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Curriculum Vitae

Dr. Julio Lloret Fillol

Number of pages: 20

Section A - Short Curriculum Vitae

o Academic Career; Position & Short Visits. Fellowships & Awards

o Publications summary

Section B - Summary of the early achievements track-record

Section C - Extend Curriculum Vitae

o C.1.- List of Publications

o C.2.- List of participation in research projects

o C.3.- List of invited conferences, meetings and workshops

o C.4.- Patents

o C.5.- List of professional activities

o C.6.- Detailed independent research

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Section A - Short Curriculum Vitae

Dr. Julio Lloret Fillol (18/03/1977) Researcher ID: A-3102-2009

Current Position

ICREA Research Professor and Research Group Leader at the

Institute of Chemical Research of Catalonia ICIQ (Tenure-Track).

e-mail: jlloret@iciq.es

Web site: http://www.iciq.org/research/research_group/dr-julio-lloret-fillol/

Education

26-05-2006 European Ph.D. in Chemistry with Excellent Cum Laude, Univ. of Valencia

(Spain). Ph.D. Supervisors: Prof. P. Lahuerta and Prof. J. Peréz-Prieto

06-2001 Bachelor in Chemistry, Univ. of Valencia (Spain)

01-2001 / 06-2001 Erasmus programme, the highest mark, Univ. of Loughborough (UK)

Position

Since 11 - 2015 ICREA Research Professor

Since 11 - 2014 Research Group Leader at the Institute of Chemical Research of Catalonia (ICIQ)

01-2014 - 10-2014 Young Research Group Leader at the Institut the Química Computational i Càtalisi

04-2010 - 10-2014 Independent research leader as Ramón y Cajal (2009-program) at the Univ. of Girona,

Spain (Since 32 years old).

04-2008 / 03-2010 Marie Curie IEF, Univ. of Heidelberg, Germany (Prof. L. H. Gade)

12-2006 / 04-2008 Post-Doc MEyC, Univ. of Heidelberg, Germany (Prof. L. H. Gade)

07-2006 / 12-2006 Post-Doc, Univ. of Valencia, Spain (Prof. M. Ubeda)

01-2002 / 06-2006 Ph.D. student, Univ. of Valencia, Spain.

08-2001 / 12-2001 Univ. of Würzburg, Germany (contracted by SFB347 and BASF) (Prof. H. Werner)

01-2001 / 06-2001 Undergraduate student, Univ. of Loughborough, Erasmus program, UK (Prof. J. Parr)

Short Visits

07-2013 / 08-2013 University of Minnesota. Visiting professor, EEUU (Host: Prof. Dr. L. Que)

10-2006 / 11-2006 Universitat Rovira i Virgili. Visiting professor, Spain (Host: Dr. J. Carbó)

07-2005 / 09-2005 Univ. of Heidelberg, as visiting student, Germany (Prof. L. H. Gade)

06-2004 / 08-2004 Univ. of Joensuu, as visiting student, Finland (Prof. T.A.Pakkanen & P. Hirva)

07-2003 / 08-2003 Max-Plank-Institut für Kohlenforschung, Germany (Prof. L. Gooβen)

04-2002 Univ. Autónoma de Barcelona, Spain (Prof. A. Lledós)

Fellowships and Awards

2019 Thieme Chemistry Journals Award

2017 Young Academy of Europe

2015 Young Researcher Award 2015 (under the 40’s) of the RSEQ

2015 ERC-Consolidation Grant GREENLIGHT_REDCAT (1.999.063 €)

2014 Young Researcher Award 2014 (under the 40’s) of the Organometallic Group of the RSEQ

2014 Positive evaluation in the Spanish Tenure Track Program I3.

2014 Shortlisted for the Chem Soc Rev Emerging Investigator Lectureship 2014

2013 I passed the 1st stage of the 2013-ERC Starting Grant (Interviewed in Brussels)

2013 Qualified as “professor agregat” by “Agència per a la Qualitat del Sistema Universitari Cat.”

2010 Marie Curie Reintegration Grant. WaterSplit (FP7-268445) Total Score: 91.4 over 100.

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2009 Ramón y Cajal Program (Spanish Tenure Track Program) (MICINN-RYC-2009-0540).

Highly competitive, only <7% program success. Awarded within the top 10.

2007 Marie Curie IEF for career development. CHIRGOLD - Researcher Score: 4.6 over 5.

2006 Post-Doctoral Fellowship Grant from MEyC Spanish Government. (declined after 1 year)

2006 Ph.D. Fellowship Mobility Grant from MEyC, Univ. of Heidelberg (Prof. L. H. Gade)

2004 Ph.D. Fellowship Mobility Grant from MEyC, Univ. of Joensuu (Prof. T.A. Pakkanen)

2002 MEyC Ph.D. Fellowship Grant of the Spanish Government

2002 Ph.D. Fellowship Grant “Fundación Jose y Ana Royo” (declined after 1 year)

2001 Erasmus Fellowship Grant from MEyC, Univ. of Loughborough, UK

2001 Collaboration Grant from MEyC, Spanish government at Univ. of Valencia, Spain

Supervisions and Commissions

Supervision of Graduate Students Fellows

2010 – 2014

As an independent

researcher (at Univ.

of Girona, Spain)

- Supervised 4 Ph.D. students: Mr. Z. Codolá, Mr. F. Acuña, Mr. G. Sabeña,

Mr. A. Call.

- 7 Master Students: Research work on catalysis at Univ. of Girona: Mr. Z.

Codolá (2010), Mr. F. Acuña (2011), Mr. G. Sabenya (2011) and Mr. A. Call

(2011). Supervisor of the master research work on Data mining and

knowledge discovery of Mr. R. Eduart (2012) at Univ. of Buenos Aires.

Supervisor of the Master research work on Computational chemistry and

Catalysis of Ms. C. Casadevall and C. Vignatti (2013).

Zoel Codolà, my first Ph.D. student, has been awarded with the prestigious European Young Chemists

Award 2014. He also had been awarded with a Principe de Asturias Fellowship and had the highest mark

in the Master Defence of his promotion and received the highest Ph.D. mark.

Arnau Call and Ferran Acuña have been awarded with an FPU and FI fellowships, respectively. Both

received the highest Ph.D. mark.

Carla Casadevall has had the highest Master thesis mark of her promotion.

2015 – 2018

At ICIQ

- 8 PhD students under supervision: Mrs. C. Casadevall (4th y), Mr. M.

Claros (3rd y), Mr. K. Michaliszyn (3rd y), Mr. S. Fernandez (2nd y), and Mr. J.

Aragó (2nd year), Mrs. G. Dubed Bandomo (1st y), Mrs. P. David (0 y) and

Mrs. P. Gutierrez (0 y).

- 3 Master Students: Research work on computational chemistry at Univ. of

Girona: Mr. S. Fernandez (2017), Mr. Master BIST: M. Bueno (2018). Master

URV on catalysis Mr. L. Montiel (2018).

Sergio Fernandez has had the highest Master thesis mark of his promotion and awarded with an FPU

Teaching Activities

2010 – 2013 Lecturer of Inorganic Chemistry in the Chemistry Department. Teaching background

on “Materials Science” subject. (30 h)

2013 – 2019 Lecturer of Master of Computational Chemistry and Catalysis of the Department of

Chemistry at Girona University. Teaching background on “Catalysis apply to the

energy production” subject (30 h)

2013.10 Lecturer on the postgraduate program of the Univ. Nacional Autónoma de Mexico.

“Catalysis apply for the energy production” (4.5 h)

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Commissions of Trust

• Member of Ph.D. thesis jury on seven occasions (Girona, Barcelona, 2xMadrid, Castellon, and

Perugia (Italy, 2014) and Stockholm (Sweden, June 2014).

• Reviewer of scientific journals such as Nat. Chem., J. Am. Chem. Soc, ACIE among others.

• Regular reviewer of the Petroleum Research Foundation, Spanish national basic research program,

and FET-open Horizon 2020. Marie Skłodowska-Curie actions – Individual Fellowships (H2020-

MSCA-IF-2014), among other agencies

ORGANIZACION CONGRESOS

2015 – 3- 6-Nov. XII Simposio de Investigadores Jóvenes, Barcelona, Spain. Member of the organization and scientific

committee.

2018 – 30 Jul – 4 – Aug 43nd International Conference on Coordination Chemistry" in Sendai (Japan). Symposium S33

Functional hybrid materials for catalytic energy conversion, Organizer

2018 – 18-19-Oct. 2nd Trans Pyrenean Meeting in Catalysis (TraPCat2), Tarragona, Spain. Organizer

During my PostDoc (at University of Heidelberg, Germany)

• PhD advisor of Mr. A. Kruckenberg, Mr. P. Scherl and advisor for diplomarbeiten Mr. Achim

Kruckenberg, Mr. Peter Scherl and Mr. Christoph Rettenmeier (Univ. of Heidelberg, Germany).

• Assistant professor in“Anorganisch-Chemisches Forschungspraktikum” (4 undergrad student’s, total of

60 days).

Memberships of Scientific Societies

• Partner member of the WG3 CARISMA COST ACTION and CHAOS ACTION

• Member of the “Real Sociedad Española de Química” (RSEQ, since 2003) and of the American Chemical

Society (ACS, since 2009)

Major Collaborations Active

- Collaborations in Europe

Prof. Dr. M. Beller (LIKAT at the Univ. of Rostock), Prof. Dr. Beatriz Royo (ITQB at the Univ. Nova de

Lisboa), Dr W. R. Browne (Univ. of Groningen), Prof. Dr. Julia Pérez-Prieto (Univ. of Valencia), Prof. Dr.

Lutz Hans Gade (Univ. of Heidelberg), Dr. Miquel Costas (Univ. of Girona), Dr. Josep M. Lluis (Univ. of

Girona), Dr. Ruben Mas (Univ. Autonoma de Madrid), Prof. Dr. George JP Britovsek (Imperial College,

London), Dr. Olaf Rüdinger (Max Plank Institute Mulheim, Germany).

- Collaborations with the rest of the world

Prof. Dr. L. Que (Univ. of Minnessota), Prof. Dr. E. Münck (Carnegie Mellon University), Prof. Dr. G

Ghirlanda (Arizona State University).

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Publications summary

During my scientific carrier, I have produced over

74 scientific publications in the most prestigious

international journals, three book chapters and

around 80 communications in international forums

and conferences. I have been invited to give

lectures over 60 times. Among all of them, I want

to remark the talks in the University of Michigan,

Arizona, and Minnesota (about top 20 USA

universities in the Shanghai ranking) and the

International School of Organometallic Chemistry.

My research has also delivered in 6 Spanish/International patents. Since April-2010 I have published as an

independent researcher a collection of papers in top international peer-reviewed journals: 1 x Nat. Chem.

2011, 807-813 (>460 cites indexed in crossref and highlighted), 2 x Nature Communication, 2 x ACIE.

(one VIP), 6 x J. Am Chem. Soc, 9 x Chem. Eur. J. (one Frontispiece), 2 Chem Sci (one cover picture), 3

Chem. Commun. (one cover picture) among others.

According to the ISI Web of Knowledge, I have over 2300 citations with a google scholar h index of 27.

Since 2010, I have supervised 4 Ph.D. thesis and currently are ongoing eight more.

Selected Publications as the corresponding author derived from the PI independent research work

1) “Efficient Water Oxidation Catalysts Based on Readily Available Iron Coordination Complexes” J.

Lloret-Fillol et al. - Nature Chem. 2011, 807-813 (>460 citations, crossref).

2) “Electronic Effects in Iron-Catalyzed Water Oxidation” - Chem. Eur. J. 2013, 19, 8042. (70 c.)

3). “Highly Effective Water Oxidation Catalysis with Ir Complexes”- Chem.Eur.J.2013, 19, 7203. (59c.)

4). “Triggering the generation of an iron(IV)-oxo compound and its reactivity towards sulfides by RuII

photocatalysis.” J. Am. Chem. Soc, 2014, 136, 4624. (37 c.)

5) “Photo- and electro-catalytic H2 production by new 1st-row transition metal complexes based on an

aminopyridine pentadentate ligand” - Chem. Eur. J. 2014, 20, 6171-6183. (43 c.)

6) “Evidence for an Oxygen Evolution Fe-O-Ce Intermediate in iron-Cat.WO” - Nature Comm.

01/2015; 6:5865. (40 c.)

7) “Cobalt-Copper Dual Light-Driven Catalytic Reduction of Aldehydes and Aromatic Ketones in

Aqueous Media.” Chem. Sci., 2017, 8, 4739

Cover picture

Highlighted in Chemistry World from RSC and ChemistryViews from Wiley

Most downloaded articles of 2017: Energy and Catalysis

8) “Understanding Light-driven H2 Evolution through the Electronic Tuning of Aminopyridine Cobalt

Complexes.” Chem Sci., 2018, 9, 2609.

Editors’ Choice Collection.

Collection to celebrate our diverse and global authorship.

9) “A Highly Active N-heterocyclic Carbene MnI Electrocatalyst for CO2 Reduction.” Angew. Chem.,

2018, 57, 4603.

10) “Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation Catalysts

by Deuteration of Oxidation Sensitive Sites.” J. Am. Chem. Soc. 141, 323

Five patents:

WO/2013/004874, WO/2014/076340, ES2440896B1 and WO2015059337A1

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Section B - Summary of the achievements track-record as an independent researcher

Dr. Julio Lloret Fillol has started a new research group at the ICIQ since November of 2014. Currently, the

working research group is mainly formed by:

Prof. LLORET FILLOL JULIO 20825037D Principal Researcher - CELEX-ICIQ-ICREA

CASADEVALL SERRANO CARLA Ph.D. Student; FPU

CLAROS MIGUEL Ph.D. Student; CELLEX-ICIQ

Michaliszyn Klaudia Ph.D. Student; ERC

Fernandez Sergio Ph.D. Student; FPU

Aragó Jordi Ph.D. Student; FPI

Dubed Bandomo Geyla Caridad Ph.D. Student; ERC

Pascual David Ph.D. Student; ERC

Gutierrez Luis Ph.D. Student; ERC

Dr Noufal Kandoth Juan de la cierva

Dr Federico Franco COFUND EU-ICIQ-IPMP; ERC

Dr Sekhar Mondal Suvendu COFUND EU-ICIQ-IPMP; ERC

Dr. Bucci Alberto A-LEAF

Dr. Martin Vlad ERC

The research lines of the group at the ICIQ are devoted to providing further understanding on mechanism

principles participating in artificial photosynthetic schemes and develop systems for the synthesis of fine

chemicals:

1) Reductive chemistry for the synthesis of fine chemicals and fuels.

I have been awarded with a Consolidator Grant of the European Research Council to develop this project.

a. Water Reduction (WR): We have identified new highly efficient cobalt molecular water reduction

catalysts that operate in both photo- and electrochemical (J. Lloret and co. Chem. Eur. J. 2014, 20,

6171) conditions, with improved performances through electronic tuning of the ligand (> 8500 TON

and 52000 TON/h). We have also unequivocally identified the metal protonation as the rate

determining step of the light-driven H2 evolution mechanism (Chem. Sci., 2018, 9, 2609. This article

is part of the themed collections: Editors’ Choice Collection, Collection to celebrate our diverse and

global authorship). We have taken advantage of the ligand platform versatility to study the effect of

secondary effects in catalysis by developing artificial metalloenzymes. Interesting enough, the

catalytic performance improved upon catalyst encapsulation in streptavidin. We suggested that the

protein pocket aid the delivery of protons over the catalytic center.

b. CO2 Reduction Catalysis (RC): We have also studied the CO2 reduction activity for the same cobalt

complexes and studied the mechanism of action (Under preparation). On the other hand, and in

collaboration with Prof. B. Royo (ITQB, Nova University of Lisbon) we have developed the first

purely organometallic Mn complexes for CO2 reduction. The systems reveal an extraordinary

electrocatalytic CO2 reduction activity even in the absence of protons. Mechanistic insights reveal

proposed intermediates in CO2 reduction such as [Mn(CO)4] [M-OCOH] and [M-H] (Angew. Chem.

Int. Ed. 2018, 57, 4603).

c. Modify electrodes with COFs: We have developed new COFs based on the {Mn(CO)3} motive

characterized by 13C-NMR, IR and EXAFS, with high catalytic activity and good selectivity for CO2

reduction to CO at low overpotential in water at pH 7.5.

d. Reactivity of organometallic complexes: We are also exploring the reactivity of 1st-row transition

metal complexes based on the tripodal C3‐Symmetric HTIM(PR2)3 family of ligands (Eur. J. Inorg.

Chem. 2018, 23, 2612; Cover picture; ICIQ special issue). The systems are catalytically active and

selective for the hydroboration of CO2 to formic acid. Moreover, the nickel derivates are highly active

and selective for the hydrogenation of N-heterocycles.

e. Towards Light-driven Water Reduction Catalysis; Beyond Artificial Photosynthesis: Same cobalt

complexes developed for WR are also active catalyst for the reduction of ketones to alcohols using

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water as a source of H2 and light as the driving source (A. Call and J. Lloret-Fillol Chem Sci, 2017,

8, 4739 (Cover picture) and Chem. Commun. 2018, 9643).

2) Oxidation Chemistry; Water Oxidation Catalysts (WOC).

Water is the most appealing global-scale source of electrons that can be used to store energy into chemical

bonds. However, it is also considered one of the bottlenecks for the development of artificial photosynthesis.

WO needs to be catalyzed in order to proceed at low energy barriers and practical reaction rates. Intermediates

involved in water oxidation are highly unstable, and their characterization is still very challenging (CCR 2017,

334, 2 and book chapters 2018-2019, CV publications 73-74).

a. Well-defined Iron Complexes for WO: in collaboration with Dr. M. Costas: We have discovered

highly efficient homogeneous iron catalysts for WO (Lloret et al. Nat. Chem. 2011, 807-813). These

findings constitute a breakthrough in the field of WOC. Further studies allowed me to suggest two

new intermediates in WO and organic oxidation a FeV=O (Chem. Eur. J. 2012, 18, 13269) and a rare

{Fe-O-Ce} intermediate (Chem. Eur. J. 2013, 19, 8042, Highlighted in Angewandte Chemie and as

Frontispiece). Theoretical studies, carried out in my group, aid me to unravel the mechanism of WO

catalyzed by non-heme iron complexes, the ligand role, and the requirements to develop active

catalysts for WO (Chem. Eur. J. 2014, 20, 5696 and Inorg. Chem. 2014, 53, 5474-5485). Recently, I

have finally characterized the proposed exotic {Fe-O-Ce} intermediate (resonance Raman, EXAFS,

high-field EPR, and Mössbauer) in collaboration with Prof. L. Que and Prof. E. Münck. The discovery

of this heterometallic complex opens the possibility to study in detail the role of the Lewis acid in the

O-O bond formation reaction, mimicking the PSII. (Nature Commun. 2015 NCOMMS-14-03271A)

These results call the attention of Prof. K. Morokuma among others, which embarked in studying

theoretical aspects of the reaction. Also, I have led to the discovery of the reactivity enhancement (100

fold) of an oxo-iron(IV) towards oxygen atom transfer reactions by photochemical irradiation, J.

Lloret-Fillol, and co. JACS 2014 136, 4624. We have also improved 10-fold the water oxidation

catalysts by deuteration of oxidation-sensitive sites. More importantly, this provides the strongest

evidence of a molecular system in the literature (JACS 2019, 141, 323).

b. Well-defined Ruthenium Complexes for WO: We have elucidated the WO mechanism for

homologous Ru complexes (Chem. Eur. J. 2016, 22, 20111). Among the most challenging are the

intermediates located after the O-O bond formation event, which is irreversible and usually the rate

determining step. For this reason, there is no clear experimental information of the reactivity nor the

intermediates after the O-O bond formation event. Fortunately, we have obtained a full

characterization and reactivity of an intermediate located after the O-O bond formation. The

characterized intermediate is better described as a RuIV-peroxo species using spectroscopic (L-edge

XAS, Raman) and spectrometric studies in combination with theoretical calculations (Manuscript in

preparation).

c. Materials. Molecular complexes are convenient platforms for study mechanism of water oxidation.

However, their instability against oxidative damage challenges their technological application. On the

other hand, mix metal oxides (MM’Ox) are extremely robust materials. However, their understanding

is more challenging. In this regard, we are developing synthetic protocols to control wet synthesis

MM’Ox that gives highly active materials which can also serve as model systems for study.

3) Computational Mechanistic Investigation.

We have usually combined experimental and theoretical studies (in collaboration with J. M. Lluis at

UdG) to understand the reaction mechanisms better. Just an example of operative pathways in Ag

catalyzed cross-coupling reactions (Nature Commun 2014).

4) Development of Hight Throughput Experimental Techniques.

In other to accelerate the development of light-driven methodologies we have developed parallel

screening platforms of 24 and 48 reactions under temperature (-80 to 120 ºC) and light intensity control.

A new design provides an anaerobic environment which allows for low-temperature studies. The

irradiation is homogeneous in all reaction positions with a standard deviation lower than 2.5 %. The

system can be calibrated with a convenient toolkit to control all different variables precisely.

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Section C - Extended Curriculum Vitae

C.1. List of Publications since 2010, (* Corresponding author)

2019

77.- “Advances in the Electrochemical Catalytic Reduction of CO2 with Metal Complexes” Federico

Franco, Sergio Fernandez, Julio Lloret-Fillol* Current Opinion In Electrochemistry -Organic and

Molecular Electrochemistry (2019) – Edited by Marc Robert, 2019 In press

76.- “Water Oxidation Catalysis with Well-defined Molecular Iron Complexes” Carla Casadevall,

Alberto Bucci, Miquel Costas,* Julio Lloret-Fillol* Advances in Inorganic Chemistry V 74 on Water

Oxidation Catalysis– Edited by Rudi van Eldik and Colin Hubbard, 2019 In press

75.- “Water Oxidation Catalyzed by First Row Transition Metal Complexes.” Julio Lloret-Fillol,* Miquel

Costas,* Advances in Organometallic Chemistry– Edited by Pedro Perez , 2019 In press

74.- “Visible Light Reductive Cyclization of Unactivated Alkyl Chlorides with Tethered Alkenes” M.

Claros, F. Ungeheuer, F. Franco, V. Martin-Diaconescu, A. Casitas,* J. Lloret-Fillol,* Angew. Chem.

Int. Ed. 2019, DOI: 10.1002/anie.201812702

73.- “Catalytic water oxidation: Water Oxidation to O2 Mediated by 3d Transition Metal Complexes.”

Zoel Codolà, Julio Lloret-Fillol,* Miquel Costas,* in “Non-Noble Metal Catalysis: Molecular

Approaches and Reactions” John Wiley & Sons, 2019 Edited by Bert Klein Gebbink and Marc-Etienne

Moret.

72.- Design of Iron Coordination Complexes as Highly Active Homogenous Water Oxidation

Catalysts by Deuteration of Oxidation Sensitive Sites Zoel Codolà, Ilaria Gamba, Ferran Acuña,

Carla Casadevall, Martin Clémancey, Jean-Marc Latour,Josep M. Luis, Julio Lloret-Fillol* and Miquel

Costas* J. Am. Chem. Soc. 2019, 141, 323.

2018

71.- Enhance and Control of the Selectivity in Light-driven Ketone versus Water Reduction Using

Aminopyridine Cobalt Complexes Arnau Call, and Julio Lloret-Fillol* Chem. Commun. 2018, 9643

70.- Manganese N-Heterocyclic Carbene Complexes for Catalytic Reduction of Carbonyl Groups with

Silanes Mara F. Pinto, Federico Franco, Julio Lloret-Fillol, Beatriz Royo,* ChemCatChem 2018, 10,

2734

Cover Picture

69.- Synthesis and Reactivity of Copper(I) Complexes based on C3-Symmetric Tripodal HTIM(PR2)3

Ligands Ekaterina S. Smirnova, Ferran Acuña-Parés, Eduardo C. Escudero-Adán, Christian Jelsch,

Julio Lloret-Fillol* Eur. J. Inorg. Chem. 2018, 2612

Cover Picture

68.- Spectroscopic and DFT Characterization of a Highly Reactive Nonheme FeV-oxo Intermediate

Ruixi Fan, Joan Serrano-Plana, Williamson N. Oloo, Apparao Draksharapu, Anna Company, Margarida

Borrell, Julio Lloret-Fillol, Yisong Guo,* Emile Bominaar,* Lawrence Que Jr.,* Miquel Costas,*

Eckard Münck,* J. Am. Chem. Soc., 2018, 140, 3916

67.- A Highly Active N-heterocyclic Carbene MnI Electrocatalyst for CO2 Reduction Federico Franco,

Mara F. Pinto, Beatriz Royo,* and Julio Lloret-Fillol* Angew. Chem., 2018, 57, 4603

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66.- Understanding Light-driven H2 Evolution through the Electronic Tuning of Aminopyridine

Cobalt Complexes Arnau Call, Federico Franco, Noufal Kandoth, Sergio Fernandez, Maria Gonzalez,

Julia Perez-Prieto, Josep M. Luis, Julio Lloret-Fillol,* Chem Sci., 2018, 9, 2609

This article is part of the themed collections:

▪ Editors’ Choice Collection.

▪ Collection to celebrate our diverse and global authorship.

65.- Modified High Surface Carbon Fiber Electrode as Efficient Electro-Organocatalytic Material for

Hydrogen Production Octavio Gonzalez del Moral, Arnau Call, Federico Franco, Jose Antonio Nieto-

Rodríguez, María Frias, Sergio Díaz-Tendero, Jose Aleman, Jose L. G. Fierro, Miquel Costas, Julio

Lloret-Fillol, Rubén Mas-Ballesté* Chem. Eur. J., 2018, 24, 3305

64.- Design of Zn-, Cu- and Fe-BPA complexes confined in a self-assembled nanocage via bipyridine

anchoring Cédric Colomban, Vlad Martin-Diaconescu, Teodor Parella, Sébastien Goeb, Cristina

García-Simón, Julio Lloret-Fillol, Miquel Costas, and Xavi Ribas Inorg Chem., 2018, 57, 3529

2017

63.- Cobalt-Copper Dual Light-Driven Catalytic Reduction of Aldehydes and Aromatic Ketones in

Aqueous Media Arnau Call, Carla Casadevall, Ferran Acuña-Parés, Alicia Casitas, and Julio Lloret-

Fillol* Chem. Sci. 2017, 8, 4739

Cover Picture

Most downloaded articles of 2017: Energy and Catalysis

62.- Making and Breaking of the O-O Bond at Iron Complexes Gerard Sabenya, Laura Lázaro, Ilaria

Gamba, Vlad Martin-Diaconescu,* Erik Andris, Thomas Weyhermüller, Frank Neese,* Jana Roithova,*

Eckhard Bill,* Julio Lloret-Fillol,* Miquel Costas.* J. Am. Chem. Soc., 2017, 139, 9168

61.- Making and Breaking of the O-O Bond at Iron Complexes Ilaria Gamba, Zoel Codolà, Julio Lloret-

Fillol,* Miquel Costas,* Coordination Chemistry Reviews 2017, 334, 2

2016

60.- Nuevas estrategias para la conversión de la energía solar en enlaces químicos Zoel Codolà, Arnau

Call, Ferran Acuña-Pares, Julio Lloret Fillol* Anales 2016, 112, 133

59.- Spectroscopic, electrochemical and computational characterization of Ru species involved in

catalytic water oxidation. Evidence for [RuV(O)(Py2Metacn)] intermediate, Carla Casadevall, Zoel

Codola, Miquel Costas, Julio Lloret-Fillol* Chem. Eur. J. 2016, 22, 10111

58.- Water oxidation: High five iron, Julio Lloret-Fillol, Miquel Costas Nature Energy 2016, 137,

10.1038/nenergy.2016.23

2015

57.- Oxidant-Free Au(I)-Catalyzed Halide Exchange and Csp2-O Bond Forming Reactions, J. Serra, C.

J. Whiteoak, F. Acuña-Parés, M. Font, J. M. Luis, J. LloretFillol and Xavi Ribas,* J. Am. Chem. Soc.

2015, 137, 13389

56.- Non-heme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and their Reactivities

Towards Hydrogen- and Oxygen-Atom Transfer Reactions, M. Mitra, H. Nimir, S. Demeshko, S.

Bhat, M. Haukka, J. Lloret-Fillol, G. C. Lisensky, F. Meyer, A. A. Shteinman, W. R. Browne, D. A.

Hrovat, M. G. Richmond, M. Costas, and E. Nordlander* Inorg. Chem. 2015 , 54, 7152

55.- Non-heme Fe(IV) Oxo Complexes of Two New Pentadentate Ligands and their Reactivities

Towards Hydrogen- and Oxygen-Atom Transfer Reactions, Teresa Corona, Florian F Pfaff, Ferran

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Acuña‐Parés, Apparao Draksharapu, Christopher J Whiteoak, Vlad Martin‐Diaconescu, Julio

Lloret‐Fillol, Wesley R Browne, Kallol Ray, Anna Company* Chem. Eur. J. 2015, 21, 15029

54.- H2 oxidation versus organic substrate oxidation in non-heme iron mediated reactions with H2O2

Azin Hassanpour, Ferran Acuña-Parés, Josep M Luis, Olaf Cusso, Silvia Morales de la Rosa, José

Miguel Campos-Martín, Jose LG Fierro, Miquel Costas, Julio Lloret-Fillol, Rubén Mas-Ballesté Chem.

Commun 2015, 51, 14992

53.- Evidence for an Oxygen Evolving Fe–O–Ce Intermediate in Iron-Catalysed Water Oxidation Zoel

Codolà, Laura Gómez, Scott T. Kleespies, Lawrence Que, Jr.,* Miquel Costas* and Julio Lloret-Fillol*

Nature Communications 01/2015, 6:5865

52.- Synergistic Interplay of a Non-Heme Iron Catalyst and Amino Acid Co-Ligands in H2O2

Activation for Asymmetric Epoxidation of a-Alkyl-Substituted Styrenes, O. Cusso, X. Ribas, J.

Lloret-Fillol, and M. Costas* Angew. Chem Int Ed. 2015, 54, 2729

Very Important Paper

2014

51.- Observació directa de cicles redox de Ag (I)/Ag (III) de dos electrons en catàlisi de

funcionalització d’halurs d’aril Marc Font, Ferran Acuña-Parés, Teodor Parella, Jordi Serra, Josep M

Luis, Julio Lloret-Fillol, Miquel Costas, Xavi Ribas Revista de la Societat Catalana de Química 2014

13:40.

50.- Direct observation of two-electron Ag(I)/Ag(III) redox chemistry in silver-catalyzed aryl halide

functionalizations Marc Font, Ferran Acuña-Parés, Teodor Parella, Jordi Serra, Josep M. Luis, Julio

Lloret-Fillol, Miquel Costas, Xavi Ribas* Nature Communications 2014 5:4373

49.- Aryl-Copper(III)-acetylides as key intermediates in Csp2-Csp model couplings under mild

conditions Mireia Rovira, Marc Font, Ferran Acuña-Parés, Teodor Parella, Josep M. Luis, Julio Lloret-

Fillol, Xavi Ribas* Chem. Eur. J. 2014, 20, 10005

48.- Light-Driven Hydrogen Generation: Efficient Copper-Based Water Reduction Catalysts Henrik

Junge, Zoel Codolà, Anja Kammer, Nils Rockstroh, Shu-Ping Luo, Michael Karnahl, Marga-Martina

Pohl, Sebastian Wohlrab, Julio Lloret-Fillol, Miquel Costas, and Matthias Beller* Journal of Molecular

Catalysis A: Chemical 2014, 395, 449

47.- Theoretical Study of the Water Oxidation Mechanism with Non-heme Iron Complexes. Evidence

that the FeIV(O) Species Cannot React with the Water Molecule to Form the O-O Bond Ferran

Acuña-Parés, Miquel Costas, Josep M. Luis* and Julio Lloret-Fillol* Inorg. Chem. 2014, 53, 5474

46.- Aminopyridine Iron and Manganese Complexes as Molecular Catalysts for Challenging

Oxidative Transformations Zoel Codolà, Julio Lloret-Fillol,* Miquel Costas* Book Chapter in

Progress in Inorganic Chemistry 2014, 447-532

45.- Photo- and electro-catalytic H2 production by new 1st row transition metal complexes based on

an aminopyridine pentadentate ligand Arnau Call, Zoel Codolà, F. Acuña-Pares Julio Lloret-Fillol*

Chem. Eur. J.. 2014, 20, 6171

44.- Triggering the generation of an iron(IV)-oxo compound and its reactivity towards sulfides by RuII

photocatalysis Anna Company,* María González-Béjar, Gerard Sabeña, Laura Gómez, Miquel

Costas,* Julia Pérez-Prieto* Julio Lloret-Fillol* J. Am. Chem. Soc. 2014, 4624-4533

43.- Comprehensive Coordination Chemistry III; Small molecule models for non-prophyrinic iron

and manganese oxygenases Anna Company,* Julio Lloret Fillol,* Miquel Costas*, Elsevier, 2014,

V3.18, 487-564.

42.- Unraveling the mechanism of water oxidation catalyzed by non-heme iron complexes F. Acuña-

11

Pares, Z. Codolà, M. Costas, J.M Luis,* J.Lloret-Fillol,* Chem. Eur. J. 2014, 20, 5696

41.- Evidence that Steric Factors Modulate Reactivity of Tautomeric Iron-Oxo Species in

Stereospecific Alkane C-H Hydroxylation Mainak Mitra, Julio Lloret-Fillol, Matti Haukka, Miquel

Costas,* Ebbe Nordlander* Chem. Commun., 2014, 50, 1408 – 1410

2013

40 Highly Stereoselective Epoxidation with H2O2 Catalyzed by Electron-Rich Aminopyridine

Manganese Catalysts Olaf Cussó, Isaac Garcia-Bosch, David Font, Xavi Ribas, Julio Lloret-Fillol,

Miquel Costas* Org. Lett. 2013, 15, 6158-6161

39.- Asymmetric Epoxidation with H2O2 by Manipulating the Electronic Properties of Non-Heme Iron

Catalysts Ofal Cusso, Isaac Garcia-Bosch, Xavi Ribas, Julio Lloret-Fillol, Miquel Costas* J. Am.

Chem. Soc. 2013, 135, 14871

38.- Zirconium Hydrazides as Metallanitrene Synthons: Release of Molecular N2 from a

Hydrazinediido Complex Induced by Oxidative N-N-Bond Cleavage Thorsten Gehrmann, Julio

Lloret Fillol, Heike Herrmann, Hubert Wadepohl and Lutz H. Gade,* Organometallics 2013, 23, 3877-

3889

37.- Oxidation of anticancer Pt(II) monodentate phosphine complexes. Towards stable but active

Pt(IV) prodrugs M. Ángeles Medranoa, A. Álvarez-Valdés, J. Perles, J. Lloret-Fillol, S. Muñoz-

Galván, A. Carnero, C. Navarro-Ranninger, A. G. Quiroga.* Chem. Commun., 2013, 49, 4806

36.- Highly Effective Water Oxidation Catalysis with Iridium Complexes through the use of NaIO4,

Zoel Codolà; João M. S. Cardoso; Beatriz Royo; Miquel Costas; Julio Lloret-Fillol* Chem. Eur. J.

2013, 19, 7203-7213

35.- Electronic Effects on Water Oxidation Iron Catalysts Zoel Codolá, Isaac Garcia, Irene Prat, Miquel

Costas* and Julio Lloret Fillol,* Chem. Eur. J. 2013, 8042–8047

2012

34.- Iron Catalyzed C-H Hydroxylation and Olefin cis-Dihydroxylation with a Single Electron

Oxidant and Water as Oxygen Atom Source Isaac García-Bosch, Zoel Codolà, Irene Prat, Xavi

Ribas, Julio Lloret-Fillol,* Miquel Costas* Chem. Eur. J. 2012, 18, 13269

33.- Synthesis, Characterization and Thermal Rearrangement of Zirconium Tetraazadienyl and

Pentaazadienyl Complexes. Thorsten Gehrmann, Julio Lloret Fillol, Hubert Wadepohl and Lutz H.

Gade* Organometallics 2012, 31, 4504

32.- Domino Reaction Cascades With and Without Bifurcations of Zirconium Hydrazinediido

Complexes with Alkynes Thorsten Gehrmann, Solveig A. Scholl, Julio Lloret Fillol, Hubert

Wadepohl, and Lutz H. Gade* Chem. Eur. J. 2012, 18, 3925 – 3941.

31.- The More Gold – The More Enantioselective: Cyclohydroaminations of γ-Allenyl Sulfonamides

with Mono-, Bis- and Trisphospholane Gold(I) Catalysts Lara-Isabel Rodríguez, Torsten Roth, Julio

Lloret Fillol, Hubert Wadepohl, Lutz H. Gade* Chem. Eur. J. 2012, 18, 3721 – 3728

30.- Alkane C-H Oxidation Catalyzed by Transition Metal Complexes. A. Company,* Julio Lloret,* L.

Gómez,* M. Costas,* Alkane C-H Oxidation Catalyzed by Transition Metal Complexes. Netherlands

Springer Science & Business Media. ISBN: 978-90-481-3697-1. 2012, 142-228

2011

29.- Efficient Water Oxidation Catalysts Based on Readily Available Iron Coordination Complexes.

Julio Lloret Fillol,* Zoel Codolà, Isaac Garcia-Bosch, Laura Gómez, Juan José Pla, Miquel Costas,*

12

Nat. Chem. 2011, 807-813

Identified as Highly Cited Paper by ISI, Highlighted by Nachrichten aus der Chemie,

2011, 59, p.1030, as one of the most important achievements in the chemistry of 2011.

28.- Stitching Phospholanes Together Piece by Piece: New Modular Di- and Tridentate

Stereodirecting Ligands. Julio Lloret Fillol, Achim Kruckenberg, Peter Scherl, Hubert Wadepohl,

Lutz H. Gade* Chem. Eur. J. 2011, 17, 14047-14062.

27.- Zirconium-Catalyzed Multistep Reaction Sequences of Hydrazines with Alkynes: A Non-Fischer

Type Pathway to Indoles. Thorsten Gehrmann, Julio Lloret Fillol, Solveig Scholl, Hubert Wadepohl,

Lutz H. Gade* Angew. Chem., Int. Ed. 2011, 50, 5757

C.2. List of participation in research projects

14.- Light-driven Reductive Chemistry for Solar-Fuels and Solar-Chemicals. (2017 SGR 1647) (2017-

2020) PI. Julio Lloret-Fillol (22.240 EUR).

13.- Reduciones Quimicas Mediadas Por La Luz. De Combustibles A Compuestos Solares. (Ministerio

de Economía Y Competencia, CTQ2016-80038-R) (2017-2020) PI. Julio Lloret-Fillol, (70.000 EUR +

FPI; a 4 y PhD fellowship).

12.- An Artificial Leaf: a photo-electro-catalytic cell from earth-abundant materials for sustainable

solar production of CO2-based chemicals and fuels (HORIZON-2020 - FET Proactive 732840 A-

LEAF) (2017-2020) Coordinator. Jose Ramón Galan Mascaros, (7.980.861 EUR)

11.- Towards a Greener Reduction Chemistry by Using Cobalt Coordination Complexes as Catalysts

and Light-driven Water Reduction as a Source of Reductive Equivalents (ERC-2014-CoG 648304)

(2015-2020) PI. Dr. Julio Lloret Fillol (1.999.063 EUR)

10.- Study of intermediates in catalytic H2 generation with cobalt complexes based on tacn (Diamon

and Electra SINCROTRONS), 2015, measurements and travel expenses, PI: Dr. Julio Lloret-Fillol

9.- Well-Defined Iron Catalysts for Challenging Tasks (Fundação para a Ciência e a Tecnologia,

PTDC/QEQ-QIN/0565/2012) (2013-2015) PI. Dr. Beatriz Royo (148.000 EUR)

8.- Modular Ligands for water splitting (Marie Curie Reintegration Grant, FP7-PEOPLE-2010-RG FP7-

268445) PI Dr. Julio Lloret Fillol (2011/7 – 2014/7) (45.000 EUR)

7.- Design of stereoselective organometallic catalysts base on adaptable ligands through modular and

secondary interactions (Univ. of Girona). MEyC Ramón y Cajal RYC-2009-05409 P.I.: Dr. Julio

Lloret Fillol. (15.000 € + 180.000 € (salary)).

6.- Diseño bioinspirado de catalizadores para la oxidación de enlaces C-H, C=C y agua (Ministerio de

Economia y Competencia CTQ2012-37420-C02-01) PI. Dr. Miquel costas (2013 – 2015) (196.000

EUR + a fellowship PhD)

5- Supramolecular Chemistry applied to the Design, Synthesis and Evaluation of Bioactive

Compounds of Anti-inflammatory, Anti-tumour or Anti-parasitic Action (SUPRAMED)

(CONSOLIDER- CSD2010-00065) PI. Prof. Enrique Víctor García-España Mon; PI(Girona): Dr.

M. Costas (2011 – 2015) (4.000.000 EUR)

4.- Stereoselective Catalysis (SFB623-B6) PI. Prof. Dr. Lutz H. Gade (2009/2 – 2013/2)

3.- Síntesis, Reactividad y Aplicaciones de Complejos Quirales de Rh(II) Soportados con Ligandos

Quirales de Simetria C2. (CTQ2005-08351) PI. Prof. Pascual Lahuerta Peña (2002 – 2005)

2.- Asymmetric Catalysis Using Threefold Symmetry AC3S (HPRN-CT-2001-00187, European net-

work) PI. Prof. Pascual Lahuerta Peña (2002 – 2006)

13

1.- Síntesis y Estudio de la Actividad Catalítica de Nuevos Catalizadores con Ligandos Quirales,

Pinza y C3. Hetereogenización en Matrices Sólidas. (MAT2002-04421-C02-02, MCYT Spanish

Science and Technology Ministry) PI. Prof. Pascual Lahuerta Peña, Universidad de Valencia (2002 –

2005)

C.3. List of invited conferences, meetings and workshops since 2012

61.- CaixaForum Tarragona Química i energia, les fronteres del segle XXI, Tarragona, (Spain) 2019,

March 5th Julio Lloret Fillol and Anna Company Outreach Lecture

60.- 9th International Conference on Advanced Materials and Nanotechnology (AMN9) Wellington, (New

Zealand) 2019, 13th February From Well-defined Coordination Complexes towards Materials for

Artificial Photosynthesis Julio Lloret Fillol Invited Speaker.

59.- Workshop On: Otago Future Fuels (OFF), Dunedin, (New Zealand) 2019, From Well-defined

Coordination Complexes towards Materials for Artificial Photosynthesis Julio Lloret Fillol Plenary

Lecture

58.- CaixaForum Girona Química i energia, les fronteres del segle XXI, Girona, (Spain) 2019, January 29th

Julio Lloret Fillol and Anna Company Outreach Lecture

57.- Workshop On: Solar Fuel Production Based on Nanostructured Photoelectrodes and Catalysts, Braga,

(Portugal) 2018, From Well-defined Coordination Complexes towards Materials for Artificial

Photosynthesis Julio Lloret Fillol Key Note

56.- VI Workshop on Sustainable Chemistry Tools in Green Chemistry – Castellon – 2018 Design of

Catalytic Systems for Photo- and Electrochemical Transformations. On the way to Renewable Fuels

and Chemicals Julio Lloret Fillol Plenary Lecture

55.- Post-ICCC2018 meeting Fukuoka, (Japan) 2018 Light-Driven Reductive Chemistry for Renewable

Fuels and Chemicals. Julio Lloret Fillol Key Note

54.- Post-ICCC2018 meeting Oita, (Japan) 2018, Water Oxidation Catalysis with Well-defined Fe

Complexes Julio Lloret Fillol Plenary Lecture

53.- ICCC2018 Sendai, (Japan) 2018, Towards Light-Driven Reduction. From Solar Fuels to Solar

Chemicals Julio Lloret Fillol Invited Speaker

52.- BIYSC – Tarragona – ICIQ – 2018 Artificial Photosynthesis, From Solar Fuels to Solar Chemicals.

Julio Lloret Fillol Lecture – outreach activity

51.- Metting ECIR – Barcelona 2018 Mechanistic insights into water and CO2 reduction chemistry by

well-define cobalt complexes Julio Lloret Fillol Invited Speaker

50.- University of Sevilla (Spain) 2018, Towards Light-Driven Reduction. From Solar Fuels to Solar

Chemicals Julio Lloret Fillol Lecture

49.- GDR Solar Fuels, Collège de France – Paris (France) 2018. Light-driven Reductions Using Well-

Defined Coordination Complexes; From Solar Fuels to Solar Chemicals Julio Lloret Fillol Plenary

Lecture

48.- Donostia International Physics Center (DIPC) 25th May – Donostia (Spain) 2018 Light-driven

Reductions Using Well-Defined Coordination Complexes; From Solar Fuels to Solar Chemicals Julio

Lloret Fillol Lecture

14

47.- Girona Seminar (Predictive Catalysis, Transition-Metal Reactivity by Design) 2018, Girona (Spain)

Towards Light-Driven Reduction. From Solar Fuels to Solar Chemicals Julio Lloret Fillol Key Note

46.- Gordon Research Conference; Renewable Energy: Solar Fuels – Ventura (USA) 2018, Isolation and

characterization of an elusive Ru(IV) peroxo: A missing link Julio Lloret Fillol Selected poster for

oral presentation

45.- University of Arizona (USA) 2018, Artificial Photosynthesis from Solar Fuels to Solar Chemicals

Julio Lloret Fillol Lecture

44.- Barluenga Lectureship – Oviedo (Spain) 2017, Light-Driven Reduction Chemistry. From Solar Fuels

to Solar Chemicals. Julio Lloret Fillol Plenary Lecture

43.- ISOC - XI edition of the International School of Organometallic Chemistry Organometallic chemistry,

(Italy) 2017. from theory to applications , Artificial Photosynthesis from Solar Fuels To Solar

Chemicals Julio Lloret Fillol Plenary Lecture

42.- University of Oviedo (Spain) 2017. Water oxidation catalysis with well-defined Fe and Ru complexes

Julio Lloret Fillol Lecture

41.- i-Chat Frascati, Roma (Italy) 2017. Catalytic Light-Driven Reductive Transformations Mediated by

Cobalt Complexes Julio Lloret Fillol Oral Lecture

40.- Universidad de Barcelona (Spain) 2017. Towards Artificial Photosynthetic Schemes for Light-Driven

Transformations Julio Lloret Fillol Lecture

39.- ACS-(San Francisco, USA) 2017. Towards Artificial Photosynthetic Schemes for Light-Driven

Transformations Julio Lloret Fillol Oral Presentation

38.- Regensburg University From Solar Fuels to Solar Chemicals Julio Lloret Fillol Lecture

37.- Tutorial at the Graduate school "Chemical Photocatalysis" at Regensburg University MOLECULAR

CATALYSTS FOR WATER SPLITTING, A technological and scientific perspective Julio Lloret

Fillol Lecture

36.- CAIXAFORUM -2017 Lleida, (Spain) Combustibles solares Carla Casadevall, Julio Lloret-Fillol*

Plenary Leture, Outreach Activity

35.- EUCHEMS-2016 (Sevilla, Spain) Catalytic light-driven reduction of water and organic compounds by

well-defined cobalt complexes, Julio Lloret Fillol Oral Presentation

34.- 2nd International Symposium on Chemical Energy Conversion Processes (ISCECP-2) (Fukuoka,

JAPAN) 2016, Water Oxidation catalysts based on aminopyridine ligands Julio Lloret Fillol Key Note

33.- CARISMA - COST – Ljubljana (Slovenia) 2016. Spectroscopic, electrochemical and computational

characterization of Ru species involved in catalytic water oxidation Julio Lloret Fillol Key Note

32.- Pacifichem 2015 – Honolulu (USA) 2015, Aminopyridine ligands as platforms for well-defined Water

Oxidation and reduction catalysis Julio Lloret Fillol Invited Speaker

31.- Universidad de Zaragoza (Spain) 2015, Well-Defined Water Oxidation And Light-Driven Reduction

Catalysts Julio Lloret Fillol Lecture

30.- XII Simposium the Jovenes Investigadores Sigma-Aldrich – Barcelona (Spain) 2015, Aminopyridine

ligands as platforms for well-defined Water Oxidation and reduction catalysis Julio Lloret Fillol

Plenary Lecture

29.- Bienal RSEQ – A Coruña 2015. Aminopyridine Ligands as Platforms for Well-Defined Iron Water

Oxidation Catalysts and Light-Driven Cobalt Reduction Catalysts Julio Lloret Fillol Oral

Presentation

28.- Max Planck Institute for Chemical Energy Conversion 2015, Aminopyridine Ligands as Platforms for

Well-Defined Light-Driven Cobalt Reduction and Iron Water Oxidation Catalysts Julio Lloret Fillol

Lecture

15

27.- Ruhr-Universität Bochum, Young researcher talk 2015, Aminopyridine Ligands as Platforms for

Well-Defined Light-Driven Cobalt Reduction and Iron Water Oxidation Catalysts Julio Lloret Fillol

Lecture

26.- CARISMA COST ACTION – Tarragona (Spain) 2015, Homogeneous Iron-Catalysed Water

Oxidation Julio Lloret Fillol Key Note

25.- EUCHEM 2014 – Istanbul (Turkey) 2014, Aminopyridine ligands as platforms for well-defined Water

Oxidation and reduction catalysis Julio Lloret Fillol Invited Speaker

24.- ISAACS13 – Dublin (UK) 2014, Intermediates in Homogeneous Iron-Catalysed Water Oxidation

Julio Lloret Fillol Oral Presentation

23.- University of Lund 2014 (Sweden), Julio Lloret Fillol Homogeneous Water Oxidation Catalysis with

First Row Coordination Complexes Invited Lecture.

22.- NIS-Colloquium, Photo- and electrochemical Cells for Solar Fuels - Torino (Itali) 2014 Water

Oxidation Catalysis with Nonheme Iron Complexes, Julio Lloret Fillol Invited Lecture

21.- COST ACTION CM1205 CARISMA, Utrecht 2013 (Netherlass) Julio Lloret Fillol. Homogeneous

Water Oxidation Catalysis with Iron Coordination Complexes. Invited Speaker.

20.- Graduate Course at Universidad Nacional Autónoma de Mexico (UNAM, Mexico) 2013 “Catálisis

aplicada a la producción de energía” Oct. 21 - 23 of 2013 (4.5 h) Julio Lloret Fillol Lecture

19.- University of Michigan 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis

with Iron Coordination Complexes. Invited Speaker.

18.- Utah State University 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis with

Iron Coordination Complexes. Invited Speaker.

17.- University of Minnesota 2013 (EEUU) Julio Lloret Fillol. Homogeneous Water Oxidation Catalysis

with Iron Coordination Complexes. Invited Speaker.

16.- SiLQCOM 2013 Huatulco (Pacific coast of Oaxaca, Mexico), 13-17 Octubre del 2013 Julio Lloret-

Fillol* “Mechanistic Insight of Homogeneous Water Oxidation Catalysis with Iron Coordination

Complexes” Invited Speaker.

15.- COST action CM1003 Utrecht 2013 (Nederland) Julio Lloret Fillol. Homogeneous Water Oxidation

Catalysis with Iron Coordination Complexes. Oral Contribution.

14.- 1st Workshop on Advanced Materials for Solar Fuels Applications, Castellón, 11 Febrero del 2012,

Julio Lloret-Fillol* “Mechanistic Insight of Homogeneous Water Oxidation Catalysts with Iron

Coordination Complexes” Invited Lecture.

13.- IX Simposio de Investigadores Jóvenes Zaragoza, 7-10 Noviembre del 2012, Julio Lloret-Fillol*

“Mechanistic Insight of Homogeneous Water Oxidation Catalysts with Iron Coordination Complexes”

Oral Presentation.

12.- ADHOC, International Symposium on Activation of Dioxygen & Homogeneous Catalytic Oxidation

Jerusalem, Israel, 2012, 2-7 Sept. Julio Lloret Fillol,* Zoel Codolà, Isaac Garcia-Bosch, Laura

Gómez, Irene Prat and Miquel Costas,* “Homogeneous Water Oxidation Catalysts with Iron

Complexes” Oral Communication

11.- Invited Lecture Madrid 20-Genuary-2012 Julio Lloret Fillol “Efficient Water Oxidation Catalysts

Based on Readily Available Iron Coordination Complexes” Lecture.

C.4. Patents

16

1.- “Procedimiento de oxidación catalítica de agua mediante catalizadores de hierro” Julio Lloret Fillol, Zoel

Codolà, Isaac Garcia-Bosch, Laura Gómez, Juan José Pla, Miquel Costas P1969ES00, 06/07/2011

(International extended, WO/2013/004874.

2.- “Catalizadores para la epoxidación de alquenos“ Olaf Cusso, David Font Gimbernat, Irene Prat Casellas,

Anna Company Casadevall, Laura Gomez Martín, Xavier Ribas Salamaña, Isaac Garcia Bosch, Julio Lloret

Fillol, Miquel Costas Salqueiro, WO/2014/076340, 13/11/2012.

3.- “Compuesto poliamínicos y complejos metálicos que comprenden para su uso como agentes

antiparasitarios“ Xavi Rivas, Miquel Costas, Olaf Cussó, Anna Company, Julio Lloret, Manual Sánchez,

Clotilde Marín, María Jose Rosales, Francisco Olmo, ES2440896B1, 23/11/2013.

4.- “Compuesto metálicos que comprenden compuestos poliamínicos y dichos compuestos para su uso como

agentes antiparasitarios“ Olaf Cusso, Xavi Rivas, Miquel Costas, Olaf Cussó, Anna Company, Julio Lloret,

Manual Sánchez, Clotilde Marín, María Jose Rosales, Francisco Olmo, ES2439397A1 / WO2015059337A1

23/11/2013.

5.- “Un procedimiento de reducción fotocatalítico y una composición catalizadora utilizada en el

procedimiento” J. Lloret Fillol, A. Call Quintana, C. Casadevall Serrano, A. Casitas Montero.

WO/2018/211154 / PCT/ES2017/070314, 16/05/2017

6.- "Process for the activation of chloride organic compounds and a catalytic composition used in the process

Julio Lloret-Fillol, Miquel Claros, Felix Ungeheuer, Alicia Casitas. Submitted as: EP patent application No:

EP18382332.3, application date 15.05.2018