bvlabs.com
CHROMATOGRAM GUIDE
This information guide can be used to compare petroleum products under different gas chromatology conditions. Take caution when using this guide, as the chromatograms are subject to change based on the environment the petroleum is exposed to.
1
TABLE OF CONTENTS
Petroleum Hydrocarbon Reference ...................................................................................................................................................... 3
Typical Carbon Ranges …....................................................................................................................................................................... 4
Part A – Individual Chromatograms .................................................................................................................................................... 5
1. Turpentine (F2 to F4 Chromatogram) ……………………................................................................................................... 6
2. Turpentine (Enhanced chromatogram) ................................................................................................................................. 7
3. Mineral Spirits (F1 Chromatogram) …………….................................................................................................................... 8
4. Mineral Spirits (F2 to F4 Chromatogram) ………………….................................................................................................. 9
5. Stoddard Solvent (F1 Chromatogram) ………….................................................................................................................. 10
6. Stoddard Solvent (F2 to F4 Chromatogram) ………………................................................................................................ 11
7. Varsol (F1 Chromatogram) ………………….......................................................................................................................... 12
8. Varsol (F2 to F4 Chromatogram) …...…………....................................................................................................................... 13
9. Condensate (F1 Chromatogram) …………............................................................................................................................ 14
10. Unleaded Gasoline (F1 Chromatogram) …………................................................................................................................ 15
11. Unleaded Gasoline (F2 to F4 Chromatogram) ……............................................................................................................... 16
12. Unleaded Gasoline (Enhanced F2 to F4 Chromatogram) ………......................................................................................... 17
13. Leaded Gasoline (F2 to F4 Chromatogram) …….................................................................................................................. 18
14. Leaded Gasoline (Enhanced chromatogram) ....................................................................................................................... 19
15. RFA Gasoline (F2 to F4 Chromatogram) …............................................................................................................................. 20
16. RFA Gasoline (Enhanced chromatogram) ………................................................................................................................. 21
17. Aviation Fuel (Av Gas) (F2 to F4 Chromatogram) …….......................................................................................................... 22
18. Aviation Fuel (Av Gas) (Enhanced chromatogram) ……….................................................................................................. 23
19. Kerosene (F2 to F4 Chromatogram) …................................................................................................................................... 24
20. Turbine Jet Fuel (F2 to F4 Chromatogram) …....................................................................................................................... 25
21. #1 Diesel (F2 to F4 Chromatogram) ….................................................................................................................................... 26
22. #2 Diesel (F1 Chromatogram) ….............................................................................................................................................. 27
23. #2 Diesel (F2 to F4 Chromatogram) ….................................................................................................................................... 28
24. B20 Biodiesel (F1 Chromatogram) …...................................................................................................................................... 29
25. B20 Biodiesel (F2 to F4 Chromatogram) ……........................................................................................................................ 30
26. Arctic Diesel (F2 to F4 Chromatogram) ….............................................................................................................................. 31
27. Winter Diesel (F2 to F4 Chromatogram) …............................................................................................................................ 32
28. Weathered (biodegradation) Diesel (F2 to F4 Chromatogram) …..................................................................................... 33
29. #1 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 34
30. #2 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 35
31. #3 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 36
32. #4 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 37
33. #5 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 38
34. #6 Fuel Oil (F2 to F4 Chromatogram) …................................................................................................................................. 39
2
35. Transformer Oil (F2 to F4 Chromatogram) ……..................................................................................................................... 40
36. Hydraulic Oil (F2 to F4 Chromatogram) ….............................................................................................................................. 41
37. Motor Oils, various grades (F2 to F4 Chromatogram) …....................................................................................................... 42
38. Asphalt (F2 to F4 Chromatogram) ……................................................................................................................................... 43
39. Creosote (F2 to F4 Chromatogram) ….................................................................................................................................... 44
40. Corn Oil (F2 to F4 Chromatogram) …….................................................................................................................................. 45
41. Pine Needle Oil (F2 to F4 Chromatogram) …......................................................................................................................... 46
42. Peat (F2 to F4 Chromatogram) ……........................................................................................................................................ 47
43. Prudhoe Bay Crude (F1 Chromatogram) …........................................................................................................................... 48
44. Prudhoe Bay Crude (F2 to F4 Chromatogram) ….................................................................................................................. 49
45. Exxon Mobil South Venture Crude (F2 to F4 Chromatogram) …......................................................................................... 50
46. Hibernia Crude (F1 Chromatogram) …................................................................................................................................... 51
47. Hibernia Crude (F2 to F4 Chromatogram) …......................................................................................................................... 52
48. South Louisiana Crude (F1 Chromatogram) …..................................................................................................................... 53
49. South Louisiana Crude (F2 to F4 Chromatogram) …........................................................................................................... 54
Part B – Chromatogram Overlays and Comparisons ...................................................................................................................... 55
1. Comparing Leaded, Unleaded and Aviation Gasoline (F2 to F4 Chromatogram) …....................................................... 56 2. Comparing Unleaded Gasoline and #2 Diesel / Fuel Oil (F1 Chromatogram) ….............................................................. 57 3. Comparing Unleaded Gasoline and #2 Diesel / Fuel Oil (F2 to F4 Chromatogram) ….................................................... 58 4. Comparing Kerosene and Unleaded Gasoline (F2 to F4 Chromatogram) ………........................................................... 59 5. Comparing Aviation Fuel and Turbine Jet Fuel (F2 to F4 Chromatogram) ………….......................................................60 6. Comparing #2 Diesel & #2 Fuel Oil (F2 to F4 Chromatogram) ………................................................................................ 61 7. Comparing Unleaded Gasoline, #2 Diesel / Fuel Oil and 10W30 Motor Oil (F2 to F4 Chromatogram) ………………..62 8. Comparing Hydraulic and 10W30 Motor Oil .......................................................................................................................... 63 9. Comparing #2 Diesel / Fuel Oil, 10W30 Motor Oil and Asphalt (F2 to F4 Chromatogram) .............................................. 64 10. Comparing 10W30 Motor Oil, Asphalt and Peat (F2 to F4 Chromatogram) ...................................................................... 65 11. Comparing #2 and #3 Fuel Oil (F2 to F4 Chromatogram) .................................................................................................... 66 12. Comparing #5 and #6 Fuel Oil (F2 to F4 Chromatogram) .................................................................................................... 67 13. Comparing fresh to water-washed Gasoline (F2 to F4 Chromatogram) ........................................................................... 68 14. Comparing fresh to water-washed Diesel (F2 to F4 Chromatogram) ................................................................................ 69
If you have a sample of the product you are trying to confirm/negate the presence of, please submit it for analysis and comparison.
For more information about Petroleum Hydrocarbon analyses, please contact your project or account manager.
3
PETROLEUM HYDROCARBON REFERENCE
Natural Gas,
Solvents, LNG
�2 4
High Mobility Low Mobility
Diesel, Gas Oil, Furnace Oil
Gasolines Motor Oil, Lubricating Oils & Greases
Kerosenes Waxes, Heavy Fuel Oils, Road Oils, Asphalts
I I I I I 6 8 10 12 14 16 18 20 22 24 26 28 30 32 34 36 38 40 42 44 46
�
Bio enics
;.J.,J,.t-Jlli-iik
Purgeable HC by P&T or HSA
�2 4 6 8 10 12 14
Extractable Hydrocarbons by GC
SWOG, Oil & Grease
I I I I I I I I I I I I I 16 18 20 22 24 26 28 30 32 34 36 38 40
Number of Carbon Atoms
42 44 46
4
TYPICAL CARBON RANGES
5
PART A INDIVIDUAL CHROMATOGRAMS
This section contains representative Gas Chromatograph Flame Ionization Detection (GC/FID) chromatograms of a wide range of petroleum hydrocarbon products plus some naturally occurring organics. These chromatograms were generated in Bureau Veritas Laboratories by dilution of pure product and injection into the GC/FID. For products that contain a significant portion of volatile organic compounds, a chromatogram of a volatile scan (Headspace GC/FID) is included. (These are labelled ”F1 Chromatogram”).
There are usually two chromatograms for each product. In some cases, the first has an extended run time (labelled “Enhanced”) to provide enhanced peak resolution. In others, the first is the Headspace GC/FID scan. The second is always the routine extractable hydrocarbon scan with overlain hydrocarbon markers at C10 C16 C34 and C50. Most of the product descriptions are self-explanatory, however a few less common ones are defined below.
Stoddard Solvent: A petroleum distillate mixture of C7 – C12 hydrocarbons with a boiling range of 150 – 200°C. It is used to thin paints, in coatings, waxes, inks, for dry cleaning, degreasing, industrial cleaning and in herbicides. Stoddard solvent is a type of mineral spirits.
Condensate: In general, gas condensate has a specific gravity ranging from 0.5 – 0.8, and is composed of hydrocarbons such as propane, butane, pentane, hexane, etc. These are separated (condensed) from raw natural gas which is 80% – 90% methane and ethane. A major use of condensate is as a diluent for bitumen to produce diluted bitumen (dilbit) which has a low enough viscosity to be transported through pipelines.
Turpentine: A fluid obtained by the distillation of resin from live trees, mainly pines. It is mainly used as a solvent and as a source of materials for organic synthesis. Turpentine is composed of terpenes, mainly the monoterpenes alpha-pinene and beta-pinene with lesser amounts of carene, camphene, dipentene, and terpinolene.
Varsol: A petroleum-derived clear liquid used as a common organic solvent in painting. A mixture of aliphatic, open-chain or alicyclic C7 – C12 hydrocarbons, Varsol is insoluble in water and is used as an extraction solvent, as a cleaning solvent, as a degreasing solvent and as a solvent in aerosols, paints, wood preservatives, lacquers, varnishes, and asphalt products.
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
100000
200000
300000
400000
500000
600000
700000
800000
900000
C10 C16 C34 C50
6
TURPENTINE
2.00 3.00 4.00 5.00 6.00 7.00
0
100000
200000
300000
400000
500000
600000
700000
800000
900000
C10 C16
7
TURPENTINE (ENHANCED)
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
5000000
5200000
5400000
5600000
5800000
Time
Response_
MINERAL SPIRITS
8
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
50000
100000
150000
200000
250000
300000
350000
C10 C16 C34 C50
9
MINERAL SPIRITS
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
750000
800000
850000
900000
950000
Time
Response_
STODDARD SOLVENT
10
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
50000
100000
150000
200000
250000
300000
350000
400000
450000
C10 C16 C34 C50
11
STODDARD SOLVENT
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
5000000
5200000
5400000
5600000
5800000
6000000
Time
Response_
VARSOL
12
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.000
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
1.25e+07
1.3e+07
1.35e+07
Time
C10 C16 C34 C50
13
VARSOL
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50100000
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
750000
800000
850000
900000
950000
1000000
1050000
1100000
1150000
Time
Response_
CONDENSATE
14
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
750000
800000
850000
Time
UNLEADED GASOLINE
15
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000 C10 C16 C34 C50
16
UNLEADED GASOLINE
2.00 3.00 4.00 5.00 6.00 7.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000C10 C16
17
UNLEADED GASOLINE (ENHANCED)
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000
130000C10 C16 C34 C50
18
LEADED GASOLINE
2.00 3.00 4.00 5.00 6.00 7.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000
130000C10 C16
19
LEADED GASOLINE (ENHANCED)
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000C10 C16 C34 C50
20
RFA GASOLINE
2.00 3.00 4.00 5.00 6.00 7.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000C10 C16
21
RFA GASOLINE (ENHANCED)
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
C10 C16 C34 C50
22
AVIATION FUEL (AV GAS)
2.00 3.00 4.00 5.00 6.00 7.00
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
C10 C16
23
AVIATION FUEL (AV GAS) ENHANCED
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
50000
100000
150000
200000
250000
300000
350000
C10 C16 C34
24
KEROSENE
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
240000
260000
280000
C10 C16 C34
25
TURBINE JET FUEL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
C10 C16 C34
26
#1 DIESEL
3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
140000
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
500000
520000
540000
560000
580000
600000
620000
640000
660000
680000
700000
720000
740000
760000
Time-->
27
#2 DIESEL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000C10 C16 C34
28
#2 DIESEL
2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
100000
120000
140000
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
500000
520000
540000
560000
580000
600000
620000
640000
660000
Time
Response_
B20 BIODIESEL
29
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
100000
200000
300000
400000
500000
600000
700000
800000
900000
1000000
1100000
1200000
1300000
1400000
1500000
1600000
1700000
1800000
1900000
2000000
2100000
2200000
2300000
2400000
2500000
2600000
2700000
2800000
Time
Response_C10 C16 C34
30
B20 BIODIESEL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000 C10 C16 C34
31
ARCTIC DIESEL
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.000
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
1e+07
1.05e+07
1.1e+07
1.15e+07
1.2e+07
1.25e+07
1.3e+07
Time
C10 C16 C34
32
WINTER DIESEL
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
750000
800000
850000
900000
950000
1000000
1050000
1100000
1150000
1200000
1250000
1300000
1350000
1400000
1450000
Time
C10 C16 C34
33
WEATHERED DIESEL / FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
240000
260000
280000
C10 C16 C34
34
#1 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
C10 C16 C34
35
#2 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00
0
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
240000
260000C10 C16 C34
36
#3 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
C10 C16 C34 C50
37
#4 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
C10 C16 C34 C50
38
#5 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
C10 C16 C34 C50
39
#6 FUEL OIL
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.500
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
Time
C10 C16 C34 C50
40
TRANSFORMER OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
0
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
C10 C16 C34 C50
41
HYDRAULIC OIL
42
MOTOR OILS, VARIOUS GRADES
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.001000
2000
3000
4000
5000
6000
7000
8000
9000
10000
11000
12000
13000
14000
15000
16000
17000
18000
19000
20000
21000
22000
23000
24000
25000
26000
27000
28000
29000
30000
31000
32000
10W30
15W4020W50
C10 C16 C34 C50
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.000
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
32000
34000
36000
38000
40000
42000
44000
46000
48000
50000
52000
54000
56000
58000
C10 C16 C34 C50
OT (SS)
43
ASPHALT
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.500
1000000
2000000
3000000
4000000
5000000
6000000
7000000
8000000
9000000
1e+07
1.1e+07
1.2e+07
1.3e+07
1.4e+07
1.5e+07
1.6e+07
1.7e+07
1.8e+07
1.9e+07
2e+07
2.1e+07
2.2e+07
2.3e+07
2.4e+07
2.5e+07
2.6e+07
2.7e+07
Time
C10 C16 C34 C50
44
CREOSOTE
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.000
500000
1000000
1500000
2000000
2500000
3000000
3500000
4000000
4500000
5000000
5500000
6000000
6500000
7000000
7500000
8000000
8500000
9000000
9500000
Time
C10 C16 C34 C50
45
CORN OIL
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.500
2000000
4000000
6000000
8000000
1e+07
1.2e+07
1.4e+07
1.6e+07
1.8e+07
2e+07
2.2e+07
2.4e+07
2.6e+07
2.8e+07
3e+07
3.2e+07
3.4e+07
3.6e+07
3.8e+07
4e+07
4.2e+07
4.4e+07
4.6e+07
4.8e+07
5e+07
5.2e+07
5.4e+07
5.6e+07
5.8e+07
Time
C10 C16 C34 C50
46
PINE NEEDLE OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00
1000
1500
2000
2500
3000
3500
4000
4500
5000
5500
6000
6500
7000
7500
8000
8500
9000C10 C16 C34 C50
OT (SS)
47
PEAT
4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
120000
140000
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
500000
Time
Response_
PRUDHOE BAY CRUDE
48
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00
100000
200000
300000
400000
500000
600000
700000
800000
900000
1000000
1100000
1200000
1300000
1400000
1500000
1600000
1700000
Time
Response_
C50C34C16C10
49
PRUDHOE BAY CRUDE
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
5000000
5200000
5400000
5600000
5800000
Time
C10 C16 C34 C50
50
EXXON MOBIL SOUTH VENTURE CRUDE
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
100000
110000
120000
130000
140000
150000
160000
170000
180000
190000
200000
210000
220000
230000
240000
250000
260000
270000
280000
290000
300000
310000
320000
Time
Response_
HIBERNIA CRUDE OIL
51
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
4400000
4600000
4800000
Time
C10 C16 C34 C50
52
HIBERNIA CRUDE
3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
100000
110000
120000
130000
140000
150000
160000
170000
180000
190000
200000
210000
220000
230000
240000
250000
260000
270000
280000
290000
300000
310000
320000
Time
Response_
SOUTH LOUISIANA CRUDE OIL
53
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.000
200000
400000
600000
800000
1000000
1200000
1400000
1600000
1800000
2000000
2200000
2400000
2600000
2800000
3000000
3200000
3400000
3600000
3800000
4000000
4200000
Time
C10 C16 C34 C50
54
SOUTH LOUISIANA CRUDE OIL
PART B CHROMATOGRAM OVERLAYS
AND COMPARISONS
This section contains overlays of selected individual chromatograms from Part A.
55
2.00 3.00 4.00 5.00 6.000
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
70000
75000
80000
85000
90000
95000
100000
105000
110000
115000
120000
125000
130000
135000
140000
145000
150000
155000
LEADED GASOLINE
UNLEADED GASOLINE
AVIATION FUEL
56
COMPARING LEADED, UNLEADED & AVIATION GASOLINE
3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50
150000
200000
250000
300000
350000
400000
450000
500000
550000
600000
650000
700000
750000
800000
850000
900000
950000
1000000
1050000
1100000
1150000
1200000
1250000
1300000
1350000
1400000
1450000
Time
UNLEADED GASOLINE (F1 FRACTION)
#2 DIESEL / FUEL OIL (F1 FRACTION)
57
COMPARING UNLEADED GASOLINE & #2 DIESEL
2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.50 12.000
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
32000
34000
36000
38000
40000
42000
44000
46000
48000
50000
52000
54000
56000
58000
60000
62000
64000C10 C16 C34
#2 DIESEL
UNLEADED GASOLINE
58
COMPARING UNLEADED GASOLINE & #2 DIESEL
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.500
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
70000
75000
80000
85000
90000
95000
100000C10 C16 C34
KEROSENE
UNLEADED GASOLINE
59
COMPARING KEROSENE & UNLEADED GASOLINE
1.50 2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.500
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000
130000
140000
150000
160000
170000
180000
190000
200000
210000
220000
230000
240000
250000
260000
270000
280000
290000
300000C10 C16 C34
TURBINE JET FUEL
AVIATION FUEL
60
COMPARING AVIATION FUEL & TURBINE JET FUEL
2.00 2.50 3.00 3.50 4.00 4.50 5.00 5.50 6.00 6.50 7.00 7.50 8.00 8.50 9.00 9.50 10.00 10.50 11.00 11.500
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
C10 C16 C34
#2 FUEL OIL
#2 DIESEL
61
COMPARING #2 DIESEL & #2 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.000
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
70000
75000
80000
85000
90000
95000
100000
105000
110000 C10C16 C34
#2 DIESEL
UNLEADED GASOLINE
C50
10W30 MOTOR OIL
62
COMPARING UNLEADED GASOLINE, #2 DIESEL & 10W30 MOTOR OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.000
2000
4000
6000
8000
10000
12000
14000
16000
18000
20000
22000
24000
26000
28000
30000
32000
34000
36000
38000
40000
42000
44000
46000 C10 C16 C34
10W30 MOTOR OIL
HYDRAULIC OIL
C50
63
COMPARING HYDRAULIC & 10W30 MOTOR OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.000
5000
10000
15000
20000
25000
30000
35000
40000
45000
50000
55000
60000
65000
70000
75000
80000
85000
90000
95000
100000
105000
110000
115000
120000
125000
130000
135000
140000
145000
150000
155000 C10 C16 C34
10W30 MOTOR OIL
#2 FUEL OIL
C50
ASPHALT
64
COMPARING #2 DIESEL, 10W30 MOTOR OIL & ASPHALT
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.00
1000
1500
2000
2500
3000
3500
4000
4500
5000
5500
6000
6500
7000
7500
8000
8500
9000
9500
10000
10500
11000
11500
12000
12500
13000
13500
14000
14500
15000
15500 C10 C16 C34 C50
PEAT SAMPLE
10W30 MOTOR OIL
ASPHALT
65
COMPARING 10W30 MOTOR OIL, ASPHALT & PEAT
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.000
20000
40000
60000
80000
100000
120000
140000
160000
180000
200000
220000
240000
260000
280000
300000
320000
340000
360000
380000
400000
420000
440000
460000
480000
#2 FUEL OIL
#3 FUEL OIL
66
COMPARING #2 & #3 FUEL OIL
2.00 3.00 4.00 5.00 6.00 7.00 8.00 9.00 10.00 11.00 12.00 13.00 14.00 15.00 16.00 17.00 18.000
10000
20000
30000
40000
50000
60000
70000
80000
90000
100000
110000
120000
130000
140000
150000
160000
170000
180000
190000
#5 FUEL OIL
#6 FUEL OIL
67
COMPARING #5 & #6 FUEL OIL
1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00 2.10 2.20 2.30 2.40 2.50 2.60 2.70 2.80 2.90 3.00 3.10 3.20 3.30 3.40 3.50 3.60 3.700
5000000
1e+07
1.5e+07
2e+07
2.5e+07
3e+07
3.5e+07
4e+07
4.5e+07
5e+07
5.5e+07
6e+07
6.5e+07
7e+07
7.5e+07
Time
Response_
FRESH GASOLINE
WATER WASHED GASOLINE (1:1 WATER)
COMPARING FRESH TO WATER-WASHED GASOLINE
68
1.20 1.40 1.60 1.80 2.00 2.20 2.40 2.60 2.80 3.00 3.20 3.40 3.60 3.80 4.00 4.20 4.40 4.60 4.80 5.00 5.20 5.40 5.60 5.80 6.00 6.20 6.40 6.60 6.800
2e+07
4e+07
6e+07
8e+07
1e+08
1.2e+08
1.4e+08
1.6e+08
1.8e+08
2e+08
2.2e+08
2.4e+08
2.6e+08
2.8e+08
3e+08
3.2e+08
Time
Response_
FRESH DIESEL
WATER WASHED DIESEL (1:1 WATER)
COMPARING FRESH TO WATER-WASHED DIESEL
69
