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Comparison of Wood Preservatives in Stake Tests 2000 Progress Report United States Department of Agriculture Forest Service Forest Products Laboratory Research Note FPLRN02 Research Contributors, 1922–2000
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Page 1: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Comparison of Wood Preservatives in Stake Tests 2000 Progress Report

United States Department of Agriculture Forest Service Forest Products Laboratory Research Note FPL−RN−02

Research Contributors, 1922–2000

Page 2: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Abstract This report covers stake test results primarily from Southern Pine 2- by 4- by 18-in. sapwood, treated by pressure and nonpressure processes, and installed by Forest Products Laboratory employees and cooperators in decay and termite exposure sites at various times since 1938 at Saucier, Mississippi; Madison, Wisconsin; Bogalusa, Louisiana; Lake Charles, Louisiana; Jacksonville, Florida; and the Canal Zone, Panama. Also included in the tests at Saucier, Missis-sippi, are smaller pine stakes and those of treated and untreated plywood, particleboard, modified woods, laminated paper plastic, pine infected with Trichoderma mold, plus other selected wood species such as oak, Douglas-fir, and Engelmann spruce. Southern Pine untreated control stakes have had an average life of about 1 year in the Canal Zone, 1.8 to 3.6 years in Mississippi, Florida, and Louisiana, and about 6 years in Wisconsin. Superficial treatments by 3-min dipping and brushing with preservatives such as coal-tar creosote and petroleum oils containing copper naphthenate, zinc naphthenate, phenyl mercury oleate, and pentachlorophenol have added from a few months to 4 years to the life of the untreated stakes. When appropriate preservative retention levels are applied, creosote, pentachlorophenol, and selected waterborne salt preserva-tives give excellent service. In addition, this publication contains information regarding the future of the FPL treated-stake testing program.

Keywords: Preservatives, wood preservatives, pressure treated, nonpressure treated, Southern Pine, service life

Revised December 2002 Crawford, D.M.; Woodward, B. M.; Hatfield, C. A., comps. Comparison of wood preservatives in stake tests�2000 Progress Report. Res. Note FPL-RN-02. Madison, WI: U.S. Department of Agriculture, Forest Service, Forest Products Laboratory. 120 p.

A limited number of free copies of this publication are available to the public from the Forest Products Laboratory, One Gifford Pinchot Drive, Madison, WI 53726�2398. This publication is also available online at www.fpl.fs.fed.us. Laboratory publications are sent to hundreds of libraries in the United States and elsewhere.

The Forest Products Laboratory is maintained in cooperation with the University of Wisconsin.

The United States Department of Agriculture (USDA) prohibits discrimina-tion in all its programs and activities on the basis of race, color, national origin, sex, religion, age, disability, political beliefs, sexual orientation, or marital or familial status. (Not all prohibited bases apply to all programs.) Persons with disabilities who require alternative means for communication of program information (Braille, large print, audiotape, etc.) should contact the USDA�s TARGET Center at (202) 720�2600 (voice and TDD). To file a complaint of discrimination, write USDA, Director, Office of Civil Rights, Room 326-W, Whitten Building, 1400 Independence Avenue, SW, Wash-ington, DC 20250�9410, or call (202) 720�5964 (voice and TDD). USDA is an equal opportunity provider and employer.

Caution Crankcase oils may contain chlorinated naphthalenes, which have been reported to contribute to �X-disease� (hyperkeratosis) in cattle. These oils are therefore not recommended for preservative treatment of wood with which cattle may come in contact.

Pesticides can be injurious to humans, domestic animals, desirable plants, and fish or other wildlife if they are not handled or applied properly. Use all pesticides selectively and carefully. Follow rec-ommended practices for the disposal of surplus pesticides and pesticide containers.

This publication reports research-involving pesticides. It does not contain recommendations for their use, nor does it imply that the uses discussed have been registered. All uses of pesticides must be registered by appropriate State and/or Federal agencies before they can be recommended.

Acknowledgments This research note is a continuation of progress reports by the same title issued periodically from 1950 to 1962 as Report No. 1761 and as FPL�RN�02 since 1963. Several past and current Forest Prod-ucts Laboratory employees initiated the studies reported herein. These individuals are recognized in notes following the appropriate tables. The authors of this publication would like to express their appreciation to the Statistical Methods in Wood and Fiber Research and the Research Facilities Engineering staffs for their contribu-tions to the success of this publication.

Cover photos�Researchers involved in 80+ years of independent evaluation of the durability of preservative in field plots. (Research period in parentheses): (Upper left) Roy Baechler (1922�1970), Oscar Blue (1941�1970), Douglas Crawford (1970�present), Harley Davidson (1942�1979), Rodney DeGroot (1976�1999), Lee Gjovik (1961�1990), David Gutzmer (1960�1994), George Hunt (1919�1946), Bruce Johnson (1965�1994), John Kulp (1947�1967), Stan Lebow (1993�present), Ed Panek (1941�1968), Ray Wirka (1919�1942) and Bessie Woodward (1980�present).

Contents Page

Introduction........................................................................... 1

Preservatives and Modified-Wood Products Tested ............. 2 Selection and Treatment of Stakes....................................... 2 Installation and Inspection of Stakes ................................... 2 Results................................................................................... 3

Southern Pine and Plywood Stakes................................... 3 Modified-Wood Stakes ..................................................... 5

Future Research Program...................................................... 6 Units of Measure................................................................... 7 References............................................................................. 7

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Comparison of Wood Preservatives in Stake Tests 2000 Progress Report Compiled by D. M. Crawford, Forest Products Technologist B. M. Woodward, Microbiologist C. A. Hatfield, Statistician Forest Products Laboratory, Madison, Wisconsin Introduction For centuries wood has been one of the most common and easiest to use construction materials. It is used practically everywhere�in housing and agricultural buildings and as posts, utility and telephone poles, railroad ties, wharves, and piling. Wood is also a renewable material. Although we have consumed tremendous volumes of wood for centuries, the United States is growing more wood volume than it is har-vesting.

Wood is a biological material and as such it is subject to decay, insect, and marine borer attack. These agents are nature�s way of recycling wood in the natural ecosystem. Without nature�s recycling system, wood, and other cellu-lose-based materials, such as grass, leaves, and agricultural field residues, would literally bury us. However, when wood is used in a more or less permanent application, it must be protected from biological degradation. Destruction can be prevented by a number of individual methods or a combina-tion of methods.

Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine sapwood stakes treated with various wood preservatives is an effective method to test the protection provided against decay and termite attack. During 1938, the USDA Forest Service, Forest Products Laboratory (FPL), in cooperation with others, began treating test stakes of Southern Pine sapwood with several preservatives for installation at the Harrison Experimental Forest at Saucier, Mississippi. Repli-cate stakes were treated for installations at Madison, Wis-consin; Bogalusa, Louisiana; Jacksonville, Florida; and the Canal Zone, Panama. Since 1938, additional preservatives have been added to these tests, principally at the Saucier, Mississippi, station. Also installed at that station were stakes of treated and untreated modified-wood products, such as plywood, impreg, compreg, staypak, papreg, laminated acetylated wood, cyanoethylated wood, wood with thiamine destroyed, chemically modified wood, wood infected with

Trichoderma mold, embedded fiberboard (western hemlock strands in Portland cement), particleboard, and incised and unincised wood.

In 1967, another stake installation that included 11 standard wood preservatives was made in cooperation with the Wood Products Insect Laboratory, Gulfport, Mississippi, at Lake Charles, Louisiana. The area is infested by the destructive Formosan termite, Coptotermes formosanus, and stakes installed were used for comparison with the stakes at the Harrison Experimental Forest, in Saucier, Mississippi.

Stake tests are useful for screening out ineffective preserva-tive materials. Stake test results can be used to further ex-plore the preservative properties of materials that show promise in laboratory toxicity tests. However, limitations of these accelerated field tests must be recognized. Test results should not be considered as a substitute for actual service tests on full-size products such as ties, poles, or posts. Furthermore, results obtained in these stake tests are appli-cable only under the set of conditions existing in the particu-lar test. Factors such as exposure, preservative retention, preservative distribution, heartwood volume, and size (sur-face area in relation to total volume) influence the perform-ance of treated wood.

This publication is primarily a progress report on the condi-tion of the modified-wood products and stakes treated with various preservatives and oils at the time of the 1999 and 2000 inspections. The stake tests at Panama were completed with a final inspection in January 1956. Those at Jackson-ville were terminated in December 1960, and those at Boga-lusa in December 1958. Progress reports showing the condi-tion of the test stakes in 1947 and during the years 1949 to 1969, 1971, 1973, 1975, 1977, 1979, 1981, 1983, 1985, 1987, 1991, and 1995 have been published (Hunt and Sny-der 1930, Blew 1948). In addition, this publication contains information regarding the future of the FPL treated-stake testing program.

Page 4: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Preservatives and Modified-Wood Products Tested Table 1 lists the preservatives and products tested and notes existing preservative specifications in cases where specifica-tions have been issued. Table 1 also refers to Tables 2 to 76, in which test data are listed for the various materials. Formu-lations of treating solutions and descriptions of the various test materials are generally given in the tables. Complete information as to the source and composition of the various materials can, in most cases, be furnished upon request to the FPL.

Selection and Treatment of Stakes For the most part, the stakes were 2- by 4- in. (nominal) by 18-in. Southern Pine, uniformly seasoned, surfaced on four sides, and selected for freedom from heartwood, wane, objectionable knots, and other visible defects. Ten installa-tions included solid-sawn stakes of smaller size for compari-son purposes (Tables 6, 35, 37, 42, 45, 54, 56, 57, 59, 68). Before treatment, a number, either stamped on the ends or marked with lumber crayon, identified the stakes. The stakes of modified wood, with one or two exceptions, were 4 by 18 in. with variable thickness.

All preservative treatments were by pressure impregnation unless indicated. Waterborne preservatives were applied by using the full-cell process, unless noted. Preservative oils were applied by either empty-cell or full-cell methods (tolu-ene dilution), depending upon the retention level required. Complete penetration is desirable and usually noted in the pressure treatment used. For this reason, heartwood material was avoided in the Southern Pine stakes unless noted (Tables 5 and 51). In most cases, preservative retention levels were computed for individual stakes from the differ-ence in weight before and after treatment. Surplus preserva-tive was permitted to drain from the stakes before the final weight measurements were taken. Experience or exploratory treatments indicated the correct treating schedule or the treating solution concentration necessary to produce the desired preservative retention. Twenty 2- by 4-in. stakes were treated for each test variable, from which 10 acceptable stakes were selected for installation. By discarding those stakes with retention levels greater or less than desired, the 10 stakes selected by this procedure were usually found to have preservative retention levels within the desired 10% range. The stakes not acceptable for the test provided mate-rial for checking preservative penetrations. For stakes treated in liquefied petroleum gas (LPG) (Tables 42 and 45), it was impractical to follow this general procedure. These stakes were treated at a commercial plant in the presence of an FPL

representative, and retention levels were determined from the analysis of either sections of test stakes or additional matched stakes included for that purpose.

The test stakes were usually identified by a numbered metal tag nailed (riveted in the case of thin modified-wood prod-ucts) to the wide face approximately 2 in. from the top of the stake.

Installation and Inspection of Stakes The stakes at Madison, Wisconsin, and Saucier, Mississippi, were installed in plots by the randomized-block method (Fisher and Yates 1938). The stakes were set in the ground in an upright position with about half their length (9 in.) in the ground. The soil in the plot at the Harrison Experimental Forest, Saucier, Mississippi, is Poarch fine sandy loam, with 5% to 12% slope, a pH of 4.85, and an average annual rain-fall of 62 in. That area was partially cleared of trees, mostly scrub oak and gallberry with a few longleaf and slash pine, before the stakes were installed; the ground cover is now mostly wiregrass. Until late 1956, the Madison, Wisconsin, plot was located in an area of clay loam soil with a pH of 6.5 that was partially shaded by various hardwood trees and sumac, with an average annual rainfall of 31in. In October 1956, it was necessary to move the stakes to a new test plot near Madison with similar soil, but without the overstory of trees or shrubs. The soil at Bogalusa, Louisiana, is sandy loam, and that at Jacksonville, Florida, is sandy. Both plots are partially shaded. The plot at Lake Charles, Louisiana, is located on an open area partially covered with broom sedge and marsh grass. The top 10 in. of soil are sandy with some streaks of clay; underneath is heavy muck and a high water level.

The 1970, 1974, and 1984 inspections at Lake Charles, Louisiana, and the final inspection of stakes installed at the Canal Zone during January 1956 were made by representa-tives of the Wood Products Insect Laboratory, Gulfport, Mississippi, and the FPL. Representatives from the Chapman Chemical Company and the FPL did the final inspections of the stakes at Jacksonville and Bogalusa in 1960 and 1962, respectively. FPL representatives inspected the Madison and Saucier installations.

During these inspections, the stakes are removed individu-ally, scraped to facilitate inspection, examined, and returned to their original place unless their condition indicates re-moval. After examination, the stakes are given a numerical and letter rating according to the following decay and termite attack scale:

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Page 5: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

In 1985, field data were recorded using a portable computer. Until this time, the rating system was alpha�numeric. It was desirable to convert to a numeric�numeric rating system that would compare with the previous rating system and allow for some refinement. All ratings from 1991 to the present were made using the following rating scale:

Description of condition

Grade no.a Decay grades Termite grades

10 Sound. Suspicion of decay permitted

Sound. 1 to 2 small nibbles permitted

9 Trace decay to 3% of cross section

Slight evidence of feeding to 3% of cross section

8 Decay from 3% to 10% of cross section

Attack from 3% to 10% of cross section

7 Decay from 10% to 30% of cross section

Attack from 10% to 30% of cross section

6 Decay from 30% to 50% of cross section

Attack from 30% to 50% of cross section

4 Decay from 50% to 75% of cross section

Attack from 50% to 75% of cross section

0 Failure Failure aThis description of the conditions for the different grade ratings is slightly different than that given in the 1995 edition of this Research Note. The above description is consistent with Standard E07�01 of the American Wood Preservers� Association (AWPA 2001).

In Tables 2 to 76, stakes listed as �Trace� or �None� had an inspection rating of one of the following: 10-10, 10-9, 9-10, or 9-9. Stakes listed as �Serviceable but showing some decay� had one of the following inspection ratings: 8−10, 7−10, 6−10, 4−10, 8−9, 7−9, 6−9, or 4−9. Those listed as �Degraded but showing some termite attack� were field rated on the basis of 10−3, 10−7, 10−6, 10−4, 9−8, 9−7, 9−6, or 9−4. Stakes listed as �Degraded but showing some decay and termite attack� were given one of the following ratings: 8−8, 8−7, 8−6, 8−4, 7−8, 7−7, 7−6, 7−4, 6−3, 6−7, 6−6, 6−4, 4−8, 4−7, 4−6, or 4−4. Under the previous rating system,

stakes showing limited and heavy decay, termite attack, or both are grouped together. In stakes that show some deterio-ration but are not necessarily seriously decayed, unnecessary emphasis is sometimes placed on these ratings. Therefore, in making comparisons between preservatives, only the stakes actually destroyed should be considered.

Decay Termite attack

1 No decay A No attack 2 Slightly soft or suspicious B Nibbles or trails 3 Partial or limited decay C Limited attack (penetration)4 Severe decay D Heavy attack 5 Removed because of decaya

E Removed because of termite attacka

a50% or more of cross section destroyed.

For stakes classified as �Destroyed by decay fungi and ter-mites,� both forms of deterioration must be rated at least with severe decay or heavy attack (4 or D) in the inspection. In other words, a stake rated in the inspection, as 7-0 would be considered as destroyed by termites rather than by decay and termites, while one rated as 0-7 would be considered as destroyed by decay. Therefore, the system used in the tables for rating the destroyed stakes emphasizes the major factor or factors responsible for damage, but it ignores those that may have been noted but have not seriously contributed to the destruction. In estimating service life prior to 100% removal of stakes, note that the average life is approximately at the time when 60% of the stakes in a group has been removed. The new rating system is considered well suited to the requirements of the stake tests rated on the basis of vis-ual examination.

Tables 2 to 76 give the condition of the stakes at the most recent inspection. Table 77 is a summary of results obtained as the Mississippi site on 2- by 4-in. pine stakes treated with wood preservatives that are in general use.

Results The following summarizes the results of the stake tests thus far.

Southern Pine and Plywood Stakes Untreated Stakes�The untreated 2- by 4-in. Southern Pine sapwood stakes had an average life of 1.2 years in the Canal Zone, Panama; 1.8 to 2.4 years at Saucier, Mississippi, Bogalusa, Louisiana, and Jacksonville, Florida; and 4 to 6 years at Madison, Wisconsin. At Lake Charles, Louisiana, 90% of the untreated control stakes were destroyed by For-mosan termites, giving an average service life of 2.3 years. Untreated 3/4-in. pine sapwood stakes in Mississippi had an average life of 1.4 to 2.1 years.

The untreated Douglas-fir plywood stakes installed at Sau-cier, Mississippi, had an average life of about 1 to 4 years. Those glued with phenolic and urea-resin glues have lasted somewhat longer than those glued with casein glue, which had an average life of 1 year. The stakes cut from Douglas-fir lumber and of thickness similar to that of the plywood had an average life of slightly more than 2 years. Untreated plywood stakes of yellow birch, sweetgum, and tangile had an average life of less than 2 years.

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Page 6: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Untreated plywood stakes of Engelmann spruce heartwood had average lives of 2.6 years and 3.2 years for Mississippi and Wisconsin, respectively. Untreated Douglas-fir heart-wood plywood stakes had average lives of 3.2 years and 5.5 years for Mississippi and Wisconsin, respectively. South-ern Pine plywood stakes that contained about equal amounts of heartwood and sapwood had an average life of 2.8 and 5.8 years in Mississippi and Wisconsin, respectively (Table 51).

Pressure-Treated Stakes�In the more recent installations and those with the more effective preservatives, only a lim-ited number of stakes have thus far been removed, and the average life of stakes pressure treated with various preserva-tives cannot be determined. Estimates on average life were made for preservatives with significant failures at the time of the termination of several installations (Tables 2 to 5, 8, 12, 18, 38). In the Canal Zone, stakes treated with several reten-tion levels of chromated zinc arsenate (CZA) were destroyed during the 15-1/3 years of exposure. Stakes with 0.22 lb/ft3 CZA (oxide basis) had an average life of 9.2 years, and those with approximately 0.69 lb/ft3 (oxide basis) had an average life of 15.3 years. Stakes treated with CZA to retention levels of 0.22 to 0.70 lb/ft3 (oxide basis) have had 100% failures in Wisconsin after 51-1/2 years, and in Mississippi failures have been noted only with the lower retention levels (Table 4; similar comparison in Table 20). This may be attributed to the presence of arsenic-tolerant fungi at the Wisconsin test area.

Of the waterborne preservatives in tests that contain copper and arsenic (24 to 45 years in Mississippi), the formulations of ammoniacal copper arsenate (ACA) (Table 14) and chromated copper arsenate (CCA) (Tables 15, 20, 47) are better performers with no failures using retention levels of 0.29 lb/ft3 (oxide basis) or greater for CCA. Again, the overall performance of the arsenic containing preservatives (Table 20) is better in Mississippi than in Wisconsin.

Stakes treated with ammoniacal copper borate to retention levels of 0.17 and 0.22 lb/ft3 (oxide basis) have had 75% and 65% failure, respectively, in Mississippi after 25 years of service. In contrast, the ACA-treated stakes show 95% fail-ure at the 0.17-lb/ft3 retention level and 30% failure at the 0.23-lb/ft3 retention level for the same exposure (Table 52).

Results thus far on installations of pentachlorophenol with similar retention levels and different hydrocarbon solvents (Tables 17, 42, and 45) show better performance with solu-tions containing the heavy solvents such as heavy gas oil, lube oil extract (Table 17), No. 4 aromatic oil (Table 22), and AWPA P9 heavy petroleum solvent (Tables 42 and 45) than with volatile LPG or light oils such as Stoddard solvent (mineral spirits) (Tables 17 and 42). Preservatives such as rosin amine-D-pentachlorophenate (Tables 22 and 23), tributyltin oxide (Tables 36 and 41), and copper-8-quinolinolate (Tables 38 and 43) also show better perform-ance with the heavy petroleum solvent than the light

Stoddard solvent (mineral spirits). The previously mentioned heavy petroleum solvents have the following properties:

Distribution (oF) Petro-leum oils

API gravity 60oF

Flash point

(PMCC) (oF)

Vis-cosity

SUS at 100oF

Penta solvency at 75oF

(%) IBP 50% EP

Heavy gas oil, No. 101

08.3 345 167.4 20−22 600 700 734

Lube oil extract

05.1 295 196.4 28−30 440 696 736

AWPA P9, heavy

23.8 225 38.4 15 480 538 647

No. 4 aromatic

06.8 230 72.6 10+ 458 592 Cracked (85%)

Pentachlorophenol retention levels of 0.47 lb/ft3 and less are showing deterioration on the 3/4-in. stakes after 17 years of service in Mississippi. The stakes treated to retention levels of 0.34, 0.38, 0.50, 1.30, and 1.84 lb/ft3 of a water-soluble form of copper-8-quinolinolate gave service lives of 3.3, 3.8, 4.6, 6.2, 7.3, and 8.6 years, respectively (Table 54).

Coal-tar creosotes installed in Mississippi during 1940 and 1941 (Tables 4 to 6) have shown better performance than those installed in 1948 (Tables 18 and 19) (Baechler and others 1978). In the latter installation, 10 coal-tar creosotes with a retention of approximately 8 lb/ft3 showed 60% to 80% failure after 20 years, and the average life was deter-mined or estimated at 14 to 21 years. Creosotes installed earlier than 1941 showed 60% to 90% failures in 48½ to 49½ years for similar retention, which could show a service life in excess of 50 years.

Stakes pressure treated with the fire-retarding formulation containing ammonium phosphate and ammonium sulfate lasted, on an average, only 2 to 3 years in Mississippi. With these ammonium salts plus borax and boric acid, the stakes installed in 1943 lasted on the average about 4 years. The fire-retarding formulation with borax and boric acid alone has provided protection against decay and termites for an average of about 6 years (Table 13). The addition of zinc chloride and chromium compounds to combinations of boron and ammonium salts in fire retardants improved pro-tection against decay fungi and termites (Table 25). An exterior-type fire retardant containing urea, dicyandiamide, formaldehyde, and phosphoric acid in 2- by 4- by 18-in. stakes treated at retention levels of 2.8 lb/ft3, 6.0 lb/ft3 and 9.5-lb/ft3 had an average life of 4.8, 9.7 and 15.4 years, respectively. Termites caused failures at lower retentions (Table 53).

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The results of stake tests in Mississippi showed copper naphthenate provided greater protection than zinc naphthen-ate with similar retention levels (Table 7).

Rosin amine-D-pentachlorophenate in Stoddard solvent performed less satisfactorily than pentachlorophenol with that solvent and similar retention levels. Products from naval stores such as rosin oil, oleo resin, and drop liquor concen-trate with petroleum solvents appear to have limited value as preservatives but are improved by the addition of penta-chlorophenol. Urea (Table 10) has also shown limited protection. Stakes pressure treated with 5.8 lb/ft3 had an average life of 9.1 years in Mississippi. Other products showing limited preservative value in the retention levels used are acrylonitrile (cyanoethylation), ammonium hydrox-ide (thiamine destruction), amyl phenyl acetate, capric acid, copper-8-quinolinolate (in Stoddard solvent), diamyl phenol, DDT, dodecyl amine, nickel stearate, and tributyltin oxide (in Stoddard solvent).

An indication of the influence of size in test stakes is noted in Table 6. With a coal-tar creosote retention of approxi-mately 8 lb/ft3, 1/2-in.-square stakes were destroyed after 21-1/2 years with an average life of 17 years, 1-in.-square stakes after 39-1/2 years with an average life of 23.6 years, 1-1/2-in.-square stakes after 33-1/2 years with an average life of 26.6 years, and 2- by 4-in. stakes showed 70% failure after 54-1/2 years.

Note that aspen particleboard treated with CCA showed less degradation than those stakes treated with pentachlorophenol in light solvents. Stakes treated to 0.22, 0.40, and 0.82 lb/ft3 of pentachlorophenol showed failures of 100, 100, and 70% respectively, and only the low retention level (0.26 lb/ft3) of CCA showed 100% failure (Table 49). Untreated stakes of aspen particleboard showed an average life of 2.4 years.

Nonpressure-Treated Stakes�Southern Pine stakes and Douglas-fir plywood stakes treated by superficial applica-tions, such as brushing and brief dipping in coal-tar creosote and solutions of pentachlorophenol, copper naphthenate, or zinc naphthenate, have generally lasted 1 to 4 years longer than the untreated control stakes. However, stakes dipped for 15 min in coal-tar creosote had a life of about 8 years in Mississippi.

For the plywood stakes in which the veneer was treated by dipping or lengthy soaking in the preservatives before glu-ing, the results have generally been more favorable than for plywood similarly treated after gluing. In the Canal Zone, stakes soaked 18 h in solutions of pentachlorophenol or mixtures of chlorinated phenols lasted 5 to 10 years. In the United States, the stakes soaked 18 h in these solutions lasted 8 to 16 years. However, Douglas-fir plywood stakes treated by brushing, dipping, and 18-h soaking in chloro-2-phenylphenol solution lasted only a few months longer than the untreated plywood control stakes. Douglas-fir plywood stakes treated by soaking 18 h in pentachlorophenol solution

had a life of 5 years, while those similarly treated with coal-tar creosote have an estimated average life of 24 years.

At the Mississippi site, pine stakes treated by soaking in urea solution lasted about 1 to 1-1/2 years longer than the control stakes, and those similarly treated with urea-formaldehyde solution lasted about 2 to 4 years longer than the controls (Table 10). Pine stakes with increased retention levels of copper chromate and copper arsenate applied by double-diffusion have continued to perform well after 49 years in Mississippi. Failures thus far have been found primarily in the copper chromate system with 33% and 67% failed (Table 9).

Modified-Wood Stakes Plywood stakes impregnated with phenolic resin (impreg) and impregnated and compressed (compreg) have been considerably more resistant to decay and termite attack than have untreated plywood of the same species. Plywood stakes with a low resin content have had an average life of ap-proximately 7 years and those with a high resin content have lasted 12 years. In Douglas-fir plywood stakes with pheno-lic-resin-impregnated faces and untreated cores, an average life of about 3.5 years has been obtained, and somewhat better results have been noted when the edges of the ply-wood have been protected with a phenolic-resin coating. Southern Pine 2- by 4-in. stakes impregnated with a low resin content had an average life of 12 years, and those with a greater content of phenolic resin have lasted somewhat longer.

Laminated paper plastic made with phenolic resin has shown limited resistance to decay and termite attack, with the life of the stakes averaging about 6 to 8 years. Heat-stabilized birch and maple plywood (staypak) stakes have lasted about 4 to 6 years. The staypak with veneer of 1/16-in. thickness has performed better than that with 1/8-in. veneer, presumably because the thinner veneer permits a better distribution of the phenolic-resin adhesive in the plywood.

Acetylated birch (laminated veneer) has had reasonably good resistance to decay and termite attack with an average life of 17.5 years in Mississippi. Deterioration has been caused primarily by decay fungi.

Butylene oxide stakes treated to 17% to 22% weight gain had an average life of 4.7 years, and those treated to 37% to 40% weight gain had an average life of 12.2 years. Almost 67% of the butylene oxide stakes treated to 31% weight gain are showing attack and 33% have failed after 17 to 21 years of service. Propylene oxide-modified stakes gave a service life of 2.2 to 6.2 years, depending on the chemical loading (Table 50). Stakes, 3/4 in., treated with butylene oxide to 33.2% weight gain had an average life of 3.5 years (Ta-ble 56).

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Future Research Program As we move into the 21st century, it is critical to develop a wood preservative research program that addresses the fu-ture demands for durable forest products in light of a height-ened public environmental consciousness. One goal of wood preservative research is to improve methods to evaluate degradation and protection. In the past, FPL evaluated and analyzed, especially through stake tests, the performance of many preservative systems. This work contributed to this report. Although the importance of these evaluations is recognized, research direction necessitates focusing on accelerated methods to predict durability.

The FPL maintains 77 field research plots on the Harrison Experimental Forest in Saucier, Mississippi. The objective of these plots is to evaluate the performance of wood products exposed to natural environmental challengers. Many plots are approaching 55 years of age, and they represent an in-vestment of millions of research dollars. Many older plots cannot be duplicated or replaced because several of the preservatives initially used have been discontinued or banned by the U.S. Environmental Protection Agency.

The following listing summarizes the FPL recommendation for the 77 existing stake plots at the Harrison Experimental Forest. For plots that will be closed, the stakes will remain in the ground at the site, but inspections will be discontinued, and the database will be maintained in archival records.

Status of FPL-02 Research Plots

Statusa Table Plot Installed Last

inspected Statusa Table Plot Installed Last

inspected

C 2 2 1939 1966 C 40 58 1960 1978 C 3 3 1940 1967 C 42 59 1961 2000 C 4 4 1940 2000 C 45 61 1963 1998 C 5 5 1941 1996 K 43 62 1963 2000 C 6 6 1941 1996 C 44 63 1963 2000 C 7 7 1942 1992 C 46 66 1967 1997 C 8 8 1942 1963 K 47 67 1967 2002 C 9 9 1942 1997 K 48 68 1971 2000 C 10 10 1946 1960 K 49 70 1973 1998 C 11 11 1942 1950 C 50 71 1974 1995 C 12 12 1943 1963 K 51 72 1975 2000 C 13 13 1943 1950 K 52 73 1975 2002 K 14 14 1944 1999 C 53 74 1976 1993 K 15 15 1945 2000 K 54 75 1976 1993 C 16 16 1945 1996 K 55 78 1978 1998 C 17 20 1948 1998 C 56 79 1979 1989 C 18 24 1948 1992 K 57 80 1980 2002 C 19 25 1948 1998 C 58 81 1980 2000 C 20 28 1949 1995 K 59 82 1980 2000 C 21 26 1949 1995 C 60 83 1981 2000 C 22 27 1949 1999 K 61 84 1981 2002 K 26 32 1952 2002 K 62 85 1981 2002 C 24 33 1952 1997 C 63 86 1982 1996 C 23 34 1952 1997 C 64 87 1982 1996 C 25 35 1952 1997 C 65 88 1982 1996 C 28 37 1952 2000 C 66 89 1982 1996 C 29 38 1953 1992 C 67 90 1982 1999 C 30 40 1954 1995 C 68 92 1983 1995 C 31 41 1954 1995 C 68 93 1983 1995 C 32 42 1954 1995 C 69 94 1984 2000 C 33 44 1956 1981 K 70 95 1984 2002 K 34 47 1956 2000 C 71 96 1984 1996 C 35 48 1957 2000 K 72 97 1985 2002 C 36 53 1958 1967 K 73 98 1985 1999 C 37 55 1959 1989 K 74 99 1987 2000 K 38 54 1959 1968 K 75 100 1988 2002 K 41 56 1960 2000 C 76 101 1989 1998 K 39 57 1960 2000

aC indicates maintain archives, plot closed. K indicates keep plot open, study will continue.

6

Page 9: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

For the 24 plots at Harrison Experimental Forest listed as open, the current plans are to report the results of future inspections in separate publications. Reporting of results for any similar field plots installed since 1989 will also be ex-pected to be in separate publications. Thus, this publication is the last revision of FPL�RN�02. Future inspections will normally be conducted each year for the first 5 years after installation, every other year for the next 4 years, and every 3rd year for the next 6 years. After 15 years, stakes will be evaluated every 5th year.

Units of Measure Measurement values in this document are reported in Eng-lish units. The following provides equivalent International System (SI) units of measure:

English unit Conversion

factor SI unit

inch (in.) 25.4 millimeter (mm)

foot (ft) 0.3048 meter (m)

pound per cubic foot (lb/ft3)

16.02 kilogram per cubic meter (kg/m3)

oF (oF � 32)/1.8 oC

References AWPA. 2001. Standard method of evaluating wood pre-servatives by field tests with stakes. Standard E7�01. Gran-bury, TX: American Wood-Preservers� Association.

Baechler, R.H.; Gjovik, L.R.; Davidson, H.L. 1978. 1948 cooperative creosote project: review and results of field tests on costs and 2 × 4 stakes. In: Proceedings of the American Wood-Preservers� Association; 1978 April 26−28. 74: 173�180.

Blew, J.O. 1948. Comparison of wood preservatives in stake tests. In: Proceedings of the American Wood-Preservers� Association; April 27−29. 88−119.

Fisher, R.A.; Yates, F. 1938. Statistical tables for agricul-tural and medical research. London: Oliver and Boyd. 99 p.

Hunt, G.M.; Snyder, T.E. 1930. An international termite exposure test. In: Proceedings of the American Wood-Preservers� Association, January 28−30. 318−334. [Annual progress reports published in the above Proceedings each year from 1930 to 1949, 1952, 1956, 1957 (final report).]

7

Page 10: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 1�lndex to materials tested

Material Existing specification or AWPAa reference Table number

Chemical Acid copper chromate Fed. Spec. TT-W-546; AWPA P5 15, 16, 46, 47 Acrylonitrile � 36 Aldrin � 41 Ammoniacal copper arsenate Fed. Spec. TT-W-549; AWPA P5 14, 47, 51, 52, 55, 72 Ammoniacal copper borate � 52 Ammoniacal copper zinc arsenate � 62 Ammonium hydroxide � 36 Ammonium sulfate�phosphate Navy Spec. 51C38 13 Amyl phenyl acetate � 14 Basic zinc chloride � 26 Basilit UA � 30 Boliden salt S-25 � 24 Borax�boric acid Navy Spec. 51C38 13 Capric acid � 14 Chloro-2-phenylphenol � 5, 8 Chromated copper arsenate Fed. Spec. TT-W-550 Type I; AWPA P5; AWPA P5, Type A 15, 47 Chromated copper arsenate Fed. Spec. TT-W-550 Type II; AWPA P5, Type B 20, 47 Chromated copper arsenate Fed. Spec. TT-W-550 Type III; AWPA P5, Type C 48, 49, 51, 55, 57, 72, 73, 74 Chromated copper fluoride (CFK) � 59 Chromated zinc arsenate Formerly in Fed. Spec. TT-W-538; AWPA P5 4, 24 Chromated zinc chloride Fed. Spec. TT-W-551; AWPA P5 2, 16, 25, 35, 47 Chromated zinc chloride, copperized Formerly in Fed. Spec. TT-W-562; AWPA P5 31 Chromated zinc chloride (FR) AWPA P10, Type B 25 Copper arsenate AWPA Proc. 1941; pp. 23�31 9 Copper carbonate � 74 Copper chromate AWPA Proc. 1941; pp. 23�31 9 Copper�chrome�boron (CB) U.S. Patent No. 3,007,844 46 Copper�chrome�phosphorus � 48 Copper formate � 34 Copper naphthenate AWPA P8 7, 12, 16, 17, 29 Copper oxide � 74 Copper-8-quinolinolate AWPA P8 38, 43, 54, 61 Creosote, coal�tar Fed. Spec. TT-C-645; AWPA P1 4, 5, 6, 8, 16�20, 31, 35, 47,

63, 66 Creosote, coal�tar (English) � 18, 19 Creosote, coal�tar (low temperature) � 28 Creosote, coal�tar (Texas lignite) � 32 Creosote, coal�tar solution Fed. Spec. TT-C-650; AWPA P2 18, 47, 70 Creosote, petroleum solution Fed. Spec. TT-W-568 18, 47, 70 Creosote, low xylene insolubles � 75 Creosote, toluene � 6 Diamyl phenol � 14 Dichloro-diphenyl-trichloroethane (DDT) � 14 Dieldrin � 41 Dodecyl amine � 14 Drop-liquor concentrate � 27 Fire retardants � 53 Fire retardants AWPA P10 25 Fluor chrome arsenate phenol Fed. Spec. TT-W-535, Type A; AWPA P5 2, 33, 37, 47, 49 Fluor chrome arsenate phenol Fed. Spec. TT-W-535, Type B; AWPA P5 47 Fuel oils � 5, 17, 27

(Page 1 of 2)

Page 11: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 1�lndex to materials tested--concluded

Material Existing specification or AWPA reference Table number Chemical�continued

Heptadecyltrimethyltetra- hydropyrimidine (HTP) � 44 KP (copper oxide and chlorophenol) � 35 Lignite�tar extracts � 39 Mercuric chloride � 12 Minalith AWPA P10, Type C 25 Nickel�chromium�arsenic salt � 15 Nickel�sterate � 14 Oleo resin � 27 Paraffin � 32 Pentachlorophenol Fed. Spec. TT-W-570; AWPA P8 5, 8, 12, 16, 17, 22, 23, 27, 29, 31, 32,

33, 41, 42, 43, 45, 47, 49, 54, 58, 60, 61, 63, 64, 65, 68, 69, 71, 76

Petroleum oils (various types) � 17, 18, 21, 23, 45, 69, 76 Phenyl mercury oleate � 12 Phenol-formaldehyde � 67 Pyresote AWPA P10, Type D 25 Rosin amine D copper acetate complex � 27 Rosin amine D pentachlorophenate � 22, 23 Rosin oil � 27 Sodium pentachlorophenate � 2, 5 Sodium tetrachlorophenate � 2 Tetrachlorophenol � 65, 69 Toluene � 6 Tributyltin oxide � 36, 41, 61 Urea � 10 Zinc�arsenate�chromium salts � 20 Zinc chloride � 2, 4, 20, 26 Zinc naphthenate � 7, 8

Modified wood, particleboard, plywood, and paper plastic

� 14

Acetylated wood Butylene oxide U.S. Patent No. 3,985,921 50, 56 Cyanoethylated wood � 36 Embedded fiberboard � 40 Epichlorohydrin � 50 Heat-stabilized wood (Staypak) � 11 Impreg and Compreg � 3 Laminated paper plastic (Papreg) � 11 Mold-infected wood � 31 Particleboard � 49 Plywood � 3, 8, 16, 33, 51 Propylene oxide U.S. Patent No. 3,985,921 50 Wood with thiamine destroyed � 36

aAmerican Wood Preservers Association. (Page 2 of 2)

Page 12: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 2-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

with

fluo

r chr

ome

arse

nate

phe

nol--

Type

A, z

inc

chlo

ride,

and

chr

omat

ed z

inc

chlo

ride

afte

r 15

to 2

8 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Sep

tem

ber 1

938;

Bog

alus

a, L

A,D

ecem

ber 1

939;

Jac

kson

ville

, FL,

Jan

uary

193

9; H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

938;

and

Mad

ison

, WI,

Nov

embe

r 193

9 (P

lot 2

)

Con

ditio

n of

sta

kes

Dec

embe

r 196

6c (%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Dec

ayfu

ngi

Num

-an

dan

dAv

erag

e R

eten

tion

of s

alts

a (lb/

ft3 )be

r in

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

Loca

tion

Min

imum

Max

imum

Aver

age

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Sodi

um p

enta

chlo

roph

enat

eC

anal

0.24

0.28

0.26

10--

----

----

--10

010

100

6.9

LA0.

240.

280.

2610

----

----

10--

9010

100

9.2

FL0.

250.

280.

269

----

----

11--

899

100

14.2

MS

0.24

0.28

0.26

10--

----

--10

2070

1010

011

.9W

I0.

240.

280.

2610

----

----

100

----

1010

012

.5

Can

al0.

450.

540.

5010

----

----

--20

8010

100

11.2

LA0.

450.

530.

4910

----

----

30--

7010

100

10.7

FL0.

460.

550.

5010

----

----

----

88

8020

.0d

MS

0.44

0.54

0.49

10--

----

--10

--90

1010

019

.2W

I0.

440.

530.

4910

----

----

100

----

1010

016

.4

Can

al0.

690.

810.

7510

----

----

1020

7010

100

11.7

LA0.

690.

850.

7510

----

----

10--

9010

100

15.6

FL0.

680.

820.

7410

----

--40

10--

506

6020

.0d

MS

0.69

0.84

0.77

10--

----

--40

--60

1010

021

.6W

I0.

670.

810.

7610

----

----

100

----

1010

021

.0

Can

al0.

921.

060.

9810

----

----

--10

9010

100

14.3

LA0.

931.

090.

9910

----

----

10--

9010

100

16.2

FL0.

921.

080.

9810

----

--60

10--

304

40--

MS

0.93

1.09

0.97

10--

----

--20

--80

1010

025

.0W

I0.

861.

010.

9010

----

----

100

----

1010

023

.4

Sodi

um te

trach

loro

phen

ate

Can

al0.

240.

270.

2510

----

----

--60

4010

100

4.8

LA0.

230.

270.

2510

----

----

20--

8010

100

8.1

FL0.

230.

280.

25 9

----

----

22--

789

100

11.3

MS

0.23

0.27

0.25

10--

----

----

1090

1010

010

.7W

I0.

240.

270.

2510

----

----

100

----

1010

011

.4

Can

al0.

470.

560.

5110

----

----

--20

8010

100

9.9

LA0.

460.

550.

5010

----

----

20--

8010

100

10.9

FL0.

470.

550.

5210

----

----

----

100

1010

015

.3M

S0.

480.

580.

5210

----

----

----

100

1010

015

.1W

I0.

470.

550.

5210

----

----

100

----

1010

014

.5

(Pag

e 1

of 4

)

Page 13: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 2-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

with

fluo

r chr

ome

arse

nate

phe

nol--

Type

A,

zinc

chl

orid

e, a

nd c

hrom

ated

zin

c ch

lorid

e af

ter 1

5 to

28

year

s of

ser

vice

. St

akes

pla

ced

in te

st a

t Bar

ro C

olor

ado

Isla

nd, C

anal

Zon

e, S

epte

mbe

r 193

8; B

ogal

usa,

LA,

Dec

embe

r 193

9; J

acks

onvi

lle, F

L, J

anua

ry 1

939;

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 193

8; a

nd M

adis

on, W

I, N

ovem

ber 1

939

(Plo

t 2)--

cont

inue

d

Con

ditio

n of

sta

kes

Dec

embe

r 196

6c (%)

Serv

icea

ble

but

show

ing

som

e--

Dec

ayD

ecay

fung

iN

um-

and

and

Aver

age

ber i

nTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Loca

tion

Min

imum

Max

imum

Aver

age

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Sodi

um te

trach

loro

phen

ate

Can

al0.

700.

830.

7610

----

----

----

100

1010

013

.1 (

cont

inue

d)LA

0.71

0.83

0.77

10--

----

--30

--70

1010

011

.9FL

0.68

0.83

0.76

9--

----

----

1189

910

016

.8M

S0.

680.

820.

7510

----

----

----

100

1010

019

.7W

I0.

670.

810.

75 9

----

----

100

----

910

016

.7

Fluo

r chr

ome

arse

nate

Can

al0.

18 (0

.11)

0.22

(0.1

4)0.

20 (0

.12)

10--

----

----

100

--10

100

2.9

phe

nol -

- Typ

e A

LA0.

19 (0

.12)

0.22

(0.1

4)0.

20 (0

.12)

10--

----

--50

--50

1010

09.

6FL

0.18

(0.1

1)0.

21 (0

.13)

0.20

(0.1

2)10

----

----

50--

5010

100

13.9

MS

0.18

(0.1

1)0.

21 (0

.13)

0.20

(0.1

2)10

----

----

1050

4010

100

10.2

WI

0.13

(0.0

8)0.

22 (0

.14)

0.20

(0.1

2)10

----

----

100

----

1010

013

.8

Can

al0.

28 (0

.17)

0.33

(0.2

0)0.

30 (0

.19)

10--

----

----

3070

1010

06.

4LA

0.28

(0.1

7)0.

32 (0

.20)

0.30

(0.1

9)10

----

----

20--

8010

100

13.7

FL0.

29 (0

.18)

0.32

(0.2

0)0.

30 (0

.19)

10--

----

--10

0--

--10

100

15.4

MS

0.29

(0.1

8)0.

32 (0

.20)

0.30

(0.1

9)10

----

----

10--

9010

100

18.0

WI

0.27

(0.1

7)0.

30 (0

.19)

0.28

(0.1

7)10

----

----

100

----

1010

016

.5

Can

al0.

53 (0

.33)

0.66

(0.4

1)0.

60 (0

.37)

10--

----

--40

--60

1010

014

.2LA

0.56

(0.3

5)0.

64 (0

.40)

0.60

(0.3

7)10

----

----

50--

5010

100

15.6

FL0.

57 (0

.35)

0.65

(0.4

0)0.

61 (0

.38)

10--

----

--10

0--

--10

100

17.3

MS

0.57

(0.3

5)0.

65 (0

.40)

0.61

(0.3

8)10

----

----

60--

4010

100

24.1

WI

0.59

(0.3

6)0.

68 (0

.42)

0.65

(0.4

0)10

----

----

100

----

1010

016

.0

Sodi

um p

enta

chlo

roph

enat

eC

anal

0.52

0.55

0.54

10--

----

----

3070

1010

08.

7 a

nd s

odiu

m c

hlor

idee

LA0.

460.

530.

4910

----

----

----

100

1010

013

.3FL

0.48

0.54

0.50

10--

----

5010

--40

550

--M

S0.

460.

530.

4910

----

----

----

100

1010

016

.3W

I0.

460.

530.

5010

----

----

100

----

1010

016

.8

Zinc

chl

orid

eC

anal

0.44

(0.2

6)0.

53 (0

.32)

0.47

(0.2

8)10

----

----

--30

7010

100

3.9

LA0.

45 (0

.27)

0.55

(0.3

3)0.

50 (0

.30)

10--

----

--30

--70

1010

08.

2FL

0.45

(0.2

7)0.

53 (0

.32)

0.49

(0.2

9)10

----

----

20--

8010

100

12.9

MS

0.45

(0.2

7)0.

54 (0

.32)

0.50

(0.3

0)10

----

----

40--

6010

100

15.4

WI

0.45

(0.2

7)0.

53 (0

.32)

0.49

(0.2

9)10

----

----

100

----

1010

018

.3

(Pag

e 2

of 4

)

Ret

entio

n of

sal

tsa (l

b/ft3 )

Des

troye

d by

--

Page 14: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Ta

ble

2--C

ondi

tion

of S

outh

ern

Pine

sta

kes

(2 b

y 4

in. n

omin

al b

y 18

in.)

treat

ed w

ith c

hlor

inat

ed p

heno

ls a

nd w

ith fl

uor c

hrom

e ar

sena

te p

heno

l--Ty

pe A

,zi

nc c

hlor

ide,

and

chr

omat

ed z

inc

chlo

ride

afte

r 15

to 2

8 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Sep

tem

ber 1

938;

Bog

alus

a, L

A,D

ecem

ber 1

939;

Jac

kson

ville

, FL,

Jan

uary

193

9; H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

938;

and

Mad

ison

, WI,

Nov

embe

r 193

9 (P

lot 2

)--co

ntin

ued

Dec

ayD

ecay

fung

iN

um-

and

and

Aver

age

ber i

nTe

rmite

term

iteD

ecay

Term

itete

rmite

life

Pres

erva

tive

Loca

tion

Min

imum

Max

imum

Aver

age

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Zinc

chl

orid

eC

anal

0.70

(0.4

2)0.

82 (0

.49)

0.76

(0.4

5)10

----

----

----

100

1010

03.

9 (

cont

inue

d)L A

0.70

(0.4

2)0.

78 (0

.47)

0.74

(0.4

4)10

----

----

40--

6010

100

12.1

FL0.

71 (0

.42)

0.82

(0.4

9)0.

76 (0

.45 )

10--

----

--40

--60

1010

013

.5M

S0.

70 (0

.42)

0.79

(0.4

7)0.

74 (0

.44 )

10--

----

--20

1070

1010

016

.7W

I0.

65 (0

.39)

0.87

(0.5

2)0.

75 (0

.45 )

9--

----

--10

0--

--9

100

18.9

Can

al0.

94 (0

.56)

1.08

(0.6

4)1.

00 (0

.60)

10--

----

----

4060

1010

04.

0L A

0.94

(0.5

6)1.

08 (0

.64)

1.01

(0.6

0)10

----

----

70--

3010

100

11.6

FL0.

95 (0

.57)

1.08

(0.6

4)1.

02 (0

.61 )

10--

----

--20

--80

1010

015

.2M

S0.

94 (0

.56)

1.07

(0.6

4)1.

01 (0

.60 )

10--

----

--10

--90

1010

017

.3W

I0.

93 (0

.56)

1.13

(0.6

8)1.

02 (0

.61 )

10--

----

--10

0--

--10

100

19.0

Can

al1.

40 (0

.84)

1.62

(0.9

7)1.

49 (0

.89)

10--

----

----

1090

1010

07.

3L A

1.44

(0.8

6)1.

63 (0

.97)

1.52

(0.9

1)10

----

----

40--

6010

100

11.1

FL1.

41 (0

.84)

1.62

(0.9

7)1.

50 (0

.89 )

10--

----

--20

--80

1010

015

.7M

S1.

43 (0

.85)

1.63

(0.9

7)1.

52 (0

.91 )

10--

----

--50

--50

1010

017

.9W

I1.

36 (0

.81)

1.74

(1.0

4)1.

59 (0

.94 )

10--

----

--10

0--

--10

100

18.7

Chr

omat

ed z

inc

chlo

ride

Can

al0.

45 (0

.28)

0.55

(0.3

4)0.

49 (0

.30 )

10--

----

----

--10

010

100

4.9

LA0.

46 (0

.28)

0.55

(0.3

4)0.

49 (0

.30)

10--

----

--40

1050

1010

08.

6FL

0.45

(0.2

8)0.

53 (0

.33)

0.48

(0.3

0) 8

----

----

25--

758

100

14.3

MS

0.45

(0.2

8)0.

55 (0

.34)

0.49

(0.3

0 )10

----

----

3010

6010

100

14.2

WI

0.43

(0.2

6)0.

53 (0

.33)

0.46

(0.2

9 )10

----

----

100

----

1010

016

.2

Can

al0.

70 (0

.43)

0.81

(0.5

0)0.

76 (0

.47)

10--

----

----

--10

010

100

7.2

L A0.

70 (0

.43)

0.80

(0.4

9)0.

76 (0

.47)

10--

----

--40

--60

1010

010

.6FL

0.73

(0.4

5)0.

81 (0

.50)

0.77

(0.4

7 ) 9

----

----

11--

899

100

15.9

MS

0.72

(0.4

4)0.

81 (0

.50)

0.76

(0.4

7 )10

----

----

40--

6010

100

20.2

WI

0.70

(0.4

3)0.

86 (0

.53)

0.80

(0.4

9 )10

----

----

100

----

1010

014

.7

Can

al0.

95 (0

.48)

1.11

(0.6

8)1.

02 (0

.63)

10--

----

--10

--90

1010

06.

6L A

0.93

(0.5

7)1.

07 (0

.66)

1.00

(0.6

2)10

----

----

40--

6010

100

11.9

FL0.

96 (0

.59)

1.09

(0.6

7)1.

03 (0

.63 )

10--

----

1020

--70

990

17.0

d

MS

0.96

(0.5

9)1.

09 (0

.67)

1.03

(0.6

3)10

----

----

50--

5010

100

20.1

WI

0.89

(0.5

5)1.

13 (0

.70)

1.02

(0.6

3 )10

----

----

100

----

1010

018

.3

(Pag

e 3

of 4

)

Ret

entio

n of

sal

tsa (l

b/ft3 )

Con

ditio

n of

sta

kes

Dec

embe

r 196

6c (%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-

Tota

l rem

oved

Page 15: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 2-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

with

fluo

r chr

ome

arse

nate

phe

nol--

Type

A,

zinc

chl

orid

e, a

nd c

hrom

ated

zin

c ch

lorid

e af

ter 1

5 to

28

year

s of

ser

vice

. St

akes

pla

ced

in te

st a

t Bar

ro C

olor

ado

Isla

nd, C

anal

Zon

e, S

epte

mbe

r 193

8; B

ogal

usa,

LA,

Dec

embe

r 193

9; J

acks

onvi

lle, F

L, J

anua

ry 1

939;

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 193

8; a

nd M

adis

on, W

I, N

ovem

ber 1

939

(Plo

t 2)--

conc

lude

d

Dec

ayN

um-

Dec

ayfu

ngi

ber

and

and

Aver

age

inTe

rmite

term

iteD

ecay

Term

itete

rmite

life

Pres

erva

tive

Loca

tion

Min

imum

Max

imum

Aver

age

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Unt

reat

ed c

ontro

lsC

anal

----

--10

----

----

--10

0--

1010

00.

7LA

----

--10

----

----

2020

6010

100

2.9

FL--

----

10--

----

----

1090

1010

02.

8M

S--

----

10--

----

----

7030

1010

02.

9W

I--

----

10--

----

--10

0--

--10

100

5.7

a Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

b Ten

stak

es w

ere

orig

inal

ly in

stal

led

at e

ach

test

sta

tion;

this

num

ber h

as s

ince

bee

n re

duce

d ei

ther

bec

ause

of f

ailu

re to

loca

te th

e st

akes

at t

he ti

me

of i

nspe

ctio

n or

bec

ause

of d

amag

e by

fire

.c Fi

nal i

nspe

ctio

n at

Can

al Z

one,

Jan

uary

195

6; a

t Lou

isia

na, D

ecem

ber 1

958;

at F

lorid

a, D

ecem

ber 1

960;

at W

isco

nsin

, Oct

ober

196

4;

and

at M

issi

ssip

pi, D

ecem

ber 1

966.

d Estim

ate

base

d on

per

cent

age

of s

take

s re

mai

ning

afte

r fin

al in

spec

tion.

e Ret

entio

n va

lues

bas

ed o

n so

dium

pen

tach

loro

phen

ate

only

. So

dium

chl

orid

e ad

ded

was

equ

al to

20%

of w

eigh

t of s

odiu

m p

enta

chlo

roph

enat

e in

sol

utio

n.

This

stu

dy w

as in

itiat

ed b

y R

. M. W

irka.

(Pag

e 4

of 4

)

Tota

l rem

oved

Ret

entio

n of

sal

tsa (l

b/ft3 )

Con

ditio

n of

sta

kes

Dec

embe

r 196

6c (%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-

Page 16: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Con

ditio

n of

sta

kes

Janu

ary

1967

(%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Appr

oxim

ate

Num

-D

ecay

fung

iav

erag

ebe

ran

dan

dAv

erag

eSt

ake

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eG

roup

num

ber

Trea

tmen

t (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Plyw

ooda

11-

1-40

toEa

ch p

ly im

preg

nate

d w

ith a

50%

aqu

eous

sol

utio

n 10

8--

----

--38

--62

810

012

.41-

10-4

0 o

f phe

nolic

resi

n, s

low

ly d

ried,

and

cur

ed fo

r

1 da

y at

220

° F. B

onde

d w

ith p

heno

lic-re

sin

film

22-

1-40

toSa

me

as g

roup

1 e

xcep

t tha

t a 2

5% s

olut

ion

was

510

----

----

60--

4010

c10

06.

92-

10-4

0 u

sed

33-

1-40

toFa

ce p

lies

impr

egna

ted

as in

gro

up 1

and

bon

ded

10b

10--

----

----

100

--10

c10

03.

33-

10-4

0 t

o an

unt

reat

ed c

ore

with

phe

nolic

-resi

n fil

m

44-

1-40

toFa

ce p

lies

impr

egna

ted

as in

gro

up 2

and

bon

ded

5b10

----

----

--10

0--

10c

100

3.5

4-10

-40

to

an u

ntre

ated

cor

e w

ith p

heno

lic-re

sin

film

55-

1-40

toSa

me

as g

roup

2 e

xcep

t tha

t edg

es o

f spe

cim

ens

10b

10--

----

--20

80--

10c

100

4.9

5-10

-40

wer

e gi

ven

a pr

otec

tive

treat

men

t by

dipp

ing

in a

phe

nolic

resi

n co

ntai

ning

15%

alc

ohol

66-

1-40

toSa

me

as g

roup

4 e

xcep

t tha

t edg

es w

ere

prot

ecte

d5b

9--

----

--22

4433

9c10

09.

46-

10-4

0 a

s in

gro

up 5

77-

1-40

toU

ntre

ated

plie

s bo

nded

with

phe

nolic

-resi

n--

10--

----

----

7030

1010

01.

97-

1-40

film

88-

1-40

toU

ntre

ated

plie

s bo

nded

with

hot

-pre

ss u

rea

--10

----

----

--70

3010

100

1.9

8-10

-40

res

in

99-

1-40

toU

ntre

ated

plie

s bo

nded

with

cas

ein

glue

--8

----

----

--88

128d

100

1.0

9-

10-4

0 (

FPL

form

ula

4B)

1010

-1-4

0 to

Unt

reat

ed p

lies

(yel

low

birc

h) b

onde

d w

ith--

10--

----

--10

3060

1010

01.

910

-10-

40 p

heno

lic-re

sin

flim

1111

-1-4

0 to

Unt

reat

ed c

ontro

ls--s

olid

woo

d--

10--

----

----

8020

1010

02.

411

-10-

40 (

1/4

by 4

by

18 in

.)

(Pag

e 1

of 2

)

afte

r abo

ut 2

7 ye

ars

of s

ervi

ce (P

lot 3

)Ta

ble

3--C

ondi

tion

of p

lyw

ood

stak

es a

nd re

sin-

impr

egna

ted

stak

es s

et J

anua

ry 1

940

on H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S,

Page 17: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Con

ditio

n of

sta

kes

Janu

ary

1967

(%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Appr

oxim

ate

Num

-D

ecay

fung

iav

erag

ebe

ran

dan

dAv

erag

eSt

ake

rete

ntio

nin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eG

roup

num

ber

Trea

tmen

t (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Stak

es (I

mpr

eg)e

1212

-1-4

0 to

Impr

egna

ted

sam

e as

gro

up 1

1010

--10

--10

50--

308

80)

19.5

f

12-1

0-40

1313

-1-4

0 to

Impr

egna

ted

sam

e as

gro

up 2

510

----

----

50--

5010

100)

11.7

13-1

0-40

1414

-1-4

0 to

Con

trols

--unt

reat

ed--

10--

----

----

8020

1010

0)2.

514

-10-

40

Com

pres

sed

Plyw

ood

(Com

preg

)g

1515

-1-4

0 to

Dou

glas

-fir--

all p

lies

impr

egna

ted

as in

gro

up 1

,10

310

0--

----

----

----

----

15-3

-40

drie

d an

d as

sem

bled

with

out t

he u

se o

f glu

e on

a

hot p

ress

at 3

30° F

and

1,0

00 lb

. pre

ssur

e p

er s

quar

e in

ch

15-4

-40

toYe

llow

-pop

lar--

all p

lies

impr

egna

ted

and

103

----

----

1

--2

310

0)19

.615

-6-4

0 c

ompr

esse

d th

e sa

me

as fo

r Dou

glas

-fir

a Spec

imen

s in

gro

ups

1 to

9 w

ere

thre

e-pl

y D

ougl

as-fi

r; in

gro

up 1

0, y

ello

w b

irch.

Spe

cim

ens

wer

e 1/

4 by

4 b

y 18

in. a

nd m

ade

of 1

/16-

in. f

aces

and

a 1

/8-in

. cor

e. S

peci

men

s in

gro

up 1

1 w

ere

solid

Dou

glas

-fir,

1/4

by 4

by

18 in

.

b Incr

ease

bas

ed o

n tre

ated

face

s.

c Det

erio

ratio

n pr

inci

pally

in c

ores

.

d Som

e se

para

tion

of p

lies

had

also

occ

urre

d.

e Spec

imen

s ar

e So

uthe

rn P

ine

sapw

ood,

2 b

y 4

nom

inal

by

18 in

.

f Base

d on

est

imat

ed li

fe o

f 2 re

mai

ning

sta

kes.

g Dou

glas

-fir a

nd y

ello

w-p

opla

r spe

cim

ens

mad

e of

15-

1/15

-in. p

lies,

com

pres

sed

to a

thic

knes

s of

3/8

in.

Spec

imen

s w

ere

3/8

by 4

by

14 in

.

NO

TE--S

take

s re

mai

ning

afte

r the

195

2 in

spec

tion

wer

e ta

kien

up

and

rese

t in

the

sam

e ge

nera

l are

a.

This

stu

dy w

as in

itiat

ed b

y R

. M. W

irka.

(Pag

e 2

of 2

)

afte

r abo

ut 2

7 ye

ars

of s

ervi

ce (P

lot 3

)--co

nclu

ded

Tabl

e 3-

-Con

ditio

n of

ply

woo

d st

akes

and

resi

n-im

preg

nate

d st

akes

set

Jan

uary

194

0 on

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Page 18: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 4-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chr

omat

ed z

inc

arse

nate

(Bol

iden

sal

ts),

zinc

chl

orid

e,an

d co

al-ta

r cre

osot

e af

ter 1

5 to

60

year

s of

ser

vice

. St

akes

pla

ced

in te

st a

t Mad

ison

, WI,

Sept

embe

r 194

0; H

arris

on E

xper

imen

tal

arro

Col

orad

o Is

land

, Can

al Z

one,

Sep

tem

ber 1

940

(Plo

t 4)

Con

ditio

n of

sta

kes

Janu

ary

2000

a (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayAv

erag

e re

tent

ion

Num

-D

ecay

fung

i (l

b/ft3 )

ber

and

and

Aver

age

Dry

inTe

rmit e

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Loca

tion

Oil

saltb

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Zinc

chl

orid

eW

I--

0.50

(0.3

0)10

----

----

100

----

1010

014

.8M

S--

0.50

(0.3

0)10

----

----

60--

4010

100

14.2

Can

al--

0.49

(0.2

9)10

----

----

----

100

1010

03.

0

WI

--1.

03 (0

.61)

10--

----

--10

0--

--10

100

19.8

MS

--1.

02 (0

.61)

10--

----

--60

1030

1010

014

.4C

anal

--1.

01 (0

.60)

10--

----

----

--10

010

100

3.6

WI

--1.

51 (0

.90)

10--

----

--10

0--

--10

100

22.3

MS

--1.

51 (0

.90)

10--

----

--60

--40

1010

018

.1C

anal

--1.

49 (0

.89)

10--

----

----

--10

010

100

4.5

Chr

omat

ed z

inc

WI

--0.

33 (0

.22)

10--

----

--10

0--

--10

100

19.6

ars

enat

eM

S--

0.33

(0.2

2)10

----

----

30--

7010

100

33.0

(Bo

liden

sal

ts)c

Can

al--

0.33

(0.2

2)10

----

----

----

100

1010

09.

2

WI

--0.

44 (0

.29)

10--

----

--10

0--

--10

100

26.1

MS

--0.

44 (0

.29)

9--

----

--11

--89

910

039

.3C

anal

--0.

44 (0

.29)

10--

----

--30

1060

1010

011

.6

WI

--0.

60 (0

.40)

9--

----

--10

0--

--10

100

24.9

MS

--0.

58 (0

.38)

10--

----

--60

--40

1010

051

.7C

anal

--0.

58 (0

.38)

10--

----

--60

40--

1010

014

.6

WI

--0.

78 (0

.52)

10--

----

--10

0--

--10

100

34.6

MS

--0.

78 (0

.52)

10--

----

7010

--20

330

--C

anal

--0.

78 (0

.52)

10--

----

--10

0--

--10

100

15.1

WI

--1.

06 (0

.70)

9--

----

--10

0--

--10

100

36.2

MS

--1.

06 (0

.70)

10--

----

10--

----

----

--C

anal

--1.

05 (0

.69)

10--

----

--10

0--

--10

100

15.3

(Pag

e 1

of 2

)

Page 19: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine
Page 20: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Ta

ble

4--C

ondi

tion

of S

outh

ern

Pine

sta

kes

(2 b

y 4

in. n

omin

al b

y 18

in.)

treat

ed w

ith c

hrom

ated

zin

c ar

sena

te (B

olid

en s

alts

), zi

nc c

hlor

ide

and

coal

-tar c

reos

ote

afte

r 15

to 6

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

at M

adis

on, W

I, Se

ptem

ber 1

940;

Har

rison

Exp

erim

enta

lFo

rest

, Sau

cier

, MS,

Jun

e 19

40; a

nd B

arro

Col

orad

o Is

land

, Can

al Z

one,

Sep

tem

ber 1

940

(Plo

t 4)--

conc

lude

d

Con

ditio

n of

sta

kes

Janu

ary

2000

a (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayAv

erag

e re

tent

ion

Num

-D

ecay

fung

i (l

b/ft3 )

ber

and

and

Aver

age

Dry

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Loca

tion

Oil

saltb

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Coa

l-tar

cre

osot

eW

I4.

3--

10--

----

--10

0--

--10

100

37.9

MS

4.2

--10

----

----

60--

4010

100

17.8

Can

al4.

3--

10--

----

--40

--60

1010

013

.4

WI

8.0

-- 7

--71

----

29--

--2

29--

MS

8.0

--10

----

--10

40--

509

90--

Can

al8.

0--

10--

60--

1030

----

330

19d

WI

11.8

-- 9

3367

----

----

----

----

MS

11.8

--10

--10

--40

20--

305

50--

Can

al11

.8--

10--

60--

--40

----

440

18d

WI

16.3

-- 9

3356

----

11--

--1

11--

MS

16.5

--10

--10

--80

10--

--1

10--

Can

al16

.5--

10--

90--

10--

----

----

--

WI

1.8

e--

10--

----

--10

0--

--10

100

12.4

MS

1.8

e--

10--

----

--10

3060

1010

07.

7C

anal

1.8e

--10

----

----

--80

2010

100

4.8

WI

0.71

f--

10--

----

--10

0--

--10

100

8.4

MS

0.76

f--

10--

----

----

5050

1010

04.

2

Can

al

0.

76f

--10

----

----

--90

1010

100

2.5

Unt

reat

ed c

ontro

lsW

I--

--10

----

----

100

----

1010

06.

2M

S--

--10

----

----

--50

5010

100

2.2

Can

al--

--10

----

----

--90

1010

100

1.1

a Fina

l ins

pect

ion

at C

anal

Zon

e, J

anua

ry 1

956.

b Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

c Ret

entio

n ba

sed

upon

tota

l anh

ydro

us s

alts

: Zn

SO4 +

H3A

sO4 +

Na 2

HAs

O4 +

Na 2

Cr 2

O7.

d Estim

ate

base

d up

on p

erce

ntag

e of

sta

kes

rem

aini

ng a

fter f

inal

insp

ectio

n.e 15

-min

dip

at r

oom

tem

pera

ture

.f Br

ush

treat

men

t, tw

o co

ats.

This

stu

dy w

as in

itiat

ed b

y R

. M. W

irka.

(Pag

e 2

of 2

)

Page 21: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

of s

ervi

ce. S

take

s pl

aced

in te

st a

t Bar

ro C

olor

ado

Isla

nd, C

anal

Zon

e, F

ebur

ary

1941

; Bog

alus

a, L

A, M

arch

194

1; J

acks

onvi

lle, F

L, M

arch

194

1;an

d H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, F

ebru

ary

1941

(Plo

t 5)

Con

ditio

n of

sta

kes

Janu

ary

1996

c (%

)Se

rvic

eabl

e bu

tD

estro

yed

by--

Ret

entio

n of

show

ing

som

e--

Dec

ay p

rese

rvat

ivea

Num

-D

ecay

fung

i(lb

/ft3 )

ber

and

and

Aver

age

Loca

-M

ini-

Max

i-Av

er-

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

tion

mum

mum

age

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Sodi

um p

enta

chlo

roph

enat

eC

anal

0.23

0.27

0.25

10--

----

----

6040

1010

06.

4LA

0.23

0.26

0.25

10--

----

--10

--90

1010

010

.0FL

0.23

0.36

0.25

9

----

----

----

100

1010

014

.5M

S0.

230.

360.

2510

----

----

20--

8010

100

16.9

Can

al0.

310.

340.

3310

----

----

--10

9010

100

10.9

LA0.

310.

340.

3310

----

----

----

100

1010

010

.4FL

0.32

0.34

0.33

8

----

----

--12

888

100

16.4

MS

0.31

0.34

0.33

10--

----

--20

--80

1010

019

.5

Can

al0.

470.

550.

5110

----

----

--20

8010

100

12.9

LA0.

480.

540.

5110

----

----

----

100

1010

015

.5FL

0.47

0.54

0.50

10--

----

50--

--50

550

21.0

d

MS

0.47

0.55

0.51

10--

----

--10

--90

1010

021

.3

Can

al0.

730.

810.

7710

----

----

5020

3010

100

14.3

LA0.

720.

820.

77

8--

----

50--

--50

450

22.0

d

FL0.

720.

830.

7710

----

--80

----

202

2027

.0d

MS

0.72

0.83

0.77

10--

----

----

--10

010

100

26.2

Can

al0.

921.

090.

9910

----

----

70--

3010

100

14.2

LA0.

921.

090.

99

7--

----

57--

--43

343

22.0

d

FL0.

911.

100.

99

9--

----

100

----

00

--M

S0.

931.

080.

9910

----

--20

30--

508

80--

Sodi

um p

enta

chlo

roph

enat

eC

anal

0.41

0.47

0.44

10--

----

----

2080

1010

011

.1 a

nd s

odiu

m c

hrom

ate

LA0.

410.

470.

4410

----

----

----

100

1010

015

.6 3

.24:

1 ch

emic

al ra

tioFL

0.40

0.47

0.44

9

----

--44

----

565

5620

.3d

MS

0.40

0.47

0.44

10--

----

----

--10

010

100

23.0

Sodi

um p

enta

chlo

roph

enat

eC

anal

0.54

0.62

0.58

10--

----

----

--10

010

100

12.8

and

bor

axLA

0.54

0.62

0.58

9

----

----

11--

899

100

11.3

1:

0.76

che

mic

al ra

tioFL

0.53

0.62

0.57

8

----

----

----

100

1010

017

.9M

S0.

540.

610.

5810

----

----

20--

8010

100

21.0

1:

2 ch

emic

al ra

tioC

anal

0.71

0.80

0.75

10--

----

----

--10

010

100

12.2

LA0.

710.

810.

7510

----

----

10--

9010

100

9.9

FL0.

720.

820.

7610

----

----

----

100

1010

012

.9M

S0.

710.

800.

7510

----

----

----

100

1010

018

.8

(Pag

e 1

of 5

)

Tabl

e 5-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

coa

l-tar

cre

osot

e af

ter 1

5 to

55

year

s

Page 22: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 5-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

coa

l-tar

cre

osot

e af

ter 1

5 to

55

year

s of

ser

vice

. Sta

kes

plac

ed in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Feb

urar

y 19

41; B

ogal

usa,

LA,

Mar

ch 1

941;

Jac

kson

ville

, FL,

Mar

ch 1

941;

and

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Feb

ruar

y 19

41 (P

lot 5

)--co

ntin

ued C

ondi

tion

of s

take

s Ja

nuar

y 19

96c (

%)

Serv

icea

ble

but

Des

troye

d by

--R

eten

tion

ofsh

owin

g so

me-

-D

ecay

pre

serv

ativ

ea N

um-

Dec

ayfu

ngi

(lb/ft

3 )be

ran

dan

dAv

erag

eLo

ca-

Min

i-M

axi-

Aver

-in

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etio

nm

umm

umag

ete

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

1:

1.52

che

mic

al ra

tioC

anal

0.78

0.88

0.83

10--

----

--50

--50

1010

013

.0LA

0.77

0.88

0.82

10--

----

--30

--70

1010

010

.0FL

0.79

0.86

0.82

9

----

----

----

100

1010

016

.7M

S0.

790.

870.

8310

----

----

----

100

1010

018

.9

1:

3 ch

emic

al ra

tioC

anal

0.91

1.06

0.98

10--

----

----

--10

010

100

11.5

LA0.

901.

070.

9810

----

----

10--

9010

100

8.9

FL0.

921.

050.

9810

----

----

----

100

1010

013

.2M

S0.

921.

060.

9810

----

----

10--

9010

100

16.1

1:

2.27

che

mic

al ra

tioC

anal

1.00

1.19

1.09

10--

----

----

--10

010

100

12.7

LA1.

011.

161.

0910

----

----

20--

8010

100

9.9

FL1.

011.

181.

0910

----

----

----

100

1010

018

.6M

S1.

011.

181.

0910

----

----

----

100

1010

018

.6

1:

1.50

che

mic

al ra

tioC

anal

1.17

1.32

1.25

10--

----

--10

--90

1010

012

.8LA

1.17

1.32

1.25

10--

----

----

--10

010

100

14.6

FL1.

171.

321.

2510

----

--20

10--

708

8016

.5d

MS

1.17

1.33

1.25

10--

----

--10

1080

1010

020

.9

5% p

enta

chlo

roph

enol

C

anal

4.0

5.4

4.7

10--

----

--40

--60

1010

013

.0 i

n fu

el o

ileLA

4.0

5.4

4.8

10--

----

----

--10

010

100

16.6

FL 4

.0 5

.6 4

.810

----

--40

----

606

6020

.0d

MS

4.2

5.4

4.7

10--

----

----

--10

010

100

21.0

Can

al 8

.610

.5 9

.610

----

----

30--

7010

100

14.4

LA 8

.410

.9 9

.6 7

----

--57

----

433

4323

.0d

FL 8

.810

.5 9

.6 9

----

--67

----

333

3324

.0d

MS

8.6

10.5

9.6

10--

----

--10

--90

1010

027

.2

Can

al14

.016

.515

.310

----

--40

10--

506

6015

.0d

LA14

.216

.315

.3 7

----

--10

0--

----

----

--FL

14.2

16.3

15.3

10--

----

100

----

----

----

MS

14.0

16.3

15.3

10--

----

5010

--40

550

--

Can

al18

.621

.520

.110

----

--10

0--

----

----

--LA

18.2

21.7

20.1

7--

----

100

----

----

----

FL18

.221

.720

.1 9

--22

--78

----

----

----

MS

18.2

21.9

20.0

9--

----

89--

--11

111

--

(Pag

e 2

of 5

)

Page 23: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 5-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

coa

l-tar

cre

osot

e af

ter 1

5 to

55

year

s of

ser

vice

. Sta

kes

plac

ed in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Feb

urar

y 19

41; B

ogal

usa,

LA,

Mar

ch 1

941;

Jac

kson

ville

, FL,

Mar

ch 1

941;

and

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Feb

ruar

y 19

41 (P

lot 5

)--co

ntin

ued C

ondi

tion

of s

take

s Ja

nuar

y 19

96c (

%)

Serv

icea

ble

but

Des

troye

d by

--R

eten

tion

ofsh

owin

g so

me-

-D

ecay

pre

serv

ativ

ea N

um-

Dec

ayfu

ngi

(lb/ft

3 )be

ran

dan

dAv

erag

eLo

ca-

Min

i-M

axi-

Aver

-in

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etio

nm

umm

umag

ete

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

3% p

enta

chlo

roph

enol

+C

anal

4.2

5.8

4.9

10--

----

--20

--80

1010

012

.6 2

% c

hlor

o-2-

phen

ylph

enol

LA4.

45.

84.

910

----

----

----

100

1010

014

.2 i

n fu

el o

ileFL

4.4

5.8

4.9

9--

----

22--

--78

778

20.0

d

MS

4.2

5.8

4.9

10--

----

----

--10

010

100

19.2

Can

al9.

110

.910

.010

----

----

50--

5010

100

13.7

LA9.

110

.910

.0 6

----

--67

----

332

3324

.7d

FL8.

911

.010

.0 8

----

--75

----

252

2525

.3d

MS

8.9

11.0

10.0

10--

----

--10

--90

1010

024

.4

Can

al14

.216

.315

.410

----

--10

10--

809

9012

.0d

LA13

.816

.315

.3 6

----

--10

0--

----

----

--FL

13.8

16.3

15.3

9--

----

100

----

----

----

MS

14.4

16.1

15.3

10--

----

--40

--60

1010

031

.9

Coa

l-tar

cre

osot

e, g

rade

1C

anal

3.5

6.7

4.7

10--

----

1090

----

990

12.0

d

LA3.

36.

74.

6 6

----

--33

----

674

6722

.0d

FL3.

36.

54.

7 9

----

--33

33--

336

6719

.0d

MS

3.5

6.5

4.6

10--

----

--40

--60

1010

021

.3

Can

al8.

411

.610

.010

--60

--20

10--

102

2020

.0d

LA8.

611

.210

.0 4

----

--75

----

251

2526

.6d

FL8.

611

.410

.010

----

--90

10--

--1

10--

MS

8.4

11.4

10.0

10--

----

1060

--30

990

--

Can

al13

.515

.414

.410

1090

----

----

----

----

LA13

.515

.914

.5 6

5017

1717

----

----

----

FL13

.515

.914

.4 9

2256

--22

----

----

----

MS

13.3

16.1

14.5

10--

----

100

----

----

----

Fuel

oile

Can

al8.

211

.99.

910

----

----

--60

4010

100

5.9

LA8.

411

.79.

810

----

----

40--

6010

100

8.4

FL8.

211

.79.

8 8

----

----

12--

888

100

9.7

MS

8.2

11.7

9.8

10--

----

--20

1070

1010

06.

3

Can

al18

.221

.019

.410

----

----

--30

7010

100

7.8

LA18

.221

.419

.410

----

----

50--

5010

100

11.9

FL18

.221

.419

.4 9

----

----

----

100

1010

012

.4M

S18

.021

.919

.410

----

----

3010

6010

100

9.1

(Pag

e 3

of 5

)

Page 24: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 5-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

coa

l-tar

cre

osot

e af

ter 1

5 to

55

year

s of

ser

vice

. Sta

kes

plac

ed in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Feb

urar

y 19

41; B

ogal

usa,

LA,

Mar

ch 1

941;

Jac

kson

ville

, FL,

Mar

ch 1

941;

and

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Feb

ruar

y 19

41 (P

lot 5

)--co

ntin

ued C

ondi

tion

of s

take

s Ja

nuar

y 19

96c

(%)

Serv

icea

ble

but

Des

troye

d by

--R

eten

tion

ofsh

owin

g so

me-

-D

ecay

pre

serv

ativ

ea N

um-

Dec

ayfu

ngi

(lb/ft

3 )be

ran

dan

dAv

erag

eLo

ca-

Min

i-M

axi-

Aver

-in

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etio

nm

umm

umag

ete

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

5% p

enta

chlo

roph

enol

inC

anal

0.5

1.4

0.8

10--

----

----

9010

1010

02.

7 f

uel o

ile and

nap

htha

LA0.

51.

20.

810

----

----

30--

7010

100

4.2

3

-min

dip

FL0.

51.

20.

8 8

----

----

12--

888

100

5.0

MS

0.5

1.2

0.8

10--

----

--10

2070

1010

03.

2

1

8-h

soak

Can

al2.

12.

62.

410

----

----

----

100

1010

09.

1LA

2.1

2.8

2.4

9--

----

--33

--67

910

08.

4FL

2.1

3.0

2.4

10--

----

----

--10

010

100

11.9

MS

1.9

3.0

2.4

10--

----

----

--10

010

100

12.9

5% p

enta

chlo

roph

enol

inC

anal

0.7

1.2

0.9

10--

----

----

100

--10

100

3.3

soy

bean

oil,

nap

htha

and

LA0.

51.

20.

910

----

----

50--

5010

100

3.9

fue

l oil

e,f

FL0.

51.

60.

9 7

----

----

--14

867

100

5.4

3

-min

dip

MS

0.7

1.2

0.9

10--

----

----

6040

1010

04.

9

1

8-h

soak

Can

al2.

33.

72.

810

----

----

----

100

1010

010

.4LA

2.1

3.9

2.8

10--

----

--30

--70

1010

07.

6FL

2.3

3.2

2.7

10--

----

----

--10

010

100

12.2

MS

2.3

3.5

2.8

10--

----

----

--10

010

100

16.3

1

8-h

soak

gC

anal

1.1

3.0

2.3

10--

----

----

3070

1010

07.

0LA

1.8

2.6

2.3

10--

----

--20

--80

1010

06.

3FL

1.8

2.8

2.3

8--

----

--12

--88

810

09.

8M

S1.

12.

82.

210

----

----

1010

8010

100

11.9

3% p

enta

chlo

roph

enol

+ 2

%C

anal

0.9

1.6

1.2

10--

----

----

100

--10

100

2.3

chl

oro-

2-ph

enyl

phen

ol in

LA0.

91.

61.

210

----

----

40--

6010

100

4.1

nap

htha

and

fuel

oile

FL0.

71.

61.

210

----

----

1010

8010

100

5.0

3

-min

dip

MS

0.5

1.8

1.2

10--

----

--20

2060

1010

05.

3

1

8-h

soak

Can

al2.

54.

03.

110

----

----

--10

9010

100

9.0

LA2.

54.

03.

110

----

----

10--

9010

100

7.2

FL2.

33.

93.

1 8

----

----

12--

888

100

10.8

MS

2.6

4.4

3.1

10--

----

----

--10

010

100

13.8

(Pag

e 4

of 5

)

Page 25: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 5-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

chl

orin

ated

phe

nols

and

coa

l-tar

cre

osot

e af

ter 1

5 to

55

year

s of

ser

vice

. Sta

kes

plac

ed in

test

at B

arro

Col

orad

o Is

land

, Can

al Z

one,

Feb

urar

y 19

41; B

ogal

usa,

LA,

Mar

ch 1

941;

Jac

kson

ville

, FL,

Mar

ch 1

941;

and

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Feb

ruar

y 19

41 (P

lot 5

)--co

nclu

ded C

ondi

tion

of s

take

s Ja

nuar

y 19

96c (

%)

Serv

icea

ble

but

Des

troye

d by

--R

eten

tion

ofsh

owin

g so

me-

-D

ecay

pre

serv

ativ

ea N

um-

Dec

ayfu

ngi

(lb/ft

3 )be

ran

dan

dAv

erag

eLo

ca-

Min

i-M

axi-

Aver

-in

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etio

nm

umm

umag

ete

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

3% p

enta

chlo

roph

enol

+ 2

%C

anal

0.5

0.9

0.8

10--

----

----

9010

1010

01.

6 c

hlor

o-2-

phen

ylph

enol

inLA

0.5

0.9

0.7

10--

----

--30

--70

1010

03.

9 s

olve

nt o

f 80%

min

eral

spi

rits

FL0.

50.

90.

810

----

----

2010

7010

100

2.8

and

20%

moi

stur

e re

pella

ntM

S0.

50.

90.

810

----

----

2030

5010

100

3.6

3

-min

dip

1

8-h

soak

Can

al2.

15.

83.

410

----

----

--90

1010

100

4.8

LA2.

34.

63.

410

----

----

----

100

1010

09.

2FL

2.3

4.9

3.4

10--

----

--20

--80

1010

09.

6M

S2.

35.

13.

410

----

----

2010

7010

100

12.7

Unt

reat

ed c

ontro

lsC

anal

----

--10

----

----

--10

0--

1010

01.

2LA

----

--10

----

----

5020

3010

100

2.4

FL--

----

10--

----

--10

2070

1010

01.

8M

S--

----

10--

----

--30

4030

1010

02.

4

a Base

d up

on w

eigh

t of d

ry c

hem

ical

for s

odiu

m p

enta

chlo

roph

enat

e al

one

or m

ixed

with

oth

er c

hem

ical

s an

d on

wei

ght o

f sol

utio

n fo

r oth

er t

reat

men

ts.

Valu

es fo

r sta

kes

orig

inal

ly in

stal

led.

b Ten

stak

es w

ere

orig

inal

ly in

stal

led

in te

st.

This

num

ber h

as s

ince

bee

n re

duce

d ei

ther

bec

ause

of f

ailu

re to

loca

te th

e st

akes

at t

he ti

me

of t

he in

spec

tion

or b

ecau

se o

f dam

age

by fi

re.

c Fina

l ins

pect

ion

at C

anal

Zon

e, J

anua

ry 1

956;

at J

acks

onvi

lle, F

L, N

ovem

ber 1

960;

and

at B

ogal

usa,

LA,

Dec

embe

r 196

2.

d Estim

ate

base

d up

on p

erce

ntag

e of

sta

kes

rem

aini

ng a

fter f

inal

insp

ectio

n.

e Purc

hase

d an

d re

porte

d ea

rlier

as

No.

2 fu

el o

il bu

t has

sin

ce b

een

foun

d to

hav

e a

dist

illatio

n ra

nge

low

er th

an th

at fo

r typ

ical

No.

2 fu

el o

ils.

f Solv

ent c

onta

ined

1 p

art s

oybe

an o

il an

d 9

parts

eac

h of

fuel

and

nap

htha

by

volu

me.

g Spec

imen

s co

ntai

ned

som

e he

artw

ood.

This

stu

dy w

as in

itiat

ed b

y R

. M. W

irka.

(Pag

e 5

of 5

)

Page 26: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 6-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s of

diff

eren

t siz

es tr

eate

d w

ith c

oal-t

ar c

reos

ote,

tolu

ene,

and

cre

osot

e-to

luen

e m

ixtu

res

afte

r54

-1/2

yea

rs o

f ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, M

ay 1

951

(Plo

t 6)

Con

ditio

n of

sta

kes

Janu

ary

1996

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

Stak

e si

zere

tent

ion

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(in.)

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Coa

l-tar

cre

osot

e1/

2 by

1/2

by

18

7.8

8--

----

--88

--12

810

017

.1

1 by

1 b

y 18

8

.010

----

----

40--

6010

100

23.6

1-1/

2 by

1-1

/2 b

y 18

7

.910

----

----

50--

5010

100

26.6

2 by

4 n

omin

al b

y 18

3

.310

----

----

10--

9010

100

24.9

7

.810

----

--30

20--

507

70--

13.

210

----

--80

10--

102

20--

Tolu

ene

2 by

4 n

omin

al b

y 18

29.

510

----

----

--90

1010

100

2.2

Coa

l-tar

cre

osot

e 1

1.25

% b

y w

eigh

t in

tolu

ene

2 by

4 n

omin

al b

y 18

3

.4a

10--

----

--30

--70

1010

019

.1

25.

2% b

y w

eigh

t in

tolu

ene

2 by

4 n

omin

al b

y 18

8

.1a

10--

----

3040

--30

770

--

39.

0% b

y w

eigh

t in

tolu

ene

2 by

4 n

omin

al b

y 18

12

.6a

1010

----

90--

----

----

--

a Cre

osot

e on

ly.

This

stu

dy w

as in

itiat

ed b

y R

. M. W

irka.

Page 27: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 7-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per n

apht

hena

te a

nd z

inc

naph

then

ate

afte

r abo

ut 5

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

at M

adis

on, W

I, O

ctob

er 1

941,

and

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Feb

ruar

y 19

42 (P

lot 7

)

Con

ditio

n of

sta

kes

Oct

ober

199

2a (%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

ere

tent

ionb

inTe

rmite

Term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Trea

tmen

tLo

catio

n (l

b/ft3 )

test

cG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Zinc

nap

hthe

nate

Brus

h, o

ne c

oat

MS

0.6

(0.0

12)

10--

----

----

2080

1010

02.

9

sol

utio

n 17

%

WI

0.5

(0.0

10)

10--

----

--10

0--

--10

100

6.4

(2

% z

inc

met

al)

Dip

, 3

min

MS

1.0

(0.0

20)

10--

----

----

4060

1010

02.

2W

I0.

9 (0

.018

)10

----

----

100

----

1010

07.

7

1%

(0.1

2% z

inc

met

al)

Pres

sure

MS

9.9

(0.0

12)

10--

----

--50

--50

1010

011

.2W

I9.

7 (0

.011

)10

----

----

100

----

1010

019

.1

2.5

% (0

.29%

zin

c m

etal

)Pr

essu

reM

S10

.3 (0

.030

)10

----

----

50--

5010

100

15.0

WI

9.8

(0.0

29)

10--

----

--10

0--

--10

100

21.9

5.0

% (0

.59%

zin

c m

etal

)Pr

essu

reM

S10

.2 (0

.060

)10

----

----

60--

4010

100

13.5

WI

10.3

(0.0

61)

10--

----

--10

0--

--10

100

22.6

7.5

% (0

.88%

zin

c m

etal

)Pr

essu

reM

S10

.4 (0

.092

)10

----

----

60--

4010

100

19.7

WI

10.0

(0.0

88)

9d

----

----

100

----

910

030

.8

Cop

per n

apht

hena

te

Brus

h, o

ne c

oat

MS

0.5

(0.0

10)

10--

----

--20

5030

1010

03.

7

sol

utio

n 17

.5%

WI

0.5

(0.0

10)

10--

----

--10

0--

--10

100

8.6

(2

% c

oppe

r met

al)

Dip

, 3

min

MS

0.7

(0.0

14)

10--

----

--40

6010

100

5.2

WI

0.8

(0.0

15)

10--

----

--10

0--

--10

100

9.8

1%

(0.1

1% c

oppe

r met

al)

Pres

sure

MS

10.3

(0.0

12)

10--

----

--80

--20

1010

015

.9W

I10

.3 (0

.012

) 8

----

----

100

----

810

025

.5

2.5

% (0

.29%

cop

per m

etal

)Pr

essu

reM

S10

.2 (0

.029

)10

----

----

40--

6010

100

21.8

WI

9.6

(0.0

27)

4--

----

--10

0--

--4

100

34.5

5.0

% (0

.57

copp

er m

etal

)Pr

essu

reM

S10

.6 (0

.061

)10

----

----

80--

2010

100

27.1

WI

10.6

(0.0

61)

617

----

--83

----

583

--

7.5

% (0

.86%

cop

per m

etal

)Pr

essu

reM

S 9

.6 (0

.082

)10

20--

----

60--

208

8029

.6W

I9.

8 (0

.084

) 3

----

----

100

----

310

035

.4

Unt

reat

ed c

ontro

ls--

MS

--10

----

----

--30

7010

100

1.8

--W

I--

10--

----

--10

0--

--10

100

4.9

a Last

insp

ectio

n in

Mis

siss

ippi

was

198

5.b N

umbe

r in

pare

nthe

ses

is th

e re

tent

ion

base

d on

zin

c or

cop

per m

etal

.c Te

n st

akes

wer

e or

igin

ally

inst

alle

d. T

his

num

ber h

as b

een

redu

ced

for c

ause

s ot

her t

han

deca

y or

inse

ct a

ttack

.d Av

erag

e re

tent

ion

base

d on

nin

e st

akes

.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 28: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 8-

-Con

ditio

n of

trea

ted

five-

ply

exte

rior D

ougl

as-fi

r ply

woo

d st

akes

(app

roxi

mat

ely

1/2

by 4

by

18 in

.) at

fina

l ins

pect

ion

afte

r app

roxi

mat

ely

22

year

s of

exp

osur

e. S

take

s pl

aced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, F

ebru

ary

1942

(Plo

t 8)

Con

ditio

n of

sta

kes

Dec

embe

r 196

3 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Coa

l-tar

cre

osot

eBr

ush,

one

coa

tO

il

1.4

30--

----

--27

2727

3010

0

6.1

Dip

, 3 m

inO

il

1.9

30--

----

--17

2063

3010

0

9.4

Soak

, 18

hO

il

5.6

30--

7--

4727

--20

1447

24.0

b

Pres

sure

Oil

5.

930

----

--70

20--

10

930

27.0

b

Pres

sure

Oil

12.2

2928

387

28--

----

----

--

Pent

achl

orop

heno

l sol

utio

nc

5%Br

ush,

one

coa

tSo

lutio

n

0.9

30--

----

--10

6030

d30

100

2.8

Dip

, 3 m

inSo

lutio

n

1.3

30--

----

--13

6027

3010

0 3

.3So

ak, 1

8 h

Solu

tion

3.

230

----

----

333

6330

100

5.0

1.11

%Pr

essu

reSo

lutio

n26

.330

----

----

20--

80e

3010

011

.12.

25%

Pres

sure

Solu

tion

26.3

30--

----

2310

760

2377

19.0

b

Zinc

nap

hthe

nate

sol

utio

nf

4.8%

(0.5

5% z

inc)

Brus

h, o

ne c

oat

Solu

tion

0.

730

----

----

1030

6030

100

2.1

Dip

, 3 m

inSo

lutio

n 1.

130

----

----

754

4030

100

2.0

Soak

, 18

hSo

lutio

n3.

030

----

----

1343

4330

100

2.9

1.11

% (0

.13%

zin

c)Pr

essu

reSo

lutio

n 25

.530

----

----

1320

6730

100

5.3

2.25

% (0

.25%

zin

c)Pr

essu

reSo

lutio

n 25

.630

----

----

13 7

8030

100

8.9

Chl

oro-

2-ph

enyl

phen

ol s

olut

ionf

5%Br

ush,

one

coa

tSo

lutio

n .9

30--

----

--10

5040

3010

02.

2D

ip, 3

min

Solu

tion

1.2

30--

----

--17

4737

3010

02.

4So

ak, 1

8 h

Solu

tion

2.9

30--

----

--13

6027

3010

02.

6

Unt

reat

ed c

ontro

ls--

--30

----

----

2040

40e

3010

01.

8

a Of t

he 3

0 pa

nels

test

ed fo

r eac

h tre

atm

ent,

thre

e se

ts c

onta

ined

10

spec

imen

s; e

ach

set w

as s

elec

ted

from

mat

eria

l con

tribu

ted

by a

diff

eren

t man

ufac

ture

r.

b Estim

ate

base

d on

con

ditio

n of

sta

kes

at fi

nal i

nspe

ctio

n.c So

lven

t con

tined

1 p

art p

ine

oil a

nd 1

2 pa

rts S

todd

ard-

type

sol

vent

by

volu

me.

d Two

stak

es s

how

ed s

ome

dela

min

atio

n.e O

ne s

take

sho

wed

som

e de

lam

inat

ion.

f Stod

dard

-type

sol

vent

use

d.

NO

TE:

The

stak

es re

mai

ning

in te

st a

fter t

he 1

950

insp

ectio

n w

ere

take

n up

and

rese

t in

the

sam

e ge

nera

l are

a.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

and

R. M

. Wirk

a.

Trea

tmen

t

Page 29: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 9-

-Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per a

rsen

ate

and

copp

er c

hrom

ate

by th

e do

uble

-diff

usio

n pr

oces

saf

ter a

bout

55

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, F

ebru

ary

1942

(Plo

t 9)

Con

ditio

n of

sta

kes

Janu

ary

1997

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ay C

alcu

late

d re

tent

ion

of c

hem

ical

a (lb/

ft3 )N

um-

Dec

ayfu

ngi

Cop

per

Chr

omiu

m

Arse

nic

ber

and

and

Aver

age

asas

asin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Trea

tmen

tC

uSO

4N

a 2 C

rO4

Na 2

Has

O4

Tota

lte

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

6-da

y so

ak in

10.

6% c

oppe

rsu

lfate

sol

utio

n pl

us

6-da

y so

ak in

9.

8% s

odiu

mar

sena

te s

olut

ion

0.66

(0.3

3)--

0.59

(0.3

6)1.

25 (0

.69)

1070

2010

----

----

----

--

12-d

ay s

oak

in9.

8% s

odiu

mar

sena

te s

olut

ion

0.66

(0.3

3)2.

58 (1

.59)

0.75

(0.4

6)1.

41 (0

.79)

1060

3010

----

----

----

--

12-d

ay s

oak

in11

.8%

sod

ium

chro

mat

e so

lutio

n0.

66 (0

.33)

----

3.24

(1.9

2)10

80--

----

10--

10 2

20

--

3-da

y so

ak in

10.

6% c

oppe

rsu

lfate

sol

utio

n pl

us

6-da

y so

ak in

9.

8% s

odiu

mar

sena

te s

olut

ion

0.88

(0.4

4)--

0.55

(0.3

4)1.

43 (0

.78)

1030

70--

----

----

----

--

6-da

y so

ak in

11

.8%

sod

ium

chro

mat

e so

lutio

n0.

88 (0

.44)

1.57

(0.9

7)--

2.45

(1.4

1) 9

67--

----

2211

-- 3

33

--

3-da

y so

ak in

5.3

% c

oppe

rsu

lfate

sol

utio

n pl

us

6-da

y so

ak in

4.9%

sod

ium

--ar

sena

te s

olut

ion

0.31

(0.1

5)--

0.17

(0.1

0)0.

48 (0

.25)

9--

67--

--22

11 3

33

--

6-da

y so

ak in

5.9%

sod

ium

--ch

rom

ate

solu

tion

0.31

(0.1

5)0.

50 (0

.31)

--0.

81 (0

.46)

933

----

--33

33 6

67

--

Unt

reat

ed c

ontro

ls--

----

--10

----

----

--20

8010

100

1.9

a Ret

entio

n va

lues

in p

aren

thes

es a

re o

xide

s (C

uO -

CrO

3 - A

s 2O

5)b Te

n st

akes

orig

inal

ly in

stal

led;

elim

inat

ed s

take

s re

mov

ed fo

r cau

ses

othe

r tha

n de

cay

or in

sect

atta

ck.

This

stu

dy w

as in

itiat

ed b

y R

. H. B

aech

ler.

Page 30: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 10

.--C

ondi

tion

of u

rea-

treat

ed S

outh

ern

Pine

sta

kes

(2 b

y 4

in. n

omin

al b

y 18

in.)

afte

r abo

ut 1

4 to

19

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, F

ebru

ary

1942

and

Dec

embe

r 194

6, a

nd a

t Mad

ison

, WI,

April

194

2 (P

lot 1

0)

Con

ditio

n of

sta

kes

late

in 1

960

(%)

Aver

age

Serv

icea

ble

but

Des

troye

d by

--To

tal

rete

ntio

nsh

owin

g so

me-

-D

ecay

rete

ntio

nof

Num

-D

ecay

fung

iof

ure

a ur

eabe

ran

dan

dAv

erag

eor

sol

idsa

or s

olid

sain

Term

itete

rmite

Dec

ayTe

rmite

term

itelif

e

Trea

tmen

tLo

catio

n(lb

) (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Inst

alle

d 19

42

2-da

y so

akb

MS

4.7

3.4

10--

----

----

1090

1010

03.

4W

I4.

73.

410

----

----

100

----

1010

08.

1

4-da

y so

akb

MS

6.9

5.0

10--

----

----

2080

1010

03.

3W

I6.

95.

010

----

----

100

----

1010

08.

0

6-da

y so

akb

MS

10.2

7.4

10--

----

----

2080

1010

02.

9W

I10

.27.

410

----

----

100

----

1010

06.

0

B 1c (t

herm

oset

ting)

MS

9.9

7.1

10--

----

----

2080

1010

04.

5 2

-day

soa

kW

I9.

97.

110

----

----

100

----

1010

012

.5

B 1c (t

herm

oset

ting)

MS

11.2

8.1

10--

----

----

-- 1

0010

100

5.1

4-d

ay s

oak

WI

11.2

8.1

10--

----

--10

0--

--10

100

13.2

B 1

c (the

rmos

ettin

g)M

S11

.78.

410

----

----

--10

9010

100

5.6

6-d

ay s

oak

WI

11.7

8.4

10--

----

--10

0--

--10

100

15.2

Unt

reat

ed c

ontro

lsM

S--

--10

----

----

--20

8010

100

1.8

WI

----

10--

----

--10

0--

--10

100

4.8

Inst

alle

d 19

46

Ure

a re

sin,

pre

ssur

edM

S--

5.8

10--

----

--10

--90

1010

09.

1a C

alcu

late

d to

tal r

eten

tion

of u

rea

or s

olid

s fo

r 22

stak

es.

b Trea

ting

solu

tion

mad

e up

to 1

.15

parts

of u

rea

to 1

.00

part

of w

ater

by

wei

ght.

c Solu

tion

mad

e up

of 3

80 p

arts

ure

a, 3

44 p

arts

of 3

7% fo

rmal

dehy

de s

olut

ion,

231

par

ts w

ater

, 6 p

arts

sod

ium

hyd

roxi

de, a

nd 3

9 pa

rts b

orax

by

wei

ght.

d Trea

ted

with

buf

fere

d ur

ea-fo

rmal

in m

ix (2

to 1

form

alde

hyde

-ure

a ra

tio) a

t a re

sin

solid

s co

nten

t of 3

0%.

This

stu

dy w

as in

itiat

ed b

y H

arve

y H

. Sm

ith a

nd J

. Osc

ar B

lew

.

Tota

l rem

oved

Page 31: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 11--Condition of high-strength laminated paper plastic (papreg) stakes (1/8 by 4 by 14 in.) andheat stabilized plywood (Staypak) stakes (4 by 18 in.) of several thicknesses after 7 to 8 years of service.Stakes placed in test on the Harrison Experimental Forest, Saucier, MS (Plot 11)

December 1950 stakes destroyed by--Decay

Num- fungi andber termite Average

Stake in Decay fungi Termite attack attack lifenumber Composition test Number % Number % Number % (year)

Laminated Paper Plastic (Papreg)--Installed December 2, 1942

1 to 10 37.0% phenolic resina + 2% hardener, 4.7% volatile matter 10 7 70 -- -- 3 30 7.4

11 to 20 31.0% phenolic resina + 2% hardener, 10 2 20 1 10 7 70 5.6 4.4% volatile matter

21 to 30 41.0% phenolic resina + 2% hardener, 10 7 70 -- -- 3 30 8.0 4.6% volatile matter

31 to 40 37.0% phenolic resina + 2% hardener, 10 7 70 -- -- 3 30 7.2 4.7% volatile matter with surface sheets using 42.6% phenolic resin,a

4.6% volatile matterb

41 to 50 37.0% phenolic resina + 0.5% oleic 10 4 40 1 10 5 50 7.7 acid, 4.7% volatile matter

Heat-Stabilized Plywood (Staypak)--Installed June 4, 1943

19-1 and 20 plies 1/16-in. birch bonded with 2 -- -- 1 50 1 50 4.5 19-2 phenolic resin and compressed to

thickness of 1/2 in.; specific gravity 1.37

Heat-Stabilized Plywood (Staypak)--Installed December 6, 1943

s-1 to 32 plies 1/16-in. birch bonded with 5 -- -- -- -- 5c 100 5.6 s-5 phenolic resin and compressed to

thickness of 1 in.; specific gravity 1.33

21-1 to 10 plies 1/8-in. maple bonded with 5 -- -- -- -- 5 100 4.3 21-5 phenolic resin and compressed to

thickness of 5/8 in.; specific gravity 1.36

aAlcohol-soluble.bSingle surface sheet on each side, coated side out.cHeavy swelling at edges due to moisture absorption.

This study was initiated by A. H. Rauch and J. Oscar Blew.

Page 32: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 12

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

phe

nyl m

ercu

ry o

leat

e, p

enta

chlo

roph

enol

, cop

per n

apht

hena

te, a

nd

mer

curic

chl

orid

e at

fina

l ins

pect

ion

afte

r 20

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

943

(Plo

t 12)

Con

ditio

n of

sta

kes

Dec

embe

r 196

3 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

Aver

age

show

ing

som

e--

Dec

ayre

tent

ion

Num

-D

ecay

fung

iof

ber

and

and

Aver

age

solu

tion

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Trea

tmen

t (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Phen

yl m

ercu

ry o

leat

e (p

erce

ntag

e i

n na

ptha

sol

vent

)0.

43-

min

dip

1.4

10--

----

----

2080

1010

03.

70.

418

-hr s

oak

3.2

10--

----

--10

3060

1010

04.

90.

4Pr

essu

re5.

910

----

----

--10

9010

100

6.7

0.4

Pres

sure

12.1

10--

----

--30

--70

1010

08.

8

0.2

18-h

r soa

k3.

110

----

----

1030

6010

100

4.4

0.2

Pres

sure

6.0

10--

----

----

3070

1010

05.

60.

2Pr

essu

re11

.810

----

----

--30

7010

100

6.2

0.1

18-h

r soa

k3.

610

----

----

--40

6010

100

4.4

0.1

Pres

sure

5.9

10--

----

----

3070

1010

04.

60.

1Pr

essu

re11

.610

----

----

--40

6010

100

5.1

0.4a

3-m

in d

ip1.

210

----

----

--60

4010

100

3.9

0.1a

18-h

r soa

k6.

010

----

----

--20

8010

100

5.5

0.1a

Pres

sure

6.1

10--

----

--10

4050

1010

06.

20.

1aPr

essu

re12

.010

----

----

--10

9010

100

8.4

Pent

achl

orop

heno

l (5.

0%Pr

essu

re12

.110

----

--40

20--

406

6

0

20.

0b

in

pin

e-oi

l nap

htha

(1:1

2) s

olve

nt

Cop

per n

apht

hena

te (0

.5%

cop

per

Pres

sure

13.1

10--

----

7020

--10

3

30

2

5.0b

met

al in

nap

htha

sol

vent

)

(0.0

66)c

Mer

curic

chl

orid

e (1

.0%

in w

ater

)3-

min

dip

0.01

410

----

----

--50

5010

100

4.8

dr

y sa

lt18

-h s

oak

0.07

210

----

----

--20

8010

100

7.5

dr

y sa

lt

Unt

reat

ed c

ontro

ls--

--10

----

----

--60

4010

100

2.0

a Solu

tion

cont

aine

d 16

% s

olid

s as

a w

ater

repe

llent

.b Es

timat

e ba

sed

on p

erce

ntag

e of

sta

kes

rem

aini

ng a

fter f

inal

insp

ectio

n.c R

eten

tion

valu

es in

par

enth

eses

are

bas

ed o

n co

pper

met

al.

NO

TE:

The

stak

es re

mai

ning

in te

st a

fter t

he 1

952

insp

ectio

n w

ere

take

n up

and

rese

t in

the

sam

e ge

nera

l are

a.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 33: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 13--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with fire-retardantchemicals after 7 years of service. Stakes placed in test December 1943 on the HarrisonExperimental Forest, Saucier, MS, and inspected December 1950 (Plot 13)

December 1950 stakes destroyed by--

DecayRetention Num- fungi and

of dry ber termite Averagesalt in Decay fungi attack life

Treating chemicals (lb/ft3) test Number % Number % (year)

Ammonium sulfate, 78 parts; ammonium phosphate, 19 parts; sodium 3.01 10 5 50 5 50 2.4 dichromate, 3 parts (by weight) 6.17 10 6 60 4 40 3.4

Ammonium phosphate, 10 parts; ammonium sulfate, 60 parts; borax, 10 parts; 2.98 10 4 40 6 60 3.9 boric acid, 20 parts (by weight) 6.19 10 2 20 8 80 4.3

Borax, 60 parts; boric acid, 3.01 10 3 30 7 70 6.0 40 parts (by weight) 6.29 10 6 60 4 40 6.5

Untreated controls -- 10 2 20 8 80 2.2

This study was initiated by J. Oscar Blew.

Page 34: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 14--Condition of Southern Pine sapwood stakes (2 by 4 in. nominal by 18 in.) treated with various chemicals and of laminated acetylated yellow birch sapwood stakes (0.4 by 3-1/2 by 15-3/4 in.) after 55 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1944 (Plot 14)

Serviceable but Destroyed by--Average Decay

retention of Num- Decay fungipreservative ber and and Averageor dry saltb in Termite termite Decay Termite termite Total removed life

Preservativea (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Pine stakes

Ammoniacal copper arsenate (Fed. Spec. TT-W-549) (percentage in solution)

0.612 (0.59)b 0.25 (0.24) 9 -- 11 -- -- 67 -- 22 8 89 --1.29 (1.24) 0.53 (0.51) 10 -- 80 -- 10 10 -- -- 1 10 --2.57 (2.48) 1.01 (0.97) 10 70 30 -- -- -- -- -- -- -- --3.21 (3.10) 1.29 (1.25) 10 100 -- -- -- -- -- -- -- -- --

Amyl phenyl acetate (percentage in Stoddard solvent)

0.37 0.10 10 -- -- -- -- -- -- 100 10 100 6.70.93 0.03 10 -- -- -- -- -- -- 100 10 100 8.51.85 0.50 10 -- -- -- -- -- 40 60 10 100 10.0

Capric acid (percentage in Stoddard solvent)

0.37 0.10 10 -- -- -- -- 10 30 60 10 100 5.00.90 0.25 10 -- -- -- -- 10 20 70 10 100 5.31.76 0.50 10 -- -- -- -- -- 10 90 10 100 5.5

Diamyl pheno (percentage in Stoddard solvent)

0.37 0.10 10 -- -- -- -- -- 10 90 10 100 5.80.90 0.25 10 -- -- -- -- -- 10 90 10 100 8.41.76 0.51 10 -- -- -- -- -- 10 90 10 100 11.4

DDT (Dichloro-diphenyl-trichloroethane) (percentage in Stoddard solvent)

1.25 0.35 10 -- -- -- -- 100 -- -- 10 100 7.12.70 0.74 10 -- -- -- -- 70 -- 30 10 100 9.0

Dodecyl amine (percentage in Stoddard solvent)

0.37 0.10 10 -- -- -- -- -- 20 80 10 100 5.40.93 0.25 10 -- -- -- -- -- -- 100 10 100 5.71.85 0.50 10 -- -- -- -- -- 10 90 10 100 6.8

Nickel stearate (percentage in coal-tar naphtha)

0.33 0.10 10 -- -- -- -- 10 -- 90 10 100 5.60.93 0.27 10 -- -- -- -- 30 -- 70 10 100 4.91.85 0.52 10 -- -- -- -- 10 10 80 10 100 5.5

Untreated controls -- 10 -- -- -- -- -- 40 60 10 100 2.1

Yellow birch (laminated)c

Acetylated -- 10 -- -- -- -- 90 -- 10 10 100 17.5

Untreated controls -- 10 -- -- -- -- 10 10 80 10 100 2.7

aAll stakes except laminated yellow birch were pressure treated.bAmmoniacal copper arsenate solution and retention figures in parentheses are oxides (CuO and As2O5).cPrepared from six-ply, parallel-laminated, acetylated 1/16-in. veneer glued with hot-press phenolic resin. Average acetyl content 19.2% based upon ovendry weight of wood. Untreated controls prepared from untreated veneer.

NOTE: The stakes remaining in test after the 1952 inspection were reset in the same general area.

This study was initiated by A. H. Rauch and J. Oscar Blew.

Condition of stakes January 1999 (%)

showing some--

Page 35: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 15

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

aci

d co

pper

chr

omat

e, c

hrom

ated

cop

per

arse

nate

type

I, a

nd n

icke

l-ars

enic

-chr

omiu

m s

alts

afte

r 55

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t,Sa

ucie

r, M

S, D

ecem

ber 1

945

(Plo

t 15)

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nain

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Acid

cop

per c

hrom

ate

0.25

(0.1

3)10

----

----

1030

6010

100

11.6

(Fe

d. S

pec.

TT-

W-5

46)

0.51

(0.2

6)10

----

--30

50--

207

70--

0.75

(0.3

7)10

--10

1030

50--

--5

50--

Chr

omat

ed c

oppe

r ars

enat

e ty

pe I

0.26

(0.1

5)10

----

----

2010

7010

100

28.7

(Fe

d. S

epc.

TT-

W-5

50)

0.50

(0.2

9)10

--20

--50

30--

--3

30--

0.78

(0.4

4)10

1010

4020

20--

--2

20--

Nic

kel-a

rsen

ic-c

hrom

ium

sal

tsb

0.26

(0.1

6)10

----

----

1030

6010

100

17.4

0.50

(0.3

2)10

----

----

2010

7010

100

41.2

0.77

(0.5

0)10

----

--50

50--

--5

50--

Unt

reat

ed c

ontro

ls--

10--

----

--10

3060

1010

03.

2

a Ret

entio

n va

lues

in p

aren

thes

es b

ased

on

pres

erva

tive

oxid

es.

b Nic

kel s

ulfa

te (N

iSO

4 6

H2O

), 5.

5 pa

rts; s

odiu

m a

rsen

ate

(NaH

AsO

4 1

2H2O

), 4.

0 pa

rts; a

rsen

ic a

cid

(H3A

sO4)

, 1

.5 p

arts

; and

sod

ium

dic

hrom

ate

(Na 2

Cr 2

O7

2H

2O),

3.0

parts

).

Page 36: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 16

--Con

ditio

n of

Dou

glas

-fir p

lyw

ood

stak

es tr

eate

d w

ith s

ever

al w

ood

pres

erva

tives

, eith

er b

efor

e or

afte

r glu

ing

of th

e ve

neer

, afte

r 51

year

sof

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

945

(Plo

t 16)

Con

ditio

n of

sta

kes

Janu

ary

1996

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

Plyw

ooda

show

ing

som

e--

Dec

ayN

um-

Vene

erN

um-

Dec

ayfu

ngi

ber

thic

k-Av

erag

ebe

ran

dan

dAv

erag

eof

ness

rete

ntio

nb,c

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Trea

tmen

tpl

ies

(in.)

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Plyw

ood

from

Ven

eer T

reat

ed B

efor

e G

luin

gC

oal-t

ar c

reos

ote

Pres

sure

131/

1640

.910

80--

--20

----

----

----

Pres

sure

71/

830

.99

5611

1122

----

----

----

Hea

ting

and

1-ho

ur c

old

bath

d7

1/8

12.6

10--

----

--10

2070

1010

010

.224

-hou

r col

d so

ak13

1/16

12.9

1030

4010

20--

----

----

--24

-hou

r col

d so

ak7

1/8

8.4

9--

11--

89--

----

----

--10

-sec

ond

dipp

ing

131/

165.

19g

--56

1122

----

----

----

10-s

econ

d di

ppin

g7

1/8

4.6

9--

22--

67--

----

----

--C

oppe

r nap

hthe

nate

,Pr

essu

re13

1/16

15.5

(0.3

1)9

6722

--11

----

----

----

2%

cop

per m

etal

Pres

sure

71/

810

.2 (0

.20)

1030

30--

40--

----

----

-- i

n co

al-ta

r nap

htha

Hea

ting

and

1-ho

ur c

old

bath

d7

1/8

6.7

(0.1

3)9

1111

--67

11--

--1

11--

24-h

our c

old

soak

131/

1610

.1 (0

.20)

10--

40--

60--

----

----

--24

-hou

r col

d so

ak7

1/8

6.2

(0.1

2)10

----

--70

20--

103

30--

10-s

econ

d di

ppin

g13

1/16

4.2

(0.0

84)

10--

20--

80--

----

----

--10

-sec

ond

dipp

ing

71/

82.

8 (0

.056

)10

----

----

50--

5010

100

32.5

Pent

achl

orop

heno

l,Pr

essu

re13

1/16

21.4

9--

2211

67--

----

----

-- 5

% in

No.

2Pr

essu

re7

1/8

18.2

10--

----

5030

--20

550

-- f

uel o

ilH

eatin

g an

d 1-

hour

col

d ba

thd

71/

810

.310

----

--30

10--

607

70--

24-h

our c

old

soak

131/

167.

49

----

--33

44--

226

67--

24-h

our c

old

soak

71/

84.

810

----

----

1010

8010

100

23.1

10-s

econ

d di

ppin

g13

1/16

4.9

10--

----

1030

--60

990

--10

-sec

ond

dipp

ing

71/

81.

010

----

----

10--

9010

100

15.8

Chr

omat

edPr

essu

re13

1/16

1.02

e (0.6

2)6

----

--50

17--

333

50--

zin

c ch

lorid

ePr

essu

re7

1/8

1.06

e (0.6

5)10

----

----

--40

6010

100

25.8

Hea

ting

and

1-ho

ur c

old

bath

d7

1/8

0.98

(0.6

0)10

----

----

--50

5010

100

10.3

24-h

our s

teep

ing

131/

16f

1.07

(0.6

5)8

----

--88

----

121

12--

24-h

our s

teep

ing

131/

161.

84 (1

.12)

8g--

--13

5025

--12

327

--24

-hou

r ste

epin

g7

1/8f

0.59

(0.3

6)10

----

----

--10

9010

100

17.0

24-h

our s

teep

ing

71/

81.

30 (0

.79)

10--

----

--10

2070

1010

023

.610

-sec

ond

dipp

ing

131/

16f

0.61

(0.3

7)10

----

----

3010

6010

100

22.7

10-s

econ

d di

ppin

g13

1/16

0.66

(0.4

0)10

----

----

10--

9010

100

22.1

10-s

econ

d di

ppin

g7

1/8

0.35

(0.2

1)10

----

----

--20

8010

100

10.8

Acid

cop

per

Pres

sure

131/

160.

76 (0

.38)

9g--

--22

6711

----

111

-- c

hrom

ate

Pres

sure

71/

80.

79 (0

.39)

911

----

6722

----

222

--H

eatin

g an

d 1-

hour

col

d ba

thd

71/

81.

07 (0

.53)

10--

----

6030

--10

440

--24

-hou

r ste

epin

g13

1/16

f0.

88 (0

.44)

944

1133

11--

----

----

--24

-hou

r ste

epin

g13

1/16

1.89

(0.9

4)10

40--

4020

----

----

----

24-h

our s

teep

ing

71/

80.

54 (0

.27)

922

1122

3311

----

111

--24

-hou

r ste

epin

g7

1/8

1.32

(0.6

5)10

2010

2050

----

----

----

10-s

econ

d di

ppin

g13

1/16

0.87

(0.4

3)10

----

--70

30--

--3

30--

10-s

econ

d di

ppin

g13

1/16

0.61

(0.3

0)9

--11

--44

44--

--4

44--

10-s

econ

d di

ppin

g7

1/8

0.27

(0.1

3)10

----

----

20--

8010

100

18.4

10-s

econ

d di

ppin

g7

1/8

0.38

(0.1

9)10

----

----

3010

6010

100

22.2

(Pag

e 1

of 2

)

Page 37: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 16

--Con

ditio

n of

Dou

glas

-fir p

lyw

ood

stak

es tr

eate

d w

ith s

ever

al w

ood

pres

erva

tives

, eith

er b

efor

e or

afte

r glu

ing

of th

e ve

neer

, afte

r 51

year

sof

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

945

(Plo

t 16)

--con

clud

ed

Con

ditio

n of

sta

kes

Janu

ary

1996

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

Plyw

ooda

show

ing

som

e--

Dec

ayN

um-

Vene

e rN

um-

Dec

ayfu

ngi

ber

thic

k-Av

erag

ebe

ran

dan

dAv

erag

eof

ness

rete

ntio

nb,c

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Trea

tmen

tpl

ies

(in.)

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Plyw

ood

Trea

ted

Afte

r Glu

ing

Coa

l-tar

cre

osot

ePr

essu

re5

1/8

19.6

1070

1010

10--

----

----

--H

ot b

ath,

1-h

our,

and

cold

bat

h, 1

-hou

r5

1/8

2.0

1020

----

80--

----

----

--24

-hou

r col

d so

ak5

1/8

5.3

10--

----

--20

3050

1010

011

.310

-sec

ond

dipp

ing

51/

81.

0e8g

----

----

--50

508

100

5.4

Cop

per n

apht

hena

te,

Pres

sure

51/

82.

9 (0

.058

)10

----

----

5010

4010

100

18.9

(2%

cop

per m

etal

)H

ot b

ath,

1-h

our,

and

cold

in

coal

-tar n

apht

ha b

ath,

1-h

our

51/

81.

2 (0

.024

)10

----

----

60--

4010

100

12.8

24-h

our c

old

soak

51/

81.

1 (0

.022

)10

----

----

50--

5010

100

13.8

10-s

econ

d di

ppin

g5

1/8

0.4

(0.0

08)

10--

----

--60

--40

1010

010

.5

Pent

achl

orop

heno

l,Pr

essu

re5

1/8

12.5

10--

----

2030

--50

880

-- 5

% in

No.

2 fu

elH

ot b

ath,

1-h

our,

and

cold

oil

bat

h, 1

-hou

r5

1/8

2.1

10--

----

----

4060

1010

08.

324

-hou

r col

d so

ak5

1/8

2.0

10--

----

--20

1070

1010

08.

310

-sec

ond

dipp

ing

51/

80.

710

----

----

1020

7010

100

7.8

Chr

omat

ed z

inc

Pres

sure

51/

80.

62e (0

.038

)10

----

----

40--

6010

100

17.9

chl

orid

e24

-hou

r ste

epin

g5

1/8

0.35

(0.2

1)10

----

----

1030

6010

100

8.2

10-s

econ

d di

ppin

g5

1/8

0.03

(0.0

2)10

----

----

--50

5010

100

4.0

Acid

cop

per

Pres

sure

51/

80.

46 (0

.23)

1010

----

1050

--30

880

-- c

hrom

ate

24-h

our s

teep

ing

51/

80.

28 (0

.14)

10--

----

--10

4050

1010

05.

310

-sec

ond

dipp

ing

51/

80.

06 (0

.03)

10--

----

--10

6030

1010

08.

2

Non

eU

ntre

ated

131/

16--

10--

----

----

5050

1010

03.

7U

ntre

ated

71/

8--

10--

----

----

6040

1010

03.

6

a Plyw

ood

glue

d w

ith h

ot-p

ress

phe

nolic

-resi

n ad

hesi

ve.

b Oils

or d

ry s

alt a

bsor

bed

by 2

1-by

38-

in. p

lyw

ood

pane

l. S

take

s w

ere

cut f

rom

ply

woo

d pa

nels

afte

r tre

atm

ent,

and

all e

xpos

ed e

dges

of s

take

s w

ere

soa

ked

in th

e pr

eser

vativ

e be

fore

sta

kes

wer

e in

stal

led.

c Ret

entio

n va

lues

in p

aren

thes

es b

ased

on

pres

erva

tive

oxid

es o

r cop

per m

etal

.d Ve

neer

hea

ted

in d

ryer

and

then

sub

mer

ged

for 1

hou

r in

unhe

ated

pre

serv

ativ

e.e Ap

prox

imat

e va

lues

.f Ve

neer

trea

ted

prio

r to

dryi

ng.

g Spec

imen

s de

lam

inat

ed a

nd w

ere

elim

inat

ed fr

om te

st.

(Pag

e 2

of 2

)Th

is s

tudy

was

initi

ated

by

J. O

scar

Ble

w.

Page 38: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 17

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

var

ious

pet

role

um o

ils, p

enta

chlo

roph

enol

sol

utio

n, c

oppe

r nap

hthe

nate

solu

tions

, coa

l-tar

cre

osot

e, a

nd m

ixtu

res

of th

ese

pres

erva

tives

afte

r abo

ut 5

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

and

at B

ogal

usa,

LA,

Apr

il 19

48 (P

lot 2

0)

Con

ditio

n of

sta

kes

Janu

ary

1998

b (%

)Se

rvic

eabl

e bu

tD

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eO

il or

pre

serv

ativ

eLo

catio

n (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Unf

ortif

ied

petr

oleu

m o

il C

omm

erci

al a

rom

atic

sol

vent

MS

410

----

----

10--

9010

100

2.3

(M

id-U

nite

d St

ates

)LA

410

----

----

--20

8010

100

2.9

Sto

ddar

d so

lven

t (M

id-U

nite

d St

ates

)M

S4

10--

----

--10

2070

1010

02.

1LA

410

----

----

1020

7010

100

2.8

No.

2 fu

el o

il (M

id-U

nite

d St

ates

)M

S4

10--

----

--10

1080

1010

04.

4LA

410

----

----

70--

3010

100

4.1

Hea

vy th

erm

al s

ide

cut

MS

410

----

----

--10

9010

100

3.4

(M

id-U

nite

d St

ates

)LA

410

----

----

30--

7010

100

4.6

No.

200

die

sel o

il (W

est C

oast

)M

S4

10--

----

--20

1070

1010

04.

8LA

410

----

----

70--

3010

100

4.6

Cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st)

MS

410

----

----

40--

6010

100

7.6

LA4

10--

----

--40

--60

1010

07.

6M

S8

10--

----

--30

--70

1010

014

.6LA

810

--10

--50

20--

204

40--

MS

1210

----

----

40--

6010

100

17.1

LA12

10--

25--

6312

----

112

--

No.

300

fuel

oil

(Wes

t Coa

st)

MS

410

----

----

90--

1010

100

7.1

LA4

10--

----

2080

----

880

6.5c

No.

400

fuel

oil

(Wes

t Coa

st)

MS

410

----

----

80--

2010

100

5.8

LA4

10--

----

--90

--10

1010

05.

5

Ligh

t gas

oil

(Mid

-Uni

ted

Stat

es)

MS

410

----

----

50--

5010

100

6.7

LA4

10--

----

--60

--40

1010

06.

0

Den

ver N

o. 3

ble

nd (5

0-50

topp

ed c

rude

MS

410

----

----

60--

4010

100

6.4

re

sidu

al a

nd re

cycl

ed o

verh

ead

gas

oil)

LA4

10--

----

--80

--20

1010

05.

9

Hea

vy g

as o

il (M

id-U

nite

d St

ates

)M

S4

10--

----

--10

0--

--10

100

12.9

LA4

10--

----

6040

----

440

--M

S8

10--

----

1090

----

990

--LA

89

--33

--67

----

----

----

MS

1210

----

2080

----

880

--LA

125

6040

----

----

----

----

Lube

oil

extra

ct (T

exas

)M

S4

10--

----

--10

0--

--10

100

12.0

LA4

8--

----

6325

123

37--

(Pag

e 1

of 3

)

Page 39: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 17

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

var

ious

pet

role

um o

ils, p

enta

chlo

roph

enol

sol

utio

n, c

oppe

r nap

hthe

nate

solu

tions

, coa

l-tar

cre

osot

e, a

nd m

ixtu

res

of th

ese

pres

erva

tives

afte

r abo

ut 5

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

and

at B

ogal

usa,

LA,

Apr

il 19

48 (P

lot 2

0)--c

ontin

ued

Con

ditio

n of

sta

kes

Janu

ary

1998

b (%

)Se

rvic

eabl

e bu

tD

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eO

il or

pre

serv

ativ

eLo

catio

n (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Fort

ified

pet

role

um o

ils a

nd m

ixtu

res

Com

mer

cial

aro

mat

ic s

olve

nt (M

id-

MS

4.2

10--

----

----

--10

010

100

10.9

Uni

ted

Stat

es w

ith 5

% p

enta

chlo

roph

enol

)LA

4.2

10--

----

--10

--90

1010

08.

6

Sto

ddar

d so

lven

t (M

id-U

nite

d St

ates

)M

S4.

010

----

----

10--

9010

100

13.7

w

ith 5

% p

enta

chlo

roph

enol

LA4.

010

----

----

20--

8010

100

8.8

No

2 fu

el o

il (M

id-U

nite

d St

ates

)M

S4.

010

----

----

1010

8010

100

14.9

w

ith 5

% p

enta

chlo

roph

enol

LA3.

810

----

--20

----

808

8012

.5c

Hea

vy th

erm

al s

ide

cut (

Mid

-Uni

ted

Stat

es)

MS

4.0

10--

----

--20

--80

1010

014

.0

with

5%

pen

tach

loro

phen

olLA

4.0

10--

----

--10

--90

1010

010

.6

No.

200

die

sel o

il (W

est C

oast

)M

S4.

110

----

----

10--

9010

100

17.0

w

ith 5

% p

enta

chlo

roph

enol

LA4.

110

----

--50

----

505

50--

Cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st)

MS

4.2

10--

----

----

--10

010

100

16.3

w

ith 5

% p

enta

chlo

roph

enol

LA4.

18

----

--88

12--

--1

12--

MS

8.0

10--

----

--10

--90

1010

020

.7LA

7.9

8--

12--

88--

----

----

--M

S12

.010

----

----

30--

7010

100

30.2

LA12

.09

--56

--44

----

----

----

No.

300

fuel

oil

(Wes

t Coa

st) w

ithM

S4.

010

----

----

80--

2010

100

14.6

w

ith 5

% p

enta

chlo

roph

enol

LA4.

18

--12

--50

12--

253

37--

No.

400

fuel

oil

(Wes

t Coa

st) w

ithM

S4.

210

----

----

40--

6010

100

13.9

w

ith 5

% p

enta

chlo

roph

enol

LA4.

29

----

--22

22--

567

7812

.5c

Lig

ht g

as o

il (M

id-U

nite

d St

ates

) M

S4.

010

----

----

----

100

1010

015

.6

with

5%

pen

tach

loro

phen

olLA

4.2

10--

----

50--

--50

550

--

Den

ver N

o. 3

ble

nd (5

0-50

topp

ed c

rude

resi

dual

M

S4.

010

----

----

70--

3010

100

19.5

a

nd re

cycl

ed o

verh

ead

gas

oil)

with

5%

pen

tach

loro

phen

olLA

4.0

7--

----

8614

----

114

--

Hea

vy g

as o

il (M

id-U

nite

d St

ates

) M

S4.

19

----

--11

44--

448

89--

w

ith 5

% p

enta

chlo

roph

enol

LA4.

18

--12

--88

----

----

----

MS

7.9

10--

--10

1060

--20

880

--LA

7.9

6--

33--

67--

----

----

--M

S12

.010

----

--80

20--

--2

20--

LA12

.05

60--

--40

----

----

----

(Pag

e 2

of 3

)

Page 40: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 17

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

var

ious

pet

role

um o

ils, p

enta

chlo

roph

enol

sol

utio

n, c

oppe

r nap

hthe

nate

solu

tions

, coa

l-tar

cre

osot

e, a

nd m

ixtu

res

of th

ese

pres

erva

tives

afte

r abo

ut 5

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

and

at B

ogal

usa,

LA,

Apr

il 19

48 (P

lot 2

0)--c

oncl

uded

Con

ditio

n of

sta

kes

Janu

ary

1998

b (%

)Se

rvic

eabl

e bu

tD

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eO

il or

pre

serv

ativ

eLo

catio

n (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Fort

ified

pet

role

um o

ils a

nd m

ixtu

res

(con

t'd)

Lub

e oi

l ext

ract

(Tex

as)

MS

4.2

10--

----

--90

--10

1010

028

.5

with

5%

pen

tach

loro

phen

olLA

4.2

8--

----

100

----

----

----

Cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st) w

ith c

oppe

rM

S4.

210

----

----

7010

2010

100

14.3

n

apht

hena

te (0

.5%

cop

per m

etal

)LA

4.2

10--

10--

6010

--20

330

--

Cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st) w

ith c

oppe

rM

S4.

48

----

----

75--

258

100

17.4

n

apht

hena

te (0

.75%

cop

per m

etal

)LA

4.2

812

12--

6212

----

112

--

Coa

l-tar

cre

osot

eM

S4.

110

----

----

70--

3010

100

14.2

LA4.

110

----

--50

40--

105

50--

Coa

l-tar

cre

osot

e, 5

0%, a

nd c

atal

ytic

gas

-bas

e oi

l (W

est

MS

4.1

10--

----

--50

--50

1010

016

.2

Coa

st) w

ith 5

% p

enta

chlo

roph

enol

, 50%

by

volu

me

LA4.

18

----

--62

----

383

38--

Coa

l-tar

cre

osot

e, 5

0%, a

nd c

atal

ytic

gas

-bas

e oi

lM

S4.

210

----

----

90--

1010

100

18.9

(W

est C

oast

) with

cop

per n

apht

hena

te (0

.5%

cop

per

LA4.

310

----

--90

10--

--1

10--

m

etal

), 50

% b

y vo

lum

e

Coa

l-tar

cre

osot

e, 2

5%, a

nd c

atal

ytic

gas

-bas

e oi

lM

S4.

110

----

----

90--

1010

100

14.6

(W

est C

oast

) with

cop

per n

apht

hena

te (0

.75%

cop

per

LA4.

28

----

--50

38--

124

50--

m

etal

) , 7

5% b

y vo

lum

e

Cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st) w

ithM

S4.

210

----

----

2010

7010

100

24.9

5

% p

enta

chlo

roph

enol

, 50%

, and

LA4.

29

----

--10

0--

----

----

--

cat

alyt

ic g

as-b

ase

oil (

Wes

t Coa

st) w

ith

cop

per n

apht

hena

te (0

.5%

cop

per m

etal

), 50

% b

y vo

lum

e

Unt

reat

ed c

ontro

lsM

S--

10--

----

--20

2060

1010

02.

2LA

--10

----

----

----

100

1010

02.

8

a Ten

stak

es w

ere

orig

inal

ly in

stal

led

at e

ach

test

sta

tion;

this

num

ber h

as s

ince

bee

n re

duce

d be

caus

e of

failu

re to

loca

te th

e st

akes

at t

he ti

me

of in

spec

tion.

b Fina

l ins

pect

ion

at B

ogal

usa,

Nov

embe

r 196

2.c Es

timat

e ba

sed

on p

erce

ntag

e of

sta

kes

rem

aini

ng a

fter f

inal

insp

ectio

n.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.(P

age

3 of

3)

Page 41: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 18

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

var

ious

coa

l-tar

cre

osot

es a

nd c

reos

ote

solu

tions

afte

r abo

ut 4

4 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

at M

adis

on, W

I, O

ctob

er 1

948,

and

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 194

8 (P

lot 2

4)

Con

ditio

n of

sta

kes

Oct

ober

199

2a (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

eLo

catio

n (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Coa

l-tar

cre

osot

e

Low

resi

due,

stra

ight

run

MS

8.0

10--

----

3060

--10

770

17.8

b

WI

8.0

10--

40--

--60

----

660

--

Med

ium

resi

due,

stra

ight

run

MS

8.0

10--

10--

1080

----

880

18.8

b

WI

8.0

10--

70--

--30

----

330

--

Hig

h re

sidu

e, s

traig

ht ru

nM

S7.

810

--20

--20

60--

--6

6020

.3b

WI

7.8

10--

10--

----

----

----

--

Med

ium

resi

due

L

ow in

tar a

cids

MS

8.1

10--

10--

2070

----

770

19.4

b

WI

8.1

10--

100

----

----

----

----

L

ow in

nap

htha

lene

MS

8.2

10--

10--

5040

----

440

21.3

b

WI

8.2

10--

90--

--10

----

110

--

L

ow in

tar a

cids

and

MS

8.0

10--

----

3060

--10

770

18.9

b

nap

htha

lene

WI

8.0

10--

100

----

----

----

----

Low

resi

due,

low

in ta

rM

S8.

010

--10

--20

50--

207

7019

.2b

ac

ids

and

naph

thal

ene

WI

8.0

10--

40--

--60

----

660

--

Hig

h re

sidu

e, lo

w in

tar

MS

8.2

10--

10--

1070

--10

880

20.0

b

ac

ids

and

naph

thal

ene

WI

8.1

933

67--

----

----

----

--

Engl

ish

verti

cal r

etor

tM

S8.

010

----

--30

60--

107

7018

.9b

WI

8.0

1010

90--

----

----

----

--

Engl

ish

coke

ove

nM

S7.

910

----

----

70--

3010

100

13.6

WI

7.9

10--

30--

--70

----

770

--

Engl

ish

coke

ove

n, 5

0%, a

ndM

S8.

110

----

--10

40--

509

9016

.9b

Eng

lish

verti

cal r

etor

t, 50

% b

yW

I8.

110

1070

----

20--

--2

20--

vol

ume

(Pag

e 1

of 2

)

Page 42: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 18

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

var

ious

coa

l-tar

cre

osot

es a

nd c

reos

ote

solu

tions

afte

r abo

ut 4

4 ye

arof

ser

vice

. St

akes

pla

ced

in te

st a

t Mad

ison

, WI,

Oct

ober

194

8, a

nd o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

948

(Plo

t 24)

--con

clud

Con

ditio

n of

sta

kes

Oct

ober

199

2a (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

eLo

catio

n(lb

/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Med

ium

resi

due,

low

in ta

r aci

dsM

S8.

110

--20

--10

70--

--7

7020

.4b

and

nap

htha

lene

, 70%

, and

WI

8.1

10--

70--

--30

----

330

-- c

oal t

ar, 3

0% b

y vo

lum

e

Med

ium

resi

due,

low

in ta

r aci

dsM

S8.

110

--10

--20

70--

--7

7019

.6b

and

nap

htha

lene

, 70%

, and

WI

8.1

10--

70--

--30

----

330

-- p

etro

leum

oil

(Wyo

min

g r

esid

ual),

30%

by

volu

me

Petro

leum

oil

(Wyo

min

g re

sidu

al)

MS

8.1

10--

----

--90

--10

1010

03.

4W

I8.

19

----

----

100

----

910

014

.8

Unt

reat

ed c

ontro

lsM

S--

10--

----

--10

1080

1010

01.

9W

I--

10--

----

--10

0--

--10

100

5.6

a Fina

l ins

pect

ion

in M

issi

ssip

pi, N

ovem

ber 1

968.

b Estim

ate

base

d on

per

cent

age

of s

take

s re

mai

ning

afte

r fin

al in

spec

tion.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.(P

age

2 of

2)

Page 43: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 19

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

Eng

lish

coke

ove

n an

d ve

rticl

e re

tort

coal

-tar c

reos

otes

afte

r abo

ut 5

0 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 194

8 (P

lot 2

5)

Con

ditio

n of

sta

kes

Febr

uary

199

8 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Coa

l-tar

cre

osot

e5.

310

----

--10

70--

209

90--

Eng

lish

verti

cal r

etor

t10

.110

----

--20

70--

108

80--

15.0

10--

10--

90--

----

----

--

Eng

lish

coke

ove

n4.

710

----

----

80--

2010

100

16.3

10.1

10--

----

3060

10--

770

--

14.8

10--

----

2060

--20

880

--

Unt

reat

ed c

ontro

ls--

10--

----

----

--10

010

100

1.9

Page 44: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 20

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

zin

c-ar

seni

c ch

rom

ium

and

chr

omat

ed c

oppe

r ars

enat

e sa

lts a

fter a

bout

43

and

46

year

s of

ser

vice

. St

akes

pla

ced

in te

st a

t Mad

ison

, WI,

Nov

embe

r 194

9 an

d on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 194

9 (P

lot 2

8)

Con

ditio

n of

sta

kes

Janu

ary

1995

(MS)

and

Oct

ober

199

2 (W

I) (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nain

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

Loca

tion

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Zinc

-ars

enic

-chr

omiu

m s

alt (

S-32

)bW

I(0

.96)

1090

----

--10

----

110

--M

S(0

.96)

10--

----

100

----

----

----

WI

(0.7

4)10

40--

----

60--

--6

60--

MS

(0.7

2)10

----

--10

0--

----

----

--

WI

(0.5

0)10

----

----

100

----

1010

021

.8M

S(0

.50)

10--

----

100

----

----

----

WI

(0.3

5)10

----

----

100

----

1010

018

.5M

S(0

.35)

1010

----

80--

--10

110

--

WI

(0.2

2)10

----

----

100

----

1010

018

.6M

S(0

.22)

10--

----

2020

--60

880

--

Chr

omat

ed c

oppe

r ars

enat

e,W

I(1

.03)

1090

10--

----

----

----

-- t

ype

II (F

ed. S

pec.

TT-

W-5

50)

MS

(1.0

4)10

1020

1060

----

----

----

WI

(0.7

8)10

9010

----

----

----

----

MS

(0.7

9)9

11--

--89

----

----

----

WI

(0.5

2)9

--10

0--

----

----

----

--M

S(0

.52)

10--

----

100

----

----

----

WI

(0.3

7)10

--10

0--

----

----

----

--M

S(0

.37)

10--

----

100

----

----

----

WI

(0.2

6)10

--80

----

20--

--2

20--

MS

(0.2

6)10

----

--10

0--

----

----

--

Zinc

chl

orid

eW

I1.

04 (0

.61)

10--

----

--10

0--

--10

100

12.8

MS

1.04

(0.6

2)10

----

----

20--

8010

100

17.0

Coa

l-tar

cre

osot

eW

I8.

3610

--90

----

10--

--1

10--

MS

8.30

10--

----

5030

--20

550

--

Unt

reat

ed c

ontro

lsW

I--

10--

----

--10

0--

--10

100

7.0

MS

--10

----

----

1030

6010

100

2.8

b ZnO

, 97

parts

; CrO

3, 1

70 p

arts

; and

As 2

O5,

213

par

ts.

a Ret

entio

n fig

ures

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

Page 45: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 21

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

two

forti

fied

arom

atic

pet

role

um o

ils a

fter

abou

t 47

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

949

(Plo

t 26)

Con

ditio

n of

sta

kes

Janu

ary

1995

(%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

ere

tent

ion

inTe

rmit e

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Stan

dard

woo

d 3

.710

----

----

2010

7010

100

7.3

pre

serv

ativ

ea

8.2

10--

----

1020

1060

990

--

11.7

10--

----

3040

--30

770

--

Woo

d pr

eser

vativ

e N

o. 5

1746

-Rb

4.0

10--

----

--20

--80

1010

011

.6

8.0

10--

----

1020

--70

990

--

12.1

10--

----

3010

--60

770

--

Unt

reat

ed c

ontro

ls--

10--

----

----

3070

1010

02.

2

a Rep

orte

d to

be

a m

ixtu

re o

f hea

vy p

etro

leum

cre

sylic

aci

ds, a

n ar

omat

ic s

olve

nt, a

nd c

oppe

r nap

hthe

nate

equ

ival

ent t

o 0.

3% c

oppe

r met

al.

b Rep

orte

d to

be

a m

ixtu

re o

f pet

role

um c

resy

lic a

cids

, aro

mat

ic o

ils, a

nd 1

.0%

pen

tach

loro

phen

ol.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 46: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 22

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

oil

solu

tions

of r

osin

am

ine

D p

enta

chlo

roph

enat

e an

dpe

ntac

hlor

ophe

nol a

fter a

bout

50

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

949

(Plo

t 27)

Con

ditio

n of

sta

kes

Janu

ary

1999

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Ros

in a

min

e D

pen

tach

loro

phen

ate,

5%

, 4

.010

----

----

--20

8010

100

3.8

in

Stod

dard

sol

vent

7.9

10--

----

----

100

1010

05.

111

.910

----

----

----

100

1010

09.

5

Ros

in a

min

e D

pen

tach

loro

phen

ate,

5%

, 4

.210

----

----

--20

8010

100

4.5

and

par

affin

wax

, 2%

, in

Stod

dard

sol

vent

8.0

10--

----

--10

--90

1010

07.

8

Ros

in a

min

e D

pen

tach

loro

phen

ate,

5%

, 4

.010

----

----

--30

7010

100

8.0

par

affin

wax

, 2%

, and

pen

taly

n H

, 10%

, in

8.0

10--

----

--30

3040

1010

08.

7 S

todd

ard

solv

ent

Ros

in a

min

e D

pen

tach

loro

phen

ate,

5%

, 4

.010

----

----

60--

4010

100

12.8

in

No.

4 a

rom

atic

oil

7.6

10--

----

--50

--50

1010

016

.112

.310

--20

--10

70--

--7

70--

Pent

achl

orop

heno

l, 5%

, and

pin

e oi

l, 4

.110

----

----

----

100

1010

09.

5 5

%, i

n St

odda

rd s

olve

nt 8

.0 9

----

----

----

100

910

015

.5

Pent

achl

orop

heno

l, 5%

, and

pin

e oi

l, 5%

; 4

.110

----

----

--10

9010

100

12.8

par

affin

wax

, 2%

; and

pen

taly

n H

, 10%

, 7

.810

----

----

20--

8010

100

15.7

in

Stod

dard

sol

vent

Pent

achl

orop

heno

l, 5%

, in

No.

4 4

.210

----

----

60--

4010

100

21.0

aro

mat

ic o

il 8

.210

--10

--20

30--

407

70--

Unt

reat

ed c

ontro

ls--

10--

----

----

3070

1010

02.

3

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 47: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 23

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

rosi

n am

ine

D p

enta

chlo

roph

enat

e an

d pe

ntac

hlor

ophe

nol

in p

etro

leum

oil

(Wyo

min

g re

sidu

al) a

fter a

bout

45

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S,M

arch

195

2 (P

lot 3

4)

Con

ditio

n of

sta

kes

Janu

ary

1997

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Ros

in a

min

e D

pen

tach

loro

phen

ate

4.0

10--

----

--70

--30

1010

022

.4 5

% in

pet

role

um o

il 8

.010

----

----

60--

4010

100

25.7

(W

yom

ing

resi

dual

)12

.710

----

--20

50--

308

80--

Pent

achl

orop

heno

l 5%

in 4

.010

----

----

50--

5010

100

18.6

pet

role

um o

il 8

.010

----

--40

30--

306

60--

(W

yom

ing

resi

dual

)11

.710

--20

--80

----

----

----

Pet

role

um o

il 7

.710

----

----

70--

3010

100

14.6

(W

yom

ing

resi

dual

)12

.210

----

----

100

----

1010

017

.4

Unt

reat

ed c

ontro

ls--

10--

----

----

2080

1010

02.

1

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 48: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 24

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

two

Bolid

en s

alt f

orm

ulat

ions

afte

r abo

ut 4

5 ye

ars

ofse

rvic

e. S

take

s pl

aced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, M

arch

195

2 (P

lot 3

3)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Aver

age

Num

-D

ecay

fung

ire

tent

ion,

ber

and

and

Aver

age

anhy

drou

s sa

ltsa

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Bolid

en s

alts

AW

PA P

5-55

Chr

omat

ed z

inc

arse

nate

(H3A

SO4,

0.22

(0

.11)

10--

----

----

1090

1010

022

.1 2

0 pa

rts; N

a 2H

AsO

4, 2

1 pa

rts;

0.38

(0

.20)

10--

----

60--

--40

440

-- N

a 2C

r 2O

7 ⊇

H2O

, 16

parts

; and

0.77

(0

.40)

10--

----

100

----

----

----

ZnS

O4,

43

parts

)b1.

01

(0.5

3)10

c--

----

100

----

----

----

Bolid

en s

alts

S-2

5 (C

rO3,

32

parts

;

(0.3

0)10

----

--10

0--

----

----

-- C

uO, 5

par

ts; Z

nO, 1

4 pa

rts; a

nd

(0.5

0)10

----

--10

0--

----

----

-- A

s 2O

5, 4

9 pa

rts)

(0

.75)

1020

10--

70--

----

----

--

(1.

01)

944

12--

44--

----

----

--

Unt

reat

ed c

ontro

ls--

10--

----

----

2080

1010

01.

9

a Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

b Ret

entio

ns a

re s

how

n on

an

anhy

drou

s ba

sis,

and

figu

res

shou

ld b

e in

crea

sed

appr

oxim

atel

y 26

% to

obt

ain

valu

es a

s c

ompu

ted

in A

WPA

Sta

ndar

d P5

-55.

c This

sta

ke g

roup

pla

ced

in te

st in

Aug

ust 1

952.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Con

ditio

n of

sta

kes

Janu

ary

1997

(%)

Page 49: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 25

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

four

fire

-reta

rdan

t for

mul

atio

ns (A

WPA

P10

-51)

afte

rab

out 4

5 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Mar

ch 1

952a

(Plo

t 35)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

ere

tent

ionb

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Chr

omat

ed z

inc

chlo

ride

1.50

(0.

92)

10--

----

--30

--70

1010

023

.4 (

ZnC

l 2, 8

0.4

parts

;2.

91 (

1.78

)10

----

----

6010

3010

100

32.7

Na 2

Cr 2

O7

. 2H

2O, 1

9.6

parts

)6.

00 (

3.67

)10

60--

3010

----

----

----

Chr

omat

ed z

inc

chlo

ride

(FR

)1.

5310

----

----

3020

5010

100

16.5

(C

hrom

ated

zin

c ch

lorid

e, 8

0 pa

rts;

3.00

10--

----

1030

1050

990

-- H

3BO

3,10

par

ts; a

nd (N

H4)

2SO

4, 10

par

ts)

6.08

1020

--10

2020

1020

550

--

Min

alith

1.50

10--

----

----

1090

1010

03.

7 (

(NH

4)2H

PO4,

10

parts

; (N

H4)

2SO

4,3.

0010

----

----

--10

9010

100

4.9

60

parts

; Na 2

B 4O

7, 1

0 pa

rts;

6.13

10--

----

----

3070

1010

05.

1 a

nd H

3BO

, 20

parts

)

Pyre

sote

1.50

10--

----

----

1090

1010

011

.2 (

ZnC

l 2, 3

5 pa

rts; (

NH

4)SO

4,3.

0110

----

----

--20

8010

100

13.1

Na 2

Cr 2

O7

2H

2O, 5

par

ts)

6.26

10--

----

--20

2060

1010

018

.3

Unt

reat

ed c

ontro

ls--

10--

----

----

2080

1010

02.

6

a In c

oope

ratio

n w

ith B

urea

u of

Shi

ps, D

epar

tmen

t of t

he N

avy.

b Ret

entio

n va

lues

in p

aren

thes

es b

ased

on

pres

erva

tive

oxid

es.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Con

ditio

n of

sta

kes

Janu

ary

1997

(%)

Page 50: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 26

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

bas

ic z

inc

chlo

ride

and

zinc

chl

orid

eaf

ter a

bout

50

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, M

arch

195

2 (P

lot 3

2)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

ere

tent

ion

ofin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Basi

c zi

nc c

hlor

idea

1.00

10--

20--

7010

----

110

--

2.11

10--

4010

50--

----

----

--

4.13

10--

7020

10--

----

----

--

Zinc

chl

orid

e 1

.02

(0.6

1)b

10--

----

--10

--90

1010

024

.2

Unt

reat

ed c

ontro

ls--

10--

----

--10

2070

1010

02.

3

a Pers

hall

proc

ess.

Com

poun

d in

tend

ed a

s fir

e re

tard

ant w

ith re

tent

ions

of 3

-1/2

to 4

lb/ft

3 . R

eten

tions

of b

asic

zin

c ch

lorid

e ar

e ex

pres

sed

as w

eigh

t of z

inc

oxid

e.

b Ret

entio

n va

lue

in p

aren

thes

es b

ased

on

pres

erva

tive

oxid

e Zn

O.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Con

ditio

n of

sta

kes

Janu

ary

2002

(%)

Page 51: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 27

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

nav

al s

tore

s pr

oduc

ts a

fter a

bout

40

year

s of

ser

vice

.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Mar

ch 1

952

(Plo

t 36)

C

ondi

tion

of s

take

s D

ecem

ber 1

991

(%)

Serv

icea

ble

but s

how

ing

som

e--

Des

troye

d by

-- To

tal r

emov

ed

Pres

erva

tivea

Aver

age

rete

ntio

n (lb

/ft3 )

Num

ber

in te

st

Goo

d D

ecay

Te

rmite

at

tack

Dec

ay

and

term

ite

atta

ck

Dec

ay

fung

i Te

rmite

at

tack

Dec

ay

and

term

ite

atta

ck

Num

ber

%

Aver

age

life

(yea

r)

Ros

in o

il an

d N

o. 2

fuel

oil

(2:7

) 4.

1 10

30

70

100

6.8

8.

0

10�

��

�60

�40

100

5.8

12.3

10�

��

�20

�80

100

9.3

Ros

in o

il an

d N

o. 2

fuel

oil

(1:7

)

4.0

10

10

90

10

0 5.

6 8.

010

��

��

50�

5010

05.

812

.110

��

��

40�

6010

08.

6R

osin

oil

and

No.

2 fu

el o

il (1

:7)

4.0

10

20

80

10

0 11

.4

with

2.9

8% p

enta

chlo

roph

enol

8.0

10

20

80

10

0 14

.8

12.1

10

20

20

�60

80

�N

o. 2

fuel

oil

4.1

10

30

10

60

10

0 6.

1 N

o. 2

fuel

oil

with

2.9

2%

4.0

10�

��

�10

�90

100

11.1

pe

ntac

hlor

ophe

nol

8.

0 10

20

80

100

12.8

12

.310

��

��

��

100

100

25.8

No.

2 fu

el o

il w

ith 4

.94%

4.

1 10

50

50

100

12.4

pent

achl

orop

heno

l

8.0

10

40

60

10

0 13

.2

12.0

9b

33

33

33

6

6 �

R

osin

oil

and

Stod

dard

sol

vent

(1:7

) 8.

0 10

50

50

100

12.5

with

3.2

1% pe

ntac

hlor

ophe

nol

Ole

o re

sin

and

No.

2 fu

el o

il (2

:7)

4.

0 9b

��

��

��

100

100

6.1

8.1

10�

��

�40

1050

100

6.8

12.2

10�

��

�30

�70

100

10.7

Ole

o re

sin

and

Stod

dard

sol

vent

(1:7

)

8.2

10

40

10

50

10

0 10

.4

w

ith 3

.11%

pent

achl

orop

heno

lD

rop

liquo

r con

cent

rate

and

Sto

ddar

d 7.

910

��

��

20�

8010

08.

7

solv

ent (

l:7) w

ith 2

.99%

pent

achl

orop

heno

l

(Pag

e 1

of2)

Page 52: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 27

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

nav

al s

tore

s pr

oduc

ts a

fter a

bout

40

year

s of

ser

vice

.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Mar

ch 1

952

(Plo

t 36)

--con

clud

ed

Con

ditio

n of

sta

kes

Dec

embe

r 199

1 (%

)

Serv

icea

ble

but s

how

ing

som

e--

Des

troye

d by

-- To

tal r

emov

ed

Pres

erva

tive

Aver

age

rete

ntio

n (lb

/ft3 )

Num

ber

in te

st

Goo

d D

ecay

Te

rmite

at

tack

Dec

ay a

nd

term

ite

atta

ck

Dec

ay

fung

i Te

rmite

at

tack

Dec

ay a

nd

term

ite

atta

ck

Num

ber

%

Aver

age

life

(y

ear)

Ole

o re

sin

and

No.

2 fu

el o

il (1

:7)

4.1

10�

��

�50

�50

100

10.0

w

ith 2

.94%

pen

tach

loro

phen

ol

8.

0 10

30

70

100

13.5

12

.0

10�

��

20

80

100

16

.3

Dro

p liq

uor c

once

ntra

te a

nd

4.0

10

10

90

10

0 6.

8 N

o. 2

fuel

oil

(2:7

) 8.

0 10

20

80

100

7.8

12.0

10�

��

10

0

10.2

100

Dro

p liq

uor c

once

ntra

te a

nd N

o. 2

fuel

4.0

10�

��

��

�10

010

012

.2 o

il (1

:7) w

ith 3

.03%

pent

achl

orop

heno

l

8.0

10�

��

�30

�70

100

16.2

12.0

10�

��

20

80

20

.210

0

No.

2 fu

el o

il w

ith 5

% ro

sin

amin

e D

4.

1 10

50

50

100

8.0

cop

per a

ceta

te c

ompl

ex

8.

0 10

50

50

100

9.6

12.1

10�

��

60

40

15

.910

0

Unt

reat

ed c

ontro

ls

10

30

70

10

0 2.

8 a R

atio

s an

d pe

rcen

tage

s on

wei

ght b

asis

. b O

ne s

take

mis

sing

, elim

inat

ed fr

om te

st.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

(Pag

e 2

of 2

)

Page 53: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 28

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

coa

l-tar

cre

osot

es fr

om ta

rs p

rodu

ced

by lo

w-

tem

pera

ture

car

boni

zatio

n (D

isco

pro

cess

) afte

r 48

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t,

Sauc

ier,

MS,

Dec

embe

r 195

2 (P

lot 3

7)

Con

ditio

n of

sta

kes

June

200

0 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Low

-tem

pera

ture

coa

l-tar

cre

osot

e, 5

.0 8

----

--12

63--

257

88--

typ

e 1

(tar a

cids

pre

sent

)10

.2 9

--11

--22

33--

336

67--

15.4

9--

44--

56--

----

----

--

Low

-tem

pera

ture

coa

l-tar

cre

osot

e, 5

.0 9

----

----

44--

569

100

27.2

typ

e 2

(hig

h pe

rcen

tage

of t

ar a

cids

9.8

10--

20--

2050

--10

660

-- r

emov

ed)

15.2

10--

30--

6010

----

110

--

Unt

reat

ed c

ontro

ls--

10--

----

----

4060

1010

02.

3

a Ten

stak

es w

ere

orig

inal

ly in

stal

led

at e

ach

test

sta

tion;

this

num

ber h

as s

ince

bee

n re

duce

d be

caus

e of

failu

re to

loca

te th

e st

akes

at

the

time

of in

spec

tion.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 54: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 29

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

pre

serv

ativ

e oi

ls a

nd c

ondi

tione

d by

vap

or c

lean

ing

and

stea

min

g to

rem

ove

resi

dual

sol

vent

s af

ter a

bout

28-

1/2

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, A

pril

1953

a (Plo

t 38)

Aver

age

pres

erva

tive

rete

ntio

n (lb

/ft3 ) By

From

wei

ghtb

anal

ysis

cC

ondi

tion

of s

take

s O

ctob

er 1

992

(%)

Pent

a-Pe

nta-

Serv

icea

ble

but

Des

troye

d by

--ch

loro

-ch

loro

-sh

owin

g so

me-

-D

ecay

Num

-ph

enol

phen

olD

ecay

fung

iC

ondi

tioni

ngbe

ror

oran

dan

dAv

erag

eaf

ter

inSo

lu-

copp

erco

pper

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etre

atm

entd

test

tion

met

alm

etal

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Pent

achl

orop

heno

l,N

one

104.

20.

105

0.08

2--

----

--20

1070

1010

011

.6

2.5

% in

ligh

tSt

eam

ing

104.

20.

105

0.09

1--

----

--10

--90

1010

012

.4

aro

mat

ic s

olve

nte

Pent

achl

orop

heno

l,Va

por

104.

10.

102

0.06

9--

----

--10

1080

1010

011

.3

2.5

% in

ligh

tcl

eani

ng

aro

mat

ic s

olve

ntPe

ntac

hlor

ophe

nol,

Stea

min

g10

4.4

0.20

00.

139

----

----

30--

7010

100

10.8

4

.5%

in li

ght

a

rom

atic

sol

vent

e

Pent

achl

orop

heno

l,Va

por

104.

50.

225

0.13

6--

----

--20

--80

1010

014

.2

5%

in li

ght

clea

ning

a

rom

atic

sol

vent

Pent

achl

orop

heno

l,N

one

104.

60.

230

0.18

6--

----

--10

--90

1010

014

.1

5%

in li

ght

Stea

min

g10

4.8

0.24

00.

222

----

----

10--

9010

100

12.9

a

rom

atic

sol

vent

e

Pent

achl

orop

heno

l,Va

por

106.

00.

300

0.17

3--

----

----

--10

010

100

12.3

5

% in

ligh

tcl

eani

ng

aro

mat

ic s

olve

ntPe

ntac

hlor

ophe

nol,

Stea

min

g10

4.4

0.40

00.

319

----

--20

10--

708

8018

.0f

9

.1%

in li

ght

a

rom

atic

sol

vent

e

Pent

achl

orop

heno

l,Va

por

106.

00.

600

0.39

7--

----

30--

--70

770

18.5

f

1

0% in

ligh

tcl

eani

ng

aro

mat

ic s

olve

ntPe

ntac

hlor

ophe

nol,

Non

e10

6.2

0.31

00.

121

----

----

----

100

1010

016

.5

5%

in N

o. 2

St

eam

ing

106.

60.

330

0.14

6--

----

1020

--70

990

15.0

f

f

uel o

ilVa

por

107.

20.

360

0.11

1--

----

--20

--80

1010

013

.1cl

eani

ng(P

age

1 of

2)

Page 55: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 29

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

pre

serv

ativ

e oi

ls a

nd c

ondi

tione

d by

vap

or c

lean

ing

and

stea

min

g to

re

mov

e re

sidu

al s

olve

nts

afte

r abo

ut 2

8-1/

2 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Apr

il 19

53a

(Plo

t 38)

--con

clud

ed

Aver

age

pres

erva

tive

rete

ntio

n (lb

/ft3 ) By

From

wei

ghtb

anal

ysis

cC

ondi

tion

of s

take

s O

ctob

er 1

992

(%)

Pent

a-Pe

nta-

Serv

icea

ble

but

Des

troye

d by

--ch

loro

-ch

loro

-sh

owin

g so

me-

-D

ecay

Num

-ph

enol

phen

olD

ecay

fung

iC

ondi

tioni

ngbe

ror

oran

dan

dAv

erag

eaf

ter

inSo

lu-

copp

erco

pper

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

etre

atm

entd

test

tion

met

alm

etal

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Cop

per n

apht

hena

te,

Non

e10

4.6

0.02

30.

020

----

----

50--

5010

100

11.0

0

.5%

cop

per i

nSt

eam

ing

104.

50.

022

0.02

0--

----

--40

--60

1010

012

.0

ligh

t aro

mat

ic

s

olve

ntVa

por

104.

60.

023

0.01

8--

----

--40

--60

1010

011

.8cl

eani

ng

Cop

per n

apht

hena

te,

Stea

min

g10

4.4

0.02

60.

023

----

----

30--

7010

100

14.3

0

.59%

cop

per i

n

ligh

t aro

mat

ic

s

olve

nt

Cop

per n

apht

hena

te,

Vapo

r10

4.2

0.02

90.

021

----

----

30--

7010

100

13.7

0

.7%

cop

per i

ncl

eani

ng

ligh

t aro

mat

ic

s

olve

nt

Unt

reat

ed c

ontro

ls--

10--

----

----

----

--60

4010

100

2.4

a In c

oope

ratio

n w

ith th

e Bu

reau

of S

hips

, Dep

artm

ent o

f the

Nav

y.b W

eigh

ts d

eter

min

ed b

efor

e an

d af

ter t

reat

men

t, pr

ior t

o co

nditi

onin

g.c An

alys

is p

erfo

rmed

2 m

onth

s af

ter t

reat

men

t.d O

ne-h

our s

team

ing

with

max

imum

tem

pera

ture

259

o F an

d 1-

h va

cuum

, fol

low

ing

whi

ch s

team

ing

and

vacu

um p

erio

ds w

ere

repe

ated

. One

-hou

r hea

ting

in

vap

or o

f aro

mat

ic s

olve

nt w

ith m

axim

um te

mpe

ratu

re o

f 280

o F an

d 1-

h va

cuum

, fol

low

ing

whi

ch v

apor

hea

ting

and

vacu

um p

erio

ds w

ere

repe

ated

.

f Estim

ate

base

d on

per

cent

age

of s

take

s re

mai

ning

afte

r fin

al in

spec

tion.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.(P

age

2 of

2)

e Solu

tion

cont

ined

5%

est

er g

um (b

y w

eigh

t) as

a b

loom

pre

vent

ativ

e.

Page 56: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 30

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

Bas

ilit U

Aa afte

r abo

ut

Con

ditio

n of

sta

kes

Janu

ary

1995

(%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

ere

tent

ionb

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Basi

lit U

A0.

25 (0

.19

10--

----

----

5050

1010

021

.6

Basi

lit U

A0.

53 (0

.39

10--

----

70

30--

-- 3

30

--

Basi

lit U

A0.

75 (0

.56

9--

----

100

----

----

----

Unt

reat

ed c

ontro

ls--

10--

----

----

2080

1010

0 1

.8

a Con

tain

s so

dium

fluo

ride,

sod

ium

dic

hrom

ate,

and

sod

ium

ars

enat

e.

b Ret

entio

n va

lues

in p

aren

thes

es b

ased

on

pres

erva

tive

oxid

es.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

41 y

ears

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 195

4 (P

lot 4

0)

Page 57: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 31--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) of uninfected and Trichoderma mold-infected wood, treated with coal-tar creosote, pentachlorophenol solution, and copper chromated zinc chloride, after about 41 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1954 (Plot 41)

Condition of stakes January 1995 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretentiona in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testb Good Decay attack attack fungi attack attack Number % (year)

Without Mold Infection

Coal-tar creosote (high 3.9 10 -- -- -- -- 70 -- 30 10 100 25.2 residue, straight run) 7.8 9 -- -- -- 22 78 -- -- 7 78 --

12.2 10 -- 10 -- 70 20 -- -- 2 20 --

Coal-tar creosote (low 4.0 10 -- -- -- 10 20 -- 70 9 90 -- residue, low in tar acids 8.0 10 -- -- -- 40 30 -- 30 6 60 -- and naphthalenes) 12.4 8 -- -- -- 100 -- -- -- -- -- --

Pentachlorophenol 4.2 10 -- -- -- -- 10 20 70 10 100 16.7 (4.7% in No. 2 fuel oil) 8.1 9 -- -- -- -- 33 -- 67 9 100 21.6

12.1 9 -- -- -- 89 -- -- 11 1 11 --

Copperized chromated 0.34 (0.20) 10 -- -- -- -- -- 20 80 10 100 16.6 zinc chloride 0.73 (0.45) 10 -- -- -- 10 60 -- 30 9 90 --

1.15 (0.71) 9 -- -- -- 44 44 -- 11 5 56 --

Untreated controls -- 10 -- -- -- -- -- 60 40 10 100 2.1

Infected with Trichoderma Mold

Coal-tar creosote (high 4.0 10 -- -- -- 10 40 -- 50 9 90 -- residue, straight run) 8.0 10 -- -- -- 40 60 -- -- 6 60 --

12.0 9 -- -- -- 78 22 -- -- 2 22 --

Coal-tar creosote (low 4.1 10 -- -- -- -- 60 -- 40 10 100 16.6 residue, low in tar acids 8.0 10 -- -- -- 20 40 -- 40 8 80 -- and naphthalenes) 12.0 10 -- -- -- 90 -- -- 10 1 10 --

Pentachlorophenol 4.2 10 -- -- -- -- 20 20 60 10 100 17.6 (4.7% in No. 2 fuel oil) 7.8 9 -- -- -- -- 11 -- 89 9 100 19.2

11.9 10 -- -- -- 50 10 -- 40 5 50 --

Copperized chromated 0.34 (0.20) 10 -- -- -- -- -- 20 80 10 100 20.2 zinc chloride 0.74 (0.45) 9 -- -- -- 56 22 -- 22 4 44 --

1.17 (0.71) 10 -- -- -- 60 30 -- 10 4 40 --

Untreated controls -- 10 -- -- -- -- 10 30 60 10 100 2.5

aRetention values in parentheses are based on preservative oxides.

bTen stakes were originally installed at each test station; this number has since been reduced because of failure to locate the stakes at the time of inspection.

This study was initiated by Edward Panek.

Page 58: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

alone and fortified with pentachlorophenol after 41 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1954 (Plot 42)

Condition of stakes January 1995 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Texas lignite coal-tar creosote 5.0 9 -- -- -- -- 11 -- 89 9 100 17.2 9.8 10 -- -- -- 10 -- -- 90 9 90 --

15.2 10 -- -- -- 100 -- -- -- -- -- --

25% paraffin in aromatic volatile 25.9 10 -- -- -- -- 1 1 8 10 100 18.4 solvent (by weight)

5% pentachlorophenol plus 26.3 10 -- -- -- 100 -- -- -- -- -- -- 28.5% paraffin in aromatic volatile solvent (by weight) Untreated controls -- 10 -- -- -- -- -- 30 70 10 100 2.3

This study was initiated by J. Oscar Blew.

Table 32--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with Texas lignite coal-tar creosote and with paraffin

Page 59: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 33

--Con

ditio

n of

Dou

glas

-fir,

swee

tgum

, and

tang

ile p

lyw

ood

stak

es tr

eate

d w

ith p

enta

chlo

roph

enol

and

with

fluo

r chr

ome

arse

nate

phe

nol t

ype

Aaf

ter a

bout

26

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, J

anua

ry 1

956

(Plo

t 44)

a

Con

ditio

n of

sta

kes

Dec

embe

r 198

1 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

ndin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePl

ywoo

dPr

eser

vativ

ebTr

eatm

entc

(lb/ft

3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Plyw

ood

Trea

ted

Befo

re G

luin

g

Dou

glas

-fir

Pent

achl

orop

heno

lH

ot a

nd c

old

10.0

9--

----

--22

--77

910

014

.0Pe

ntac

hlor

ophe

nol

Col

d so

aked

6.3

10--

----

--30

--70

1010

08.

2Fl

uor c

hrom

e

ars

enat

e ph

enol

type

AH

ot a

nd c

old

0.5

2 (0

.32)

10--

----

--50

--50

1010

012

.3

Swee

tgum

Pent

achl

orop

heno

lH

ot a

nd c

old

15.1

10--

----

--30

--70

1010

07.

4Fl

uor c

hrom

e

ars

enat

e ph

enol

type

AH

ot a

nd c

old

0.6

2 (0

.39)

10--

----

--60

--40

1010

08.

5

Tang

ilePe

ntac

hlor

ophe

nol

Hot

and

col

d 9

.410

----

----

60--

4010

100

6.8

Fluo

r chr

ome

a

rsen

ate

phen

ol ty

pe A

Hot

and

col

d 0

.59

(0.3

7)10

----

----

10

0--

--10

100

10.4

Plyw

ood

Trea

ted

Afte

r Glu

ing

Dou

glas

-fir

Pent

achl

orop

heno

lPr

essu

re 9

.610

----

----

20--

8010

100

15.4

Pent

achl

orop

heno

lC

old

soak

ed 0

.910

----

----

2010

7010

100

5.3

Pent

achl

orop

heno

lC

old

soak

ed 1

.4e

10--

----

----

2080

1010

07.

1Fl

uor c

hrom

e

ars

enat

e ph

enol

type

APr

essu

re 0

.61

(0.3

8) 9

----

----

2222

56 9

100

18.3

Swee

tgum

Pent

achl

orop

heno

lPr

essu

re10

.610

----

----

70--

3010

100

6.3

Fluo

r chr

ome

a

rsen

ate

phen

ol ty

pe A

Pres

sure

0.5

5 (0

.34)

10--

----

--50

f10

4010

100

7.6

Tang

ilePe

ntac

hlor

ophe

nol

Pres

sure

10.4

10--

----

--70

--30

1010

013

.4Fl

uor c

hrom

e

ars

enat

e ph

enol

type

APr

essu

re 0

.60

(0.3

7)10

----

----

90--

1010

100

14.9

(Pag

e 1

of 2

)

Page 60: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 33

--Con

ditio

n of

Dou

glas

-fir,

swee

etgu

m, a

nd ta

ngile

ply

woo

d st

akes

trea

ted

with

pen

tach

loro

phen

ol a

nd w

ith fl

uor c

hrom

e ar

sena

te p

heno

l typ

e A

afte

r abo

ut 2

6 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Jan

uary

195

6 (P

lot 4

4)--c

oncl

uded

Con

ditio

n of

sta

kes

Dec

embe

r 198

1 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Plyw

ood

Pres

erva

tive

Trea

tmen

t (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Unt

reat

ed c

ontro

ls

Dou

glas

-fir

----

--10

----

----

----

100

1010

03.

6

Swee

tgum

----

--10

----

----

1010

8010

100

1.4

Tang

ile--

----

10--

----

--40

--60

1010

01.

9

a In c

oope

ratio

n w

ith th

e Bu

reau

of S

hips

, Dep

artm

ent o

f the

Nav

y.b Fo

r pen

tach

loro

phen

ol, 5

% s

olut

ion

conf

orm

ing

to M

IL-W

-181

42 (S

HIP

S) s

peci

ficat

ion,

27

Augu

st 1

954.

c Hot

and

col

d tre

atm

ent c

onsi

sted

of h

eatin

g in

a v

enee

r dry

er a

nd im

mer

sion

in u

nhea

ted

pres

erva

tive

solu

tion

until

des

ired

rete

ntio

n w

as o

btai

ned.

d Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

e Stak

es w

ere

cut f

rom

the

pane

ls a

nd th

en tr

eate

d.f O

ne s

take

dec

ayed

by

soft-

rot f

ungu

s.

NO

TE:

The

stak

es w

ere

five-

ply

vene

er, 5

/8 b

y 4

by 1

8 in

., cu

t fro

m p

anel

s 24

by

48 in

. Fo

r oth

er tr

eate

d ite

ms,

the

stak

es w

ere

cut a

fter t

reat

men

t

and

the

edge

s ex

pose

d in

saw

ing

wer

e br

ush

coat

ed w

ith th

e pr

eser

vativ

e.

This

stu

dy w

as in

itiat

ed b

y Ed

war

d Pa

nek.

(Pag

e 2

of 2

)

Page 61: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 34--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with copper formate, after about 44 years of service.Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1956 (Plot 47)

Condition of stakes January 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Average Num- Decay fungiretention ber and and Average(copper) in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Copper formate 0.03 10 -- -- -- -- 30 -- 70 10 100 7.40.06 10 -- -- -- -- 90 -- 10 10 100 25.90.09 10 -- -- -- 40 50 -- 10 6 60 --0.12 10 -- 10 -- 60 30 -- -- 3 30 --

Untreated controls -- 10 -- -- -- -- -- -- 100 10 100 3.4

This study was initiated by J. Oscar Blew.

Page 62: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 35--Condition of Southern Pine stakes treated with KPa preservative after 34 and 43 years of service. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, December 1957 and Madison, WI, May 1958 (Plot 48)

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

retentionb in Termite termite Decay Termite termite Total removed lifePreservative Location (lb/ft3) testc Good Decay attack attack fungi attack attack Number % (year)

Stakes 3/4 by 3/4 by 18 in.

KP preservative MS 0.09 9 -- -- -- -- 56 11 33 9 100 9.9MS 0.18 7 -- -- -- -- 86 -- 14 7 100 16.4MS 0.28 8 -- 29 -- -- 57 -- 14 5 71 --MS 0.37 4 -- -- -- -- 100 -- -- 4 100 25.6

Chromated zinc chloride MS 1.20 (0.73) 9 -- -- -- -- 11 67 22 9 100 13.7

Coal-tar creosote MS 11.70 8 -- -- -- 25 50 25 6 75 --

Untreated controls MS -- 10 -- -- -- -- 40 -- 60 10 100 2.1

Stakes 2 by 4 by 18 in.

KP preservative MS 0.09 10 -- -- -- -- 70 -- 30 10 100 13.5WI 0.09 8 -- -- -- -- 100 -- -- 8 100 19.8MS 0.19 9 -- 11 -- 44 44 -- -- 4 44 --WI 0.18 10 -- 30 -- -- 70 -- -- 7 70 --MS 0.27 10 10 10 10 50 20 -- -- 2 20 --WI 0.27 8 -- 63 -- -- 37 -- -- 3 37 --MS 0.37 9 11 22 22 22 22 -- -- 2 22 --WI 0.35 7 -- 100 -- -- -- -- -- -- -- --

Chromated zinc chloride MS 1.16 (0.71) 10 -- -- -- -- 20 -- 80 10 100 22.9WI 1.21 (0.74) 8 -- 25 -- -- 75 -- -- -- -- --

Coal-tar creosote MS 10.20 9 -- 22 -- 78 -- -- -- -- -- --WI 10.20 10 10 90 -- -- -- -- -- -- -- --

Untreated controls MS -- 10 -- -- -- -- 20 -- 80 10 100 2.5WI -- 10 -- -- -- -- 100 -- -- -- -- 3.6

aCopper oxide and chlorophenols.bRetention values in parentheses are based on preservative oxides.cWhen the number of stakes is less than 10, specimens were found broken and eliminated from test.

This study was initiated by J. Oscar Blew.

December 2000 (MS) (%)Condition of stakes October 1992 (WI) and

Page 63: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 36--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with tributyltin oxide, cyanoethylated stakes,and stakes treated for destruction of thiamine, after approximately 9-1/2 years of service in Mississippi and 8 years in Madison, WI. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1958 and in Wisconsin, May 1959 (Plot 53)

Condition of stakes January 1967 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Tributyltin oxidea MS 0.015 10 -- -- -- -- -- 10 90 10 100 6.4MS 0.030 10 -- -- -- -- 10 -- 90 10 100 7.2MS 0.045 10 -- -- -- -- 10 -- 90 10 100 7.4

Stoddard solvent (controls) MS 7.1 10 -- -- -- -- -- 20 80 10 100 4.0

Acrylonitrileb MS 1.23 10 -- -- -- -- -- 10 90 10 100 3.9WI 1.22 10 -- -- -- -- 100 -- -- 10 100 6.3MS 2.46 10 -- -- -- -- -- 10 90 10 100 5.3WI 2.48 10 -- -- -- -- 100 -- -- 10 100 7.8

Ammonium hydroxidec MS -- 10 -- -- -- -- -- 10 90 10 100 3.5

Untreated controls MS -- 10 -- -- -- -- -- -- 100 10 100 3.6WI -- 10 -- -- -- -- 100 -- -- 10 100 4.0

aIn Stoddard solvent.

bUsed with ammonium hydroxide for cyanoethylation.

cFollowed by steaming for thiamine destruction.

This study was initiated by J. Oscar Blew.

Page 64: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 37--Condition of Southern Pine stakes (2 by 4 in. nominal and 3/4 by 3/4 in. by 18 in.) treated with fluor chrome arsenate phenol type A (AWPA-P5 and modification) after about 30 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1959 (Plot 55)

Condition of stakes December 1989 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

retentiona in Termite termite Decay Termite termite Total removed lifePreservative (lb/ft3) testb Good Decay attack attack fungi attack attack Number % (year)

Stakes 2 by 4 Nominal by 18 in.

Fluor chrome arsenate 0.35 (0.22) 8 -- -- -- -- 63 -- 37 9 100 18.3 phenol (Federal Spec. 0.50 (0.31) 10 -- -- -- -- 80 -- 20 10 100 18.5 TT-W-535) (Type A) 0.75 (0.47) 10 -- -- -- -- 80 -- 20 10 100 25.1

Fluor chrome arsenate 0.35 (0.22) 9 -- -- -- -- 33 11 56 9 100 16.7 phenol (Type A) 0.50 (0.31) 10 -- -- -- -- 80 -- 20 10 100 17.5 (Modified)c 0.76 (0.47) 10 -- -- -- -- 90 -- 10 10 100 21.4

Untreated controls -- 10 -- -- -- -- 40 20 40 10 100 2.1

Stakes 3/4 by 3/4 by 18 in.

Fluor chrome arsenate 0.36 (0.22) 9 -- -- -- -- 33 33 33 9 100 7.4 phenol (Federal Spec. 0.51 (0.32) 9 -- -- -- -- 56 33 11 9 100 11.9 TT-W-535) (Type A) 0.77 (0.48) 8 -- -- -- -- 50 13 37 8 100 16.5

Fluor chrome arsenate 0.37 (0.23) 10 -- -- -- -- 20 30 50 10 100 8.3 phenol (Type A) 0.52 (0.32) 10 -- -- -- -- 20 40 40 10 100 11.6 (Modified)c 0.80 (0.38) 9 -- -- -- -- 56 11 33 9 100 15.3

Untreated controls -- 10 -- -- -- -- 30 20 50 10 100 1.4

aRetention values in parentheses are based on preservative oxides.

bWhen the number of stakes is less than 10, stakes were damaged mechanically and eliminated from test.

cSodium pentachlorophenate substituted for dinitrophenol.

This study was initiated by J. Oscar Blew.

Page 65: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 38

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per-8

-qui

nolin

olat

e af

ter a

ppro

xim

atel

y 9

year

s of

ser

vice

.St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

959

(Plo

t 54)

Con

ditio

n of

sta

kes

Nov

embe

r 196

8 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayAv

erag

e re

tent

ion

Num

-D

ecay

fung

iC

oppe

r-8-

ber

and

and

Aver

age

Solu

tion

quin

olin

olat

ein

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Cop

per-8

-qui

nolin

olat

e 0

.1%

in S

todd

ard

solv

ent

9.9

0.01

010

----

----

10--

9010

100

5.3

0.1

% in

Sto

ddar

d so

lven

t 9

.90.

020

10--

----

--20

1070

1010

04.

2

0.1

% in

Sto

ddar

d so

lven

t10

.00.

060

10--

----

1040

--50

990

5.6a

0.1

% in

Sto

ddar

d so

lven

t10

.20.

123

10--

----

1060

--30

990

7.8a

0.6

% p

araf

fin, 2

%; a

nd P

enta

lyn-

H,

1

0% in

Sto

ddar

d so

lven

t10

.10.

061

10--

10--

2070

----

770

8.8a

0.6

%; D

ield

rin, 0

.5%

in S

todd

ard

solv

ent

10.1

0.06

010

----

--10

70--

209

906.

6a

Unt

reat

ed c

ontro

ls--

--10

----

----

--20

8010

100

2.2

a Estim

ate

base

d on

per

cent

age

of s

take

s re

mai

ning

afte

r fin

al in

spec

tion.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 66: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 39

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

ble

nds

of e

xtra

cts

from

Tex

as li

gnite

tar a

fter a

bout

40

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

960

(Plo

t 57)

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eLi

gnite

-tar e

xtra

cts

(lb/

ft3 )te

stG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Hex

ane-

solu

ble

resi

due,

25%

; and

hex

ane

5.1

10--

----

--20

--80

1010

016

.2

dist

illate

, 75%

(by

wei

ght)

10.0

10--

----

3030

--40

770

--14

.110

----

--70

30--

--3

30--

Hig

h-bo

iling

met

hano

l sol

uble

s, 2

5%; h

exan

e5.

010

----

----

----

100

1010

018

.8

dist

illate

, 75%

(by

wei

ght)

9.3

10--

----

7010

--20

330

--15

.210

----

--10

0--

----

----

--

Hig

h-bo

iling

met

hano

l sol

uble

s, 1

0%; h

exan

e-5.

110

----

----

10--

9010

100

18.8

s

olub

le re

sidu

e, 2

0%; a

nd h

exan

e di

stilla

te,

10.1

10--

----

5020

--30

550

--

70%

(by

wei

ght)

14.7

10--

----

100

----

----

----

Hig

h-bo

iling

met

hano

l sol

uble

s, 2

0%; h

exan

e-5.

210

----

----

20--

8010

100

20.2

s

olub

le re

sidu

e, 1

0%; a

nd h

exan

e di

stilla

te,

10.0

10--

----

100

----

----

----

7

0% (b

y w

eigh

t)15

.210

----

--10

0--

----

----

--

Hig

h-bo

iling

met

hano

l sol

uble

s, 1

5%; a

nd h

exan

e5.

010

----

----

1010

8010

100

22.0

di

stilla

te, 8

5% (b

y w

eigh

t)10

.210

----

--90

----

101

10--

14.9

10--

10--

90--

----

----

--

Hig

h-bo

iling

met

hano

l sol

uble

s, 2

4,5%

; hex

ane

5.1

10--

----

1030

--30

660

--

dis

tilla

te, 7

4.5%

; and

pet

role

um s

ulfo

nate

9.

910

----

--70

20--

103

30--

(M

orpe

l X-9

14),

1% (b

y w

eigh

t)15

.010

----

--10

----

----

----

Unt

reat

ed c

ontro

ls--

10--

----

----

--10

010

100

2.6

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Page 67: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 40

--Con

ditio

n of

1- b

y 4-

by

18-in

. sta

kes

of e

mbe

dded

fibe

rboa

rda a

nd u

ntre

ated

Dou

glas

-fir h

eartw

ood

afte

r 18

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

960

(Plo

t 58)

Con

ditio

n of

sta

kes

Dec

embe

r 197

8 (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayD

ecay

fung

iN

umbe

ran

dan

dAv

erag

ein

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

eM

ater

ial

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Embe

dded

fibe

rboa

rda

6

b--

----

--10

0c--

-- 6

100

11.3

Dou

glas

-fir h

eartw

ood

10--

----

-- 7

010

2010

100

3.0

a Wes

tern

hem

lock

stra

nds

in p

ortla

nd c

emen

t.

b Stak

es m

issi

ng a

nd e

limin

ated

from

test

.

c Failu

res

attri

bute

d m

ainl

y to

the

effe

ct o

f moi

stur

e.

Page 68: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 41

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

trib

utyl

tin o

xide

and

pen

tach

loro

phen

ol s

olut

ions

with

he

avy

and

light

pet

role

um s

olve

nts,

with

and

with

out t

he a

dditi

on o

f Die

ldrin

and

Ald

rin, a

fter a

bout

40

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S, D

ecem

ber 1

960

(Plo

t 56)

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

it ete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

aG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Solu

tions

with

Sto

ddar

d so

lven

t

Trib

utyl

tin o

xide

, 0.3

%; a

nd D

ield

rin, 0

.3%

8.0

10--

----

--90

--10

1010

04.

9Tr

ibut

yltin

oxi

de, 0

.6%

; and

Die

ldrin

, 0.3

%8.

010

----

----

90--

1010

100

6.9

Trib

utyl

tin o

xide

, 0.3

%; a

nd A

ldrin

, 0.3

%8.

010

----

----

90--

1010

100

4.6

Trib

utyl

tin o

xide

0.3%

8.2

10--

----

--80

--20

1010

04.

50.

6%7.

910

----

----

50--

5010

100

7.0

Trib

utyl

tin o

xide

, 0.6

%; D

ield

rin, 0

.3%

;

and

wat

er re

pelle

nt, 4

.7%

8.0

10--

----

--10

0--

--10

100

6.9

Trib

utyl

tin o

xide

, 0.6

%; A

ldrin

, 0.3

%;

a

nd w

ater

repe

llent

, 4.7

%8.

010

----

----

70--

3010

100

5.3

Die

ldrin

, 0.6

%;

8.0

10--

----

--90

--10

1010

04.

0Pe

ntac

hlor

ophe

nol,

5%; p

ine

oil,

5%;

an

d w

ater

repe

llent

, 4.7

%8.

0 9

----

--11

44--

448

89--

Pent

achl

orop

heno

l, 5%

; pin

e oi

l, 5%

;

Die

ldrin

0.3

%; a

nd w

ater

repe

llent

, 4.7

%8.

010

----

--10

40--

509

90--

Wat

er re

pelle

nt, 4

.7%

8.0

10--

----

--80

--20

1010

04.

3Pe

ntac

hlor

ophe

nol,

5%; p

ine

oil,

5%; D

ield

rin 0

.3%

s

tabi

lizer

wax

, 2%

; an

d w

ater

repe

llent

, 4.7

%8.

0 9

----

--67

33--

--3

33--

Solu

tions

with

hea

vy p

etro

leum

sol

vent

(AW

PA P

9)

Trib

utyl

tin o

xide

, 0.3

%; a

nd D

ield

rin, 0

.3%

810

----

----

100

----

1010

022

.2Tr

ibut

yltin

oxi

de, 0

.6%

; and

Die

ldrin

, 0.3

%8

10--

----

--60

--40

1010

023

.0Tr

ibut

yltin

oxi

de0.

3%8

10--

----

--40

--60

1010

020

.80.

6%8

10--

----

--20

1070

1010

024

.0Pe

ntac

hlor

ophe

nol,

5%8

10--

----

7010

--20

330

--Pe

ntac

hlor

ophe

nol,

5%; a

nd s

tabi

lizer

wax

, 2%

810

----

--80

----

202

20--

Petro

leum

sol

vent

con

tols

8 9

----

----

11--

899

100

23.3

Unt

reat

ed c

ontro

ls--

10--

----

--70

--30

1010

03.

1a Te

n st

akes

wer

e or

igin

ally

inst

alle

d at

eac

h te

st s

tatio

n; th

is n

umbe

r has

sin

ce b

een

redu

ced

beca

use

of fa

ilure

to lo

cate

the

stak

es

at t

he ti

me

of in

spec

tion.

This

stu

dy w

as in

itiat

ed b

y Ed

war

d Pa

nek.

Page 69: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 42

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

. and

3/4

by

3/4

in. b

y 17

in.)

treat

ed w

ith p

enta

chlo

roph

enol

inliq

uefie

d pe

trole

um g

as a

nd in

hea

vy a

nd li

ght p

etro

leum

sol

vent

s af

ter a

bout

38-

1/2

year

s of

ser

vice

. St

akes

inst

alle

d at

Val

ley

View

Tes

tPl

ot, M

adis

on, W

I, an

d on

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Jul

y 19

61 (P

lot 5

9)

Aver

age

rete

ntio

n(lb

/in3 )

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)By

Serv

icea

ble

but

Des

troye

d by

--an

aly-

show

ing

som

e--

Dec

ayBy

wei

ght

sis

Num

-D

ecay

fung

iPe

nta-

Pent

a-be

ran

dan

dAv

erag

eSo

lu-

chlo

ro-

chlo

ro-

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Loca

tion

tion

phen

olph

enol

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Stak

es 2

by

4 no

min

al b

y 18

in.

Pent

achl

orop

heno

l in

MS

----

0.14

b10

----

----

10--

9010

100

18.9

liq

uefie

d pe

trole

um g

asa

MS

----

0.19

b10

----

----

10--

9010

100

15.9

MS

----

0.34

b10

----

--90

----

101

10--

MS

----

0.58

b10

----

--10

0--

----

----

--

Solu

tions

with

AW

PA P

9 (

heav

y pe

trole

um s

olve

nt)

Pen

tach

loro

phen

ol 3

.5%

(by

wei

ght)

MS

3.0

0.11

0.14

10--

----

10--

--90

990

--M

S4.

50.

190.

2210

----

--40

----

606

60--

4.2

% (b

y w

eigh

t)M

S6.

80.

290.

3210

----

--10

0--

----

----

--M

S16

.00.

670.

6910

21

--70

----

----

----

Solu

tions

with

Sto

ddar

d so

lven

t

Pe

ntac

hlor

ophe

nol,

4.0%

;M

S3.

60.

140.

1410

----

----

10--

9010

100

13.7

p

araf

fin, 2

%; a

ndM

S4.

60.

180.

1810

----

----

----

100

1010

015

.9

Pen

taly

n-H

, 10%

(by

wei

ght)

Pe

ntac

hlor

ophe

nol,

5%;

MS

7.6

0.38

0.39

10--

----

20--

--80

880

--

par

affin

, 2%

; and

MS

13.5

0.67

0.70

10--

----

100

----

----

----

P

enta

lyn-

H, 1

0% (b

y w

eigh

t)

Unt

reat

ed c

ontro

lsM

S--

----

10--

----

--30

3040

1010

02.

1

(Pag

e 1

of 2

)

Page 70: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine
Page 71: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 42

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

. and

3/4

by

3/4

in. b

y 17

in.)

treat

ed w

ith p

enta

chlo

roph

enol

inliq

uefie

d pe

trole

um g

as a

nd in

hea

vy a

nd li

ght p

etro

leum

sol

vent

s af

ter a

bout

38-

1/2

year

s of

ser

vice

. St

akes

inst

alle

d at

Val

ley

View

Tes

tPl

ot, M

adis

on, W

I, an

d on

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Jul

y 19

61 (P

lot 5

9)--c

oncl

uded

Aver

age

rete

ntio

n(lb

/in3 )

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)By

Serv

icea

ble

but

Des

troye

d by

--an

aly-

show

ing

som

e--

Dec

ayBy

wei

ght

sis

Num

-D

ecay

fung

iPe

nta-

Pent

a-be

ran

dan

dAv

erag

eSo

lu-

chlo

ro-

chlo

ro-

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Loca

tion

tion

phen

olph

enol

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)St

akes

3/4

by

3/4

by 1

7 in

.

Pent

achl

orop

heno

l in

MS

----

0.15

c10

----

----

40--

6010

100

5.5

liq

uefie

d pe

trole

um g

asa

WI

----

0.15

c15

----

----

100

----

1510

010

.0M

S--

--0.

19c

8d--

----

--50

--50

810

04.

6W

I--

--0.

19c

14d

----

----

100

----

1410

012

.4M

S--

--0.

31c

9d--

----

--22

1167

910

011

.9W

I--

--0.

31c

13d

----

----

100

----

1310

013

.7M

S--

--0.

48c

8d--

----

--38

1250

810

014

.9W

I--

--0.

48c

7d--

----

--10

0--

--7

100

17.5

Solu

tions

with

AW

PA P

9M

S3.

20.

14--

9d--

----

--11

--89

910

014

.5 (

heav

y pe

trole

um s

olve

nt)

WI

3.3

0.14

--5d

----

----

100

----

510

016

.4 P

enta

chlo

roph

enol

MS

3.8

0.16

--10

----

----

1010

8010

100

14.5

4.2

% (b

y w

eigh

t)W

I3.

90.

16--

7d--

----

--10

0--

--7

100

15.8

MS

5.7

0.24

--4d

----

----

25--

754

100

18.4

WI

5.5

0.23

--5d

----

----

100

----

510

017

.8M

S16

.70.

70--

4d--

----

----

100

410

030

.4W

I17

.20.

73--

4d--

----

--10

0--

--4

100

22.4

Solu

tions

in S

todd

ard

solv

ent

P

enta

chlo

roph

enol

, 4.0

%;

MS

3.5

0.14

--9d

----

----

4411

449

100

5.6

para

ffin,

2%

; and

WI

3.0

0.12

--11

d--

----

--10

0--

--11

100

10.8

Pent

alyn

-H, 1

0% (b

y w

eigh

t)M

S3.

90.

16--

10--

----

--30

--70

1010

04.

9W

I4.

00.

16--

13d

----

----

100

----

1310

010

.8

Pe

ntac

hlor

ophe

nol,

5.0%

;M

S6.

40.

32--

9d--

----

--22

--78

910

014

.4

pa

raffi

n, 2

.0%

; and

WI

6.6

0.33

--14

----

----

100

----

1410

014

.4

Pe

ntal

yn-H

, 10%

(by

wei

ght)

MS

14.4

0.72

--4d

----

----

50--

504

100

24.9

WI

14.6

0.73

--5d

----

----

100

----

10

021

.0U

ntre

ated

con

trols

MS

----

--10

----

----

4030

3010

100

1.5

WI

----

--15

----

----

100

----

1510

04.

0a It

has

been

repo

rted

that

the

form

ulat

ion

of tr

eatin

g so

lutio

n in

liqu

efie

d pe

trole

um g

as h

as b

een

chan

ged

sinc

e th

e st

akes

wer

e tre

ated

.b Fr

om th

e an

alys

is o

f com

posi

te s

ampl

e of

cro

ss-s

ectio

n w

afer

s ta

ken

at m

idpo

int f

rom

ten

2- b

y 4-

by

18-in

. sta

kes

and

mat

ched

to th

e 10

sta

kes

treat

ed fo

r ins

talla

tion.

Bec

ause

rete

ntio

ns w

ere

not d

eter

min

ed fo

r ind

ivid

ual t

est s

take

s, e

xtra

sta

kes

wer

e no

t tre

ated

to p

rovi

de a

sel

ectio

n, a

ccor

ding

to re

tent

ions

, for

the

test

inst

alla

tion.

c Base

d on

ana

lysi

s by

Bel

l Tel

epho

ne L

abor

ator

ies

of 2

-in. s

ectio

ns c

ut a

djac

ent t

o th

e te

st s

take

s.d St

akes

inju

red

mec

hani

cally

and

elim

inat

ed fr

om te

st.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

(Pag

e 2

of 2

)

Page 72: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 43

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per-8

-qui

nolin

olat

e an

d pe

ntac

hlor

ophe

nol i

n he

avy

petro

leum

solv

ent a

fter 3

7 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 196

3 (P

lot 6

2)

Con

ditio

n of

sta

kes

Janu

ary

2000

(%

)Av

erag

e re

tent

ion

Serv

icea

ble

but

Des

troye

d by

--C

oppe

r-8-

show

ing

som

e--

Dec

ayqu

inol

inol

ate

Num

-D

ecay

fung

ior

pen

ta-

ber

and

and

Aver

age

Solu

tion

chlo

roph

enol

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 ) (l

b/ft3 )

test

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Solu

tions

with

hea

vy p

etro

leum

sol

vent

(A

WPA

P9)

:Cop

per-8

-qui

nolin

olat

e

0.15

%9.

40.

014

10--

----

1020

1060

990

--

0.3%

10.1

0.03

010

----

----

20--

8010

100

27.3

0.6%

9.9

0.05

910

----

--10

50--

409

90--

1.2%

10.3

0.12

49a

----

--10

0--

----

----

--

Pent

achl

orop

heno

l 4.9

8%10

.60.

540

10--

10--

90--

----

----

--

Petro

leum

sol

vent

con

trols

8.5

--10

----

----

3010

6010

100

20.9

Unt

reat

ed c

ontro

ls--

--10

----

----

20--

8010

100

2.9

a Ten

stak

es o

rigin

ally

inst

alle

d; e

limin

ated

sta

kes

rem

oved

for c

ause

s ot

her t

han

deca

y or

inse

ct a

ttack

.

This

stu

dy w

as in

itiat

ed b

y L.

R. G

jovi

k.

Page 73: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 44--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with heptadecyltrimethyl-tetrahydropyrimidine(HTP) in No. 2 fuel oil after about 37 years of service. Stakes placed in test on the Harrison Experimental Forest,Saucier, MS, December 1963 (Plot 63)

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage retention ber and and Average

(lb/ft3) in Termite termite Decay Termite termite Total removed lifePreservative Solution HTP test Good Decay attack attack fungi attack attack Number % (year)

HTP, 2.5%, No. 2 fuel oil 6.0 0.150 10 -- -- -- -- -- -- 100 10 100 12.5

HTP, 5%, No. 2 fuel oil 8.1 0.406 10 -- -- -- 30 -- -- 70 7 70 --

HTP, 5%, No. 2 fuel oil 10.0 0.498 10 -- -- -- 60 20 -- 20 4 40 --

Untreated controls -- -- 10 -- -- -- -- -- -- 100 10 100 2.3

This study was initiated by H. L. Davidson.

Condition of stakes June 2000 (%)

Page 74: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 45--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in. and 3/4 by 3/4 by 16 in.) treated with pentachlorophenol in liquefied petroleum gas and in heavy and light petroleum solvents after about 35 years of service. Stakes placed in test on theHarrison Experimental Forest, Saucier, MS, December 1963 (Plot 61)

Condition of stakes February 1998 (%)Serviceable but Destroyed by--showing some-- Decay

(lb/in3) Num- Decay fungiPenta- ber and and Average

Solu- chloro- in Termite termite Decay Termite termite Total removed lifePreservative tion phenol testc Good Decay attack attack fungi attack attack Number % (year)

Stakes 2 by 4 in.

Pentachlorophenol in -- 0.34a 10 -- -- -- 10 40 -- 50 9 90 --

liquefied petroleum gasb -- 0.49a 10 -- -- -- 90 10 -- -- 1 10 ---- 0.65a 10 -- -- -- 100 -- -- -- -- -- --

-- 0.39a,d 10 -- -- -- 100 -- -- -- -- -- --

Pentachlorophenol, 5% in heavy petroleum oil 10.6 0.53a 10 10 10 80 -- -- -- -- -- -- --

Heavy petroleum oil 8.0 -- 10 -- -- -- -- 20 -- 80 10 100 19.7

Untreated controls -- -- 10 -- -- -- -- 20 -- 80 10 100 2.5

Stakes 3/4 by 3/4 in.

Pentachlorophenol in -- 0.34a 10 -- -- -- -- 70 -- 30 10 100 8.6

liquefied petroleum gasb -- 0.40a 8 -- -- -- -- 75 -- 25 8 100 7.2-- 0.59a 6 -- -- -- -- 67 -- 33 6 100 9.1-- 0.70a 8 -- -- -- -- 50 -- 50 8 100 16.5

Pentachlorophenol, 5% in heavy petroleum oil 10.8 0.54e 4 -- -- -- -- 50 -- 50 4 100 20.7

Heavy petroleum oil 8.3 -- 8 -- -- -- -- 75 25 -- 8 100 6.6

Untreated controls -- -- 10 -- -- -- -- 40 10 50 10 100 1.4

aBy x-ray analysis of samples from pieces from which stakes were cut.

bWith cosolvent of isopropyl ether.cWhen the number of stakes is less than 10, stakes were damaged mechanically and eliminated from test.

dTreated in commercial charge with poles and crossarms.eComputed.

This study was initiated by J. Oscar Blew.

Average retention

Page 75: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 46

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per-c

hrom

e-bo

ron

and

acid

cop

per c

hrom

ate

pres

erva

tives

afte

r 30

year

s of

ser

vice

. St

akes

pla

ced

in te

st o

n th

e H

arris

on E

xper

imen

tal

Fore

st, S

auci

er, M

S, J

anua

ry 1

967

(Plo

t 66)

Con

ditio

n of

sta

kes

Janu

ary

1997

(%)

Serv

icea

ble

but

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nain

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

ePr

eser

vativ

e (l

b/ft3 )

test

bG

ood

Dec

ayat

tack

atta

ckfu

ngi

atta

ckat

tack

Num

ber

%(y

ear)

Cop

per-c

hrom

e-bo

ron

0.25

(0.

13)

10--

----

--60

--40

1010

03.

9 (

a pr

oduc

t of

0.30

(0.

16)

10--

----

--60

--40

1010

04.

9 D

r. W

olm

an, G

mbH

, 0.

60 (

0.31

)10

----

----

100

----

1010

05.

5 S

inzh

eim

, Ger

man

y,1.

11 (

0.58

)10

----

--10

90--

--9

90--

cov

ered

by

U.S

. pat

ent

1.24

(0.

65)

911

22--

1144

--11

556

-- N

o. 3

,007

,844

)1.

64 (

0.86

)10

2020

--20

40--

--4

40--

Acid

cop

per c

hrom

ate

0.30

(0.

14)

10--

----

--10

0--

--10

100

6.1

(AW

PA P

5-68

)0.

60 (

0.29

)10

----

----

100

----

1010

04.

6

Unt

reat

ed c

ontro

ls--

10--

----

--10

90--

1010

02.

6

a Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

b Ten

stak

es o

rigin

ally

inst

alle

d; e

limin

ated

sta

kes

rem

oved

for c

ause

s ot

her t

han

deca

y or

inse

ct a

ttack

.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.

Des

troye

d by

--

Page 76: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 47

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

11

stan

dard

woo

d pr

eser

vativ

es a

fter a

bout

35

year

s of

ser

vice

.St

akes

pla

ced

in te

st in

Nov

embe

r 196

7 at

Lak

e C

harle

s, L

A, in

an

area

infe

sted

by

Form

osan

term

ites

and

on th

eH

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S (P

lot 6

7)

Con

ditio

n of

sta

kes

Janu

ary

2002

(MS)

and

Jan

uary

198

4 (L

A) (

%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

eAW

PAre

tent

iona

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Stan

dard

Loca

tion

(lb/

ft3 )te

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Cre

osot

e, c

oal-t

arP1

-65

LA 4

.910

10--

--50

40--

--4

40--

10.2

1060

20--

20--

----

----

--15

.010

100

----

----

----

----

--M

S5.

110

----

--40

50--

106

60--

9.7

10--

10--

90--

----

----

--15

.410

--40

--60

----

----

----

Cre

osot

e-co

al-ta

rP2

-68

LA4.

710

----

--60

40--

--4

40--

sol

utio

n (7

0-30

)9.

910

9010

----

----

----

----

14.9

1010

0--

----

----

----

----

MS

3.9

10--

----

2050

--30

880

--10

.710

1040

--50

----

----

----

16.2

1020

80--

----

----

----

--

Cre

osot

e-pe

trole

umP3

-67

LA5.

810

1010

--40

30--

104

40--

sol

utio

n (5

0-50

)12

.110

7010

--20

----

----

----

18.3

1010

0--

----

----

----

----

MS

6.0

10--

----

3050

--20

770

--12

.110

1030

--60

----

----

----

18.5

1010

6010

20--

----

----

--

Pent

achl

orop

heno

l,P8

-64

and

LA5.

810

40--

--60

----

----

----

5%

in h

eavy

pet

role

um P

9-67

9.9

1070

10--

20--

----

----

-- 1

5.1

1080

20--

----

----

----

--M

S

7.0

10--

----

8010

--10

220

--

9.5

10--

----

100

----

----

----

14.

69

--22

--78

----

----

----

Acid

cop

per c

hrom

ate

P5-6

8LA

0.50

(0.2

5)10

----

----

3060

1010

100

8.5

1.00

(0.5

0)9

--11

--78

----

111

11--

1.49

(0.7

4)9

2010

--60

----

----

----

MS

0.51

(0.2

5)10

----

--30

60--

107

70--

1.01

(0.5

0)10

4020

----

40--

--4

40--

1.54

(0.7

6)9

56--

1111

22--

--2

22--

Amm

onia

cal c

oppe

r ars

enat

eP5

-68

LA0.

25 (0

.24)

10--

----

1070

--20

990

--0.

46 (0

.44)

10--

----

8020

----

220

--0.

67 (0

.63)

1010

1070

10--

--1

10--

MS

0.26

(0.2

5)10

--10

--60

20--

103

30--

0.48

(0.4

5)10

--60

--30

10--

--1

10--

0.70

(0.6

6)10

1030

--60

----

----

----

(Pag

e 1

of 2

)

Page 77: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 47

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

11

stan

dard

woo

d pr

eser

vativ

es a

fter a

bout

35

year

s of

ser

vice

.St

akes

pla

ced

in te

st in

Nov

embe

r 196

7 at

Lak

e C

harle

s, L

A, in

an

area

infe

sted

by

Form

osan

term

ites

and

on th

eH

arris

on E

xper

imen

tal F

ores

t, Sa

ucie

r, M

S (P

lot 6

7)--c

oncl

uded

Con

ditio

n of

sta

kes

Janu

ary

2002

(MS)

and

Jan

uary

198

4 (L

A) (

%)

Serv

icea

ble

but

Des

troye

d by

--sh

owin

g so

me-

-D

ecay

Num

-D

ecay

fung

iAv

erag

ebe

ran

dan

dAv

erag

eAW

PAre

tent

ion

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

Stan

dard

Loca

tion

(lb/

ft3 )te

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Chr

omat

ed c

oppe

r ars

enat

eP5

-68

LA0.

40 (0

.23)

10--

----

7010

1010

330

-- t

ype

A0.

76 (0

.44)

1050

10--

40--

----

----

--1.

11 (0

.64)

1090

10--

----

----

----

--M

S0.

39 (0

.22)

10--

2010

3030

--10

440

--0.

76 (0

.44)

1050

--40

--10

----

110

--1.

14 (0

.66)

810

0--

----

----

----

----

Chr

omat

ed c

oppe

r ars

enat

eP5

-68

LA0.

25 (0

.23)

10--

----

8010

--10

220

-- t

ype

B0.

44 (0

.40)

1020

30--

50--

----

----

--0.

65 (0

.59)

1080

10--

10--

----

----

--M

S0.

25 (0

.23)

10--

20--

5030

----

330

--0.

42 (0

.38)

10--

20--

6010

10--

220

--0.

61 (0

.55)

1030

5020

----

----

----

--

Chr

omat

ed z

inc

chlo

ride

P5-6

8LA

0.76

(0.4

6)10

----

----

--80

2010

100

6.0

1.02

(0.6

2)10

----

----

1060

3010

100

7.2

1.50

(0.9

2)9

----

----

1167

229

100

8.3

MS

0.76

(0.4

6)10

----

----

30--

7010

100

13.8

1.02

(0.6

2)10

----

----

30--

7010

100

14.9

1.57

(0.9

6)10

----

----

70--

3010

100

17.8

Fluo

r chr

ome

arse

nate

phe

nol

P5-6

8LA

0.35

(0.2

2)10

----

--10

5020

209

90--

typ

e A

0.50

(0.3

1)10

----

--20

1010

608

80--

1.11

(0.6

9)10

----

--30

70--

--7

70--

MS

0.36

(0.2

2)10

----

----

60--

4010

100

19.3

0.51

(0.3

1)10

----

--10

60--

309

90--

1.16

(0.7

2)10

----

--50

40--

105

50--

Fluo

r chr

ome

arse

nate

phe

nol

P5-6

8LA

0.35

(0.2

1)10

----

--10

2010

609

90--

typ

e B

0.50

(0.3

0)10

----

--20

60--

208

80--

1.12

(0.6

8)10

1010

--50

30--

--3

30--

MS

0.35

(0.2

1)9

----

----

4411

449

100

19.2

0.51

(0.3

0)10

----

--20

70--

108

80--

1.19

(0.7

2)9

--11

--56

33--

--3

33--

Unt

reat

ed c

ontro

lsLA

--10

----

----

1090

--10

100

2.3

MS

--10

----

----

3020

5010

100

2.3

a Ret

entio

n va

lues

in p

aren

thes

es a

re b

ased

on

pres

erva

tive

oxid

es.

b Ten

stak

es o

rigin

ally

inst

alle

d; e

limin

ated

sta

kes

rem

oved

for c

ause

s ot

her t

han

deca

y or

inse

ct a

ttack

.

This

stu

dy w

as in

itiat

ed b

y J.

Osc

ar B

lew

.(P

age

2 of

2)

Page 78: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 48

--Con

ditio

n of

Sou

ther

n Pi

ne s

take

s (2

by

4 in

. nom

inal

by

18 in

.) tre

ated

with

cop

per c

hrom

e ph

osph

orus

and

chr

omat

ed c

oppe

rar

sena

te ty

pe II

I pre

serv

ativ

es a

fter a

bout

29

and

20 y

ears

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Exp

erim

enta

l For

est,

Sauc

ier,

MS,

Dec

embe

r 197

1, a

nd M

adis

on, W

I, M

ay 1

972

(Plo

t 68)

Con

ditio

n of

sta

kes

Janu

ary

2000

(MS)

and

Oct

ober

199

2 (W

I) (%

)Se

rvic

eabl

e bu

t D

estro

yed

by--

show

ing

som

e--

Dec

ayN

um-

Dec

ayfu

ngi

Aver

age

ber

and

and

Aver

age

rete

ntio

nin

Term

itete

rmite

Dec

ayTe

rmite

term

iteTo

tal r

emov

edlif

e

Pres

erva

tive

Loca

tion

(lb/

ft3 )te

stc

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Cop

per c

hrom

e ph

osph

orus

MS

0.26

a10

----

--40

60--

--6

60--

WI

0.27

a 9

--33

----

67--

--6

67--

MS

0.46

a10

1010

1020

50--

--5

50--

MS

0.75

a10

5010

20--

20--

--2

20--

WI

0.74

a10

7030

----

----

----

----

MS

1.50

a10

50--

--30

20--

--2

20--

Chr

omat

ed c

oppe

r ars

enat

e ty

pe II

IM

S0.

20b

1010

----

90--

----

----

--

(Fed

. Spe

c. T

T-W

-550

)W

I0.

20b

1020

80--

----

----

----

--

MS

0.40

b10

8010

10--

----

----

----

WI

0.40

b10

100

----

----

----

----

--

MS

0.60

b10

9010

----

----

----

----

WI

0.60

b10

9010

----

----

----

----

Unt

reat

ed c

ontro

lsM

S--

10--

----

--10

--90

1010

02.

9W

I--

9--

----

--10

0--

--9

100

7.4

a Ret

entio

n ba

sed

on O

smos

e C

ompa

ny's

ana

lysi

s of

pre

serv

ativ

e ox

ides

.

b Ret

entio

n ba

sed

on p

rese

rvat

ive

oxid

es.

c Ten

stak

es o

rigin

ally

inst

alle

d; e

limin

ated

sta

kes

rem

oved

for c

ause

s ot

her t

han

deca

y or

inse

ct a

ttack

.

This

stu

dy w

as in

itiat

ed b

y L.

R. G

jovi

k.

Page 79: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Tabl

e 49

--Con

ditio

n of

asp

en p

artic

lebo

arda s

take

s (3

/4 b

y 4

by 1

8 in

.) tre

ated

with

chr

omat

ed c

oppe

r ars

enat

e ty

pe II

I, flu

or c

hrom

e ar

sena

te p

heno

l

type

A, a

nd p

enta

chlo

roph

enol

in e

than

ol o

r min

eral

spi

rits

afte

r abo

ut 2

5-1/

2 ye

ars

of s

ervi

ce.

Stak

es p

lace

d in

test

on

the

Har

rison

Ex

perim

enta

l For

est,

Sauc

ier,

MS,

May

197

3 (P

lot 7

0)

Con

ditio

n of

sta

kes

Febr

uary

199

8 (%

)Av

erag

eSe

rvic

eabl

e bu

t D

estro

yed

by--

rete

ntio

nsh

owin

g so

me-

-D

ecay

base

d on

Num

-D

ecay

fung

ipr

eser

vativ

e be

ran

dan

dAv

erag

eox

ides

inTe

rmite

term

iteD

ecay

Term

itete

rmite

Tota

l rem

oved

life

Pres

erva

tive

(lb/

ft3 )te

stb

Goo

dD

ecay

atta

ckat

tack

fung

iat

tack

atta

ckN

umbe

r%

(yea

r)

Flak

es tr

eate

d be

fore

fabr

icat

ion

into

par

ticle

boar

dc

Chr

omat

ed c

oppe

r ars

enta

te ty

pe II

I0.

25 9

--22

--11

67--

--6

67--

(Fe

d. S

pec.

TT-

W-5

50)

0.40

10--

10--

3060

----

660

--0.

8010

1080

----

10--

--1

10--

Fluo

r chr

ome

arse

nate

phe

nol t

ype

A0.

2510

----

----

90--

1010

100

6.0

(Fe

d. S

pec.

TT-

W-5

35)

0.50

10--

----

--90

--10

1010

08.

8

Pent

achl

orop

heno

l (Fe

d. S

pec.

TT-

W-5

70)

0.25

10--

----

--40

--60

1010

05.

5 i

n et

hano

l 0.

4010

----

----

50--

5010

100

7.5

0.80

10--

----

1050

--40

990

--

Pres

sure

-trea

ted

parti

cleb

oard

Chr

omat

ed c

oppe

r ars

enta

te ty

pe II

I0.

26 8

----

--10

0--

--8

100

19.7

(Fe

d. S

pec.

TT-

W-5

50)

0.41

9--

11--

6722

----

222

--0.

8410

6030

10--

----

----

----

Fluo

r chr

ome

arse

nate

phe

nol t

ype

A0.

2610

----

----

70--

3010

100

7.5

(Fe

d. S

pec.

TT-

W-5

35)

0.54

9--

----

--10

0--

--9

100

11.3

Pent

achl

orop

heno

l (Fe

d. S

pec.

TT-

W-5

70)

0.22

10--

----

--70

--30

1010

05.

55%

in m

iner

al s

pirit

s an

d 4%

pin

e oi

l0.

4010

----

----

80--

2010

100

8.5

0.82

10--

----

3050

--20

770

--

Unt

reat

ed c

ontro

ls--

10--

----

--10

1080

1010

02.

4

a Den

sity

40

lb/ft

3 .b Te

n st

akes

orig

inal

ly in

stal

led;

elim

inat

ed s

take

s re

mov

ed fo

r cau

ses

othe

r tha

n de

cay

or in

sect

atta

ck.

c Flak

es s

pray

ed w

ith p

rede

term

ined

am

ount

of p

rese

rvat

ive

solu

tion

whi

le b

eing

tum

bled

in s

cree

n.

This

stu

dy w

as in

itiat

ed b

y L.

R. G

jovi

k.

Page 80: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 50--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with propylene oxide, butylene oxide, andepichlorohydrin/propylene oxide combinations after 17 and 21 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, October 31, 1974, and September 1978 (Plot 71)

Condition of stakes August 1995 (%)Serviceable but Destroyed by--

Average showing some-- Decayloading-- Num- Decay fungiWeight ber and and Averageadd-on in Termite termite Decay Termite termite Total removed life

Nontoxic preservatives (%) test Good Decay attack attack fungi attack attack Number % (year)

Propylene oxide 15-27 2 -- -- -- -- -- -- 100 2 100 2.229-33 3 -- -- -- -- 33 -- 67 3 100 6.2

Butylene oxide 17-22 2 -- -- -- -- -- -- 100 2 100 4.737-40 3 -- -- -- -- 100 -- -- 3 100 12.231a 15 -- 7 -- 53 33 -- -- 5 33 --

Epichlorohydrin, 1 part; 10 1 -- -- -- -- -- -- 100 1 100 9.2 propylene oxide, 2 parts 26 1 -- -- -- -- -- -- 100 1 100 5.2

Controls -- 16 -- -- -- -- 56 -- 44 16 100 3.0

aFifteen butylene-oxide-treated stakes installed in Mississippi, September 1978.

Data presented in this table are part of a larger study under the guidance of R. M. Rowell.

Page 81: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)

Condition of stakes January 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Southern Pinea,b nominal 2- by 4-in. by 18-in. unincised

Chromated copper MS 0.23 10 20 60 10 10 -- -- -- -- -- -- arsenate WI 0.14 10 70 30 -- -- -- -- -- -- -- -- type III MS 0.28 10 70 10 20 -- -- -- -- -- -- --

WI 0.19 9d 100 -- -- -- -- -- -- -- -- --MS 0.48 10 90 10 -- -- -- -- -- -- -- --WI 0.29 10 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- 10 20 10 60 9 90 --WI -- 10 -- 50 -- -- 50 -- -- 5 50 --

Southern Pinea,b nominal 2- by 4-in. by 18-in. incised

Chromated copper MS 0.27 10 70 10 -- 20 -- -- -- -- -- -- arsenate WI 0.19 10 90 10 -- -- -- -- -- -- -- -- type III MS 0.47 10 100 -- -- -- -- -- -- -- -- --

WI 3.30 10 100 -- -- -- -- -- -- -- -- --MS 0.62 10 100 -- -- -- -- -- -- -- -- --WI 0.37 10 100 -- -- -- -- -- -- -- -- --

Southern Pinea 3/4- by 3-1/2 by 18-in. plywood

Chromated copper MS 0.39 10 20 30 -- 20 30 -- -- 3 30 -- arsenate WI 0.38 10 60 40 -- -- -- -- -- -- -- -- type IIIc MS 0.80 10 100 -- -- -- -- -- -- -- -- --

WI 0.78 9d 100 -- -- -- -- -- -- -- -- --MS 1.22 10 100 -- -- -- -- -- -- -- -- --WI 1.17 9d 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- -- -- 10 90 10 100 2.8WI -- 9d -- -- -- -- 100 -- -- 10 100 5.8

Chromated copper MS 0.36f 9d 11 44 11 22 11 -- -- 1 11 --

arsenate WI 0.36f 9d 22 78 -- -- -- -- -- -- -- -- type IIIe MS 0.75f 10 100 -- -- -- -- -- -- -- -- --

WI 0.75f 10 100 -- -- -- -- -- -- -- -- --MS 1.16f 10 100 -- -- -- -- -- -- -- -- --

WI 1.16f 9d 100 -- -- -- -- -- -- -- -- --

Chromated copper MS 0.36f 9d 33 56 -- 11 -- -- -- -- -- -- arsenate WI 0.36f 9d 67 33 -- -- -- -- -- -- -- -- type IIIg MS 0.75f 10 90 10 -- -- -- -- -- -- -- --

WI 0.75f 10 100 -- -- -- -- -- -- -- -- --MS 1.16f 10 100 -- -- -- -- -- -- -- -- --WI 1.16f 9d 100 -- -- -- -- -- -- -- -- --

(Page 1 of 6)

Page 82: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)--continued

Serviceable but Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Southern Pinea,b nominal 2- by 4-in. by 18-in. unincised

Ammoniacal copper MS 0.11 10 -- 10 -- -- 20 10 60 9 90 -- arsenate WI 0.07 10 10 90 -- -- -- -- -- -- -- --

MS 0.30 10 -- 70 -- 10 10 10 -- 2 20 --WI 0.16 10 100 -- -- -- -- -- -- -- -- --MS 0.42 10 60 40 -- -- -- -- -- -- -- --WI 0.26 10 100 -- -- -- -- -- -- -- -- --

Southern Pinea,b nominal 2- by 4-in. by 18-in. incised

Ammoniacal copper MS 0.14 10 -- 40 -- 10 50 -- -- 5 50 -- arsenate WI 0.07 10 20 70 -- -- 10 -- -- 1 10 --

MS 0.30 9d 56 33 -- 11 -- -- -- -- -- --WI 0.15 10 70 30 -- -- -- -- -- -- -- --MS 0.65 10 60 40 -- -- -- -- -- -- -- --WI 0.39 10 100 -- -- -- -- -- -- -- -- --

Southern Pinea 3/4- by 3-1/2- by 18-in. plywood

Ammoniacal copper MS 0.39 10 -- 40 -- -- 60 -- -- 6 60 -- arsenatec WI 0.38 10 10 90 -- -- -- -- -- -- -- --

MS 0.81 10 20 80 -- -- -- -- -- -- -- --WI 0.79 10 90 10 -- -- -- -- -- -- -- --MS 1.19 10 20 80 -- -- -- -- -- -- -- --WI 1.15 9d 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.38f 10 -- 20 -- 10 70 -- -- 7 70 -- arsenatec WI 0.38f 9d -- 89 -- -- 11 -- -- 1 11 --

MS 0.77f 10 30 70 -- -- -- -- -- -- -- --WI 0.77f 10 70 30 -- -- -- -- -- -- -- --MS 1.08f 10 30 70 -- -- -- -- -- -- -- --WI 1.08f 10 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.38f 10 -- 10 -- 10 70 -- 10 8 80 -- arsenatec WI 0.38f 9d 11 89 -- -- -- -- -- -- -- --

MS 0.77f 10 20 70 -- -- 10 -- -- 1 10 --WI 0.77f 10 100 -- -- -- -- -- -- -- -- --MS 1.08f 10 20 80 -- -- -- -- -- -- -- --WI 1.08f 9d 90 10 -- -- -- -- -- -- -- --

(Page 2 of 6)

Condition of stakes January 2000 (%)

showing some--Destroyed by--

Total removed

Page 83: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)--continued

DecayNum- Decay fungi

Average ber and and Averageretention in Termite termite Decay Termite termite life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Douglas-fir nominal 2- by 4-in. by 18-in. unincised

Chromated copper MS 0.66 10 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.55 10 100 -- -- -- -- -- -- -- -- -- type III MS 1.24 10 100 -- -- -- -- -- -- -- -- --

WI 0.82 9d 89 11 -- -- -- -- -- -- -- --MS 1.62 10 100 -- -- -- -- -- -- -- -- --WI 1.11 10 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- -- 10 10 80 10 100 4WI -- 10 -- 20 -- -- 80 -- -- 8 80 --

Chromated copper MS 0.66 10 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.56 10 90 10 -- -- -- -- -- -- -- -- type III MS 1.28 10 100 -- -- -- -- -- -- -- -- --

WI 0.96 10 100 -- -- -- -- -- -- -- -- --MS 1.88 10 100 -- -- -- -- -- -- -- -- --WI 1.28 10 100 -- -- -- -- -- -- -- -- --

Douglas-fir 3/4- by 3-1/2- by 18-in. plywood

Chromated copper MS 0.62 10 90 10 -- -- -- -- -- -- -- -- arsenate WI 0.62 10 90 10 -- -- -- -- -- -- -- -- type IIIc MS 1.25 10 100 -- -- -- -- -- -- -- -- --

WI 1.22 10 90 10 -- -- -- -- -- -- -- --MS 1.88 10 90 10 -- -- -- -- -- -- -- --WI 1.83 10 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- -- 20 20 60 10 100 3WI -- 8d -- -- -- -- 100 -- -- 8 100 6

Chromated copper MS 0.60f 9d 100 -- -- -- -- -- -- -- -- --

arsenate WI 0.60f 8d 100 -- -- -- -- -- -- -- -- --

type IIIe MS 1.21f 9d 100 -- -- -- -- -- -- -- -- --

WI 1.21f 9d 100 -- -- -- -- -- -- -- -- --

MS 1.82f 10 100 -- -- -- -- -- -- -- -- --

WI 1.82f 10 100 -- -- -- -- -- -- -- -- --

Chromated copper MS 0.60f 10 100 -- -- -- -- -- -- -- -- --

arsenate WI 0.60 10 100 -- -- -- -- -- -- -- -- --

type IIIg MS 1.21f 10 100 -- -- -- -- -- -- -- -- --

WI 1.21f 8d 100 -- -- -- -- -- -- -- -- --

MS 1.82f 10 100 -- -- -- -- -- -- -- -- --

WI 1.82f 9d 100 -- -- -- -- -- -- -- -- --

(Page 3 of 6)

Total removed

Condition of stakes January 2000 (%)Serviceable but showing some--

Destroyed by--

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Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)--continued

DecayNum- Decay fungi

Average ber and and Averageretention in Termite termite Decay Termite termite life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Douglas-fir nominal 2- by 4-in. by 18-in. unincised

Ammoniacal copper MS 0.70 10 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.61 10 80 20 -- -- -- -- -- -- -- --

MS 1.42 10 100 -- -- -- -- -- -- -- -- --WI 1.29 10 100 -- -- -- -- -- -- -- -- --MS 2.14 10 50 50 -- -- -- -- -- -- -- --WI 1.95 9d 78 11 -- -- -- -- -- -- -- --

Douglas-fir 2- by 4-in. nominal by 18-in. incised

Ammoniacal copper MS 0.70 10 70 30 -- -- -- -- -- -- -- -- arsenate WI 0.62 10 90 10 -- -- -- -- -- -- -- --

MS 1.41 10 100 -- -- -- -- -- -- -- -- --WI 1.26 10 100 -- -- -- -- -- -- -- -- --MS 2.17 10 100 -- -- -- -- -- -- -- -- --WI 2.00 10 100 -- -- -- -- -- -- -- -- --

Douglas-fir 3/4- by 3-1/2- by 18-in. plywood

Ammoniacal copper MS 0.63 10 60 30 -- 10 -- -- -- -- -- -- arsenatec WI 0.62 10 40 60 -- -- -- -- -- -- -- --

MS 1.30 10 100 -- -- -- -- -- -- -- -- --WI 1.27 10 100 -- -- -- -- -- -- -- -- --MS 1.97 10 100 -- -- -- -- -- -- -- -- --WI 1.93 10 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.64f 10 20 80 -- -- -- -- -- -- -- -- arsenatee WI 0.64f 9d 33 67 -- -- -- -- -- -- -- --

MS 1.30f 10 100 -- -- -- -- -- -- -- -- --WI 1.30f 9d 100 -- -- -- -- -- -- -- -- --MS 1.97f 10 100 -- -- -- -- -- -- -- -- --WI 1.97f 9d 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.64f 10 50 50 -- -- -- -- -- -- -- -- arsenateg WI 0.64f 10 80 20 -- -- -- -- -- -- -- --

MS 1.30f 10 100 -- -- -- -- -- -- -- -- --WI 1.30f 9d 100 -- -- -- -- -- -- -- -- --MS 1.97f 10 90 10 -- -- -- -- -- -- -- --WI 1.97f 10 100 -- -- -- -- -- -- -- -- --

(Page 4 of 6)

Total removed

Condition of stakes January 2000 (%)

showing some--Serviceable but Destroyed by--

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Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)--continued

Condition of stakes January 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Engelmann spruce nominal 2- by 4-in. by 18-in. unincised

Chromated copper MS 0.31 10 80 -- -- 10 -- -- 10 1 10 -- arsenate WI 0.21 8d 88 12 -- -- -- -- -- -- -- -- type III MS 0.50 10 50 10 10 10 10 10 -- 2 20 --

WI 0.40 10 100 -- -- -- -- -- -- -- -- --MS 0.65 10 100 -- -- -- -- -- -- -- -- --WI 0.48 10 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- -- 10 10 80 10 100 3.3WI -- 10 -- -- -- -- 10 -- -- 1 10 7.5

Engelmann spruce nominal 2- by 4-in. by 18-in. incised

Chromated copper MS 0.41 10 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.28 9d

78 22 -- -- -- -- -- -- -- -- type III MS 0.66 10 100 -- -- -- -- -- -- -- -- --

WI 0.56 10 100 -- -- -- -- -- -- -- -- --MS 1.02 10 100 -- -- -- -- -- -- -- -- --WI 0.86 10 90 -- -- -- 10 -- -- 1 10 --

Engelmann spruce 3/4- by 3-1/2-in. by 18-in. plywood

Chromated copper MS 0.71 10 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.70 9d 89 11 -- -- -- -- -- -- -- -- type IIIc MS 1.38 10 100 -- -- -- -- -- -- -- -- --

WI 1.34 9d 100 -- -- -- -- -- -- -- -- --MS 2.03 10 100 -- -- -- -- -- -- -- -- --WI 1.82 9d 100 -- -- -- -- -- -- -- -- --

None MS -- 10 -- -- -- -- 10 20 70 10 100 2.6WI -- 8d -- -- -- -- 100 -- -- 8 100 3.1

Chromated copper MS 0.67f 10 90 10 -- -- -- -- -- -- -- -- arsenate WI 0.67f 10 80 20 -- -- -- -- -- -- -- -- type IIIe MS 1.25f 10 100 -- -- -- -- -- -- -- -- --

WI 1.26f 9d 100 -- -- -- -- -- -- -- -- --MS 1.76f 9d 100 -- -- -- -- -- -- -- -- --WI 1.76f 9d 100 -- -- -- -- -- -- -- -- --

Chromated copper MS 0.67f 9d 100 -- -- -- -- -- -- -- -- -- arsenate WI 0.67f 9d 100 -- -- -- -- -- -- -- -- -- type IIIg MS 1.25f 10 100 -- -- -- -- -- -- -- -- --

WI 1.25f 9d 100 -- -- -- -- -- -- -- -- --MS 1.76f 9d 100 -- -- -- -- -- -- -- -- --WI 1.76f 9d 100 -- -- -- -- -- -- -- -- --

(Page 5 of 6)

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Table 51--Condition of Southern Pine, Douglas-fir, and Engelmann spruce heartwood stakes treated with ammoniacal copper arsenate and chromated copper arsenate after approximately 26 years of service. Stakes placed in test at Madison, WI, May 1976, and on the Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 72)--concluded

Condition of stakes January 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative Location (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Engelmann spruce nominal 2- by 4-in. by 18-in. unincised

Ammoniacal copper MS 0.26 9d11 89 -- -- -- -- -- -- -- --

arsenate WI 0.20 10 30 70 -- -- -- -- -- -- -- --MS 0.63 10 60 40 -- -- -- -- -- -- -- --WI 0.50 10 100 -- -- -- -- -- -- -- -- --MS 1.03 10 80 20 -- -- -- -- -- -- -- --WI 0.75 10 90 10 -- -- -- -- -- -- -- --

Engelmann spruce nominal 2- by 4-in.by 18-in. incised

Ammoniacal copper MS 0.42 10 40 60 -- -- -- -- -- -- -- -- arsenate WI 0.30 10 60 40 -- -- -- -- -- -- -- --

MS 0.97 10 80 20 -- -- -- -- -- -- -- --WI 0.81 10 80 20 -- -- -- -- -- -- -- --MS 1.41 10 80 20 -- -- -- -- -- -- -- --WI 1.16 10 100 -- -- -- -- -- -- -- -- --

Engelmann spruce 3/4- by 3-1/2-in. by 18-in. plywood

Ammoniacal copper MS 0.70 10 20 70 -- -- -- -- -- -- -- -- arsenatec WI 0.68 10 60 40 -- -- -- -- -- -- -- --

MS 1.42 10 60 40 -- -- -- -- -- -- -- --WI 1.35 9d 100 -- -- -- -- -- -- -- -- --MS 2.14 10 60 40 -- -- -- -- -- -- -- --WI 2.08 9d 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.65f 10 10 90 -- -- -- -- -- -- -- -- arsenatee WI 0.65f 10 80 20 -- -- -- -- -- -- -- --

MS 1.29f 10 70 30 -- -- -- -- -- -- -- --WI 1.29f 9d 100 -- -- -- -- -- -- -- -- --MS 2.02f 10 90 10 -- -- -- -- -- -- -- --WI 2.02f 8d 100 -- -- -- -- -- -- -- -- --

Ammoniacal copper MS 0.65f 10 20 80 -- -- -- -- -- -- -- -- arsenateg WI 0.65f 9d 100 -- -- -- -- -- -- -- -- --

MS 1.29f 10 80 20 -- -- -- -- -- -- -- --WI 1.29f 8d 100 -- -- -- -- -- -- -- -- --MS 2.02f 10 90 10 -- -- -- -- -- -- -- --WI 2.02f 9d 100 -- -- -- -- -- -- -- -- --

aSome Southern Pine contained a small amount of sapwood, and the Southern Pine plywood was mixed heartwood and sap.bResin content of Southern Pine ranged from 0.87% to 27.4%.cTreated as 3/4- by 3-1/2 by 18-in. stakes.dTen stakes originally installed; eliminations were for causes other than decay or insect attack.eStakes cut from treated 2- by 4-ft panel.fRetention by weight of panels from which stakes were cut.

in which the panels were treated.This study was initiated by L. R. Gjovik.

(Page 6 of 6)

gStakes cut from treated 2- by 4-ft panel; all cut surfaces given a liberal brush coat of a 4.5% solution of the preservative

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DecayNum- Decay fungi

Average ber and and Averageretentiona in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Ammoniacal copper 1.33 20 85 10 -- 5 -- -- -- -- -- -- borate 0.66 20 50 25 -- -- 25 -- -- 5 25 --

0.45 20 25 60 -- 15 -- -- -- -- -- --0.33 20 20 40 -- 10 30 -- -- 6 30 --0.22 20 5 25 -- -- 70 -- -- 14 70 --0.17 20 -- 25 -- -- 70 -- 5 15 75 --

Ammoniacal copper 1.35 20 55 45 -- -- -- -- -- -- -- -- arsenate 0.66 20 35 65 -- -- -- -- -- -- -- --

0.46 20 25 75 -- -- -- -- -- -- -- --0.33 20 -- 75 -- 20 5 -- -- 1 5 --0.23 20 -- 50 -- 20 25 -- 5 6 30 --0.17 20 -- -- -- 5 50 -- 45 19 95 --

Untreated controls -- 20 -- -- -- -- 5 20 75 20 100 2.6aRetention based on preservative oxides.

This study was initiated by B.R. Johnson.

Table 52--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with ammoniacal copper borate and ammoniacal copper asrsenate after approximately 25 years of service. Stakes placed in test on the

showing some--

Harrison Experimental Forest, Saucier, MS, December 1975 (Plot 73)

Condition of stakes June 2002 (%)Serviceable but Destroyed by--

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Table 53--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with fire-retardant chemicals after about 17-1/2 years of service. Stakes placed in test on the Harrison Experimental Forest,

Condition of stakes December 1993 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

UDFP fire 2.8 9 -- -- -- -- -- 100 -- 9 100 4.8 retardanta 6.0 10 -- -- -- -- -- 90 10 10 100 9.7

9.5 10 -- -- -- -- 30 40 30 10 100 15.4

Untreated controls -- 10 -- -- -- -- 10 -- 90 10 100 2.5

aReported to contain urea, dicyandiamide, formaldehyde, and phosphoric acid.

This study was initiated by L. R. Gjovik.

Saucier, MS, May 1976 (Plot 74)

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Table 54--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in. and 3/4 by 3/4 in.) treated with pentachlorophenol in light cycle oil and copper-8-quinolinolate after 17 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1976 (Plot 75)

Condition of stakes December 1993 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testb Good Decay attack attack fungi attack attack Number % (year)

Stakes 2 by 4 by 18 in.Pentachlorophenol 0.48 10 -- 10 -- 90 -- -- -- -- -- --

Copper-8-quinolinolatea 1.12 10 -- -- -- 60 10 -- 30 4 40 --Untreated controls -- 10 -- -- -- -- 30 20 50 10 100 2.5

Stakes 3/4 by 3/4 by 18 in.

Pentachlorophenol 0.21 8 -- -- -- -- 25 -- 75 8 100 13.20.31 10 -- -- -- 30 40 10 20 7 70 --0.38 10 -- -- -- 30 30 -- 10 4 40 --0.47 10 -- -- -- 70 20 -- 10 3 30 --0.67 10 -- 10 -- 90 -- -- -- -- -- --

Copper-8-quinolinolatea 0.34 9 -- -- -- -- 11 44 44 9 100 3.30.38 10 -- -- -- -- 30 30 40 10 100 3.80.50 10 -- -- -- -- 20 10 70 10 100 4.60.94 10 -- -- -- -- 30 20 50 10 100 6.21.16 7 -- -- -- -- 43 -- 5 7 100 8.01.30 9 -- -- -- -- 44 11 44 9 100 7.31.84 8 -- -- -- -- 25 -- 75 8 100 8.6

Untreated controls -- 8 -- -- -- -- 38 12 50 8 100 2.3

aWater-soluble form containing 1.07% copper metal (PQ-8).bTen stakes originally installed; eliminations were for mechanical damage or causes other than decay or insect attack.This study was initiated by L. R. Gjovik.

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Table 55--Condition of Southern Pine and Douglas-fir Comply stakes (2 by 4 in. nominal by 18 in.) treated with chromated copper arsenate and ammoniacal copper arsenate after about 20 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, November 1978 (Plot 78)

Condition of stakes February 1998 (%)Average Serviceable but retention showing some-- Decaybased on Num- Decay fungi

preservative ber and and Averageoxides in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine

Chromated copper arsentate type III 0.25 10 10 80 10 -- -- -- -- -- -- --0.40 10 70 30 -- -- -- -- -- -- -- --0.77 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 100 -- -- 10 100 2.5

Douglas-fir

Chromated copper arsentate type III 0.26 10 -- 90 -- -- 10 -- -- 1 10 --0.60 10 70 30 -- -- -- -- -- -- -- --

Ammoniacal copper arsenate 0.25 10 -- 30 -- 10 60 -- -- 6 60 --0.39 10 -- 100 -- -- -- -- -- -- -- --0.62 9 30 60 -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 70 -- 30 10 100 3.5

aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.

This study was initiated by L. R. Gjovik.

Destroyed by--

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Table 56--Condition of Southern Pine stakes (3/4 by 3/4 in. nominal by 18 in.) treated with butylene oxide after 10 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1979 (Plot 79)

Condition of stakes December 1989 (%)Serviceable but Destroyed by--

Average showing some-- Decayloading-- Num- Decay fungiWeight ber and and Averageadd-on in Termite termite Decay Termite termite Total removed life

Preservative (%) test Good Decay attack attack fungi attack attack Number % (year)

Butylene oxide 33.2 20 -- -- -- -- 100 -- -- 20 100 3.5

Untreated controls -- 10 -- -- -- -- 80 -- 20 10 100 1.9

Data presented in this table are part of a larger study under the guidance of R. M. Rowell.

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Table 57--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in. and 3/4 by 3/4 by 18 in.) treated with chromated copper arsenate type Cusing conventional full-cell (FC) process and Mississippi State University (MSU process--empty cell) after about 22 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, April 1980 (Plot 80)

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Chromated copper arsenate type C 2- by 4- by 18-in. stakes

Full cell 0.14 10 10 20 -- 70 -- -- -- -- -- --0.27 10 50 40 -- 10 -- -- -- -- -- --0.40 10 80 20 -- -- -- -- -- -- -- --0.62 10 100 -- -- -- -- -- -- -- -- --0.79 10 100 -- -- -- -- -- -- -- -- --

3/4- by 3/4- by 18-in. stakes

0.14 9 -- -- 10 40 20 20 -- 4 44 --0.27 10 10 30 -- 50 10 -- -- 1 10 --0.40 9 55 22 11 11 -- -- -- -- -- --0.61 10 70 10 10 10 -- -- -- -- -- --0.80 10 100 -- -- -- -- -- -- -- -- --

2- by 4- by 18-in. stakes

Empty cell 0.15b 10 10 10 -- 80 -- -- -- -- -- --0.26 10 10 80 -- 10 -- -- -- -- -- --0.33 10 80 20 -- -- -- -- -- -- -- --0.59 10 100 -- -- -- -- -- -- -- -- --0.78 10 90 10 -- -- -- -- -- -- -- --

3/4- by 3/4- by 18-in. stakes

0.14c 10 -- 10 -- -- 30 10 50 9 90 --0.27 10 -- -- -- 10 40 30 20 9 70 --0.40 10 -- 20 10 50 20 -- -- 2 20 --0.61 10 10 70 -- 10 10 -- -- 1 10 --0.80 9 55 33 -- -- -- -- 11 1 11 --

2- by 4- by 18-in. stakes

Untreated controls -- 10 -- -- -- -- 20 -- 80 10 100 2.3

3/4- by 3/4- by 18-in. stakes

-- 10 -- -- -- -- 50 -- 50 10 100 1.9aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.bThe retentions are based on chemical analysis after treatment.cThe retentions are estimates based on the full-cell treatments.

This study was initiated by L. R. Gjovik.

Condition of stakes January 2002 (%)

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diluted with mineral spirits and water-dispersible pentachlorophenol after 20 years of service. Stakes placed in

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termitetermite DecayTermitetermite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Water-dispersible 0.10 10 -- -- -- 10 -- -- 90 9 90 -- pentachlorophenol 0.18 9 -- -- -- -- 33 -- 67 9 100 11.9

0.35 10 -- -- -- 100 -- -- -- -- -- --0.37 10 -- -- -- 70 -- -- 30 3 30 --0.74b 10 -- 10 -- 90 -- -- -- -- -- --

Penta P9 in mineral 0.09 10 -- -- -- 10 -- 10 80 9 90 -- spirits 0.18 10 -- -- -- 80 -- -- 20 2 20 --

0.33 10 -- 20 -- 80 -- -- -- -- -- --0.78 10 20 40 10 30 -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 30 20 50 10 100 2.1

aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.

bConcentrate diluted in tap water. At all other retentions of water-dispersible pentachlorophenol, concentrate was diluted in a 50/50 dionized tap-water solution.

This study was initiated by L. R. Gjovik.

Condition of stakes June 2000 (%)

test on the Harrison Experimental Forest, Saucier, MS, June 1980 (Plot 81)

Table 58--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol in P9 oil

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chromated copper fluoride (CFK) after approximately 20 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, June 1980 (Plot 82)

Condition of stakes June 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretentiona in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testb Good Decay attack attack fungi attack attack Number % (year)

2- by 4- by 18-in. stakes

Chromated copper 0.28 10 10 -- -- 50 10 -- 30 4 40 -- fluoride (CFK) 0.58 9 -- 22 22 56 -- -- -- -- -- --

1.22 10 100 -- -- -- -- -- -- -- -- --1.57 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 10 -- 90 10 100 1.9

2.5- by 5.0- by 50-cm stakes

Chromated copper 0.30 10 -- -- -- 30 30 -- 40 7 70 -- fluoride (CFK) 0.62 10 20 30 -- 40 10 -- -- 1 10 --

1.26 10 90 10 -- -- -- -- -- -- --1.69 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- -- 20 80 10 100 1.6

aRetention based on preservative oxides.bTen stakes were originally installed at each test station; this number has since been reduced because of failure to locate the stakes at the time of inspection.

Table 59--Condition of Southern Pine stakes ( 2 by 4 in. nominal by 18 in. and 2.5 by 5.0 cm by 50 cm) treated with

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Table 60--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with water-dispersible pentachlorophenolafter 19 years of service. Stakes placed in test on the Harrison Experimental Forest,

Condition of stakes June 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Water-dispersible 0.10 10 -- -- -- -- 40 10 50 10 100 11.9 pentachlorophenol 0.18 10 -- -- -- 20 10 -- 70 8 80 --

0.43 10 -- -- -- 100 -- -- -- -- -- --0.84 10 10 10 -- 80 -- -- -- -- -- --1.75 10 70 30 -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 30 20 50 10 100 2.4

Saucier, MS, May 1981 (Plot 83)

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Serviceable but Destroyed by--showing some-- Decay

Active Num- Decay fungiAverage ingre- ber and and Averageretention dient in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Didecyl dimethyl ammonium 0.19 0.10 10 -- -- -- -- 20 -- 80 10 100 4.8chloride, 50.0% 0.41 0.21 10 -- -- -- -- -- 20 80 10 100 9.8

0.60 0.30 10 -- -- -- -- 30 -- 70 10 100 14.90.78 0.39 10 -- -- -- 50 -- -- 50 5 50 --

Coco dimethyl benzyl ammonium 0.45 0.06 10 -- -- -- -- 60 -- 40 10 100 4.3 chlorides, 9.8% + 3.8% 0.81 0.11 10 -- -- -- -- 100 -- -- 10 100 8.8copper as the metal 1.19 0.16 9 -- -- -- 11 77 -- 11 8 89 --

1.62 0.22 9 -- 11 -- 33 44 -- 11 4 44 --

Didecyl dimethyl ammonium chloride, 0.40 0.11 10 -- -- -- -- 60 -- 40 10 100 7.5 20%, + 6.3% copper as the metal 0.81 0.21 10 -- -- -- 40 50 -- 10 6 60 --

1.21 0.32 10 -- 10 -- 60 30 -- -- 3 30 --1.60 0.42 8 -- 25 -- 75 -- -- -- -- -- --

Dimethyl cocoamine 2-ethyl hexoate, 0.30 0.08 10 -- -- -- -- 30 10 60 10 100 3.220%; copper 2-ethyl hexoate, 21.0% 0.61 0.16 10 -- -- -- -- 100 -- -- 10 100 6.3(3.8% metallic copper) 0.90 0.24 10 -- -- -- -- 80 -- 20 10 100 10.1

1.20 0.32 10 -- -- -- 10 60 -- 30 9 90 --Copper 2-ethyl hexoate, 35.0% 0.40 0.17 10 -- -- -- -- 90 -- 10 10 100 5.5

(6.3 metallic copper) 0.80 0.33 10 -- -- -- 20 80 -- -- 8 80 --1.20 0.50 10 -- -- -- 10 80 -- 10 9 90 --1.61 0.66 10 -- -- -- 10 70 -- 10 8 80 --

Pentachlorophenol, 21.9%, and 0.82 0.20 10 -- -- -- 20 20 -- 60 8 80 --2.4% other chlorophenols 1.66 0.40 8 -- -- -- 87 -- -- 10 1 13 --

3.23 0.78 10 -- 50 -- 50 -- -- -- -- -- --4.12 1.00 10 -- 50 -- 50 -- -- -- -- -- --

Pentachlorophenol, 27.6%, and 0.65 0.20 10 -- -- -- -- 10 -- 90 10 100 --3.1% other chlorophenols 1.30 0.40 10 -- 20 -- 80 -- -- -- -- --

2.60 0.80 10 -- 20 -- 80 -- -- -- -- -- --3.27 1.00 10 -- 60 -- 40 -- -- -- -- -- --

Tri-n-butyl tin oxide, 9.5%, dimethyl 0.40 0.20 10 -- -- -- -- 20 10 70 10 100 4.8benzyl ammonium chloride, 20%, 0.81 0.40 10 -- -- -- -- 30 10 60 10 100 10.1and dimethyl ethyl benzyl ammonium 1.21 0.60 9 -- -- -- 33 22 -- 44 6 67 --chloride, 20% 1.63 0.81 9 -- 11 -- 78 11 -- -- 1 11 --

Diluted in toluene

Copper-8-quinolinolate, 0.675% 1.50 0.01 10 -- -- -- -- 20 10 70 10 100 5.9 (0.12% metallic copper) 2.96 0.02 10 -- -- -- -- 50 -- 50 10 100 12.1

8.75 0.06 10 -- 30 -- 70 -- -- -- -- -- --17.50 0.12 8 37 25 10 37 -- -- -- -- -- --

Pentachlorophenol, 6.3%, and 2.86 0.20 10 -- -- -- 60 10 -- 30 4 40 -- other chlorophenols, 0.7%, 5.73 0.40 10 -- 20 -- 80 -- -- -- -- -- -- in No. 2 diesel fuel 11.44 0.80 10 30 40 10 20 -- -- -- -- -- --

14.29 1.00 10 60 20 -- 20 -- -- -- -- -- --

Untreated controls -- -- 20 -- -- -- -- 25 -- 75 20 100 2.4 aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.This study was initiated by R.C. DeGroot.

Condition of stakes January 2002 (%)

Table 61--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with eight water-based formulations of wood preservatives and with Cu-8-quinolinolate and pentachlorophenol in toluene after about 21 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1981 (Plot 84)

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Table 62--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with ammoniacal copper zinc arsenate (ACZA) after 21 years of service. Stakes placed in test on the Harrison Experimental Forest,

Condition of stakes January 2002 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Ammoniacal copper 0.10 10 -- -- -- -- 80 -- 20 10 100 16.0 zinc arsenate 0.25 10 -- 100 -- -- -- -- -- -- -- --

0.40 10 20 60 10 -- -- -- 10 1 10 --0.60 10 90 10 -- -- -- -- -- -- -- --1.22 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- -- 10 90 10 100 2.0

This study was initiated by L. R. Gjovik.

Saucier, MS, December 1981 (Plot 85)

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Condition of stakes January 1996 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiPenta- ber and and Average

Solu- chloro- Creo- in Termitetermite Decay Termite termite Total removed lifePreservative tion phenol sote test Good Decay attack attack fungi attack attack Number % (year)Emulsified pentachlorophenol- creosote

Pentachlorophenol 17.90% 0.50 0.10 0.10 10 -- -- -- -- 30 -- 70 10 100 6.0

Other chlorophenols 2.10% 1.02 0.20 0.20 10 -- -- -- 50 10 -- 40 5 50 --P-1 creosote 20.0% 2.00 0.40 0.40 10 -- -- -- 100 -- -- -- -- -- --

2.98 0.60 0.60 10 -- -- -- 100 -- -- -- -- -- --4.00 0.80 0.80 10 10 10 -- 80 -- -- -- -- -- --

Pentachlorophenol 21.76% 0.40 0.10 0.04 10 -- -- -- -- -- -- 100 10 100 6.9Other chlorophenols 2.56% 0.84 0.21 0.08 10 -- -- -- 80 20 -- -- 2 20 --P-1 creosote 20.0% 1.65 0.41 0.16 10 -- -- -- 100 -- -- -- -- -- --

2.49 0.62 0.25 10 -- -- -- 100 -- -- -- -- -- --3.29 0.82 0.33 10 -- 10 -- 90 -- -- -- -- -- --

Untreated controls -- -- -- 10 -- -- -- -- 20 10 70 10 100 2.0

This study was initiated by by R.C. DeGroot.

Table 63--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with water-based emulsions of pentachlorophenol and creosote after 14-1/2 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1982 (Plot 86)

Average retention (lb/ft3)

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Table 64--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol emulsion and pentachlorophenol in P9 type A oil diluted with mineral spirits after 14-1/2 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1982 (Plot 87)

Condition of stakes January 1996 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Emulsified 0.10 10 -- -- -- -- -- 10 90 10 100 7.7 pentachlorophenol 0.20 10 -- -- -- 80 -- -- 20 2 20 --

0.40 10 -- -- -- 100 -- -- -- -- -- --0.60 10 -- -- -- 100 -- -- -- -- -- --0.80 10 -- -- -- 100 -- -- -- -- -- --

Pentachlorophenol 0.10 10 -- -- -- 70 10 -- 20 3 30 -- in P9 oil and 0.20 10 -- -- -- 100 -- -- -- -- -- -- mineral spirits

Untreated controls -- 10 -- -- -- -- 50 -- 50 10 100 1.6

This study was initiated by R. C. DeGroot.

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Table 65--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol, tetrachlorophenol, and tetrachlorophenol plus copper oxide in water and ammonia after 14-1/2 years of service.Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1982 (Plot 88)

Condition of stakes January 1996 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Pentachlorophenol in 0.13 10 -- -- -- -- -- 20 80 10 100 4.2 water and ammonia 0.26 10 -- -- -- -- 60 10 30 10 100 7.6

0.40 10 -- -- -- -- 50 -- 50 10 100 9.70.62 10 -- -- -- 90 10 -- -- 1 10 --1.03 10 -- -- -- 100 -- -- -- -- -- --1.49 10 -- 20 -- 80 -- -- -- -- -- --

Tetrachlorophenol and 0.12 10 -- -- -- -- 40 -- 60 10 100 5.7 copper oxide in water 0.25 10 -- -- -- -- 90 -- 10 10 100 9.6 and ammonia 0.41 10 -- 10 -- 50 20 -- -- 2 20 --

0.62 10 40 20 30 10 -- -- -- -- -- --0.98 10 80 -- -- 20 -- -- -- -- -- --

Tetrachlorophenol 0.25 10 -- -- -- -- 20 -- 80 10 100 6.90.40 10 -- -- -- 10 20 -- 70 9 90 --0.60 10 -- -- -- 30 10 -- 60 7 70 --1.02 10 -- -- -- 100 -- -- -- -- -- --1.52 10 -- -- -- 100 -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 50 10 40 10 100 2.3

This study was initiated by L. R. Gjovik.

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Table 66--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with 2% sulfur in creosote after

Condition of stakes January 1996 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Coal-tar creosote with 2.01 10 -- -- -- -- 40 -- 60 10 100 9.5 5% sulfur in toluene 3.19 8 -- -- -- 100 -- -- -- -- -- --

4.43 10 -- -- -- 100 -- -- -- -- -- --6.28 9 -- -- 33 67 -- -- -- -- -- --9.20 10 40 10 -- 50 -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 10 10 80 10 100 2.8

This study was initiated by L.R. Gjovik.

14-1/2 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1982 (Plot 89)

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Table 67--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with phenol-formaldehyde resin after about 17 years of service. Stakes placed in test on the Harrison Experimental Forest,

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Phenol-formaldehyde 1.00 10 -- -- -- -- 10 -- 90 10 100 3.2 resin 1.90 10 -- -- -- -- 50 -- 50 10 100 3.2

3.01 10 -- -- -- -- 10 -- 90 10 100 5.06.15 10 -- -- -- 10 40 10 40 9 90 --

10.22 9 -- -- -- 22 56 -- 22 7 78 --

Phenol-formaldehyde resin 0.08 10 -- -- -- -- 40 -- 60 10 100 2.5 and pentachlorophenol 0.14 10 -- -- -- -- 50 10 40 10 100 3.7

0.30 10 -- -- -- -- 20 -- 80 10 100 4.80.49 10 -- -- -- -- 10 10 80 10 100 7.40.79 10 -- -- -- 10 20 -- 60 8 80 --

Untreated controls -- 10 -- -- -- -- 10 20 70 10 100 3.4

aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.

This study was initiated by L. R. Gjovik.

Condition of stakes January 1999 (%)

Saucier, MS, December 1982 (Plot 90)

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pentachlorophenol-creosote emulsion, ammonium pentachlorophenol, and pentachlorophenol in P9 oil after 12 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1983 (Plots 92 and 93)

Condition of stakes August 1995 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

2- by 4- by 18-in. stakes

Pentachlorophenol 0.14 10 -- -- -- -- 40 -- 60 10 100 7.0 emulsion 0.20 10 -- -- -- 100 -- -- -- -- -- --

0.28 10 -- -- -- 100 -- -- -- -- -- --0.40 10 -- -- -- 100 -- -- -- -- -- --0.56 10 10 -- -- 90 -- -- -- -- -- --0.81 10 10 10 -- 80 -- -- -- -- -- --

Pentachlorophenol-creosote 0.14 10 -- -- -- -- 50 -- 50 10 100 6.5 emulsion diluted with 0.20 10 -- -- -- 10 10 -- 80 9 90 -- 3% ammonia 0.28 10 -- -- -- 70 -- -- 30 3 30 --

0.40 10 -- -- -- 100 -- -- -- -- -- --0.55 10 -- -- -- 100 -- -- -- -- -- --0.85 10 -- -- -- 100 -- -- -- -- -- --

Ammonium 0.16 10 -- -- -- -- 40 -- 60 10 100 6.6 pentachlorophenol 0.20 10 -- -- -- -- 30 -- 70 10 100 6.1

0.27 10 -- -- -- 10 30 -- 60 9 90 --0.38 10 -- -- -- 90 -- -- 10 1 10 --0.55 10 -- -- -- 100 -- -- -- -- -- --0.77 10 -- -- -- 100 -- -- -- -- -- --

Pentachlorophenol in P9 0.14 10 -- -- -- 100 -- -- -- -- -- -- oil and toluene 0.20 10 -- -- -- 100 -- -- -- -- -- --

0.28 10 -- -- -- 100 -- -- -- -- -- --0.40 10 30 10 10 50 -- -- -- -- -- --0.56 10 60 10 10 20 -- -- -- -- -- --0.80 10 90 10 -- -- -- -- -- -- -- --

Toluene only 30.70 10 -- -- -- -- 10 10 80 10 100 2.7

Mineral spirits only 26.00 10 -- -- -- -- 10 20 70 10 100 3.3

Untreated controls -- 10 -- -- -- -- -- 10 90 10 100 1.7

(Page 1 of 2)

Table 68--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol emulsion,

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Condition of stakes August 1995 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

3/4- by 3/4- by 18-in. stakes

Pentachlorophenol 0.14 25 -- -- -- -- 24 -- 76 25 100 3.4 emulsion 0.21 25 -- -- -- 4 52 -- 44 24 96 --

0.28 25 -- -- -- -- 40 4 56 25 100 6.60.40 25 -- -- -- 28 16 4 52 18 72 --0.56 24 -- -- -- 72 8 -- 16 6 25 --0.81 25 -- -- -- 92 8 -- -- 2 8 --

Pentachlorophenol-creosote 0.14 25 -- -- -- -- 24 -- 76 25 100 2.7 emulsion diluted with 0.21 25 -- -- -- -- 36 -- 64 25 100 3.5 3% ammonia 0.30 25 -- -- -- -- 40 4 56 25 100 5.1

0.46 25 -- -- -- 4 32 -- 64 24 96 --0.58 24 -- -- -- 47 33 -- 21 13 54 --0.87 23 -- -- -- 96 -- 4 -- 1 4 --

Ammonium 0.16 24 -- -- -- -- 4 8 88 24 100 2.7 pentachlorophenol 0.22 24 -- -- -- -- 21 4 75 24 100 3.5

0.28 25 -- -- -- -- 48 4 48 25 100 4.30.42 25 -- -- -- 4 32 8 56 24 96 --0.63 25 -- -- -- 40 28 -- 32 15 60 --0.89 23 -- -- 4 83 4 -- 9 3 13 --

Pentachlorophenol in P9 0.16 24 -- -- -- 8 32 -- 60 22 92 -- oil and toluene 0.20 25 -- -- -- 36 20 8 36 16 64 --

0.27 25 -- -- -- 84 4 -- 12 4 16 --0.40 24 -- -- 4 88 8 -- -- 2 8 --0.56 25 20 4 8 60 8 -- -- 2 8 --0.80 25 40 20 40 -- -- -- -- -- -- --

Untreated controls -- 25 -- -- -- -- 32 8 60 25 100 1.1

This study was initiated by by R.C. DeGroot.(Page 2 of 2)

service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1983 (Plots 92 and 93)--concluded

Table 68--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol emulsion, pentachlorophenol-creosote emulsion, ammonium pentachlorophenol, and pentachlorophenol in P9 oil after 12 years of

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Table 69--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol in P9 oil and toluene,tetrachlorophenol in P9 oil and toluene, and P9 oil and toluene after about 16 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1984 (Plot 94)

Condition of stakes June 2000 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Pentachlorophenol in P9 oil 0.10 10 -- 20 -- 10 30 -- 40 7 70 -- and toluene 0.24 10 -- 30 -- 60 -- -- -- -- -- --

0.40 10 40 60 -- -- -- -- -- -- -- --0.60 10 100 -- -- -- -- -- -- -- -- --1.24 10 100 -- -- -- -- -- -- -- -- --

Tetrachlorophenol and P9 oil 0.10 10 -- -- -- 10 30 -- 60 9 90 -- and toluene 0.25 10 -- 40 -- 50 10 -- -- 1 10 --

0.40 10 -- 40 -- 60 -- -- -- -- -- --0.60 10 70 30 -- -- -- -- -- -- -- --1.25 10 100 -- -- -- -- -- -- -- -- --

P9 oil and toluene 1.34 10 -- -- -- -- 20 -- 80 10 100 8.43.50 10 -- 20 -- 30 30 -- 20 5 50 --5.83 10 -- 20 -- 50 30 -- -- 3 30 --8.70 10 50 30 10 10 -- -- -- -- -- --

18.03 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 10 40 50 10 100 1.6

This study was initiated by L. R. Gjovik.

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Table 70--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with creosote coal-tar, coal-tarcreosote and 2% sulfur, coal-tar creosote and phentachlorophenol with inhibitor, after about 18 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1984 (Plot 95)

Condition of stakes January 2002 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Creosote coal-tar 1.69 10 -- -- -- 10 50 -- 40 9 90 --3.31 8 -- -- -- 13 87 -- -- 7 87 --4.93 9 -- -- -- 33 67 -- -- 6 67 --6.59 10 -- 20 -- 60 20 -- -- 2 20 --

Coal-tar creosote 2.23 10 -- -- -- 10 70 -- 20 9 90 -- plus 2% sulfur 3.48 10 -- -- -- 70 -- 30 10 100 13.6

4.93 9 -- -- -- 11 89 -- -- 8 89 --6.58 10 -- -- -- 10 80 -- 10 9 90 --

Coal-tar creosote 2.11 9 -- -- -- 44 -- 56 9 100 13.1 and pentachlorophenol 3.57 9 -- -- -- 44 56 -- -- 5 56 -- with inhibitor 4.70 10 -- 10 -- 80 10 -- -- 1 10 --

6.83 10 -- 10 -- 70 20 -- -- 2 20 --

Untreated controls -- 10 -- -- -- -- 10 -- 90 10 100 1.9

aTen stakes originally installed; this number has since been reduced because of failure to locate the stakes

This study was initiated by L.R. Gjovik.

at the time of inspection.

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Condition of stakes January 1996 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)Penta amine 0.14 10 -- -- -- -- 40 -- 60 10 100 2.3 in water 0.21 10 -- -- -- -- -- -- 100 10 100 3.4

0.28 10 -- -- -- -- 20 -- 80 10 100 4.20.39 10 -- -- -- 10 50 -- 40 9 90 --0.57 9 -- -- -- -- 33 -- 67 9 100 5.40.80 10 -- -- -- -- 50 10 40 10 100 7.0

Pentachlorophenol 0.14 10 -- -- -- -- 50 -- 50 10 100 7.4 in P9 oil and toluene 0.21 10 -- -- -- 30 10 10 50 7 70 --

0.28 10 -- -- -- 70 10 -- 20 3 30 --0.44 10 -- -- -- 90 10 -- -- 1 10 --0.55 10 -- 10 50 40 -- -- -- -- -- --0.80 10 30 10 -- 50 10 -- -- 1 10 --

Untreated controls -- 10 -- -- -- -- 50 20 30 10 100 1.1

Table 71--Condition of Southern Pine stakes (3/4 by 3/4 by 18 in.) treated with penta amine in water and pentachlorophenol in P9 oil and toluene after approximately 12 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, December 1984 (Plot 96)

This study was initiated by R.C. DeGroot.

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by 18 in.) incised and unincised, treated with ammoniacal copper arsenate and chromated copper arsenate III after 10 and 17 years.Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1985 and near Portland, ME, August 1985 (Plot 97)

Condition of stakes September 1995 (ME) and January 2002 (MS) (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

Loca- retention in Termite termite Decay Termite termite Total removed lifePreservative tion (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

White pine--unincised

Ammoniacal copper arsenate ME 0.32 10 90 10 -- -- -- -- -- -- -- --MS 0.26 10 -- 40 -- 10 40 -- 10 5 50 --ME 0.38 10 90 10 -- -- -- -- -- -- -- --MS 0.42 9 33 56 -- 11 -- -- -- -- -- --ME 0.71 10 100 -- -- -- -- -- -- -- -- --MS 0.72 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.30 10 100 -- -- -- -- -- -- -- -- --MS 0.31 10 100 -- -- -- -- -- -- -- -- --ME 0.46 10 100 -- -- -- -- -- -- -- -- --MS 0.44 10 90 10 -- -- -- -- -- -- -- --ME 0.66 10 100 -- -- -- -- -- -- -- -- --MS 0.65 10 100 -- -- -- -- -- -- -- -- --

White pine--incised

Ammoniacal copper arsenate ME 0.32 10 90 10 -- -- -- -- -- -- -- --MS 0.26 10 70 20 -- -- 10 -- -- 1 10 --ME 0.44 10 100 -- -- -- -- -- -- -- -- --MS 0.42 10 80 10 -- -- 10 -- -- 1 10 --ME 0.80 10 100 -- -- -- -- -- -- -- -- --MS 0.73 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.32 10 100 -- -- -- -- -- -- -- -- --MS 0.33 10 100 -- -- -- -- -- -- -- -- --ME 0.47 10 100 -- -- -- -- -- -- -- -- --MS 0.52 10 100 -- -- -- -- -- -- -- -- --ME 0.72 10 100 -- -- -- -- -- -- -- -- --MS 0.74 10 100 -- -- -- -- -- -- -- -- --

Untreated controls ME -- 10 10 50 -- -- 40 -- -- 4 40 --MS -- 10 -- -- -- -- 60 -- 40 10 100 2.4

Red pine--unincised

Ammoniacal copper arsenate ME 0.29 10 60 40 -- -- -- -- -- -- -- --MS 0.29 10 -- 30 -- 10 40 -- 20 6 60 --ME 0.38 10 100 -- -- -- -- -- -- -- -- --MS 0.30 10 40 50 -- -- 10 -- -- 1 10 --ME 0.67 10 100 -- -- -- -- -- -- -- -- --MS 0.44 10 90 10 -- -- -- -- -- -- -- --

Table 72--Condition of balsam fir, eastern hemlock, eastern larch, eastern spruce, red pine and white pine stakes (2 by 4 in. nominal

(Page 1 of 5)

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Condition of stakes September 1995 (ME) and January 2002 (MS) (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

Loca- retention in Termite termite Decay Termite termite Total removed lifePreservative tion (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Red pine--unincised--con.

Chromated copper arsenate III ME 0.18 10 90 10 -- -- -- -- -- -- -- --MS 0.23 10 60 30 10 -- -- -- -- -- -- --ME 0.33 10 100 -- -- -- -- -- -- -- -- --MS 0.32 9 78 11 11 -- -- -- -- -- -- --ME 0.70 10 100 -- -- -- -- -- -- -- -- --MS 0.46 10 90 -- -- 10 -- -- -- -- -- --

Red pine--incised

Ammoniacal copper arsenate ME 0.26 10 70 30 -- -- -- -- -- -- -- --MS 0.31 10 30 50 -- -- 20 -- -- 2 20 --ME 0.45 10 100 -- -- -- -- -- -- -- -- --MS 0.40 10 90 -- -- 10 -- -- -- -- -- --ME 0.53 10 100 -- -- -- -- -- -- -- -- --MS 0.64 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.23 10 100 -- -- -- -- -- -- -- -- --MS 0.25 10 100 -- -- -- -- -- -- -- -- --ME 0.45 10 100 -- -- -- -- -- -- -- -- --MS 0.40 10 100 -- -- -- -- -- -- -- -- --ME 0.78 10 100 -- -- -- -- -- -- -- -- --MS 0.55 10 100 -- -- -- -- -- -- -- -- --

Untreated controls ME -- 10 -- 80 -- -- 20 -- -- 2 20 --MS -- 10 -- -- -- -- 70 -- 30 10 100 3.7

Eastern spruce--unincised--con.

Ammoniacal copper arsenate ME 0.13 10 30 70 -- -- -- -- -- -- -- --MS 0.16 10 -- -- -- 10 30 -- 60 9 90 --ME 0.21 10 20 80 -- -- -- -- -- -- -- --MS 0.25 10 -- 10 -- -- 40 20 30 9 90 --ME 0.26 10 50 50 -- -- -- -- -- -- -- --MS 0.39 10 70 30 -- -- -- -- -- -- -- --

by 18 in.) incised and unincised, treated with ammoniacal copper arsenate and chromated copper arsenate III after 10 and 17 years.Table 72--Condition of balsam fir, eastern hemlock, eastern larch, eastern spruce, red pine and white pine stakes (2 by 4 in. nominal

(Page 2 of 5)

Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1985 and near Portland, ME, August 1985 (Plot 97)--continued

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Table 72--Condition of balsam fir, eastern hemlock, eastern larch, eastern spruce, red pine and white pine stakes (2 by 4 in. nominal by 18 in.) incised and unincised, treated with ammoniacal copper arsenate and chromated copper arsenate III after 10 and 17 years.

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

Loca- retention in Termite termite Decay Termite termite Total removed lifePreservative tion (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Eastern spruce--unincised--con.

Chromated copper arsenate III ME 0.10 10 80 20 -- -- -- -- -- -- -- --MS 0.14 10 -- 10 -- 60 20 -- 10 3 30 --ME 0.13 10 90 10 -- -- -- -- -- -- -- --MS 0.20 10 70 10 10 -- 10 -- -- 1 10 --ME 0.53 10 100 -- -- -- -- -- -- -- -- --MS 0.71 10 100 -- -- -- -- -- -- -- -- --

Eastern spruce--incised

Ammoniacal copper arsenate ME 0.20 10 20 80 -- -- -- -- -- -- -- --MS 0.24 10 10 70 -- 10 10 -- -- 1 10 --ME 0.28 10 70 30 -- -- -- -- -- -- -- --MS 0.28 10 50 20 -- 10 20 -- -- 2 20 --ME 0.39 10 80 20 -- -- -- -- -- -- -- --MS 0.48 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.20 10 100 -- -- -- -- -- -- -- -- --MS 0.25 10 100 -- -- -- -- -- -- -- -- --ME 0.28 10 100 -- -- -- -- -- -- -- -- --MS 0.35 10 100 -- -- -- -- -- -- -- -- --ME 0.54 10 100 -- -- -- -- -- -- -- -- --MS 0.78 10 100 -- -- -- -- -- -- -- -- --

Untreated controls ME -- 10 -- 40 -- -- 60 -- -- 6 60 --MS -- 10 -- -- -- -- 40 30 30 10 100 2.2

Balsam fir--unincised

Ammoniacal copper arsenate ME 0.20 10 50 50 -- -- -- -- -- -- -- --MS 0.26 10 -- 30 -- -- 30 -- 40 7 70 --ME 0.25 10 70 30 -- -- -- -- -- -- -- --MS 0.32 10 30 50 10 10 -- -- -- -- -- --ME 0.42 10 100 -- -- -- -- -- -- -- -- --MS 0.59 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.19 10 100 -- -- -- -- -- -- -- -- --ME 0.40 10 100 -- -- -- -- -- -- -- -- --ME 0.59 10 100 -- -- -- -- -- -- -- -- --

Condition of stakes September 1995 (ME) and January 2002 (MS) (%)

(Page 3 of 5)

Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1985 and near Portland, ME, August 1985 (Plot 97)--continued

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Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

Loca- retention in Termite termite Decay Termite termite Total removed lifePreservative tion (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Balsam fir--incised

Ammoniacal copper arsenate ME 0.31 10 80 20 -- -- -- -- -- -- -- --MS 0.29 10 60 30 -- -- 10 -- -- 1 10 --ME 0.35 10 100 -- -- -- -- -- -- -- -- --MS 0.40 10 100 -- -- -- -- -- -- -- -- --ME 0.47 10 100 -- -- -- -- -- -- -- -- --MS 0.73 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.29 10 100 -- -- -- -- -- -- -- -- --ME 0.53 10 100 -- -- -- -- -- -- -- -- --ME 0.73 10 100 -- -- -- -- -- -- -- -- --

Untreated controls ME -- 10 -- 60 -- -- 40 -- -- 4 40 --MS -- 10 -- -- -- -- 50 -- 50 10 100 3.8

Eastern hemlock--unincised

Ammoniacal copper arsenate ME 0.22 10 90 10 -- -- -- -- -- -- -- --MS 0.20 10 50 40 -- 10 -- -- -- -- -- --ME 0.38 10 80 20 -- -- -- -- -- -- -- --MS 0.32 10 10 60 -- -- 30 -- -- 3 30 --ME 0.36 10 100 -- -- -- -- -- -- -- -- --MS 0.37 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.20 10 100 -- -- -- -- -- -- -- -- --ME 0.30 10 100 -- -- -- -- -- -- -- -- --ME 0.41 10 100 -- -- -- -- -- -- -- -- --

Eastern hemlock--incised

Ammoniacal copper arsenate ME 0.28 10 90 10 -- -- -- -- -- -- -- --MS 0.34 10 60 30 -- -- 10 -- -- 1 10 --ME 0.41 10 100 -- -- -- -- -- -- -- -- --MS 0.38 10 100 -- -- -- -- -- -- -- -- --ME 0.56 10 100 -- -- -- -- -- -- -- -- --MS 0.68 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.25 10 100 -- -- -- -- -- -- -- -- --ME 0.38 10 100 -- -- -- -- -- -- -- -- --ME 0.57 10 100 -- -- -- -- -- -- -- -- --

Condition of stakes September 1995 (ME) and January 2002 (MS) (%)

by 18 in.) incised and unincised, treated with ammoniacal copper arsenate and chromated copper arsenate III after 10 and 17 years.Table 72--Condition of balsam fir, eastern hemlock, eastern larch, eastern spruce, red pine and white pine stakes (2 by 4 in. nominal

(Page 4 of 5)

Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1985 and near Portland, ME, August 1985 (Plot 97)--continued

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Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Average

Loca- retention in Termite termite Decay Termite termite Total removed lifePreservative tion (lb/ft3) test Good Decay attack attack fungi attack attack Number % (year)

Eastern hemlock--incised--con.

Untreated controls ME -- 10 10 40 -- -- 50 -- -- 5 50 --MS -- 10 -- -- -- -- 50 -- 50 10 100 3.7

Eastern larch--unincised

Ammoniacal copper arsenate ME 0.15 10 50 50 -- -- -- -- -- -- -- --MS 0.18 10 -- 10 -- 50 20 -- 20 4 40 --ME 0.23 10 100 -- -- -- -- -- -- -- -- --MS 0.20 10 30 20 -- 30 10 -- 10 2 20 --ME 0.24 10 100 -- -- -- -- -- -- -- -- --MS 0.41 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.10 10 100 -- -- -- -- -- -- -- -- --ME 0.18 10 100 -- -- -- -- -- -- -- -- --ME 0.33 10 100 -- -- -- -- -- -- -- -- --

Eastern larch--incised

Ammoniacal copper arsenate ME 0.16 10 90 10 -- -- -- -- -- -- -- --MS 0.25 10 20 40 -- 30 -- -- 10 1 10 --ME 0.25 10 90 10 -- -- -- -- -- -- -- --MS 0.32 10 80 20 -- -- -- -- -- -- -- --ME 0.32 10 100 -- -- -- -- -- -- -- -- --MS 0.60 10 100 -- -- -- -- -- -- -- -- --

Chromated copper arsenate III ME 0.14 10 100 -- -- -- -- -- -- -- -- --ME 0.28 10 100 -- -- -- -- -- -- -- -- --ME 0.49 10 100 -- -- -- -- -- -- -- -- --

Untreated controls ME -- 10 10 70 -- -- 20 -- -- 2 20 --MS -- 10 -- -- -- -- 30 -- 70 10 100 3.9

aTen stakes originally installed; eliminations were for causes other than decay or insect attack.

This study was initiated by L.R. Gjovik.

Condition of stakes September 1995 (ME) and January 2002 (MS) (%)

by 18 in.) incised and unincised, treated with ammoniacal copper arsenate and chromated copper arsenate III after 10 and 17 years.

(Page 5 of 5)

Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, May 1985 and near Portland, ME, August 1985 (Plot 97)--concluded

Table 72--Condition of balsam fir, eastern hemlock, eastern larch, eastern spruce, red pine and white pine stakes (2 by 4 in. nominal

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Condition of stakes January 1999 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termitetermite DecayTermite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine--Southern Pine--Southern PineCut from 4 by 4 treated panel

Ammoniacal copper 0.09 10 -- -- -- -- 90 -- 10 10 100 5.3 arsenate 0.20 9 11 11 -- 22 44 -- 11 5 56 --

0.40 10 -- 40 30 -- -- 30 -- 3 30 --0.58 10 -- 40 -- -- -- 60 -- 6 60 --1.18 10 -- 20 -- -- -- 80 -- 8 80 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.09 10 -- 20 -- 10 70 -- -- 7 70 --0.20 10 50 10 -- 20 -- 20 -- 2 20 --0.41 10 30 -- -- -- -- 70 -- 7 70 --0.58 10 20 -- -- -- -- 80 -- 8 80 --1.24 10 -- -- -- -- -- 100 -- 10 100 13.2

Treated as stakes

0.33 10 40 -- -- -- -- 60 -- 6 60 --0.52 10 10 -- -- -- -- 90 -- 9 90 --

Cut from 4 by 4 treated panel

Chromated copper 0.09 10 -- -- -- -- 10 -- 90 10 100 5.8 arsenate III 0.19 10 10 40 10 20 -- 20 -- 2 20 --

0.40 10 10 -- -- -- -- 90 -- 9 90 --0.59 10 30 -- -- -- -- 70 -- 7 70 --1.18 10 20 -- -- -- -- 80 -- 8 80 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 10 20 -- 20 10 -- 40 5 50 --0.19 10 40 10 10 10 10 10 10 3 30 --0.40 10 30 -- -- -- -- 70 -- 7 70 --0.59 10 40 -- -- -- -- 60 -- 6 60 --1.18 10 20 -- -- -- -- 80 -- 8 80 --

Treated as stakes

0.41 10 40 -- -- -- -- 60 -- 6 60 --0.59 10 -- -- -- -- -- 100 -- 10 100 13.2

Untreated controls -- 10 -- -- -- -- 50 -- 50 10 100 1.7(Page 1 of 5)

Table 73--Condition of three-ply plywood, layed up in combinations of Southern Pine, sweetgum, and yellow poplar,treated with ammoniacal copper arsenate and chromated copper arsenate after about 16-1/2 years. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, November 1985 (Plot 98)

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Condition of stakes January 1999 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termitetermite DecayTermite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine--Southern Pine--SweetgumCut from 4 by 4 treated panel

Ammoniacal copper 0.10 10 -- -- -- -- 80 -- 20 10 100 4.4 arsenate 0.20 10 -- -- -- 20 70 10 -- 8 80 --

0.40 10 40 -- -- -- -- 60 -- 6 60 --0.61 10 30 10 -- -- -- 60 -- 6 60 --1.25 10 20 -- -- -- -- 80 -- 8 80 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 10 -- -- -- 80 -- 10 9 90 --0.20 10 -- 20 -- 40 20 20 -- 4 40 --0.41 9 44 -- -- -- -- 56 -- 5 56 --0.61 10 30 -- -- -- -- 70 -- 7 70 --1.25 10 10 -- -- -- -- 90 -- 9 90 --

Treated as stakes

0.42 10 30 -- -- -- -- 70 -- 7 70 --0.62 10 30 -- -- -- -- 70 -- 7 70 --

Cut from 4 by 4 treated panel

Chromated copper 0.10 10 -- -- -- -- 60 -- 40 10 100 6.1 arsenate III 0.20 10 -- 20 -- 50 20 -- 10 3 30 --

0.41 10 70 -- -- -- -- 30 -- 3 30 --0.61 10 30 -- -- -- -- 70 -- 7 70 --1.22 10 -- -- -- -- -- 100 -- 10 100 13.2

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 9 -- -- -- 11 44 -- 44 8 89 --0.20 10 20 30 -- 20 -- 20 10 3 30 --0.40 10 10 10 -- -- -- 80 -- 8 80 --0.61 10 30 -- -- -- -- 70 -- 7 70 --1.22 10 10 -- -- -- -- 90 -- 9 90 --

Treated as stakes

0.41 10 40 10 -- -- -- 50 -- 5 50 --0.58 10 20 -- -- -- 10 70 -- 8 80 --

Untreated controls -- 10 -- -- -- -- 30 -- 70 10 100 1.4

Table 73--Condition of three-ply plywood, layed up in combinations of Southern Pine, sweetgum, and yellow poplar,

(Page 2 of 5)

treated with ammoniacal copper arsenate and chromated copper arsenate after about 16-1/2 years. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, November 1985 (Plot 98)--continued

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Condition of stakes January 1999 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Total removed Averageretention in Termitetermite DecayTermite termite life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine--Sweetgum--Southern PineCut from 4 by 4 treated panel

Ammoniacal copper 0.10 10 -- -- -- -- 100 -- -- 10 100 5.0 arsenate 0.19 10 -- 10 -- 10 50 -- 30 8 80 --

0.40 10 40 10 -- -- 10 30 10 5 50 --0.61 10 10 -- -- -- -- 90 -- 9 90 --1.24 10 -- -- -- -- -- 100 -- 10 100 13.2

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 -- -- -- -- 100 -- -- 10 100 7.90.19 10 -- 20 40 30 10 -- 4 40 --0.40 10 30 30 -- -- 10 30 -- 4 40 --0.62 10 20 -- -- -- -- 80 -- 8 80 --1.24 10 20 -- -- -- -- 80 -- 8 80 --

Treated as stakes

0.39 10 60 -- -- -- -- 40 -- 4 40 --0.61 10 40 -- -- -- -- 60 -- 6 60 --

Cut from 4 by 4 treated panel

Chromated copper 0.10 10 -- -- -- -- 40 -- 60 10 100 6.2 arsenate III 0.19 10 30 -- 10 30 20 10 -- 3 30 --

0.40 10 30 10 10 -- -- 50 -- 5 50 --0.63 10 -- -- -- -- -- 100 -- 10 100 13.21.22 10 10 -- -- -- -- 90 -- 9 90 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 -- -- -- -- 20 20 60 10 100 5.80.19 10 30 -- -- 20 30 20 -- 5 50 --0.40 10 70 -- -- -- -- 30 -- 3 30 --0.62 10 10 -- -- -- -- 90 -- 9 90 --1.20 10 10 -- 10 -- -- 80 -- 8 80 --

Treated as stakes0.41 10 30 -- -- -- -- 70 -- 7 70 --0.59 10 20 -- -- -- -- 80 -- 8 80 --

Untreated controls -- 10 -- -- -- -- 50 -- 50 10 100 1.2(Page 3 of 5)

Table 73--Condition of three-ply plywood, layed up in combinations of Southern Pine, sweetgum, and yellow poplar,treated with ammoniacal copper arsenate and chromated copper arsenate after about 16-1/2 years. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, November 1985 (Plot 98)--continued

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Condition of stakes January 1999 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termitetermite DecayTermite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine--Southern Pine-Yellow PoplarCut from 4 by 4 treated panel

Ammoniacal copper 0.10 10 -- -- -- -- 60 -- 40 10 100 5.4 arsenate 0.20 10 -- 50 -- 20 10 20 -- 3 30 --

0.40 10 10 20 -- 10 -- 50 10 6 60 --0.62 10 30 -- -- 10 -- 60 -- 6 60 --1.27 10 10 -- -- -- -- 90 -- 9 90 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 -- -- -- 20 70 -- 10 8 80 --0.20 10 10 40 -- 10 20 20 -- 4 40 --0.40 10 30 20 -- -- -- 50 -- 5 50 --0.62 10 30 -- -- -- -- 70 -- 7 70 --1.27 10 20 -- -- -- -- 80 -- 8 80 --

Treated as stakes

0.40 10 40 10 -- 10 -- 40 -- 4 40 --0.64 10 30 -- -- -- -- 70 -- 7 70 --

Cut from 4 by 4 treated panel

Chromated copper 0.10 8 -- -- -- -- 25 -- 75 8 100 7.2 arsenate III 0.20 10 -- 50 10 30 10 -- -- 1 10 --

0.40 10 30 -- -- -- -- 70 -- 7 70 --0.62 10 20 -- -- -- -- 80 -- 8 80 --1.23 10 20 -- -- -- -- 80 -- 8 80 --

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 9 -- -- -- -- 56 44 5 9 100 8.10.20 10 10 -- 10 60 10 10 -- 2 20 --0.40 10 30 20 -- -- -- 50 -- 5 50 --0.62 10 20 -- -- -- -- 80 -- 8 80 --1.23 10 -- -- -- -- -- 100 -- 10 100 13.2

Treated as stakes

0.43 10 60 -- -- -- -- 40 -- 4 40 --0.63 10 -- -- -- -- -- 100 -- 10 100 13.2

Untreated controls -- 10 -- -- -- -- 70 -- 30 10 100 1.1(Page 4 of 5)

Table 73--Condition of three-ply plywood, layed up in combinations of Southern Pine, sweetgum, and yellow poplar,treated with ammoniacal copper arsenate and chromated copper arsenate after about 16-1/2 years. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, November 1985 (Plot 98)--continued

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Condition of stakes January 1999 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termitetermite DecayTermite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Southern Pine--Yellow Poplar--Southern PineCut from 4 by 4 treated panel

Ammoniacal copper 0.10 10 -- -- -- -- 90 -- 10 10 100 4.2 arsenate 0.20 10 -- -- -- 60 40 -- -- 4 40 --

0.41 10 40 -- -- -- -- 50 10 6 60 --0.62 10 30 20 -- -- -- 50 -- 5 50 --1.25 10 -- -- -- -- -- 100 -- 10 100 13.2

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 10 -- -- -- -- 60 -- 40 10 100 8.00.20 10 10 30 -- -- 30 10 20 6 60 --0.41 10 30 -- -- -- -- 70 -- 7 70 --0.62 10 -- -- -- -- -- 100 -- 10 100 13.21.24 10 -- -- -- -- -- 100 -- 10 100 13.2

Treated as stakes

0.38 10 40 -- -- -- -- 50 10 6 60 --0.59 10 20 -- -- -- -- 80 -- 8 80 --

Cut from 4 by 4 treated panel

Chromated copper 0.10 9 -- -- -- -- 22 -- 78 9 100 6.2 arsenate III 0.20 10 10 -- -- 50 30 10 -- 4 40 --

0.41 10 30 -- 20 -- -- 50 -- 5 50 --0.62 10 10 -- -- -- -- 90 -- 9 90 --1.20 10 -- -- -- -- -- 100 -- 10 100 13.2

Cut from 4 by 4 treated panels, cut edge dip treated

0.10 9 -- -- -- -- 44 -- 56 9 100 6.90.20 10 50 -- 10 20 20 -- -- 2 20 --0.41 10 40 -- -- -- -- 60 -- 6 60 --0.62 10 10 -- -- -- -- 90 -- 9 90 --1.21 10 10 -- -- -- -- 90 -- 9 90 --

Treated as stakes

0.45 10 40 -- -- -- -- 60 -- 6 60 --0.63 10 20 -- -- -- -- 80 -- 8 80 --

Untreated controls -- 10 -- -- -- -- 50 -- 50 10 100 1.4

aTen stakes were originally installed. This number has been reduced for causes other than decay or insect attack.

This study was initiated by R.C. DeGroot and L.R. Gjovik.(Page 5 of 5)

treated with ammoniacal copper arsenate and chromated copper arsenate after about 16-1/2 years. Stakes placedin test on the Harrison Experimental Forest, Saucier, MS, November 1985 (Plot 98)--concluded

Table 73--Condition of three-ply plywood, layed up in combinations of Southern Pine, sweetgum, and yellow poplar,

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Table 74--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with copper carbonate and copper oxide in combination with pelargonic acid and octanoic acid after about 13 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, April 1987 (Plot 99)

Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termitetermite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)

Copper carbonate/ 0.10 9 11 11 -- 33 44 -- -- 4 40 --pelargonic acid 0.25 10 30 20 -- -- 50 -- -- 5 50 --

0.40 10 60 20 -- -- 20 -- -- 2 20 --0.60 10 60 10 -- -- 20 -- 10 3 30 --1.00 9 89 -- -- -- 11 -- -- 1 11 --

Copper carbonate/ 0.10 9 -- 22 11 44 22 -- -- 2 22 --octanoic acid 0.25 10 20 30 -- 10 40 -- -- 4 40 --

0.41 9 56 11 -- -- 33 -- -- 3 30 --0.59 9 78 -- -- -- 22 -- -- 2 22 --1.00 10 70 -- -- -- 30 -- -- 3 30 --

Copper oxide/ 0.10 10 20 40 -- 10 30 -- -- 3 30 --pelargonic acid 0.25 10 40 20 -- -- 40 -- -- 4 40 --

0.40 10 100 -- -- -- -- -- -- -- --0.60 10 50 -- -- -- 50 -- -- 5 50 --1.00 10 50 20 -- -- 30 -- -- 3 30 --

Copper oxide/ 0.10 10 -- 30 10 40 10 -- 10 2 20 --octanoic acid 0.25 10 30 10 -- 10 30 -- 20 5 50 --

0.41 10 80 10 -- -- 10 -- -- 1 10 --0.59 8 63 -- -- -- 37 -- -- 3 37 --1.01 9 67 11 -- -- 22 -- -- 2 22 --

Chromated copper 0.10 9 -- 22 -- 56 11 -- 11 2 22 --arsenate 0.25 9 100 -- -- -- -- -- -- -- -- --

0.40 10 100 -- -- -- -- -- -- -- -- --0.60 10 100 -- -- -- -- -- -- -- -- --

Untreated controls -- 10 -- -- -- 30 10 60 10 100 2.3

aTen stakes originally installed; eliminated stakes removed for causes other than decay or insect attack.

Condition of stakes June 2000 (%)

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with xylene insolubles less than 0.1% (clean creosote) plus additives of chlorpyrifos and chlorothalonil after about

Condition of stakes January 2002 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) testa Good Decay attack attack fungi attack attack Number % (year)AWPA P1-13 creosote 1.0 9 -- -- -- -- 67 -- 33 9 100 8.7 with xylene insolubles 2.0 10 -- -- -- -- 80 -- 20 10 100 11.7 less than 0.1% 4.0 10 -- 30 40 -- 30 -- -- 3 30 --

6.2 10 10 60 -- 10 20 -- -- 2 20 --8.5 10 10 70 -- 20 -- -- -- -- -- --

+0.5% chlorpyrifos 1.0 10 -- -- -- -- 80 -- 20 10 100 9.12.0 10 -- -- -- 10 90 -- -- 9 90 --3.9 10 -- 40 -- 30 30 -- -- 3 30 --6.0 10 -- 90 -- 10 -- -- -- -- -- --8.3 10 -- 70 -- 30 -- -- -- -- -- --

+0.78% chlorpyrifos 1.0 10 -- -- -- -- 90 -- 10 10 100 8.42.0 10 -- -- -- -- 100 -- -- 10 100 12.64.0 10 -- 20 -- 20 60 -- -- 6 60 --6.0 10 -- 60 -- 40 -- -- -- -- -- --8.2 10 -- 70 -- 30 -- -- -- -- -- --

+2% chlorothalonil 1.0 10 -- -- -- -- 60 10 30 10 100 9.72.0 10 -- 10 -- -- 90 -- -- 9 90 --4.0 10 -- 60 -- 30 10 -- -- 1 10 --6.0 10 -- 90 -- 10 -- -- -- -- -- --8.2 10 40 50 -- 10 -- -- -- -- -- --

Untreated controls -- 10 -- -- -- -- 10 80 10 10 100 1.7

aTen stakes were originally installed; this number has since been reduced because of failure to locate the stakes at the time of inspection.

Table 75--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with toluene-diluted AWPA P1-13 creoso

14 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, April 1988 (Plot 100)

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Table 76--Condition of Southern Pine stakes (2 by 4 in. nominal by 18 in.) treated with pentachlorophenol (manufactured 24 years apart) after 9 years of service. Stakes placed in test on the Harrison Experimental Forest, Saucier, MS, April 1989 (Plot 101)

Condition of stakes February 1998 (%)Serviceable but Destroyed by--showing some-- Decay

Num- Decay fungiAverage ber and and Averageretention in Termite termite Decay Termite termite Total removed life

Preservative (lb/ft3) test GoodDecay attack attack fungi attack attack Number % (year)Pentachlorophenol 0.1 10 40 40 10 10 -- -- -- -- -- -- (1965 manufacture 0.2 10 50 50 -- -- -- -- -- -- -- -- date) in 20% P9 oil 0.4 10 60 40 -- -- -- -- -- -- -- -- and toluene 0.6 10 80 20 -- -- -- -- -- -- -- --Pentachlorophenol 0.1 10 100 -- -- -- -- -- -- -- -- -- (1989 manufacture 0.2 10 90 -- 10 -- -- -- -- -- -- -- date) in 20% P9 oil 0.4 10 100 -- -- -- -- -- -- -- -- -- and toluene 0.6 10 80 20 -- -- -- -- -- -- -- --20% P9 oil and toluene 0.6 10 100 -- -- -- -- -- -- -- -- --Untreated controls -- 10 -- -- -- -- 60 -- 40 10 100 2.0

This study was initiated by L.R. Gjovik.

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Table 77--Summary of 2- by 4-in. stake selected results obtained in Mississippiwith wood preservatives in general use

DataAverage from Averageretentiona table life

Preservative (lb/ft3) number (year) Remarks

Acid copper chromate 0.25 (0.13) 15 11.6 -- (Fed. Spec. TT-W-546) 0.30 (0.14) 46 6.1 --

0.51 (0.25) 47 -- 70% failed after 35 years0.51 (0.26) 15 -- 70% failed after 55 years0.60 (0.29) 46 4.6 --0.75 (0.37) 15 -- 50% failed after 55 years1.01 (0.50) 47 -- 40% failed after 35 years1.54 (0.76) 47 -- 22% failed after 35 years

Ammoniacal copper borate (0.17) 52 -- 75% failed after 25 years(0.22) 52 -- 65% failed after 25 years(0.33) 52 -- 25% failed after 25 years(0.45) 52 -- No failures after 25 years(0.66) 52 -- 15% failed after 25 years(1.33) 52 -- No failures after 25 years

Ammoniacal copper arsenate 0.17 52 -- 95% failed after 25 years (Fed. Spec. TT-W-549) 0.23 52 -- 30% failed after 25 years

0.25 (0.24) 14 -- 89% failed after 55 years0.26 (0.25) 47 -- 30% failed after 35 years0.48 (0.45) 47 -- 10% failed after 35 years0.53 (0.51) 14 -- 10% failed after 55 years1.01 (0.97) 14 -- No failures after 55 years1.29 (1.25) 14 -- No failures after 55 years

Chromated copper arsenate 0.26 (0.15) 15 28.7 -- Type I (Fed. Spec. TT-W-550) 0.39 (0.22) 47 -- 40% failed after 35 years

0.50 (0.29) 15 -- 30% failed after 55 years0.76 (0.44) 47 -- 10% failed after 35 years0.78 (0.44) 15 -- 20% failed after 55 years

Type II (Fed. Spec. TT-W-550) 0.25 (0.23) 47 -- 30% failed after 35 years(0.26) 20 -- No failures after 46 years(0.37) 20 -- No failures after 46 years(0.52) 20 -- No failures after 46 years(0.79) 20 -- No failures after 46 years(1.04) 20 -- No failures after 46 years

Type III (Fed. Spec. TT-W-550) (0.14) 57 -- No failures after 22 years(0.20) 48 -- No failures after 29 years(0.25) 55 -- No failures after 20 years(0.27) 57 -- No failures after 22 years(0.40) 48 -- No failures after 29 years(0.40) 55 -- No failures after 20 years(0.40) 57 -- No failures after 22 years(0.60) 48 -- No failures after 29 years(0.62) 57 -- No failures after 22 years(0.77) 55 -- No failures after 20 years(0.79) 57 -- No failures after 22 years

(Page 1 of 4)

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Table 77--Summary of 2- by 4-in. stake selected results obtained in Mississippiwith wood preservatives in general use--continued

DataAverage from Averageretentiona table life

Preservative (lb/ft3) number (year) Remarks

Chromated zinc arsenate (former Fed. Spec. TT-W-538) 0.22 (0.11) 24 22.1 --

0.33 (0.22) 4 33.0 --0.44 (0.29) 4 39.3 --0.38 (0.20) 24 -- 40% failed after 45 years0.77 (0.40) 24 -- No failures after 45 years1.01 (0.53) 24 -- No failures after 45 years0.58 (0.38) 4 51.7 --0.78 (0.52) 4 -- 30% failed after 60 years1.06 (0.70) 4 -- No failures after 60 years

Chromated zinc chloride 0.49 (0.30) 2 14.2 -- (Fed. Spec. TT-W-551) 0.76 (0.47) 2 20.2 --

0.76 (0.46) 47 13.8 --1.03 (0.63) 2 20.1 --1.02 (0.62) 47 14.9 --1.50 (0.92) 25 23.4 --1.57 (0.96) 47 17.8 --2.91 (1.78) 25 32.7 --6.00 (3.67) 25 -- No failures after 45 years

Copper-8-quinolinolate 0.01 38 5.3 -- Stoddard solvent 0.02 38 4.2 --

0.06 38 5.6 --0.12 38 7.8 --

Copper-8-quinolinolate 0.01 43 -- 90% failed after 37 years AWPA P9 heavy petroleum 0.03 43 27.3 --

0.06 43 -- 90% failed after 37 years0.12 43 -- No failures after 37 years

Copper naphthenate 0.11% copper in No. 2 fuel oil 10.3 (0.012) 7 15.9 -- 0.29% copper in No. 2 fuel oil 10.2 (0.029) 7 21.8 -- 0.57% copper in No. 2 fuel oil 10.6 (0.061) 7 27.1 -- 0.86% copper in No. 2 fuel oil 9.6 (0.082) 7 29.6 --

Creosote, coal-tar 3.3 6 24.9 -- 4.1 17 14.2 -- 4.2 4 17.8 -- 4.6 5 21.3 -- 7.8 6 -- 70% failed after 54-1/2 years 8.0 4 -- 90% failed after 60 years 8.3 20 -- 50% failed after 46 years 10.0 5 -- 90% failed after 55 years 11.8 4 -- 50% failed after 60 years 13.2 6 -- 20% failed after 54-1/2 years 14.5 5 -- No failures after 55 years 16.5 4 -- 10% failed after 60 years

(Page 2 of 4)

Page 123: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 77--Summary of 2- by 4-in. stake selected results obtained in Mississippiwith wood preservatives in general use--continued

DataAverage from Averageretentiona table life

Preservative (lb/ft3) number (year) Remarks

Creosote, coal-tar--continued

Low residue, straight run 8.0 18 17.8 --

Medium residue, straight run 8.0 18 18.8 --

High residue, straight run 7.8 18 20.3 --

Medium residue Low in tar acids 8.1 18 19.4 -- Low in naphthalene 8.2 18 21.3 -- Low in tar acids and naphthalene 8.0 18 18.9 --

Low residue Low in tar acids and naphthalene 8.0 18 19.2 --

High residue Low in tar acids and naphthalene 8.2 18 20.0 --

English vertical retort 5.3 19 -- 90% failed after 50 years8.0 18 18.9 --10.1 19 -- 80% failed after 50 years15.0 19 -- No failures after 50 years

English coke oven 4.7 19 16.3 --7.9 18 13.6 --10.1 19 -- 70% failed after 50 years14.8 19 -- 80% failed after 50 years

Fluor chrome arsenate phenol type A (Fed. Spec. TT-W-535) 0.20 (0.12) 2 10.2 --

0.30 (0.19) 2 18.0 --0.35 (0.22) 37 18.3 --0.50 (0.31) 37 18.4 --0.61 (0.38) 2 24.1 --

Pentachlorophenol (various solvents)b

Liquified petroleum gas 0.14 42 18.9 --0.19 42 15.9 --0.34 42 -- 10% failed after 38-1/2 years0.34 45 -- 90% failed after 35 years0.49 45 -- 10% failed after 35 years0.58 42 -- No failures after 38-1/2 years0.65 45 -- No failures after 35 years

Stoddard solvent (mineral spirits) 0.14 42 13.7 --0.18 42 15.9 --0.38 42 -- 80% failed after 38-1/2 years0.67 42 -- No failures after 38-1/2 years4.00 17 13.7 --4.10 22 9.5 --8.00 22 15.5 --

(Page 3 of 4)

Page 124: Comparison of wood Preservatives in Stake Tests--2000 ...Results of an international termite exposure test in 1930 (Hunt and Snyder) indicated that exposing 2- by 4- by 18-in. pine

Table 77--Summary of 2- by 4-in. stake selected results obtained in Mississippiwith wood preservatives in general use--concluded

DataAverage from Averageretentiona table life

Preservative (lb/ft3) number (year) Remarks

Heavy gas oil (Mid-United States) 4.10 17 -- 89% failed after 50 years7.90 17 -- 80% failed after 50 years

12.00 17 -- 20% failed after 50 years

No. 4 aromatic oil (West Coast) 4.20 22 21.0 --8.20 22 -- 70% failed after 50 years

AWPA P9 (heavy petroleum) 0.11 42 -- 90% failed after 38-1/2 years0.19 42 -- 60% failed after 38-1/2 years0.29 42 -- No failures after 38-1/2 years0.53 45 -- No failures after 35 years0.67 42 -- No failures after 38-1/2 years

Tributyltin oxide 0.015 36 6.4 -- Stoddard solvent 0.030 36 7.2 --

0.045 36 7.4 --7.900 41 7.0 --8.200 41 4.5 --

AWPA P9 (heavy petroleum) --3% 8.00 41 20.86% 8.00 41 24.0 --

Petroleum solvent controls 4.00 17 7.6 --4.10 17 4.4 --4.00 17 12.9 --7.70 23 14.6 --7.90 17 -- 90% failed after 50 years8.00 45 19.7 --8.00 41 23.3 --8.00 17 14.6 --8.10 18 3.4 --8.50 43 20.9 --9.80 5 6.3 --

12.00 17 17.1 --12.10 17 -- 80% failed after 50 years19.40 5 9.1 --

Untreated stakes -- Misc. 1.8 to --3.6

aRetention values in parentheses are based on preservative oxides or copper metal.

bSee Tables 5 and 17 for pentachlorophenol in other solvents.(Page 4 of 4)


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