Classification of selected substances http://echa.europa.eu/web/guest/information-on-chemicals/cl-inventory-database
www.kemi.se
Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
1 143-33-9
2 117-81-7
3 67-56-1
4 57-27-2
5 7439-97-6
6 50-29-3
7 52645-53-1
8 7440-02-0
9 103-90-2
Codification of Hazard Pictograms
GHS01 GHS05 GHS03 GHS04
GHS06 GHS07 GHS08
GHS02
GHS09
Substance 1
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
1 143-33-9 Sodium cyanide Acute Tox. 2 Acute Tox. 1 Eye Dam. 1 Acute Tox. 2 Aquatic Acute 1 Aquatic Chronic 1
GHS05 GHS06 GHS09
H300 H310 H318 H330 H400 H410
No
Substance 2
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
2 117-81-7 DEHP Repr. 1B GHS08 H360FD Yes
Substance 3
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
3 67-56-1 Methanol Flam. Liq. 2 Acute Tox. 3 Acute Tox. 3 Acute Tox. 3 STOT SE 1
GHS02 GHS06 GHS08
H225 H301 H311 H331 H370
Yes
Substance 4
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
4 57-27-2 Morphine Acute Tox. 4 GHS07 H302 No
Substance 5
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
5 7439-97-6 Mercury Acute Tox. 2 Repr. 1B STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1
GHS06 GHS08 GHS09
H330 H360D H372 H400 H410
Yes
Substance 6
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
6 50-29-3 DDT Acute Tox. 3 Carc. 2 STOT RE 1 Aquatic Acute 1 Aquatic Chronic 1
GHS06 GHS08 GHS09
H301 H351 H372 H400 H410
Yes
Substance 7
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
7 52645-53-1 Permethrin Acute Tox. 4 Skin Sens. 1 Acute Tox. 4 Aquatic Acute 1 Aquatic Chronic 1
GHS07 GHS09
H302 H317 H332 H400 H410
Yes
Substance 8
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
8 7440-02-0 Nickel powder Skin Sens. 1 Carc. 2 STOT RE 1 Aquatic Chronic 3
GHS07 GHS08
H317 H351 H372 H412
Yes
Substance 9
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Substance CAS No Name Classification Pictogram(s) Hazard statement(s)
EU Harmonized C&L?
9 103-90-2 Paracetamol Acute Tox. 4 Aquatic Chronic 3
GHS07 H302 H412
No
Hazard communication Exercises
• Pretend that you are an inspector visiting a manufacturer/importer of chemical products
• You are there to find out if the company is in compliance with GHS when it comes to hazard information given in labels and SDS
• Check for incompliances for these 3 products, Aldicarb, Sodium Fluoroacetate, Phosphine
Exercise 1-is this label correct? Use criteria given in SDS
• SDS information
• 11. Toxicological information Acute toxicity Oral 40 mg/kg bw Dermal 500 mg/kg bw Inhalation (mist) 0,25 mg/L
• 12. Ecological information Acute LC50 (fish) 150 mg/L EC 50 (algea) 0,5 mg/L Chronic NOEC (fish) 0,03 mg/L Non rapidly degradable
• ALDICARB (CAS nr: 116-06-3)
• Fatal if swallowed
• Very toxic to aquatic life with long lasting effects
Exercise 2-is this label correct? Use criteria given in SDS
• SDB information
• 11. Toxicological information Acute toxicity Oral 8 mg/kg bw Dermal 30 mg/kg bw Inhalation (gas) 400 ppmV
• 12. Ecological information Acute LC50 (fish) 150 mg/L EC 50 (algea) 0,5 mg/L Chronic NOEC (fish) 1,35 mg/L Non rapidly degradable
•
• Sodium fluoroacetate (CAS nr: 62-74-8)
• Harmful if swallowed
WARNING
Exercise 3 – is this label correct, use EU Inventory
•
• Phosphine (CAS nr: 7803-51-2)
• Extremely flammable gas
Danger