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10/6/2004 1 CHEMREC CHEMREC Black Liquor Gasification Technology Presentation at Workshop on Liquid Biofuels from Black Liquor Gasification IEA Bioenergy ExCo Meeting Ottawa, Canada October 6, 2004 Ingvar Landälv [email protected] Chemrec AB www.chemrec.se
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Page 1: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 1 CHEMREC

CHEMREC Black Liquor Gasification Technology

Presentation atWorkshop on Liquid Biofuels from Black Liquor

Gasification

IEA Bioenergy ExCo MeetingOttawa, Canada October 6, 2004

Ingvar Landä[email protected]

Chemrec ABwww.chemrec.se

Page 2: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 2 CHEMREC

CHEMREC SCOPE OF BUSINESS

The Scope of Business of Chemrec AB shall be:

“Technical Development and Commercialisation of energy and chemical recovery systems based on black liquor gasification”.

Page 3: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 3 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 4: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 4 CHEMREC

The Pulp Mill

Page 5: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 5 CHEMREC

Composition of Wood and Black Liquor

Wood Type Cellulose Hemi-cellulose

Lignine Extractives+ others

Spruce 42% 28% 27% 3%

Fir 41% 28% 27% 4%

Birch 41% 34% 21% 4%

Black Liquor Composition

Component % MassC 34.55H 3.59S 4.35O 34.70Na 18.45K 2.96Cl 1.40N -

Total (%): 100.0

Combustible CharacteristicsBL, Dry Solids % Mass 80%HHV MJ/kg, DS 14.2NHV MJ/kg, DS 12.0

A Biomass

Feedstock in Liquid State

Page 6: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 6 CHEMREC

32

7

14

9

18

20

12

17

10

11

8

21

5

19

4

16 15

13

23

1

6

22

Recovery Boilers in SwedenSite Nr. Mill - Owner Capacity tDS/24h Start-up

1 Karlsborg - Billerud 1250 19802 Munksund - SCA 600 19653 Kraftliner Piteå - Kappa 1450 19724 Obbola - SCA 850 19625 Husum - M-Real 750 1965

Husum - M-Real 700 1978Husum - M-Real 1100 1988

6 Domsjö - 375 1958Domsjö - 375 1964

7 Dynäs - Frantschach 915 19788 Östrand - SCA 1500 19829 Iggesund - Holmen 520 1966

Iggesund - Holmen 520 196710 Vallvik - Rottneros 1000 199911 Norrsundet - Stora 540 1970

Norrsundet - Stora 460 196512 Korsnäs - Kinnevik 865 1968

Korsnäs - Kinnevik 1550 198713 Skutskär - STORA 585 1967

Skutskär - STORA 1900 197614 Frövi - ASSI Domän 520 197015 Skoghall - STORA 300 1957

Skoghall - STORA 910 196916 Gruvön - Billerud 500 1959

Gruvön - Billerud 760 1972Gruvön - Billerud 2500 2000

17 Billingsfors - Munksjö 230 197618 Bäckhammar - 570 197619 Aspa - Munksjö 510 197320 Skärblacka - Billerud 600 1962

Skärblacka - Billerud 1250 197621 Värö - Södra 1400 1972

Värö - Södra Under construction22 Mönsterås - Södra 1600 1979

Mönsterås - Södra 4000 199623 Mörrum - Södra 2000 1995

Mörrum - Södra 740 1970

Total No. of boilers 37Total capacity 36195 tDS/24h

39 TWh (LHV) Year 2000

Page 7: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 7 CHEMREC

Illustration of Recovery Boiler Capacities in Europe

= clusters of mills together having a large boiler capacity

= important single mill

Page 8: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 8 CHEMREC

0

50

100

150

200

250

300

1965 1970 1975 1980 1985 1990 1995 2000 2005 2010 2015 2020 2025

Bla

ck L

iquo

r as

Dry

Sol

ids

(Mto

n)

0.0

0.6

1.2

1.8

2.4

3.0

3.6

App

rox.

Ene

rgy

Con

tent

, LHV

(EJ)

South AmericaOceaniaNorth AmericaEuropeAsiaAfrica

Estimated Black Liquor Production (World)

Japan50 TWh

South America44 TWh

Sweden39 TWh

World~ 600 TWh

ASIA80 TWh

Europe120 TWh

North America350 TWh

Page 9: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 9 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 10: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 10 CHEMREC

Drivers for Technology Change

Possible Achievements with Gasification

Atmospheric Booster

Pressurized BLGCC/MF

Develop Technology for Incremental Capacity X (X)

Improved Cooking Methods(More pulp per ton of wood)

X

Improved Energy Recovery(Power or Automotive Fuels)

X

Improved Safety X X

Page 11: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 11 CHEMREC

Years of Start-up and Re-build of North American Recovery Boilers

Number of boilers

0

2

4

6

8

10

12

14

16

18

20

1938

1947

1949

1951

1953

1955

1957

1959

1961

1963

1965

1967

1969

1971

1973

1975

1977

1979

1981

1983

1985

1987

1989

1991

1993

1995

1997

SOURCE: Weyerhaeuser START-UPS RE-BUILDS

Page 12: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 12 CHEMREC

1000 Years of Global CO2 Change

Cam

brid

ge U

nive

rsity

Pre

ss

CO2 concentration, [ppm]

380

360

340

320

300

280

2601000 1250 1500 1750 2000

Page 13: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 13 CHEMREC

Oil- and Natural Gas ConsumptionHistory and Prognoses

0

10

20

30

40

50

60

70

80

1930 1940 1950 1960 1970 1980 1990 2000 2010 2020 2030 2040 2050

Gig

abar

rel o

il eq

uiva

lent

Crude oil supply Heavy etc.Unconventional oil PolarNGL Natural gas supplyNon-con gas Oil demandTotal oil and gas demand Discovered oil fields

Discoveries(Oil and Gas)

OilConsumption

Oiland Gas

Page 14: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 14 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 15: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 15 CHEMREC

Technology of today for the Recovery of Cooking Chemicals

ConcentratorsStrongblackliquor

Weakblackliquor

WeakwashDissolving

tank

Woodchips

Pulp White liquor Green liquorCausticizing

Digester

Steam

Smelt

Fluegas

RecoveryBoiler

Page 16: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 16 CHEMREC

Gasification Technology for the Recovery of Cooking Chemicals

ConcentratorsStrongblackliquor

Weakblackliquor

Woodchips

Pulp White liquor Green liquorCausticizing

DigesterGasifier

RAW GAS

Page 17: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 17 CHEMREC

Main Blocks in a Pulp & Paper Mill

Pulp Mill

Green Liquor

Internal heat and power

Pulp

Black Liquor

PowerBoiler

Recovery Boiler

Pulp Wood

Page 18: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 18 CHEMREC

P&P Mill with Motor Fuel Production and Heat/Power Unit

Pulp Mill

Green Liquor

Methanol/DME

Internal heat and power

Biomassfed power

boileror IGCC

BLGMF

Pulp Wood

AdditionalRenewableEnergy

Black Liquor

Pulp

Page 19: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 19 CHEMREC

Black Liquor Gasification withMotor Fuels Production (BLGMF)

BlackBlackLiquorLiquor

GreenGreenLiquorLiquor

SyngasSyngas

Methanol /Methanol /DMEDME

Methanol / DME SynthesisMethanol / DME Synthesis

Gasification & Gas Gasification & Gas CoolingCooling

Gas Gas CleanClean--UpUp & Sulfur & Sulfur HandlingHandling

Air SeparationAir Separation

HighHigh--SulfiditySulfidityLiquorLiquor

OxygenOxygen

Page 20: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 20 CHEMREC

Gasification Technology Principles

Raw Syngas

Green Liquor

Condensate

Black Liquor GAS COOLER

Oxygen

Atomizing medium

GASIFIER

QUENCH

HX

C.W

BFW

LP-Steam

MP-Steam

Weak wash

CLEAN COOLEDSYNGAS

ATOMISATION

GAS AND SMELT

SEPARATION

PARTICULATE REMOVAL &

CONDENSATE RECOVERY

SMELTON WALL

Page 21: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 21 CHEMREC

BLGMF Process: Biomass-to-fuel EfficiencyCase: Power Boiler

Pulp Mill

Green Liquor

Methanol/DME

Internal heat and power

Black Liquor

Biomassfed

powerboiler

BLGMF

Production Efficiency = Methanol/ DMEAdditional Renewable Energy

= 65-70 %

Same Power Need withRB or BL Gasification.

AdditionalRenewableEnergy

Pulp

Page 22: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 22 CHEMREC

BLGMF Process: Biomass-to-fuel EfficiencyCase: Power IGCC

Pulp Mill

Green Liquor

Methanol/DME

Internal heat and power

Black Liquor

Biomassfed

powerIGCC

BLGMF

Production Efficiency = Methanol/ DMEAdditional Renewable Energy

= 80-90 %

Same Power Need withRB or BL Gasification.

AdditionalRenewableEnergy

Pulp

Page 23: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 23 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 24: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 24 CHEMREC

Production potential in Sweden

20 TWh*

DME

24 TWh

Hydrogen

20 TWh

Metanol

Black Liquorenergy

39 TWh

or

or

* Corresponds to approx. 30% of Swedish consumption of gasolineand diesel year 2000

30 TWh addedbiomass

Available black liquor energyin Swedish pulp mills

Case with biomass fed power boiler

Page 25: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 25 CHEMREC

Overall energy balance for all Swedish pulp Mills (figures for year 2000)

SwedishPulp Millsyear 2000

PULP WOOD *)

Approx.90 TWh

17 TWh bioenergy,5 TWh oil and20 TWh el. (1999/2000)

PULP

ca50 TWh

*) As pulp wood andas biomaterial from saw mills

Page 26: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 26 CHEMREC

Overall energy balance – Fuel generation at all Swedish pulp Mills using the BLGMF process

(figures for year 2000)

SwedishPulp Millsyear 2000

PULP WOOD *)

Approx.90 TWh

PULP

ca50 TWh

17 TWh bioenergy,5 TWh oil and20 TWh el. (1999/2000)

20-30 TWh **) Automotive Fuels(DME and/or Methanol)

20 TWh

Volvos new D9A enginewill be adopted for DME

*) As pulp wood andas biomaterial from saw mills

**) Depending on energyconversion technology

Page 27: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 27 CHEMREC

Recovery Boilers in Canada

COUNTRY COMPANY GROUP MILLTOTAL PULP

CAPACITYCHEMICAL PULP

CAPACITYRECOVERY

BOILERS

REC. BOILER CAPACITY (TDS/DAY)

REC. BOILER STARTUP YEAR

MOST RECENT REC. BOILER

REBUILD

OTHER REC. BOILER

REBUILDS

Canada ABITIBI-CONSOLODATED INC. ABITIBI-CONSOLODATED INC. FORT FRANCES, ON 340 190 1 950 1971 1985Canada ABITIBI-CONSOLODATED INC. TROIS RIVIERES, QU 195 95 1 365 1947 1989Canada ALBERTA-PACIFIC FOREST INDUSTRIES INC. BOYLE, AL 505 505 1 2640 1993Canada AV CELL INC. ATHOLVILLE, NB 110 110 1 545 1983 1998 1995Canada AVENOR INC. BOWATER CORPORATION DRYDEN, ON 300 300 1 1160 1966Canada AVENOR INC. THUNDER BAY, ON 770 430 1 910 1966 1988Canada 1 1360 1976Canada CANADIAN FOREST PRODUCTS LTD. CANFOR CORPORATION PRINCE GEORGE, BC (INTERCONTINENTAL PULP MILL) 255 255 1 1440 1968 1993Canada CANADIAN FOREST PRODUCTS LTD. PRINCE GEORGE, BC (PRINCE GEORGE PULP AND PAPER) 270 270 1 500 1983Canada 1 1090 1966 1966Canada CARIBOO PULP & PAPER CO. QUESNEL, BC 310 310 1 1810 1972 1994 1989Canada CASCADES EAST ANGUS INC. CASCADES CORPORATION EAST ANGUS, QU 60 60 1 295 1938Canada CELGAR PULP CO. STONE CONTAINER CORPORATION CASTLEGAR, BC 420 420 1 2610 1993Canada CRESTBROOK FOREST INDUSTRIES LTD. SKOOKUMCHUCK, BC 215 215 1 1575 1993Canada DAISHOWA MARUBENI INTERNATIONAL LTD. DAISHOWA GROUP PEACE RIVER, AL 390 390 1 1700 1990Canada DOMTAR PAPERS DOMTAR INC. CORNWALL, ON 270 190 1 600 1959Canada DOMTAR PAPERS WINDSOR, QU 340 340 1 1480 1987Canada DONOHUE INC. DONOHUE INC. ST. FELICIEN, QU 320 320 1 1360 1978Canada E.B. EDDY FOREST PRODUCTS LTD. E.B. EDDY CORPORATION ESPANALDA, ON 342 342 1 1905 1983 1997 1991Canada EUROCAN PULP & PAPER CO. WEST FRASIER TIMBER CO. KITIMAT, BC 440 335 1 1540 1970 1989 1982Canada FLETCHER CHALLENGE CANADA LTD. FLETCHER CHALLENGE CORPORATION CAMPBELL RIVER, BC 770 340 1 710 1959Canada 1 1485 1963 1990Canada FLETCHER CHALLENGE CANADA LTD. CROFTON, BC 780 395 1 1080 1976 1992Canada 1 1800 1991Canada FLETCHER CHALLENGE CANADA LTD. MACKENZIE, BC 200 200 1 1260 1972 1985Canada HARMAC PACIFIC INC. NANAIMO, BC 380 380 1 1090 1963 1983Canada 1 540 1953 1997 1988Canada 1 350 1951 1994Canada HOWE SOUND PULP AND PAPER LTD. CANFOR CORPORATION PORT MELLON, BC 495 315 1 2990 1990Canada INDUSTRIES JAMES MACLAREN INC. NORANDA FOREST INC. THURSO, QU 235 235 1 410 1990Canada 1 585 1984 1990Canada IRVING PULP & PAPER LTD. IRVING PULP & PAPER LTD. SAINT JOHN, NB 285 285 1 1425 1970 1994Canada JAMES RIVER - MARATHON LTD. FORT JAMES CORPORATION MARATHON, ON 170 170 1 990 1979 1989 1991Canada KIMBERLY-CLARK FOREST PRODUCTS INC. KIMBERLY-CLARK CORPORATION TERRACE BAY, ON 480 460 1 1090 1973 1997Canada 1 1090 1979 1996Canada KIMBERLY-CLARK NOVA SCOTIA INC. ABERCHROMBIE POINT, NS 245 245 1 1300 1967 1984 1981Canada MALETTE KRAFT PULP & POWER TEMBEC CORPORATION SMOOTH ROCK FALLS, ON 170 170 1 555 1965Canada 1 500 1992Canada NORAMPAC INC. RED ROCK, ON (CONTAINERBOARD MILL) 385 385 1 1090 1982Canada 1 1200 1997Canada NORKRAFT QUEVILLON INC. DOMTAR INC. LEBEL-SUR-QUEVILLON, QU 280 280 1 1346 1997Canada NORTHWOOD PULP AND TIMBER LTD. PRINCE GEORGE, BC 515 515 1 1250 1966 1977Canada 1 1500 1982Canada PACIFICA PAPERS INC. POWELL RIVER, BC (POWELL RIVER DIVISION) 660 190 1 1090 1967 1985Canada REPAP NEW BRUNSWICK INC. REPAP ENTERPRISES INC. NEWCASTLE, NB 235 235 1 1215 1991Canada SKEENA CELLULOSE INC. PRINCE RUPERT, BC 450 450 1 1170 1978Canada 1 1575 1966Canada ST. ANNE-NACKAWIC PULP COMPANY LTD. PARSON & WHITTEMORE CORPORATION NACKAWIC, NB 240 240 1 910 1970 1985Canada ST. LAURENT PAPERBOARD INC. ST. LAURENT PAPERBOARD INC. LATUQUE, QU 445 445 1 1575 1975 1992Canada 1 585 1966 1997Canada 1 450 1957 1997Canada STONE CONTAINER (CANADA) INC. STONE CONTAINER CORPORATION NEW RICHMOND, QU 200 200 1 750 1965Canada STONE CONTAINER (CANADA) INC. PORTAGE DU FORT, QU 1 915 1967Canada TOLKO MANITOBA THE PAS, MA 125 125 1 635 1971Canada WELDWOOD OF CANADA LIMITED CHAMPION INTERNATIONAL CORP. HINTON, AL 385 385 1 1090 1979 1990Canada 1 1215 1989Canada WESTERN PULP LIMITED PARTNERSHIP SQUAMISH, BC 240 240 1 1755 1988Canada WEYERHAEUSER CANADA LTD. WEYERHAEUSER CORPORATION GRANDE PRAIRIE, AL 320 320 1 1550 1973 1990Canada WEYERHAEUSER CANADA LTD. KAMLOOPS, BC 440 440 1 410 1965Canada 1 2040 1972Canada WEYERHAEUSER CANADA LTD. PRINCE ALBERT, SA (PRINCE ALBERT PULP & PAPER MILL) 340 340 1 1040 1968 2000Canada 1 585 1977SUM CANADA 15322 13062 72026 1974

72026 tpd<=>

95 TWh/yr

Page 28: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 28 CHEMREC

Pulp and Paper Mills in Canada

Page 29: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 29 CHEMREC

Production Potential – North America

175 TWh*

DME

210 TWh

Hydrogen

175 TWh*Methanol

Black Liquor energy

350 TWh

or

or

260 TWhBiomass Energy

Equals

50 milj metric tons dry biomass

Available black liquor Energyin North American pulp millsBiomass Boiler

Case

* Corresponds to 7% of Canadian plus 2% of US automotive fuels consumption

Page 30: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 30 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 31: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 31 CHEMREC

The “BLGMF” StudySupported by the EU Altener II Program and the

Swedish National Energy Administration

• Duration: Feb 2002 - Nov 2003• Total cost: €400,000• Contents: - Process design

- Mill integration- Energy balances- Cost estimate- Market barriers

Page 32: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 32 CHEMREC

BLGMF Study Project Partners

Process engineering consultant

Gasification technologysupplier

National gasoline andoil distributor

World’s largest methanolproducer and distributor

World-known automotiveand engine developer

Automotive fuel andengine consultant

Research centre forpulp and papermaking

Page 33: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 33 CHEMREC

Cost of fuel at pump, EUR or SEK per liter gasoline equivalent

(incl. distribution cost but excl. taxes)

Source: Swedish National Road Administration, 2002

0

2

4

6

8

10

12(SEK/l.g.e.) (EUR/l.g.e)

0

0.25

1.0

1.25

0.50

0.75CO2 –tax 2 USD/

gal

1.5 USD/gal

Gasoline EtOH(Wheat)

EtOH(Wood)

MeOH(NG)

MeOH(Biomass

gasification)

MeOH/DME,this study

Page 34: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 34 CHEMREC

Fuel output from use of 1 MJ of energy

Fuel output from use of 1 MJ of energy

0,00,10,20,30,40,50,60,70,8

DME (Natural gas)

Syndiesel(Natural gas)

DME (Biomass)

Syndiesel(Biomass)

MJ

Diesel engine fuel Naphta, waxes

Source: Volvo The BLGMF study

DME*(Biomass)

*Same for MeOH

Page 35: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 35 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 36: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 36 CHEMREC

Pressurised BLG Development DP-2

DP-1Airseparation

Gasifier

Quench

Power

Oxygen

Raw gasBlackliquor

Greenliquor Syn Gas

Gascooling

Sulphurgeneration

Absorber Stripper

Polysulfid -generation

GasMP/LPSteam

Gas Clean-up

Condensate

Electric Power or SynfuelPlant

Gasification

CounterCurrent

Condenser

Hotwater

Polysulfide

White Liquor

Sulphur handling

Weakwash

Electric Power or

Methanol/ DME

Page 37: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 37 CHEMREC

CHEMREC DEVELOPMENT PLANTSDP-1 & DP-2

Plant Location Process UnitsCapacitytDS per d /MWt

Pressure(bar)

Purpose

DP1*) Piteå,North Sweden

- Gasification- Gas Cooling- Gas Cleaning

20 / 3 32 - Verify Plant technicalfeatures.

- Secure performance for DP-2

DP2*) Kappa Kraftliner

Piteå

- Full BLGCCconcept

~300 / 45 32 - Fully develop the BLGCCconcept.

- Net product approx .10 MWeand 35 t/h of steam.

*) Plant Investments Supported by a Grant from the Swedish Government of 238 MSEK, approx 25 Mill €

Page 38: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 38 CHEMREC

CHEMREC’S DP-1 PLANT AT PITEÅ

Page 39: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 39 CHEMREC

DP1 Piping Model – From the mill side

Page 40: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 40 CHEMREC

Time Schedule Pressurized BLG Development

DP-1, Piteå, Sweden• EPC• Operation

Demos in Sweden• DP-2 BLGCC, Piteå• DP-3 BLGMF, MörrumCD, USA *

Commercialisation

2004 2005 2006 2007 2008

Activity Quarter 1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4 1 2 3 4

*) A US CD-plant project is planned to start after evaluation of Swedish DP-1 operating results

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10/6/2004 41 CHEMREC

Fluidized bed reactorUsed for SP2 FT-fuel

SP 1:Entrained Flow CarboV at Atm. Pressure

SP 2: Press.EntrainedFlow at 30 bar

SP 3: Entrained Flow Gasification ofBlack Liquor

DME / Methanol

BTL

Fuel

Ethanol

Wood

Straw

EnergyCrops

SP1NTVProcess

Optim.

SP2BTL Process.

Optim.

SP 4: Thermochemistryfor Bioethanol & Enzymatic pathway

SP 2: Circulating Fluid. Bed Reactor

SP2: Gas

Cleaning

SP2: FTSynthesis

SP2: FTSynthesis

SP1: Gas treatment

SP4: Gastreatment

SP2: Catalytic Cracking

SP1:Hydro-cracking

SP1: FT-synthesis

Catalytic reaction

Aut

omot

ive

Tes

ting

SP3BTL f. Black.

LiquorPlant up-scalingSP3: Gas

treatment

SP2:Gas treatment

SP4Bio Ethanol

Prod.

Opt

imum

fuel

pro

duct

ion

Indu

st. &

Pol

it. R

ecom

men

datio

ns

SP5BiofuelAssess.

The RENEW Project: Biomass to Liquid Fuels A Project within EU’s 6th Framework Program

Liquid Fuels Gaseous Fuels

4 years30 partners~30 MMUSD

ChemecVolvoSTFISödra CellEcotraffic

Coordinator: Volkswagen

Page 42: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 42 CHEMREC

Overall Concept for the SP3 BLGMF Plant

~35MW Extra Biomass tocompensate BLGMF

Fuel generation

PULP/PAPER

WOOD FORPULPING

Södra Cells

Pulp Mill

at Mörrum

O2

Plant

Gasification Gas Cleaning +Synthesis

BLGAMF PLANT

45 MWBlack Liquor

GreenLiquor

Sulphur

Expanded Mill incl. BLGMF

CO2

22 MW~ 4 t/h of MeOH

(or corresp. DME)

Page 43: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 43 CHEMREC

Renew SP3

SP3 will determine technical and commercial impact of locating a small BLGMF plant at a pulp mill

Key input from work at four locations:1. Chemrec´s Development Plant under construction in

Piteå, north Sweden – Start-up 4th quarter 20042. Södra Cell’s pulp Mill in Mörrum, South Sweden3. STFI laboratories in Stockholm4. VOLVO Engine Development Laboratories in

Gothenburg

Page 44: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 44 CHEMREC

Södra Cell Mörrum Mill

Page 45: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 45 CHEMREC

Södra Cell Mörrum Mill with Planned BLGMF Plant

Planned BLGMF

Demonstration

BiomassTo the

Mill:~650MW

Black liquor usage: ~360MW

Black liquor: ~45MW

DME &Methanol

Page 46: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 46 CHEMREC

Contents

1. Black Liquor: Where? What? How much?2. Why new technology? Some reasons.3. The Chemrec BLGMF concept 4. Impact of introducing the BLGMF concept

- Sweden- Canada and the US

5. BLGMF economics6. Development status7. Funding requirement and structure

Page 47: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 47 CHEMREC

Chemrec New Financial Structure(Capital Requirement, MUSD)

Shareholders

Participants

1.6

BLG Programincluding

1.The R&D pgm2.The development

plant

Chemrec AB

Engineering Services Supplier

Industrial Actor

Financial investor

NykombSynergetics

Energy Industry

Research FoundationsSTEM

Pulp& Paper Industry

Swedish Universities

Swedish Energy Agency

8.4

1.3 1.31.3

1.1

4.0

Page 48: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

CHEMREC

Two Phases in the BLG R&D Program

2001 - 2003 2004 - 2006

0. Co-ordination ETC

1. Reactor/nozzle CFD modeling ETC/LuTH

2. Quench/Cooler CFD modeling LuTH

3. Inorganic Chemistry UmU

4. Reaction kinetics CTH

4.

3.

2.

1.

0.

Phase 1

Phase 29. Multi-disciplinary System Analysis Mh

8. Construction mtrl for green liquor KI

7. Non process elements STFI

6. Alternate cooking cycles STFI

5. Direct Caustication with borates ETC

MUSD / phase

2.4

5.7

Page 49: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 49 CHEMREC

Chemrec New Financial Structure(Capital Requirement, MUSD)

Shareholders

BLG Programincluding

1.The R&D pgm2.The development

plant

Chemrec AB

Participants

Engineering Services Supplier

Industrial Actor

Financial investor

NykombSynergetics

Energy Industry

Research FoundationsSTEM

Pulp& Paper Industry

Swedish Universities

Swedish Energy Agency

8.4

1.3 1.31.3

1.1

4.0

Financing in Place

1.6

Page 50: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 50 CHEMREC

Chemrec Pitea BLG User Group

Nordic Companies: Status re. User Group participation- Kappa Kraftliner Provides land for DP-1 and favourable

media supply

- SCA Committed to contribute cash and in kind

- SVEASKOG Committed to contribute cash

- Södra Cell Committed to contribute cash and partici-pates with Chemrec in Renew EUproject

- Vattenfall Committed to contribute cash

Page 51: CHEMREC Black Liquor Gasification Technology€¦ · Impact of introducing the BLGMF concept-Sweden - Canada and the US 5. BLGMF economics 6. ... LH V (E J) South America Oceania

10/6/2004 51 CHEMREC

Chemrec Pitea BLG User Group

North American Companies: Status re. User Group participation

-Weyerhaeuser Since several years these companies-International Paper work together with the DOE in the area-Georgia Pacific of biomass and black liquor gasification.-StoraEnso NA Meetings have been held in June and-Mead Westvaco July, 2004 for definition of a novel

“US Biorefinery concept”

Objective: The above companies discuss to formalize a USBLG consortium in a legal entity owned jointly by the companies and partly funded by the DOE. Chemrec AB hope that the consortium during the second half 2004 will negotiate participation in Chemrec’s DP-1 effort in Piteå.

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10/6/2004 52 CHEMREC

One solution! Questions?


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