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Co Injection

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    Co-injection ProcessTechnical Challenges and Solutions

    2012Moldex3D R11

    European

    Webinar

    Series

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    Current position:

    CoreTech System Technical Research Division

    Education:PhD in Polymer Science from the University of

    Connecticut

    Specialization:

    Polymer rheology, processing, and properties,polymer composite, biomedical materials,

    degradable polymers, and plastics applications

    in industrial design

    Dr. Sun has researched parenteral drug packaging in Eli Lilly and Company. He hasalso worked with Teleflex Medical to develop a fully absorbable bone graft composite.He is now a senior research engineer supporting the development of advancedinjection molding CAE software and also in charge of material testing and measurement

    in Coretech System company.

    Shih-Po Sun, Ph.D.

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    Contents

    > Part 1:

    Introduction to co-injection molding

    Product common defects and solutions

    Product development through CAE

    > Part 2:

    Case study 1: Earphone hookMeeting product spec how to resolve unwanted warpage

    Case study 2: Car door panel

    Prioritize gate location for ideal filling pattern

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    Multi-material injection

    Also called multi-component injection molding (MCM)

    Processes of combining different material qualities and

    properties in one component.

    PP

    TPVPC

    In-mold assemblyCo-injection

    PP

    EVOH

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    Multi-material injection family

    Multi-material processes

    Multi-component

    Bi-injection

    Co-injection

    (Sandwich)

    Multi-shot

    Rotating tool

    Core back

    Transfer

    Over-molding

    Insert

    Lost core

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    Skin / core combinations

    Handle, lever : Computer housing:

    Soft feel skin / hard core Unfilled skin / core with conductive filler

    Garden furniture: Yogurt pot:

    Virgin skin / recycled core Pigmented skin / uncolored core

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    Stages

    Step 1

    Empty cavity1st shot (skin): blue2nd shot (core): yellow

    Step 2

    Skin injection

    Step 3Core injection

    Step 4Second skininjection for

    1-2-1 structure

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    Todays objective - aesthetics

    Structural product: co-injection is preferred toconventional structural foam or fiber reinforced plastics

    because of its superior surface finish.A solid skin combined with a structural foam coreprovides the advantages such as low molded-in stress,sink-free parts without the skin surface defects

    Quality surface is obtained in fiber reinforced plasticssince the fiber-loaded material is restricted in the core ofthe part.

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    Todays objective - property combination

    Combined properties: one can achieve a combination ofproperties not available in a single resin by combining

    different materials.For instance:

    An elastomeric skin over a rigid core will provide astructure with a soft touch.

    A brittle material can be encased by a material of highimpact resistance or high ductility.

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    Sustainability

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    > Recycled core reduces costs

    > Recycled core reuses waste

    > Engineering core structure, e.g. fiber

    foaming, enhances product strength or

    performance

    > Virgin skin provides quality aesthetic

    finish for recycled or engineering core

    > Elastomer skin improves surface touch

    > No increase on cycle times comparing to

    sequential or multi-component molding

    Benefits of using co-injection molding

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    Important processing considerations

    > Strength Material adhesion

    > Skin / core distribution Flow characteristics

    > Specification Shrinkage / Warpage

    > Performance Material selection

    Related processing conditions:

    Material properties, injection rate, skin-core transition ratio,

    skin/core temperature and packing pressure

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    Machine design - nozzle

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    Machine design hot runner

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    Machine design multiple gate

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    Process Co-Injection Bi-Injection Insert Molding Over Molding Multi-Shot

    Interface

    Controllability Poor

    Poor

    Good

    Good

    Good

    # of Nozzles 1 n 1 n n

    # of Materials 2 2 2 2 2

    Mold Complexity Low Low Low Medium High

    PartComplexity

    Simple Very simple Medium High Very high

    Use ofPreforms

    No No Yes No No

    Source: http://www.isr.umd.edu

    Multi-Material Molding ProcessComparisons

    interface depends on the laminar flow of materials interface is controlled by the mold geometryn the number of separate materials being used

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    How to turn single shot machine into aco-injection one?

    Source: Krauss Maffei

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    Co-injection machine design - Melt

    Milacron

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    Co-injection machine design Mold

    Meiki

    Master Mold Plate US patent 6196822

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    Co-injection machine design - Screw

    Spirex Twinshot

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    Source: Engel

    Material compatibility

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    Material Properties

    Viscosity f( , T, P, ) Volume f(T, P)&

    Heat conductivity f(T) Heat capacity f(T)

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    Relationship

    between and u

    or viscosity,

    Thermal conductivity, kHeat capacity, Cp

    Temperature-pressure dependent volume, V(T, P)

    Modulus, G

    ( ) 0=+

    u

    t

    Mass balance

    Energy balance

    &: =

    + TkTtTCp u

    Momentum balance

    gpDt

    D +=

    u

    CAE procedureThermoset conversion balance

    0=++ RjX&

    Density,

    Conversion rate,R

    Flow behavior

    Cooling, warpage analysis

    Equations to describe melt flow

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    Important questions

    How does my change of design affectthe skin/core distribution?

    What is my flow orientation for thecore layer? If the core is fiber filled.

    Where is the area with high stress andtemperature?

    How does the core layer affect overallwarpage?

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    Skin / core evolution

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    > Two materials can only be processed successfully by co-injection molding if their processing properties match.

    Previous studies have suggested that the core/skinviscosity ratio should be between 0.5 and 5.

    > Lower viscosity ratios would lead to breakthrough ofcore material.

    > Higher viscosity ratios would lead to poor mold filling,finger like defects and a variable core thickness throughthe part.

    Gomes, 2011, Polym Eng. Sci.

    Viscosity limitations of 2 materials

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    Effect of viscosity ratio

    Yottha Srithep, 2008

    viscous

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    Higher

    Lower

    2nd

    shotviscosity

    co

    mparedto1stshot

    Skin-core ratio (1st shot volume / total volume)

    80% 70% 60%

    A

    B

    Material: PC

    Effect of viscosity ratio

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    Injection rate effect

    Yottha Srithep, 2008

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    Injection rate effect

    Skin injection speed constantCore injection speed

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    Material break through

    Source: C-Mold

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    Core filling ratio

    Vcore/Vtotal

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    Material break through prediction

    Two opposing forces: viscosity vs. filling ratioLess viscous core requires higher skin filling ratio to prevent break through.

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    Controlled break out technique

    Lattoflex, Winx300

    IF 99 design award

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    Break through simulation

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    Cornering effect

    > Uneven distribution, uneven thickness

    Flow around corners must be considered indesign phase to prevent thin inside corners.

    Use a generous radius.

    Source: Gas-assist injection molding:principles and applications

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    Flow

    behaviorPartdesign

    Processingcondition

    Materialselection

    Mold

    design

    Design considerations

    Quality

    product

    Material distribution vs. Design criteria?

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    Questions

    If I want to

    Which design change is possible?

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    Benefit of CAE

    CAE is a must in predicting the spatial distribution of core and skin.

    General knowledge is difficult to predict the simultaneous flow of two

    materials.

    Knowing the melt front evolution of both shots, CAE can:

    Evaluate the flow front pattern to aid in part design and gate placement

    Predict the extent of penetration of the core material and the skinbreakthrough point

    Determine injection pressure and clamping force for proper moldingmachine selection

    Determine the best switch point from skin injection to core injection

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    Benefits of Moldex3D

    Moldex3D can help users in all aspects of co-injection molding

    process:

    > For mold design, locate the optimum gate locations

    > For cost reduction, evaluate the maximum core ratio without

    causing break through.

    > For structural analysis, provide skin thickness distribution.

    > For quality control, pinpoint potential locations with high

    temperature and stress.

    > For spec requirement, precisely estimate shrinkage and

    warpage concerning the interaction between skin and core

    material.

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    Case Study 1: Earphone hook

    > The hook connects to the phone and mic assembly.

    > The hook design has a flexible skin to provide better feel oftouch in contact with the ear.

    > The hook should have enough stiffness to withstanddeformation.

    > The hook dimension should meet specification.

    O i i l i l d i

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    Original sequential design

    PP

    TPE

    U i i j ti

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    Using co-injection process

    Benefit:

    > The co-injection process provides ideal material

    combination of soft skin / hard core to meet designcriteria.

    Concern:

    > Part and process design to reach desired mechanicalstrength

    > Warpage due to imbalanced core distribution

    M lt f t l ti

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    Melt front evolution

    Skin ratio

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    Skin ratio

    90% 80%

    50%70%

    Break through occurred!

    Skin ratio

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    Skin ratio

    Cornering effect

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    Cornering effect

    Core travels toward

    inside of the corner

    Shrinkage X-axis direction

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    Shrinkage, X-axis direction

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    10

    Gate location design

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    Gate location design

    70% skin filling ratio

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    70% skin filling ratio

    Controlled break through

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    Controlled break through

    40% skin filling ratio

    0.07 sBreak through occurred

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    Skin ratio

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    Skin ratio

    Shrinkage, X-axis direction

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    g ,

    10

    Moldex3D FEA workflow

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    Element properties

    Structural simulationsoftware

    Material parameters

    Flow analysis

    +

    Structural analysis result

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    y

    B.C.Fixed locationaround the joint

    Load500g of force applied at the end

    Deformation results

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    Case study 2: door panel

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    > The size of the door panel requires multiple gate mold design.

    > The core amount should be maximized without surfacing.

    Using co-injection process

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    Benefit:

    > Co-injection integrates rigid and flexible components into

    a single molded structure with a single step.> The core should be completely contained within the

    flexible material.

    Concern:> Number and location of the gates to ensure balanced

    melt flow and material distribution

    > Warpage due to imbalanced core distribution

    Information

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    > Dimension

    > Dimension710476 mm

    > Thickness : 7 mm

    > Volume

    1660 c.c.

    > Material

    > Skin : TPO

    > Core : PP

    > Processing condition

    > Time (total): 5 s

    > Melt temperature: 260 C

    > Mold temperature: 40 C

    Hot Runner 12.0 8.0mm

    Gate Type : circularDiameter8 mm

    Single skin material filling

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    Skin /core material filling

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    Number of gates

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    5 gates, 60% skin ratio 6 gates, 60% skin ratio

    Increasing skin ratio

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    6 gates, 70% skin ratio 6 gates, 80% skin ratio

    Gate location modification

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    Gate contribution

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    Skin ratio

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    Clamping force

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    Skin in contact with the wall

    Volumetric shrinkage

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    Warpage, Y-direction

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    Conclusions

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    > Co-injection process brings design versatility to newlydesigned or existing products. While the transition to co-injection process from already own equipment is not

    difficult, optimizing part design and processingconditions to achieve desired material distribution poseschallenges.

    > CAE flow analysis is an indispensible tool providing

    complete solution for managers, designers, andengineers to fully control the outcome of their fiberreinforced plastic product.

    > Modules in Moldex3D work seamlessly together

    providing invaluable information throughout the entiredesign, manufacturing, and usage phases.

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    If you have questions, please type

    into the chat box.

    Contact Information

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    Dr. Sun

    [email protected]

    Dannick

    [email protected]

    Vincent

    [email protected]

    Next Webinar

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    TopicLatest Development in Long / Short Fiber Reinforced

    Plastics Applications, Processing Techniques and

    Simulation Technology

    Goals Lean how to estimate fiber orientations to gain strategic

    benefits by adopting CAE incorporated design.

    Have an overview on the design work flow from part geometryall the way to dimension accuracy and mechanical properties.

    Speed up your fiber product development with a clearer viewon most important design considerations and processingcontrols.

    Time

    9:00AM UTC -13 January,2012


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