Polyguard epoxy Base- Part B Not available. Solid. GHS product identioier Other means oo identioication Product type Emergency telephone number (with hours oo operation) Section 1. Identioication : : : : Manuoacturer : Identioied uses Polyguard epoxy Base- Part B SAFETY DATA SHEET Compliant SDS oor GHS: HazCom 2012 / United States; WHMIS 2015 / Canada Protection of pipeline field joints, girth welds, valves, fittings and a holiday repair material on FBE coated pipe and for pipeline coating rehabilitation. Supplier's details : Crossroads & C&I 11104 180 Street NW Edmonton, Alberta Canada T5S 2X5 Polyguard Products Inc. 3801 South Interstate 45 Ennis, TX 75119 Tel: (800)541-4994 CHEMTREC, U.S. : 1-800-424-9300 International: +1-703-527-3887 (24/7) Section 2. Hazards identioication ACUTE TOXICITY (oral) - Category 4 ACUTE TOXICITY (inhalation) - Category 2 SKIN CORROSION/IRRITATION - Category 2 SERIOUS EYE DAMAGE/ EYE IRRITATION - Category 2A SKIN SENSITIZATION - Category 1 GERM CELL MUTAGENICITY - Category 2 SPECIFIC TARGET ORGAN TOXICITY (REPEATED EXPOSURE) - Category 2 AQUATIC HAZARD (ACUTE) - Category 1 AQUATIC HAZARD (LONG-TERM) - Category 1 Classioication oo the substance or mixture : Signal word : Danger Hazard pictograms : GHS label elements OSHA/HCS status : This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). 1/13 Tel : +1-888-GHS-7769 (447-7769) / +1-450-GHS-7767 (447-7767) www.kmkregservices.com www.askdrluc.com www.ghssmart.com
Transcript
Polyguard epoxy Base- Part BNot available.
Solid.
GHS product identioierOther means oo identioicationProduct type
Emergency telephone number (with hours oo operation)
Section 1. Identioication::
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Manuoacturer :
Identioied uses
Polyguard epoxy Base- Part B
SAFETY DATA SHEETCompliant SDS oor GHS: HazCom 2012 / United States; WHMIS 2015 / Canada
Protection of pipeline field joints, girth welds, valves, fittings and a holiday repair material on FBE coated pipe and for pipeline coating rehabilitation.
H302 - Harmful if swallowed.H319 - Causes serious eye irritation.H315 - Causes skin irritation.H317 - May cause an allergic skin reaction.H341 - Suspected of causing genetic defects.H373 - May cause damage to organs through prolonged or repeated exposure.H410 - Very toxic to aquatic life with long lasting effects.
Precautionary statementsPrevention : P201 - Obtain special instructions before use.
P202 - Do not handle until all safety precautions have been read and understood.P281 - Use personal protective equipment as required.P280 - Wear protective gloves. Wear eye or face protection.P284 - Wear respiratory protection.P271 - Use only outdoors or in a well-ventilated area.P273 - Avoid release to the environment.P260 - Do not breathe vapor.P270 - Do not eat, drink or smoke when using this product.P264 - Wash hands thoroughly after handling.P272 - Contaminated work clothing should not be allowed out of the workplace.
Response : P391 - Collect spillage.P314 - Get medical attention if you feel unwell.P308 + P313 - IF exposed or concerned: Get medical attention.P304 + P340 + P310 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or physician.P301 + P312 + P330 - IF SWALLOWED: Call a POISON CENTER or physician if you feel unwell. Rinse mouth.P302 + P352 + P362-2 + P363 - IF ON SKIN: Wash with plenty of soap and water. Take off contaminated clothing. Wash contaminated clothing before reuse.P333 + P313 - If skin irritation or rash occurs: Get medical attention.P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsing.P337 + P313 - If eye irritation persists: Get medical attention.
Storage : P405 - Store locked up.Disposal : P501 - Dispose of contents and container in accordance with all local, regional, national
and international regulations.Hazards not otherwise classioied (HNOC)
There are no additional ingredients present which, within the current knowledge oo the supplier and in the concentrations applicable, are classioied as hazardous to health or the environment and hence require reporting in this section.
Occupational exposure limits, io available, are listed in Section 8.
Any concentration shown as a range is to protect conoidentiality or is due to batch variation.
Wash out mouth with water. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by medical personnel. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Get medical attention. If necessary, call a poison center or physician. Never give anything by mouth to an unconscious person. If unconscious,place in recovery position and get medical attention immediately.
Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 20 minutes. Get medical attention.
Wash with plenty of soap and water. Wash contaminated clothing thoroughly with water before removing it, or wear gloves. Continue to rinse for at least 20 minutes. Get medical attention. In the event of any complaints or symptoms, avoid further exposure.Wash clothing before reuse. Clean shoes thoroughly before reuse.
Get medical attention immediately. Call a poison center or physician. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. In case of inhalation of decomposition products in a fire, symptoms may be delayed. The exposed person may need to be kept under medical surveillance for 48 hours.
Section 4. First aid measures
Eye contact
Skin contact
Inhalation
Ingestion :
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:Description oo necessary oirst aid measures
Most important symptoms/eooects, acute and delayed
Inhalation : Fatal if inhaled. Exposure to decomposition products may cause a health hazard.Serious effects may be delayed following exposure.
Harmful if swallowed. Irritating to mouth, throat and stomach.:IngestionSkin contact : Causes skin irritation. May cause an allergic skin reaction.
Causes serious eye irritation.:Eye contact
Over-exposure signs/symptoms
Inhalation No known significant effects or critical hazards.:
Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Protection oo oirst-aiders : No action shall be taken involving any personal risk or without suitable training. If it is suspected that fumes are still present, the rescuer should wear an appropriate mask or self-contained breathing apparatus. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Wash contaminated clothing thoroughly with water before removing it, or wear gloves.
Notes to physician : In case of inhalation of decomposition products in a fire, symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48 hours.
Specioic treatments : No specific treatment.
Skin contact
Ingestion No known significant effects or critical hazards.
Adverse symptoms may include the following:irritationredness
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See toxicological inoormation (Section 11)
Indication oo immediate medical attention and special treatment needed, io necessary
Section 5. Fire-oighting measures
No special measures are required.
Hazardous thermal decomposition products
Specioic hazards arising orom the chemical
Decomposition products may include the following materials:carbon dioxidecarbon monoxidenitrogen oxidesmetal oxide/oxides
This material is very toxic to aquatic life with long lasting effects. Fire water contaminated with this material must be contained and prevented from being discharged to any waterway, sewer or drain.
Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode.
Special protective equipment oor oire-oighters
Use an extinguishing agent suitable for the surrounding fire.Extinguishing media
: No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or walk through spilled material. Do not breathe vapor or mist.Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment.
For non-emergency personnel
For emergency responders : If specialized clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non-emergency personnel".
Section 6. Accidental release measuresEnvironmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Water polluting material. May be harmful to the environment if released in large quantities. Collect spillage.
Methods and materials oor containment and cleaning upStop leak if without risk. Move containers from spill area. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal.
:Spill
Section 7. Handling and storage
Advice on general occupational hygiene
Conditions oor saoe storage,including any incompatibilities
Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating,drinking and smoking. See also Section 8 for additional information on hygiene measures. Remove contaminated clothing and protective equipment before entering eating areas.
Store in accordance with local regulations. Store in original container protected from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Keep container tightly closed and sealed until ready for use. Containers that have been opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabeled containers.Use appropriate containment to avoid environmental contamination.
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Protective measures Put on appropriate personal protective equipment (see Section 8). Persons with a history of skin sensitization problems should not be employed in any process in which this product is used. Avoid exposure - obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest. Avoid release to the environment. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Keep in the original container or an approved alternative made from a compatible material, kept tightly closed when not in use. Empty containers retain product residue and can be hazardous. Do not reuse container.
Hand protection Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated.
Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists,gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: chemical splash goggles.
Eye/oace protection
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Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
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Environmental exposure controls
: Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation.
Appropriate engineering controls
: Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits.
Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period.Appropriate techniques should be used to remove potentially contaminated clothing.Contaminated work clothing should not be allowed out of the workplace. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location.
Hygiene measures :Individual protection measures
Skin protection
Other skin protection : Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.
Section 8. Exposure controls/personal protectionUse a properly fitted, air-purifying or supplied air respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator.
Respiratory protection :
Section 9. Physical and chemical properties
Physical state
Melting point
Vapor pressure
Relative densityVapor density
Solubility
Liquid. [Paste.]
Not available.
1.05Not available.Not available.
Not soluble in water.
Amine-like.Odor
pH
Blue.Color
Evaporation rate Not available.
Auto-ignition temperature
Flash point
Not available.
Closed cup: 104°C (219.2°F) [Pensky-Martens.]
Not available.
10.7
Viscosity Dynamic (room temperature): 11000 to 12000 mPa·s (11000 to 12000 cP)
Not available.Odor threshold
Partition coeooicient: n-octanol/water
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Appearance
Boiling point : Not available.
Flammability (solid, gas) : Not available.Lower and upper explosive (olammable) limits
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Decomposition temperature : Not available.
Volatility Not available.:VOC : 0 g/L
Section 10. Stability and reactivity
Hazardous decomposition products
Conditions to avoid No specific data.
Under normal conditions of storage and use, hazardous decomposition products should not be produced.
The product is stable.Chemical stability
Reactive or incompatible with the following materials: oxidizing materials.
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Incompatible materials :
Possibility oo hazardous reactions
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
May cause damage to organs through prolonged or repeated exposure. Once sensitized, a severe allergic reaction may occur when subsequently exposed to very low levels.
General :
No known significant effects or critical hazards.Carcinogenicity :Suspected of causing genetic defects.Mutagenicity :No known significant effects or critical hazards.Teratogenicity :
Developmental eooects : No known significant effects or critical hazards.Fertility eooects : No known significant effects or critical hazards.
Skin contact
Ingestion
Inhalation No known significant effects or critical hazards.
No known significant effects or critical hazards.
Adverse symptoms may include the following:irritationredness
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Eye contact : Adverse symptoms may include the following:pain or irritationwateringredness
Potential chronic health eooects
Delayed and immediate eooects and also chronic eooects orom short and long term exposure
Numerical measures oo toxicity
Route ATE valueAcute toxicity estimates
Potential immediate eooects
: No known significant effects or critical hazards.Short term exposure
Potential delayed eooects : No known significant effects or critical hazards.
Potential immediate eooects
: No known significant effects or critical hazards.Long term exposure
Potential delayed eooects : No known significant effects or critical hazards.
Section 13. Disposal considerationsThe generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling empty containers that have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers.
:Disposal methods
United States - RCRA Toxic hazardous waste "U" List
Reportable quantity4432.6 lbs / 2012.4 kg [506.31 gal / 1916.6 L]Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity)transportation requirements.
The marine pollutant mark is not required when transported in sizes of ≤5 L or ≤5 kg.
Emergency schedules (EmS)F-A, S-A
The environmentally hazardous substance mark may appear if required by other transportation regulations.
Packing group
Additional inoormation
Environmental hazards
No. Yes. No.
AERG : 154
Special precautions oor user
Transport in bulk according to Annex II oo MARPOL 73/78 and the IBC Code
Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage.
: Not available.
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DOT-RQ Details Phenol 1000 lbs / 454 kg:
II
The marine pollutant mark is not required when transported by road or rail.
No.
Section 15. Regulatory inoormationU.S. Federal regulations :
: Listed
: Not listed
: Not listed
: Not listed
: Not listed
United States inventory (TSCA 8b): Not determined.
SARA 302/304
SARA 304 RQ : 4432.6 lbs / 2012.4 kg [506.3 gal / 1916.6 L]
Composition/inoormation on ingredients
Name % EHS (lbs) (lbs)(gallons) (gallons)
SARA 302 TPQ SARA 304 RQ
SARA 311/312Classioication : Immediate (acute) health hazard
Delayed (chronic) health hazard
Phenol 10 - 30 Yes. 500 / 10000 - 1000 -
Clean Water Act (CWA) 311: Phenol
Clean Water Act (CWA) 307: Phenol; 29H,31H-phthalocyaninato(2-)-N29,N30,N31,N32 copper
Clean Air Act Section 112(b) Hazardous Air Pollutants (HAPs)Clean Air Act Section 602 Class I SubstancesClean Air Act Section 602 Class II SubstancesDEA List I Chemicals (Precursor Chemicals)DEA List I Chemicals (Precursor Chemicals)
The following components are listed: Phenol; M-phenylenebis(methylamine)
No products were found.
Massachusetts :
SARA 313
Product name CAS number %
SARA 313 notifications must not be detached from the SDS and any copying and redistribution of the SDS shall include copying and redistribution of the notice attached to copies of the SDS subsequently redistributed.
Phenol 108-95-2 10 - 30
Phenol 108-95-2 10 - 30
Form R - Reporting requirements
Supplier notioication
Calioornia Prop. 65
New York : The following components are listed: PhenolNew Jersey : The following components are listed: Phenol; M-phenylenebis(methylamine); 29H,31H-
phthalocyaninato(2-)-N29,N30,N31,N32 copperPennsylvania : The following components are listed: Phenol; M-phenylenebis(methylamine); 29H,31H-
KMK Regulatory Services Inc.Notice to readerTo the best oo our knowledge, the inoormation contained herein is accurate. However, neither the above-named supplier, nor any oo its subsidiaries, assumes any liability whatsoever oor the accuracy or completeness oo the inoormation contained herein.Final determination oo suitability oo any material is the sole responsibility oo the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
