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Chapter 5
Energy Flow in the Life of a Cell
5.1 What Is Energy?
• Energy is the capacity to do work.– Synthesizing molecules– Moving objects– Generating heat and light
5.1 What Is Energy?• Types of energy
– Kinetic: energy of movement– Potential: stored energy
Fig. 5-1
5.1 What Is Energy?• First Law of Thermodynamics
– “Energy cannot be created nor destroyed, but it can change its form.”
– Example: potential energy in gasoline can be converted to kinetic energy in a car, but the energy is not lost
5.1 What Is Energy?• Second Law of Thermodynamics
– “When energy is converted from one form to another, the amount of useful energy decreases.”
– No process is 100% efficient.– Example: more potential energy is in the
gasoline than is transferred to the kinetic energy of the car moving
– Where is the rest of the energy? It is released in a less useful form as heat—the total energy is maintained.
5.1 What Is Energy?• Matter tends to become less organized.
– There is a continual decrease in useful energy, and a build up of heat and other non-useful forms of energy.
– Entropy: the spontaneous reduction in ordered forms of energy, and an increase in randomness and disorder as reactions proceed
– Example: gasoline is made up of an eight-carbon molecule that is highly ordered
– When broken down to single carbons in CO2, it is less ordered and more random.
5.1 What Is Energy?
• In order to keep useful energy flowing in ecosystems where the plants and animals produce more random forms of energy, new energy must be brought in.
5.1 What Is Energy?
• Sunlight provides an unending supply of new energy to power all plant and animal reactions, leading to increased entropy.
Fig. 5-2
5.2 How Does Energy Flow In Chemical Reactions?
• Chemical reaction: the conversion of one set of chemical substances (reactants) into another (products)– Exergonic reaction: a reaction that releases
energy; the products contain less energy than the reactants
energyreleased
reactants
productsExergonic reaction
++
(a)
5.2 How Does Energy Flow In Chemical Reactions?
• Exergonic reaction
Fig. 5-3a
5.2 How Does Energy Flow In Chemical Reactions?
• Endergonic reaction: a reaction that requires energy input from an outside source; the products contain more energy than the reactants
energyused
products
reactantsEndergonic reaction
++
(b)
5.2 How Does Energy Flow In Chemical Reactions?
• Endergonic reaction
Fig. 5-3b
5.2 How Does Energy Flow In Chemical Reactions?
• Exergonic reactions release energy.– Example: sugar burned by a flame in the presence
of oxygen produces carbon dioxide (CO2) and water
– Sugar and oxygen contain more energy than the molecules of CO2 and water.
– The extra energy is released as heat.
5.2 How Does Energy Flow In Chemical Reactions?
• Burning glucose releases energy.
Fig. 5-4
energyreleased
C6H12O6 6 O2
(glucose) (oxygen)+
6 CO2
(carbondioxide)
6 H2O(water)
+
5.2 How Does Energy Flow In Chemical Reactions?
• Endergonic reactions require an input of energy.– Example: sunlight energy + CO2 + water in
photosynthesis produces sugar and oxygen– The sugar contains far more energy than the CO2
and water used to form it.
5.2 How Does Energy Flow In Chemical Reactions?
• Photosynthesis requires energy.
Fig. 5-5
C6H12O6 6 O2
(glucose) (oxygen)+
6 CO2
(carbondioxide)
6 H2O(water)
+
energy
high
low
progress of reaction progress of reaction
energycontent
ofmolecules
Activation energy neededto ignite glucose
Energy level of reactants
glucose + O2
CO2 + H2O CO2 + H2O
glucose
Activationenergycapturedfromsunlight
Energy level of reactants
Burning glucose (sugar): an exergonic reaction Photosynthesis: an endergonic reaction(a) (b)
5.2 How Does Energy Flow In Chemical Reactions?
• All reactions require an initial input of energy.– The initial energy input to a chemical reaction is called
the activation energy.
Fig. 5-6
5.2 How Does Energy Flow In Chemical Reactions?
• The source of activation energy is the kinetic energy of movement when molecules collide.
• Molecular collisions force electron shells of atoms to mingle and interact, resulting in chemical reactions.
5.2 How Does Energy Flow in Chemical Reactions?
• Exergonic reactions may be linked with endergonic reactions.– Endergonic reactions obtain energy from
energy-releasing exergonic reactions in coupled reactions.
– Example: the exergonic reaction of burning gasoline in a car provides the endergonic reaction of moving the car
– Example: exergonic reactions in the sun release light energy used to drive endergonic sugar-making reactions in plants
5.3 How Is Energy Carried Between Coupled Reactions?
• The job of transferring energy from one place in a cell to another is done by energy-carrier molecules.– ATP (adenosine triphosphate) is the main energy
carrier molecule in cells, and provides energy for many endergonic reactions.
ADP
ATP
phosphate
energy
+
A P P P
A P P P
5.3 How Is Energy Carried Between Coupled Reactions?
• ATP is made from ADP (adenosine diphosphate) and phosphate plus energy released from an exergonic reaction (e.g., glucose breakdown) in a cell.
Fig. 5-7
5.3 How Is Energy Carried Between Coupled Reactions?
• ATP is the principal energy carrier in cells.– ATP stores energy in its phosphate bonds and
carries the energy to various sites in the cell where energy-requiring reactions occur.
– ATP’s phosphate bonds then break yielding ADP, phosphate, and energy.
– This energy is then transferred to the energy-requiring reaction.
phosphateADP
energy
ATP+
A
A P P P
P P P
5.3 How Is Energy Carried Between Coupled Reactions?
• Breakdown of ATP releases energy.
Fig. 5-8
5.3 How Is Energy Carried Between Coupled Reactions?
• To summarize:– Exergonic reactions (e.g., glucose breakdown)
drive endergonic reactions (e.g., the conversion of ADP to ATP).
– ATP moves to different parts of the cell and is broken down exergonically to liberate its energy to drive endergonic reactions.