Certify Sulfur and Monitor Critical Elements at Sub-ppm LevelsASTM D2622, D7039, D7536, D4929 SH / T...

Certify Sulfur and Monitor Critical Elements at Sub-ppm Levels

Benchtop, Process and Portable Analysis Solutions

better analysis counts

Petroleum Systems Services Corporation Page 1 of 16

518-581-0189

X-IDSample Cup

The Petra series delivers high-precision D4294 sulfur analysis across a broad measurement range. Petra MAX™ delivers D4294 sulfur analysis in addition to 12 elements from P to Zn, for rapid monitoring of critical elements like Ca, Fe, K, Ni, and V at sub-ppm levels.

Petra is powered by High Definition X-ray Fluorescence (HDXRF®) technology: an elemental analysis technique offering significantly enhanced detection performance over traditional XRF technology.

Sulfur Measurement Advanced

Technical Specifications

Petra MAX

Dynamic Range Sulfur 5.7 ppm – 10 wt%

Limit of Detection (ppm @ 600 s)

Sulfur 5.7 ppm

Applications Hydrocarbons, water and catalysts

Petra 4294Dynamic Range Sulfur 2.6 ppm – 10 wt%

Limit of Detection (ppm @ 600 s) Sulfur 2.6 ppmApplications Hydrocarbons

P Cl K Ca V Cr17 3 0.7 0.4 0.1 0.09

Mn Fe Co Ni Cu Zn0.07 0.07 0.07 0.04 0.1 0.1

Petra Series Autosampler boasts a novel design with advanced software features for a more flexible and efficient workflow. Using unique identifier (X-ID) sample cups and an open-ended sample slide, the autosampler offers sample tracking and continuous sample loading. It is an optional add-on feature for a Petra 4294 or Petra MAX analyzer. QR/barcode scanner included with purchase.

Advanced Workflow

ASTM D4294ISO 8754 | IP 336


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Features and Benefits• Powered by MWDXRF• LOD:

- Sulfur: 0.4 ppm at 300 s - Chlorine: 0.3 ppm at 300 s

• Dynamic Range: - Sulfur: 0.4 ppm to 5 wt% - Chlorine: 0.3 ppm to 3000 ppm

• Extremely low maintenance: no conversion gasses, heating elements, columns, or quartz tubing

Options• LIMS data output compatible software

Features and Benefits• Powered by MWDXRF• LOD:

- Sulfur: 0.7 ppm at 300 s - Lead: 0.002 g/L at 300 s

• Dynamic Range: - Sulfur: 0.7 ppm to 5000 ppm - Lead: 0.002 g/L to 10.000 g/L


Sindie® +Cl is a two-in-one instrument enabling trace analysis of both sulfur and chlorine with one push of a button. It is the ideal solution to certify sulfur levels in finished products and assess chlorine for corrosion mitigation.

As aviation industry requirements become more stringent, lead detection is critical in such products as aviation gasoline and jet fuel. Sindie® +Pb delivers unprecedented precision and accuracy for sulfur and lead detection.

TWO critical measurements, ONE push of a button, ZERO hassle

Sulfur PLUS Lead Analysis in Petroleum Products

ASTM D2622, D7039, D7536, D4929 SH / T 0842

ASTM D7039 and ISO 20884


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ASTM D2622 & D7039ISO 20884

Features and Benefits• Powered by MWDXRF• Easy to use

- Intuitive touch screen - Just plug-in and measure - Measurement time: 30-900 s

• Low and high range calibrations available: - Low Range: LOD - 3000 ppm - High Range: 0.3 wt% - 10 wt%


• 75 W air-cooled excitation tube

Options• 8-cell Autosampler• Helium optical path available• LIMS data output compatible software

The Sindie® 2622 series complies with ASTM D2622, D7039 and ISO 20884 methods, enabling complete flexibility in sulfur analysis. With no compromises in detection, performance and reliability, Sindie 2622 is the ideal sulfur analytical solution from ultra low sulfur diesel and gasoline to heavy fuel oil and crudes.

Sulfur Analysis with Compliance Flexibility


Sindie 2622 Gen 2Dynamic Range 0.4 ppm to 10 wt%

Limit of Detection (LOD) 0.4 ppm at 300 s

Sample Cup Traditional XRF

Sindie 2622 Gen 3Dynamic Range 0.15 ppm to 10 wt%

Limit of Detection (LOD) 0.15 ppm at 300 s

Sample Cup Accucell

AUTOSAMPLER • 8 sample cell capacity• Increases productivity• Utilizes XOS Accucell

sample cups


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Features and Benefits • Powered by MWDXRF• Easy to use



• 75 W air-cooled excitation tube

Options • Extended Range (XR): 0.3 wt% - 10 wt%• LIMS data output compatible software

From ultra low sulfur diesel and gasoline, to heavy fuel oil and crudes, the Sindie® 7039 series delivers unprecedented precision and accuracy. Sindie 7039 is the ideal analytical solution for the refining industry where detection, performance and reliability are critical.

Monochromatic Wavelength Dispersive X-ray Fluorescence (MWDXRF) utilizes state-of-the-art focusing and monochromating optics to increase excitation intensity and dramatically improve signal-to-background ratio compared to traditional WDXRF instruments. This enables significantly improved detection limits, precision, and a reduced sensitivity to matrix effects. A monochromatic and focused primary beam excites the sample and secondary characteristic fluorescence X-rays are emitted from the sample. A second monochromating optic selects the sulfur characteristic X-rays and directs these X-rays to the detector.

Sulfur Analysis in Liquid Hydrocarbons

Advanced Analysis with MWDXRF


Sindie 7039 Gen 2

Dynamic Range 0.4 ppm to 3000 ppm

Limit of Detection 0.4 ppm at 300 s

Sample Cup Traditional XRF

Sindie 7039 Gen 3

Dynamic Range 0.15 ppm to 3000 ppm

Limit of Detection 0.15 ppm at 300 s

Sample Cup Accucell

Options 8-cell Autosampler



518-581-0189

15 Tech Valley Drive East Greenbush, New York 12061 USAPH 518.880.1500 FAX 518.880.1510 [email protected] www.xos.com

©XOS all rights reserved. Petra MAX, Petra 4294, Sindie, HDXRF and MWDXRF are trademarks of XOS.

Sindie® OTG is a portable sulfur analyzer, delivering reliable and precise results in hydrocarbons from ULSD and gasoline to marine fuels and crudes. Operate in-the-field, on-board marine environments, and in laboratories.

Sindie® Online is an industrial grade process sulfur analyzer with breakthrough detection capability to monitor ultra low sulfur in petroleum or aqueous process streams. This process analyzer presents the ultimate solution for refineries and pipeline terminals where measurement speed and reliability are essential.

Portable Sulfur Analysis

Effective Online Sulfur Analysis in Petroleum Process Streams

Features and Benefits • Powered by MWDXRF• LOD: 0.7 ppm at 900 s• Dynamic Range: 0.7 ppm - 10 wt%• Use Accucells for hassle-free sample prep• Fits on any bench and compatible for use in mobile labs/vans

- Dimensions: 34cm (w) x 23.5cm (d) x 30cm (h) - Weight: 18.5 kg - Utility: Standard wall power: 100-240 VAC at 2.2 A

Features and Benefits • Powered by MWDXRF• Uses ASTM D7039 technology• ATEX Zone 1 and NEC Cl | Div 2 Certified• LOD: 0.5 ppmw in hydrocarbon matrices @ 300 s• LOD: 1.5 ppmw in aqueous streams @ 300 s• Dynamic Range: 0.5 ppmw – 3000 ppmw

Options • Multi-stream analysis capability• Extended Range (XR) available for measurements

above 3000 ppmw up to weight percent levels


SindieONLINE

ATEX and NEC Certified


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Monitor Chlorine in Crude at Sub-ppm Levels

Benchtop and Online Analysis Solutions



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ASTM D7536 and D4929

Applications• Total chlorine analysis from aqueous solutions

and aromatic products to heavy fuels, crudes, and catalyst

• For refineries, petrochemical and additive plants, pipeline terminals, and test laboratories

Features and Benefits• LOD: 0.13 ppm for hydrocarbons• LOD: 0.3 ppm for aqueous samples• Dynamic Range: 0.13 ppm to 3000 ppm• Fits on any lab bench• Easy to use



Options• LIMS data output compatible software• Extended Range (XR): 0.13 ppm to 4 wt%• Catalyst testing capability• Accu-flow*• 8-cell Autosampler* • Accucell Sample Basket Available

*Accu-flow and Autosampler options cannot be combined.

Clora® is a compact analyzer to measure total chlorine in liquid hydrocarbons such as aromatics, distillates, heavy fuels, crude oils, and aqueous solutions. Clora delivers unprecedented accuracy and precision for petroleum and petrochemical applications where ease-of-use, reliability and measurement speed are critical.

Total Chlorine Analysis in Liquid Hydrocarbons

Get Accu-flow to Eliminate Particle SettlingThe optional Accu-flow design allows the sample to flow continuously during the measurement. This continuous flow eliminates the settling of chlorine, producing accurate and precise total chlorine results.


518-581-0189

ASTM D7536 and D4929

Applications• Total chlorine analysis from aqueous solutions and

aromatic products to heavy fuels and crudes• For refineries, petrochemical and additive plants,

pipeline terminals and test laboratories

Features and Benefits• LOD: 0.07 ppm in 600 s • Dynamic Range: 0.07 ppm - 2 wt%• Automatic sulfur correction• Fits on any lab bench• Easy to use


• Extremely low maintenance: no conversion gasses, heating elements, columns, acids, or quartz tubing

• Replaceable air-cooled X-ray tube


Clora® 2XP is designed for use with liquid hydrocarbons such as aromatics, distillates, heavy fuels and crude oils, as well as aqueous solutions. The enhanced precision of Clora 2XP is ideal for testing related to catalyst poisoning in reformers or for sites with fluid catalytic crackers and hydrocrackers monitoring very low levels of chlorine.

Twice the Precision, Twice the Performance

Automatic Sulfur CorrectionMany heavy samples, like crude oil, VGO or coker residual, may have percent-level sulfur present while chlorine may be as low as a few parts per million. High sulfur levels will typically depress the chlorine measurement result during XRF analysis. Clora 2XP is able to measure the chlorine and sulfur concentrations simultaneously, and the sulfur counts information is then used to automatically correct the chlorine measurement.


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ASTM D2622, D7039, D7536, D4929,

SH / T 0842

Applications• Total sulfur analysis from ultra low sulfur fuels to

crudes• Total chlorine analysis from aqueous solutions

and aromatic products to heavy fuels, crudes, andcatalyst

• For use in refinery labs, pipeline terminals, additiveplants and inspection laboratories

Features and Benefits• Sulfur

- LOD: 0.4 ppm at 300 s- Dynamic Range: 0.4 ppm to 5 wt%

• Chlorine- LOD: 0.3 ppm at 300 s- Dynamic Range: 0.3 ppm to 3000 ppm

• Extremely low maintenance: no conversion gasses,heating elements, columns, or quartz tubing

• Automatic sulfur correction for chlorine• Easy to use

- Intuitive touch screen- Just plug-in and measure- Measurement time: 30-900 s

• Fits on any lab bench


Sindie +Cl® is a two-in-one instrument enabling trace analysis of both sulfur and chlorine with one push of a button. It is the ideal solution to certify sulfur levels in finished products, assess chlorine for corrosion mitigation, and optimize process parameters.

TWO critical measurements, ONE push of a button, ZERO hassle

Two Critical MeasurementsSindie +Cl performs trace analysis of both sulfur and chlorine with one push of a button. You can measure both elements in one sample, or measure each separately by simply inserting a new sample.


518-581-0189

Applications • Upstream desalting, refining, power generation

and effluent management• Total chlorine analysis in:

- raw and desalted crudes - water and effluent streams - refinery process streams - finished product

Features • Uses ASTM D7536 technology• ATEX Zone 1 and NEC Cl | Div 2 Certified• LOD: 0.2 ppmw in hydrocarbon matrices @ 300 s• LOD: 0.6 ppmw in aqueous streams @ 300 s• Dynamic range: 0.2 ppmw – 3000 ppmw• Calibration is linear up to 3000 ppmw and one

calibration curve runs all hydrocarbon matrices• Robust industrial design: wall mounted or stand

alone

Benefits • Continuous, real-time analysis• Rapid response to upsets• Easy to use with intuitive touch screen interface• Direct measurement in ppm wt• Low Maintenance: no consumable liquids, gasses,

combustion, or sample conversion• Not sensitive to sample temperature changes

Options • Multi-stream analysis capability• Auto-validation capability

ATEX and NEC Certified

Chlorine contributes significantly to the corrosion of plant equipment and must be treated accordingly. With ever-changing crude quality and potential for process upsets, chlorine levels can shift quickly, making real-time analytical results invaluable. Powered by MWDXRF®, Clora® Online uses ASTM D7536 technology and delivers real-time, continuous analysis of total chlorine from 0.2 ppmw up to 3000 ppmw. By monitoring desalted crude, a plant can optimize performance and immediately see impacts of crude changes (including organic chloride). This process analyzer is ATEX and NEC certified for hazardous area locations.

Online Chlorine Analysis in Liquid Hydrocarbon Process Streams

ONLINE


518-581-0189

15 Tech Valley Drive East Greenbush, New York 12061 USAPH 518.880.1500 FAX 518.880.1510 [email protected] www.xos.com

©XOS all rights reserved. Clora, Clora 2XP, Clora Online and Sindie +Cl are registered trademarks of XOS.

Monitoring chlorine for corrosion mitigation is critical during refining processes. Chlorine can poison expensive catalysts and lead to corrosion in overhead or reactor effluent systems. Clora® analyzers offer breakthrough analytical solutions for the determination of chlorine in liquid hydrocarbon samples such as aromatics, distillates and heavy fuels, and aqueous solutions.

Monochromatic Wavelength Dispersive X-ray Fluorescence (MWDXRF) utilizes state-of-the-art focusing and monochromating optics to increase excitation intensity and dramatically improve signal-to-background ratio compared to traditional WDXRF instruments. This enables significantly improved detection limits, precision, and a reduced sensitivity to matrix effects. A monochromatic and focused primary beam excites the sample and secondary characteristic fluorescence X-rays are emitted from the sample. A second monochromating optic selects the chlorine characteristic X-rays and directs these X-rays to the detector. MWDXRF is a direct measurement technique and does not require consumable gasses or sample conversion delivering robust and low-maintenance analyzers with dramatically lower detection limits and faster response times.

Accu-flow technology helps to minimize the effects of particulate settling, which is common when testing for chlorides in crude oil using XRF in the laboratory. Over a typical measurement cycle, the heavier particles can settle to the bottom of the sample cup and cause higher than normal results. Accu-flow pushes the sample through the system keeping the sample uniform, delivering a result that better reflects crude streams as they exist in the refinery. Accu-flow is available with Clora® benchtop analyzers.

Benchtop and Online Chlorine Analysis

Advanced Analysis with MWDXRF

Eliminate Particle Settling with Accu-flow

POLYCHROMATIC X-RAYS

FROM SOURCE

MONOCHROMATIC EXCITATION

X-RAYS FROM SAMPLE

DETECTOR

SELECTEDMONOCHROMATIC

SAMPLE X-RAYS

SAMPLE

OPTIC 1 OPTIC 2


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Applications• Total silicon analysis in hydrocarbons and

bio fuels• For use in refinery labs, pipeline terminals,

additive plants, and inspection laboratories

Features and Benefits• LOD: 0.65 ppm at 600 s• Dynamic Range: 0.65 ppm - 3000 ppm• Fits on any lab bench• Touch Screen user interface• User programmable measurement time:

30-900 s• No conversion gasses, heating elements,

quartz tubes or columns• 75 W air-cooled excitation tube


From gasoline to ethanol and toluene, Signal® delivers total silicon analysis. Powered by MWDXRF®, Signal is a robust analysis solution for demanding petroleum and industrial environments.

Silicon Analysis in Petroleum and Bio Fuels


ASTM D7757


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POLYCHROMATIC X-RAYS

FROM SOURCE

MONOCHROMATIC EXCITATION

X-RAYS FROM SAMPLE

DETECTOR

SELECTEDMONOCHROMATIC

SAMPLE X-RAYS

SAMPLE

OPTIC 1 OPTIC 2

Model SignalTest Method ASTM D7757Dimensions 37 cm (w) x 50 cm (d) x 34 cm (h)Power 100-120 VAC, 47-63 HZ at 6.0 Amps/

200-240 VAC, 47-63 HZ at 6.0 AmpsSample Cup Volume 10 mlAmbient Temperature 5-40° C (40-104° F) Requirements Dynamic Range 0.65 ppm - 3000 ppmMeasurement User selectable: 30-900 sCalibration 8 calibration curves. Automatic and

manual calibration functionality

Product Specifications

15 Tech Valley Drive, East Greenbush, New York 12061 USAPH 518.880.1500 FAX 518.880.1510 [email protected] xos.com

©XOS all rights reserved. Signal and MWDXRF are registered trademarks of XOS.

TRUSTED PRECISION Monochromatic Wavelength Dispersive X-ray Fluorescence (MWDXRF) utilizes state-of-the-art focusing and monochromating optics to increase excitation intensity and dramatically improve signal-to-background over high power traditional WDXRF instruments. This enables significantly improved detection limits and precision, and a reduced sensitivity to matrix effects. A monochromatic and focused primary beam excites the sample and secondary characteristic fluorescence X-rays are emitted from the sample. A second monochromating optic selects the silicon characteristic X-rays and directs these X-rays to the detector. MWDXRF is a direct measurement technique and does not require consumable gasses or sample conversion.

LOW RANGE CALIBRATION Signal uses a weighted least squares regression which is extremely linear and easy to set up. Typical correlation (R value) is expected to be on the order of 0.999 or better.

Low Range Calibration

Precision Typical repeatability (r) and reproducibility (R)

values in gasoline, at 95% confidence. 600 s measurement time.

Silicon Concentration (ppm) r R

2 0.4 0.7

5 0.5 0.8

8 0.6 1.0

15 0.8 1.4

100 2 4

500 5 10


518-581-0189

Applications• Total phosphorus analysis in hydrocarbons,

bio-fuels and aqueous matrices• For use in refinery, additive plants, oil recycle

facilities and test labs

Features and Benefits• LOD: 0.4 ppm at 600 s • Dynamic Range: 0.4 ppm to 3000 ppm• Automatic sulfur correction• Fits on any lab bench• Robust touch-screen user interface• User programmable measurement time: 30-900 s • Extremely low maintenance: no conversion gasses,

heating elements, columns, or quartz tubing• Low power air-cooled excitation X-ray tube

Options• LIMS data output compatible software• Accu-flow

From crude oil to bio-fuels, in additives or water, Phoebe® delivers unprecedented precision and accuracy for quantification of phosphorus. Phoebe delivers a LOD of 0.4 ppm in hydrocarbon matrices in a ten-minute measurement cycle.

Total Phosphorus Analysis in Hydrocarbon and Aqueous Matrices


xos.com


518-581-0189

POLYCHROMATICX-RAYS

FROM SOURCE

MONOCHROMATICEXCITATION

X-RAYSFROM SAMPLE

SULFURBEAM

PHOSPHORUSBEAM

SAMPLE

OPTIC 1 OPTICS 2 & 3

P S

DETECTOR

TRUSTED PRECISION Monochromatic Wavelength Dispersive X-ray Fluorescence (MWDXRF®) utilizes state-of-the-art focusing and monochromating optics to increase excitation intensity and dramatically improve signal-to-background over high power traditional WDXRF instruments. This enables significantly improved detection limits and precision and a reduced sensitivity to matrix effects. A monochromatic and focused primary beam excites the sample and secondary characteristic fluorescence X-rays are emitted from the sample. A second monochromating optic selects the phosphorus characteristic X-rays and directs these X-rays to the detector. The third optic is used for sulfur correction of the phosphorus measurement. MWDXRF is a direct measurement technique and does not require consumable gasses or sample conversion.

AUTOMATIC SULFUR CORRECTION Many heavy samples, like crude oil, VGO or coker residual, may have percent-level sulfur present while phosphorus may be as low as a few parts per million. High sulfur levels will typically increase the phosphorus measurement result during XRF analysis. Phoebe is able to measure the phosphorus and sulfur concentrations simultaneously, and the sulfur counts information is then used to automatically correct the phosphorus measurement.

ACCU-FLOW Accu-flow allows the sample to flow continuously during measurement. This continuous flow eliminates the settling or inhomogeneity effects of phosphorus, producing accurate and precise total chlorine results.

15 Tech Valley Drive, East Greenbush, New York 12061 USAPH 518.880.1500 FAX 518.880.1510 [email protected] xos.com

©XOS all rights reserved. Phoebe and MWDXRF are registered trademarks of XOS.

Model PhoebeDimensions 37 cm (w) x 50 cm (d) x 34 cm (h)Power 100-120 VAC, 47-63 HZ at 6.0 Amps Sample Cup Volume 10 mlAmbient Temperature Requirements 5-40° C (40-104° F) Dynamic Range 0.4 ppm - 3000 ppmMeasurement User selectable: 30-900 sCalibration 8 calibration curves. Automatic and manual calibration functionality

Product Specifications

Precision Typical repeatability (r) and reproducibility (R) values, at 95% confidence.

Measurement time: 600 s.

Phosphorus (ppm) in crude oil r R

2 0.8 1.2

5 1.0 1.6

10 1.4 2.0

15 1.7 2.5

20 1.9 2.8


518-581-0189

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Certify Sulfur and Monitor Critical Elements at Sub-ppm LevelsASTM D2622, D7039, D7536, D4929 SH / T...

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