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CHEMICAL ENGINEER
University of Valladolid
Ana Celina Gondim Santos
Sara Prez Nieto
(Group B - 22)
Valladolid, 20 de Octubre de 2011
Chemical Engineering Laboratory II
CHILLING ADSORPTION
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1. INTRODUCTION
Cooling adsorption systems
Advantages:environmentally friendly refrigerants
can recover waste heat at low temperature levelslow operation costs
Evaluation of an Adsorption cooling system:
coefficient of performance (COP)specific cooling power (SCP)
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Oil crisis (1970)Ecological problems (1990)
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2. ADSORPTION REFRIGERATOR
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2.1 System configuration and operation
Figure 1. General basis system layout of the adsorption chiller.
ADSORBENT
ADSORBATE
Adsorbent cooling:adsorption process +
refrigerant evaporation
Adsorbent heating:desorption process +
refrigerant condensation
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2. ADSORPTION REFRIGERATOR
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2.1 System configuration and operation
Figure 2. Photograph of the silica gel-water adsorption chiller.
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2. ADSORPTION REFRIGERATOR
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2.2 Parameters of work
Parameters that influence in the performance of
the system:Temperature of cooling waterAdsorption temperature
Heating source temperature
Desorption temperature
Cycle time
to get more cooling.
load control toolTand madsorbed(Pconst)
Tand P(madsorbed-const)
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2. ADSORPTION REFRIGERATOR
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2.3 Key issues for the development of adsorption
systems
The hight cost of production is a drawback foradsorption systems.
To become more commercially attractive, it isnecessary to make a cost and size reduction:
Increasing the SCP throught enhancement of the
internal and external heat transfer of the adsorber;
Increasing the COP throught the improvement of the
heat management.
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2. ADSORPTION REFRIGERATOR
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2.3 Key issues for the development of adsorption
systems
The main technologies to enhance the externalheat transfer are related to:
extended surfaces: to increase of the heat
exchange area;
coated adsorbers: to increase the wall heat transfercoefficient;
heat pipe technology: to have a high heat flux densityand less intermediate elements.
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2. ADSORPTION REFRIGERATOR
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2.3 Key issues for the development of adsorption
systems
The main technologies to enhance the internalheat transfer are related to:
consolidated adsorbents: because consolidatedadsorbents have lower mass transfer properties than
granular adsorbents, which could lead to very lowadsorption rates.
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3. RESEARCHS
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3.1 Researches tendency
Increase in adsorption cooling systemsperformance compete with electric compressionmachines.
R&D develop performing
Harmonization of the adsorbent with thethermodynamic cycle.
Adsorbents
Components
Sistems
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3. RESEARCHS
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3.1 Researches tendency
Investigation in adsorbing materials:
silica gel/water
zeolite/water
activated carbon
activated carbon fibres/ammonia
Methanol
R134a
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3. RESEARCHS
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3.1 Researches tendency
Simulation constant values:
Overall heat transfer coefficient for adsorbentbeds;
Evaporator;
Condenser.
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3. RESEARCHS
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3.1 Researches tendency
Figura 5. Design drawing and a frontal view of theadsorption chiler test facility.
/
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3. RESEARCHS
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3.2 Read Researches
Development and test of two heat regenerative
adsorption systems:
ice making and air conditioning;
activated carbon-methanol adsorption pair;
cycle time was short good heat transfer.
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3. RESEARCHS
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3.2 Read Researches
Testing of the lab scale adsorption chiller:
Study the influence of the cycle time;
Study the relative duration of the isobaric steps;
Relative duration of the isobaric steps on theperformance of an adsorption cooling system.
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3. RESEARCHS
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3.2 Read Researches
Design and performance prediction of a newgeneration adsorption chiller:
(Mathematical model)
Describe the heat and mass transfer process
Adsorbent bedthe composite adsorbentthe metal of the tubethe working fluids
Condensercooling waterthe metal of the tuberefrigerant
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3. RESEARCHS
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3.2 Read Researches
Optimization the operation strategy :
Different temperatures of hot water inlet, cooling waterinlet and chilling water inlet different COP and coolingcapacity;
Conventional chiller;
Composite adsorbenthigher cooling capacityCOP slightly higher
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4 . APLICATIONS
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Jiagsu Province, China
cool a grain depot during hot summers ;
silica-gel adsorption chiller driven by a lowtemperature heat source .
Shanghai Research Institute of Building Science
chillers being used in the air conditioning system of agreen building.
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4 . APLICATIONS
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Figure 6. (a) Shanghai Green Building; (b) equipment room.
(a) (b)
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4 . APLICATIONS
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European project Climasol
examples of buildings that already use solar-poweredsorption air conditioners
System located in the cosmetic company
adsorption chillers powered by hot water in thesummer
Chinese policy for energy exploitation
small power adsorption chillerssuitable for combined cooling, heating and power
systems or heating and power system
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5 . CONCLUSIONS
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We tried to synthesize the four articles, taking the best thateach had. It was observed that:
Adsorption cooling systems are becoming increasinglyconsidered for applications where cooling is required and
low grade heat is available. Adsorption refrigerating machines consist essentially of anevaporator, a condenser, valves, and an adsorber-reactorcontaining a porous medium as adsorbent.
Some parameters influence in the performance of the system
and there are drawbacks in these systems that dont makethem so commercially attractive. Researches about adsorption cooling are divided into some
specifics ways to improve adsorption cooling systems. Looking for real application for the cooling adsorption, some
buildings and grain depot were found in Asia and Europe.
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Thank you!
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CHEMICAL ENGINEER
University of Valladolid
Ana Celina Gondim Santos
Sara Prez Nieto
(Group B - 22)
Valladolid, 20 de Octubre de 2011
Chemical Engineering Laboratory II
CHILLING ADSORPTION