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Class 18 Solar Energy

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1 Class 18 Solar Energy Many kinds of Solar Energy available to us With different benefits and costs Solar can heat and produce electricity, and dry things out (desiccant – to be used for refrigeration) http://www.eere.energy.gov/consumer/your_home/designing_remodeling/index.cfm/mytopic=10270 D. Long, PSc 320 2008 Summer or Winter? 2 x 23.5º = 47º Solar Thermal: For heated water or circulated in house Concentrated Solar Power: CSP Photovoltaics… 4 kinds well address 1) Single Crystal Silicon – Expensive, not used much anymore 2) Polycrystalline Silicon – Most Popular 3) Thin Films – Up and Coming 4) HEPV Triple Junction Gallium Arsenide: >40%. $50,000 / m 2 … Used with Solar Concentrators It takes more energy to make the cells than they produce in their lifetime- No, Energy payback time ~ 1.5 years - Financial payback time ~ 7 years... Competitive?
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Class 18 Solar Energy

Many kinds of Solar Energy available to us With different benefits and costs Solar can heat and produce electricity, and dry things out (desiccant – to be used for refrigeration)

http://www.eere.energy.gov/consumer/your_home/designing_remodeling/index.cfm/mytopic=10270

D. Long, PSc 320 2008

Summer or Winter?

2 x 23.5º = 47º

Solar Thermal: For heated water or circulated in house Concentrated Solar Power: CSP

Photovoltaics… 4 kinds we’ll address 1) Single Crystal Silicon – Expensive, not used much anymore 2) Polycrystalline Silicon – Most Popular 3) Thin Films – Up and Coming 4) HEPV Triple Junction Gallium Arsenide: >40%.

$50,000 / m2 … Used with Solar Concentrators “It takes more energy to make the cells than they produce in their lifetime”

- No, Energy payback time ~ 1.5 years - Financial payback time ~ 7 years... Competitive?

2

41% achieved in laboratory Photosynthesis?

Efficiency: 0.3 % Combustion is also inefficient

We don’t have the land and water to provide the world with energy this way. Can we artificially improve the efficiency?

Radiant energy => chemical potential energy

CuInGaSe2

LEDs: semiconductors…. Like a diode, or a solar cell

•  Forward Bias p-n junction: •  Light is created by flowing current from

battery

-Si-

- - -Si-

- - -Si-

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-Si-

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- -

-Si-

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+ -B

- -

-P-

- -

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-Si-

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-B

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-P-

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-

“n”-Type

“p”-Type

Silicon “doping”

3

e

e

- + Electric Load

http://chuck-wright.com/SolarSprintPV/SolarSprintPV.html

www.polarpowerinc.com

Conventional p-n junction photovoltaic (solar) cell

Jenny Nelson, The Physics of Solar Cells, 2003.

e-

usable photo-voltage (qV)

Energy

e-

n-type p-type

ηmax = 32% heat loss

heat loss

h+

Voltage Gap

Wavelength (m)

1 eV 2 eV 3 eV

Lower energy

Single Junction limit: 32%

4

Multijunction cells

Grid

p

p

p

p

p n

n n

+ + ++

p n

p

p

n n

+ + ++

p n p n + + ++

Ge Substrate (0.67 eV)

GaAs (1.42 eV)

GaInP (1.90 eV)

AlInP

AlGaInP

GaInP

GaInP

n GaAs

GaAs:N:Bi (1.05 eV) GaAs:N:Bi

GaAs:N:Bi

n n

41% Efficiency achieved in laboratory Costs are estimated at $50,000/m2, so concentrators must be used.

Traditional Thin Film Solar Cells

CIGS (CuInGaSe2) World record: 19.5 % Stable Is there enough Indium left? amorphous Si World record: 12.1 % not completely stable CdTe World record: 16.5 % Stable Cd is toxic

A thin film of semiconductor is deposited by low cost methods. Less material is used. Cells can be flexible and integrated directly into roofing material.

Roll-to-Roll coating: A route to taking the costs below $50/m2

and keeping efficiency > 10 %.

P. Fairley, IEEE Spectrum. Jan. 2004 p.28

Nanosolar “A New Day Dawning? Silicon Valley Sunrise,” Nature 443, September 7, 2006, p. 19. Cheap, Fast, High Efficiency (~19%)

Cost of Indium

5

Conjugated polymers

CuPc

Abundant: > 70,000 tons/year Non-toxic Low-cost: ~1$/g 17¢/m2

Stable

Peter Peumans (Stanford Electrical Engineering)

Conjugated (semiconducting) molecules

Copper Phthalocyanine,

Organic LED Displays Organic LED Lighting

Electronic Paper w/ polymer backplane

GE

A New Generation of Low-Cost Organic Electronics

Organic Solar Cells

Konarka

Polymer Vision’s Readius

GE

Source: Johnson (2002) and Dunay (2003)

1976

PR=0.80R2 = 0.99

$1

$10

$100

0 1 10 100 1,000 10,000

cumulative PV production (GWp)

Who

lesa

le p

rice

(200

2$/W

p)

2002

Photovoltaic Cost Decreases

Moore’s Law of Technology Improvement

$2 per Watt

First Solar: CdTe (Cadmium Telluride) Thin Film

10.4 % efficiency Big big: Carrizo Plain, 550 MW

Cost ($/W) Cell $1.00 Making the module $0.00 Inverter $0.50 Retro fit installation $4-5.00 TOTAL $6

Home Installation more expensive than in Desert

Inverter: Converts HV DC to Grid AC


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