: cement at 15:85 with bentonite up to 8%

15:85:8 FAC (2) (Flyash cement) (1) Nowlite 2

Ratio of flyash: cement at 35:65 with bentonite up to 6%

AFL-Lite FAC (2) (1) Halliburton Light cement Nowlite 1

Ratio of flyash: cement at 50:50 with bentonite up to 4%

50:50:4 FAC (2) (1) Fillmaster Halliburton Pozment A Nowlite 3

Blends of Portland cement, Flyash and Gel (Bentonite)

Other ratios FAC (2), Econofill (1)

Blends of cement. Flyash and silica fume On request WMC-1,

WMC-1B

Blends containing cement, silica fume and pozzolan microspheres

FM-Lite HILITE My-T-Lite 1200 Nowlite 1200

Blends of containing lightweight pozzolan microspheres

On request Cenolite LITEFILL Litemaster, Litemaster 2

SpheraLite Cement

Blends containing lightweight glass beads Lite Set

Blends of cement, flyash, lime and silica for high temperature applications

On request

HTLD (High temperature Low Density

Cement)

Low density cement blend with superior compressive strength (10.5 to 12.5 ppg)

Proprietary blend LiteCRETE On request

High density cement blend with superior mixing and rheological properties (17.5 to 24 ppg)

Proprietary blend LW-6/MPA-1, Portland Blend LiteCRETE On request

Expanding cements containing calcium sulfate hemihydrate or similar

Self Stress Cement Bondmaster On request Expand-O-Mix

SPECIALTY CEMENT BLENDS (CONT. 1)

General formulation Specific formulation American

Fracmaster Ltd

BJ Services Dowell Fracmaster Halliburton Nowsco Canada

San Antonio

Expanding cements containing metal oxide expanding agents

Expanding cement containing gas generating agents

Rapid Gel SPC

Containing calcium sulfate hemihydrate or gypsum

Sure Fill RFC

(Regulated fill-up cement

Thixmaster On request Thix-Mix

Crosslinked polymer complexes Thix-Set 31

Thixotropic cements

Proprietary additives Thixofil Versaset BVC-30

Permafrost cement Cold Set Arcticset cement Permafrost

cement Polarset Cement

Cements to improve bonding

Containing polymeric additives such us latex, polyvinyl alcohol, etc.

Wellbond Service Telmaster Latex

Cement

Salt containing or salt saturated cements

Salt Saturated Cement

Cements to improve bonding to salt formations Proprietary additives to

improve bonding to salt formations

Saltbond cement On request

Carbon dioxide resistant cements CO2 resistant

cement Flexcem, Thermalock

Acid resistant cement Portland cements with additives to reduce acid solubility

Flexcem, Epseal

Synthetic resin cement Epoxy resin cement Synthetic cement Epseal,

Atratalock

Acid soluble cement Non-Portland inorganic cement completely soluble in acid

Magne Plus Acid soluble cement On request Acid soluble

cement

Storable liquid cement Water-based liquid cement slurry Liquid Stone

SPECIALTY CEMENT BLENDS (CONT. 2)

General formulation Specific formulation American

Fracmaster Ltd

BJ Services Dowell Fracmaster Halliburton Nowsco Canada

San Antonio

Fiber cement

Cement containing fibers to increase resistance to mechanical shock and tensile stress

Fiber cement On request On request On request

Deepwater cement

Blend for cold temperature of deep water drilling where shallow water flow zones are a problem

Deep Set RAS Flow Stop I, Flow Stop

4000

(1) No compositional name used. Blends are referred to by their actual composition (35:65:6, 50:50:2, etc). (2) Flyash cement or FAC is used to describe all blends of flyash and cement. The ratio is specific for the appication.


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