DECHEMA e.V. - Willkommen — Verbundzentrale des GBV · 18:30 Novel Bronsted acidic ionic liquids...

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1st International Congresson Ionic Liquids (COIL)

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Salzburg, AustriaJune 19-22, 2005

DECHEMA DECHEMA e.V.

1st International Congress on Ionic Liquids (COIL), June 19 - 22, 2005, Salzburg/Austria

Sunday, 19 June 2005 Page

14:15 PLENARY LECTURESeparations using ionic liquids: The challenges of multiple mechanismsR.D. Rogers. V.A. Cocalia, K.E. Gutowski, N.J. Bridges,J.D. Holbrey, The University of Alabama, Tuscaloosa, AL/USA 28

15:00 Comprehensive data retrieval system for ionic liquidsJ.W. Maqee, M. Frenkel, National Institute of Standards andTechnology, Boulder, CO/USA 29

15:30 Application of ionic liquids in industrial hydrosilylation catalysis:A new approachB. Weyershausen, Degussa AG, Essen/D; T.J. Geldbach,P.J. Dyson, EPFL, Lausanne/CH 30

16:00 Chiral ionic liquids as new reaction media for asymmetric synthesisG. Vo-Thanh, B. Pegot, A. Loupy, Paris South University, Orsay/F 31

17:00 Ionic liquids for the application as lubricantsN. Dorr. A. Pauschitz, A. Ecker, F. Franek, AC2T research GmbH,Wiener Neustadt/A 32

17:30 Unusual evolution of catalytic behaviour in polymer-supportedionic liquidsN. Basov, University of Newcastle/UK; A.I. Cooper, CM. Davies,University of Liverpool/UK; R. Jachuk, K. Scott, University of Newcastle/UK;J.L. Xiao, N. Winterton, University of Liverpool/UK 33

18:00 Ionic liquids for storage and delivery of hazardous gasesD.J. Tempel. P.H. Henderson, J.R. Brzozowski, R.M. Pearlstein,J.J. Hart, D. Tavianini, Air Products & Chemicals,Inc., Allentown, PA/USA

18:30 Novel Bronsted acidic ionic liquids based on N-protonatede-caprolactam and their applications in clean acid catalysisS. Guo, Z. Du, Y. Deng. Lanzhou Institute of Chemical Physics/VRC

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TIB/UB Hannover 89127 399 674

1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria

Monday, 20 June 2005 Page

08:30 PLENARY LECTURE

"Cosi fan tutte" ("They all do it") An improved way of "doing it"M. Maase, BASF Aktiengesellschaft, Ludwigshafen/D 37

09:15 Enzyme modification for utilizing biocatalysts in ionic liquidsM. Goto, T. Maruyama, N. Kamiya, Kyushu University, Fukuoka/J 38

09:45 Controlled polymerizations in ionic liquidsP. Kubisa, T. Biedroti, Centre of Molecular and MacromolecularStudies, L6dz/PL 39

10:45 PLENARY LECTURENovel (weakly) basic ionic liquidsD.R. MacFarlane, Monash Univeristy, Clayton Victoria/AUS 40

11:30 Aliquat 336® - a versatile and affordable cation source for anentirely new family of hydrofobic ionic liquidsJ. Mikkola, Abo Akademi University, Turku/FIN 41

12:00 Electrochemical applications of ionic liquids based oncholine chlorideA.P. Abbott, G. Capper, K. McKeiizie, University of Leicester/UK 42

14:00 PLENARY LECTURETask specific ionic liquids: A new generation of soluble supportsfor organic synthesisM. Vaultier, Universite de Rennes/F 43

14:45 Nanocomposite ion-gel electrolyte for dye-sensitized solar cellsH. Matsui. H. Usui, T. Kitamura, N. Tanabe, Fujikura Ltd., Tokyo/J;M. Watanabe, Yokohama National University, Tokyo/J; S. Yanagida,Osaka University, Tokyo/J 44

15:15 Evaluation of a RDC for extraction with ionic liquidsG.W. Meindersma, G.S. Vos, M.B. Klaren, A.B. de Haan,University of Twente, Enschede/NL 45


Tuesday, 21 June 2005 Page


Ionic liquids in catalysis: Some examples of applicationsH. Olivier-Bourbigou, IFP-Lyon, Vernaison/F 46

09:15 Modeling ionic liquids using a systematic all-atom force field.Di-alkylimidazolium and tetra-alkylammonium cations, halide,triflate, bistrisflilamide, nitrate and hexaflurophosphate anionsJ. Canongia Lopes, Technical University of Lisbon/P; A. Padua,University of Blaise Pascal, Clermont-Ferrand/F 47

09:45 Stable membranes involving ionic liquidsC. Oral, Istanbul Technical University/TR; D. Camper, J. Bara,C. Koval, R. Noble, University of Colorado, Boulder, CO/USA 48

10:45 PLENARY LECTURENovel findings and new challenges in the thermodynamicsof ionic liquidsL.P.N. Rebelo, Universidade Nova de Lisboa, Oeiras/P 49

11:30 Airborne nL-droplets of ionic liquids:A new platform for chemical reaction monitoring byRaman spectroscopyB. Lendl, Vienna University of Technology/A; M. Lopez-Pastor,M. Valcarcel-Cases, University of C6rdoba/E 50

12:00 Electrocatalytic synthesis of conducting polyphenylenesin room temperature ionic liquidsD. Yu. Kultin, L.M. Kustov, O.K. Lebedeva, Moscow StateUniversity/RUS; A.V. Ivanov, N.D. Zelinsky Institute of OrganicChemistry, Moscow/RUS 51

14:00 PLENARY LECTUREStrategy and recent results in evaluation of risk potential of ionicliquids: A basis for eco-design of sustainable productsB. Jastorff, University of Bremen/D 52

14:45 Asymmetric electrosynthesis in ionic liquids using chiralpolyaniline electrodesG.G. Wallace. Y. Pornputtkul, L.A.P. Kane-Maguire,University of Wollongong/AUS

15:15 High-pressure phase equilibria of binary and ternary systemsof ionic liquids and supercritical fluidsA. Shariati, K. Gutkowski, C.J. Peters.Delft University of Technology/NL

16:15 Ionic liquids for safe high performance lithium ion batteriesA. Prodi-Schwab. C. Jost, M. Pascaly, Degussa AG, Marl/D;M. Holzapfel, P. Novak, Paul Scherrer Institut, Villigen/CH

16:45 New technologies for ionic liquids productionN.V. Iqnat'ev, U. Welz-Biermann, Merck KGaA, Darmstadt/D

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Wednesday, 21 June 2005 Page


Development of an industrial process for the lewis acid/Iodide salt-catalysed rearrangement of 3,4-epoxy-1-butene to2,5-DihydrofuranS.N. Falling, Eastman Chemical Company, Kingsport, TN/USA 58

09:15 Physicochemical properties of ionic liquids and theirrole in electrochemistry and electrochemical devicesM. Watanabe, Yokohama National University, Japan/J

09:45 Synthesis and its role in the creation of new ionic liquidsJ.H. Davis, University of South Alabama, AL/USA

10:45 Electrochemical deposition of nanostructured metalsand alloys from ionic liquidsH. Natter, R. Hempelmann. University of Saarland, Saarbrucken/D;F. Endres, Technical University of Clausthal-Zellerfeld/D

11:15 Solvation in ionic liquids: conformations, interaction and liquidstructure by molecular simulationA.A.H. Padua, J. Deschamps, University Blaise Pascal, Aubiere/F;J.N. Canongia Lopes, Technical University of Lisbon/P

11:45 Factors influencing liquid/jiquid and solid/liquid phaseseparations in organic/ionic liquid/carbon dioxide mixturesB.R. Mellein, E.M. Saurer, S.N.V.K. Aki, J.F. Brennecke,University of Notre Dame, IN/USA

13:30 PLENARY LECTUREIon-ion and ion-solute interactions in ionic liquidsC. Hardacre, Queen's University of Belfast/UK

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Peculiarity of the liquid/vapour interface of ionic liquidsV. Halka, R. Tsekov, W. Frevland, University of Karlsruhe/D

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New applications of supported ionic liquid-phase (SILP)catalysts in continuous flow processesA. Riisager, R. Fehrmann, Technical University of Denmark, Lyngby/DK;M. Haumann, P. Wasserscheid, University of Erlangen- Nuremberg/D 68

15:45 Structure and activity of Candida antarctica lipase B in ionic liquidsF. van Rantwijk. Delft University of Technology/NL; F. Secundo,Istituto di Chimica del Riconoscimento Molecolare, Milano/I;R.A. Sheldon, Delft University of Technology/NL 69


Development of functional materials based on ionic liquidsH. Ohno, Tokyo University of Agriculture & Technology/J 70


Posterprogramme

Topic ANew ionic liquids - synthesis of ionic liquids

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An oxidizing ionic liquid based on Cr(VI) anionF. Heidarizadeh, A. YarAhmadi, Shahid Chamran University, Ahvaz/IR 72

W-methyl-A/-alkylpyrrolidinium nonafluoro-1-butanesulfonate salts:physical properties and plastic crystal behaviourK.J. Fraser. M. Forstyth, Monash University, Melbourne/AUS;S.A. Forsyth, The Queen's University Belfast/UK; P.C. Howlett,D.R MacFarlane, Monash University, Melbourne/AUS 73

Novel carboxylate ionic liquidsK. Johansson, D.R. MacFarlane, P.J. Newman,Monash University, Melbourne/AUS

New campher derived chiral ionic liquidsP. Gartner, K. Bica, Technical University of Vienna/A

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Investigation of physicochemical properties of novel ionic liquidsO. Korbut, A. Amann, N.V. Ignat'ev, U. Welz-Biermann,Merck KGaA, Darmstadt/D 76

Synthesis and properties of dialkylphosphate ILE. Sitsen, P. Wasserscheid, University of Erlangen-Nuremberg/D 78

Allylimidazolium salts as low viscous room temperature ionic liquidsT. Mizumo. E. Marwanta, N. Matsumi, H. Ohno,Tokyo University of Agriculture &Technology/J 79

Preparation of 1,2,3-Triazoles using ionic liquidsH. Leinonen, M. Lajunen, University of Oulu/FIN 80

Enantiopur thiazolinium salts from the chiral poolD. Bregeon, J. Levillain, University of Caen/F; F. Guillen, J.C. Plaquevent,University of Rouen/F; A.C. Gaumont, University of Caen/F 81

A 10 Ligand modified ionic liquid: application in the carbonphosphorus cross coupling reactionH. Valette, J. Levillain, University of Caen/F; J.C. Plaquevent,University of Rouen/F; A.C. Gaumont, University of Caen/F 82

A 11 Synthesis and phase equilibria of alkyl-(2-hydroxyethyl)-dimethyl-ammonium ionic liquidsR. Bogel-Lukasik, New University of Lisbon, Oeiras/P;U. Domanska-Zelazna, Warsaw University of Technology/PL 83

A 12 Imidazolium-based zwitterions: a "greener" entry to ILs, TSILsand ligandsE. Bouajila, M. Picquet, D. Poinsot, I. Tkatchenko.University of Bourgogne, Dijon/F 84


Topic ANew ionic liquids - synthesis of ionic liquids

A13 Cancelled

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Novel isothiocyanato esters appended to task-specificionic liquid for ionic liquid phase organic synthesis (loLiPOS)methodologyH. Hakkou, J.P. Bazureau, J.J. Vanden Eynde,University of Rennes 1/F 85

1-n-butyl-2,3-dimethylimidazo!ium (BMMI)trichlorogermanate(ll).A superior low oxydation state-IL for the electrodeposition of GeH. Schottenberger, G. Bentivoglio, Leopold- Franzens-University,Innsbruck/A; M. Rauch, G. Winkler, W. Porcham, Swarovski GmbH &Co. KG, Wattens/A; H.-P. Martinz, Plansee AG, Reutte/A; G. Nauer,R. Tvaoi. R. Krendelsberger, ECHEM Center of Competence in AppliedElectrochemistry GmbH, Wiener Neustadt/A 86

From bronsted ionic liquids to coordination polymersZ. Fei. P.J. Dyson, EPFL-BCH, Lausanne/CH

Novel task-specific ionic liquids for CO2 captureA. Vass. University of Veszprem/H; A V£go, MOL Hungarian Oiland Gas Company, Szolnok/H; J, Dudas, E. Pallai-Varsanyi,University of Veszprem/H

Chiral anions for chiral ionic liquids:synthesis and applicationR. Gausepohl. W. Leitner, RWTH Aachen/D

Cancelled

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Liquid structures of two 1,3-dialkylimidazolium bistriflamideionic liquidsD.T. Bowron, Rutherford Appleton Laboratory, Oxon/UK; C. Hardacre,M. Nieuwenhuyzen, O. Sheppard, The Queen's University of Belfast/UK;A.K. Soper, Rutherford Appleton Laboratory, Oxon/UK 91

Kinetic and reaction engineering aspects of IL synthesisA. Grofte Bowing, A. Jess, University of Bayreuth/D

Functionalized ionic liquids for catalysis and spectroscopyR. Giernoth, University of Cologne/D

New ionic liquids incorporating the benzene functional groupE. Tojo, F. Santamarta, J. Tojo, E. Gomez, University of Vigo/E

Synthesis of multiester-appended imidazolium task-specificionic liquidsW.-G. Geng, X.-H. Li, L.-F. Wang, W.-P. Pan, H.-L. Duan,South China University of Technology, Guangzhou/PRC

Synthesis of ionic liquidsP. Chwala, M. Deetlefs, M.J. Earle, S. Forsvth, U. Froehlich,N. Gunaratne, S. Huq, The Queen's University of Belfast/UK

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Topic B PageThermodynamic properties - modelling

B 1 Ternary systems solute-ionic Mquid-scCO2: solute distributionbetween the two phases from supercritical fluid chromatographyJ. Planeta, M. Roth, Academy of Sciences of the Czech Republic,Brno/CZ 98

B 2 Prediction of gas solubility in ionic liquids by molecular simulationI. Urukova, D. Tuma. G. Maurer, University of Kaiserslautem/D 99

B 3 Exploratory molecular modelling studies of interactionsbetween oligomers of cellulose and its derivatives with ionic liquidsB. Derecskei, A. Derecskei-Kovacs. Millennium Chemicals Inc.Research Center, Baltimore, MD/USA 100

B 4 Cancelled

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Thermophysical properties of imidazolium and pyridinium ionic liquidsJ.M. Crosthwaite, University of Notre Dame, IN/USA; M.J. Muldoon,University of St. Andrews/UK; J.K. Dixon, L.J. Ropel, L.S. Belveze,D.G. Hert, P.A. Jefson, G.F. Grubb, J.F. Brennecke, University of NotreDame, IN/USA 101

Improving and understanding the CO2-philicity of ionic liquidsM.J. Muldoon. University of St. Andrews/UK; S.N.V.K. Aki,J.L. Anderson, J.F. Brennecke, University of Notre Dame, IN/USA

Solvent strength effects on the antisolvent ability of CO2 withorganic/IL mixturesB.R. Mellein. L.J. Miller, M.J. Muldoon, S.N.V.K. Aki, J.F. Brennecke,University of Notre Dame, IN/USA

Pure and mixed gas solubilities CO2/IL mixturesS.N.V.K. Aki, D.G. Hert, J.L. Anderson,J.F. Brennecke, University of Notre Dame, IN/USA

B 9 Cancelled

B 10 Liquid phase behaviour of [HMIn][PF6] with alkanesA.B. Pereiro, A. Rodriguez, J. Canosa, J. Tojp. University of Vigo/E

B 11 Application hole theory to the viscosity of ionic liquidsA. Abbott, University of Leicester/UK

B12 Cancelled

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Correlation monitored by NMR between the nature and thestructure of Ionic liquid and the catalytic activity in the isomerisationreaction of 2-methyl-3-butenenitrile to 3-pentenenitrile catalysedby the mixture of Ni(COD)2 and Ph2P(C6H5SO3Na)V. Lecocq, C.C. Santini, Y. Chauvin, J.-M. Basset, CNRS-CPE Lyon,Villeurbanne/F; J.-C. Galland, Rhodia Recherches, St Fons/F 107

Physical properties and vapor- liquid equilibria of the system:1-hexyl-3methylimidazolium chloride ([C6min][CI]) + ethanol + waterE. Gomez, A. Domingez, E. Tojo, J. Toio. University of Vigo/E 109


Topic BThermodynamic properties - modelling

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B 15 The effect of salt additive on the conductivity of quaternaryammonium-based ionic liquidM. Egashira, N. Yoshimoto, M. Morita, Yamaguchi University, Ube/J;J. Yamaki, Kyushu University, Fukuoka/J 110

B 16 The donor and acceptor properties of several room-temperatureionic liquids investigated by redox reaction potentialsM. Yamagata, N. Tachikawa, Y. Katayama, T. Miura,Keio University, Yokohama/J 111

B 17 Thermodynamic phase behaviours of carbon dioxide andhydrofluorocarbons in ionic liquidsA. Yokozeki, M.B. Shiflett, DuPont, Wilmington, DE/USA 112

Synthesis and physico-chemical properties of ionic liquidsE. Bogel-Lukasik. New University of Lisbon, Oeiras/P;U. Domanska-Zelazna, Warsaw University of Technology/PL 113

Determination of gas sorption and mass transfer in ionicliquids by means of a magnetic suspension balanceC. Kern. W. Korth, A. Jess, University of Bayreuth/D 114

Thermodynamics of 1-n-alkyl-3-methylimidazolium bromidesY.U. Paulechka. G.J. Kabo, Belarusian State University, Minsk/BY;E.I. Lozinskaya, AS. Shaplov, Ya.S. Vygodskii,Russian Academy of Sciences, Moscow/RUS 115

Determination of enthalpies of vaporization of ionic liquidsbased on correlations with surface tension and densityG.J. Kabo, Y.U. Paulechka. A.A. Strechan, Belarusian State University,Minsk/BY 116

B 22 Unique solubility and phase transitions of Lewis basic ionic liquidsbased on 1-alkyl-4-aza-1-azoniabicyclo[2.2.2]octane saltsM. Yoshizawa-Fuiita. D.R. MacFarlane, M. Forsyth,Monash University, Clayton/AUS 117

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B23 A free energy-based molecular simulation method forcomputing melting points of ionic liquidsP.M. Eike, E.J. Maginn, University of Notre Dame, IN/USA 118

B 24 Molecular simulation of liquid-liquid equilibria betweenimidazolium-and pyridinium-based ionic liquids and 1-butanolT.I. Morrow, E.J. Maginn, University of Notre Dame, IN/USA 119

B 25 "Anion size" as a new criterion for activating C2-H hydrogenbonding of imidazolium ionic liquids"K. Nobuoka. S. Kitaoka, M. lio, Oita University/J; A. Wakisaka,AIST, Tukuba/J; Y. Ishikawa, Oita University/J 120

B 26 Phase equilibria of binary mixtures containing1,3-dialkylimidazolium ionic liquidsU. Domanska-Zelazna, Warsaw University of Technology/PL 121



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Measurement of the selective sorption on hexafluorophsphateand ethylsulphate (EcoEng 212) in CH4/C02 mixtures up to 13 MPaH.W. Losch. F. Dreisbach, Rubotherm Prazisionsmesstechnik GmbH,Bochum/D; M. Uerdingen, Solvent Innovation GmbH, Cologne/D 122

Thermophysical and thermodynamic characterization of[bmim][BF4] and [bmim][PF6] over an extended P,T rangeJ.M.S.S. Esperanca, R. Gomes de Azevedo, V. Najdanovic-Visak,New University of Lisbon, Oeiras/P; M. Nunes da Ponte, FCT/UNL,Caparica/P; Z.P. Visak, New University of Lisbon, Oeiras/P;H.J.R. Guedes, FCT/UNL, Caparica/P; L.P.N. Rebelo,New University of Lisbon, Oeiras/P 123

Pressure and alkyl chain effects on the thermophysical andthermodynamic properties of [Cn(n=4,6)mim][NTf2]Z.P. Visak. J.M.S.S. Esperanca, R. Gomes de Azevedo, P.F. Pires,New University of Lisbon, Oeiras/P; J. Szydloswski, Warsaw Universityof Technology/PL; H.J.R. Guedes, FCT/UNL, Caparica/P; L.P.N. Rebelo,New University of Lisbon, Oeiras/P 125

A theoretical approach to propose the metabolic pathwayof imidazolium based ionic liquids-selected substances andtheir effects on cell viabilityS. Stolte, J. Ranke, B. Jastorff, Center for Environmental Researchand Technology (UFT), Bremen/D 126

Low-temperature physical properties of 1-butyl-3-methylimidazolium hexafluorophosphate [C4 mim] [PF6] in aglass and crystal statesS.E. Demvanov. L.A. Kurochkin, National Academy of Sciences ofBelarus, Minsk/BY; G.J. Kabo, E.V. Pavlechko, Belarusian StateUniversity, Minsk/BY

Study of water-ionic liquid interactions using mid-infraredspectroscopy and chemometricsM. Lopez-Pastor. University of C6rdoba/E; M.J. Ayora-Canada,University of Jaen/E; B. Lendl, Vienna University of Technology/A;M. Valcarcel-Cases, University of C6rdoba/E,

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Deviations from ideality in mixtures of two ionic liquidswith a common ionH.J.R. Guedes. FCT/UNL, Caparica/P; J.N. Canongia Lopes,T.C. Cordeiro, IST/UTL, Lisbon/P; S. Huq, K.R. Seddon, The Queen'sUniversity of Belfast/UK; L.P.N. Rebelo, New University of Lisbon,Oeiras/P 129

Evidence for phase separation upon temperature increasein ionic liquid solutionsJ. Lachwa. New University of Lisbon, Oeiras/P; J. Szydlowski,A. Makowska, Warsaw University of Technology/PL; J.M.S.S. Espercanca,New University of Lisbon, Oeiras/P; K.R. Seddon, The Queen'sUniversity of Belfast/UK; L.P.N. Rebelo, New University of Lisbon,Oeiras/P 130



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Ionic liquid effects on micellar characteristics of sodiumdodecyl sulfate in aqueous solutionM. Blesic. A. Lopes, L.P.N. Rebelo, New University of Lisbon, Oeiras/P 131

Phase diagram of different [Rmim]CI/lnCI3 ionic liquids andtheir use in Friedel-crafts acylation reactionsJ. Karkkainen, University of Oulu/FIN; M.J. Earle, K.R. Seddon,The Queen's University of Belfast/UK; M.K. Lajunen,University of Oulu/FIN

Electron donor and electron acceptor (EDA) complexes asprobes to determine ionic liquids solvent propertiesC. Chiappe, D. Pieraccini. C.S. Pomelli, University of Pisa/I

Density and viscosity measurement of ionic liquid:influence of temperature and water contentJ. Jacguemin. P. Husson, V. Majer, A.A.H. Padua,University Blaise Pascal, Aubiere/F

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Dynamics and interactions in room temperature ionic liquidsE.W. Castner Jr., H. Shirota, T. Fadeeva, Rutgers University,Piscataway, NJ/USA; A.M. Funston, J.F. Wishart, Brookhaven NationalLaboratory, Upton, NY/USA 135

Conformational states of the 1-n-butyl-3-methylimidazolium cationV.N. Emel'yanenko, G.N. Roganov, Mogilev State University of Foodstaffs,Mogilev/BY; Y.U. Paulechka, Belarusian State University, Minsk/BY 136

Solvation in ionic liquids: conformations, interaction and liquidstructure by molecular simulationA.A.H. Padua, J. Deschamps, University Blaise Pascal, Aubiere/F;J.N. Canongia Lopes, New University of Lisbon, Oeiras/P 137

Diffusion coeffcients of ionic liquids in water and in organic phasesJ. Morel, M.F. Costa Gomes. A.A.H. Padua, University Blaise Pascal,Aubiere/F 138

Solubility of gases in ionic liquidsM. Costa Gomes, P. Husson, J. Jacguemin. V. Majer, A.A.H. Padua,University Blaise Pascal, Aubiere/F 139

Solubility of carbon dioxide in ionic liquids and in ionicliquids-molecular solvent mixturesG. Hong, M. Costa Gomes, P. Husson, University Blaise Pascal, Aubiere/F;M. Deetlefs, C. Hardacre. The Queen's University of Belfast/UK 140

Rare earth iodides in ionic liquidsA. Mudring. A. Babai, R. Giernoth, University of Cologne/D 141

New soft materials? - Strong luminescence of rare earthcompounds in ionic liquidsA. Mudring. A. Babai, R. Giernoth, S. Arenz, University of Cologne/D;K. Binnemans, K. Driessen, P. Nockemann, University of Leuven/B 142

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Solubility and diffusivity measurements of carbon dioxideand hydrofluorocarbons in ionic liquidsM.B. Shiflett. A. Yokozeki, DuPont, Wilmington, DE/USA

Activity coefficients and heats of dilution of organic solventsin ionic liquidsS. Vereykin, A. Heintz, University of Rostock/D; J. Safarov,Azerbaijan Technical University, Baku/AZ; W. Marczak,University of Silesia, Katowice/PL

Liquid-liquid euqilibria, liquid densities and interphase tensionmeasurements in ionic liquid + non-aqueous solvent mixturesA. Heintz, J.K. Lehmann, A. Tschersich, C. Wertz,University of Rostock/D

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Air-liquid interface of ionic liquid-H2O binary system studiedby surface tension measurement and sum-frequency generationspectroscopyJ. Sung, Y. Jeon, D. Kim, Sogang University, Seoul/ROK;T. Iwahashi, T. limori, K. Seki, Y. Ouchi, Nagoya University/J 146

Mixture properties of trialkyl-substituted imidazolium-based ILsY. Andrivko, R. Krendelsberger, G.E. Nauer, ECHEM Center ofCompetence in Applied Electrochemistry GmbH, Wiener Neustadt/A;H. Schottenberger, Leopold-.Franzens-University, Innsbruck/A 147

Gas solubility in imidazolium-based ionic liquids at elevatedpressures up to 10 MPaJ. Kumelan, A. Perez-Salado Kamps, D. Tuma, G. Maurer,University of Kaiserslautern/D 148

IV-SFG studies on the alkyl chain length dependence of air/liquidinterface structure of ionic liquids [CnMIM]BF4

T. Iwahashi, T. Tohyama, K. Kanai, T. limori, K. Seki, Nagoya University/J;D. Kim, Sogang University, Seoul/ROK; Y. Ouchi, Nagoya University/J 149

Study of thermal properties and stability of selected ionic liquidsX.J. Pan, K. Ballerat-Busserolles, P. Husson, J. Jacguemin. UniversityBlaise Pascal, Aubiere/F; A. Mettlem, P. Wasserscheid, University ofErlangen-Nuremberg/D; V. Majer, University Blaise Pascal, Aubiere/F 150

Spectroscopic and electrochemical characterization of niobium(V) andtantalum(V) in ionic liquids 1-butyl-1-methyl-pyrrolidinium-MeCI6 and 1-hexyl-1-methyl-pyrrolidinium-MeCI6 (Me-Nb, Ta)O.B. Babushkina, G.E. Nauer, ECHEM Center of Competence in AppliedElectrochemistry, Wiener Neustadt/A 151

Structure and dynamics of ionic liquids of 1-alkyl-3-methylimidazolium cationsM.C.C. Ribeiro, University of Sao Paulo/BR; S. Urahata,University of South Florida, Tampa, FL/USA 152

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Hydrogen solubility in the system ionic liquid/CO2/H2

T. Hofener. M. Solinas, W. Leitner, RWTH Aachen/D

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A crystal clear perplexing packing puzzleW.A. Henderson, P. Trulove, U.S. Naval Academy, Annapolis, MD/USA;S. Passerini, ENEA, Rome/I; H. De Long, AFOSR, Arlington, VA/USA 154

Phase diagrams of solutions of ionic liquidsW. Schroer, M. Wagner, O. Stanga, D. Saracsan,University of Bremen/D 155

The dielectric constant of imidazolium-based ionic liquidsC. Wakai, M. Ott, A. Oleinikova, H. Weingartner.Ruhr-University of Bochum/D 156

The characterisation of ionic liquidsM. Deetlefs, G. Driver, M.J. Earle, C. Hardacre, S. Huq, I. Nyambiya,W.R. Pitner, N.V. Plechkova, G. Rogers, C. Villagran,The Queen's University of Belfast/UK 157

Derivation of an accurate forcefield for ionic liquid simulationM. Del Popolo, J. Kohanoff, C. Pinilla, R.M. Lynden-Bell, T. Youngs,The Queen's University of Belfast/UK 158

Process development using ionic liquids - Friedel-crafts benzoylationC. Hardacre, D. Milrov. P. Nancarrow, D.W. Rooney, J.M. Thompson,The Queen's University of Belfast/UK 159

The physical properties of ionic liquidsM. Deetlefs. G. Driver, M.J. Earle, B.S. Engel, S. Huq, G. Rogers,K.R. Seddon, The Queen's University of Belfast/UK; M. Shara,The American National History Museum, New York, NY/USA; A. Stark,M.-J. Torres, The Queen's University of Belfast/UK 160

Imidazolium-based ionic liquids: optimized synthesis, eutecticmixtures, and X-ray crystal structures of pure and mixed saltsM. Andre, Sandoz GmbH, Kundl/A; G. Laus, Immodal Pharmaka GmbH,Volders/A; H. Schottenberger, G. Bentivoglio, K. Wurst, U.J. Griesser,R.K.R. Jetti, E. Gstrein, Leopold-Franzen-University, Innsbruck/A 161

Molecular simulation of ionic liquids: predictive determination ofthermophysical properties and phase behaviourC. Cadena, D.M. Eike, T.I. Morrow, J.K. Shah, E.J. Maginn.University of Notre Dame, IN/USA 162

Liquid - liquid behaviour of ionic liquid + alcohol + water andsupercritical CO2-induced phase changesV. Naidanovic-Visak, L.P.N. Rebelo, M. Nunes da Ponte,New University of Lisbon, Oeiras/P 163

Solvent and transport properties of ionic liquids for organic acidsJ. Martak. S. Schlosser, Slovak University of Technology,Bratislava/SK 165

12


Topic CApplications in synthesis / catalysis / biocatalysis

C1 Cancelled

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Studies on synthesis of conducting polymers using roomtemperature melt as an electrolyteS. Geetha, D.C. Trivedi, Central Electro-chemical Research Institute,Karaikudi/IND 167

Phosphine-free carbonylation of olefins into carboxylic acidsin IL mediumA.L. Lapidus, O.L. Eliseev, T.N. Bondarenko, N.N. Styopin,Zelinsky Institute of Organic Chemistry, Moscow/RUS 168

Ionic liquids as solvents for mild and efficient synthesis ofperoxy compoundsS. Baj, A. Chrobok. Silesian University of Technology, Gliwice/PL 169

Sonochemistry in ionic liquids, a novel concept and synergy forpromoting organic transformations at ambient temperature usinga non-thermal energy transfer processK.V. Srinivasan, T. Daniel, National Chemical Laboratory, Pune/IND 170

Room temperature ionic liquids, a novel and green reactionmedia/promoter for the selective synthesis of biologically activeheterocyclesT. Daniel, K.V. Srinivasan, National Chemical Laboratory, Pune/IND 171

Room temperature ionic liquid promoted rapid and efficientsynthesis of fS-enaminones at ambient conditionsT. Daniel, A. Gholap, N. Chakor, R.J. Lahoti, K.V. Srinivasan,National Chemical Laboratory, Pune/IND 172

Continuous hydroformylation of propene using supportedionic liquid phase (SILP) catalystsA. Riisager, S. Flicker, R. Fehrmann, Technical University of Denmark,Lyngby/DK; M. Haumann. B.S.K. Gorle, P. Wasserscheid, University ofErlangen-Nuremberg/D 173

Recyclability of enzymes in ionic liquid solventsL. Gubicza, T. Frater, K. Belafi-Bako, University of Veszprem/H 174

Esterification in ionic liquidsH.-J. Bart, D. Navdenov. Technical University of Kaiserslautem/D 175

Purpose-built ionic liquid solvents for lanthanide reagentsin organic synthesisS. Arenz. R. Giernoth, University of Cologne/D 176

Transition metal catalyzed reactions in purpose-built ionic liquidsR. Giernoth, M.S. Krumm. University of Cologne/D 177

Mechanistic studies on the reactivity of Pt(ll) complexes inimidazolium-based ionic liquidsC.F. Weber. P. Miner, R. Puchta, R. van Eldik, University ofErlangen-Nuremberg/D 178

13

1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria 1st international Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria

Topic C PageApplications in synthesis / catalysis / biocatalysis

C 14 Ionic liquids as protein solventsK. Fuiita. D.R. MacFarlane, M. Forsyth, Monash University,Clayton/AUS 179

C 15 The influence of ionic liquid on the preparation of polythiophenesJ.M. Pringle. M. Forsyth, D.R. MacFarlane, Monash University,Melbourne/AUS; K. Wagner, D.L. Officer, Massey University,Palmerston North/NZ 180

C 16 Solubility and diffusion of gases in ionic liquidsD. Camper. C. Becker, C. Koval, R. Noble, University of Colorado,Boulder, CO/USA 181

C 17 Alkylimidazolium and alkylammonium perhalogenoborates, -phosphates, and -aluminates as solvents and catalysts inreactions of CH-acidsS.G. Zlotin. G.V. Kryshtal, G.M. Zhdankina, E.S. Putilova,Russian Academy of Sciences, Moscow/RUS 182

C 18 Evidences of the organising ability of ionic liquids on therate of the elimination reactionF. D'Anna. V. Frenna, V. Pace, R. Noto, University of Palermo/I 184

C 19 Peptide synthesis in ionic liquidsH. Vallette. L. Ferron, University of Rouen, Mont-Saint-Aignan/F;A.-C. Gaumont, University of Caen/F; J.-C. Plaquevent, Universityof Rouen, Mont-Saint-Aignan/F 185

C 20 Porphyrin preparations utilizing ionic liquidsS. Kitaoka. K. Nobuoka, Y. Ishikawa, Oita University/J 186

C 21 Ionic liquids-the reaction media for metathesis andethenolysis of olefinsA.V. Vasnev. A.A. Greish, L.M. Kustov, Russian Academy of Science,Moscow/RUS 187

C 22 Directing reaction thermodynamics in catalytic processesby use of supported ionic liquidsO. Jimenez. T.E. Muller, J.A. Lercher, Technical University of Munich,Garching/D 188 V

C 23 Comparative behaviour of tantalum-based mesoporouscatalysts in sulfoxidation of pyrimidine thioethers in ionic andmolecular solventsV. Cimpeanu, V.I. Parvulescu. University of Bucharest/RO; C. Hardacre,The Queen's University of Belfast/UK 189

C 24 Novel micro-reactor-systems for the innovative synthesisof ionic liquids (NEMESIS)T.J.S. Schubert, loLiTec GmbH & Co. KG, Freiburg/D 190

14


C 25 Immobilised ionic liquids, supported imidazolium,phosphonium, pyrolidinium and pyridinium saltsA. Tulloch, J. Sharpe, Johnson Matthey Catalysts, Cleveland/UK;E. Modrogan, W. Holderich, RWTH Aachen/D

C 26 Cancelled

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C33

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Chemoselective synthesis of monoalkylated anilinespromoted by ionic liquidsC. Chiappe, P. Piccioli, D. Pieraccini. University of Pisa/I

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Further examples of application of protic imidazoliumsalts in catalytic C-C bond formation reactionsK. Landolsi, F. Bouachir, Faculty of Sciences, Monastir/TN; E. Bouajila,M. Picquet, D. Poinsot, I. Tkatchenko, University of Bourgogne, Dijon/F 193

W-heterocyclic carbenes and phosphorous ylides: their relevanceto understanding the chemistry of imidazolium and phosphorousbased ionic liquidsT. Ramnial, J. Clyburne, Simon Fraser University, Burnaby/CDN 194

Synthesis of functionalized decaboranes and o-carboranesin ionic liquidsU. Kusari, Y. Li, L.G. Sneddon, University of Pennsylvania, Philadelphia,PA/USA; M.G. Bradley, Widener University, Chester, PA/USA 195

Ionic liquid phase technology applied to the synthesis of asmall library of 1,4-dihydropyridines and pyridine-3,5-dicarboxylateJ.C. Legeay, J.P. Bazureau, University of Rennes 1/F 196

Combination of acidic task-specific ionic liquid (TSIL) andmicrowave irradiation applied to Biginelli reactionA. Afran, J.P. Bazureau, University of Rennes 1/F 197

Synthesis of deoxybenzoins in ionic liquids and solvent-freeconditions under microwave irradiationU. Hakala. K. Wahala, University of Helsinki/FIN 198

Catalytic Friedel-crafts acylation: beneficial combinationof ionic liquids with supercritical carbondioxideF. Zaved. RWTH Aachen/D; P. Schulz, University of Erlangen-Nuremberg/D;L. Greiner, RWTH Aachen/D; P. Wasserscheid, University of Erlangen-Nuremberg/D; W. Leitner, RWTH Aachen/D 199

Azocoupling reaction of 2-naphthol withsubstituted benzenediazonium salts in [bmim]+[BF4]"'. Hanusek. V. Machacek, University of Pardubice/CZ; A. Lycka,Research Institute for Organic Syntheses, Pardubice/CZ

Kinetic resolution of cyclic secondary and tertiary alcohols byUpases in ionic liquidsM. Paris, L. Scarpelli, A. Sega, A. Solinas, M. Taddei,University of Siena/I

15

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Synthesis in ionic liquidsA. Brennan, S. Doherty, M.J. Earle. P. Goodrich, C. Hardacre,J.D. Holbrey, S.P. Katdare, P.B. McCormac, A. Ramani, K.R. Seddon,The Queen's University of Belfast/UK 202

Catalysis in ionic liquidsM.J. Earle, C. Hardacre, J. Karkkainen, S.P. Katdare, B.J. McAuley,N.V. Plechkova, A. Ramani, J.M. Thompson, M. Faneslow,The Queen's University of Belfast/UK 203

Working towards ,,lab-on-a-chip" in ionic liquidsA. Brennan, P. Goodrich, C. Hardacre, The Queen's University ofBelfast/UK; B. O'Sullivan, University of Sheffield/UK; D.W. Rooney, TheQueen's University of Belfast/UK; P. Styring, University of Sheffield/UK 204

Reaction engineering at the QUILL research centreK. Anderson, A. Brennan, P. Goodrich, C. Hardacre, D. Milroy,E.A. Mullan, P. Nancarrow, D.W. Rooney, J.M. Thompson.The Queen's University of Belfast/UK

Applications of ionic liquids to solid-supported reactions inthe synthesis of natural and modified oligomersM.J. Earle, M. Gilea. K.R. Seddon, J.S. Vyle, The Queen's Universityof Belfast/UK

C 42 Cancelled

C 43 Synthesis of ionic liquidsP. Chwala, M. Deetlefs, M.J. Earle, S. Forsvth, U. Froehlich,N. Gunaratne, S. Huq, The Queen's University of Belfast/UK

C 44 Improving and understanding the CO2-philicity of ionic liquidsM.J. Muldoon. University of St. Andrews/UK; S.N.V.K. Aki,J.L. Anderson, J.F. Brennecke, University of Notre Dame, IN/USA

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Topic DApplications in separation

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Stable nanostructures with lyotropic liquid crystals and ioniciquids for gas separationsJ. Bara, D. Camper, D. Gin, C. Koval, R. Noble,University of Colorado, Boulder, CO/USA

Molecular structure effects on CO2 absorption in roomtemperature ionic liquidsL. Galan Sanchez, J. Ribe Espel, G.W. Meindersma, A.B. de Haan,University of Twente, Enschede/NL

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Microwave-assisted extraction of pyrene into RTILsK.S. Khachatrvan, Lomonosov Moscow State University/RUS;I.V. Kubrakova , Vernadsky Institute of Geochemistry and AnalyticalChemistry, Moscow/RUS; A.A. Formanovski, I.V. Pletnev, LomonosovMoscow State University/RUS 212

Ionic liquids as extraction solvents and analysis media fordetermination of organic compoundsI. Pletnev, S. Smirnova, K. Khachatryan, N. Shvedene,Lomonosov Moscow State University/RUS 213

Extraction-voltammetric determination of phenols andcatecholamines using RTILsK.S. Khachatryan, N.V. Shvedene, M. Yu. Nemilova, I.V. Pletnev,Lomonosov Moscow State University/RUS 214

Extraction of organic compounds into imidazolium RTILsK.S. Khachatryan, S.V. Smirnova. I.I. Torocheshnikova, I.V. Pletnev,Lomonosov Moscow State University/RUS 215

Extraction with ionic liquids at UFT BremenS. Ziegert, M. Schluter, B. Jastorff, J. Thoming. Center forEnvironmental Research and Technology (UFT), Bremen/D 216

Supercritical carbon dioxide as extraction medium forreaction mixtures containing ionic liquidsA. Hebach. N. Dahmen, A. Oberhof, E. Ember, O. Walter,Research Center Karlsruhe/D , 217

Citrus essential oil terpenless by liquid-liquid extractionusing ionic liquidsA. Arce. P. Casais, H. Rodriguez, O. Rodriguez, A. Soto,University of Santiago de Compostela/E 218

Effect of anion fluorination in ionic liquids as solvents forthe liquid extraction of alcohols from ethersA. Arce. P. Lopez, H. Rodriguez, O. Rodriguez, E. Rodil,A. Soto, University of Santiago de Compostela/E 219

Ionic liquids: breaking azeotrops efficiently byextractive distillationY. Beste. M. Eggersmann, H. Schoenmakers,BASF Aktiengesellschaft, Ludwigshafen/D 220

17

1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria 1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria

Topic DApplications in separation

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The separation of hexene isomers using ionic liquidsW. Fei. J.Q. Zhu, J. Chen, Tsinghua University, Beijing/PRC

Measurement of the partition coefficient of tetracycline andoxytetracycline in biphasic water + ionic liquid systemsA. Arce, A. Soto, University of Santiago de Compostela/E;M. Khoshkbarchi, Aspen Technology, Calgary/CDN

Evaluation of a rotating disc contactor (RDC) for extractionwith ionic IquidsG.W. Meindersma. G.S. Vos, M.B. Klaren, A.B. de Haan,University of Twente, Enschede/NL

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Application of ionic liquids in aqueous capillary electrophoresisM.P. Marszall. M.J. Markuszewski, R. Kaliszan, P. Stepnowski,Medical University of Gdansk/PL 224

Mechanism of lanthanoid ion transfer into hydrophobicionic liquids: evidences of cation exchangeN. Kozonoi, M. Otsuka, Shibaura Institute of Technology, Tokyo/J;K. Mizuoka, Y. Ikeda, Tokyo Institute of Technology/J 225

Topic EApplications in electrochemistry

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Electrochemical synthesis and cycling of conductingpolymers in ionic liquidsJ.M. Pringle. M. Forsyth, D.R. MacFarlane,Monash University, Melbourne/AUS

Electrochromic application of eutectic mixture ionic liquidsJ.S. Oh, B.B. Lee, J.D. Park, S.J. Moon,LG Chemical Ltd., Daejeon/ROK

Novel ionic liquid based electrolytes for dye-sensitizedsolar cells-characterization & assessment of qualityD. Gerhard. S. Himmler, P. Wasserscheid,University of Erlangen-Nuremberg/D

Co-deposition of Al-Cr-Ni Alloys in AICI3-EMIC ambienttemperature molten saltM. Ueda, H. Ebe, T. Ohtsuka, Hokkaido University, Sapporo/J

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Insertion of lithium into graphite in a room-temperature ionic liquidthrough a solid-electrolyte interface filmY. Katavama. T. Morita, T. Miura, Keio University, Yokohama/J 231

Preparation of nanofiberic polymer electrolyte based onionic liquid using electrospinningC.K. Lee. I.Y. Kim, S.I. Kim, S.J. Kim, Hanyang University,Seoul/ROK 232

Ionic liquids in ion-selective electrode membranesD.V. Chernvshov, N.V. Shvedene, M.Yu. Nemilova, R.I. Abdraeva,V.E. Baulin, I.V. Pletnev, Moscow State University/RUS 233

Application of the ionic liquids in the charge transfer acrossinterface between two immiscible electrolyte solutionsV. Sviridov. N.V. Shvedene, I.V. Pletnev, N.K. Zaitsev, LomonosovMoscow State University/RUS; S.V. Shorin, Gubkin RussianState University of Oil and Gas, Moscow/RUS 234

Conductivity measurement of ionic liquids at low andambient temperaturesW. Korth. C. Kern, A. Jess, University of Bayreuth/D 235

Electrolytic conductivity of four imidazolium-basedroom-temperature ionic liquids and the effect of a water impurityJ.A. Wideoren. J.W. Magee, National Institute of Standards and Technology,Boulder, CO/USA; K.N. Marsh, University of Canterbury, Christchurch/NZ;E.M. Saurer, University of Notre Dame, IN/USA 236

Giant increase of the electrical conductivity in aqueoussolutions of ionic liquidsJ. Vila, P. Gines, E. Jimenez, O. Cabeza, University of Coruna/E 237

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Topic E PageApplications in electrochemistry

E 12 Proton conduction mechanism in zwitterionic liquidsM. Yoshizawa-Fuiita. D.R. MacFarlane, N. Byrne, M. Forsyth,Monash University, Clayton/AUS; H. Ohno, Tokyo Universityof Agriculture & Technology/J 238

E 13 Electrochemical preparation of chiral polyaniline in ionic liquidsY. Pornputtkul. L.A.P Kane-Maguire, G.G. Wallace,University of Wollongong/AUS 239

E 14 Intercalation of ammonium ions into a graphite electrodeT. Matsui, M. Deguchi, H. Yoshizawa, Matsushita Battery Ind.Co., Ltd., Moriguchi City, Osaka/J 240

E15 Cancelled

E16

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E23

Topic EApplications in electrochemistryP 24 Novel ionic liquids based electrolytes for dye-sensitized solar

cells - synthetic strategies and ionic liquid cocktailsS. Himmler, D. Gerhard, P. Wasserscheid,University of Erlangen-Nuremberg/D

Topic FApplications in analytics

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248

Electrochemical studies on the contrasting diffusionalbehaviour of A/,JV,/V',N-Tetraalkyl-para-phenylenediamine,its radical cation and dication in room temperature ionicliquids and acetonitrileR.G. Evans. O.V. Klymenko, R.G. Compton, University of Oxford/UK 241

Electrochemical stability of selected ionic liquids-dependencieson electrode materials, additives and impuritiesA. Bosmann. T.J.S. Schubert, loLiTec GmbH & Co. KG, Freiburg/D 242

Nanoscale electrodeposition from ionic liquidsC.L.R. Aravinda, D. Borissov, W. Frevland, O. Mann,University of Karlsruhe/D 243

Novel Ionic liquid-based electrolytes and precursor compositesas basic concept for the traceless electrodeposition of metals,refractive metals and related materialsG. Nauer, R. Krendelsberger, R. Tyagi, ECHEM Center of Competence inApplied Electrochemistry GmbH, Wiener Neustadt/A; H. Schottenberger,G. Bentivoglio, Leopold-Franzens-Universitat, Innsbruck/A; M. Rauch,G. Winkler, W. Porcham, Swarovski GmbH & Co KG, Wattens/A;H.-P. Martinz, Plansee AG, Reutte/A 244

Cancelled

Electrochemistry of copper in imidazolium based ionic liquidsR. Tvaoi. R. Krendelsberger, R. Sonnleitner, C. Stacker, G.E. Nauer,ECHEM Center of Competence in Applied Electrochemistry GmbH,Wiener Neustadt/A 245

Electrochemical reduction of oxygen and carbon dioxidein room temperature ionic liquids and the opportunities forgas sensingM.C. Buzzeo. O.V. Klymenko, R.G. Compton, University of Oxford/UK 246

Electrochemistry of reactive metal electrodes in roomtemperature ionic liquidsP.C. Howlett, D.R. MacFarlane, M. Forsyth, Monash University,Melbourne/AUS 247

F1

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F4

Advanced NMR techniques for use in ionic liquidsR. Giernoth, D. Bankmann. University of Cologne/D 250

Ion selective electrodes as a tool for the determination of theionic liquid solubility in waterN.V. Shvedene, V.V. Sviridov, E.R. Ismailova, I.V. Pletnev, LomonosovMoscow State University/RUS; A.A. Formanovsky, Shemyakin-OvchinnikovInstitute of Bioorganic Chemistry, Moscow/RUS 251

Radiolytic studies of fast reactions in ionic liquidsJ F Wishart, A.M. Funston, T. Szreder, Brookhaven NationalLaboratory, Upton, NY/USA 252

Identification of new applications of ionic liquids:cleaning additives & chemical sensorsA. Bosmann, T.J.S. Schubert, loLiTec GmbH & Co. KG, Freiburg/D 253

$ 5 Ion chromatography - a powerful tool for the quality controlof ionic liquidsT.J.S. Schubert, A. Bosmann, loLiTec GmbH & Co. KG, Freiburg/D 255

256

,•••- F 6 Ionic mesomorphic liquids: their properties and application for"'*• developing novel photorefractive materials•V; T.A. Mirnaya, S.V. Volkov, Institute of General and Inorganic

Chemistry, Kiev/UA

¥ 7 Development of an LC/MS analytical procedure for ionic liquidswith emphasis on phosphonium ionic liquidsT.T. Chang. Cytec Industries Inc., Stamford, CT/USA; M.J. Piquette,Cytec Industries Inc., Stamford, CT/USA; D. Nucciarone, I. Wiater-Protas,Cytec Canada Inc., Niagara Falls, Ontario/CDN 257

Ionic liquids as advantageous solvents for head-space gaschromatography of compounds with low vapor pressureM. Andre. J. Loidl, Sandoz GmbH, Kundl/A; G. Laus, Immodal PharmakaGmbH, Volders/A; H. Schottenberger, G. Bentivoglio,K. Wurst, Leopold-Franzens-University, Innsbruck/A 258

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Topic GEnvironmental issues, texicology

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Environmental behaviour of ionic liquids biodegradationof 1-butyl-3-methylimidazolium tetrafluoroborateS. Kumar. W. Ruth, U. Kragl, B. Sprenger, University of Rostock/D 260

Cytotoxicity and possible mechanisms for the inductionof apoptosis by imidazolium ionic liquidsC. Schmidt, D. Beyersmann, University of Bremen/D 261

Quantitative structure-property modelling of ionic liquid aquatictoxicity: insight into structural features that determine toxicity fordaphnia magna and vibrio fischeriD.J. Couling, P.M. Eike. J.F. Brennecke, E.J. Maginn,University of Notre Dame, IN/USA 262

Energetic, environmental and economic balances:spice up your ionic liquid research efficiencyA. Stark. D. Kralisch, G. Kreisel, B. Ondruschka,Friedrich-Schiller-University, Jena/D 263

Toxicity and biodegradability of imidazolium and pyridiniumionic liquidsK.M. Dochertv, R.J. Bernot, G.A. Lamberti, C.F. Kulpa, J.F. Brennecke,University of Notre Dame, IN/USA 264

Ionic liquids in soil: effects and exposure on an imidazoliumIL on the springtail folsomia Candida (Collembola) in comparisonto a quaternary ammonium compoundT. Juffernholz. K. Thiele, University of Bremen/D 265

Last Minute Poster Page

LM 1 Grandfather imidazolium salts stimulate new combinatorial conceptsfor task-specific functionalized RTILsG. Laus. E. Kristeva, J. Schutz, H. Schottenberger, G. Bentivoglio,W. Klotzer, J. Stadlwieser, Leopold-Franzens-University, Innsbruck/A;H. Sixta, Lenzing AG, Lenzing/A 267

LM 2 Cation-anion interactions in imidazolium halidotelluratesS.M. Narhi, J. Karkkainen, J. Asikkala, R. Oilunkaniemi, R.S. Laitinen,M.K. Lajunen, University of Oulu/FIN 268

LM 3 Liquid-liquid equilibrium in binary systems 1-Butyl-3-methylimidazoliumhexafluorophosphate + water and 1-Butyl-3-methylimidazoliumhexafluorophosphate + 1 -butanol by the volumetric methodM. Bendova, I. Wichterle, Academy of Sciences of the Czech Republic,Prague/CZ 269

LM 4 What can we learn about nature of cation...anion interactions in crystalsof ionic liquids?D.G. Golovanoy, K.A. Lyssenko, M.Yu. Antipin, A.S. Shaplov,Ya.S. Vygodskii, E.I. Lozinskaya, Institute of Organoelement Compounds,Moscow/RUS 270

LM 5 Free radical alternating copolymerization of vinyl acetate andhalogen ring-substituted methyl-2-cyano-3-phenyl-2-propenoatesin ionic liquidsG.B. Kharas. C.A. Diener, X. Tian, DePaul University, Chicago, IL/USA 271

LM 6 Corrosion behaviour of ionic liquidsM. Uerdingen, C. Treber, Solvent Innovation GmbH, Cologne/D;M. Balser, Aachen University of Technology/D; C. Werner, Enthone GmbH,Langenfeld/D; G. Schmitt, Iserlohn University of Applied Sciences/D 272

LM 7 [EMIM][EtSO4] - a toxicologically fully investigated ionic liquidC. Hilgers. M. Uerdingen, Solvent Innovation GmbH, Cologne/D;B. Weyershausen, Degussa AG, Essen/D 273

LM 8 3-Picoline - an excellent precursor for ionic liquidsR. van Hal. M. Uerdingen, Solvent Innovation GmbH, Cologne/D 274

LM 9 Application of ionic liquids in palladium catalyzed homogenoustransfer hydrogenationZ. Baan. Budapest University of Technology and Economics/H;Z. Finta, Chinoin Pharmaceutical and Chemical Works Ltd., Budapest/H;Gy. Keglevich, Budapest University of Technology and Economics/H;I. Hermecz, Chinoin Pharmaceutical and Chemical Works Ltd.,Budapest/H 275

LM 10 Anomaly of charge transport of an iodide/tri-iodide redox. (, couple in an ionic liquidI* R. Kawano. M. Watanabe, Yokohama National University/J 276

i? LM 11 Experimental determination of density of room temperature%. ionic liquids using tube vibrating densimeter». Y.A. Sanmamed, D. Gonzalez-Salgado. C.A. Cerdeirifia, J. Troncoso,If. L. Romani, University of Vigo, Ourense/E 277

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LM 12 Ionic liquids as templates for the fabrication of nanostructured materialsH. Kaper, B. Smarsly, M. Antonietti, MPI of Colloids and Interfaces,Potsdam/D 279

LM 13 Free-radical copolymerization of donor/acceptor systems inionic liquidsG. Schmidt-Naake, I. Wocht, M. Drache, Technical University of Clausthal,Clausthal-Zellerfeld/D 280

LM 14 Copolymerisation of ionic liquid monomersC. Schmidt. F. Merz, G. Schmidt-Naake, Technical University ofClausthal, Clausthal-Zellerfeld/D 282

LM 15 Organic reactions catalysed by 2-tosylamidocarbonyl-L-prolinein ionic liquidsM. Meciarova, S. Toma, Comenius University, Bratislava/SK; B. Koch,A. Berkessel, University of Cologne/D 284

LM 16 A new concept in continuous Friedel-Crafts alkylation usingacidic ionic liquids in a loop reactorP. Wasserscheid, N. Brausch, N. Hofmann, University of Erlangen-Nuremberg/D 286

LM 17 A quasi-solid-state redox electrolyte based on R'R"lm+l-ionic liquid trimethoxysilane derivateV. Jovanovski, A. Surca Vuk, R. Jese, S. Hocevar, B. Orel,National Institute of Chemistry, Ljubljana/SLO 287

LM 18 Efficient phase transfer of cationic quantum dots into ionic liquidsT. Nakashima. T. Kawai, Nara Institute of Science and Technology/J 288

LM 19 Solubility of carbon dioxide in systems with [BMIM][BF4] andsome selected organic compoundsE. Kuhne, J. van Spronsen, G.J. Witkamp, C.J. Peters,Technical University of Delft/NL 289

LM 20 A quasi-solid-state redox electrolyte based on R'R"lm+l- ionic liquidtrimethoxysilane derivate

29^V. Singh. V. Srivastava, Thapar Institute of Engineering & Technology,Patiala/IND; M. Vaultier, University of Rennes/F

LM 21 Behavior of the immobilized penicillin G amidase in ionic liquidsC. Ebert, A.. Basso, S. Cantone, P. Linda, University of Trieste/I 291

LM 22 Baeyer-Villiger oxidation of cycloalkanones in ionic liquidswith Pt catalystsV. Conte, B. Floris, P. Galloni, V. Mirruzzo, University of Rome/I;G. Strukul, University of Venice/I 293

LM 23 High efficiency methanol carbonylation process utilizing a gasstripped reactor and ionic liquid catalyst systemG. Tustin, Eastman Chemical Company, Kingsport, TN/USA 294

LM 24 Chiral ionic liquids as new reaction media for asymmetric synthesisB. Pegot. G. Vo-Thanh, A. Loupy, Paris South University, Orsay/F 295


Last Minute Poster

LM 25 Electrochemistry of aluminum in ionic liquidsV. Kamavaram, G. Ramana Reddv, The University of Alabama,Tuscaloosa, AL/USA

Page

296

LM 26 Application of ionic liquid as thermal storage & heat transfer mediaM. Zhang, V. Kamavaram, G. Ramana Reddv. The University ofAlabama, Tuscaloosa, AL/USA 297

LM 27 Oxidation and oxybromination reactions with peroxo metalcomplexes in ionic liquidsV. Conte, B. Floris, P. Galloni, A. Silvaoni, University of Rome/I 298

LM 28 Ionic liquids based on trialkylsylfonium halides and aluminiumor gallium chlorides - potential electrolytes for dye-sensitizedsolar cellsM. Gorlov. A. Hagfeldt, L. Kloo, Royal Institute of Technology,Stockholm/S 299

LM 29 Quantum chemical aided design of ionic liquids as electrolytesfor the electrodeposition of metalsM. Kroon, Delft University of Technology/NL; W. Buijs, C.J. Peters,Delft University of Technology, DelftChemTech (PCMT)/NL;G.J. Witkamp, Delft University of Technology/NL 300

LM 30 Hydrogen solubility in [BMIM][BF4] and the effect of CO2 andthe hydrogenation catalyst ((R,R)-Me-DuPHOS)Rh(COD)BF4 onthe hydrogen solubilityV.A. Toussaint, L.J. Florusse, C.J. Peters, Delft University of Technology,DelftChemTech (PCMT)/NL 301

LM 31 N,N,N',N',N",N"- hexaalkylguanidinium salts as new innovativeionic liquidsW. Kantlehner. R. Kreli, J. Mezger, E.V. Stoyanov, FH Aalen/D 302

LM 32 Ionic liquids as reaction medium in cellulose functionalizationS. Barthel. K. Schwikal, T. Heinze, University of Jena/D 303

LM 33 Ionic liquids: design, preparation and application to "green" chemistryL. Melki. N. Greenspoon, S. Guernik, Chemada Fine Chemicals,Nir Itzhak/IL; L. Gurewitz, A. Mementov, R. Macievich, S. Grinberg,S. Geresh, Ben Gurion University, Beer Sheva/IL 304

LM 34 Lability of imidazolium ring hydrogens. Study of isotopicexchanges in d6-DMSO and D2OA. Vioux. J. Lavis, J. Le Bideau, University of Montpellier/F;E. Clot, CNRS, Montpellier/F 305

LM 35 Crystallization of very low-melting ionic liquids by zone-meltingN. Winterton. A. Roy-Chaudhury, A. Steiner, A.I. Cooper,K.A. Johnson, University of Liverpool/UK 307

]f LM 36 High pressure applications for ionic liquids containing systems$? N. Brausch, P. Schulz, University of Erlangen-Nuremberg/D; A. Unger,

Parr Instrument (Deutschland) GmbH, Frankfurt/D; P. Wasserscheid,University of Erlangen-Nuremberg/D 308

24 25



LM 37 Imidazolium ionic liquids toxicity to two Baltic microalgae,Oocystis submarina and Cyclotella meneghinianaM. Nedzi, P. Stepnowski, A. Lataa, W. Mrozik, University of Gdansk/PL 309

LM 38 15N NMR spectra of some ionic liquidsA. Lvcka. R. Dolecek, A. Kolonicny, V. Pejchal,Research Institute for Organic Syntheses, Pardubice/CZ 310

LM 39 Ionic liquids as solvents for near-infrared emitting lanthanidecomplexesK. Driesen. P. Nockemann, K. Binnemans, K. U. Leuven/B 311

LM 40 Enhanced photostability of a luminescent europium complexin an imidazolium ionic liquidP. Nockemann. E. Beurer, K. Driesen, R. Van Deun, K. Binnemans,K. U. Leuven/B 312

LM 41 Preparation of hydrophilic ionic liquids using a silver-freemetathesis reactionP. Nockemann, B. Thiis. K. Driesen, K. Binnemans, K. U. Leuven/B 313

LM 42 Glycosylation with trichloroacetimidates in ionic liquids:influence of the reaction medium on the stereochemical outcomeL. Poletti. University of Milan/I; A. Rencurosi, CNR - ISTM, Milan/I;L. Lay, G. Russo, University of Milan/I 314

LM 43 Diels-alder cycloadditions in ionic liquids. A kinetic andstereochemical investigationR. Bini. C. Chiappe, University of Pisa/I; V. Llopis-Mestre, T. Welton,Imperial College, London/UK 315

LM 44 Kinetic evidence for the duality of SN1 and SN2 mechanism for theMenschutkin reaction in ionic liquidsC. Chiappe, D. Pieraccini. University of Pisa/I 316

LM 45 Ionic liquids impact on aquatic environmentC. Chiappe, D. Pieraccini. C. Pretti, M. Gregori, F. Abramo,L. Intorre, University of Pisa/I 317

LM 46 Synthesis of multiester-appended imidazolium task-specificionic liquids v

W.-G. Geng, X.-H. Li, L.-F. Wang, W.-P. Pan, H.-L. Duan,South China University of Technology, Guangzhou/VRC 318

LM 47 Magnetic ionic liquid, BMIM[FeCI4]S. Havashi. I. Yasuhiro, S. Toshirou, Y. Osamu, H. Hiro-o,University of Tokyo/J 321

LM 48 Influence of water activity and water miscibility of the solvent onwhole-cell biotransformations of beta-keto esters in ionic liquidsS. Brodmann. M. Bertau, Technical University of Dresden/D 322

LM 49 Selective conversion of alkanediol to bromoalkanol in ionic liquids:ionic liquid functioning as a protecting groupL. Liu, Academia Sinica, Taipei/RC 323

r 1st International Congress on Ionic Liquids (COIL), June 19-22, 2005, Salzburg/Austria

Last Minute Poster

LM 50 Corrosion of metals and alloys in [C4mim][Tf2N]A. Lavacchi, U. Bardi, I. Perissi, S. Caporali, University of Firenze,Sesto Fiorentino/I

i

£ •

Page

324

LM 51 Imidazolium salts, functionalised by ethyne- andethynedicobalthexacarbonyl as terminal substituents and linkers,including novel ILs andS. Cronje, H.G. Raubenheimer, C.E, Strasser, University of Stellenbosch/ZA;G. Nauer, University of Vienna/A; H. Schottenberger, K. Wurst, G. Bonn,M. Rauch, University of Innsbruck/ARTILs 325

LM 52 Relative ion-pairing strenght in gas phase by electrosprayionization mass spectrometry of ionic liquidsC. Chiappe, D. Pieraccini, T. Siciliano, University of Pisa/I 326

LM 53 Properties and applications of guanidinium salts as a potential newgeneration of ionic liquidsL C. Branco, REQUIMTE, Lisbon/P; C.A.M. Afonso, CQFM- 1ST,Lisbon/P 3 2 7

LM 54 Ionic liquid crystal as a hole transport layer of dye-sensitized solar cellsS Yanagida. N. Yamanaka, Osaka University/J; R. Kwano, YokohamaNational University/J; W. Kubo, T. Kitamura, Y. Wada, Osaka University/J;M. Watanabe, Yokohama National University/J 328

tM 55 Microwave-assisted synthesis of novel ionic liquidsP. Abramovitch, C. Holliday, Anderson College, SC/USA;R.A. Abramovitch, Clemson University, SC/USA 329

IM 56 Influence of gamma irradiation on the physical properties ofhydrophobic room temperature ionic liquids [BuMelm]PF6 and

* [BuMelm][(CF3SO2)2N]S.I. Nikitenko, Institute of Physical Chemistry, Moscow/RUS; M. Faucon,M. Gastaladi, B. Saucerotte, I. Bisel, P. Moisy, L. Berthon, C. Berthon,Commissariat a I'Energie Atomique, Bagnols sur Ceze/F 330

t M 57 Chiral ionic liquids as new reaction media for asymmetric synthesisB. Peaot. G. Vo-Thanh, A. Loupy, Paris South University, Orsay/F 331

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