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ACW_2013_DATA_REVISEDSCREENINGRESULTS_TM_2014-0206.DOCX 1 ES012314223812DFW TECHNICAL MEMORANDUM American Creosote Works Superfund Site Decision Unit Preliminary Risk Evaluation by Media (Soil, Sediment and Surface Water), Version 1.1 PREPARED FOR: Mike Hebert/EPA Region 6 Remedial Project Manager PREPARED BY: CH2M HILL DATE: February 21, 2014 COPY TO: Kenneth Shewmake/EPA John Knott/CH2M HILL Scott McKinley/CH2M HILL Vijaya Mylavarapu/CH2M HILL PROJECT: EPA Region 6 Remedial Action Contract EPW06021 Task Order No. 0051RIFS06G3 CH2M HILL Project No. 411242.RA.04 DCN: 005102026 This Technical Memorandum (TM) presents a human health, preliminary risk evaluation (PRE) for environmental media present in the Decision Units (DU) located at the American Creosote Works (ACW) Superfund site in Winnfield, Louisiana. The PRE is based on laboratory analysis of samples collected in February and March 2013. The PRE was performed as generally described in the U.S. Environmental Protection Agency (EPA) approved Work Plan Revision No. 2 American Creosote Works Superfund Site Remedial Investigation/Feasibility Study (CH2M HILL, 2012) (Task 7 of the scope). As noted in the work plan, a full risk assessment is being conducted only for the Former Process Area DU and the Creek DU. The information presented in this TM is expected to be used by EPA to determine whether a more comprehensive risk assessment for these DUs is warranted. Preliminary Risk Evaluation Approach The PRE for each DU was calculated by dividing the maximum detected dioxin/furan and polycyclic aromatic hydrocarbon (PAH) concentrations, expressed in 2,3,7,8 tetrachlorodibenzopdioxin (TCDD) toxicity equivalents (dioxin TEQ) and benzo(a)pyrene toxicity equivalents (BAP TEQ), by their corresponding residential and industrial exposurebased regional screening levels (RSLs) (EPA, 2013), and multiplying the result by a target excess lifetime cancer risk (ELCR) of 1 x 10 6 . The screening comparison results are summarized in Tables 1A for residential scenario and Table 1B for industrial scenario with the detailed information presented in Risk Assessment Guidance for Superfund (RAGS) Part D Table 2 format for all DUs in the accompanying attachment. As previously stated, a comprehensive quantitative risk assessment for the newly collected data is being conducted for the Former Process Area DU and the Creek DU; that assessment is being presented in the Risk Assessment Addendum (pending). All other DUs are being addressed through only the screening approach presented in the attachment. However, a PRE for residential scenario for soil, sediment, and surface water data from all the DUs (including the former Process Area DU and the Creek DU), and a PRE for industrial scenario for soil and sediment from all DUs are presented in this TM for comparison. A PRE for the groundwater medium was not performed because a majority of the groundwater data is from monitoring wells located within the former Process Area DU, and the adjacent Northern DU, which are included as part of the quantitative risk evaluation. Role of Background in the Preliminary Risk Evaluation Background dioxin/furan and PAH concentrations were evaluated using laboratory analysis results for samples collected from the Background DU, as shown in Tables 2a and 2b of the attachment. These values were included in the DUspecific Tables 2.1 to 2.16 of the attachment, and a detected chemical was identified as a chemical of 009527
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ACW_2013_DATA_REVISEDSCREENINGRESULTS_TM_2014-0206.DOCX 1 ES012314223812DFW

T E C H N I C A L M E M O R A N D U M  American Creosote Works Superfund Site Decision Unit Preliminary Risk Evaluation by Media (Soil, Sediment and Surface Water), Version 1.1 PREPARED FOR: Mike Hebert/EPA Region 6 Remedial Project Manager 

PREPARED BY: CH2M HILL 

DATE: February 21, 2014 

COPY TO: Kenneth Shewmake/EPA  John Knott/CH2M HILL Scott McKinley/CH2M HILL Vijaya Mylavarapu/CH2M HILL 

PROJECT: EPA Region 6 Remedial Action Contract EP‐W‐06‐021 Task Order No. 0051‐RIFS‐06G3 CH2M HILL Project No. 411242.RA.04 

DCN: 0051‐02026 

 This Technical Memorandum (TM) presents a human health, preliminary risk evaluation (PRE) for environmental media present in the Decision Units (DU) located at the American Creosote Works (ACW) Superfund site in Winnfield, Louisiana. The PRE is based on laboratory analysis of samples collected in February and March 2013. The PRE was performed as generally described in the U.S. Environmental Protection Agency (EPA) approved Work Plan Revision No. 2 American Creosote Works Superfund Site Remedial Investigation/Feasibility Study (CH2M HILL, 2012) (Task 7 of the scope). As noted in the work plan, a full risk assessment is being conducted only for the Former Process Area DU and the Creek DU. The information presented in this TM is expected to be used by EPA to determine whether a more comprehensive risk assessment for these DUs is warranted.  

Preliminary Risk Evaluation Approach The PRE for each DU was calculated by dividing the maximum detected dioxin/furan and polycyclic aromatic hydrocarbon (PAH) concentrations, expressed in 2,3,7,8 tetrachlorodibenzo‐p‐dioxin (TCDD) toxicity equivalents (dioxin TEQ) and benzo(a)pyrene toxicity equivalents (BAP TEQ), by their corresponding residential and industrial exposure‐based regional screening levels (RSLs) (EPA, 2013), and multiplying the result by a target excess lifetime cancer risk (ELCR) of 1 x 10‐6. The screening comparison results are summarized in Tables 1A for residential scenario and Table 1B for industrial scenario with the detailed information presented in Risk Assessment Guidance for Superfund (RAGS) Part D Table 2 format for all DUs in the accompanying attachment. 

As previously stated, a comprehensive quantitative risk assessment for the newly collected data is being conducted for the Former Process Area DU and the Creek DU; that assessment is being presented in the Risk Assessment Addendum (pending). All other DUs are being addressed through only the screening approach presented in the attachment. However, a PRE for residential scenario for soil, sediment, and surface water data from all the DUs (including the former Process Area DU and the Creek DU), and a PRE for industrial scenario for soil and sediment from all DUs are presented in this TM for comparison. A PRE for the groundwater medium was not performed because a majority of the groundwater data is from monitoring wells located within the former Process Area DU, and the adjacent Northern DU, which are included as part of the quantitative risk evaluation.  

Role of Background in the Preliminary Risk Evaluation Background dioxin/furan and PAH concentrations were evaluated using laboratory analysis results for samples collected from the Background DU, as shown in Tables 2a and 2b of the attachment. These values were included in the DU‐specific Tables 2.1 to 2.16 of the attachment, and a detected chemical was identified as a chemical of 

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potential concern (COPC) only if it exceeded the background threshold value (BTV). The background dioxin TEQ and BAP TEQ concentrations are higher than their respective residential RSLs. The DU‐specific maximum‐detected dioxin TEQ and BAP TEQ concentrations were greater than their respective background values.  

Preliminary Risk Evaluation Results Summary Tables 1A and 1B summarize the PRE estimates by media for each DU. The various DUs data screening in Tables 2.1 to 2.16 and background DU in Tables 2a and 2b, provided in the attachment, present the more detailed screening comparisons of the DU‐specific data against the background data, and the RSLs. The PREs indicate the following:  

The residential scenario based total PRE (dioxin TEQ plus BAP TEQ) ELCR was above the upper bound of theComprehensive Environmental Response, Compensation and Liability Act (CERCLA) risk range of 1 in 1 millionto 1 in 10,000 (1x10‐6 to 1x10‐4) for all of the DUs in surface soil as well as subsurface soil, with the exceptionof subsurface soil PRE for Southern DU and the Tar Mat DU (see Table 1A), where the PRE lies within theCERCLA risk range. The industrial scenario based PRE was above the upper‐bound limit of the 1x10‐4 at 2 of theDUs, and nearly above the limit at Northern DU (see Table 1B).

The highest BAP TEQ concentrations of 59.1 milligram per kilogram (mg/kg) in surface soil and 296 mg/kg insubsurface soil occurred within the Process Area DU. The Non‐Process Area DU had the highest dioxin TEQconcentration of 14,634 nanogram per kilogram (ng/kg) in surface soil. Subsurface soil dioxin/furan samplingand analysis was not performed for any of the DUs.

The Non‐Process Area DU PRE is driven primarily by the presence dioxin/furans in surface soil, whereas in theother DUs, PAHs are the primary risk driver.

BAP TEQ constituents were detected in each of the creek sediment samples, including the backgroundlocations. PAH concentrations were highest in the north segment between the Process Area and NorthernDUs. The residential scenario based PRE for surface water and sediment is presented in Table 1A, and theindustrial scenario based PRE for sediment is presented in Table 1B for the Creek DU. A more suitableexposure scenario for the Creek DU is a recreational receptor. A quantitative risk evaluation for therecreational exposure scenario is presented in the Risk Assessment (Version 1.1) and Risk AssessmentAddendum.

The background soil samples had detectable dioxin/furan and PAH concentrations. The estimated background threshold values (BTVs) are included in Tables 1A and 1B. However, the concentration levels are lower than those detected in the various DUs. It is not known if the presence of these constituents is attributable to former ACW operations or other non‐point anthropogenic sources.

Overall, based on the PRE, a quantitative risk assessment is expected to be helpful with future risk management decisions for the remaining DUs. The quantitative risk assessment would evaluate the use of the maximum detected concentration versus a 95 percent upper confidence limit (UCL) in determining the exposure point concentration, evaluate pertinent exposure scenarios, and further assess background contribution to the total ELCR. Based on the direction provided by EPA, after a review of the information presented in this TM, the draft Human Health Risk Assessment Addendum report for the 2013 data will be finalized and submitted for review. 

Preliminary Risk Evaluation Uncertainty Use of the maximum detected concentrations in the dioxin TEQ and BAP TEQ determination may overestimate potential exposure risk for both the residential and industrial scenarios, depending on the concentration distributions in a sample group across a DU. The statistical mean and the UCL on the mean values, which could be lower than the maximum detected concentration provide a more reasonable risk estimations particularly for PAHs. Conversely, if the data set is small and the concentration distribution is skewed, then the use of a 95 percent UCL could result in selecting the maximum detected concentration. Thus, the PREs presented in Tables 1A and 1B are considered to be conservatively estimated. 

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The PREs presented in Tables 1A and 1B do not include contributions from other carcinogenic COPCs detected (such as naphthalene and pentachlorophenol) in samples collected from each DU. Therefore, risks may be underestimated where these COPCs are present. Additionally, a PRE was not performed for non‐carcinogenic COPCs because only a few non‐carcinogenic COPCs were detected in the samples. Therefore, not including the non‐carcinogenic COPC based PRE in this preliminary risk screening is not expected to alter the overall PRE outcome. 

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TABLE 1A Summary of the Data Health‐Based Screening Results for Various Decision Units* American Creosote Works Superfund Site 

 

                         Dioxins  PAHs  Quantitative RA 

 Table   Medium Dioxin TEQ

(ng/kg) PRE   

(ELCR) BAP TEQ 

(mg/kg or µg/L) PRE            

(ELCR) Total PRE (ELCR) 

Exceeds Upper Bound of CERCLA Risk Range 

 RSL (Residential)**  4.5  0.015 

Table 2.1  Surface Soil (0 to 1 feet bgs) at Northern DU  175.1  3.9E‐05  17.7  1.2E‐03  1.2E‐03  Yes 

Table 2.2  Subsurface Soil (1 to 10 feet bgs) at Northern DU  NA  NA  1.96  1.3E‐04  1.3E‐04  Yes 

Table 2.3  Surface Soil (0 to 1 feet bgs) at Non‐Process Area DU   14,634.0  3.3E‐03  4.54  3.0E‐04  3.6E‐03  Yes 

Table 2.4 Subsurface Soil (1 to 10 feet bgs) at Non‐Process Area DU  NA  NA  2.83  1.9E‐04  1.9E‐04  Yes 

Table 2.5  Surface Soil (0 to 1 feet bgs) at Process Area DU  237.4  5.3E‐05  59.1  3.9E‐03  4.0E‐03  Yes 

Table 2.6  Subsurface Soil (1 to 10 feet bgs) at Process Area DU  NA  NA  296  2.0E‐02  2.0E‐02  Yes 

Table 2.7  Surface Soil (0 to 1 feet bgs) at Southern DU  288.0  6.4E‐05  4.87  3.2E‐04  3.9E‐04  Yes 

Table 2.8  Subsurface Soil (1 to 10 feet bgs) at Southern DU  NA  NA  1.12  7.4E‐05  7.4E‐05  No 

Table 2.9  Surface Soil (0 to 1 feet bgs) at Western DU  199.8  4.4E‐05  3.85  2.6E‐04  3.0E‐04  Yes 

Table 2.10  Subsurface Soil (1 to 10 feet bgs) at Tar Mat DU  285.4  6.3E‐05  0.23  1.5E‐05  7.9E‐05  No 

RSLs Sediment (Residential)**  

RSL Surface Water (tapwater)** 

4.5 

NA      

0.015 

0.0029     

Table 2.11  Surface Water (Fire Water Pond)  NA  NA  0.28  9.8E‐05  9.8E‐05  No 

Table 2.12  Sediment (Fire Water Pond)  79.96  1.8E‐05  0.44  2.9E‐05  4.7E‐05  No 

Table 2.13  Surface Water (North Creosote Branch Creek)  NA  NA  0.17  5.8E‐05  5.8E‐05  No 

Table 2.14  Sediment (North Creosote Branch Creek)  60.55  1.3E‐05  3.33  2.2E‐04  2.4E‐04  Yes 

Table 2.15  Surface Water (West Creosote Branch Creek)  NA  NA  0.40  1.4E‐04  1.4E‐04  Yes 

Table 2.16  Sediment (West Creosote Branch Creek)  7.66  1.70E‐06  0.401  2.7E‐05  2.8E‐05  No 

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TABLE 1A Summary of the Data Health‐Based Screening Results for Various Decision Units* American Creosote Works Superfund Site 

 

                         Dioxins  PAHs  Quantitative RA 

 Table   Medium Dioxin TEQ

(ng/kg) PRE   

(ELCR) BAP TEQ 

(mg/kg or µg/L) PRE            

(ELCR) Total PRE (ELCR) 

Exceeds Upper Bound of CERCLA Risk Range 

 Background Values 

Table 2a  Surface Soil BTVs  31.81  NA  0.432  NA  NA 

Table 2a  Subsurface Soil BTVs  NA  NA  0.425  NA  NA 

Table 2b  Surface water BTVs  NA  NA  21.134   NA  NA 

Table 2b  Sediment BTVs  10.77  NA  0.876  NA  NA 

Notes: *Table 2 includes additional details for the screening summarized values in this table. ** ‐ PRE was calculated for surface water using the tap water RSL values of 0.0029 µg/L for PAHs and PRE was calculated for sediment using the soil residential RSL value of 4.5 ng/kg for dioxins and 0.015 mg/kg for PAHs. µg/L = microgram per liter BAP‐TEQ = benzo(a)pyrene toxicity equivalent concentration bgs = below ground surface Dioxin TEQ = 2,3,7,8‐TCDD toxicity equivalent concentration DU = Decision Unit kg = kilogram mg = milligram NA = not applicable ng = nanogram PRE = Preliminary Risk Evaluation = (Dioxin TEQ or BAP TEQ/ Residential RSL)*10^‐6 for carcinogens RSL = regional screening level   

 

   

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TABLE 1B  Summary of the Data Health‐Based Screening Results for Various Decision Units ‐ Industrial PREs*  American Creosote Works Superfund Site

      Dioxins  PAHs  Quantitative RA  Table   Medium  Dioxin 

TEQ PRE (ELCR)  BAP TEQ  PRE 

(ELCR) Total PRE (ELCR) 

Exceeds Upper Bound of CERCLA 

Risk Range        (ng/kg)     (mg/kg)          

 RSL (Industrial)**  18     0.21          Table 2.1  Surface Soil (0 to 1 feet bgs) at Northern DU  175.1  9.73E‐06  17.7  8.43E‐05  9.40E‐05  No 

Table 2.2  Subsurface Soil (1 to 10 feet bgs) at Northern DU  NA  NA  1.96  9.33E‐06  9.33E‐06  No 

Table 2.3  Surface Soil (0 to 1 feet bgs) at Non‐Process Area DU   14,634.00  8.13E‐04  4.54  2.16E‐05  8.35E‐04  Yes 

Table 2.4  Subsurface Soil (1 to 10 feet bgs) at Non‐Process Area DU  NA  NA  2.83  1.35E‐05  1.35E‐05  No 

Table 2.5  Surface Soil (0 to 1 feet bgs) at Process Area DU  237.4  1.32E‐05  59.1  2.81E‐04  2.95E‐04  Yes 

Table 2.6  Subsurface Soil (1 to 10 feet bgs) at Process Area DU  NA  NA  296  1.41E‐03  1.41E‐03  Yes 

Table 2.7  Surface Soil (0 to 1 feet bgs) at Southern DU  288  1.60E‐05  4.87  2.32E‐05  3.92E‐05  No 

Table 2.8  Subsurface Soil (1 to 10 feet bgs) at Southern DU  NA  NA  1.12  5.33E‐06  5.33E‐06  No 

Table 2.9  Surface Soil (0 to 1 feet bgs) at Western DU  199.8  1.11E‐05  3.85  1.83E‐05  2.94E‐05  No 

Table 2.10  Subsurface Soil (1 to 10 feet bgs) at Tar Mat DU  285.4  1.59E‐05  0.23  1.10E‐06  1.70E‐05  No 

RSLs Sediment (Industrial)**   18        0.21          Table 2.12  Sediment (Fire Water Pond)  79.96  4.44E‐06  0.44  2.10E‐06  6.54E‐06  No 

Table 2.14  Sediment (North Creosote Branch Creek)  60.55  3.36E‐06  3.33  1.59E‐05  1.92E‐05  No 

Table 2.16  Sediment (West Creosote Branch Creek)  7.66  4.26E‐07  0.401  1.91E‐06  2.34E‐06  No 

 Background Values                   Table 2a  Surface Soil BTVs  31.81  NA  0.432  NA  NA    

Table 2a  Subsurface Soil BTVs  NA  NA  0.425  NA  NA    

Table 2b  Surface water BTVs  NA  NA  21.134  NA  NA    

Table 2b  Sediment BTVs  10.77  NA  0.876  NA  NA    

   

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Notes:          *Table 1b includes additional details for the screening, and this table summarized the screening. ** ‐ PRE was calculated for sediment using the soil Industrial RSL value of 18 ng/kg for dioxins and 0.21 mg/kg for PAHs. Surface water criteria were not available for industrial workers for a PRE calculation. µg/L = microgram per liter     BAP‐TEQ = benzo(a)pyrene toxicity equivalent concentration     bgs = below ground surface     Dioxin TEQ = 2,3,7,8‐TCDD toxicity equivalent concentration     DU = Decision Unit     kg = kilogram       mg = milligram       NA = not applicable    ng = nanogram       PRE = Preliminary Risk Evaluation = (Dioxin TEQ or BAP TEQ/ Residential RSL)*10^‐6 for carcinogens RSL = regional screening level    

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North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSurface Soil (0-1 foot bgs) and Dioxins/Furans

Emissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 8.90E+02 6.39E+03 ng/kg NDU-SU03 6 / 6 - 6.39E+03 8.54E+02 NA NA NA -- (5)Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.05E+01 5.49E+01 ng/kg NDU-SU03 6 / 6 - 5.49E+01 2.08E+01 NA NA NA -- (5)

(Northern Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 4.83E+01 1.88E+02 ng/kg NDU-SU03 6 / 6 - 1.88E+02 2.55E+01 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 1.50E+01 J 1.06E+02 ng/kg NDU-SU03 6 / 6 - 1.06E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 5.47E+00 2.06E+01 L,J ng/kg NDU-SU03 6 / 6 - 2.06E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.31E-01 L,J 2.65E+01 ng/kg NDU-SU04 5 / 6 1.00E+00 - 1.00E+00 2.65E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 2.60E+03 3.12E+04 ng/kg NDU-SU03 6 / 6 - 3.12E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 3.83E+02 2.50E+03 ng/kg NDU-SU03 6 / 6 - 2.50E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.10E+04 J 5.41E+04 J ng/kg NDU-SU02 6 / 6 - 5.41E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 4.53E+01 J 1.79E+02 J ng/kg NDU-SU03 6 / 6 - 1.79E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 6.70E+01 1.75E+02 ng/kg NDU-SU03 6 / 6 - 1.75E+02 3.18E+01 1.80E+01 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.01E+01 4.85E+01 ng/kg NDU-SU04 6 / 6 - 4.85E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 6.77E+02 1.83E+03 ng/kg NDU-DU 6 / 6 - 1.83E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.61E+01 8.19E+01 ng/kg NDU-SU03 6 / 6 - 8.19E+01 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 2.89E+01 9.58E+01 ng/kg NDU-DU 6 / 6 - 9.58E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.32E+01 6.56E+01 ng/kg NDU-DU 6 / 6 - 6.56E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 5.40E+00 J 1.15E+01 J ng/kg NDU-SU04 6 / 6 - 1.15E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.45E+00 L,J 4.42E+00 ng/kg NDU-SU04 6 / 6 - 4.42E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.17E+01 7.17E+01 ng/kg NDU-DU 6 / 6 - 7.17E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 3.68E+00 L,J 2.38E+01 ng/kg NDU-DU 6 / 6 - 2.38E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 8.69E-01 2.13E+00 L,J ng/kg NDU-SU03 4 / 6 0.00E+00 - 1.00E+00 2.13E+00 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 2.16E+03 4.87E+03 ng/kg NDU-SU03 6 / 6 - 4.87E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 7.54E+02 J 1.81E+03 J ng/kg NDU-DU 6 / 6 - 1.81E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 8.96E+02 4.24E+03 ng/kg NDU-SU03 6 / 6 - 4.24E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 5.49E+01 J 3.10E+02 J ng/kg NDU-SU04 6 / 6 - 3.10E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.08E+01 8.83E+01 J ng/kg NDU-DU 6 / 6 - 8.83E+01 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 5.70E-03 1.10E-02 mg/Kg NDU-SB10 2 / 11 4.00E-03 - 3.80E-01 1.10E-02 NA 2.20E+02 nc NA NA No BSL83-32-9 Acenaphthene 1.90E-02 L,J 1.90E-01 L,J mg/Kg NDU-SB11 3 / 11 1.90E-01 - 3.80E-01 1.90E-01 NA 3.30E+03 nc NA NA No BSL208-96-8 Acenaphthylene 8.90E-02 L,J 3.20E+00 mg/Kg NDU-SB11 5 / 11 1.90E-01 - 3.80E-01 3.20E+00 NA 3.30E+03 nc NA NA No BSL120-12-7 Anthracene 3.90E-02 L,J 7.70E-01 L,J mg/Kg NDU-SB11 6 / 11 1.90E-01 - 5.30E+00 7.70E-01 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 1.20E-02 7.10E+00 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 7.10E+00 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.70E-02 1.20E+01 J mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 1.20E+01 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 5.70E-02 J 1.80E+01 mg/Kg NDU-SB11 11 / 11 1.90E-02 - 5.30E+00 1.80E+01 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 6.80E-02 L,J 9.50E+00 mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 9.50E+00 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 4.10E-02 L,J 1.20E+01 J mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 1.20E+01 1.78E-01 2.10E+01 ca NA NA -- (6)86-74-8 Carbazole 3.70E-02 L,J 6.30E-02 L,J mg/Kg NDU-SB04 4 / 11 1.90E-01 - 5.30E+00 6.30E-02 NA NA NA NA No NTX218-01-9 Chrysene 3.70E-02 L,J 1.40E+01 mg/Kg NDU-SB11 10 / 11 1.90E-01 - 5.30E+00 1.40E+01 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 3.10E-02 J 2.30E+00 J mg/Kg NDU-SB11 9 / 11 4.00E-03 - 3.80E-01 2.30E+00 1.00E-02 2.10E-01 ca NA NA -- (6)132-64-9 Dibenzofuran 1.90E-02 L,J 2.70E-02 L,J mg/Kg NDU-SB10 3 / 11 1.90E-01 - 5.30E+00 2.70E-02 NA 1.00E+02 nc NA NA No BSL206-44-0 Fluoranthene 3.20E-02 L,J 1.30E+01 mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 1.30E+01 1.79E-01 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 2.00E-02 L,J 4.70E-02 L,J mg/Kg NDU-SB10 2 / 11 1.90E-01 - 3.80E-01 4.70E-02 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 5.90E-02 7.90E+00 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 7.90E+00 3.10E-02 2.10E+00 ca NA NA -- (6)91-20-3 Naphthalene 1.80E-03 L,J 1.40E-01 L,J mg/Kg NDU-SB11 4 / 11 4.00E-03 - 3.80E-01 1.40E-01 NA 1.80E+01 ca NA NA No BSL87-86-5 Pentachlorophenol 5.20E-02 L,J 1.90E-01 mg/Kg NDU-SB07 2 / 11 8.00E-03 - 7.80E-01 1.90E-01 9.60E-03 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 1.90E-02 L,J 2.50E-01 mg/Kg NDU-SB05 7 / 11 1.90E-01 - 5.30E+00 2.50E-01 NA 1.70E+04 nc NA NA No BSL

TABLE 2.1OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Qualifier Qualifier

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009535

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

TABLE 2.1OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Qualifier Qualifier

Minimum MaximumConcentration Concentration

129-00-0 Pyrene 5.70E-02 L,J 1.30E+01 mg/Kg NDU-SB11 10 / 11 1.90E-01 - 5.30E+00 1.30E+01 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 2.95E-02 1.77E+01 mg/Kg NDU-SB11 11 / 11 - 1.77E+01 4.32E-01 2.10E-01 ca NA NA Yes ASL

Residential ScenarioSurface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 8.90E+02 6.39E+03 ng/kg NDU-SU03 6 / 6 - 6.39E+03 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.05E+01 5.49E+01 ng/kg NDU-SU03 6 / 6 - 5.49E+01 2.08E+01 NA NA NA -- (5)(Northern Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 4.83E+01 1.88E+02 ng/kg NDU-SU03 6 / 6 - 1.88E+02 2.55E+01 NA NA NA -- (5)

19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 1.50E+01 J 1.06E+02 ng/kg NDU-SU03 6 / 6 - 1.06E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 5.47E+00 2.06E+01 L,J ng/kg NDU-SU03 6 / 6 - 2.06E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.31E-01 L,J 2.65E+01 ng/kg NDU-SU04 5 / 6 1.00E+00 - 1.00E+00 2.65E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 2.60E+03 3.12E+04 ng/kg NDU-SU03 6 / 6 - 3.12E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 3.83E+02 2.50E+03 ng/kg NDU-SU03 6 / 6 - 2.50E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.10E+04 J 5.41E+04 J ng/kg NDU-SU02 6 / 6 - 5.41E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 4.53E+01 J 1.79E+02 J ng/kg NDU-SU03 6 / 6 - 1.79E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 6.70E+01 1.75E+02 ng/kg NDU-SU03 6 / 6 - 1.75E+02 3.18E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.01E+01 4.85E+01 ng/kg NDU-SU04 6 / 6 - 4.85E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 6.77E+02 1.83E+03 ng/kg NDU-DU 6 / 6 - 1.83E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.61E+01 8.19E+01 ng/kg NDU-SU03 6 / 6 - 8.19E+01 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 2.89E+01 9.58E+01 ng/kg NDU-DU 6 / 6 - 9.58E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.32E+01 6.56E+01 ng/kg NDU-DU 6 / 6 - 6.56E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 5.40E+00 J 1.15E+01 J ng/kg NDU-SU04 6 / 6 - 1.15E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.45E+00 L,J 4.42E+00 ng/kg NDU-SU04 6 / 6 - 4.42E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.17E+01 7.17E+01 ng/kg NDU-DU 6 / 6 - 7.17E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 3.68E+00 L,J 2.38E+01 ng/kg NDU-DU 6 / 6 - 2.38E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 8.69E-01 2.13E+00 L,J ng/kg NDU-SU03 4 / 6 0.00E+00 - 1.00E+00 2.13E+00 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 2.16E+03 4.87E+03 ng/kg NDU-SU03 6 / 6 - 4.87E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 7.54E+02 J 1.81E+03 J ng/kg NDU-DU 6 / 6 - 1.81E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 8.96E+02 4.24E+03 ng/kg NDU-SU03 6 / 6 - 4.24E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 5.49E+01 J 3.10E+02 J ng/kg NDU-SU04 6 / 6 - 3.10E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.08E+01 8.83E+01 J ng/kg NDU-DU 6 / 6 - 8.83E+01 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 5.70E-03 1.10E-02 mg/Kg NDU-SB10 2 / 11 4.00E-03 - 3.80E-01 1.10E-02 NA 2.30E+01 nc NA NA No BSL83-32-9 Acenaphthene 1.90E-02 L,J 1.90E-01 L,J mg/Kg NDU-SB11 3 / 11 1.90E-01 - 3.80E-01 1.90E-01 NA 3.40E+02 nc NA NA No BSL208-96-8 Acenaphthylene 8.90E-02 L,J 3.20E+00 mg/Kg NDU-SB11 5 / 11 1.90E-01 - 3.80E-01 3.20E+00 NA 3.40E+02 nc NA NA No BSL120-12-7 Anthracene 3.90E-02 L,J 7.70E-01 L,J mg/Kg NDU-SB11 6 / 11 1.90E-01 - 5.30E+00 7.70E-01 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 1.20E-02 7.10E+00 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 7.10E+00 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.70E-02 1.20E+01 J mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 1.20E+01 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 5.70E-02 J 1.80E+01 mg/Kg NDU-SB11 11 / 11 1.90E-02 - 5.30E+00 1.80E+01 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 6.80E-02 L,J 9.50E+00 mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 9.50E+00 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 4.10E-02 L,J 1.20E+01 J mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 1.20E+01 1.78E-01 1.50E+00 ca NA NA -- (6)86-74-8 Carbazole 3.70E-02 L,J 6.30E-02 L,J mg/Kg NDU-SB04 4 / 11 1.90E-01 - 5.30E+00 6.30E-02 NA NA NA NA No NTX218-01-9 Chrysene 3.70E-02 L,J 1.40E+01 mg/Kg NDU-SB11 10 / 11 1.90E-01 - 5.30E+00 1.40E+01 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 3.10E-02 J 2.30E+00 J mg/Kg NDU-SB11 9 / 11 4.00E-03 - 3.80E-01 2.30E+00 1.00E-02 1.50E-02 ca NA NA -- (6)132-64-9 Dibenzofuran 1.90E-02 L,J 2.70E-02 L,J mg/Kg NDU-SB10 3 / 11 1.90E-01 - 5.30E+00 2.70E-02 NA 7.80E+00 nc NA NA No BSL206-44-0 Fluoranthene 3.20E-02 L,J 1.30E+01 mg/Kg NDU-SB11 11 / 11 1.90E-01 - 5.30E+00 1.30E+01 1.79E-01 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 2.00E-02 L,J 4.70E-02 L,J mg/Kg NDU-SB10 2 / 11 1.90E-01 - 3.80E-01 4.70E-02 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 5.90E-02 7.90E+00 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 5.30E+00 7.90E+00 3.10E-02 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 1.80E-03 L,J 1.40E-01 L,J mg/Kg NDU-SB11 4 / 11 4.00E-03 - 3.80E-01 1.40E-01 NA 3.60E+00 ca NA NA No BSL87-86-5 Pentachlorophenol 5.20E-02 L,J 1.90E-01 mg/Kg NDU-SB07 2 / 11 8.00E-03 - 7.80E-01 1.90E-01 9.60E-03 8.90E-01 ca NA NA No BSL

PAGE 2 OF 3

009536

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

TABLE 2.1OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Qualifier Qualifier

Minimum MaximumConcentration Concentration

85-01-8 Phenanthrene 1.90E-02 L,J 2.50E-01 mg/Kg NDU-SB05 7 / 11 1.90E-01 - 5.30E+00 2.50E-01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 5.70E-02 L,J 1.30E+01 mg/Kg NDU-SB11 10 / 11 1.90E-01 - 5.30E+00 1.30E+01 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 2.95E-02 1.77E+01 mg/Kg NDU-SB11 11 / 11 - 1.77E+01 4.32E-01 1.50E-02 ca NA NA Yes ASL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HHRA = Human Health Risk AssessmentThe SL for anthracene was used as the SL for phenanthrene. J = compound was detected below the reporting limit in the sampleSL for benzo(a)pyrene was used as the SL for total BAP TEQ. L = compound was detected above the Method Detection Limit (MDL) but

below the Contract Required Quantitation Limit (CRQL)(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) NA = not available

Deletion Reason: Below Screening Level (BSL) SL = screening levelNo Toxicity Information (NTX) SVOC = semi-volatile organic compound

TEQ = toxic equivalent(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." mg/kg = milligram per kilogram

ng/kg = nanogram per kilogram(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, PAH = polycyclic aromatic hydrocarbon

indeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ."

PAGE 3 OF 3

009537

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSubsurface Soil (1-10 feet bgs) SVOCs

and Emissions from 92-52-4 1,1'-Biphenyl 1.80E+00 1.80E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E-01 1.80E+00 NA 2.10E+01 nc NA NA No BSLSubsurface Soil 91-57-6 2-Methylnaphthalene 2.30E-03 L,J 8.30E+00 mg/Kg NDU-SB11 2 / 11 4.00E-03 - 2.00E+00 8.30E+00 NA 2.20E+02 nc NA NA No BSL

(Northern Decision Unit) 83-32-9 Acenaphthene 9.30E+00 9.30E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 9.30E+00 NA 3.30E+03 nc NA NA No BSL120-12-7 Anthracene 4.20E+00 J,^ 4.20E+00 J,^ mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 4.20E+00 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 2.00E-03 L,J 2.40E+00 mg/Kg NDU-SB11 5 / 11 4.00E-03 - 2.00E-01 2.40E+00 NA 2.10E+00 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 3.80E-03 L,J 1.20E+00 J mg/Kg NDU-SB11 5 / 11 4.00E-03 - 2.00E-01 1.20E+00 NA 2.10E-01 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 3.40E-03 L,J 1.20E+00 mg/Kg NDU-SB11 9 / 11 4.00E-03 - 2.00E-01 1.20E+00 4.33E-03 2.10E+00 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 2.70E-02 L,J 7.30E-01 mg/Kg NDU-SB11 5 / 11 1.90E-01 - 2.00E-01 7.30E-01 2.80E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 4.10E-02 L,J 8.70E-01 J mg/Kg NDU-SB11 7 / 11 1.90E-01 - 2.00E-01 8.70E-01 1.75E-01 2.10E+01 ca NA NA -- (5)117-81-7 Bis(2-Ethylhexyl)phthalate 1.10E+00 1.10E+00 mg/Kg NDU-SB05 1 / 11 1.90E-01 - 2.00E-01 1.10E+00 NA 1.20E+02 ca NA NA No BSL86-74-8 Carbazole 1.50E+00 1.50E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E-01 1.50E+00 NA NA NA NA No NTX218-01-9 Chrysene 7.50E-02 L,J 2.00E+00 mg/Kg NDU-SB11 2 / 11 1.90E-01 - 2.00E-01 2.00E+00 4.56E-02 2.10E+02 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 3.10E-03 L,J 3.20E-01 mg/Kg NDU-SB11 6 / 11 4.00E-03 - 2.00E-01 3.20E-01 4.10E-03 2.10E-01 ca NA NA -- (5)132-64-9 Dibenzofuran 6.50E+00 6.50E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 6.50E+00 NA 1.00E+02 nc NA NA No BSL206-44-0 Fluoranthene 2.70E-02 L,J 9.40E+00 mg/Kg NDU-SB11 4 / 11 1.90E-01 - 2.00E+00 9.40E+00 NA 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 8.60E+00 8.60E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 8.60E+00 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 3.20E-03 L,J 6.80E-01 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 2.00E-01 6.80E-01 4.42E-03 2.10E+00 ca NA NA -- (5)91-20-3 Naphthalene 1.60E-03 L,J 1.60E+01 mg/Kg NDU-SB11 4 / 11 4.00E-03 - 2.00E+00 1.60E+01 NA 1.80E+01 ca NA NA No BSL85-01-8 Phenanthrene 2.20E+01 J,^ 2.20E+01 J,^ mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 2.20E+01 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 3.10E-02 L,J 6.90E+00 mg/Kg NDU-SB11 4 / 11 1.90E-01 - 2.00E+00 6.90E+00 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 5.22E-03 1.96E+00 mg/Kg NDU-SB11 11 / 11 - 1.96E+00 4.25E-01 2.10E-01 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.00E-02 3.40E-02 mg/Kg NDU-SB06 3 / 11 8.00E-03 - 1.00E-02 3.40E-02 NA 6.30E+04 nc NA NA No BSL98-82-8 Isopropylbenzene (Cumene) 2.60E-03 L,J 2.60E-03 L,J mg/Kg NDU-SB11 1 / 11 4.00E-03 - 5.00E-03 2.60E-03 NA 2.68E+02 csat NA NA No BSL

Residential ScenarioSubsurface Soil and SVOCs

Emissions from 92-52-4 1,1'-Biphenyl 1.80E+00 1.80E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E-01 1.80E+00 NA 5.10E+00 nc NA NA No BSLSubsurface Soil 91-57-6 2-Methylnaphthalene 2.30E-03 L,J 8.30E+00 mg/Kg NDU-SB11 2 / 11 4.00E-03 - 2.00E+00 8.30E+00 NA 2.30E+01 nc NA NA No BSL

(Northern Decision Unit) 83-32-9 Acenaphthene 9.30E+00 9.30E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 9.30E+00 NA 3.40E+02 nc NA NA No BSL120-12-7 Anthracene 4.20E+00 J,^ 4.20E+00 J,^ mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 4.20E+00 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 2.00E-03 L,J 2.40E+00 mg/Kg NDU-SB11 5 / 11 4.00E-03 - 2.00E-01 2.40E+00 NA 1.50E-01 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 3.80E-03 L,J 1.20E+00 J mg/Kg NDU-SB11 5 / 11 4.00E-03 - 2.00E-01 1.20E+00 NA 1.50E-02 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 3.40E-03 L,J 1.20E+00 mg/Kg NDU-SB11 9 / 11 4.00E-03 - 2.00E-01 1.20E+00 4.33E-03 1.50E-01 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 2.70E-02 L,J 7.30E-01 mg/Kg NDU-SB11 5 / 11 1.90E-01 - 2.00E-01 7.30E-01 2.80E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 4.10E-02 L,J 8.70E-01 J mg/Kg NDU-SB11 7 / 11 1.90E-01 - 2.00E-01 8.70E-01 1.75E-01 1.50E+00 ca NA NA -- (5)117-81-7 Bis(2-Ethylhexyl)phthalate 1.10E+00 1.10E+00 mg/Kg NDU-SB05 1 / 11 1.90E-01 - 2.00E-01 1.10E+00 NA 3.50E+01 ca NA NA No BSL86-74-8 Carbazole 1.50E+00 1.50E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E-01 1.50E+00 NA NA NA NA No NTX218-01-9 Chrysene 7.50E-02 L,J 2.00E+00 mg/Kg NDU-SB11 2 / 11 1.90E-01 - 2.00E-01 2.00E+00 4.56E-02 1.50E+01 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 3.10E-03 L,J 3.20E-01 mg/Kg NDU-SB11 6 / 11 4.00E-03 - 2.00E-01 3.20E-01 4.10E-03 1.50E-02 ca NA NA -- (5)132-64-9 Dibenzofuran 6.50E+00 6.50E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 6.50E+00 NA 7.80E+00 nc NA NA No BSL206-44-0 Fluoranthene 2.70E-02 L,J 9.40E+00 mg/Kg NDU-SB11 4 / 11 1.90E-01 - 2.00E+00 9.40E+00 NA 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 8.60E+00 8.60E+00 mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 8.60E+00 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 3.20E-03 L,J 6.80E-01 mg/Kg NDU-SB11 10 / 11 4.00E-03 - 2.00E-01 6.80E-01 4.42E-03 1.50E-01 ca NA NA -- (5)91-20-3 Naphthalene 1.60E-03 L,J 1.60E+01 mg/Kg NDU-SB11 4 / 11 4.00E-03 - 2.00E+00 1.60E+01 NA 3.60E+00 ca NA NA Yes ASL85-01-8 Phenanthrene 2.20E+01 J,^ 2.20E+01 J,^ mg/Kg NDU-SB11 1 / 11 1.90E-01 - 2.00E+00 2.20E+01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 3.10E-02 L,J 6.90E+00 mg/Kg NDU-SB11 4 / 11 1.90E-01 - 2.00E+00 6.90E+00 NA 1.70E+02 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.2OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 2

009538

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.2OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

BAPTEQ Total BAP TEQ 5.22E-03 1.96E+00 mg/Kg NDU-SB11 11 / 11 - 1.96E+00 4.25E-01 1.50E-02 ca NA NA Yes ASLVOCs

67-64-1 Acetone 1.00E-02 3.40E-02 mg/Kg NDU-SB06 3 / 11 8.00E-03 - 1.00E-02 3.40E-02 NA 6.10E+03 nc NA NA No BSL98-82-8 Isopropylbenzene (Cumene) 2.60E-03 L,J 2.60E-03 L,J mg/Kg NDU-SB11 1 / 11 4.00E-03 - 5.00E-03 2.60E-03 NA 2.10E+02 nc NA NA No BSL

(1) Maximum concentration is used for screening. ^ = high estimateCOPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. csat = soil saturationThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. nc = noncarcinogenicNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HEAST = Health Effects Assessment Summary TablesThe SL for anthracene was used as the SL for phenanthrene. HQ = hazard quotientSL for benzo(a)pyrene was used as the SL for total BAP TEQ. HHRA = Human Health Risk Assessment

NA = not available(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) J = compound was detected below the reporting limit in the sample

Deletion Reason: Below Screening Level (BSL) L = compound was detected above the Method Detection Limit (MDL) but below the No Toxicity Information (NTX) Contract Required Quantitation Limit (CRQL)

BAP TEQ = benzo(a)pyrene toxic equivalent(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, SL = screening level

indeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. SVOC = semi-volatile organic compoundVOC = volatile organic compoundmg/kg = milligram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 2 OF 2

009539

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSurface Soil (0-1 foot bgs) and Dioxins/Furans

Emissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 5.05E+03 6.68E+05 ng/kg NPDU-SU02 6 / 6 - 6.68E+05 8.54E+02 NA NA NA -- (5)Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 3.99E+01 2.96E+03 ng/kg NPDU-SU02 6 / 6 - 2.96E+03 2.08E+01 NA NA NA -- (5)

(Non-Process Area 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1.29E+02 1.84E+04 ng/kg NPDU-SU02 6 / 6 - 1.84E+04 2.55E+01 NA NA NA -- (5)Decision Unit) 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 2.52E+01 4.82E+03 J ng/kg NPDU-SU02 6 / 6 - 4.82E+03 2.56E+01 NA NA NA -- (5)

40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 6.65E+00 7.79E+02 ng/kg NPDU-SU02 6 / 6 - 7.79E+02 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.54E-01 L,J 1.22E+01 ng/kg NPDU-SU02 6 / 6 - 1.22E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 1.04E+04 1.14E+06 ng/kg NPDU-SU02 6 / 6 - 1.14E+06 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 7.51E+02 7.21E+04 J ng/kg NPDU-SU02 6 / 6 - 7.21E+04 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 5.31E+04 J 5.23E+06 J ng/kg NPDU-SU02 6 / 6 - 5.23E+06 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 4.70E+01 J 2.54E+03 J ng/kg NPDU-SU02 6 / 6 - 2.54E+03 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 1.15E+02 1.46E+04 ng/kg NPDU-SU02 6 / 6 - 1.46E+04 3.18E+01 1.80E+01 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 7.24E+00 4.63E+02 ng/kg NPDU-SU02 6 / 6 - 4.63E+02 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 8.18E+02 1.30E+05 ng/kg NPDU-DU 6 / 6 - 1.30E+05 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 5.88E+01 9.10E+03 ng/kg NPDU-DU 6 / 6 - 9.10E+03 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 3.13E+01 4.89E+03 ng/kg NPDU-SU02 6 / 6 - 4.89E+03 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.16E+01 J 3.61E+03 J ng/kg NPDU-SU02 6 / 6 - 3.61E+03 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 5.46E+00 1.01E+03 J ng/kg NPDU-SU02 6 / 6 - 1.01E+03 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.14E+00 L,J 1.65E+02 ng/kg NPDU-SU02 6 / 6 - 1.65E+02 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 2.45E+01 3.04E+03 ng/kg NPDU-SU02 6 / 6 - 3.04E+03 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 3.28E+00 4.69E+02 ng/kg NPDU-SU02 6 / 6 - 4.69E+02 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 5.19E-01 1.31E+01 ng/kg NPDU-DU 5 / 6 - 1.31E+01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 3.47E+03 7.00E+05 ng/kg NPDU-DU 6 / 6 - 7.00E+05 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 8.87E+02 J 1.53E+05 J ng/kg NPDU-SU02 6 / 6 - 1.53E+05 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 3.62E+03 6.93E+05 ng/kg NPDU-SU02 6 / 6 - 6.93E+05 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 8.60E+01 J 6.21E+03 J ng/kg NPDU-SU02 6 / 6 - 6.21E+03 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.04E+01 J 5.14E+02 J ng/kg NPDU-SU02 6 / 6 - 5.14E+02 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 2.40E-03 L,J 4.00E-03 L,J mg/kg NPDU-SB05 2 / 15 3.70E-03 - 8.00E-02 4.00E-03 NA 2.20E+02 nc NA NA No BSL208-96-8 Acenaphthylene 6.00E-02 L,J 1.40E-01 L,J mg/kg NPDU-SB04 2 / 15 1.90E-01 - 2.20E+00 1.40E-01 NA 3.30E+03 nc NA NA No BSL120-12-7 Anthracene 2.80E-02 L,J 2.00E-01 J,^ mg/kg NPDU-SB04 3 / 15 1.90E-01 - 2.20E+00 2.00E-01 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 9.20E-03 3.50E+00 mg/kg NPDU-SB04 14 / 15 3.70E-03 - 2.00E+00 3.50E+00 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.70E-02 2.60E+00 mg/kg NPDU-SB01 14 / 15 3.80E-03 - 2.10E+00 2.60E+00 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 2.40E-02 3.20E+00 mg/kg NPDU-SB01 14 / 15 3.80E-03 - 2.10E+00 3.20E+00 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 2.40E-02 L,J 2.00E+00 L,J mg/kg NPDU-SB01 10 / 15 1.90E-01 - 2.20E+00 2.00E+00 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 2.60E-02 L,J 2.60E+00 J mg/kg NPDU-SB04 15 / 15 1.90E-01 - 4.30E-01 2.60E+00 1.78E-01 2.10E+01 ca NA NA -- (6)117-81-7 Bis(2-Ethylhexyl)phthalate 2.00E-02 L,J 8.20E-02 L,J mg/kg NPDU-SB05 8 / 15 1.90E-01 - 2.20E+00 8.20E-02 NA 1.20E+02 ca NA NA No BSL86-74-8 Carbazole 4.60E-02 L,J 4.60E-02 L,J mg/kg NPDU-SB04 1 / 15 1.90E-01 - 2.20E+00 4.60E-02 NA NA NA NA NA No NTX218-01-9 Chrysene 2.80E-02 L,J 5.60E+00 mg/kg NPDU-SB04 10 / 15 1.90E-01 - 2.00E+00 5.60E+00 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 6.70E-03 1.10E+00 mg/kg NPDU-SB01 14 / 15 3.70E-03 - 4.00E-01 1.10E+00 1.00E-02 2.10E-01 ca NA NA -- (6)84-74-2 Di-n-Butyl Phthalate 2.20E-02 L,J 5.00E-02 L,J mg/kg NPDU-SB09 5 / 15 1.90E-01 - 2.20E+00 5.00E-02 NA 6.20E+03 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 2.10E-02 L,J 6.90E-02 L,J mg/kg NPDU-SB05 4 / 15 1.90E-01 - 2.20E+00 6.90E-02 NA 6.20E+02 nc NA NA No BSL206-44-0 Fluoranthene 3.20E-02 L,J 8.70E+00 mg/kg NPDU-SB04 12 / 15 1.90E-01 - 2.20E+00 8.70E+00 1.79E-01 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 2.20E-02 2.30E+00 J mg/kg NPDU-SB01 14 / 15 3.70E-03 - 2.10E+00 2.30E+00 3.10E-02 2.10E+00 ca NA NA -- (6)91-20-3 Naphthalene 1.90E-03 L,J 3.20E-02 mg/kg NPDU-SB12 4 / 15 3.70E-03 - 8.00E-02 3.20E-02 NA 1.80E+01 ca NA NA No BSL87-86-5 Pentachlorophenol 9.00E-03 9.50E-01 mg/kg NPDU-SB02 13 / 15 7.60E-03 - 8.70E-01 9.50E-01 9.60E-03 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 2.00E-02 L,J 1.80E-01 ^ mg/kg NPDU-SB04 7 / 15 1.90E-01 - 2.20E+00 1.80E-01 NA 1.70E+04 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.3OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009540

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.3OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

129-00-0 Pyrene 2.80E-02 L,J 9.50E+00 mg/kg NPDU-SB04 10 / 15 1.90E-01 - 2.20E+00 9.50E+00 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 4.85E-03 L,J 4.54E+00 mg/kg NPDU-SB01 15 / 15 5.42E-03 - 1.48E+00 4.54E+00 4.32E-01 2.10E-01 ca NA NA Yes ASL

Residential ScenarioSurface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 5.05E+03 6.68E+05 ng/kg NPDU-SU02 6 / 6 - 6.68E+05 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 3.99E+01 2.96E+03 ng/kg NPDU-SU02 6 / 6 - 2.96E+03 2.08E+01 NA NA NA -- (5)(Non-Process Area 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1.29E+02 1.84E+04 ng/kg NPDU-SU02 6 / 6 - 1.84E+04 2.55E+01 NA NA NA -- (5)

Decision Unit) 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 2.52E+01 4.82E+03 J ng/kg NPDU-SU02 6 / 6 - 4.82E+03 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 6.65E+00 7.79E+02 ng/kg NPDU-SU02 6 / 6 - 7.79E+02 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.54E-01 L,J 1.22E+01 ng/kg NPDU-SU02 6 / 6 - 1.22E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 1.04E+04 1.14E+06 ng/kg NPDU-SU02 6 / 6 - 1.14E+06 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 7.51E+02 7.21E+04 J ng/kg NPDU-SU02 6 / 6 - 7.21E+04 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 5.31E+04 J 5.23E+06 J ng/kg NPDU-SU02 6 / 6 - 5.23E+06 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 4.70E+01 J 2.54E+03 J ng/kg NPDU-SU02 6 / 6 - 2.54E+03 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 1.15E+02 1.46E+04 ng/kg NPDU-SU02 6 / 6 - 1.46E+04 3.18E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 7.24E+00 4.63E+02 ng/kg NPDU-SU02 6 / 6 - 4.63E+02 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 8.18E+02 1.30E+05 ng/kg NPDU-DU 6 / 6 - 1.30E+05 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 5.88E+01 9.10E+03 ng/kg NPDU-DU 6 / 6 - 9.10E+03 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 3.13E+01 4.89E+03 ng/kg NPDU-SU02 6 / 6 - 4.89E+03 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.16E+01 J 3.61E+03 J ng/kg NPDU-SU02 6 / 6 - 3.61E+03 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 5.46E+00 1.01E+03 J ng/kg NPDU-SU02 6 / 6 - 1.01E+03 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.14E+00 L,J 1.65E+02 ng/kg NPDU-SU02 6 / 6 - 1.65E+02 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 2.45E+01 3.04E+03 ng/kg NPDU-SU02 6 / 6 - 3.04E+03 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 3.28E+00 4.69E+02 ng/kg NPDU-SU02 6 / 6 - 4.69E+02 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 5.19E-01 1.31E+01 ng/kg NPDU-DU 5 / 6 - 1.31E+01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 3.47E+03 7.00E+05 ng/kg NPDU-DU 6 / 6 - 7.00E+05 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 8.87E+02 J 1.53E+05 J ng/kg NPDU-SU02 6 / 6 - 1.53E+05 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 3.62E+03 6.93E+05 ng/kg NPDU-SU02 6 / 6 - 6.93E+05 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 8.60E+01 J 6.21E+03 J ng/kg NPDU-SU02 6 / 6 - 6.21E+03 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.04E+01 J 5.14E+02 J ng/kg NPDU-SU02 6 / 6 - 5.14E+02 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 2.40E-03 L,J 4.00E-03 L,J mg/kg NPDU-SB05 2 / 15 3.70E-03 - 8.00E-02 4.00E-03 NA 2.30E+01 nc NA NA No BSL208-96-8 Acenaphthylene 6.00E-02 L,J 1.40E-01 L,J mg/kg NPDU-SB04 2 / 15 1.90E-01 - 2.20E+00 1.40E-01 NA 3.40E+02 nc NA NA No BSL120-12-7 Anthracene 2.80E-02 L,J 2.00E-01 J,^ mg/kg NPDU-SB04 3 / 15 1.90E-01 - 2.20E+00 2.00E-01 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 9.20E-03 3.50E+00 mg/kg NPDU-SB04 14 / 15 3.70E-03 - 2.00E+00 3.50E+00 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.70E-02 2.60E+00 mg/kg NPDU-SB01 14 / 15 3.80E-03 - 2.10E+00 2.60E+00 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 2.40E-02 3.20E+00 mg/kg NPDU-SB01 14 / 15 3.80E-03 - 2.10E+00 3.20E+00 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 2.40E-02 L,J 2.00E+00 L,J mg/kg NPDU-SB01 10 / 15 1.90E-01 - 2.20E+00 2.00E+00 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 2.60E-02 L,J 2.60E+00 J mg/kg NPDU-SB04 15 / 15 1.90E-01 - 4.30E-01 2.60E+00 1.78E-01 1.50E+00 ca NA NA -- (6)117-81-7 Bis(2-Ethylhexyl)phthalate 2.00E-02 L,J 8.20E-02 L,J mg/kg NPDU-SB05 8 / 15 1.90E-01 - 2.20E+00 8.20E-02 NA 3.50E+01 ca NA NA No BSL86-74-8 Carbazole 4.60E-02 L,J 4.60E-02 L,J mg/kg NPDU-SB04 1 / 15 1.90E-01 - 2.20E+00 4.60E-02 NA NA NA NA NA No NTX218-01-9 Chrysene 2.80E-02 L,J 5.60E+00 mg/kg NPDU-SB04 10 / 15 1.90E-01 - 2.00E+00 5.60E+00 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 6.70E-03 1.10E+00 mg/kg NPDU-SB01 14 / 15 3.70E-03 - 4.00E-01 1.10E+00 1.00E-02 1.50E-02 ca NA NA -- (6)84-74-2 Di-n-Butyl Phthalate 2.20E-02 L,J 5.00E-02 L,J mg/kg NPDU-SB09 5 / 15 1.90E-01 - 2.20E+00 5.00E-02 NA 6.10E+02 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 2.10E-02 L,J 6.90E-02 L,J mg/kg NPDU-SB05 4 / 15 1.90E-01 - 2.20E+00 6.90E-02 NA 6.10E+01 nc NA NA No BSL206-44-0 Fluoranthene 3.20E-02 L,J 8.70E+00 mg/kg NPDU-SB04 12 / 15 1.90E-01 - 2.20E+00 8.70E+00 1.79E-01 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 2.20E-02 2.30E+00 J mg/kg NPDU-SB01 14 / 15 3.70E-03 - 2.10E+00 2.30E+00 3.10E-02 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 1.90E-03 L,J 3.20E-02 mg/kg NPDU-SB12 4 / 15 3.70E-03 - 8.00E-02 3.20E-02 NA 3.60E+00 ca NA NA No BSL87-86-5 Pentachlorophenol 9.00E-03 9.50E-01 mg/kg NPDU-SB02 13 / 15 7.60E-03 - 8.70E-01 9.50E-01 9.60E-03 8.90E-01 ca NA NA Yes ASL

PAGE 2 OF 3

009541

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.3OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

85-01-8 Phenanthrene 2.00E-02 L,J 1.80E-01 ^ mg/kg NPDU-SB04 7 / 15 1.90E-01 - 2.20E+00 1.80E-01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 2.80E-02 L,J 9.50E+00 mg/kg NPDU-SB04 10 / 15 1.90E-01 - 2.20E+00 9.50E+00 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 4.85E-03 L,J 4.54E+00 mg/kg NPDU-SB01 15 / 15 5.42E-03 - 1.48E+00 4.54E+00 4.32E-01 1.50E-02 ca NA NA Yes ASL

(1) Maximum concentration is used for screening. ^ = high estimateCOPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for Total Dioxin TEQ. BAP = benzo(a)pyrene The SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HHRA = Human Health Risk AssessmentThe SL for anthracene was used as the SL for phenanthrene. J = compound was detected below the reporting limit in the sampleSL for benzo(a)pyrene was used as the SL for total BAP TEQ. L = compound was detected above the Method Detection Limit (MDL) but

below the Contract Required Quantitation Limit (CRQL)(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) NA = not available

Deletion Reason: Below Screening Level (BSL) SL = screening levelNo Toxicity Information (NTX) SVOC = semi-volatile organic compound

(5) Dioxin/furan congeners will be addressed in total in the HHRA as total dioxin TEQ. TEQ = toxic equivalentmg/kg = milligram per kilogram

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, ng/kg = nanogram per kilogramindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." PAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009542

North Area, American Creosote Works

Winnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSubsurface Soil (1-10 feet bgs) SVOCs

and Emissions from 92-52-4 1,1'-Biphenyl 5.30E-02 L,J 1.70E+00 L,J mg/Kg NPDU-SB12 2 / 13 1.70E-01 - 6.30E+00 1.70E+00 NA 2.10E+01 nc NA NA No BSLSubsurface Soil 91-57-6 2-Methylnaphthalene 5.80E-03 2.50E+00 mg/Kg NPDU-SB12 3 / 13 4.00E-03 - 4.20E-01 2.50E+00 NA 2.20E+02 nc NA NA No BSL

(Non-Process Area 106-44-5 4-Methylphenol (p-Cresol) 3.80E-02 L,J 3.80E-02 L,J mg/Kg NPDU-SB13 1 / 13 1.70E-01 - 6.30E+00 3.80E-02 NA 6.20E+03 nc NA NA No BSLDecision Unit) 83-32-9 Acenaphthene 5.10E-03 1.60E+01 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 1.60E+01 NA 3.30E+03 nc NA NA No BSL

208-96-8 Acenaphthylene 2.20E-01 2.20E-01 mg/Kg NPDU-SB12 1 / 13 3.30E-03 - 2.20E-01 2.20E-01 NA 3.30E+03 nc NA NA No BSL98-86-2 Acetophenone 2.10E-02 L,J 2.10E-02 L,J mg/Kg GP-07 1 / 13 1.70E-01 - 6.30E+00 2.10E-02 NA 2.52E+03 csat NA NA No BSL120-12-7 Anthracene 7.20E-03 8.90E+00 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 8.90E+00 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 3.00E-03 L,J 7.60E+00 J mg/Kg NPDU-SB12 6 / 13 3.30E-03 - 4.20E-01 7.60E+00 NA 2.10E+00 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 9.10E-02 1.70E+00 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 4.20E-01 1.70E+00 NA 2.10E-01 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 2.40E-03 L,J 1.60E+00 mg/Kg NPDU-SB12 6 / 13 3.30E-03 - 4.20E-01 1.60E+00 4.33E-03 2.10E+00 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 9.50E-02 L,J 2.20E+00 L,J mg/Kg NPDU-SB12 2 / 13 3.30E-03 - 6.30E+00 2.20E+00 2.80E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 3.20E-02 L,J 1.30E+00 mg/Kg NPDU-SB12 4 / 13 3.30E-03 - 4.20E-01 1.30E+00 1.75E-01 2.10E+01 ca NA NA -- (5)117-81-7 Bis(2-Ethylhexyl)phthalate 1.80E-02 L,J 1.80E-02 L,J mg/Kg NPDU-SB11 1 / 13 1.70E-01 - 6.30E+00 1.80E-02 NA 1.20E+02 ca NA NA No BSL86-74-8 Carbazole 2.60E-02 L,J 2.70E+00 L,J mg/Kg NPDU-SB12 3 / 13 1.70E-01 - 6.30E+00 2.70E+00 NA NA NA NA No NTX218-01-9 Chrysene 2.30E-01 4.40E+00 J mg/Kg NPDU-SB12 2 / 13 3.30E-03 - 4.20E-01 4.40E+00 4.56E-02 2.10E+02 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 2.60E-03 L,J 1.40E-01 mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 4.30E-02 1.40E-01 4.10E-03 2.10E-01 ca NA NA -- (5)132-64-9 Dibenzofuran 4.30E-01 1.20E+01 mg/Kg NPDU-SB12 2 / 13 1.70E-01 - 6.30E+00 1.20E+01 NA 1.00E+02 nc NA NA No BSL84-74-2 Di-n-Butyl Phthalate 2.10E-02 L,J 3.30E-02 L,J mg/Kg NPDU-SB13 4 / 13 1.70E-01 - 6.30E+00 3.30E-02 NA 6.20E+03 nc NA NA No BSL206-44-0 Fluoranthene 8.20E-03 3.00E+01 mg/Kg NPDU-SB12 7 / 13 3.30E-03 - 6.30E+00 3.00E+01 NA 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 5.40E-03 1.80E+01 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 1.80E+01 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 4.10E-03 5.50E-01 mg/Kg NPDU-SB12 9 / 13 3.30E-03 - 4.20E-01 5.50E-01 4.42E-03 2.10E+00 ca NA NA -- (5)91-20-3 Naphthalene 6.70E-03 4.30E+00 J mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 4.20E-01 4.30E+00 NA 1.80E+01 ca NA NA No BSL87-86-5 Pentachlorophenol 4.90E-03 L,J 1.90E+01 mg/Kg NPDU-SB12 7 / 13 6.70E-03 - 1.30E+01 1.90E+01 NA 2.70E+00 ca NA NA Yes ASL85-01-8 Phenanthrene 1.80E-02 6.00E+01 mg/Kg NPDU-SB12 7 / 13 3.30E-03 - 6.30E+00 6.00E+01 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 6.70E-03 2.00E+01 mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 6.30E+00 2.00E+01 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 5.53E-03 2.83E+00 mg/Kg NPDU-SB12 10 / 13 - 2.83E+00 4.25E-01 2.10E-01 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.30E-02 7.20E-02 mg/Kg NPDU-SB13 8 / 12 8.00E-03 - 1.10E-02 7.20E-02 NA 6.30E+04 nc NA NA No BSL100-41-4 Ethylbenzene 1.20E-03 3.60E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 3.60E-03 NA 2.70E+01 ca NA NA No BSL98-82-8 Isopropylbenzene (Cumene) 9.10E-04 L,J 3.40E-03 L,J mg/Kg NPDU-SB13 2 / 12 4.00E-03 - 6.00E-03 3.40E-03 NA 2.68E+02 csat NA NA No BSL

XYLENEMP m,p-Xylene 3.30E-03 9.10E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 9.10E-03 NA 2.58E+02 csat NA NA No BSL78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.30E-02 1.30E-02 mg/Kg NPDU-SB13 1 / 12 8.00E-03 - 1.10E-02 1.30E-02 NA 2.00E+04 nc NA NA No BSL95-47-6 o-Xylene 1.90E-03 5.70E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 5.70E-03 NA 3.00E+02 nc NA NA No BSL108-88-3 Toluene 2.10E-03 3.30E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 3.30E-03 NA 8.18E+02 csat NA NA No BSL

Residential ScenarioSubsurface Soil and SVOCs

Emissions from 92-52-4 1,1'-Biphenyl 5.30E-02 L,J 1.70E+00 L,J mg/Kg NPDU-SB12 2 / 13 1.70E-01 - 6.30E+00 1.70E+00 NA 5.10E+00 nc NA NA No BSLSubsurface Soil 91-57-6 2-Methylnaphthalene 5.80E-03 2.50E+00 mg/Kg NPDU-SB12 3 / 13 4.00E-03 - 4.20E-01 2.50E+00 NA 2.30E+01 nc NA NA No BSL

(Non-Process Area 106-44-5 4-Methylphenol (p-Cresol) 3.80E-02 L,J 3.80E-02 L,J mg/Kg NPDU-SB13 1 / 13 1.70E-01 - 6.30E+00 3.80E-02 NA 6.10E+02 nc NA NA No BSLDecision Unit) 83-32-9 Acenaphthene 5.10E-03 1.60E+01 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 1.60E+01 NA 3.40E+02 nc NA NA No BSL

208-96-8 Acenaphthylene 2.20E-01 2.20E-01 mg/Kg NPDU-SB12 1 / 13 3.30E-03 - 2.20E-01 2.20E-01 NA 3.40E+02 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.4OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009543

North Area, American Creosote Works

Winnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.4OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

98-86-2 Acetophenone 2.10E-02 L,J 2.10E-02 L,J mg/Kg GP-07 1 / 13 1.70E-01 - 6.30E+00 2.10E-02 NA 7.80E+02 nc NA NA No BSL120-12-7 Anthracene 7.20E-03 8.90E+00 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 8.90E+00 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 3.00E-03 L,J 7.60E+00 J mg/Kg NPDU-SB12 6 / 13 3.30E-03 - 4.20E-01 7.60E+00 NA 1.50E-01 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 9.10E-02 1.70E+00 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 4.20E-01 1.70E+00 NA 1.50E-02 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 2.40E-03 L,J 1.60E+00 mg/Kg NPDU-SB12 6 / 13 3.30E-03 - 4.20E-01 1.60E+00 4.33E-03 1.50E-01 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 9.50E-02 L,J 2.20E+00 L,J mg/Kg NPDU-SB12 2 / 13 3.30E-03 - 6.30E+00 2.20E+00 2.80E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 3.20E-02 L,J 1.30E+00 mg/Kg NPDU-SB12 4 / 13 3.30E-03 - 4.20E-01 1.30E+00 1.75E-01 1.50E+00 ca NA NA -- (5)117-81-7 Bis(2-Ethylhexyl)phthalate 1.80E-02 L,J 1.80E-02 L,J mg/Kg NPDU-SB11 1 / 13 1.70E-01 - 6.30E+00 1.80E-02 NA 3.50E+01 ca NA NA No BSL86-74-8 Carbazole 2.60E-02 L,J 2.70E+00 L,J mg/Kg NPDU-SB12 3 / 13 1.70E-01 - 6.30E+00 2.70E+00 NA NA NA NA No NTX218-01-9 Chrysene 2.30E-01 4.40E+00 J mg/Kg NPDU-SB12 2 / 13 3.30E-03 - 4.20E-01 4.40E+00 4.56E-02 1.50E+01 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 2.60E-03 L,J 1.40E-01 mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 4.30E-02 1.40E-01 4.10E-03 1.50E-02 ca NA NA -- (5)132-64-9 Dibenzofuran 4.30E-01 1.20E+01 mg/Kg NPDU-SB12 2 / 13 1.70E-01 - 6.30E+00 1.20E+01 NA 7.80E+00 nc NA NA Yes ASL84-74-2 Di-n-Butyl Phthalate 2.10E-02 L,J 3.30E-02 L,J mg/Kg NPDU-SB13 4 / 13 1.70E-01 - 6.30E+00 3.30E-02 NA 6.10E+02 nc NA NA No BSL206-44-0 Fluoranthene 8.20E-03 3.00E+01 mg/Kg NPDU-SB12 7 / 13 3.30E-03 - 6.30E+00 3.00E+01 NA 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 5.40E-03 1.80E+01 mg/Kg NPDU-SB12 3 / 13 3.30E-03 - 6.30E+00 1.80E+01 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 4.10E-03 5.50E-01 mg/Kg NPDU-SB12 9 / 13 3.30E-03 - 4.20E-01 5.50E-01 4.42E-03 1.50E-01 ca NA NA -- (5)91-20-3 Naphthalene 6.70E-03 4.30E+00 J mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 4.20E-01 4.30E+00 NA 3.60E+00 ca NA NA Yes ASL87-86-5 Pentachlorophenol 4.90E-03 L,J 1.90E+01 mg/Kg NPDU-SB12 7 / 13 6.70E-03 - 1.30E+01 1.90E+01 NA 8.90E-01 ca NA NA Yes ASL85-01-8 Phenanthrene 1.80E-02 6.00E+01 mg/Kg NPDU-SB12 7 / 13 3.30E-03 - 6.30E+00 6.00E+01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 6.70E-03 2.00E+01 mg/Kg NPDU-SB12 5 / 13 3.30E-03 - 6.30E+00 2.00E+01 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 5.53E-03 2.83E+00 mg/Kg NPDU-SB12 10 / 13 - 2.83E+00 4.25E-01 1.50E-02 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.30E-02 7.20E-02 mg/Kg NPDU-SB13 8 / 12 8.00E-03 - 1.10E-02 7.20E-02 NA 6.10E+03 nc NA NA No BSL100-41-4 Ethylbenzene 1.20E-03 3.60E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 3.60E-03 NA 5.40E+00 ca NA NA No BSL98-82-8 Isopropylbenzene (Cumene) 9.10E-04 L,J 3.40E-03 L,J mg/Kg NPDU-SB13 2 / 12 4.00E-03 - 6.00E-03 3.40E-03 NA 2.10E+02 nc NA NA No BSL

XYLENEMP m,p-Xylene 3.30E-03 9.10E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 9.10E-03 NA 6.30E+01 nc NA NA No BSL78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.30E-02 1.30E-02 mg/Kg NPDU-SB13 1 / 12 8.00E-03 - 1.10E-02 1.30E-02 NA 2.80E+03 nc NA NA No BSL95-47-6 o-Xylene 1.90E-03 5.70E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 5.70E-03 NA 6.90E+01 nc NA NA No BSL108-88-3 Toluene 2.10E-03 3.30E-03 mg/Kg NPDU-SB13 2 / 12 1.00E-03 - 1.00E-03 3.30E-03 NA 5.00E+02 nc NA NA No BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2 Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. csat = soil saturationThe SL for acenaphthene was used as the SL for acenaphthylene. nc = noncarcinogenicThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HEAST = Health Effects Assessment Summary TablesNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HQ = hazard quotientThe SL for anthracene was used as the SL for phenanthrene. HHRA = Human Health Risk AssessmentSL for benzo(a)pyrene was used as the SL for total BAP TEQ. NA = not availableThe SL for xylenes was used as the SL for m,p-Xylene (sum of isomers). J = compound was detected below the reporting limit in the sample

L = compound was detected above the Method Detection Limit (MDL) but below the

PAGE 2 OF 3

009544

North Area, American Creosote Works

Winnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.4OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) Contract Required Quantitation Limit (CRQL)Deletion Reason: Below Screening Level (BSL) BAP TEQ = benzo(a)pyrene toxic equivalent

No Toxicity Information (NTX) SL = screening levelSVOC = semi-volatile organic compound

(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, VOC = volatile organic compoundindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. mg/kg = milligram per kilogram

PAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009545

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSurface Soil (0-1 foot bgs) and Dioxins/Furans

Emissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1.65E+03 1.06E+04 ng/kg PADU-SU02 4 / 4 - 1.06E+04 8.54E+02 NA NA NA -- (5)Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.72E+01 6.27E+01 ng/kg PADU-SU02 4 / 4 - 6.27E+01 2.08E+01 NA NA NA -- (5)

(Process Area 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 5.01E+01 2.58E+02 ng/kg PADU-SU02 4 / 4 - 2.58E+02 2.55E+01 NA NA NA -- (5)Decision Unit) 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 3.33E+01 1.10E+02 ng/kg PADU-SU01 4 / 4 - 1.10E+02 2.56E+01 NA NA NA -- (5)

40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 5.57E+00 1.83E+01 ng/kg PADU-SU01 4 / 4 - 1.83E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 3.92E-01 L,J 1.83E+00 L,J ng/kg PADU-SU02 4 / 4 - 1.83E+00 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 3.24E+03 2.85E+04 ng/kg PADU-SU02 4 / 4 - 2.85E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 3.39E+02 J 2.09E+03 J ng/kg PADU-SU02 4 / 4 - 2.09E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.97E+04 J 1.10E+05 J ng/kg PADU-SU02 4 / 4 - 1.10E+05 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 3.43E+01 J 1.24E+02 J ng/kg PADU-DU 4 / 4 - 1.24E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 4.69E+01 2.37E+02 ng/kg PADU-SU02 4 / 4 - 2.37E+02 3.18E+01 1.80E+01 ca NA NA Yes ASL

41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 7.85E+00 1.88E+01 J ng/kg PADU-SU02 4 / 4 - 1.88E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 3.19E+02 1.78E+03 ng/kg PADU-SU02 4 / 4 - 1.78E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.98E+01 1.31E+02 ng/kg PADU-SU02 4 / 4 - 1.31E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.63E+01 J 9.06E+01 J ng/kg PADU-SU02 4 / 4 - 9.06E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 7.30E+00 2.83E+01 ng/kg PADU-SU02 4 / 4 - 2.83E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 3.33E+00 J 1.34E+01 J ng/kg PADU-SU02 4 / 4 - 1.34E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 8.36E-01 L,J 3.25E+00 L,J ng/kg PADU-SU02 4 / 4 - 3.25E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.32E+01 5.08E+01 ng/kg PADU-SU02 4 / 4 - 5.08E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 2.11E+00 L,J 8.70E+00 L,J ng/kg PADU-SU02 4 / 4 - 8.70E+00 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 3.17E-01 L,J 4.72E-01 L,J ng/kg PADU-SU02 4 / 4 - 4.72E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 1.27E+03 7.89E+03 ng/kg PADU-SU02 4 / 4 - 7.89E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 4.19E+02 J 2.11E+03 J ng/kg PADU-SU02 4 / 4 - 2.11E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.08E+03 6.65E+03 ng/kg PADU-SU02 4 / 4 - 6.65E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 4.98E+01 J 1.75E+02 J ng/kg PADU-SU02 4 / 4 - 1.75E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 7.58E+00 J 1.77E+01 J ng/kg PADU-SU02 4 / 4 - 1.77E+01 2.73E+01 NA NA NA -- (5)

SVOCs92-52-4 1,1'-Biphenyl 3.20E-02 L,J 2.70E+01 mg/kg PADU-SB08 3 / 15 2.00E-01 - 5.80E+00 2.70E+01 NA 2.10E+01 nc NA NA Yes ASL58-90-2 2,3,4,6-Tetrachlorophenol 6.80E-02 L,J 7.90E+01 mg/kg PADU-SB08 4 / 15 2.00E-01 - 5.80E+00 7.90E+01 NA 1.80E+03 nc NA NA No BSL91-57-6 2-Methylnaphthalene 5.60E-03 6.60E+01 L,J mg/kg PADU-SB08 10 / 15 3.80E-03 - 5.70E+02 6.60E+01 NA 2.20E+02 nc NA NA No BSL91-94-1 3,3'-Dichlorobenzidine 6.10E-01 L,J 6.10E-01 L,J mg/kg PADU-SB02 1 / 15 2.00E-01 - 5.80E+00 6.10E-01 NA 3.80E+00 ca NA NA No BSL106-44-5 4-Methylphenol (p-Cresol) 7.40E-01 L,J 7.40E-01 L,J mg/kg PADU-SB08 1 / 15 2.00E-01 - 5.80E+00 7.40E-01 2.07E-01 6.20E+03 nc NA NA No BSL83-32-9 Acenaphthene 2.40E-02 L,J 2.50E+02 L,J mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.70E+02 2.50E+02 NA 3.30E+03 nc NA NA No BSL208-96-8 Acenaphthylene 2.60E-01 L,J 6.40E+00 mg/kg PADU-SB08 3 / 15 2.00E-01 - 5.60E+00 6.40E+00 NA 3.30E+03 nc NA NA No BSL98-86-2 Acetophenone 1.90E+00 L,J 1.90E+00 L,J mg/kg PADU-SB08 1 / 15 2.00E-01 - 5.80E+00 1.90E+00 NA 2.52E+03 csat NA NA No BSL120-12-7 Anthracene 2.20E-02 L,J 6.30E+02 mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.70E+02 6.30E+02 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 1.30E-02 J 1.20E+02 L,J mg/kg PADU-SB08 15 / 15 3.90E-03 - 5.70E+02 1.20E+02 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.20E-02 3.20E+01 mg/kg PADU-SB08 15 / 15 3.80E-03 - 5.80E+00 3.20E+01 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 1.30E-02 6.00E+01 mg/kg PADU-SB08 15 / 15 3.90E-03 - 5.80E+00 6.00E+01 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 2.10E-02 L,J 1.00E+01 mg/kg PADU-SB08 15 / 15 2.00E-01 - 5.80E+00 1.00E+01 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 5.50E-02 L,J 4.20E+01 mg/kg PADU-SB08 14 / 15 9.30E-02 - 5.80E+00 4.20E+01 1.78E-01 2.10E+01 ca NA NA -- (6)85-68-7 Benzyl Butyl Phthalate 3.00E-01 L,J 6.60E-01 L,J mg/kg PADU-SB08 2 / 15 2.00E-01 - 5.80E+00 6.60E-01 1.74E-01 9.10E+02 ca NA NA No BSL117-81-7 Bis(2-Ethylhexyl)phthalate 2.00E-02 L,J 8.20E-01 L,J mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.80E+00 8.20E-01 NA 1.20E+02 ca NA NA No BSL86-74-8 Carbazole 1.10E-01 L,J 1.10E+02 L,J mg/kg PADU-SB08 5 / 15 2.00E-01 - 5.70E+02 1.10E+02 NA NA NA NA NA No NTX218-01-9 Chrysene 1.20E-01 L,J 2.20E+02 L,J mg/kg PADU-SB08 13 / 15 9.30E-02 - 5.70E+02 2.20E+02 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 1.20E-02 6.90E+00 mg/kg PADU-SB08 14 / 15 3.80E-03 - 5.80E+00 6.90E+00 1.00E-02 2.10E-01 ca NA NA -- (6)

Qualifier Qualifier

TABLE 2.5OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009546

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.5OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

132-64-9 Dibenzofuran 2.00E-02 L,J 1.90E+02 L,J mg/kg PADU-SB08 6 / 15 2.00E-01 - 5.70E+02 1.90E+02 NA 1.00E+02 nc NA NA Yes ASL84-74-2 Di-n-Butyl Phthalate 2.50E-02 L,J 5.20E-02 L,J mg/kg PADU-SB11 4 / 15 2.00E-01 - 5.80E+00 5.20E-02 NA 6.20E+03 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 1.70E-02 L,J 5.60E-01 L,J mg/kg PADU-SB02 2 / 15 2.00E-01 - 5.80E+00 5.60E-01 NA 6.20E+02 nc NA NA No BSL206-44-0 Fluoranthene 5.00E-02 L,J 5.60E+02 L,J mg/kg PADU-SB08 15 / 15 2.00E-01 - 5.70E+02 5.60E+02 1.79E-01 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 4.30E-02 L,J 2.30E+02 L,J mg/kg PADU-SB08 5 / 15 2.00E-01 - 5.70E+02 2.30E+02 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.30E-02 1.60E+01 mg/kg PADU-SB08 15 / 15 3.80E-03 - 5.70E+00 1.60E+01 3.10E-02 2.10E+00 ca NA NA -- (6)91-20-3 Naphthalene 8.80E-03 2.00E+02 L,J mg/kg PADU-SB08 10 / 15 3.80E-03 - 5.70E+02 2.00E+02 NA 1.80E+01 ca NA NA Yes ASL87-86-5 Pentachlorophenol 1.50E-02 J 5.30E+03 mg/kg PADU-SB08 15 / 15 7.70E-03 - 1.10E+03 5.30E+03 9.60E-03 2.70E+00 ca NA NA Yes ASL85-01-8 Phenanthrene 1.80E-02 L,J 1.00E+03 mg/kg PADU-SB08 13 / 15 2.00E-01 - 5.70E+02 1.00E+03 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 4.30E-02 L,J 4.20E+02 L,J mg/kg PADU-SB08 14 / 15 2.00E-01 - 5.70E+02 4.20E+02 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 1.59E-02 5.91E+01 mg/kg PADU-SB08 15 / 15 0.00E+00 - 0.00E+00 5.91E+01 4.32E-01 2.10E-01 ca NA NA Yes ASL

VOC67-64-1 Acetone 1.70E-02 1.70E-02 mg/kg PADU-SB01 1 / 1 1.10E-02 - 1.10E-02 1.70E-02 NA 6.30E+04 nc NA NA No BSL

Residential ScenarioSurface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1.65E+03 1.06E+04 ng/kg PADU-SU02 4 / 4 - 1.06E+04 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.72E+01 6.27E+01 ng/kg PADU-SU02 4 / 4 - 6.27E+01 2.08E+01 NA NA NA -- (5)(Process Area 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 5.01E+01 2.58E+02 ng/kg PADU-SU02 4 / 4 - 2.58E+02 2.55E+01 NA NA NA -- (5)Decision Unit) 19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 3.33E+01 1.10E+02 ng/kg PADU-SU01 4 / 4 - 1.10E+02 2.56E+01 NA NA NA -- (5)

40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 5.57E+00 1.83E+01 ng/kg PADU-SU01 4 / 4 - 1.83E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 3.92E-01 L,J 1.83E+00 L,J ng/kg PADU-SU02 4 / 4 - 1.83E+00 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 3.24E+03 2.85E+04 ng/kg PADU-SU02 4 / 4 - 2.85E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 3.39E+02 J 2.09E+03 J ng/kg PADU-SU02 4 / 4 - 2.09E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.97E+04 J 1.10E+05 J ng/kg PADU-SU02 4 / 4 - 1.10E+05 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 3.43E+01 J 1.24E+02 J ng/kg PADU-DU 4 / 4 - 1.24E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 4.69E+01 2.37E+02 ng/kg PADU-SU02 4 / 4 - 2.37E+02 3.18E+01 4.50E+00 ca NA NA Yes ASL

41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 7.85E+00 1.88E+01 J ng/kg PADU-SU02 4 / 4 - 1.88E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 3.19E+02 1.78E+03 ng/kg PADU-SU02 4 / 4 - 1.78E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.98E+01 1.31E+02 ng/kg PADU-SU02 4 / 4 - 1.31E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.63E+01 J 9.06E+01 J ng/kg PADU-SU02 4 / 4 - 9.06E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 7.30E+00 2.83E+01 ng/kg PADU-SU02 4 / 4 - 2.83E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 3.33E+00 J 1.34E+01 J ng/kg PADU-SU02 4 / 4 - 1.34E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 8.36E-01 L,J 3.25E+00 L,J ng/kg PADU-SU02 4 / 4 - 3.25E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.32E+01 5.08E+01 ng/kg PADU-SU02 4 / 4 - 5.08E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 2.11E+00 L,J 8.70E+00 L,J ng/kg PADU-SU02 4 / 4 - 8.70E+00 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 3.17E-01 L,J 4.72E-01 L,J ng/kg PADU-SU02 4 / 4 - 4.72E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 1.27E+03 7.89E+03 ng/kg PADU-SU02 4 / 4 - 7.89E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 4.19E+02 J 2.11E+03 J ng/kg PADU-SU02 4 / 4 - 2.11E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.08E+03 6.65E+03 ng/kg PADU-SU02 4 / 4 - 6.65E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 4.98E+01 J 1.75E+02 J ng/kg PADU-SU02 4 / 4 - 1.75E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 7.58E+00 J 1.77E+01 J ng/kg PADU-SU02 4 / 4 - 1.77E+01 2.73E+01 NA NA NA -- (5)

SVOCs92-52-4 1,1'-Biphenyl 3.20E-02 L,J 2.70E+01 mg/kg PADU-SB08 3 / 15 2.00E-01 - 5.80E+00 2.70E+01 NA 5.10E+00 nc NA NA Yes ASL58-90-2 2,3,4,6-Tetrachlorophenol 6.80E-02 L,J 7.90E+01 mg/kg PADU-SB08 4 / 15 2.00E-01 - 5.80E+00 7.90E+01 NA 1.80E+02 nc NA NA No BSL91-57-6 2-Methylnaphthalene 5.60E-03 6.60E+01 L,J mg/kg PADU-SB08 10 / 15 3.80E-03 - 5.70E+02 6.60E+01 NA 2.30E+01 nc NA NA Yes ASL91-94-1 3,3'-Dichlorobenzidine 6.10E-01 L,J 6.10E-01 L,J mg/kg PADU-SB02 1 / 15 2.00E-01 - 5.80E+00 6.10E-01 NA 1.10E+00 ca NA NA No BSL106-44-5 4-Methylphenol (p-Cresol) 7.40E-01 L,J 7.40E-01 L,J mg/kg PADU-SB08 1 / 15 2.00E-01 - 5.80E+00 7.40E-01 2.07E-01 6.10E+02 nc NA NA No BSL83-32-9 Acenaphthene 2.40E-02 L,J 2.50E+02 L,J mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.70E+02 2.50E+02 NA 3.40E+02 nc NA NA No BSL208-96-8 Acenaphthylene 2.60E-01 L,J 6.40E+00 mg/kg PADU-SB08 3 / 15 2.00E-01 - 5.60E+00 6.40E+00 NA 3.40E+02 nc NA NA No BSL

PAGE 2 OF 3

009547

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.5OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

98-86-2 Acetophenone 1.90E+00 L,J 1.90E+00 L,J mg/kg PADU-SB08 1 / 15 2.00E-01 - 5.80E+00 1.90E+00 NA 7.80E+02 nc NA NA No BSL120-12-7 Anthracene 2.20E-02 L,J 6.30E+02 mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.70E+02 6.30E+02 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 1.30E-02 J 1.20E+02 L,J mg/kg PADU-SB08 15 / 15 3.90E-03 - 5.70E+02 1.20E+02 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.20E-02 3.20E+01 mg/kg PADU-SB08 15 / 15 3.80E-03 - 5.80E+00 3.20E+01 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 1.30E-02 6.00E+01 mg/kg PADU-SB08 15 / 15 3.90E-03 - 5.80E+00 6.00E+01 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 2.10E-02 L,J 1.00E+01 mg/kg PADU-SB08 15 / 15 2.00E-01 - 5.80E+00 1.00E+01 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 5.50E-02 L,J 4.20E+01 mg/kg PADU-SB08 14 / 15 9.30E-02 - 5.80E+00 4.20E+01 1.78E-01 1.50E+00 ca NA NA -- (6)85-68-7 Benzyl Butyl Phthalate 3.00E-01 L,J 6.60E-01 L,J mg/kg PADU-SB08 2 / 15 2.00E-01 - 5.80E+00 6.60E-01 1.74E-01 2.60E+02 ca NA NA No BSL117-81-7 Bis(2-Ethylhexyl)phthalate 2.00E-02 L,J 8.20E-01 L,J mg/kg PADU-SB08 7 / 15 2.00E-01 - 5.80E+00 8.20E-01 NA 3.50E+01 ca NA NA No BSL86-74-8 Carbazole 1.10E-01 L,J 1.10E+02 L,J mg/kg PADU-SB08 5 / 15 2.00E-01 - 5.70E+02 1.10E+02 NA NA NA NA NA No NTX218-01-9 Chrysene 1.20E-01 L,J 2.20E+02 L,J mg/kg PADU-SB08 13 / 15 9.30E-02 - 5.70E+02 2.20E+02 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 1.20E-02 6.90E+00 mg/kg PADU-SB08 14 / 15 3.80E-03 - 5.80E+00 6.90E+00 1.00E-02 1.50E-02 ca NA NA -- (6)132-64-9 Dibenzofuran 2.00E-02 L,J 1.90E+02 L,J mg/kg PADU-SB08 6 / 15 2.00E-01 - 5.70E+02 1.90E+02 NA 7.80E+00 nc NA NA Yes ASL84-74-2 Di-n-Butyl Phthalate 2.50E-02 L,J 5.20E-02 L,J mg/kg PADU-SB11 4 / 15 2.00E-01 - 5.80E+00 5.20E-02 NA 6.10E+02 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 1.70E-02 L,J 5.60E-01 L,J mg/kg PADU-SB02 2 / 15 2.00E-01 - 5.80E+00 5.60E-01 NA 6.10E+01 nc NA NA No BSL206-44-0 Fluoranthene 5.00E-02 L,J 5.60E+02 L,J mg/kg PADU-SB08 15 / 15 2.00E-01 - 5.70E+02 5.60E+02 1.79E-01 2.30E+02 nc NA NA Yes ASL86-73-7 Fluorene 4.30E-02 L,J 2.30E+02 L,J mg/kg PADU-SB08 5 / 15 2.00E-01 - 5.70E+02 2.30E+02 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.30E-02 1.60E+01 mg/kg PADU-SB08 15 / 15 3.80E-03 - 5.70E+00 1.60E+01 3.10E-02 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 8.80E-03 2.00E+02 L,J mg/kg PADU-SB08 10 / 15 3.80E-03 - 5.70E+02 2.00E+02 NA 3.60E+00 ca NA NA Yes ASL87-86-5 Pentachlorophenol 1.50E-02 J 5.30E+03 mg/kg PADU-SB08 15 / 15 7.70E-03 - 1.10E+03 5.30E+03 9.60E-03 8.90E-01 ca NA NA Yes ASL85-01-8 Phenanthrene 1.80E-02 L,J 1.00E+03 mg/kg PADU-SB08 13 / 15 2.00E-01 - 5.70E+02 1.00E+03 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 4.30E-02 L,J 4.20E+02 L,J mg/kg PADU-SB08 14 / 15 2.00E-01 - 5.70E+02 4.20E+02 NA 1.70E+02 nc NA NA Yes ASLBAPTEQ Total BAP TEQ 1.59E-02 5.91E+01 mg/kg PADU-SB08 15 / 15 0.00E+00 - 0.00E+00 5.91E+01 4.32E-01 1.50E-02 ca NA NA Yes ASL

VOC67-64-1 Acetone 1.70E-02 1.70E-02 mg/kg PADU-SB01 1 / 1 1.10E-02 - 1.10E-02 1.70E-02 NA 6.10E+03 nc NA NA No BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for pyrene was used as the SL for benzo(g,h,i)perylene. HEAST = Health Effects Assessment Summary TablesNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HQ = hazard quotientThe SL for anthracene was used as the SL for phenanthrene. HHRA = Human Health Risk AssessmentSL for benzo(a)pyrene was used as the SL for 'Total BAP TEQ'. J = compound was detected below the reporting limit in the sample

L = compound was detected above the Method Detection Limit (MDL) but (4) Rationale Codes Selection Reason: Above Screening Levels (ASL) below the Contract Required Quantitation Limit (CRQL)

Deletion Reason: Below Screening Level (BSL) NA = not availableNo Toxicity Information (NTX) SL = screening level

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." SVOC = semi-volatile organic compoundVOC = volatile organic compound

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, TEQ = toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." mg/kg = milligram per kilogram

ng/kg = nanogram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009548

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSubsurface Soil (1-10 feet bgs) SVOCs

and Emissions from 92-52-4 1,1'-Biphenyl 1.90E-02 L,J 4.40E+02 mg/kg GP-17 45 / 79 5.65E-02 - 5.30E+02 4.40E+02 NA 2.10E+01 nc NA NA Yes ASLSubsurface Soil 58-90-2 2,3,4,6-Tetrachlorophenol 4.20E-02 L,J 9.80E+02 mg/kg GP-26 9 / 59 1.70E-01 - 4.80E+02 9.80E+02 NA 1.80E+03 nc NA NA No BSL(Process Area 95-95-4 2,4,5-Trichlorophenol 6.64E-02 8.90E+00 L,J mg/kg GP-27 3 / 79 5.65E-02 - 9.90E+01 8.90E+00 NA 6.20E+03 nc NA NA No BSLDecision Unit) 88-06-2 2,4,6-Trichlorophenol 5.12E-01 5.12E-01 mg/kg GP-39 1 / 79 5.65E-02 - 9.90E+01 5.12E-01 NA 6.20E+01 nc NA NA No BSL

120-83-2 2,4-Dichlorophenol 1.00E-01 3.45E-01 mg/kg GP-39 2 / 79 5.65E-02 - 9.90E+01 3.45E-01 NA 1.80E+02 nc NA NA No BSL105-67-9 2,4-Dimethylphenol 3.40E-02 L,J 1.80E+02 mg/kg GP-17 21 / 79 1.13E-01 - 9.90E+01 1.80E+02 NA 1.20E+03 nc NA NA No BSL91-57-6 2-Methylnaphthalene 4.50E-03 2.60E+03 mg/kg GP-17 51 / 79 3.60E-03 - 5.30E+02 2.60E+03 NA 2.20E+02 nc NA NA Yes ASL95-48-7 2-Methylphenol (o-Cresol) 2.10E-02 L,J 9.10E+01 mg/kg GP-17 13 / 79 5.65E-02 - 9.90E+01 9.10E+01 NA 3.10E+03 nc NA NA No BSL106-44-5 4-Methylphenol (p-Cresol) 1.90E-02 L,J 1.40E+02 mg/kg GP-17 11 / 60 1.70E-01 - 9.90E+01 1.40E+02 NA 6.20E+03 nc NA NA No BSL83-32-9 Acenaphthene 4.50E-03 2.70E+03 mg/kg GP-17 60 / 79 3.30E-03 - 5.30E+02 2.70E+03 NA 3.30E+03 nc NA NA No BSL208-96-8 Acenaphthylene 3.60E-03 1.10E+02 mg/kg GP-17 60 / 79 3.30E-03 - 9.90E+01 1.10E+02 NA 3.30E+03 nc NA NA No BSL98-86-2 Acetophenone 1.80E-02 L,J 4.80E+00 mg/kg GP-12 18 / 79 5.65E-02 - 9.90E+01 4.80E+00 NA 2.52E+03 csat NA NA No BSL120-12-7 Anthracene 4.20E-03 2.84E+03 mg/kg GP-23 68 / 79 3.30E-03 - 5.30E+02 2.84E+03 NA 1.70E+04 nc NA NA No BSL100-52-7 Benzaldehyde 1.80E-02 L,J 1.30E-01 L,J mg/kg GP-09 5 / 79 1.13E-01 - 9.90E+01 1.30E-01 NA 1.16E+03 csat NA NA No BSL56-55-3 Benzo(a)anthracene 3.90E-03 5.65E+02 mg/kg GP-22 68 / 79 3.30E-03 - 5.30E+02 5.65E+02 NA 2.10E+00 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 9.40E-03 1.87E+02 mg/kg GP-22 64 / 79 3.30E-03 - 5.30E+02 1.87E+02 NA 2.10E-01 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 5.00E-03 2.80E+02 L,J mg/kg GP-12 67 / 79 3.30E-03 - 5.30E+02 2.80E+02 4.33E-03 2.10E+00 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 4.30E-03 5.00E+01 mg/kg GP-04 59 / 79 3.30E-03 - 9.90E+01 5.00E+01 2.80E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 3.70E-03 1.98E+02 mg/kg GP-22 63 / 79 3.30E-03 - 4.80E+02 1.98E+02 1.75E-01 2.10E+01 ca NA NA -- (5)85-68-7 Benzyl Butyl Phthalate 2.20E-01 L,J 2.20E-01 L,J mg/kg PADU-SB02 1 / 79 1.70E-01 - 9.90E+01 2.20E-01 1.82E-01 9.10E+02 ca NA NA No BSL117-81-7 Bis(2-Ethylhexyl)phthalate 1.80E-02 L,J 1.79E+00 B mg/kg GP-39 15 / 79 1.70E-01 - 9.90E+01 1.79E+00 NA 1.20E+02 ca NA NA No BSL86-74-8 Carbazole 1.90E-02 L,J 9.75E+02 J mg/kg GP-23 51 / 79 5.83E-02 - 5.35E+02 9.75E+02 NA NA NA NA NA No NTX75-15-0 Carbon Disulfide 2.60E-03 L,J 4.60E-03 mg/kg PADU-SB09 2 / 11 4.10E-03 - 5.30E-03 4.60E-03 NA 3.70E+02 nc NA NA No BSL218-01-9 Chrysene 3.40E-03 8.05E+02 mg/kg GP-22 63 / 79 3.30E-03 - 5.30E+02 8.05E+02 4.56E-02 2.10E+02 ca NA NA -- (5)

108394/106445 3&4-Methylphenol (m&p-Cresol) 1.13E-01 1.73E+01 mg/kg GP-18 4 / 19 5.65E-02 - 5.68E+00 1.73E+01 NA 3.10E+03 nc NA NA No BSL53-70-3 Dibenz(a,h)anthracene 4.80E-03 2.50E+01 L,J mg/kg GP-17 54 / 79 3.30E-03 - 9.90E+01 2.50E+01 4.10E-03 2.10E-01 ca NA NA -- (5)132-64-9 Dibenzofuran 2.90E-02 L,J 1.90E+03 mg/kg GP-17 52 / 79 5.83E-02 - 5.67E+02 1.90E+03 NA 1.00E+02 nc NA NA Yes ASL84-66-2 Diethyl Phthalate 5.90E-01 L,J 5.90E-01 L,J mg/kg PADU-SB08 1 / 79 1.70E-01 - 9.90E+01 5.90E-01 NA 4.90E+04 nc NA NA No BSL84-74-2 Di-n-Butyl Phthalate 2.00E-02 L,J 4.00E-02 L,J mg/kg PADU-SB12 5 / 79 1.70E-01 - 9.90E+01 4.00E-02 NA 6.20E+03 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 2.50E-01 L,J 8.50E-01 L,J mg/kg GP-05 3 / 79 1.70E-01 - 9.90E+01 8.50E-01 NA 6.20E+02 nc NA NA No BSL206-44-0 Fluoranthene 4.00E-03 3.60E+03 L,J mg/kg GP-26 68 / 79 3.30E-03 - 4.00E+03 3.60E+03 NA 2.20E+03 nc NA NA Yes ASL86-73-7 Fluorene 3.40E-03 2.10E+03 mg/kg GP-17 63 / 79 3.30E-03 - 5.30E+02 2.10E+03 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 4.20E-03 7.70E+01 mg/kg GP-17 64 / 79 3.30E-03 - 9.90E+01 7.70E+01 4.42E-03 2.10E+00 ca NA NA -- (5)91-20-3 Naphthalene 3.50E-03 6.40E+03 mg/kg GP-03 59 / 79 3.30E-03 - 5.30E+02 6.40E+03 NA 1.80E+01 ca NA NA Yes ASL87-86-5 Pentachlorophenol 5.30E-03 L,J 4.20E+04 J mg/kg GP-26 58 / 79 6.60E-03 - 7.90E+03 4.20E+04 NA 2.70E+00 ca NA NA Yes ASL85-01-8 Phenanthrene 5.80E-03 9.00E+03 mg/kg GP-26 66 / 79 3.30E-03 - 4.00E+03 9.00E+03 NA 1.70E+04 nc NA NA No BSL108-95-2 Phenol 6.60E-02 L,J 7.50E+01 mg/kg GP-17 8 / 79 5.65E-02 - 9.90E+01 7.50E+01 NA 1.80E+04 nc NA NA No BSL129-00-0 Pyrene 4.50E-03 2.17E+03 mg/kg GP-22 69 / 79 3.30E-03 - 5.30E+02 2.17E+03 NA 1.70E+03 nc NA NA Yes ASLBAPTEQ Total BAP TEQ 3.40E-06 2.96E+02 mg/kg GP-22 70 / 79 0.00E+00 - 0.00E+00 2.96E+02 4.25E-01 2.10E-01 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.00E-02 1.20E-01 mg/kg PADU-SB03 11 / 11 8.30E-03 - 1.10E-02 1.20E-01 NA 6.30E+04 nc NA NA No BSL71-43-2 Benzene 2.00E-03 2.00E-03 mg/kg PADU-SB07 1 / 11 8.30E-04 - 1.10E-03 2.00E-03 NA 5.40E+00 ca NA NA No BSL100-41-4 Ethylbenzene 1.20E-03 1.20E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 1.20E-03 NA 2.70E+01 ca NA NA No BSL

XYLENEMP m,p-Xylene 3.10E-03 3.10E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 3.10E-03 NA 2.58E+02 csat NA NA No BSL78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.10E-02 2.10E-02 mg/kg PADU-SB03 1 / 11 8.30E-03 - 1.10E-02 2.10E-02 NA 2.00E+04 nc NA NA No BSL95-47-6 o-Xylene 3.10E-03 3.10E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 3.10E-03 NA 3.00E+02 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.6OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009549

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.6OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

108-88-3 Toluene 3.40E-03 3.40E-03 mg/kg PADU-SB07 1 / 11 8.30E-04 - 1.10E-03 3.40E-03 NA 8.18E+02 csat NA NA No BSLResidential Scenario

Subsurface Soil and SVOCsEmissions from 92-52-4 1,1'-Biphenyl 1.90E-02 L,J 4.40E+02 mg/kg GP-17 45 / 79 5.65E-02 - 5.30E+02 4.40E+02 NA 5.10E+00 nc NA NA Yes ASLSubsurface Soil 58-90-2 2,3,4,6-Tetrachlorophenol 4.20E-02 L,J 9.80E+02 mg/kg GP-26 9 / 59 1.70E-01 - 4.80E+02 9.80E+02 NA 1.80E+02 nc NA NA Yes ASL(Process Area 95-95-4 2,4,5-Trichlorophenol 6.64E-02 8.90E+00 L,J mg/kg GP-27 3 / 79 5.65E-02 - 9.90E+01 8.90E+00 NA 6.10E+02 nc NA NA No BSLDecision Unit) 88-06-2 2,4,6-Trichlorophenol 5.12E-01 5.12E-01 mg/kg GP-39 1 / 79 5.65E-02 - 9.90E+01 5.12E-01 NA 6.10E+00 nc NA NA No BSL

120-83-2 2,4-Dichlorophenol 1.00E-01 3.45E-01 mg/kg GP-39 2 / 79 5.65E-02 - 9.90E+01 3.45E-01 NA 1.80E+01 nc NA NA No BSL105-67-9 2,4-Dimethylphenol 3.40E-02 L,J 1.80E+02 mg/kg GP-17 21 / 79 1.13E-01 - 9.90E+01 1.80E+02 NA 1.20E+02 nc NA NA Yes ASL91-57-6 2-Methylnaphthalene 4.50E-03 2.60E+03 mg/kg GP-17 51 / 79 3.60E-03 - 5.30E+02 2.60E+03 NA 2.30E+01 nc NA NA Yes ASL95-48-7 2-Methylphenol (o-Cresol) 2.10E-02 L,J 9.10E+01 mg/kg GP-17 13 / 79 5.65E-02 - 9.90E+01 9.10E+01 NA 3.10E+02 nc NA NA No BSL106-44-5 4-Methylphenol (p-Cresol) 1.90E-02 L,J 1.40E+02 mg/kg GP-17 11 / 60 1.70E-01 - 9.90E+01 1.40E+02 NA 6.10E+02 nc NA NA No BSL83-32-9 Acenaphthene 4.50E-03 2.70E+03 mg/kg GP-17 60 / 79 3.30E-03 - 5.30E+02 2.70E+03 NA 3.40E+02 nc NA NA Yes ASL208-96-8 Acenaphthylene 3.60E-03 1.10E+02 mg/kg GP-17 60 / 79 3.30E-03 - 9.90E+01 1.10E+02 NA 3.40E+02 nc NA NA No BSL98-86-2 Acetophenone 1.80E-02 L,J 4.80E+00 mg/kg GP-12 18 / 79 5.65E-02 - 9.90E+01 4.80E+00 NA 7.80E+02 nc NA NA No BSL120-12-7 Anthracene 4.20E-03 2.84E+03 mg/kg GP-23 68 / 79 3.30E-03 - 5.30E+02 2.84E+03 NA 1.70E+03 nc NA NA Yes ASL100-52-7 Benzaldehyde 1.80E-02 L,J 1.30E-01 L,J mg/kg GP-09 5 / 79 1.13E-01 - 9.90E+01 1.30E-01 NA 7.80E+02 nc NA NA No BSL56-55-3 Benzo(a)anthracene 3.90E-03 5.65E+02 mg/kg GP-22 68 / 79 3.30E-03 - 5.30E+02 5.65E+02 NA 1.50E-01 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 9.40E-03 1.87E+02 mg/kg GP-22 64 / 79 3.30E-03 - 5.30E+02 1.87E+02 NA 1.50E-02 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 5.00E-03 2.80E+02 L,J mg/kg GP-12 67 / 79 3.30E-03 - 5.30E+02 2.80E+02 4.33E-03 1.50E-01 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 4.30E-03 5.00E+01 mg/kg GP-04 59 / 79 3.30E-03 - 9.90E+01 5.00E+01 2.80E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 3.70E-03 1.98E+02 mg/kg GP-22 63 / 79 3.30E-03 - 4.80E+02 1.98E+02 1.75E-01 1.50E+00 ca NA NA -- (5)85-68-7 Benzyl Butyl Phthalate 2.20E-01 L,J 2.20E-01 L,J mg/kg PADU-SB02 1 / 79 1.70E-01 - 9.90E+01 2.20E-01 1.82E-01 2.60E+02 ca NA NA No BSL117-81-7 Bis(2-Ethylhexyl)phthalate 1.80E-02 L,J 1.79E+00 B mg/kg GP-39 15 / 79 1.70E-01 - 9.90E+01 1.79E+00 NA 3.50E+01 ca NA NA No BSL86-74-8 Carbazole 1.90E-02 L,J 9.75E+02 J mg/kg GP-23 51 / 79 5.83E-02 - 5.35E+02 9.75E+02 NA NA NA NA NA No NTX75-15-0 Carbon Disulfide 2.60E-03 L,J 4.60E-03 mg/kg PADU-SB09 2 / 11 4.10E-03 - 5.30E-03 4.60E-03 NA 8.20E+01 nc NA NA No BSL218-01-9 Chrysene 3.40E-03 8.05E+02 mg/kg GP-22 63 / 79 3.30E-03 - 5.30E+02 8.05E+02 4.56E-02 1.50E+01 ca NA NA -- (5)

108394/106445 3&4-Methylphenol (m&p-Cresol) 1.13E-01 1.73E+01 mg/kg GP-18 4 / 19 5.65E-02 - 5.68E+00 1.73E+01 NA 3.10E+02 nc NA NA No BSL53-70-3 Dibenz(a,h)anthracene 4.80E-03 2.50E+01 L,J mg/kg GP-17 54 / 79 3.30E-03 - 9.90E+01 2.50E+01 4.10E-03 1.50E-02 ca NA NA -- (5)132-64-9 Dibenzofuran 2.90E-02 L,J 1.90E+03 mg/kg GP-17 52 / 79 5.83E-02 - 5.67E+02 1.90E+03 NA 7.80E+00 nc NA NA Yes ASL84-66-2 Diethyl Phthalate 5.90E-01 L,J 5.90E-01 L,J mg/kg PADU-SB08 1 / 79 1.70E-01 - 9.90E+01 5.90E-01 NA 4.90E+03 nc NA NA No BSL84-74-2 Di-n-Butyl Phthalate 2.00E-02 L,J 4.00E-02 L,J mg/kg PADU-SB12 5 / 79 1.70E-01 - 9.90E+01 4.00E-02 NA 6.10E+02 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 2.50E-01 L,J 8.50E-01 L,J mg/kg GP-05 3 / 79 1.70E-01 - 9.90E+01 8.50E-01 NA 6.10E+01 nc NA NA No BSL206-44-0 Fluoranthene 4.00E-03 3.60E+03 L,J mg/kg GP-26 68 / 79 3.30E-03 - 4.00E+03 3.60E+03 NA 2.30E+02 nc NA NA Yes ASL86-73-7 Fluorene 3.40E-03 2.10E+03 mg/kg GP-17 63 / 79 3.30E-03 - 5.30E+02 2.10E+03 NA 2.30E+02 nc NA NA Yes ASL193-39-5 Indeno(1,2,3-c,d)Pyrene 4.20E-03 7.70E+01 mg/kg GP-17 64 / 79 3.30E-03 - 9.90E+01 7.70E+01 4.42E-03 1.50E-01 ca NA NA -- (5)91-20-3 Naphthalene 3.50E-03 6.40E+03 mg/kg GP-03 59 / 79 3.30E-03 - 5.30E+02 6.40E+03 NA 3.60E+00 ca NA NA Yes ASL87-86-5 Pentachlorophenol 5.30E-03 L,J 4.20E+04 J mg/kg GP-26 58 / 79 6.60E-03 - 7.90E+03 4.20E+04 NA 8.90E-01 ca NA NA Yes ASL85-01-8 Phenanthrene 5.80E-03 9.00E+03 mg/kg GP-26 66 / 79 3.30E-03 - 4.00E+03 9.00E+03 NA 1.70E+03 nc NA NA Yes ASL108-95-2 Phenol 6.60E-02 L,J 7.50E+01 mg/kg GP-17 8 / 79 5.65E-02 - 9.90E+01 7.50E+01 NA 1.80E+03 nc NA NA No BSL129-00-0 Pyrene 4.50E-03 2.17E+03 mg/kg GP-22 69 / 79 3.30E-03 - 5.30E+02 2.17E+03 NA 1.70E+02 nc NA NA Yes ASLBAPTEQ Total BAP TEQ 3.40E-06 2.96E+02 mg/kg GP-22 70 / 79 0.00E+00 - 0.00E+00 2.96E+02 4.25E-01 1.50E-02 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.00E-02 1.20E-01 mg/kg PADU-SB03 11 / 11 8.30E-03 - 1.10E-02 1.20E-01 NA 6.10E+03 nc NA NA No BSL71-43-2 Benzene 2.00E-03 2.00E-03 mg/kg PADU-SB07 1 / 11 8.30E-04 - 1.10E-03 2.00E-03 NA 1.10E+00 ca NA NA No BSL100-41-4 Ethylbenzene 1.20E-03 1.20E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 1.20E-03 NA 5.40E+00 ca NA NA No BSL

XYLENEMP m,p-Xylene 3.10E-03 3.10E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 3.10E-03 NA 6.30E+01 nc NA NA No BSL78-93-3 Methyl Ethyl Ketone (2-Butanone) 2.10E-02 2.10E-02 mg/kg PADU-SB03 1 / 11 8.30E-03 - 1.10E-02 2.10E-02 NA 2.80E+03 nc NA NA No BSL95-47-6 o-Xylene 3.10E-03 3.10E-03 mg/kg PADU-SB08 1 / 11 8.30E-04 - 1.10E-03 3.10E-03 NA 6.90E+01 nc NA NA No BSL

PAGE 2 OF 3

009550

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.6OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

108-88-3 Toluene 3.40E-03 3.40E-03 mg/kg PADU-SB07 1 / 11 8.30E-04 - 1.10E-03 3.40E-03 NA 5.00E+02 nc NA NA No BSL

(1) Maximum concentration is used for screening. v = low estimate

COPC = chemical of potential concern(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/

To Be Considered(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenic

adjusted using HQ=0.1. csat = soil saturationThe SL for acenaphthene was used as the SL for acenaphthylene. nc = noncarcinogenicThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HEAST = Health Effects Assessment Summary TablesNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HQ = hazard quotientThe SL for 'Cresol, m-' was used as the SL for 'Cresols, m&p'. HHRA = Human Health Risk AssessmentThe SL for anthracene was used as the SL for phenanthrene. NA = not availableSL for benzo(a)pyrene was used as the SL for total BAP TEQ. B = compound was detected in the associated blank so the result may be biased highThe SL for xylenes was used as the SL for m,p-Xylene (sum of isomers). J = compound was detected below the reporting limit in the sample

L = compound was detected above the Method Detection Limit (MDL) but below the (4) Rationale Codes Selection Reason: Above Screening Levels (ASL) Contract Required Quantitation Limit (CRQL)

Deletion Reason: Below Screening Level (BSL) BAP TEQ = benzo(a)pyrene toxic equivalentNo Toxicity Information (NTX) SL = screening level

SVOC = semi-volatile organic compound(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, VOC = volatile organic compound

indeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. mg/kg = milligram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009551

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial Scenario

Surface Soil (0-1 foot bgs) and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1.07E+03 1.09E+04 ng/kg SDU-SU01 9 / 9 - 1.09E+04 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 3.33E+01 9.48E+01 ng/kg SDU-SU07 9 / 9 - 9.48E+01 2.08E+01 NA NA NA -- (5)(Southern Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 4.14E+01 3.07E+02 ng/kg SDU-SU07 9 / 9 - 3.07E+02 2.55E+01 NA NA NA -- (5)

19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 4.12E+01 1.98E+02 ng/kg SDU-SU07 9 / 9 - 1.98E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.42E+01 3.97E+01 ng/kg SDU-SU01 9 / 9 - 3.97E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1.12E+00 2.96E+00 ng/kg SDU-SU06 9 / 9 - 2.96E+00 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 2.71E+03 2.68E+04 ng/kg SDU-SU01 9 / 9 - 2.68E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 4.01E+02 2.28E+03 ng/kg SDU-SU07 9 / 9 - 2.28E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.44E+04 J 1.09E+05 J ng/kg SDU-SU01 9 / 9 - 1.09E+05 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 6.66E+01 J 1.91E+02 J ng/kg SDU-SU07 9 / 9 - 1.91E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 5.45E+01 2.88E+02 ng/kg SDU-SU01 9 / 9 - 2.88E+02 3.18E+01 1.80E+01 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.11E+01 4.18E+01 ng/kg SDU-SU01 9 / 9 - 4.18E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 1.38E+02 1.92E+03 ng/kg SDU-SU01 9 / 9 - 1.92E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 1.12E+01 1.60E+02 ng/kg SDU-SU07 9 / 9 - 1.60E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 6.28E+00 9.23E+01 J ng/kg SDU-SU07 9 / 9 - 9.23E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 2.77E+00 6.19E+01 J ng/kg SDU-SU01 9 / 9 - 6.19E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 1.30E+00 L,J 1.92E+01 J ng/kg SDU-SU07 9 / 9 - 1.92E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 3.83E-01 L,J 4.46E+00 ng/kg SDU-SU07 9 / 9 - 4.46E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 5.10E+00 8.35E+01 ng/kg SDU-SU07 9 / 9 - 8.35E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 8.13E-01 L,J 1.24E+01 ng/kg SDU-SU01 9 / 9 - 1.24E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 4.40E-01 L,J 1.04E+00 ng/kg SDU-SU07 5 / 9 - 1.04E+00 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 6.04E+02 7.60E+03 ng/kg SDU-SU07 9 / 9 - 7.60E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 1.63E+02 2.75E+03 J ng/kg SDU-SU07 9 / 9 - 2.75E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 5.75E+02 6.85E+03 ng/kg SDU-SU01 9 / 9 - 6.85E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 1.88E+01 J 3.22E+02 J ng/kg SDU-SU07 9 / 9 - 3.22E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 2.98E+00 3.23E+01 J ng/kg SDU-SU07 9 / 9 - 3.23E+01 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 2.90E-02 L,J 2.90E-02 L,J mg/Kg SDU-SB01 1 / 13 4.00E-03 - 4.70E-02 2.90E-02 NA 2.20E+02 nc NA NA No BSL208-96-8 Acenaphthylene 1.70E-01 L,J 1.70E-01 L,J mg/Kg SDU-SB01 1 / 13 2.00E-01 - 2.40E+00 1.70E-01 NA 3.30E+03 nc NA NA No BSL120-12-7 Anthracene 2.50E-02 L,J 1.80E-01 L,J mg/Kg SDU-SB01 3 / 13 2.00E-01 - 2.40E+00 1.80E-01 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 8.40E-03 2.70E+00 J mg/Kg SDU-SB09 12 / 13 4.00E-03 - 2.40E+00 2.70E+00 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.10E-02 3.20E+00 mg/Kg SDU-SB09 12 / 13 4.00E-03 - 2.40E+00 3.20E+00 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 9.20E-03 4.30E+00 mg/Kg SDU-SB09 13 / 13 4.00E-03 - 2.40E+00 4.30E+00 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 5.00E-02 L,J 3.20E-01 mg/Kg SDU-SB10 2 / 13 2.00E-01 - 2.40E+00 3.20E-01 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 6.50E-02 3.50E+00 J mg/Kg SDU-SB09 5 / 13 4.10E-02 - 2.40E+00 3.50E+00 1.78E-01 2.10E+01 ca NA NA -- (6)86-74-8 Carbazole 2.10E-02 L,J 2.10E-02 L,J mg/Kg SDU-SB02 1 / 13 2.00E-01 - 2.40E+00 2.10E-02 NA NA NA NA No NTX218-01-9 Chrysene 2.20E-02 L,J 3.40E+00 J mg/Kg SDU-SB09 8 / 13 4.00E-03 - 2.40E+00 3.40E+00 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 4.60E-03 6.90E-01 mg/Kg SDU-SB09 12 / 13 4.00E-03 - 4.70E-01 6.90E-01 1.00E-02 2.10E-01 ca NA NA -- (6)206-44-0 Fluoranthene 4.50E-02 L,J 3.60E+00 mg/Kg SDU-SB09 5 / 13 2.00E-01 - 2.40E+00 3.60E+00 1.79E-01 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.60E-02 2.60E+00 J mg/Kg SDU-SB01 13 / 13 4.00E-03 - 4.70E-01 2.60E+00 3.10E-02 2.10E+00 ca NA NA -- (6)91-20-3 Naphthalene 5.80E-03 7.20E-02 mg/Kg SDU-SB01 2 / 13 4.00E-03 - 4.70E-02 7.20E-02 NA 1.80E+01 ca NA NA No BSL87-86-5 Pentachlorophenol 5.30E-03 L,J 1.40E-01 J mg/Kg SDU-SB01 10 / 13 8.00E-03 - 9.50E-02 1.40E-01 9.60E-03 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 2.50E-02 L,J 2.50E-02 L,J mg/Kg SDU-SB04 1 / 13 2.00E-01 - 2.40E+00 2.50E-02 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 3.30E-02 L,J 6.00E+00 mg/Kg SDU-SB09 4 / 13 2.00E-01 - 2.40E+00 6.00E+00 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 7.77E-03 4.87E+00 mg/Kg SDU-SB09 13 / 13 - 4.87E+00 4.32E-01 2.10E-01 ca NA NA Yes ASL

Qualifier Qualifier

TABLE 2.7OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009552

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.7OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

Residential ScenarioSurface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 1.07E+03 1.09E+04 ng/kg SDU-SU01 9 / 9 - 1.09E+04 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 3.33E+01 9.48E+01 ng/kg SDU-SU07 9 / 9 - 9.48E+01 2.08E+01 NA NA NA -- (5)(Southern Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 4.14E+01 3.07E+02 ng/kg SDU-SU07 9 / 9 - 3.07E+02 2.55E+01 NA NA NA -- (5)

19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 4.12E+01 1.98E+02 ng/kg SDU-SU07 9 / 9 - 1.98E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.42E+01 3.97E+01 ng/kg SDU-SU01 9 / 9 - 3.97E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1.12E+00 2.96E+00 ng/kg SDU-SU06 9 / 9 - 2.96E+00 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 2.71E+03 2.68E+04 ng/kg SDU-SU01 9 / 9 - 2.68E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 4.01E+02 2.28E+03 ng/kg SDU-SU07 9 / 9 - 2.28E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.44E+04 J 1.09E+05 J ng/kg SDU-SU01 9 / 9 - 1.09E+05 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 6.66E+01 J 1.91E+02 J ng/kg SDU-SU07 9 / 9 - 1.91E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 5.45E+01 2.88E+02 ng/kg SDU-SU01 9 / 9 - 2.88E+02 3.18E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.11E+01 4.18E+01 ng/kg SDU-SU01 9 / 9 - 4.18E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 1.38E+02 1.92E+03 ng/kg SDU-SU01 9 / 9 - 1.92E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 1.12E+01 1.60E+02 ng/kg SDU-SU07 9 / 9 - 1.60E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 6.28E+00 9.23E+01 J ng/kg SDU-SU07 9 / 9 - 9.23E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 2.77E+00 6.19E+01 J ng/kg SDU-SU01 9 / 9 - 6.19E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 1.30E+00 L,J 1.92E+01 J ng/kg SDU-SU07 9 / 9 - 1.92E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 3.83E-01 L,J 4.46E+00 ng/kg SDU-SU07 9 / 9 - 4.46E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 5.10E+00 8.35E+01 ng/kg SDU-SU07 9 / 9 - 8.35E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 8.13E-01 L,J 1.24E+01 ng/kg SDU-SU01 9 / 9 - 1.24E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 4.40E-01 L,J 1.04E+00 ng/kg SDU-SU07 5 / 9 - 1.04E+00 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 6.04E+02 7.60E+03 ng/kg SDU-SU07 9 / 9 - 7.60E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 1.63E+02 2.75E+03 J ng/kg SDU-SU07 9 / 9 - 2.75E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 5.75E+02 6.85E+03 ng/kg SDU-SU01 9 / 9 - 6.85E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 1.88E+01 J 3.22E+02 J ng/kg SDU-SU07 9 / 9 - 3.22E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 2.98E+00 3.23E+01 J ng/kg SDU-SU07 9 / 9 - 3.23E+01 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 2.90E-02 L,J 2.90E-02 L,J mg/Kg SDU-SB01 1 / 13 4.00E-03 - 4.70E-02 2.90E-02 NA 2.30E+01 nc NA NA No BSL208-96-8 Acenaphthylene 1.70E-01 L,J 1.70E-01 L,J mg/Kg SDU-SB01 1 / 13 2.00E-01 - 2.40E+00 1.70E-01 NA 3.40E+02 nc NA NA No BSL120-12-7 Anthracene 2.50E-02 L,J 1.80E-01 L,J mg/Kg SDU-SB01 3 / 13 2.00E-01 - 2.40E+00 1.80E-01 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 8.40E-03 2.70E+00 J mg/Kg SDU-SB09 12 / 13 4.00E-03 - 2.40E+00 2.70E+00 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.10E-02 3.20E+00 mg/Kg SDU-SB09 12 / 13 4.00E-03 - 2.40E+00 3.20E+00 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 9.20E-03 4.30E+00 mg/Kg SDU-SB09 13 / 13 4.00E-03 - 2.40E+00 4.30E+00 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 5.00E-02 L,J 3.20E-01 mg/Kg SDU-SB10 2 / 13 2.00E-01 - 2.40E+00 3.20E-01 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 6.50E-02 3.50E+00 J mg/Kg SDU-SB09 5 / 13 4.10E-02 - 2.40E+00 3.50E+00 1.78E-01 1.50E+00 ca NA NA -- (6)86-74-8 Carbazole 2.10E-02 L,J 2.10E-02 L,J mg/Kg SDU-SB02 1 / 13 2.00E-01 - 2.40E+00 2.10E-02 NA NA NA NA No NTX218-01-9 Chrysene 2.20E-02 L,J 3.40E+00 J mg/Kg SDU-SB09 8 / 13 4.00E-03 - 2.40E+00 3.40E+00 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 4.60E-03 6.90E-01 mg/Kg SDU-SB09 12 / 13 4.00E-03 - 4.70E-01 6.90E-01 1.00E-02 1.50E-02 ca NA NA -- (6)206-44-0 Fluoranthene 4.50E-02 L,J 3.60E+00 mg/Kg SDU-SB09 5 / 13 2.00E-01 - 2.40E+00 3.60E+00 1.79E-01 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.60E-02 2.60E+00 J mg/Kg SDU-SB01 13 / 13 4.00E-03 - 4.70E-01 2.60E+00 3.10E-02 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 5.80E-03 7.20E-02 mg/Kg SDU-SB01 2 / 13 4.00E-03 - 4.70E-02 7.20E-02 NA 3.60E+00 ca NA NA No BSL87-86-5 Pentachlorophenol 5.30E-03 L,J 1.40E-01 J mg/Kg SDU-SB01 10 / 13 8.00E-03 - 9.50E-02 1.40E-01 9.60E-03 8.90E-01 ca NA NA No BSL85-01-8 Phenanthrene 2.50E-02 L,J 2.50E-02 L,J mg/Kg SDU-SB04 1 / 13 2.00E-01 - 2.40E+00 2.50E-02 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 3.30E-02 L,J 6.00E+00 mg/Kg SDU-SB09 4 / 13 2.00E-01 - 2.40E+00 6.00E+00 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 7.77E-03 4.87E+00 mg/Kg SDU-SB09 13 / 13 - 4.87E+00 4.32E-01 1.50E-02 ca NA NA Yes ASL

PAGE 2 OF 3

009553

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.7OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientNo screening level is available for carbazole. The HEAST cancer slope factor has been withdrawn. HHRA = Human Health Risk AssessmentThe SL for anthracene was used as the SL for phenanthrene. J = compound was detected below the reporting limit in the sampleSL for benzo(a)pyrene was used as the SL for total BAP TEQ. L = compound was detected above the Method Detection Limit (MDL) but

below the Contract Required Quantitation Limit (CRQL)(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) NA = not available

Deletion Reason: Below Screening Level (BSL) SL = screening levelNo Toxicity Information (NTX) SVOC = semi-volatile organic compound

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." TEQ = toxic equivalentmg/kg = milligram per kilogram

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, ng/kg = nanogram per kilogramindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." PAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009554

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSubsurface Soil (1-10 feet bgs) SVOCs

and Emissions from 208-96-8 Acenaphthylene 9.30E-02 L,J 9.30E-02 L,J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 9.30E-02 NA 3.30E+03 nc NA NA No BSLSubsurface Soil 120-12-7 Anthracene 2.00E-01 L,J,^ 2.00E-01 L,J,^ mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.00E-01 NA 1.70E+04 nc NA NA No BSL

(Southern Decision Unit) 56-55-3 Benzo(a)anthracene 7.40E-03 7.40E-01 J mg/Kg SDU-SB12 2 / 13 4.00E-03 - 2.50E-01 7.40E-01 NA 2.10E+00 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 6.80E-01 6.80E-01 mg/Kg SDU-SB12 1 / 13 4.00E-03 - 2.50E-01 6.80E-01 NA 2.10E-01 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 5.30E-03 8.30E-01 mg/Kg SDU-SB12 5 / 13 4.00E-03 - 2.50E-01 8.30E-01 4.33E-03 2.10E+00 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 3.10E-02 L,J 4.30E-01 mg/Kg SDU-SB12 2 / 13 1.90E-01 - 2.50E-01 4.30E-01 2.80E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 6.90E-01 J 6.90E-01 J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 6.90E-01 1.75E-01 2.10E+01 ca NA NA -- (5)218-01-9 Chrysene 9.60E-01 J 9.60E-01 J mg/Kg SDU-SB12 1 / 13 4.00E-03 - 2.50E-01 9.60E-01 4.56E-02 2.10E+02 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 1.80E-03 L,J 2.20E-01 mg/Kg SDU-SB12 6 / 13 4.00E-03 - 4.80E-02 2.20E-01 4.10E-03 2.10E-01 ca NA NA -- (5)132-64-9 Dibenzofuran 2.30E-02 L,J 2.30E-02 L,J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.30E-02 NA 1.00E+02 nc NA NA No BSL206-44-0 Fluoranthene 3.30E+00 3.30E+00 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 3.30E+00 NA 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 2.70E-01 2.70E-01 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.70E-01 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 5.60E-03 5.10E-01 mg/Kg SDU-SB12 9 / 13 4.00E-03 - 2.50E-01 5.10E-01 4.42E-03 2.10E+00 ca NA NA -- (5)87-86-5 Pentachlorophenol 6.80E-02 L,J 6.80E-02 L,J mg/Kg SDU-SB12 1 / 13 8.00E-03 - 9.70E-02 6.80E-02 NA 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 4.50E-01 J,^ 4.50E-01 J,^ mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 4.50E-01 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 2.20E+00 2.20E+00 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.20E+00 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 6.12E-03 1.12E+00 mg/Kg SDU-SB12 9 / 13 - 1.12E+00 4.25E-01 2.10E-01 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.00E-02 L,J 1.40E-01 J mg/Kg SDU-SB12 5 / 11 9.00E-03 - 1.30E-02 1.40E-01 NA 6.30E+04 nc NA NA No BSL75-15-0 Carbon Disulfide 1.80E-03 L,J 7.80E-03 J mg/Kg SDU-SB12 2 / 11 4.00E-03 - 6.00E-03 7.80E-03 NA 3.70E+02 nc NA NA No BSL

Residential ScenarioSubsurface Soil and SVOCs

Emissions from 208-96-8 Acenaphthylene 9.30E-02 L,J 9.30E-02 L,J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 9.30E-02 NA 3.40E+02 nc NA NA No BSLSubsurface Soil 120-12-7 Anthracene 2.00E-01 L,J,^ 2.00E-01 L,J,^ mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.00E-01 NA 1.70E+03 nc NA NA No BSL

(Southern Decision Unit) 56-55-3 Benzo(a)anthracene 7.40E-03 7.40E-01 J mg/Kg SDU-SB12 2 / 13 4.00E-03 - 2.50E-01 7.40E-01 NA 1.50E-01 ca NA NA -- (5)50-32-8 Benzo(a)pyrene 6.80E-01 6.80E-01 mg/Kg SDU-SB12 1 / 13 4.00E-03 - 2.50E-01 6.80E-01 NA 1.50E-02 ca NA NA -- (5)205-99-2 Benzo(b)fluoranthene 5.30E-03 8.30E-01 mg/Kg SDU-SB12 5 / 13 4.00E-03 - 2.50E-01 8.30E-01 4.33E-03 1.50E-01 ca NA NA -- (5)191-24-2 Benzo(g,h,i)perylene 3.10E-02 L,J 4.30E-01 mg/Kg SDU-SB12 2 / 13 1.90E-01 - 2.50E-01 4.30E-01 2.80E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 6.90E-01 J 6.90E-01 J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 6.90E-01 1.75E-01 1.50E+00 ca NA NA -- (5)218-01-9 Chrysene 9.60E-01 J 9.60E-01 J mg/Kg SDU-SB12 1 / 13 4.00E-03 - 2.50E-01 9.60E-01 4.56E-02 1.50E+01 ca NA NA -- (5)53-70-3 Dibenz(a,h)anthracene 1.80E-03 L,J 2.20E-01 mg/Kg SDU-SB12 6 / 13 4.00E-03 - 4.80E-02 2.20E-01 4.10E-03 1.50E-02 ca NA NA -- (5)132-64-9 Dibenzofuran 2.30E-02 L,J 2.30E-02 L,J mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.30E-02 NA 7.80E+00 nc NA NA No BSL206-44-0 Fluoranthene 3.30E+00 3.30E+00 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 3.30E+00 NA 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 2.70E-01 2.70E-01 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.70E-01 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 5.60E-03 5.10E-01 mg/Kg SDU-SB12 9 / 13 4.00E-03 - 2.50E-01 5.10E-01 4.42E-03 1.50E-01 ca NA NA -- (5)87-86-5 Pentachlorophenol 6.80E-02 L,J 6.80E-02 L,J mg/Kg SDU-SB12 1 / 13 8.00E-03 - 9.70E-02 6.80E-02 NA 8.90E-01 ca NA NA No BSL85-01-8 Phenanthrene 4.50E-01 J,^ 4.50E-01 J,^ mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 4.50E-01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 2.20E+00 2.20E+00 mg/Kg SDU-SB12 1 / 13 1.90E-01 - 2.50E-01 2.20E+00 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 6.12E-03 1.12E+00 mg/Kg SDU-SB12 9 / 13 - 1.12E+00 4.25E-01 1.50E-02 ca NA NA Yes ASL

VOCs67-64-1 Acetone 1.00E-02 L,J 1.40E-01 J mg/Kg SDU-SB12 5 / 11 9.00E-03 - 1.30E-02 1.40E-01 NA 6.10E+03 nc NA NA No BSL75-15-0 Carbon Disulfide 1.80E-03 L,J 7.80E-03 J mg/Kg SDU-SB12 2 / 11 4.00E-03 - 6.00E-03 7.80E-03 NA 8.20E+01 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.8OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 2

009555

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Soil Exposure Medium: Subsurface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.8OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

(1) Maximum concentration is used for screening. ^ = high estimateCOPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientThe SL for anthracene was used as the SL for phenanthrene. HHRA = Human Health Risk AssessmentSL for benzo(a)pyrene was used as the SL for total BAP TEQ. NA = not available

J = compound was detected below the reporting limit in the sample(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) L = compound was detected above the Method Detection Limit (MDL) but below the

Deletion Reason: Below Screening Level (BSL) Contract Required Quantitation Limit (CRQL)BAP TEQ = benzo(a)pyrene toxic equivalentSL = screening level

(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, SVOC = semi-volatile organic compoundindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. VOC = volatile organic compound

mg/kg = milligram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 2 OF 2

009556

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial ScenarioSurface Soil (0-1 foot bgs) and Dioxins/Furans

Emissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.51E+03 7.92E+03 ng/kg WDU-SU02 3 / 3 - 7.92E+03 8.54E+02 NA NA NA -- (5)Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 4.01E+01 8.77E+01 ng/kg WDU-DU 3 / 3 - 8.77E+01 2.08E+01 NA NA NA -- (5)

(Western Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 8.40E+01 2.22E+02 ng/kg WDU-SU02 3 / 3 - 2.22E+02 2.55E+01 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 5.25E+01 1.21E+02 ng/kg WDU-SU02 3 / 3 - 1.21E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.08E+01 1.86E+01 ng/kg WDU-SU02 3 / 3 - 1.86E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 8.77E-01 9.97E-01 ng/kg WDU-SU02 3 / 3 - 9.97E-01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 6.23E+03 2.00E+04 ng/kg WDU-SU02 3 / 3 - 2.00E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 9.24E+02 2.04E+03 ng/kg WDU-SU02 3 / 3 - 2.04E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 3.05E+04 J 7.95E+04 J ng/kg WDU-SU02 3 / 3 - 7.95E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 1.01E+02 J 1.48E+02 J ng/kg WDU-DU 3 / 3 - 1.48E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 7.73E+01 2.00E+02 ng/kg WDU-SU02 3 / 3 - 2.00E+02 3.18E+01 1.80E+01 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.83E+01 2.26E+01 ng/kg WDU-DU 3 / 3 - 2.26E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 5.69E+02 1.52E+03 ng/kg WDU-SU02 3 / 3 - 1.52E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 3.53E+01 1.13E+02 ng/kg WDU-SU02 3 / 3 - 1.13E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.94E+01 4.31E+01 ng/kg WDU-SU02 3 / 3 - 4.31E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.25E+01 2.73E+01 ng/kg WDU-SU02 3 / 3 - 2.73E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 4.74E+00 J 1.06E+01 J ng/kg WDU-SU02 3 / 3 - 1.06E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.49E+00 L,J 2.70E+00 ng/kg WDU-SU02 3 / 3 - 2.70E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 2.14E+01 5.54E+01 ng/kg WDU-SU02 3 / 3 - 5.54E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 1.24E+00 L,J 7.97E+00 ng/kg WDU-SU02 3 / 3 - 7.97E+00 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 4.65E-01 L,J 6.10E-01 ng/kg WDU-SU02 2 / 3 1.00E+00 - 1.00E+00 6.10E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 1.82E+03 5.88E+03 ng/kg WDU-SU02 3 / 3 - 5.88E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 6.14E+02 J 1.83E+03 J ng/kg WDU-SU02 3 / 3 - 1.83E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.58E+03 5.80E+03 ng/kg WDU-SU02 3 / 3 - 5.80E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 6.08E+01 J 1.89E+02 J ng/kg WDU-SU02 3 / 3 - 1.89E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.62E+01 2.66E+01 ng/kg WDU-SU02 3 / 3 - 2.66E+01 2.73E+01 NA NA NA -- (5)

SVOCs208-96-8 Acenaphthylene 2.50E-01 L,J 2.50E-01 L,J mg/Kg WDU-SB04 1 / 10 1.90E-01 - 2.10E+00 2.50E-01 NA 3.30E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 4.00E-03 L,J 1.60E+00 J mg/Kg WDU-SB04 7 / 10 4.00E-03 - 2.00E-01 1.60E+00 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.50E-02 J 2.40E+00 mg/Kg WDU-SB04 8 / 10 4.00E-03 - 2.10E+00 2.40E+00 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 8.40E-03 J 2.70E+00 mg/Kg WDU-SB04 10 / 10 4.00E-03 - 2.10E+00 2.70E+00 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 1.30E-02 1.50E+00 J mg/Kg WDU-SB04 8 / 10 4.00E-03 - 2.20E-01 1.50E+00 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 8.60E-02 2.10E+00 J mg/Kg WDU-SB04 5 / 10 3.90E-02 - 2.10E+00 2.10E+00 1.78E-01 2.10E+01 ca NA NA -- (6)85-68-7 Benzyl Butyl Phthalate 5.00E-02 L,J 5.00E-02 L,J mg/Kg WDU-SB03 1 / 10 1.90E-01 - 2.10E+00 5.00E-02 1.74E-01 9.10E+02 ca NA NA No BKG, BSL218-01-9 Chrysene 4.40E-03 1.30E+00 J mg/Kg WDU-SB04 7 / 10 4.00E-03 - 2.00E-01 1.30E+00 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 5.70E-03 8.00E-01 J mg/Kg WDU-SB04 9 / 10 4.00E-03 - 2.00E-01 8.00E-01 1.00E-02 2.10E-01 ca NA NA -- (6)117-84-0 Di-n-Octylphthalate 2.00E-02 L,J 2.20E-02 L,J mg/Kg WDU-SB03 2 / 10 1.90E-01 - 2.10E+00 2.20E-02 NA 6.20E+02 nc NA NA No BSL206-44-0 Fluoranthene 2.10E-02 L,J 1.70E+00 L,J mg/Kg WDU-SB04 5 / 10 1.90E-01 - 2.10E+00 1.70E+00 1.79E-01 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 8.80E-03 2.00E+00 J mg/Kg WDU-SB04 10 / 10 4.00E-03 - 2.00E-01 2.00E+00 3.10E-02 2.10E+00 ca NA NA -- (6)87-86-5 Pentachlorophenol 7.50E-03 L,J 5.10E-02 J mg/Kg WDU-SB06 2 / 10 8.00E-03 - 8.20E-02 5.10E-02 9.60E-03 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 2.50E-02 L,J 4.90E-02 L,J mg/Kg WDU-SB06 2 / 10 1.90E-01 - 2.10E+00 4.90E-02 NA 1.70E+04 nc NA NA No BSL129-00-0 Pyrene 2.90E-02 L,J 1.90E+00 L,J mg/Kg WDU-SB04 5 / 10 1.90E-01 - 2.10E+00 1.90E+00 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 1.17E-02 3.85E+00 mg/Kg WDU-SB04 10 / 10 - 3.85E+00 4.32E-01 2.10E-01 ca NA NA Yes ASL

Qualifier Qualifier

TABLE 2.9OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009557

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.9OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

Residential ScenarioSurface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.51E+03 7.92E+03 ng/kg WDU-SU02 3 / 3 - 7.92E+03 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 4.01E+01 8.77E+01 ng/kg WDU-DU 3 / 3 - 8.77E+01 2.08E+01 NA NA NA -- (5)(Western Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 8.40E+01 2.22E+02 ng/kg WDU-SU02 3 / 3 - 2.22E+02 2.55E+01 NA NA NA -- (5)

19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 5.25E+01 1.21E+02 ng/kg WDU-SU02 3 / 3 - 1.21E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 1.08E+01 1.86E+01 ng/kg WDU-SU02 3 / 3 - 1.86E+01 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 8.77E-01 9.97E-01 ng/kg WDU-SU02 3 / 3 - 9.97E-01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 6.23E+03 2.00E+04 ng/kg WDU-SU02 3 / 3 - 2.00E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 9.24E+02 2.04E+03 ng/kg WDU-SU02 3 / 3 - 2.04E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 3.05E+04 J 7.95E+04 J ng/kg WDU-SU02 3 / 3 - 7.95E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 1.01E+02 J 1.48E+02 J ng/kg WDU-DU 3 / 3 - 1.48E+02 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 7.73E+01 2.00E+02 ng/kg WDU-SU02 3 / 3 - 2.00E+02 3.18E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 1.83E+01 2.26E+01 ng/kg WDU-DU 3 / 3 - 2.26E+01 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 5.69E+02 1.52E+03 ng/kg WDU-SU02 3 / 3 - 1.52E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 3.53E+01 1.13E+02 ng/kg WDU-SU02 3 / 3 - 1.13E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.94E+01 4.31E+01 ng/kg WDU-SU02 3 / 3 - 4.31E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.25E+01 2.73E+01 ng/kg WDU-SU02 3 / 3 - 2.73E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 4.74E+00 J 1.06E+01 J ng/kg WDU-SU02 3 / 3 - 1.06E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.49E+00 L,J 2.70E+00 ng/kg WDU-SU02 3 / 3 - 2.70E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 2.14E+01 5.54E+01 ng/kg WDU-SU02 3 / 3 - 5.54E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 1.24E+00 L,J 7.97E+00 ng/kg WDU-SU02 3 / 3 - 7.97E+00 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 4.65E-01 L,J 6.10E-01 ng/kg WDU-SU02 2 / 3 1.00E+00 - 1.00E+00 6.10E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 1.82E+03 5.88E+03 ng/kg WDU-SU02 3 / 3 - 5.88E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 6.14E+02 J 1.83E+03 J ng/kg WDU-SU02 3 / 3 - 1.83E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.58E+03 5.80E+03 ng/kg WDU-SU02 3 / 3 - 5.80E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 6.08E+01 J 1.89E+02 J ng/kg WDU-SU02 3 / 3 - 1.89E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.62E+01 2.66E+01 ng/kg WDU-SU02 3 / 3 - 2.66E+01 2.73E+01 NA NA NA -- (5)

SVOCs208-96-8 Acenaphthylene 2.50E-01 L,J 2.50E-01 L,J mg/Kg WDU-SB04 1 / 10 1.90E-01 - 2.10E+00 2.50E-01 NA 3.40E+02 nc NA NA No BSL56-55-3 Benzo(a)anthracene 4.00E-03 L,J 1.60E+00 J mg/Kg WDU-SB04 7 / 10 4.00E-03 - 2.00E-01 1.60E+00 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.50E-02 J 2.40E+00 mg/Kg WDU-SB04 8 / 10 4.00E-03 - 2.10E+00 2.40E+00 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 8.40E-03 J 2.70E+00 mg/Kg WDU-SB04 10 / 10 4.00E-03 - 2.10E+00 2.70E+00 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 1.30E-02 1.50E+00 J mg/Kg WDU-SB04 8 / 10 4.00E-03 - 2.20E-01 1.50E+00 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 8.60E-02 2.10E+00 J mg/Kg WDU-SB04 5 / 10 3.90E-02 - 2.10E+00 2.10E+00 1.78E-01 1.50E+00 ca NA NA -- (6)85-68-7 Benzyl Butyl Phthalate 5.00E-02 L,J 5.00E-02 L,J mg/Kg WDU-SB03 1 / 10 1.90E-01 - 2.10E+00 5.00E-02 1.74E-01 2.60E+02 ca NA NA No BKG, BSL218-01-9 Chrysene 4.40E-03 1.30E+00 J mg/Kg WDU-SB04 7 / 10 4.00E-03 - 2.00E-01 1.30E+00 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 5.70E-03 8.00E-01 J mg/Kg WDU-SB04 9 / 10 4.00E-03 - 2.00E-01 8.00E-01 1.00E-02 1.50E-02 ca NA NA -- (6)117-84-0 Di-n-Octylphthalate 2.00E-02 L,J 2.20E-02 L,J mg/Kg WDU-SB03 2 / 10 1.90E-01 - 2.10E+00 2.20E-02 NA 6.10E+01 nc NA NA No BSL206-44-0 Fluoranthene 2.10E-02 L,J 1.70E+00 L,J mg/Kg WDU-SB04 5 / 10 1.90E-01 - 2.10E+00 1.70E+00 1.79E-01 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 8.80E-03 2.00E+00 J mg/Kg WDU-SB04 10 / 10 4.00E-03 - 2.00E-01 2.00E+00 3.10E-02 1.50E-01 ca NA NA -- (6)87-86-5 Pentachlorophenol 7.50E-03 L,J 5.10E-02 J mg/Kg WDU-SB06 2 / 10 8.00E-03 - 8.20E-02 5.10E-02 9.60E-03 8.90E-01 ca NA NA No BSL85-01-8 Phenanthrene 2.50E-02 L,J 4.90E-02 L,J mg/Kg WDU-SB06 2 / 10 1.90E-01 - 2.10E+00 4.90E-02 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 2.90E-02 L,J 1.90E+00 L,J mg/Kg WDU-SB04 5 / 10 1.90E-01 - 2.10E+00 1.90E+00 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 1.17E-02 3.85E+00 mg/Kg WDU-SB04 10 / 10 - 3.85E+00 4.32E-01 1.50E-02 ca NA NA Yes ASL

PAGE 2 OF 3

009558

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.9OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential Soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientThe SL for anthracene was used as the SL for phenanthrene. HHRA = Human Health Risk AssessmentSL for benzo(a)pyrene was used as the SL for total BAP TEQ. J = compound was detected below the reporting limit in the sample

L = compound was detected above the Method Detection Limit (MDL) but (4) Rationale Codes Selection Reason: Above Screening Levels (ASL) below the Contract Required Quantitation Limit (CRQL)

Deletion Reason: Below Screening Level (BSL) NA = not availableBelow Background Value (BKG) SL = screening level

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." SVOC = semi-volatile organic compoundTEQ = toxic equivalent

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, mg/kg = milligram per kilogramindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." ng/kg = nanogram per kilogram

PAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009559

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Industrial Scenario

Surface Soil (0-1 foot bgs) and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.32E+03 1.08E+04 ng/kg TMDU-SB02 3 / 3 - 1.08E+04 8.54E+02 NA NA NA -- (5)Subsurface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 7.54E+01 2.36E+02 ng/kg TMDU-SB03 3 / 3 - 2.36E+02 2.08E+01 NA NA NA -- (5)

(Tar Mat Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 9.00E+01 3.51E+02 ng/kg TMDU-SB02 3 / 3 - 3.51E+02 2.55E+01 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 9.31E+01 3.02E+02 ng/kg TMDU-SB03 3 / 3 - 3.02E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 3.82E+01 1.02E+02 ng/kg TMDU-SB03 3 / 3 - 1.02E+02 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.60E+00 1.61E+01 ng/kg TMDU-SB03 3 / 3 - 1.61E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 5.76E+03 2.00E+04 ng/kg TMDU-SB02 3 / 3 - 2.00E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 2.14E+03 6.35E+03 ng/kg TMDU-SB03 3 / 3 - 6.35E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.70E+04 9.11E+04 J ng/kg TMDU-SB02 3 / 3 - 9.11E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 6.13E+02 J 2.62E+03 J ng/kg TMDU-SB03 3 / 3 - 2.62E+03 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 1.08E+02 2.85E+02 ng/kg TMDU-SB03 3 / 3 - 2.85E+02 3.18E+01 1.80E+01 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 3.27E+02 1.50E+03 ng/kg TMDU-SB03 3 / 3 - 1.50E+03 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 2.36E+02 1.61E+03 ng/kg TMDU-SB02 3 / 3 - 1.61E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.72E+01 1.33E+02 ng/kg TMDU-SB02 3 / 3 - 1.33E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.77E+01 6.24E+01 ng/kg TMDU-SB02 3 / 3 - 6.24E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 9.34E+00 2.90E+01 ng/kg TMDU-SB03 3 / 3 - 2.90E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 6.77E+00 1.75E+01 J ng/kg TMDU-SB02 3 / 3 - 1.75E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 2.12E+00 L,J 5.87E+00 ng/kg TMDU-SB03 3 / 3 - 5.87E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.42E+01 4.92E+01 ng/kg TMDU-SB02 3 / 3 - 4.92E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 4.18E+00 1.02E+01 ng/kg TMDU-SB03 3 / 3 - 1.02E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 2.83E-01 L,J 6.95E-01 ng/kg TMDU-SB03 3 / 3 - 6.95E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 9.50E+02 7.52E+03 ng/kg TMDU-SB02 3 / 3 - 7.52E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 3.63E+02 2.05E+03 ng/kg TMDU-SB02 3 / 3 - 2.05E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 8.63E+02 7.38E+03 ng/kg TMDU-SB02 3 / 3 - 7.38E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 1.19E+02 J 4.01E+02 J ng/kg TMDU-SB03 3 / 3 - 4.01E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 5.13E+01 2.26E+02 ng/kg TMDU-SB03 3 / 3 - 2.26E+02 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 1.30E-02 2.80E-02 mg/Kg TMDU-SB03 3 / 3 4.00E-03 - 4.00E-03 2.80E-02 NA 2.20E+02 nc NA NA No BSL120-12-7 Anthracene 5.40E-02 L,J 6.40E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 6.40E-02 NA 1.70E+04 nc NA NA No BSL56-55-3 Benzo(a)anthracene 9.20E-02 2.20E-01 mg/Kg TMDU-SB03 3 / 3 3.80E-02 - 2.00E-01 2.20E-01 1.50E-02 2.10E+00 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 5.30E-02 1.30E-01 mg/Kg TMDU-SB02 3 / 3 3.80E-02 - 3.80E-02 1.30E-01 1.46E-02 2.10E-01 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 1.50E-01 J 2.70E-01 J mg/Kg TMDU-SB03 3 / 3 3.80E-02 - 2.00E-01 2.70E-01 3.40E-02 2.10E+00 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 5.40E-02 L,J 9.40E-02 L,J mg/Kg TMDU-SB02 3 / 3 2.00E-01 - 2.00E-01 9.40E-02 5.63E-02 1.70E+03 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 9.30E-02 L,J 1.30E-01 L,J mg/Kg TMDU-SB02 3 / 3 2.00E-01 - 2.00E-01 1.30E-01 1.78E-01 2.10E+01 ca NA NA -- (6)117-81-7 Bis(2-Ethylhexyl)phthalate 3.90E-02 L,J 5.50E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.50E-02 NA 1.20E+02 ca NA NA No BSL218-01-9 Chrysene 2.40E-01 3.50E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 3.50E-01 3.00E-02 2.10E+02 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 1.90E-02 4.30E-02 mg/Kg TMDU-SB02 3 / 3 4.00E-03 - 3.80E-02 4.30E-02 1.00E-02 2.10E-01 ca NA NA -- (6)132-64-9 Dibenzofuran 6.40E-02 L,J 6.40E-02 L,J mg/Kg TMDU-SB03 1 / 3 2.00E-01 - 2.00E-01 6.40E-02 NA 1.00E+02 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 3.00E-02 L,J 4.50E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 4.50E-02 NA 6.20E+02 nc NA NA No BSL206-44-0 Fluoranthene 4.80E-01 8.50E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 8.50E-01 1.79E-01 2.20E+03 nc NA NA No BSL86-73-7 Fluorene 2.40E-02 L,J 2.40E-02 L,J mg/Kg TMDU-SB02 1 / 3 2.00E-01 - 2.00E-01 2.40E-02 NA 2.20E+03 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 7.40E-02 J 1.70E-01 J mg/Kg TMDU-SB02 3 / 3 3.80E-02 - 3.80E-02 1.70E-01 3.10E-02 2.10E+00 ca NA NA -- (6)91-20-3 Naphthalene 2.10E-02 3.00E-02 L,J mg/Kg TMDU-SB03 3 / 3 4.00E-03 - 3.80E-02 3.00E-02 NA 1.80E+01 ca NA NA No BSL87-86-5 Pentachlorophenol 1.20E-02 6.30E-02 J mg/Kg TMDU-SB02 3 / 3 8.00E-03 - 8.00E-03 6.30E-02 9.60E-03 2.70E+00 ca NA NA No BSL85-01-8 Phenanthrene 2.90E-01 5.30E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.30E-01 NA 1.70E+04 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.10OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 3

009560

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.10OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

129-00-0 Pyrene 2.60E-01 5.20E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.20E-01 NA 1.70E+03 nc NA NA No BSLBAPTEQ Total BAP TEQ 1.05E-01 2.27E-01 mg/Kg TMDU-SB03 3 / 3 - 2.27E-01 4.32E-01 2.10E-01 ca NA NA No BKG, ASL

Residential Scenario

Surface Soil and Dioxins/FuransEmissions from 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.32E+03 1.08E+04 ng/kg TMDU-SB02 3 / 3 - 1.08E+04 8.54E+02 NA NA NA -- (5)

Surface Soil 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 7.54E+01 2.36E+02 ng/kg TMDU-SB03 3 / 3 - 2.36E+02 2.08E+01 NA NA NA -- (5)(Tar Mat Decision Unit) 57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 9.00E+01 3.51E+02 ng/kg TMDU-SB02 3 / 3 - 3.51E+02 2.55E+01 NA NA NA -- (5)

19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 9.31E+01 3.02E+02 ng/kg TMDU-SB03 3 / 3 - 3.02E+02 2.56E+01 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 3.82E+01 1.02E+02 ng/kg TMDU-SB03 3 / 3 - 1.02E+02 7.48E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 4.60E+00 1.61E+01 ng/kg TMDU-SB03 3 / 3 - 1.61E+01 5.34E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 5.76E+03 2.00E+04 ng/kg TMDU-SB02 3 / 3 - 2.00E+04 1.61E+03 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 2.14E+03 6.35E+03 ng/kg TMDU-SB03 3 / 3 - 6.35E+03 2.22E+02 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 1.70E+04 9.11E+04 J ng/kg TMDU-SB02 3 / 3 - 9.11E+04 1.42E+04 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 6.13E+02 J 2.62E+03 J ng/kg TMDU-SB03 3 / 3 - 2.62E+03 4.04E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 1.08E+02 2.85E+02 ng/kg TMDU-SB03 3 / 3 - 2.85E+02 3.18E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 3.27E+02 1.50E+03 ng/kg TMDU-SB03 3 / 3 - 1.50E+03 8.10E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 2.36E+02 1.61E+03 ng/kg TMDU-SB02 3 / 3 - 1.61E+03 1.84E+02 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.72E+01 1.33E+02 ng/kg TMDU-SB02 3 / 3 - 1.33E+02 8.06E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.77E+01 6.24E+01 ng/kg TMDU-SB02 3 / 3 - 6.24E+01 5.05E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 9.34E+00 2.90E+01 ng/kg TMDU-SB03 3 / 3 - 2.90E+01 4.29E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 6.77E+00 1.75E+01 J ng/kg TMDU-SB02 3 / 3 - 1.75E+01 9.99E-01 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 2.12E+00 L,J 5.87E+00 ng/kg TMDU-SB03 3 / 3 - 5.87E+00 5.20E-01 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.42E+01 4.92E+01 ng/kg TMDU-SB02 3 / 3 - 4.92E+01 6.60E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 4.18E+00 1.02E+01 ng/kg TMDU-SB03 3 / 3 - 1.02E+01 2.40E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 2.83E-01 L,J 6.95E-01 ng/kg TMDU-SB03 3 / 3 - 6.95E-01 8.94E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 9.50E+02 7.52E+03 ng/kg TMDU-SB02 3 / 3 - 7.52E+03 5.48E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 3.63E+02 2.05E+03 ng/kg TMDU-SB02 3 / 3 - 2.05E+03 1.54E+02 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 8.63E+02 7.38E+03 ng/kg TMDU-SB02 3 / 3 - 7.38E+03 4.35E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 1.19E+02 J 4.01E+02 J ng/kg TMDU-SB03 3 / 3 - 4.01E+02 2.65E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 5.13E+01 2.26E+02 ng/kg TMDU-SB03 3 / 3 - 2.26E+02 2.73E+01 NA NA NA -- (5)

SVOCs91-57-6 2-Methylnaphthalene 1.30E-02 2.80E-02 mg/Kg TMDU-SB03 3 / 3 4.00E-03 - 4.00E-03 2.80E-02 NA 2.30E+01 nc NA NA No BSL120-12-7 Anthracene 5.40E-02 L,J 6.40E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 6.40E-02 NA 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 9.20E-02 2.20E-01 mg/Kg TMDU-SB03 3 / 3 3.80E-02 - 2.00E-01 2.20E-01 1.50E-02 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 5.30E-02 1.30E-01 mg/Kg TMDU-SB02 3 / 3 3.80E-02 - 3.80E-02 1.30E-01 1.46E-02 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 1.50E-01 J 2.70E-01 J mg/Kg TMDU-SB03 3 / 3 3.80E-02 - 2.00E-01 2.70E-01 3.40E-02 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 5.40E-02 L,J 9.40E-02 L,J mg/Kg TMDU-SB02 3 / 3 2.00E-01 - 2.00E-01 9.40E-02 5.63E-02 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 9.30E-02 L,J 1.30E-01 L,J mg/Kg TMDU-SB02 3 / 3 2.00E-01 - 2.00E-01 1.30E-01 1.78E-01 1.50E+00 ca NA NA -- (6)117-81-7 Bis(2-Ethylhexyl)phthalate 3.90E-02 L,J 5.50E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.50E-02 NA 3.50E+01 ca NA NA No BSL218-01-9 Chrysene 2.40E-01 3.50E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 3.50E-01 3.00E-02 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 1.90E-02 4.30E-02 mg/Kg TMDU-SB02 3 / 3 4.00E-03 - 3.80E-02 4.30E-02 1.00E-02 1.50E-02 ca NA NA -- (6)132-64-9 Dibenzofuran 6.40E-02 L,J 6.40E-02 L,J mg/Kg TMDU-SB03 1 / 3 2.00E-01 - 2.00E-01 6.40E-02 NA 7.80E+00 nc NA NA No BSL117-84-0 Di-n-Octylphthalate 3.00E-02 L,J 4.50E-02 L,J mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 4.50E-02 NA 6.10E+01 nc NA NA No BSL206-44-0 Fluoranthene 4.80E-01 8.50E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 8.50E-01 1.79E-01 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 2.40E-02 L,J 2.40E-02 L,J mg/Kg TMDU-SB02 1 / 3 2.00E-01 - 2.00E-01 2.40E-02 NA 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 7.40E-02 J 1.70E-01 J mg/Kg TMDU-SB02 3 / 3 3.80E-02 - 3.80E-02 1.70E-01 3.10E-02 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 2.10E-02 3.00E-02 L,J mg/Kg TMDU-SB03 3 / 3 4.00E-03 - 3.80E-02 3.00E-02 NA 3.60E+00 ca NA NA No BSL87-86-5 Pentachlorophenol 1.20E-02 6.30E-02 J mg/Kg TMDU-SB02 3 / 3 8.00E-03 - 8.00E-03 6.30E-02 9.60E-03 8.90E-01 ca NA NA No BSL

PAGE 2 OF 3

009561

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Soil Exposure Medium: Surface Soil and Ambient Air

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.10OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

85-01-8 Phenanthrene 2.90E-01 5.30E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.30E-01 NA 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 2.60E-01 5.20E-01 mg/Kg TMDU-SB03 3 / 3 2.00E-01 - 2.00E-01 5.20E-01 NA 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 1.05E-01 2.27E-01 mg/Kg TMDU-SB03 3 / 3 - 2.27E-01 4.32E-01 1.50E-02 ca NA NA No BKG, ASL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement A for the calculation of the soil background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for pyrene was used as the SL for benzo(g,h,i)perylene. HEAST = Health Effects Assessment Summary TablesThe SL for anthracene was used as the SL for phenanthrene. HQ = hazard quotientSL for benzo(a)pyrene was used as the SL for total BAP TEQ. HHRA = Human Health Risk Assessment

J = compound was detected below the reporting limit in the sample(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) L = compound was detected above the Method Detection Limit (MDL) but

Deletion Reason: Below Screening Level (BSL) below the Contract Required Quantitation Limit (CRQL)NA = not available

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." SL = screening levelSVOC = semi-volatile organic compound

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, TEQ = toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." mg/kg = milligram per kilogram

ng/kg = nanogram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 3 OF 3

009562

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Future Medium: Surface Water Exposure Medium: Surface Water

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Surface Water SVOCs(Fire Water Pond) 50-32-8 Benzo(a)pyrene 1.90E-01 2.00E-01 µg/L FWP-FP1-SW01 2 / 6 - 2.00E-01 3.60E-01 2.90E-03 ca NA NA -- (5)

117-81-7 Bis(2-Ethylhexyl)phthalate 5.90E-01 L,J 8.70E-01 L,J µg/L FWP-FP6-SW01 2 / 6 5.00E+00 - 5.00E+00 8.70E-01 NA 4.80E+00 ca NA NA No BSL53-70-3 Dibenz(a,h)anthracene 5.50E-02 L,J 7.20E-02 L,J µg/L FWP-FP2-SW01 2 / 6 - 7.20E-02 1.64E-01 2.90E-03 ca NA NA -- (5)84-74-2 Di-n-Butyl Phthalate 6.40E-01 L,J 7.40E-01 L,J µg/L FWP-FP5-SW01 3 / 6 5.00E+00 - 5.00E+00 7.40E-01 NA 6.70E+01 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.10E-01 1.30E-01 µg/L FWP-FP1-SW01 3 / 6 - 1.30E-01 2.60E-01 2.90E-02 ca NA NA -- (5)91-20-3 Naphthalene 8.90E-02 L,J 3.10E-01 µg/L FWP-FP6-SW01 6 / 6 - 3.10E-01 9.70E-01 1.40E-01 ca NA NA No BKG, ASL

BAPTEQ Total BAP TEQ 1.28E-01 2.84E-01 µg/L FWP-FP1-SW01 3 / 6 - 2.84E-01 2.11E+01 2.90E-03 ca NA NA No BKG, ASL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the surface water background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for tap water (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for benzo(a)pyrene was used as the SL for total BAP TEQ. HQ = hazard quotient

NA = not available(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) J = compound was detected below the reporting limit in the sample

Deletion Reason: Below Screening Level (BSL) L = compound was detected above the Method Detection Limit (MDL) but below the Contract Required Quantitation Limit (CRQL)

(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, BAP TEQ = benzo(a)pyrene toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. PAH = polycyclic aromatic hydrocarbon

SL = screening levelSVOC = semi-volatile organic compoundµg/L= microgram per literPAH = polycyclic aromatic hydrocarbon

Qualifier Qualifier

TABLE 2.11OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 1

009563

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Sediment Dioxins/Furans(Fire Water Pond) 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 4.09E+02 2.65E+03 ng/kg FWP-FP2-SD01 3 / 3 - 2.65E+03 2.68E+02 NA NA NA -- (5)

39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 1.05E+01 3.93E+01 ng/kg FWP-FP2-SD01 3 / 3 - 3.93E+01 5.05E+00 NA NA NA -- (5)57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1.56E+01 8.09E+01 ng/kg FWP-FP2-SD01 3 / 3 - 8.09E+01 8.64E+00 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 2.25E+01 8.18E+01 ng/kg FWP-FP2-SD01 3 / 3 - 8.18E+01 6.91E+00 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 3.41E+00 1.17E+01 ng/kg FWP-FP2-SD01 3 / 3 - 1.17E+01 1.99E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 6.16E-01 3.06E+00 ng/kg FWP-FP6-SD01 3 / 3 - 3.06E+00 4.68E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 1.02E+03 5.98E+03 ng/kg FWP-FP2-SD01 3 / 3 - 5.98E+03 5.37E+02 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 3.50E+02 1.79E+03 ng/kg FWP-FP2-SD01 3 / 3 - 1.79E+03 8.49E+01 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 7.42E+03 J 2.51E+04 J ng/kg FWP-FP2-SD01 3 / 3 - 2.51E+04 9.18E+03 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 4.94E+01 J 2.20E+02 ng/kg FWP-FP2-SD01 3 / 3 - 2.20E+02 1.48E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 2.40E+01 8.00E+01 ng/kg FWP-FP2-SD01 3 / 3 - 8.00E+01 1.08E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 3.23E+01 7.19E+01 ng/kg FWP-FP2-SD01 3 / 3 - 7.19E+01 7.61E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 4.84E+01 3.78E+02 ng/kg FWP-FP2-SD01 3 / 3 - 3.78E+02 2.83E+01 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 2.96E+00 2.40E+01 ng/kg FWP-FP2-SD01 3 / 3 - 2.40E+01 3.66E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.10E+00 L,J 8.95E+00 ng/kg FWP-FP2-SD01 3 / 3 - 8.95E+00 2.62E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.50E+00 L,J 1.23E+01 ng/kg FWP-FP2-SD01 3 / 3 - 1.23E+01 2.27E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 1.96E+00 L,J 2.74E+00 ng/kg FWP-FP2-SD01 2 / 3 1.00E+00 - 1.00E+00 2.74E+00 1.02E+00 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 1.31E+00 L,J 1.31E+00 L,J ng/kg FWP-FP2-SD01 1 / 3 - 1.31E+00 NA NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 3.18E+00 3.22E+01 ng/kg FWP-FP2-SD01 3 / 3 - 3.22E+01 3.04E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 2.82E+00 9.54E+00 ng/kg FWP-FP2-SD01 2 / 3 1.00E+00 - 1.00E+00 9.54E+00 2.15E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 3.07E-01 L,J 4.18E-01 L,J ng/kg FWP-FP3-SD01 3 / 3 - 4.18E-01 4.55E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 1.37E+02 1.12E+03 ng/kg FWP-FP2-SD01 3 / 3 - 1.12E+03 1.10E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 5.52E+01 J 4.62E+02 ng/kg FWP-FP2-SD01 3 / 3 - 4.62E+02 4.02E+01 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.06E+02 9.61E+02 ng/kg FWP-FP2-SD01 3 / 3 - 9.61E+02 1.06E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 1.26E+01 J 1.05E+02 ng/kg FWP-FP2-SD01 3 / 3 - 1.05E+02 1.60E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 3.71E+00 2.42E+01 ng/kg FWP-FP2-SD01 3 / 3 - 2.42E+01 7.21E+00 NA NA NA -- (5)

SVOCs118-79-6 2,4,6-Tribromophenol 4.55E-01 6.56E-01 mg/Kg FWP-FP2-SD01 5 / 5 - 6.56E-01 NA NA NA NA No NTX321-60-8 2-Fluorobiphenyl 2.23E-01 4.08E-01 mg/Kg FWP-FP2-SD01 5 / 5 - 4.08E-01 NA NA NA NA No NTX367-12-4 2-Fluorophenol 3.68E-01 5.78E-01 mg/Kg FWP-FP2-SD01 5 / 5 - 5.78E-01 NA NA NA NA No NTX120-12-7 Anthracene 4.96E-02 4.96E-02 mg/Kg FWP-FP4-SD01 1 / 6 4.00E-03 - 4.00E-03 4.96E-02 2.25E-01 1.70E+03 nc NA NA No BKG, BSL56-55-3 Benzo(a)anthracene 3.80E-03 L,J 2.17E-01 J mg/Kg FWP-FP2-SD01 3 / 6 4.00E-03 - 4.00E-03 2.17E-01 NA 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 1.85E-01 2.61E-01 J mg/Kg FWP-FP2-SD01 2 / 6 4.00E-03 - 4.00E-03 2.61E-01 NA 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 1.40E-02 4.46E-01 J mg/Kg FWP-FP2-SD01 3 / 6 4.00E-03 - 4.00E-03 4.46E-01 NA 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 1.40E-02 1.40E-02 mg/Kg FWP-FP1-SD01 1 / 6 4.00E-03 - 4.00E-03 1.40E-02 NA 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 1.10E-02 3.29E-01 J mg/Kg FWP-FP2-SD01 3 / 6 4.00E-03 - 4.00E-03 3.29E-01 NA 1.50E+00 ca NA NA -- (6)65-85-0 Benzoic Acid 1.55E+00 J 1.55E+00 J mg/Kg FWP-FP4-SD01 1 / 5 - 1.55E+00 NA 2.40E+04 nc NA NA No BSL117-81-7 Bis(2-Ethylhexyl)phthalate 4.55E-01 J 4.55E-01 J mg/Kg FWP-FP2-SD01 1 / 6 2.30E-01 - 2.30E-01 4.55E-01 NA 3.50E+01 ca NA NA No BSL218-01-9 Chrysene 7.20E-03 2.91E-01 J mg/Kg FWP-FP2-SD01 3 / 6 4.00E-03 - 4.00E-03 2.91E-01 2.15E-01 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 3.60E-03 L,J 3.60E-03 L,J mg/Kg FWP-FP1-SD01 1 / 6 4.00E-03 - 4.00E-03 3.60E-03 NA 1.50E-02 ca NA NA -- (6)206-44-0 Fluoranthene 1.20E-01 4.78E-01 mg/Kg FWP-FP5-SD01 3 / 6 2.30E-01 - 2.30E-01 4.78E-01 6.75E-01 2.30E+02 nc NA NA No BKG, BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.50E-02 1.50E-02 mg/Kg FWP-FP1-SD01 1 / 6 4.00E-03 - 4.00E-03 1.50E-02 NA 1.50E-01 ca NA NA -- (6)85-01-8 Phenanthrene 1.54E-01 3.37E-01 mg/Kg FWP-FP4-SD01 2 / 6 4.00E-03 - 4.00E-03 3.37E-01 8.65E-01 1.70E+03 nc NA NA No BKG, BSL129-00-0 Pyrene 9.50E-03 4.21E-01 mg/Kg FWP-FP5-SD01 4 / 6 4.00E-03 - 4.00E-03 4.21E-01 4.65E-01 1.70E+02 nc NA NA No BKG, BSLBAPTEQ Total BAP TEQ 9.20E-03 4.35E-01 mg/Kg FWP-FP5-SD01 3 / 6 - 4.35E-01 8.76E-01 1.50E-02 ca NA NA No BKG, ASL

VOCs67-64-1 Acetone 3.70E-02 3.70E-02 mg/Kg FWP-FP3-SD01 1 / 6 9.00E-03 - 1.40E-02 3.70E-02 NA 6.10E+03 nc NA NA No BSL

Qualifier Qualifier

TABLE 2.12OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 2

009564

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.12OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

100-41-4 Ethylbenzene 1.50E-03 1.50E-03 mg/Kg FWP-FP3-SD01 1 / 6 1.00E-03 - 1.00E-03 1.50E-03 NA 5.40E+00 ca NA NA No BSL108-88-3 Toluene 2.50E-03 2.50E-03 mg/Kg FWP-FP3-SD01 1 / 6 1.00E-03 - 1.00E-03 2.50E-03 NA 5.00E+02 nc NA NA No BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the sediment background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for Total Dioxin TEQ. BAP = benzo(a)pyrene The SL for pyrene was used as the SL for benzo(g,h,i)perylene. HEAST = Health Effects Assessment Summary TablesThe SL for anthracene was used as the SL for phenanthrene. HQ = hazard quotientSL for benzo(a)pyrene was used as the SL for total BAP TEQ. HHRA = Human Health Risk Assessment

J = compound was detected below the reporting limit in the sample(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) L = compound was detected above the Method Detection Limit (MDL) but

Deletion Reason: Below Screening Level (BSL) below the Contract Required Quantitation Limit (CRQL)No Toxicity Information (NTX) NA = not availableBelow Background Value (BKG) SL = screening level

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." SVOC = semi-volatile organic compoundVOC = volatile organic compound

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz(a,h)anthracene, TEQ = toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." mg/kg = milligram per kilogram

ng/kg = nanogram per kilogramPAH = polycyclic aromatic hydrocarbon

PAGE 2 OF 2

009565

North Area, American Creosote Works

Winnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Surface Water Exposure Medium: Surface Water

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Surface Water SVOCs(North Creosote 91-57-6 2-Methylnaphthalene 1.30E-01 1.80E-01 µg/L CBC-FW2-SW01 2 / 12 - 1.80E-01 1.70E-01 2.70E+00 nc NA NA No BSLBranch Creek) 83-32-9 Acenaphthene 5.00E-01 L,J 5.00E-01 L,J µg/L CBC-N4-SW01 1 / 12 5.00E+00 - 5.00E+00 5.00E-01 NA 4.00E+01 nc NA NA No BSL

191-24-2 Benzo(g,h,i)perylene 6.40E-01 L,J 7.00E-01 L,J µg/L CBC-FW2-SW01 5 / 12 5.00E+00 - 5.00E+00 7.00E-01 NA 8.70E+00 nc NA NA No BSL85-68-7 Benzyl Butyl Phthalate 4.90E-01 L,J 1.40E+00 L,J µg/L CBC-FW2-SW01 2 / 12 5.00E+00 - 5.00E+00 1.40E+00 NA 1.40E+01 ca NA NA No BSL

117-81-7 Bis(2-Ethylhexyl)phthalate 6.90E-01 L,J 8.40E+00 µg/L CBC-FW2-SW01 11 / 12 5.00E+00 - 5.00E+00 8.40E+00 NA 4.80E+00 ca NA NA Yes ASL105-60-2 Caprolactam 1.20E+01 1.20E+01 µg/L CBC-N9-SW01 1 / 12 5.00E+00 - 5.00E+00 1.20E+01 NA 7.70E+02 nc NA NA No BSL53-70-3 Dibenz(a,h)anthracene 9.10E-02 L,J 9.10E-02 L,J µg/L CBC-FW1-SW01 1 / 12 - 9.10E-02 1.64E-01 2.90E-03 ca NA NA -- (5)84-66-2 Diethyl Phthalate 4.50E-01 L,J 1.60E+00 L,J µg/L CBC-FW2-SW01 6 / 12 5.00E+00 - 5.00E+00 1.60E+00 1.03E+00 1.10E+03 nc NA NA No BSL84-74-2 Di-n-Butyl Phthalate 7.50E-01 L,J 2.30E+00 L,J µg/L CBC-N5-SW01 11 / 12 5.00E+00 - 5.00E+00 2.30E+00 NA 6.70E+01 nc NA NA No BSL

117-84-0 Di-n-Octylphthalate 5.60E-01 L,J 9.40E-01 L,J µg/L CBC-FW2-SW01 4 / 12 5.00E+00 - 5.00E+00 9.40E-01 NA 1.60E+01 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.70E-01 1.70E-01 µg/L CBC-FW1-SW01 1 / 12 - 1.70E-01 2.60E-01 2.90E-02 ca NA NA -- (5)91-20-3 Naphthalene 9.60E-02 L,J 7.90E-01 µg/L CBC-FW2-SW01 11 / 12 - 7.90E-01 9.70E-01 1.40E-01 ca NA NA No BKG, ASL87-86-5 Pentachlorophenol 1.10E-01 L,J 2.90E-01 J µg/L CBC-N2-SW01 7 / 12 - 2.90E-01 NA 3.50E-02 ca NA NA Yes ASL

BAPTEQ Total BAP TEQ 1.69E-01 1.69E-01 µg/L CBC-FW1-SW01 1 / 12 - 1.69E-01 2.11E+01 2.90E-03 ca NA NA No BKG, ASLVOCs

106-46-7 1,4-Dichlorobenzene 2.50E-01 L,J 2.50E-01 L,J µg/L CBC-FW2-SW01 1 / 12 - 2.50E-01 5.90E-01 4.20E-01 ca NA NA No BKG, BSL67-64-1 Acetone 4.60E+00 L,J 2.50E+01 µg/L CBC-FW2-SW01 9 / 12 5.00E+00 - 5.00E+00 2.50E+01 1.85E+01 1.20E+03 nc NA NA No BSL71-43-2 Benzene 1.00E-01 L,J 4.40E-01 L,J µg/L CBC-FW2-SW01 3 / 12 - 4.40E-01 7.50E-01 3.90E-01 ca NA NA No BKG, ASL75-27-4 Bromodichloromethane 1.30E+00 1.80E+00 µg/L CBC-N7-SW01 3 / 12 - 1.80E+00 NA 1.20E-01 ca NA NA Yes ASL

108-90-7 Chlorobenzene 4.00E-02 L,J 4.00E-02 L,J µg/L CBC-FW1-SW01 1 / 12 - 4.00E-02 NA 7.20E+00 nc NA NA No BSL67-66-3 Chloroform 4.00E-01 L,J 1.70E+00 µg/L CBC-N7-SW01 5 / 12 - 1.70E+00 NA 1.90E-01 ca NA NA Yes ASL

124-48-1 Dibromochloromethane 5.40E-01 8.80E-01 µg/L CBC-N7-SW01 3 / 12 - 8.80E-01 NA 1.50E-01 ca NA NA Yes ASL100-41-4 Ethylbenzene 1.10E-01 L,J 1.80E-01 L,J µg/L CBC-N3-SW01 7 / 12 - 1.80E-01 3.90E-01 1.30E+00 ca NA NA No BKG, BSL78-93-3 Methyl Ethyl Ketone (2-Butanone) 1.80E+00 L,J 1.80E+00 L,J µg/L CBC-FW1-SW01 1 / 12 5.00E+00 - 5.00E+00 1.80E+00 NA 4.90E+02 nc NA NA No BSL95-47-6 o-Xylene 1.30E-01 L,J 1.70E-01 L,J µg/L CBC-N3-SW01 3 / 12 - 1.70E-01 NA 1.90E+01 nc NA NA No BSL

1634-04-4 tert-Butyl Methyl Ether 8.50E-02 L,J 4.00E-01 L,J µg/L CBC-FW1-SW01 2 / 12 - 4.00E-01 7.20E-01 1.20E+01 ca NA NA No BKG, BSL108-88-3 Toluene 9.50E-02 L,J 4.70E-01 L,J µg/L CBC-FW2-SW01 6 / 12 - 4.70E-01 7.10E-01 8.60E+01 nc NA NA No BKG, BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the surface water background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for tap water (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientThe SL for benzo(a)pyrene was used as the SL for total BAP TEQ. NA = not available

J = compound was detected below the reporting limit in the sample(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) L = compound was detected above the Method Detection Limit (MDL) but below the

Deletion Reason: Below Screening Level (BSL) Contract Required Quantitation Limit (CRQL)Below Background Value (BKG) BAP TEQ = benzo(a)pyrene toxic equivalent

(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, PAH = polycyclic aromatic hydrocarbonindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. SL = screening level

SVOC = semi-volatile organic compoundVOC = volatile organic compoundµg/L= microgram per literPAH = polycyclic aromatic hydrocarbon

Qualifier Qualifier

TABLE 2.13OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 1

009566

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Sediment Dioxins/Furans(North Creosote 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 5.09E+01 2.97E+03 ng/kg CBC-N2-SD01 7 / 7 - 2.97E+03 2.68E+02 NA NA NA -- (5)Branch Creek) 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 6.51E-01 L,J 7.31E+00 ng/kg CBC-N6-SD01 7 / 7 - 7.31E+00 5.05E+00 NA NA NA -- (5)

57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 1.52E+00 L,J 6.54E+01 ng/kg CBC-N2-SD01 7 / 7 - 6.54E+01 8.64E+00 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 2.03E+00 L,J 1.07E+01 J ng/kg CBC-N2-SD01 7 / 7 - 1.07E+01 6.91E+00 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 3.04E-01 L,J 4.74E+00 ng/kg CBC-N6-SD01 7 / 7 - 4.74E+00 1.99E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 2.03E-01 L,J 1.94E+00 ng/kg CBC-N6-SD01 7 / 7 - 1.94E+00 4.68E-01 NA NA NA -- (5)37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 1.36E+02 1.17E+04 ng/kg CBC-N2-SD01 7 / 7 - 1.17E+04 5.37E+02 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 4.50E+01 6.13E+02 J ng/kg CBC-N2-SD01 7 / 7 - 6.13E+02 8.49E+01 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 8.00E+02 3.14E+04 J ng/kg CBC-N2-SD01 7 / 7 - 3.14E+04 9.18E+03 NA NA NA -- (5)36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 5.34E+00 3.26E+01 J ng/kg CBC-N6-SD01 7 / 7 - 3.26E+01 1.48E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 2.62E+00 6.06E+01 ng/kg CBC-N2-SD01 7 / 7 - 6.06E+01 1.08E+01 4.50E+00 ca NA NA Yes ASL41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 3.62E+00 1.94E+01 ng/kg CBC-N7-SD01 7 / 7 - 1.94E+01 7.61E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 6.40E+00 5.67E+02 ng/kg CBC-N2-SD01 7 / 7 - 5.67E+02 2.83E+01 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 4.03E-01 L,J 3.92E+01 ng/kg CBC-N2-SD01 7 / 7 - 3.92E+01 3.66E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 3.04E+00 2.65E+01 J ng/kg CBC-N2-SD01 5 / 7 - 2.65E+01 2.62E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 1.89E-01 L,J 6.85E+00 J ng/kg CBC-FW2-SD01 6 / 7 - 6.85E+00 2.27E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 7.67E-01 L,J 2.99E+00 J ng/kg CBC-N2-SD01 5 / 7 - 2.99E+00 1.02E+00 NA NA NA -- (5)57117-41-6 1,2,3,7,8-Pentachlorodibenzofuran 6.06E-02 L,J 2.12E+00 L,J ng/kg CBC-FW2-SD01 4 / 7 0.00E+00 - 1.00E+00 2.12E+00 NA NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 2.32E+00 L,J 1.09E+01 ng/kg CBC-FW2-SD01 5 / 7 - 1.09E+01 3.04E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 4.97E-01 L,J 5.54E+00 ng/kg CBC-FW2-SD01 5 / 7 - 5.54E+00 2.15E+00 NA NA NA -- (5)51207-31-9 2,3,7,8-Tetrachlorodibenzofuran 9.93E-02 L,J 1.33E+00 ng/kg CBC-FW2-SD01 5 / 7 - 1.33E+00 4.55E-01 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 2.05E+01 3.15E+03 ng/kg CBC-N2-SD01 7 / 7 - 3.15E+03 1.10E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 6.13E+00 6.01E+02 J ng/kg CBC-N2-SD01 7 / 7 - 6.01E+02 4.02E+01 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 1.75E+01 3.93E+03 ng/kg CBC-N2-SD01 7 / 7 - 3.93E+03 1.06E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 5.04E-01 1.16E+02 J ng/kg CBC-FW2-SD01 7 / 7 - 1.16E+02 1.60E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 5.14E-01 1.73E+02 ng/kg CBC-FW2-SD01 7 / 7 - 1.73E+02 7.21E+00 NA NA NA -- (5)

SVOCs118-79-6 2,4,6-Tribromophenol 4.59E-01 6.14E-01 mg/Kg CBC-N1-SD01 5 / 5 - 6.14E-01 NA NA NA NA No NTX321-60-8 2-Fluorobiphenyl 2.94E-01 3.64E-01 mg/Kg CBC-N2-SD01 5 / 5 - 3.64E-01 NA NA NA NA No NTX367-12-4 2-Fluorophenol 4.06E-01 5.23E-01 mg/Kg CBC-N3-SD01 5 / 5 - 5.23E-01 NA NA NA NA No NTX83-32-9 Acenaphthene 9.60E-03 1.25E+00 mg/Kg CBC-N2-SD01 7 / 12 4.00E-03 - 7.80E-02 1.25E+00 1.70E-01 3.40E+02 nc NA NA No BSL208-96-8 Acenaphthylene 4.40E-03 2.00E-01 J mg/Kg CBC-N10-SD01 7 / 12 4.00E-03 - 8.00E-02 2.00E-01 NA 3.40E+02 nc NA NA No BSL120-12-7 Anthracene 6.10E-03 6.80E-01 mg/Kg CBC-N2-SD01 7 / 12 4.00E-03 - 7.80E-02 6.80E-01 2.25E-01 1.70E+03 nc NA NA No BSL56-55-3 Benzo(a)anthracene 1.80E-02 2.62E+00 mg/Kg CBC-N2-SD01 8 / 12 4.00E-03 - 2.30E-01 2.62E+00 NA 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.70E-02 2.36E+00 mg/Kg CBC-N2-SD01 8 / 12 4.00E-03 - 4.60E-01 2.36E+00 NA 1.50E-02 ca NA NA -- (6)205-99-2 Benzo(b)fluoranthene 2.00E-02 4.31E+00 mg/Kg CBC-N2-SD01 9 / 12 4.00E-03 - 2.00E+00 4.31E+00 NA 1.50E-01 ca NA NA -- (6)191-24-2 Benzo(g,h,i)perylene 1.70E-02 1.52E+00 mg/Kg CBC-N2-SD01 7 / 12 4.00E-03 - 4.60E-01 1.52E+00 NA 1.70E+02 nc NA NA No BSL207-08-9 Benzo(k)fluoranthene 1.50E-02 2.25E+00 mg/Kg CBC-N2-SD01 8 / 12 4.00E-03 - 4.60E-01 2.25E+00 NA 1.50E+00 ca NA NA -- (6)117-81-7 Bis(2-Ethylhexyl)phthalate 3.00E-02 L,J 3.41E-01 mg/Kg CBC-N2-SD01 5 / 12 2.10E-01 - 2.00E+00 3.41E-01 NA 3.50E+01 ca NA NA No BSL218-01-9 Chrysene 1.40E-02 4.41E+00 mg/Kg CBC-N2-SD01 9 / 12 4.00E-03 - 4.60E-01 4.41E+00 2.15E-01 1.50E+01 ca NA NA -- (6)53-70-3 Dibenz(a,h)anthracene 6.80E-03 2.40E-01 J mg/Kg CBC-N10-SD01 6 / 12 4.00E-03 - 7.80E-02 2.40E-01 NA 1.50E-02 ca NA NA -- (6)84-74-2 Di-n-Butyl Phthalate 3.40E-02 L,J 3.60E-02 L,J mg/Kg CBC-N9-SD01 2 / 12 2.10E-01 - 2.00E+00 3.60E-02 NA 6.10E+02 nc NA NA No BSL206-44-0 Fluoranthene 1.90E-02 L,J 7.51E+00 mg/Kg CBC-N2-SD01 11 / 12 4.50E-02 - 9.90E-01 7.51E+00 6.75E-01 2.30E+02 nc NA NA No BSL86-73-7 Fluorene 8.70E-03 7.56E-01 mg/Kg CBC-N2-SD01 7 / 12 4.00E-03 - 7.80E-02 7.56E-01 2.35E-01 2.30E+02 nc NA NA No BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.50E-02 1.57E+00 mg/Kg CBC-N2-SD01 7 / 12 4.00E-03 - 4.60E-01 1.57E+00 NA 1.50E-01 ca NA NA -- (6)91-20-3 Naphthalene 2.00E-02 1.16E-01 mg/Kg CBC-N2-SD01 2 / 12 4.00E-03 - 7.80E-02 1.16E-01 NA 3.60E+00 ca NA NA No BSL87-86-5 Pentachlorophenol 2.10E-02 L,J 6.10E-02 J mg/Kg CBC-N10-SD01 4 / 11 1.60E-02 - 4.30E-01 6.10E-02 NA 8.90E-01 ca NA NA No BSL

Qualifier Qualifier

TABLE 2.14OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 2

009567

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.14OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

85-01-8 Phenanthrene 6.00E-03 1.32E+00 mg/Kg CBC-N2-SD01 9 / 12 4.00E-03 - 7.80E-02 1.32E+00 8.65E-01 1.70E+03 nc NA NA No BSL129-00-0 Pyrene 2.20E-02 8.31E+00 mg/Kg CBC-N2-SD01 11 / 12 4.00E-03 - 4.60E-01 8.31E+00 4.65E-01 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 3.93E-02 3.33E+00 mg/Kg CBC-N2-SD01 9 / 12 - 3.33E+00 8.76E-01 1.50E-02 ca NA NA Yes ASL

VOCs100-41-4 Ethylbenzene 8.60E-04 L,J 8.60E-04 L,J mg/Kg CBC-N6-SD01 1 / 12 1.00E-03 - 2.00E-03 8.60E-04 NA 5.40E+00 ca NA NA No BSL

XYLENEMP m,p-Xylene 2.90E-03 2.90E-03 mg/Kg CBC-N6-SD01 1 / 12 1.00E-03 - 2.00E-03 2.90E-03 NA 6.30E+01 nc NA NA No BSL95-47-6 o-Xylene 7.90E-04 L,J 7.90E-04 L,J mg/Kg CBC-N6-SD01 1 / 12 1.00E-03 - 2.00E-03 7.90E-04 NA 6.90E+01 nc NA NA No BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the sediment background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for acenaphthene was used as the SL for acenaphthylene. HEAST = Health Effects Assessment Summary TablesThe SL for pyrene was used as the SL for benzo(g,h,i)perylene. HQ = hazard quotientThe SL for anthracene was used as the SL for phenanthrene. HHRA = Human Health Risk AssessmentSL for benzo(a)pyrene was used as the SL for total BAP TEQ. J = compound was detected below the reporting limit in the sampleThe SL for xylenes was used as the SL for m,p-Xylene (sum of isomers). L = compound was detected above the Method Detection Limit (MDL) but

below the Contract Required Quantitation Limit (CRQL)(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) NA = not available

Deletion Reason: Below Screening Level (BSL) SL = screening levelNo Toxicity Information (NTX) SVOC = semi-volatile organic compound

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." VOC = volatile organic compoundTEQ = toxic equivalent

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, mg/kg = milligram per kilogramindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." ng/kg = nanogram per kilogram

PAH = polycyclic aromatic hydrocarbon

PAGE 2 OF 2

009568

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Surface Water Exposure Medium: Surface Water

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Surface Water SVOCs(West Creosote 50-32-8 Benzo(a)pyrene 1.80E-01 2.20E-01 µg/L CBC-W3-SW01 4 / 4 - 2.20E-01 3.60E-01 2.90E-03 ca NA NA -- (5)Branch Creek) 53-70-3 Dibenz(a,h)anthracene 5.50E-02 L,J 1.50E-01 µg/L CBC-W3-SW01 2 / 4 - 1.50E-01 1.64E-01 2.90E-03 ca NA NA -- (5)

84-66-2 Diethyl Phthalate 4.30E-01 L,J 4.30E-01 L,J µg/L CBC-W1-SW01 1 / 4 5.00E+00 - 5.00E+00 4.30E-01 1.03E+00 1.10E+03 nc NA NA No BKG, BSL193-39-5 Indeno(1,2,3-c,d)Pyrene 1.20E-01 2.30E-01 µg/L CBC-W3-SW01 4 / 4 - 2.30E-01 2.60E-01 2.90E-02 ca NA NA -- (5)91-20-3 Naphthalene 1.00E-01 2.10E-01 µg/L CBC-W1-SW01 4 / 4 - 2.10E-01 9.70E-01 1.40E-01 ca NA NA No BKG, ASL87-86-5 Pentachlorophenol 1.00E-01 L,J 4.30E-01 µg/L CBC-W3-SW01 2 / 4 - 4.30E-01 NA 3.50E-02 ca NA NA Yes ASL

BAPTEQ Total BAP TEQ 2.53E-01 4.04E-01 µg/L CBC-W1-SW01 4 / 4 - 4.04E-01 2.11E+01 2.90E-03 ca NA NA No BKG, ASLVOC

67-64-1 Acetone 1.00E+00 L,J 1.00E+00 L,J µg/L CBC-W2-SW01 1 / 4 5.00E+00 - 5.00E+00 1.00E+00 1.85E+01 1.20E+03 nc NA NA No BKG, BSL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the surface water background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for tap water (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenicThe SL for benzo(a)pyrene was used as the SL for total BAP TEQ. HQ = hazard quotient

NA = not available(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) J = compound was detected below the reporting limit in the sample

Deletion Reason: Below Screening Level (BSL) L = compound was detected above the Method Detection Limit (MDL) but below the Contract Required Quantitation Limit (CRQL)

(5) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, BAP TEQ = benzo(a)pyrene toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as Total BAP TEQ. PAH = polycyclic aromatic hydrocarbon

SL = screening levelSVOC = semi-volatile organic compoundVOC = volatile organic compoundµg/L= microgram per literPAH = polycyclic aromatic hydrocarbon

Qualifier Qualifier

TABLE 2.15OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

PAGE 1 OF 1

009569

North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Sediment Dioxins/Furans(West Creosote 35822-46-9 1,2,3,4,6,7,8-Heptachlorodibenzo-p-dioxin 2.73E+02 2.73E+02 ng/kg CBC-W3-SD01 1 / 1 - 2.73E+02 2.68E+02 NA NA NA -- (5)Branch Creek) 39227-28-6 1,2,3,4,7,8-Hexachlorodibenzo-p-dioxin 2.69E+00 2.69E+00 ng/kg CBC-W3-SD01 1 / 1 - 2.69E+00 5.05E+00 NA NA NA -- (5)

57653-85-7 1,2,3,6,7,8-Hexachlorodibenzo-p-dioxin 7.63E+00 7.63E+00 ng/kg CBC-W3-SD01 1 / 1 - 7.63E+00 8.64E+00 NA NA NA -- (5)19408-74-3 1,2,3,7,8,9-Hexachlorodibenzo-p-dioxin 5.18E+00 5.18E+00 ng/kg CBC-W3-SD01 1 / 1 - 5.18E+00 6.91E+00 NA NA NA -- (5)40321-76-4 1,2,3,7,8-Pentachlorodibenzo-p-dioxin 8.82E-01 L,J 8.82E-01 L,J ng/kg CBC-W3-SD01 1 / 1 - 8.82E-01 1.99E+00 NA NA NA -- (5)1746-01-6 2,3,7,8-Tetrachlorodibenzo-p-dioxin 1.66E-01 L,J 1.66E-01 L,J ng/kg CBC-W3-SD01 1 / 1 - 1.66E-01 4.68E-01 NA NA NA -- (5)

37871-00-4 Heptachlorinated Dibenzo-p-dioxins (Total) 5.91E+02 5.91E+02 ng/kg CBC-W3-SD01 1 / 1 - 5.91E+02 5.37E+02 NA NA NA -- (5)34465-46-8 Hexachlorinated Dibenzo-p-dioxins (Total) 5.68E+01 5.68E+01 ng/kg CBC-W3-SD01 1 / 1 - 5.68E+01 8.49E+01 NA NA NA -- (5)3268-87-9 Octachlorodibenzo-p-Dioxin 3.27E+03 3.27E+03 ng/kg CBC-W3-SD01 1 / 1 - 3.27E+03 9.18E+03 NA NA NA -- (5)

36088-22-9 Pentachlorinated Dibenzo-p-dioxins (Total) 8.14E+00 8.14E+00 ng/kg CBC-W3-SD01 1 / 1 - 8.14E+00 1.48E+01 NA NA NA -- (5)DIOXTEQ Total Dioxin TEQ 7.66E+00 7.66E+00 ng/kg CBC-W3-SD01 1 / 1 - 7.66E+00 1.08E+01 4.50E+00 ca NA NA No BKG, ASL

41903-57-5 Tetrachlorinated Dibenzo-p-Dioxins (Total) 4.00E+00 4.00E+00 ng/kg CBC-W3-SD01 1 / 1 - 4.00E+00 7.61E+00 NA NA NA -- (5)67562-39-4 1,2,3,4,6,7,8-Heptachlorodibenzofuran 5.85E+01 5.85E+01 ng/kg CBC-W3-SD01 1 / 1 - 5.85E+01 2.83E+01 NA NA NA -- (5)55673-89-7 1,2,3,4,7,8,9-Heptachlorodibenzofuran 3.82E+00 3.82E+00 ng/kg CBC-W3-SD01 1 / 1 - 3.82E+00 3.66E+00 NA NA NA -- (5)70648-26-9 1,2,3,4,7,8-Hexachlorodibenzofuran 1.63E+00 L,J 1.63E+00 L,J ng/kg CBC-W3-SD01 1 / 1 - 1.63E+00 2.62E+00 NA NA NA -- (5)57117-44-9 1,2,3,6,7,8-Hexachlorodibenzofuran 9.85E-01 L,J 9.85E-01 L,J ng/kg CBC-W3-SD01 1 / 1 - 9.85E-01 2.27E+00 NA NA NA -- (5)72918-21-9 1,2,3,7,8,9-Hexachlorodibenzofuran 4.78E-01 L,J 4.78E-01 L,J ng/kg CBC-W3-SD01 1 / 1 - 4.78E-01 1.02E+00 NA NA NA -- (5)60851-34-5 2,3,4,6,7,8-Hexachlorodibenzofuran 1.80E+00 L,J 1.80E+00 L,J ng/kg CBC-W3-SD01 1 / 1 - 1.80E+00 3.04E+00 NA NA NA -- (5)57117-31-4 2,3,4,7,8-Pentachlorodibenzofuran 3.71E-01 L,J 3.71E-01 L,J ng/kg CBC-W3-SD01 1 / 1 - 3.71E-01 2.15E+00 NA NA NA -- (5)38998-75-3 Heptachlorinated Dibenzofurans (Total) 2.17E+02 2.17E+02 ng/kg CBC-W3-SD01 1 / 1 - 2.17E+02 1.10E+02 NA NA NA -- (5)55684-94-1 Hexachlorinated Dibenzofurans (Total) 4.97E+01 4.97E+01 ng/kg CBC-W3-SD01 1 / 1 - 4.97E+01 4.02E+01 NA NA NA -- (5)39001-02-0 Octachlorodibenzofuran 2.24E+02 2.24E+02 ng/kg CBC-W3-SD01 1 / 1 - 2.24E+02 1.06E+02 NA NA NA -- (5)30402-15-4 Pentachlorinated Dibenzofurans (Total) 7.75E+00 7.75E+00 ng/kg CBC-W3-SD01 1 / 1 - 7.75E+00 1.60E+01 NA NA NA -- (5)55722-27-5 Tetrachlorinated Dibenzofurans (Total) 1.11E+00 1.11E+00 ng/kg CBC-W3-SD01 1 / 1 - 1.11E+00 7.21E+00 NA NA NA -- (5)

SVOCs118-79-6 2,4,6-Tribromophenol 5.06E-01 6.87E-01 mg/Kg CBC-W3-SD01 4 / 4 - 6.87E-01 NA NA NA NA No NTX321-60-8 2-Fluorobiphenyl 3.21E-01 4.36E-01 mg/Kg CBC-W4-SD01 4 / 4 - 4.36E-01 NA NA NA NA No NTX367-12-4 2-Fluorophenol 4.40E-01 6.00E-01 mg/Kg CBC-W4-SD01 4 / 4 - 6.00E-01 NA NA NA NA No NTX83-32-9 Acenaphthene 5.34E-02 5.34E-02 mg/Kg CBC-W4-SD01 1 / 4 - 5.34E-02 1.70E-01 3.40E+02 nc NA NA No BKG, BSL56-55-3 Benzo(a)anthracene 3.56E-01 J 3.56E-01 J mg/Kg CBC-W4-SD01 1 / 4 - 3.56E-01 NA 1.50E-01 ca NA NA -- (6)50-32-8 Benzo(a)pyrene 2.18E-01 J 2.18E-01 J mg/Kg CBC-W4-SD01 1 / 4 - 2.18E-01 NA 1.50E-02 ca NA NA -- (6)

205-99-2 Benzo(b)fluoranthene 3.38E-01 J 3.38E-01 J mg/Kg CBC-W4-SD01 1 / 4 - 3.38E-01 NA 1.50E-01 ca NA NA -- (6)207-08-9 Benzo(k)fluoranthene 2.26E-01 J 2.26E-01 J mg/Kg CBC-W4-SD01 1 / 4 - 2.26E-01 NA 1.50E+00 ca NA NA -- (6)218-01-9 Chrysene 4.51E-01 J 4.51E-01 J mg/Kg CBC-W4-SD01 1 / 4 - 4.51E-01 2.15E-01 1.50E+01 ca NA NA -- (6)206-44-0 Fluoranthene 7.23E-02 J 5.96E-01 mg/Kg CBC-W4-SD01 2 / 4 - 5.96E-01 6.75E-01 2.30E+02 nc NA NA No BKG, BSL87-86-5 Pentachlorophenol 1.57E-01 1.57E-01 mg/Kg CBC-W4-SD01 1 / 4 - 1.57E-01 NA 8.90E-01 ca NA NA No BSL85-01-8 Phenanthrene 1.30E-01 1.30E-01 mg/Kg CBC-W4-SD01 1 / 4 - 1.30E-01 8.65E-01 1.70E+03 nc NA NA No BKG, BSL

129-00-0 Pyrene 6.99E-02 J 1.94E+00 mg/Kg CBC-W4-SD01 3 / 4 - 1.94E+00 4.65E-01 1.70E+02 nc NA NA No BSLBAPTEQ Total BAP TEQ 4.01E-01 4.01E-01 mg/Kg CBC-W4-SD01 1 / 4 - 4.01E-01 8.76E-01 1.50E-02 ca NA NA No BKG, ASL

(1) Maximum concentration is used for screening. COPC = chemical of potential concern

(2) Refer to Table 2, Supplement B for the calculation of the sediment background values. ARAR/TBC = Applicable or Relevant and Appropriate Requirement/ To Be Considered

(3) Regional screening levels for industrial and residential soil (November 2013). Concentrations based on non-carcinogenic health effects are ca = carcinogenicadjusted using HQ=0.1. nc = noncarcinogenic

Qualifier Qualifier

TABLE 2.16OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

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North Area, American Creosote WorksWinnfield, Louisiana

Scenario Timeframe: Current/Future Medium: Sediment Exposure Medium: Sediment

Exposure CAS Chemical Units Location Detection Range of Concentration Background Screening Potential Potential COPC Rationale forPoint Number of Maximum Frequency Detection Used for Value Toxicity Value ARAR/TBC ARAR/TBC Flag Selection or

Concentration Limits Screening Value Source Deletion(1) (2) (3) (4)

Qualifier Qualifier

TABLE 2.16OCCURRENCE, DISTRIBUTION, AND SELECTION OF CHEMICALS OF POTENTIAL CONCERN

Minimum MaximumConcentration Concentration

The SL for 2,3,7,8-TCDD was used as the SL for total dioxin TEQ. BAP = benzo(a)pyrene The SL for anthracene was used as the SL for phenanthrene. HEAST = Health Effects Assessment Summary TablesSL for benzo(a)pyrene was used as the SL for total BAP TEQ. HQ = hazard quotient

HHRA = Human Health Risk Assessment(4) Rationale Codes Selection Reason: Above Screening Levels (ASL) J = compound was detected below the reporting limit in the sample

Deletion Reason: Below Screening Level (BSL) L = compound was detected above the Method Detection Limit (MDL) but No Toxicity Information (NTX) below the Contract Required Quantitation Limit (CRQL)Below Background Value (BKG) NA = not available

(5) Dioxin/furan congeners will be addressed in total in the HHRA as "Total Dioxin TEQ." SL = screening levelSVOC = semi-volatile organic compound

(6) Carcinogenic PAHs (benzo[a]pyrene, benzo[a]anthracene, benzo[b]fluoranthene, benzo[k]fluoranthene, chrysene, dibenz[a,h]anthracene, TEQ = toxic equivalentindeno[1,2,3-cd]pyrene) will be addressed in total in the HHRA as "Total BAP TEQ." mg/kg = milligram per kilogram

ng/kg = nanogram per kilogramPAH = polycyclic aromatic hydrocarbon

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009571

TABLE 2 SUPPLEMENT ABackground Threshold Values for SoilRisk Assessment Addendum, American Creosote Works, Winnfield, Louisiana

Chemical Units FOD DL RangeArithmetic Mean (1) 2x Mean 95/95 UTL (3)

95/95 UTL Basis BTV (4)

SVOCs ‐ Surface Soil (0‐1 foot)4‐Methylphenol (p‐Cresol) mg/kg 0.11 L,J 0.11 L,J 1 / 6 2.00E‐01 ‐ 2.10E‐01 0.103 NA 0.207 NC (a) 0.207

Benzo(a)anthracene mg/kg 0.006 0.015 2 / 6 4.00E‐03 ‐ 4.00E‐03 0.00481 NA 0.00962 0.015 (b) 0.015Benzo(a)pyrene mg/kg 0.034 0.034 1 / 6 4.00E‐03 ‐ 4.00E‐03 0.00731 NA 0.0146 NC (a) 0.0146

Benzo(b)fluoranthene mg/kg 0.018 0.034 2 / 6 4.00E‐03 ‐ 4.00E‐03 0.00998 NA 0.0200 0.034 (b) 0.034Benzo(g,h,i)perylene mg/kg 0.0051 0.035 L,J 6 / 6 4.00E‐03 ‐ 2.10E‐01 0.0139 NA 0.0279 0.0563 (c) 0.0563Benzo(k)fluoranthene mg/kg 0.03 L,J 0.03 L,J 1 / 6 2.00E‐01 ‐ 2.10E‐01 0.0892 NA 0.1783 NC (a) 0.178Benzyl Butyl Phthalate mg/kg 0.017 L,J 0.017 L,J 1 / 6 2.00E‐01 ‐ 2.10E‐01 0.087 NA 0.174 NC (a) 0.174

Chrysene mg/kg 0.0081 0.03 L,J 2 / 6 4.00E‐03 ‐ 2.10E‐01 0.00766 NA 0.0153 0.03 (b) 0.03Dibenz(a,h)anthracene mg/kg 0.0061 0.01 2 / 6 4.00E‐03 ‐ 4.00E‐03 0.00399 NA 0.00798 0.01 (b) 0.01

Fluoranthene mg/kg 0.033 L,J 0.033 L,J 1 / 6 2.00E‐01 ‐ 2.10E‐01 0.0897 NA 0.1793 NC (a) 0.179Indeno(1,2,3‐c,d)Pyrene mg/kg 0.0032 L,J 0.031 2 / 6 4.00E‐03 ‐ 4.00E‐03 0.00701 NA 0.0140 0.031 (b) 0.031

Pentachlorophenol mg/kg 0.0088 J 0.0088 J 1 / 6 8.00E‐03 ‐ 8.00E‐03 0.0048 NA 0.0096 NC (a) 0.0096Total BAP TEQ mg/kg 0.00577 0.0523 3 / 6  ‐  0.312 NA 0.623 0.432 (d) 0.432

SVOCs ‐ Subsurface Soil (5‐7 feet)Benzo(b)fluoranthene mg/kg 0.0033 L,J 0.0033 L,J 1 / 6 4.00E‐03 ‐ 4.00E‐03 0.00217 NA 0.00433 NC (a) 0.0043Benzo(g,h,i)perylene mg/kg 0.005 0.028 L,J 4 / 6 4.00E‐03 ‐ 2.10E‐01 0.0427 NA 0.0853 0.028 (d) 0.028Benzo(k)fluoranthene mg/kg 0.016 L,J 0.016 L,J 1 / 6 1.90E‐01 ‐ 2.10E‐01 0.0877 NA 0.1753 NC (a) 0.175Benzyl Butyl Phthalate mg/kg 0.035 L,J 0.035 L,J 1 / 6 1.90E‐01 ‐ 2.10E‐01 0.0908 NA 0.1817 NC (a) 0.182

Chrysene mg/kg 0.024 L,J 0.024 L,J 1 / 6 4.00E‐03 ‐ 2.10E‐01 0.0228 NA 0.0456 NC (a) 0.0456Dibenz(a,h)anthracene mg/kg 0.0026 L,J 0.0026 L,J 1 / 6 4.00E‐03 ‐ 4.00E‐03 0.00205 NA 0.0041 NC (a) 0.0041Indeno(1,2,3‐c,d)Pyrene mg/kg 0.0035 L,J 0.0035 L,J 1 / 6 4.00E‐03 ‐ 4.00E‐03 0.00221 NA 0.00442 NC (a) 0.00442

Total BAP TEQ mg/kg 0.00455 0.00655 3 / 6  ‐  0.310 NA 0.619 0.425 (d) 0.425Dioxins/Furans ‐ Surface Soil (0‐0.2 feet) †

1,2,3,4,6,7,8‐Heptachlorodibenzo‐p‐dioxin ng/kg 86.3 476 5 / 5 2.39E+00 ‐ 2.49E+00 229 306 457 853.5 (c) 853.51,2,3,4,7,8‐Hexachlorodibenzo‐p‐dioxin ng/kg 1.1 L,J 10.2 5 / 5 2.39E+00 ‐ 2.49E+00 4.93 4.89 9.86 20.82 (c) 20.821,2,3,6,7,8‐Hexachlorodibenzo‐p‐dioxin ng/kg 2.73 14.2 5 / 5 2.39E+00 ‐ 2.49E+00 7.53 7.85 15.06 25.47 (c) 25.471,2,3,7,8,9‐Hexachlorodibenzo‐p‐dioxin ng/kg 2.09 L,J 13.1 5 / 5 2.39E+00 ‐ 2.49E+00 6.75 6.76 13.51 25.64 (c) 25.641,2,3,7,8‐Pentachlorodibenzo‐p‐dioxin ng/kg 0.552 L,J 3.42 5 / 5 2.39E+00 ‐ 2.49E+00 1.92 1.53 L,J 3.83 7.479 (c) 7.4792,3,7,8‐Tetrachlorodibenzo‐p‐dioxin ng/kg 0.111 L,J 0.534 4 / 5 4.77E‐01 ‐ 4.98E‐01 0.349 0.468 L,J 0.698 0.534 (d) 0.534

Heptachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 203 916 5 / 5 ‐  480 575 961 1605 (c) 1605Hexachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 29.1 120 5 / 5 ‐  71.8 71.2 143.6 222.2 (c) 222.2

Octachlorodibenzo‐p‐Dioxin ng/kg 3300 8250 J 5 / 5 4.77E+00 ‐ 4.98E+00 5954 7140 J 11908 14219 (c) 14219Pentachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 7.08 20.4 5 / 5 ‐  14.0 13.4 28.0 40.37 (c) 40.37

Total Dioxin TEQ ng/kg 5.76 17.6396 5 / 5 ‐  9.91 11 19.83 31.81 (c) 31.81Tetrachlorinated Dibenzo‐p‐Dioxins (Total) ng/kg 1.46 4.29 5 / 5 ‐  3.03 3.21 6.06 8.103 (c) 8.1031,2,3,4,6,7,8‐Heptachlorodibenzofuran ng/kg 47 117 5 / 5 2.39E+00 ‐ 2.49E+00 70.2 75.2 140.5 184.1 (c) 184.11,2,3,4,7,8,9‐Heptachlorodibenzofuran ng/kg 0.968 L,J 4.61 5 / 5 2.39E+00 ‐ 2.49E+00 2.34 2.97 4.67 8.061 (c) 8.0611,2,3,4,7,8‐Hexachlorodibenzofuran ng/kg 2.49 3.77 5 / 5 2.39E+00 ‐ 2.49E+00 2.91 2.57 5.81 5.054 (c) 5.0541,2,3,6,7,8‐Hexachlorodibenzofuran ng/kg 1.41 L,J 2.86 5 / 5 2.39E+00 ‐ 2.49E+00 2.00 1.71 L,J 4.00 4.294 (c) 4.2941,2,3,7,8,9‐Hexachlorodibenzofuran ng/kg 0.347 L,J 0.655 L,J 5 / 5 2.39E+00 ‐ 2.49E+00 0.506 0.651 L,J 1.013 0.999 (c) 0.9991,2,3,7,8‐Pentachlorodibenzofuran ng/kg 0.312 L,J 0.52 L,J 4 / 5 2.39E+00 ‐ 2.49E+00 0.576 0.362 L,J 1.152 0.52 (d) 0.522,3,4,6,7,8‐Hexachlorodibenzofuran ng/kg 2.56 4.57 5 / 5 2.39E+00 ‐ 2.49E+00 3.23 2.79 6.46 6.6 (c) 6.62,3,4,7,8‐Pentachlorodibenzofuran ng/kg 0.595 L,J 1.51 L,J 5 / 5 2.39E+00 ‐ 2.49E+00 0.92 0.742 L,J 1.84 2.403 (c) 2.40

Min DetConcentration/Qual

Max DetConcentration/Qual

DU Sample (2)

Concentration/Qual

PAGE 1 OF 2009572

TABLE 2 SUPPLEMENT ABackground Threshold Values for SoilRisk Assessment Addendum, American Creosote Works, Winnfield, Louisiana

Chemical Units FOD DL RangeArithmetic Mean (1) 2x Mean 95/95 UTL (3)

95/95 UTL Basis BTV (4)

Min DetConcentration/Qual

Max DetConcentration/Qual

DU Sample (2)

Concentration/Qual2,3,7,8‐Tetrachlorodibenzofuran ng/kg 0.216 L,J 0.526 5 / 5 4.77E‐01 ‐ 4.98E‐01 0.353 0.355 L,J 0.706 0.894 (c) 0.894

Heptachlorinated Dibenzofurans (Total) ng/kg 75 318 5 / 5 ‐  164 210 328 547.5 (c) 547.5Hexachlorinated Dibenzofurans (Total) ng/kg 35.3 96.5 J 5 / 5 ‐  56.7 57.4 113.4 154.4 (c) 154.4

Octachlorodibenzofuran ng/kg 28.1 236 5 / 5 4.77E+00 ‐ 4.98E+00 117 177 235 435.1 (c) 435.1Pentachlorinated Dibenzofurans (Total) ng/kg 8.37 16.2 5 / 5 ‐  13.1 10.9 26.3 26.48 (c) 26.48Tetrachlorinated Dibenzofurans (Total) ng/kg 5.91 16.8 5 / 5 ‐  9.97 8.52 19.94 27.31 (c) 27.31

Notes:(1) Arithmetic mean was calculated using one‐half of the non‐detect results. J = compound was detected below the reporting limit in the sample(2)  Composite samples were collected for dioxins/furans. Each decision unit (DU) was divided into sample units (SUs) of approximately  L = compound was detected above the Method Detection Limit (MDL) but      2‐acre areas for the incremental composite sampling (ICS). One ICS sample was collected per SU using discrete sample locations within that                      below the Contract Required Quantitation Limit (CRQL)     SU. A composite sample was also collected for each DU and was comprised of the SU samples from that DU. Only the SU composite      samples were included in the 95/95 UTL calculation. The DU sample results are provided for comparison purposes.(3) EPA's ProUCL Software, version 5.0, was used to estimate the 95/95 UTL. If the data followed multiple distributions, the lowest UTL was selected.(4) The 95/95 UTL was selected as the BTV. Two times the arithmetic mean was used as the BTV if a 95/95 UTL could not be calculated. 95/95 UTL Basis Notes:      (a) A 95/95 UTL was not calculated because there was only one detected value.BTV = background threshold value (b) Data do not follow a discernible distribution.Det = detected (c) Data appear Normal at 5% Significance Level.DL = detection limit (d) Data appear Lognormal at 5% Significance Level.DU = decision unitFOD = frequency of detectionMax = maximummg/kg = milligram per kilogramMin = minimumNC = not calculatedng/kg = nanogram per kilogramQual = qualifierSU = sample unitSVOC = semi‐volatile organic chemicalUTL = upper tolerance level

PAGE 2 OF 2009573

TABLE 2 SUPPLEMENT BBackground Threshold Values for Surface Water and SedimentRisk Assessment Addendum, American Creosote Works, Winnfield, Louisiana

Chemical Units FODArithmetic Mean (1)

BTV (2)

(2x Mean)Surface Water

1,4‐Dichlorobenzene µg/L 0.34 L,J 0.34 L,J 1 / 2 0.295 0.5902‐Methylnaphthalene µg/L 0.12 0.12 1 / 2 0.0850 0.170

Benzo(a)pyrene µg/L 0.17 0.19 2 / 2 0.180 0.360Dibenz(a,h)anthracene µg/L 0.075 L,J 0.089 L,J 2 / 2 0.0820 0.164

Diethyl Phthalate µg/L 0.41 L,J 0.62 L,J 2 / 2 0.515 1.0300Indeno(1,2,3‐c,d)Pyrene µg/L 0.13 0.13 2 / 2 0.130 0.260

Naphthalene µg/L 0.16 0.81 2 / 2 0.485 0.97Total BAP TEQ µg/L 0.283 0.289 2 / 2 10.6 21.1

Acetone µg/L 16 16 1 / 2 9.25 18.5Benzene µg/L 0.5 0.5 1 / 2 0.375 0.750

Ethylbenzene µg/L 0.14 L,J 0.14 L,J 1 / 2 0.195 0.390m,p‐Xylene µg/L 0.2 L,J 0.2 L,J 1 / 2 0.225 0.45

tert‐Butyl Methyl Ether µg/L 0.47 L,J 0.47 L,J 1 / 2 0.360 0.720Toluene µg/L 0.46 L,J 0.46 L,J 1 / 2 0.355 0.71

Sediment1,2,3,4,6,7,8‐Heptachlorodibenzo‐p‐dioxin ng/kg 59.9 208 2 / 2 134 2681,2,3,4,7,8‐Hexachlorodibenzo‐p‐dioxin ng/kg 1.9 L,J 3.15 2 / 2 2.53 5.051,2,3,6,7,8‐Hexachlorodibenzo‐p‐dioxin ng/kg 1.93 L,J 6.71 2 / 2 4.32 8.641,2,3,7,8,9‐Hexachlorodibenzo‐p‐dioxin ng/kg 2.51 4.4 2 / 2 3.46 6.911,2,3,7,8‐Pentachlorodibenzo‐p‐dioxin ng/kg 0.813 L,J 1.18 L,J 2 / 2 0.997 1.992,3,7,8‐Tetrachlorodibenzo‐p‐dioxin ng/kg 0.121 L,J 0.347 L,J 2 / 2 0.234 0.468

Heptachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 137 400 2 / 2 269 537Hexachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 23.3 61.6 J 2 / 2 42.5 84.9

Octachlorodibenzo‐p‐Dioxin ng/kg 2980 6200 J 2 / 2 4590 9180Pentachlorinated Dibenzo‐p‐dioxins (Total) ng/kg 3.71 11.1 J 2 / 2 7.41 14.8

Total Dioxin TEQ ng/kg 4.87 7.09 2 / 2 5.39 10.8Tetrachlorinated Dibenzo‐p‐Dioxins (Total) ng/kg 1.14 6.47 2 / 2 3.81 7.611,2,3,4,6,7,8‐Heptachlorodibenzofuran ng/kg 5.07 23.2 2 / 2 14.1 28.31,2,3,4,7,8,9‐Heptachlorodibenzofuran ng/kg 2.49 2.49 1 / 2 1.83 3.661,2,3,4,7,8‐Hexachlorodibenzofuran ng/kg 1.45 L,J 1.45 L,J 1 / 2 1.31 2.621,2,3,6,7,8‐Hexachlorodibenzofuran ng/kg 1.1 L,J 1.1 L,J 1 / 2 1.14 2.271,2,3,7,8,9‐Hexachlorodibenzofuran ng/kg 0.239 L,J 0.783 L,J 2 / 2 0.511 1.022,3,4,6,7,8‐Hexachlorodibenzofuran ng/kg 1.87 L,J 1.87 L,J 1 / 2 1.52 3.042,3,4,7,8‐Pentachlorodibenzofuran ng/kg 0.977 L,J 0.977 L,J 1 / 2 1.07 2.152,3,7,8‐Tetrachlorodibenzofuran ng/kg 0.189 L,J 0.266 L,J 2 / 2 0.228 0.455

Heptachlorinated Dibenzofurans (Total) ng/kg 11.1 98.4 2 / 2 54.8 109.5Hexachlorinated Dibenzofurans (Total) ng/kg 6.16 34 J 2 / 2 20.1 40.2

Octachlorodibenzofuran ng/kg 6.29 100 2 / 2 53.1 106Pentachlorinated Dibenzofurans (Total) ng/kg 2.18 13.8 J 2 / 2 7.99 16.0Tetrachlorinated Dibenzofurans (Total) ng/kg 1.45 5.76 2 / 2 3.61 7.21

Acenaphthene mg/Kg 0.075 L,J 0.075 L,J 1 / 2 0.0850 0.170Anthracene mg/Kg 0.13 0.13 1 / 2 0.113 0.225Chrysene mg/Kg 0.12 0.12 1 / 2 0.108 0.215

Fluoranthene mg/Kg 0.58 0.58 1 / 2 0.338 0.675Fluorene mg/Kg 0.14 0.14 1 / 2 0.118 0.235

Phenanthrene mg/Kg 0.77 0.77 1 / 2 0.433 0.865Pyrene mg/Kg 0.37 0.37 1 / 2 0.233 0.465

Total BAP TEQ mg/Kg 0.0937 0.0937 1 / 2 0.438 0.876Notes:(1) Arithmetic mean was calculated using one‐half of the non‐detect results.(2) BTV selected as two times the arithmetic mean.

BTV = background threshold valueDet = detected J = compound was detected below the reporting limit in the sampleFOD = frequency of detection L = compound was detected above the Method Detection Limit (MDL) but below the Max = maximum                     Contract Required Quantitation Limit (CRQL)mg/kg = milligram per kilogramMin = minimumng/kg = nanogram per kilogramQual = qualifierµg/L= microgram per liter

Min DetConcentration/Qual

Max DetConcentration/Qual

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