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Class 18 Solar Energy
Many kinds of Solar Energy available to us With different benefits and costs Solar can heat and produce electricity, and dry things out (desiccant – to be used for refrigeration)
http://www.eere.energy.gov/consumer/your_home/designing_remodeling/index.cfm/mytopic=10270
D. Long, PSc 320 2008
Summer or Winter?
2 x 23.5º = 47º
Solar Thermal: For heated water or circulated in house Concentrated Solar Power: CSP
Photovoltaics… 4 kinds we’ll address 1) Single Crystal Silicon – Expensive, not used much anymore 2) Polycrystalline Silicon – Most Popular 3) Thin Films – Up and Coming 4) HEPV Triple Junction Gallium Arsenide: >40%.
$50,000 / m2 … Used with Solar Concentrators “It takes more energy to make the cells than they produce in their lifetime”
- No, Energy payback time ~ 1.5 years - Financial payback time ~ 7 years... Competitive?
2
41% achieved in laboratory Photosynthesis?
Efficiency: 0.3 % Combustion is also inefficient
We don’t have the land and water to provide the world with energy this way. Can we artificially improve the efficiency?
Radiant energy => chemical potential energy
CuInGaSe2
LEDs: semiconductors…. Like a diode, or a solar cell
• Forward Bias p-n junction: • Light is created by flowing current from
battery
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+ -B
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“n”-Type
“p”-Type
Silicon “doping”
3
e
e
- + Electric Load
http://chuck-wright.com/SolarSprintPV/SolarSprintPV.html
www.polarpowerinc.com
Conventional p-n junction photovoltaic (solar) cell
Jenny Nelson, The Physics of Solar Cells, 2003.
e-
usable photo-voltage (qV)
Energy
e-
n-type p-type
ηmax = 32% heat loss
heat loss
hν
h+
Voltage Gap
Wavelength (m)
1 eV 2 eV 3 eV
Lower energy
Single Junction limit: 32%
4
Multijunction cells
Grid
p
p
p
p
p n
n n
+ + ++
p n
p
p
n n
+ + ++
p n p n + + ++
Ge Substrate (0.67 eV)
GaAs (1.42 eV)
GaInP (1.90 eV)
AlInP
AlGaInP
GaInP
GaInP
n GaAs
GaAs:N:Bi (1.05 eV) GaAs:N:Bi
GaAs:N:Bi
n n
41% Efficiency achieved in laboratory Costs are estimated at $50,000/m2, so concentrators must be used.
Traditional Thin Film Solar Cells
CIGS (CuInGaSe2) World record: 19.5 % Stable Is there enough Indium left? amorphous Si World record: 12.1 % not completely stable CdTe World record: 16.5 % Stable Cd is toxic
A thin film of semiconductor is deposited by low cost methods. Less material is used. Cells can be flexible and integrated directly into roofing material.
Roll-to-Roll coating: A route to taking the costs below $50/m2
and keeping efficiency > 10 %.
P. Fairley, IEEE Spectrum. Jan. 2004 p.28
Nanosolar “A New Day Dawning? Silicon Valley Sunrise,” Nature 443, September 7, 2006, p. 19. Cheap, Fast, High Efficiency (~19%)
Cost of Indium
5
Conjugated polymers
CuPc
Abundant: > 70,000 tons/year Non-toxic Low-cost: ~1$/g 17¢/m2
Stable
Peter Peumans (Stanford Electrical Engineering)
Conjugated (semiconducting) molecules
Copper Phthalocyanine,
Organic LED Displays Organic LED Lighting
Electronic Paper w/ polymer backplane
GE
A New Generation of Low-Cost Organic Electronics
Organic Solar Cells
Konarka
Polymer Vision’s Readius
GE
Source: Johnson (2002) and Dunay (2003)
1976
PR=0.80R2 = 0.99
$1
$10
$100
0 1 10 100 1,000 10,000
cumulative PV production (GWp)
Who
lesa
le p
rice
(200
2$/W
p)
2002
Photovoltaic Cost Decreases
Moore’s Law of Technology Improvement
$2 per Watt
First Solar: CdTe (Cadmium Telluride) Thin Film
10.4 % efficiency Big big: Carrizo Plain, 550 MW
Cost ($/W) Cell $1.00 Making the module $0.00 Inverter $0.50 Retro fit installation $4-5.00 TOTAL $6
Home Installation more expensive than in Desert
Inverter: Converts HV DC to Grid AC