CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Certificate of TestProject: CellSafe Lithium Battery Recall Kit Date: March 15, 2019 Document No.: CBRPT013 Project Manager: Dylan Vandemark Date of Testing: March 15, 2019
Description: Lithium-Ion Thermal Runaway Containment Study Within Fiberboard Boxes Details: TEST 13: 15” x 8” x 4” Folded Mailer with closure tape, B-flute with 2.0lbs of CellBlockEX within
heat sensitive textile pillow lined with fire resistant textile.
Purpose: This test was conducted to demonstrate and document the capability of CellBlockEX® to contain a thermal event involving lithium ion cells and batteries (UN 3480) within a fiberboard box.
Test Sample TENERGY 18650 9.6 Wh, 15 count @ 100% SOC (144 total Wh), installed in 1x15 tight Identification: arrangement inside of box between CellBlock® extinguishing pillows. These cells are the same as
used by the FAA William J. Hughes Technical Center and represent one of the most volatile cells commercially available.
Test Equipment: FireRod heater cartridge, 110 DC Power Supply, Type-K Thermocouples
Procedure: Single cell ignition by heating at a rate of 2°C/sec to vent and thermal runaway or 200°C. Record temperature every 1 second on the ignition cell, adjecent cell, middle cell, aft cell, box top, box bottom, and box left; record photographs and video.
The results and any data provided by CellBlock in any format (“Data”) apply only to the sample(s) tested and shall not be considered indicative of the qualities of apparently identical or similar samples. This certificate does not indicate successful or unsuccessful completion of a test or qualification program. CellBlock disclaims all warranties, express or implied, and liability for the performance of the tested sample(s) and use of any Data.
CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Project: CellSafe Lithium Battery Recall Kit Date: March 15, 2019 Document No.: CBRPT013 Project Manager: Dylan Vandemark Date of Testing: March 15, 2019
Results: An initiation cell was heated until it experienced rapid disassembly (thermal event). The initiation cell exposed adjacent cells to heat, fire and ejected contents. The cells were assembled in close proximity to each other, but the CellBlockEX material was effective in preventing propagation of all remaining test cells (cells 2 through 15). The heat generated from the initiated thermal event melted the heat sensitive textile material as intended, dispersing CellBlockEX loose-fill. While initially there was significant smoke that exited the seams of the box, once the CellBlockEX material was released it absorbed significant quantities of the smoke as can be viewed in the video recordings. The test was performed with a quantity of CellBlockEX consistent with a ratio of 1.98 cubic inches per Watt hour (Wh) of cells, which is below the recommended quantity of 3-5 cubic inches per Wh (in/Wh) of CellBlockEX. The maximum internal temperature recorded was 722.18°C. The maxiumum adjacent cell temperature recorded was 120.33°C. The maximum external temperature recorded was 26.62°C on the box bottom. The result was positive in that:
• There was no hazardous flame or hazardous fragments that exited the package. • No outer package charring was observed. • The thermal runaway was suppressed and fully contained • The CellBlockEX absorbed the gas from the thermal event • Propagation was prevented. • No damage or leaking electrolyte was observed from adjacent cells.
Prepared by: ________________________________ Reviewed by: _________________________________ Sarah Grasso Dylan Vandemark Assistant VP of Product Development
List of Attachments: Attachment 1: Test Photos Attachment 2: Thermocouple Data
The results and any data provided by CellBlock in any format (“Data”) apply only to the sample(s) tested and shall not be considered indicative of the qualities of apparently identical or similar samples. This certificate does not indicate successful or unsuccessful completion of a test or qualification program. CellBlock disclaims all warranties, express or implied, and liability for the performance of the tested sample(s) and use of any Data.
CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Certificate of Test – Attachments Page 3 March 15, 2019
Ignition cell assembly pre test
Inside view with battery assembly and thermocouples pre test
Inside view with pillow enclosing batteries pre test
Outside/top view of box pre test
Inside package view pre test
Outside/bottom view of box pre test
CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Certificate of Test – Attachments Page 4 March 15, 2019
Top/front view post test Bottom/front view post test
Top/left view post testTop/right view post test
Top/left view pre testTop/right view pre test
CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Certificate of Test – Attachments Page 5 March 15, 2019
Open/pillow folded over view post test
Open closeup view post test
Open view post test
Unpropagated batteries post test - undamaged; no leaking electrolyte observed
Inside view with batteries removed post test Inside/emptied view post test
CellBlock FCS, LLC 234 Northeast Road, Standish, Maine 04084
800-440-4119 CELLBLOCKFCS.COM
Certificate of Test – Thermocouple Data Page 6 March 15, 2019
3597 146.38 95.86 22.46 18.52 18.5 15.28 17.783598 146.31 95.83 22.46 18.52 18.46 15.27 17.783599 146.25 95.82 22.46 18.52 18.45 15.27 17.773600 146.22 95.8 22.46 18.52 18.44 15.26 17.78
max ignition cell722.18max adjacent 120.33max outside temp26.62
0
100
200
300
400
500
600
700
8001
111
221
331
441
551
661
771
881
991
1101
1211
1321
1431
1541
1651
1761
1871
1981
2091
2201
2311
2421
2531
2641
2751
2861
2971
3081
3191
3301
3411
3521
Time (seconds)
Ignition Cell Adjacent Cell Center Cell Aft Cell
Box Top Box Left Box Bottom
3597 146.38 95.86 22.46 18.52 18.5 15.28 17.783598 146.31 95.83 22.46 18.52 18.46 15.27 17.783599 146.25 95.82 22.46 18.52 18.45 15.27 17.773600 146.22 95.8 22.46 18.52 18.44 15.26 17.78
max ignition cell722.18max adjacent 120.33max outside temp26.62
0
100
200
300
400
500
600
700
8001
111
221
331
441
551
661
771
881
991
1101
1211
1321
1431
1541
1651
1761
1871
1981
2091
2201
2311
2421
2531
2641
2751
2861
2971
3081
3191
3301
3411
3521
Time (seconds)
Ignition Cell Adjacent Cell Center Cell Aft Cell
Box Top Box Left Box Bottom
Thermocouple dataMaxiumum internal temperature reached 722.18°C at ignition cell. Maximum adjacent cell temperature reached 120.33°C.Maximum exterior temperature reached 26.62°C on box bottom.
722.18°C
120.33°C
26.62°C
Tem
pera
ture
(c)
TEST CBRPT013