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Chapter 1 -
Materials and equipment Design
PETR 350DESCRIPTION
This is a multidisciplinary course aimed at: study of the materials selection process for
equipment used in gas and oil operations
Corrosion mechanisms and inhibition methods
Codes, standards and applicable specificationspresented along with their applications
1
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Chapter 1 -
Learning Objectives
Learners will: become familiar with metals used in equipment in
the oil and gas sector
understand the differences in properties between
carbon steels, stainless steels, alloys andsuperalloys
know and understand the primary corrosionmechanisms and the conditions under which theyoccur
become familiar with codes , standards andspecifications as applied to oil and gas industryequipment
2
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Chapter 1 -
recognize the criticality of material failures inequipment performance
This course will provide the learner with thetechnical aspects of metallic and non-metallicmaterials and their properties.
Material selection criteria and applicationsspecific to the oil and gas industry will becovered.
The course will include equipment designconsiderations along with codes, standards and
specifications utilized in the oil and gas industry.Corrosion mechanisms and mitigation techniqueswill be covered.
3
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Chapter 1 -
Resource Material
References: Specifications CSA for pipeline
SpecificationsAPI for drill pipe, tubing andcasing
Chemical Engineering Design and Analysis,Duncan, T. Michael
Journal of Petroleum Technology
Oil and Gas Journal
Introduction to the Canadian Natural GasIndustry, Canadian Energy Research Institute
Energy Research Institute
4
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Chapter 1 - 5
LECTURES
Lecturer: Ahmed Yusuf
Time: Sunday 8.00 9.30 am8.00 9.30 am
Location: B1 G02
Activities: Present new material
Announce reading and homework
Take Final Exam*
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Chapter 1 - 6
Purpose:
Discuss homework, quizzes, exams
Hand back graded quizzes, exams
Discuss concepts from lecture
Instructor:
Times and Places:Sun.
Tue.
10:00 - 12.00 noon
10:00 - 12.00 noon
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Chapter 1 - 7
Purpose: To learn more about materials by relatinglecture material with observations. Also to learn to properlyformulate and write engineering reports and proposals.
Instructor: Sondus
Location: B4
LABORATORY SECTIONS
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Chapter 1 - 8
TEACHING ASSISTANTS
Teaching Assistants will
participate in tutorial sessions,
have office hours to help you with course material
and problem sets.
NameEng. Sondus
Office_ XXX
Tel.X-XXXX
E-mail_____
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Chapter 1 - 9
Required text: Materials Science and Engineering: An Introduction
W.D. Callister, Jr., 7th edition, John Wiley and Sons,Inc. (2007).
COURSE MATERIALS
Optional Material:
Chemistry Books
Physical Metallurgy Books
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Chapter 1 - 10
GRADING
Assignments in-tutorial 10%
Laboratory Reports 10%
Based on core homework problems
Midterm #1 30%
Tentatively scheduled for:Material covered:
Final 50%
Tentatively scheduled for:Material covered:
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Chapter 1 - 11
READING SCHEDULE
Week
123456
78
910
Topic
General Intro; Atomic BondingCrystalline Structure; Imperfections
Diffusion; Mechanical PropertiesStrengthening Mechanisms; Failure
Phase DiagramsKinetics & Phase Transformations
Processing & Applications of MetalsStruc., Prop., Proc., Applic. of CeramicsStruc., Prop. of Polymers; Composites
Corrosion; Elec. & Thermal Prop.Magnetic & Optical Prop.
Materials Selection; Econ. & Envir. Issues
Chapter
1,23,45,67,89
1011
12,1315,16
17,18,19*20*,21*22*,23*
Lectures: will highlight important portions of each chapter.*These chapters available at website www.wiley.com/college/callister.
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Chapter 1 - 12
Chapter 1 - Introduction
What is materials science? Why should we know about it?
Materials drive our society
Stone Age Bronze Age
Iron Age
Now?
Silicon Age? Polymer Age?
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Chapter 1 - 13
Example Hip Implant
With age or certain illnesses joints deteriorate.
Particularly those with large loads (such as hip).
Adapted from Fig. 22.25, Callister 7e.
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Chapter 1 - 14
Example Hip Implant
Requirements
mechanical
strength (manycycles)
good lubricity
biocompatibility
Adapted from Fig. 22.24, Callister 7e.
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Chapter 1 - 15
Example Hip Implant
Adapted from Fig. 22.26, Callister 7e.
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Chapter 1 - 16
Hip Implant
Key problems to overcome
fixation agent to holdacetabular cup
cup lubrication material
femoral stem fixing agent(glue)
must avoid any debris in cup
Adapted from chapter-opening photograph,Chapter 22, Callister 7e.
FemoralStem
Ball
AcetabularCup and Liner
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Chapter 1 - 17
Example Develop New Types ofPolymers
Commodity plastics large volume ca. $0.50 / lbEx. PolyethylenePolypropylenePolystyreneetc.
Engineering Resins small volume > $1.00 / lbEx. Polycarbonate
NylonPolysulfoneetc.
Can polypropylene be upgraded to properties (and price) nearthose of engineering resins?
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Chapter 1 - 18
ex: hardness vs structure of steel Properties depend on structure
Data obtained from Figs. 10.30(a)and 10.32 with 4 wt% C composition,and from Fig. 11.14 and associateddiscussion, Callister 7e.Micrographs adapted from (a) Fig.10.19; (b) Fig. 9.30;(c) Fig. 10.33;and (d) Fig. 10.21, Callister 7e.
ex: structure vs cooling rate of steel Processing can change structure
Structure, Processing, & Properties
H
ardness(BH
N)
Cooling Rate (C/s)
100
2 00
3 00
4 00
5 00
6 00
0.01 0.1 1 10 100 1000
(d)
30mm(c)
4mm
(b)
30mm
(a)
30mm
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Chapter 1 - 19
Types of Materials Metals:
Strong, ductile high thermal & electrical conductivity
opaque, reflective.
Polymers/plastics: Covalent bonding sharing of es
Soft, ductile, low strength, low density thermal & electrical insulators
Optically translucent or transparent.
Ceramics: ionic bonding (refractory) compounds of metallic
& non-metallic elements (oxides, carbides, nitrides, sulfides) Brittle, glassy, elastic
non-conducting (insulators)
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Chapter 1 - 20
1. Pick Application Determine required Properties
2. Properties Identify candidate Material(s)3. Material Identify required Processing
Processing: changes structureand overall shapeex: casting, sintering, vapor deposition, doping
forming, joining, annealing.
Properties: mechanical, electrical, thermal,magnetic, optical, deteriorative.
Material: structure, composition.
The Materials Selection Process
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Chapter 1 - 21
ELECTRICAL
Electrical Resistivity of Copper:
Adding impurity atoms to Cu increases resistivity. Deforming Cu increases resistivity.
Adapted from Fig. 18.8, Callister 7e.(Fig. 18.8 adapted from: J.O. Linde,Ann Physik5, 219 (1932); andC.A. Wert and R.M. Thomson,Physics of Solids, 2nd edition,McGraw-Hill Company, New York,1970.)
T(C)-200 -100 0
1
2
3
4
5
6
Resistiv
ity,r
(10-8O
hm-m)
0
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Chapter 1 - 22
THERMAL Space Shuttle Tiles:
--Silica fiber insulation
offers low heat conduction.
Thermal Conductivityof Copper:
--It decreases whenyou add zinc!
Adapted fromFig. 19.4W, Callister6e. (Courtesy ofLockheed AerospaceCeramics Systems,Sunnyvale, CA)(Note: "W" denotes fig.
is on CD-ROM.)
Adapted from Fig. 19.4, Callister 7e.(Fig. 19.4 is adapted from Metals Handbook:Properties and Selection: Nonferrous alloys andPure Metals, Vol. 2, 9th ed., H. Baker,(Managing Editor), American Society for Metals,1979, p. 315.)
Composition (wt% Zinc)
ThermalCondu
ctivity
(W/m-K)
400
300200
100
00 10 20 30 40
100mm
Adapted from chapter-opening photograph,Chapter 19, Callister 7e.(Courtesy of LockheedMissiles and SpaceCompany, Inc.)
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Chapter 1 - 23
MAGNETIC Magnetic Permeability
vs. Composition:--Adding 3 atomic % Si
makes Fe a betterrecording medium!
Adapted from C.R. Barrett, W.D. Nix, andA.S. Tetelman, The Principles ofEngineering Materials, Fig. 1-7(a), p. 9,1973. Electronically reproducedby permission of Pearson Education, Inc.,Upper Saddle River, New Jersey.
Fig. 20.23, Callister 7e.(Fig. 20.23 is from J.U. Lemke, MRS Bulletin,Vol. XV, No. 3, p. 31, 1990.)
Magnetic Storage:
--Recording mediumis magnetized byrecording head.
Magnetic Field
Magnetization Fe+3%Si
Fe
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Chapter 1 - 24
Transmittance:
--Aluminum oxide may be transparent, translucent, oropaque depending on the material structure.
Adapted from Fig. 1.2,Callister 7e.(Specimen preparation,P.A. Lessing; photo by S.Tanner.)
single crystalpolycrystal:low porosity
polycrystal:high porosity
OPTICAL
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Chapter 1 - 25
DETERIORATIVE Stress & Saltwater...
--causes cracks!
Adapted from chapter-opening photograph,Chapter 17, Callister 7e.(from Marine Corrosion, Causes, andPrevention, John Wiley and Sons, Inc., 1975.) 4mm
--material:7150-T651 Al "alloy"(Zn,Cu,Mg,Zr)
Adapted from Fig. 11.26,Callister 7e. (Fig. 11.26 provided courtesy of G.H.
Narayanan and A.G. Miller, Boeing CommercialAirplane Company.)
Heat treatment: slows
crack speed in salt water!
Adapted from Fig. 11.20(b), R.W. Hertzberg, "Deformation andFracture Mechanics of Engineering Materials" (4th ed.), p. 505, JohnWiley and Sons, 1996. (Original source: Markus O. Speidel, BrownBoveri Co.)
held at160C for 1 hrbefore testing
increasing loadcrac
kspeed(m/s)
as-is
10-10
10-8
Alloy 7178 tested insaturated aqueous NaCl
solution at 23C
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Chapter 1 - 26
Use the right material for the job.
Understand the relation between properties,
structure, and processing.
Recognize new design opportunities offeredby materials selection.
Course Goals:
SUMMARY