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www.postersession.com Conclusions Acknowledgements D. Robillard , C. Taylor, T. Smith, J . Brousseau , J. Lofto , B . Johnston Supervised by Sandra Johnstone, as part of GEOL 300: Igneous & Metamorphic Petrology course requirements, Spring 2015 Nanoose Geology Geochemistry Petrography In order to determine the nature of metamorphism, 9 thin sections (7 from 2015; 2 from 2009) were analyzed using petrographic microscopes. Photomicrographs of basalt from each site are shown below in plane polarized light (PPL) and cross polarized light (XPL). Predictions or Comments Similar anomaly at Nankivell Point (as outlined in the 2009 study)? Results show a Karmutsen signature within mapped Sicker Group territory Evidence of contact metamorphism? Hornblende-hornfels-type (contact ) metamorphism adjacent to intrusion Different geochemical signatures proximal to the intrusion? Basalt at Sites 1 & 2 display variable and inconsistent geochemical affinites Sincere thanks to the following contributors: Acme Labs in Vancouver, BC, for geochemical analysis. Vancouver Petrographics in Langley, BC, for thin sections. Students of GEOL300 for their participation in field studies. Sandra Johnstone for her guidance in completing this research. Results suggest that geochemical anomalies at Nankivell Point may be explained through contact metamorphism. Based on geochemical and petrographic observations, we interpret that the basalt as Nankivell Point may represent metamorphosed Sicker Group basalt. However, further sampling is necessary. Recommendations for future research: 1. Produce detailed geologic maps for all three sites. 2. Collect more samples and analyze metamorphic variability closer to and further from the intrusive contact at Nankivell Point 3. Investigate the validity of mapped Karmutsen Fm. at Site 1. Fig. 1. Current BCGS geology map of the Nanoose Peninsula study area. Note the location of 3 sample sites. Site 1 is located at “Ainsley Beach” where Karmutsen Fm. basalt shares a suspected fault-related contact with a quartz-diorite “Island Intrusion” of the Bonanza Arc. Site 2 is located at Nankivell Point where quartz-diorite shares an intrusive relationship with basalt interpreted as part of the Sicker Group [8] . Site 3 is located along Dolphin Beach where Sicker Group pillow basalt is most dominant. Sicker-type-rocks associate with the Nanoose Complex (mapped in blue); however, stratigraphic relationships are unclear; age constraints are broadly Paleozoic [8] . Map derived from BCGS data available at mapplace.ca. Base map modified by Robillard et al. (2015). Field Photos Regional Geology Vancouver Island is mostly of the exotic Wrangellia terrane, which formed during three major volcanic episodes [2] : 1. Sicker Group island - arc volcanism ( 380 - 360 Ma) [8] . These rocks comprise the basement of Wrangellia and are overlain by limestone of the Buttle Lake Group. 2. Karmutsen Fm . ocean - island volcanism ( 230 - 225 Ma) [3] . Karmutsen basalt represents the most widespread unit on Vancouver Island and is overlain by Quatsino Fm. limestone. 3. Bonanza island - arc volcanism ( 202 - 168 Ma) [1] . Bonanza rocks represent the final episode of Wrangellian volcanism and commonly intrude older Wrangellian rocks. Wrangellia collided with North America ~100 Ma [8] . Thus, rock units comprising Wrangellia are commonly folded and faulted. The geology of Nanoose is not well understood [8] . Mafic volcanic rock (i.e., basalt) is currently mapped as Sicker Group in the northeast and Karmutsen Formation (Fm.) in the southeast (Fig. 1). However, a 2009 study by VIU students suggests that Sicker Group basalt at Nankivell Point may actually be part of the Karmutsen Fm. The goal of this research is to investigate an anomalous geochemical result from the 2009 study at Nankivell Point in order to determine if (a) basalt is incorrectly mapped as Sicker Group, or (b) if metamorphism is causing this anomaly. If basalt at Nankivell Point is incorrectly mapped as Sicker Group (and is in fact Karmutsen Fm.), we expect a lack of contact metamorphism in addition to Karmutsen signatures on AFM, MnO/TiO 2 /P 2 O 5 , TAS, and Harker diagrams. If, however, metamorphism is responsible for geochemical anomalies reported in 2009, we expect contact metamorphic mineral assemblages and different geochemical signatures in samples closer to and further from a local intrusive body. 1. Canil, D., Styan, J., Larocque, J., Bonnet, E., & Kyba, J. (2010). Thickness and composition of the Bonanza arc crustal section, Vancouver Island, Canada. Geological Society of America Bulletin, B26578-1. 2. DeBari, S.M., Anderson, R.G., & Mortensen, J.K. (1999). Correlation among lower to upper crustal components in an island arc: the Jurassic Bonanza arc, Vancouver Island, Canada. Canadian Journal of Earth Sciences, 36(8), 1371-1413. 3. Greene, A.R., Scoates, J.S., Weis, D., Nixon, G.T., & Keiffer, B. (2009). Melting history and magma evolution of basalts and picrites from the accreted Wrangellia ocean plateau, Vancouver Island, Canada. Journal of Petrology. 4. Le Maitre, R. W., Streckeisen, A., Zanettin, B., Le Bas, M. J., Bonin, B., & Bateman, P. (Eds.). (2002). Igneous rocks: a classification and glossary of terms: recommendations of the International Union of Geological Sciences Subcommission on the Systematics of Igneous Rocks. Cambridge University Press. 5. Massey, N.W.D. (1995). Geology and mineral resources of the Alberni-Nanaimo Lakes sheet, Vancouver Island: 92F/1W, 92F/2E, 92F/7E. British Columbia, Geological Survey. 6. Massey, N.W.D. (1995). Geology and mineral resources of the Cowichan Lake sheet, Vancouver Island: 92C/16. British Columbia, Geological Survey. 7. Winter, J.D. (2010). Principles of igneous and metamorphic petrology, 2nd Ed. Prentice Hall. 8. Yorath, C.J., Sutherland, A., and Massey, N.W.D. (1999). Lithoprobe, Southern Vancouver Island, British Columbia: Geology, Geological Survey of Canada Bulletin 498. Whole-rock geochemistry for 7 basalt samples (5 from 2015; 2 from 2009 study) was analyzed using inductively coupled plasma mass spectrometry (ICP-MS). These data are compared with published geochemical data [3,5,6,8] on Karmutsen Fm. and Sicker Group rocks. Site 1 hosts 2 different varieties of altered basalt. Further from the intrusion, sulphide-bearing “basalt” is heavily altered and contains some clastic material of unknown composition (Fig. 6). Closer to the contact, typical fine-grained basalt is less oxidized and contains some 2 mm amygdules of calcite and cubic pyrite (Fig. 2). Site 2 also hosts 2 types of altered basalt. Further from the intrusion, brown-hornblende-rich basalt (Fig. 3) contains mineral assemblages that may suggest hornblende-hornfels-facies metamorphism. Close to the intrusion, clinopyroxene is more dominant and overprints twinned plagioclase phenocrysts (Fig. 4). Site 3 showcases dark-green, opaque-rich, plagiophyric pillow basalt (Fig.6). Mineral assemblages (Fig. 5) resemble those characteristic of prehnite-pumpellyite to lower-greenschist-facies metamorphism [7] . Fig. 6. ( ) Alteration and clasts noted in basalt at Site 1. Clastic material is not characteristic of Karmutsen Fm. basalt. ( ) Intrusive contact at Site 2, marked by abundant dykes and felsic veins. ( ) Green pillow basalt at Site 3 is interpreted as part of the Sicker Group. Photos by Sandra Johnstone. Na 2 O + K 2 O Fe 2 O 3 T MgO Derived from more-evolved magma MnO*10 TiO 2 P 2 O 5 *10 0 2 4 6 8 10 12 14 37 42 47 52 57 62 67 72 77 Na 2 O + K 2 O (wt. %) SiO 2 (wt. %) 0 1 2 3 4 5 6 7 8 42 47 52 57 62 67 72 77 Na 2 O (wt. %) SiO 2 (wt. %) 0 5 10 15 20 42 47 52 57 62 67 72 77 Al 2 O 3 (wt. %) SiO 2 (wt. %) 0 2 4 6 8 10 12 14 16 18 20 42 47 52 57 62 67 72 77 CaO (wt. %) SiO 2 (wt. %) 0 5 10 15 20 25 42 47 52 57 62 67 72 77 Fe 2 O 3 T (wt. %) SiO 2 (wt. %) 0 2 4 6 8 10 12 14 16 18 20 42 47 52 57 62 67 72 77 MgO (wt. %) SiO 2 (wt. %) (a) (b) (c) (d) (e) (f) (g) (h) (a) AFM diagram. Sicker Group plots dominantly calc-alkaline, while Karmutsen Fm. plots tholeiitic. Note considerable signature overlap. (b) MnO/TiO 2 /P 2 O 5 diagram. Note distinct separation between Sicker Group and Karmutsen Fm data. Site 1 & 2 samples vary with location. (c) TAS diagram. Boundaries define specific volcanic rock types [4] . Sicker Group data spans various rock types; Karmutsen Fm. plots strongly within the basalt category [4] . No genetic significance implied. (d-h) Harker diagrams. Major oxides are plotted against SiO 2 . Plots show consistent trends. However, notice that overlap is significant. Introduction References Fig. 2. Fine-grained basalt in PPL (left) and XPL (right). Clinopyroxene overprints feldspar laths. Opaques represent Fe-Ti oxides and cubic pyrite. 50 μ m 50 μ m 200 μ m 200 μ m 50 μ m 50 μ m Sicker affinity: Karmutsen affinity: Sicker affinity: Karmutsen affinity: Sicker affinity: Karmutsen affinity: Sicker affinity: Karmutsen affinity: Fig. 3. Brown-hornblende-rich basalt in PPL (left) and XPL (right). Hornblende dominates and crystallizes with glomeroporphyritic style. 50 μ m 50 μ m Fig. 4. Typical fine-grained basalt in PPL (left) and XPL (right). Plagioclase is overprinted by abundant clinopyroxene. Note similarities with Fig. 2. Fig. 5. Quartz-epidote vein in PPL (left) and XPL (right). Also note fibrous pumpellyitean indicator mineral for prehnite-pumpellyite metamorphism [7] . Calc-alkaline Tholeiitic Basalt Data Legend *Note the location of each sample relative to the intrusion Published Data: Sicker Group Karmutsen Formation WELCOME TO NANOOSE PENINSULA Nankivell Point “Ainsley BeachDolphin Beach 1 2 3 1:30,000 1 km Bonanza Arc “Island Intrusions” Sicker-related “Nanoose Complex” Karmutsen Fm. Fault structure Ocean Site number Nanoose Study Area Lantzville Nanaimo Schooner Cove Sicker Group Karmutsen Fm. e pidote a ltered plagioclase hornblende clinopyroxene
Transcript
Page 1: D. Robillard, C. Taylor, T. Smith, J. Brousseau, J. Lofto ... · PDF fileD. Robillard, C. Taylor, T. Smith, J. Brousseau, ... Regional Geology • Vancouver Island is mostly of the

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Conclusions

Acknowledgements

D. Robillard, C. Taylor, T. Smith, J. Brousseau, J. Lofto, B. Johnston

Supervised by Sandra Johnstone, as part of GEOL 300: Igneous & Metamorphic Petrology course requirements, Spring 2015

Nanoose Geology

Geochemistry Petrography

In order to determine the nature of metamorphism, 9 thin sections

(7 from 2015; 2 from 2009) were analyzed using petrographic

microscopes. Photomicrographs of basalt from each site are shown

below in plane polarized light (PPL) and cross polarized light (XPL).

Predictions or Comments

Similar anomaly at Nankivell Point

(as outlined in the 2009 study)?

Results show a Karmutsen signature

within mapped Sicker Group territory

Evidence of contact metamorphism? Hornblende-hornfels-type (contact )

metamorphism adjacent to intrusion

Different geochemical signatures

proximal to the intrusion?

Basalt at Sites 1 & 2 display variable

and inconsistent geochemical affinites

Sincere thanks to the following contributors:

• Acme Labs in Vancouver, BC, for geochemical analysis.

• Vancouver Petrographics in Langley, BC, for thin sections.

• Students of GEOL300 for their participation in field studies.

• Sandra Johnstone for her guidance in completing this research.

Results suggest that geochemical anomalies at Nankivell Point

may be explained through contact metamorphism. Based on

geochemical and petrographic observations, we interpret that the

basalt as Nankivell Point may represent metamorphosed Sicker

Group basalt. However, further sampling is necessary.

Recommendations for future research:

1. Produce detailed geologic maps for all three sites.

2. Collect more samples and analyze metamorphic variability

closer to and further from the intrusive contact at Nankivell Point

3. Investigate the validity of mapped Karmutsen Fm. at Site 1.

Fig. 1. Current BCGS geology map of the Nanoose Peninsula study

area. Note the location of 3 sample sites. Site 1 is located at “Ainsley

Beach” where Karmutsen Fm. basalt shares a suspected fault-related

contact with a quartz-diorite “Island Intrusion” of the Bonanza Arc. Site

2 is located at Nankivell Point where quartz-diorite shares an intrusive

relationship with basalt interpreted as part of the Sicker Group[8]. Site 3

is located along Dolphin Beach where Sicker Group pillow basalt is

most dominant. Sicker-type-rocks associate with the Nanoose

Complex (mapped in blue); however, stratigraphic relationships are

unclear; age constraints are broadly Paleozoic[8]. Map derived from

BCGS data available at mapplace.ca. Base map modified by Robillard

et al. (2015).

Field Photos

Regional Geology

• Vancouver Island is mostly of the exotic Wrangellia terrane,

which formed during three major volcanic episodes[2]:

1. Sicker Group island-arc volcanism (380-360 Ma)[8]. These

rocks comprise the basement of Wrangellia and are overlain

by limestone of the Buttle Lake Group.

2. Karmutsen Fm. ocean-island volcanism (230-225 Ma)[3].

Karmutsen basalt represents the most widespread unit on

Vancouver Island and is overlain by Quatsino Fm. limestone.

3. Bonanza island-arc volcanism (202-168 Ma)[1]. Bonanza

rocks represent the final episode of Wrangellian volcanism

and commonly intrude older Wrangellian rocks.

• Wrangellia collided with North America ~100 Ma[8]. Thus, rock

units comprising Wrangellia are commonly folded and faulted.

The geology of Nanoose is not well understood[8]. Mafic volcanic

rock (i.e., basalt) is currently mapped as Sicker Group in the

northeast and Karmutsen Formation (Fm.) in the southeast (Fig.

1). However, a 2009 study by VIU students suggests that Sicker

Group basalt at Nankivell Point may actually be part of the

Karmutsen Fm. The goal of this research is to investigate an

anomalous geochemical result from the 2009 study at Nankivell

Point in order to determine if (a) basalt is incorrectly mapped as

Sicker Group, or (b) if metamorphism is causing this anomaly.

If basalt at Nankivell Point is incorrectly mapped as Sicker Group

(and is in fact Karmutsen Fm.), we expect a lack of contact

metamorphism in addition to Karmutsen signatures on AFM,

MnO/TiO2/P2O5, TAS, and Harker diagrams. If, however,

metamorphism is responsible for geochemical anomalies

reported in 2009, we expect contact metamorphic mineral

assemblages and different geochemical signatures in samples

closer to and further from a local intrusive body.

1. Canil, D., Styan, J., Larocque, J., Bonnet, E., & Kyba, J. (2010). Thickness and composition of the Bonanza arc

crustal section, Vancouver Island, Canada. Geological Society of America Bulletin, B26578-1.

2. DeBari, S.M., Anderson, R.G., & Mortensen, J.K. (1999). Correlation among lower to upper crustal components in

an island arc: the Jurassic Bonanza arc, Vancouver Island, Canada. Canadian Journal of Earth Sciences, 36(8),

1371-1413.

3. Greene, A.R., Scoates, J.S., Weis, D., Nixon, G.T., & Keiffer, B. (2009). Melting history and magma evolution of

basalts and picrites from the accreted Wrangellia ocean plateau, Vancouver Island, Canada. Journal of Petrology.

4. Le Maitre, R. W., Streckeisen, A., Zanettin, B., Le Bas, M. J., Bonin, B., & Bateman, P. (Eds.). (2002). Igneous

rocks: a classification and glossary of terms: recommendations of the International Union of Geological Sciences

Subcommission on the Systematics of Igneous Rocks. Cambridge University Press.

5. Massey, N.W.D. (1995). Geology and mineral resources of the Alberni-Nanaimo Lakes sheet, Vancouver Island:

92F/1W, 92F/2E, 92F/7E. British Columbia, Geological Survey.

6. Massey, N.W.D. (1995). Geology and mineral resources of the Cowichan Lake sheet, Vancouver Island: 92C/16.

British Columbia, Geological Survey.

7. Winter, J.D. (2010). Principles of igneous and metamorphic petrology, 2nd Ed. Prentice Hall.

8. Yorath, C.J., Sutherland, A., and Massey, N.W.D. (1999). Lithoprobe, Southern Vancouver Island, British

Columbia: Geology, Geological Survey of Canada Bulletin 498.

Whole-rock geochemistry for 7 basalt samples (5 from 2015; 2 from

2009 study) was analyzed using inductively coupled plasma mass

spectrometry (ICP-MS). These data are compared with published

geochemical data[3,5,6,8] on Karmutsen Fm. and Sicker Group rocks.

Site 1 hosts 2 different varieties of altered basalt. Further from the

intrusion, sulphide-bearing “basalt” is heavily altered and contains

some clastic material of unknown composition (Fig. 6). Closer to the

contact, typical fine-grained basalt is less oxidized and contains some

2 mm amygdules of calcite and cubic pyrite (Fig. 2).

Site 2 also hosts 2 types of altered basalt. Further from the intrusion,

brown-hornblende-rich basalt (Fig. 3) contains mineral assemblages

that may suggest hornblende-hornfels-facies metamorphism. Close to

the intrusion, clinopyroxene is more dominant and overprints twinned

plagioclase phenocrysts (Fig. 4).

Site 3 showcases dark-green, opaque-rich, plagiophyric pillow basalt

(Fig.6). Mineral assemblages (Fig. 5) resemble those characteristic of

prehnite-pumpellyite to lower-greenschist-facies metamorphism[7].

Fig. 6. ( ) Alteration and clasts noted

in basalt at Site 1. Clastic material is

not characteristic of Karmutsen Fm.

basalt. ( ) Intrusive contact at Site 2,

marked by abundant dykes and felsic

veins. ( ) Green pillow basalt at Site 3

is interpreted as part of the Sicker

Group. Photos by Sandra Johnstone.

Na2O + K2O

Fe2O3T

MgO

Derived from

more-evolved magma

MnO*10

TiO2

P2O5*10

0

2

4

6

8

10

12

14

37 42 47 52 57 62 67 72 77

Na

2O

+ K

2O

(w

t. %

)

SiO2 (wt. %)

0

1

2

3

4

5

6

7

8

42 47 52 57 62 67 72 77

Na

2O

(w

t. %

)

SiO2 (wt. %)

0

5

10

15

20

42 47 52 57 62 67 72 77

Al 2

O3

(wt. %

)

SiO2 (wt. %)

0

2

4

6

8

10

12

14

16

18

20

42 47 52 57 62 67 72 77

CaO

(w

t. %

)

SiO2 (wt. %)

0

5

10

15

20

25

42 47 52 57 62 67 72 77

Fe

2O

3T

(w

t. %

)

SiO2 (wt. %)

0

2

4

6

8

10

12

14

16

18

20

42 47 52 57 62 67 72 77

MgO

(w

t. %

)

SiO2 (wt. %)

(a) (b)

(c) (d)

(e) (f)

(g) (h)

(a) AFM diagram. Sicker Group plots dominantly calc-alkaline, while

Karmutsen Fm. plots tholeiitic. Note considerable signature overlap.

(b) MnO/TiO2/P2O5 diagram. Note distinct separation between Sicker

Group and Karmutsen Fm data. Site 1 & 2 samples vary with location.

(c) TAS diagram. Boundaries define specific volcanic rock types[4].

Sicker Group data spans various rock types; Karmutsen Fm. plots

strongly within the basalt category[4]. No genetic significance implied.

(d-h) Harker diagrams. Major oxides are plotted against SiO2. Plots

show consistent trends. However, notice that overlap is significant.

Introduction

References

Fig. 2. Fine-grained basalt in PPL (left) and XPL (right). Clinopyroxene

overprints feldspar laths. Opaques represent Fe-Ti oxides and cubic pyrite.

50μm 50μm

200μm 200μm

50μm 50μm

Sicker affinity: Karmutsen affinity:

Sicker affinity: Karmutsen affinity:

Sicker affinity: Karmutsen affinity:

Sicker affinity: Karmutsen affinity:

Fig. 3. Brown-hornblende-rich basalt in PPL (left) and XPL (right).

Hornblende dominates and crystallizes with glomeroporphyritic style.

50μm 50μm

Fig. 4. Typical fine-grained basalt in PPL (left) and XPL (right). Plagioclase

is overprinted by abundant clinopyroxene. Note similarities with Fig. 2.

Fig. 5. Quartz-epidote vein in PPL (left) and XPL (right). Also note fibrous

pumpellyite—an indicator mineral for prehnite-pumpellyite metamorphism[7].

Calc-alkaline

Tholeiitic

Basalt

Data Legend *Note the location of each sample relative to the intrusion

Published Data: Sicker Group Karmutsen Formation

W E L C O M E T O N A N O O S E P E N I N S U L A

Nankivell Point

“Ainsley Beach”

Dolphin Beach

1

2

3

1:30,000

1 km

Bonanza Arc“Island Intrusions”

Sicker-related“Nanoose Complex”

Karmutsen Fm.

Fault structure

Ocean

Site number

Nanoose

Study Area

Lantzville

NanaimoSchooner

Cove

Sicker Group

Karmutsen Fm.

epidote

altered

plagioclase

hornblende

clinopyroxene

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