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    Chapter 1 -

    Materials and equipment Design

    PETR 350DESCRIPTION

    This is a multidisciplinary course aimed at: study of the materials selection process for

    equipment used in gas and oil operations

    Corrosion mechanisms and inhibition methods

    Codes, standards and applicable specificationspresented along with their applications

    1

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    Chapter 1 -

    Learning Objectives

    Learners will: become familiar with metals used in equipment in

    the oil and gas sector

    understand the differences in properties between

    carbon steels, stainless steels, alloys andsuperalloys

    know and understand the primary corrosionmechanisms and the conditions under which theyoccur

    become familiar with codes , standards andspecifications as applied to oil and gas industryequipment

    2

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    Chapter 1 -

    recognize the criticality of material failures inequipment performance

    This course will provide the learner with thetechnical aspects of metallic and non-metallicmaterials and their properties.

    Material selection criteria and applicationsspecific to the oil and gas industry will becovered.

    The course will include equipment designconsiderations along with codes, standards and

    specifications utilized in the oil and gas industry.Corrosion mechanisms and mitigation techniqueswill be covered.

    3

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    Chapter 1 -

    Resource Material

    References: Specifications CSA for pipeline

    SpecificationsAPI for drill pipe, tubing andcasing

    Chemical Engineering Design and Analysis,Duncan, T. Michael

    Journal of Petroleum Technology

    Oil and Gas Journal

    Introduction to the Canadian Natural GasIndustry, Canadian Energy Research Institute

    Energy Research Institute

    4

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    Chapter 1 - 5

    LECTURES

    Lecturer: Ahmed Yusuf

    Time: Sunday 8.00 9.30 am8.00 9.30 am

    Location: B1 G02

    Activities: Present new material

    Announce reading and homework

    Take Final Exam*

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    Chapter 1 - 6

    Purpose:

    Discuss homework, quizzes, exams

    Hand back graded quizzes, exams

    Discuss concepts from lecture

    Instructor:

    Times and Places:Sun.

    Tue.

    10:00 - 12.00 noon

    10:00 - 12.00 noon

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    Chapter 1 - 7

    Purpose: To learn more about materials by relatinglecture material with observations. Also to learn to properlyformulate and write engineering reports and proposals.

    Instructor: Sondus

    Location: B4

    LABORATORY SECTIONS

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    Chapter 1 - 8

    TEACHING ASSISTANTS

    Teaching Assistants will

    participate in tutorial sessions,

    have office hours to help you with course material

    and problem sets.

    NameEng. Sondus

    Office_ XXX

    Tel.X-XXXX

    E-mail_____

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    Chapter 1 - 9

    Required text: Materials Science and Engineering: An Introduction

    W.D. Callister, Jr., 7th edition, John Wiley and Sons,Inc. (2007).

    COURSE MATERIALS

    Optional Material:

    Chemistry Books

    Physical Metallurgy Books

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    Chapter 1 - 10

    GRADING

    Assignments in-tutorial 10%

    Laboratory Reports 10%

    Based on core homework problems

    Midterm #1 30%

    Tentatively scheduled for:Material covered:

    Final 50%

    Tentatively scheduled for:Material covered:

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    Chapter 1 - 11

    READING SCHEDULE

    Week

    123456

    78

    910

    Topic

    General Intro; Atomic BondingCrystalline Structure; Imperfections

    Diffusion; Mechanical PropertiesStrengthening Mechanisms; Failure

    Phase DiagramsKinetics & Phase Transformations

    Processing & Applications of MetalsStruc., Prop., Proc., Applic. of CeramicsStruc., Prop. of Polymers; Composites

    Corrosion; Elec. & Thermal Prop.Magnetic & Optical Prop.

    Materials Selection; Econ. & Envir. Issues

    Chapter

    1,23,45,67,89

    1011

    12,1315,16

    17,18,19*20*,21*22*,23*

    Lectures: will highlight important portions of each chapter.*These chapters available at website www.wiley.com/college/callister.

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    Chapter 1 - 12

    Chapter 1 - Introduction

    What is materials science? Why should we know about it?

    Materials drive our society

    Stone Age Bronze Age

    Iron Age

    Now?

    Silicon Age? Polymer Age?

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    Chapter 1 - 13

    Example Hip Implant

    With age or certain illnesses joints deteriorate.

    Particularly those with large loads (such as hip).

    Adapted from Fig. 22.25, Callister 7e.

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    Chapter 1 - 14

    Example Hip Implant

    Requirements

    mechanical

    strength (manycycles)

    good lubricity

    biocompatibility

    Adapted from Fig. 22.24, Callister 7e.

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    Chapter 1 - 15

    Example Hip Implant

    Adapted from Fig. 22.26, Callister 7e.

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    Chapter 1 - 16

    Hip Implant

    Key problems to overcome

    fixation agent to holdacetabular cup

    cup lubrication material

    femoral stem fixing agent(glue)

    must avoid any debris in cup

    Adapted from chapter-opening photograph,Chapter 22, Callister 7e.

    FemoralStem

    Ball

    AcetabularCup and Liner

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    Chapter 1 - 17

    Example Develop New Types ofPolymers

    Commodity plastics large volume ca. $0.50 / lbEx. PolyethylenePolypropylenePolystyreneetc.

    Engineering Resins small volume > $1.00 / lbEx. Polycarbonate

    NylonPolysulfoneetc.

    Can polypropylene be upgraded to properties (and price) nearthose of engineering resins?

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    Chapter 1 - 18

    ex: hardness vs structure of steel Properties depend on structure

    Data obtained from Figs. 10.30(a)and 10.32 with 4 wt% C composition,and from Fig. 11.14 and associateddiscussion, Callister 7e.Micrographs adapted from (a) Fig.10.19; (b) Fig. 9.30;(c) Fig. 10.33;and (d) Fig. 10.21, Callister 7e.

    ex: structure vs cooling rate of steel Processing can change structure

    Structure, Processing, & Properties

    H

    ardness(BH

    N)

    Cooling Rate (C/s)

    100

    2 00

    3 00

    4 00

    5 00

    6 00

    0.01 0.1 1 10 100 1000

    (d)

    30mm(c)

    4mm

    (b)

    30mm

    (a)

    30mm

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    Chapter 1 - 19

    Types of Materials Metals:

    Strong, ductile high thermal & electrical conductivity

    opaque, reflective.

    Polymers/plastics: Covalent bonding sharing of es

    Soft, ductile, low strength, low density thermal & electrical insulators

    Optically translucent or transparent.

    Ceramics: ionic bonding (refractory) compounds of metallic

    & non-metallic elements (oxides, carbides, nitrides, sulfides) Brittle, glassy, elastic

    non-conducting (insulators)

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    Chapter 1 - 20

    1. Pick Application Determine required Properties

    2. Properties Identify candidate Material(s)3. Material Identify required Processing

    Processing: changes structureand overall shapeex: casting, sintering, vapor deposition, doping

    forming, joining, annealing.

    Properties: mechanical, electrical, thermal,magnetic, optical, deteriorative.

    Material: structure, composition.

    The Materials Selection Process

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    Chapter 1 - 21

    ELECTRICAL

    Electrical Resistivity of Copper:

    Adding impurity atoms to Cu increases resistivity. Deforming Cu increases resistivity.

    Adapted from Fig. 18.8, Callister 7e.(Fig. 18.8 adapted from: J.O. Linde,Ann Physik5, 219 (1932); andC.A. Wert and R.M. Thomson,Physics of Solids, 2nd edition,McGraw-Hill Company, New York,1970.)

    T(C)-200 -100 0

    1

    2

    3

    4

    5

    6

    Resistiv

    ity,r

    (10-8O

    hm-m)

    0

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    Chapter 1 - 22

    THERMAL Space Shuttle Tiles:

    --Silica fiber insulation

    offers low heat conduction.

    Thermal Conductivityof Copper:

    --It decreases whenyou add zinc!

    Adapted fromFig. 19.4W, Callister6e. (Courtesy ofLockheed AerospaceCeramics Systems,Sunnyvale, CA)(Note: "W" denotes fig.

    is on CD-ROM.)

    Adapted from Fig. 19.4, Callister 7e.(Fig. 19.4 is adapted from Metals Handbook:Properties and Selection: Nonferrous alloys andPure Metals, Vol. 2, 9th ed., H. Baker,(Managing Editor), American Society for Metals,1979, p. 315.)

    Composition (wt% Zinc)

    ThermalCondu

    ctivity

    (W/m-K)

    400

    300200

    100

    00 10 20 30 40

    100mm

    Adapted from chapter-opening photograph,Chapter 19, Callister 7e.(Courtesy of LockheedMissiles and SpaceCompany, Inc.)

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    Chapter 1 - 23

    MAGNETIC Magnetic Permeability

    vs. Composition:--Adding 3 atomic % Si

    makes Fe a betterrecording medium!

    Adapted from C.R. Barrett, W.D. Nix, andA.S. Tetelman, The Principles ofEngineering Materials, Fig. 1-7(a), p. 9,1973. Electronically reproducedby permission of Pearson Education, Inc.,Upper Saddle River, New Jersey.

    Fig. 20.23, Callister 7e.(Fig. 20.23 is from J.U. Lemke, MRS Bulletin,Vol. XV, No. 3, p. 31, 1990.)

    Magnetic Storage:

    --Recording mediumis magnetized byrecording head.

    Magnetic Field

    Magnetization Fe+3%Si

    Fe

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    Chapter 1 - 24

    Transmittance:

    --Aluminum oxide may be transparent, translucent, oropaque depending on the material structure.

    Adapted from Fig. 1.2,Callister 7e.(Specimen preparation,P.A. Lessing; photo by S.Tanner.)

    single crystalpolycrystal:low porosity

    polycrystal:high porosity

    OPTICAL

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    Chapter 1 - 25

    DETERIORATIVE Stress & Saltwater...

    --causes cracks!

    Adapted from chapter-opening photograph,Chapter 17, Callister 7e.(from Marine Corrosion, Causes, andPrevention, John Wiley and Sons, Inc., 1975.) 4mm

    --material:7150-T651 Al "alloy"(Zn,Cu,Mg,Zr)

    Adapted from Fig. 11.26,Callister 7e. (Fig. 11.26 provided courtesy of G.H.

    Narayanan and A.G. Miller, Boeing CommercialAirplane Company.)

    Heat treatment: slows

    crack speed in salt water!

    Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation andFracture Mechanics of Engineering Materials" (4th ed.), p. 505, JohnWiley and Sons, 1996. (Original source: Markus O. Speidel, BrownBoveri Co.)

    held at160C for 1 hrbefore testing

    increasing loadcrac

    kspeed(m/s)

    as-is

    10-10

    10-8

    Alloy 7178 tested insaturated aqueous NaCl

    solution at 23C

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    Chapter 1 - 26

    Use the right material for the job.

    Understand the relation between properties,

    structure, and processing.

    Recognize new design opportunities offeredby materials selection.

    Course Goals:

    SUMMARY