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Please Note: This Certification page is from my personal copy of the project work, hence the reason why it was signed by only my project supervisor (Engr. Shedrach M.U.). Other copies were submitted to the department for signing and documentation and were not returned back to me.
ABSTRACT
Corrosion has been a problem experienced by sea vessels such as ships, dredgers pipelines and other structures, which have led to loss of billions of dollars globally, pollution and even loss of lives, thus necessitating on-going research on how to efficiently curtail its effects. Therefore, this project is basically to design and install a cathodic protection system on coated steel (as used for parts of a dredger). Sacrificial anode cathodic protection system was used as the protection applied to the steel and a single packaged zinc anode was installed alongside the steel. When the whole system was connected, the zinc being higher in the electrochemical series corroded preferentially in place of the steel since they are in the same conductive electrolyte (i.e. the environment). A wooden test post was installed alongside the steel pipe where all the cables from the steel and the anode were displayed and connected for CP monitoring. The CP system was monitored for days and it was observed that the potential readings obtained were within the standard -850mV to -1150mV. This proved that the submerged mild steel was ‘cathodically protected’ from corrosion. Thus cathodic protection method could be used to protect steel of structures or vessels hence prevent losses.
INTRODUCTION
The first practical use of cathodic protection is
generally credited to Sir Humphrey Davy in the
1820s. Davy’s advice was sought by the Royal
Navy in investigating the corrosion of copper
sheeting used for cladding hulls of naval vessels.
Davy found that he could preserve copper in sea
water by the attachment of small quantities of
iron or zinc; the copper became, as Davy put it,
“cathodically protected” (Francis, 2004).
Davy was assisted by his pupil Michael Faraday,
who continued his research after Davy’s death. In
1834, Faraday discovered the connection
between corrosion, weight loss and electric
current and thus laid foundation for future
application of cathodic protection method.
Heldtberg et al (2004), reported that a case study
of a ship James Matthews, 1841 was conducted
and that a laboratory simulation study of the
impact of pH and chloride content on the
corrosion of cast iron and mild steel was carried
out. It was found that there was a linear
relationship between the corrosion rate of cast
iron and the log of chloride ion concentration in
the pH range 7.8< pH >5.5 with only a small pH
effect noted for the given range of conditions.
Studies on a 19th century mild steel sample
indicated that the corrosion rate was linearly
dependent on the square root of the chloride ion
concentration and the corrosion rate fell in a
linear fashion as the pH was increased to strongly
alkaline solutions of sodium hydroxide. It has
been more than 30 years since the first CP system
was installed on a reinforced concrete bridge
deck in 1973 near Sly Park, California. Today, it is
estimated that over two million of concrete
structures are cathodically protected worldwide.
(Callon et al, 2004)
It has been established that electric current can
generate corrosion, corrosion, in turn can
generate electric current. As indicated by these
phenomena, it is then possible to prevent
corrosion by the use of electrical current. This,
there, is the basis for cathodic protection. When
direct current is applied with a polarity which
opposes the natural corrosion mechanisms, and
with sufficient magnitude to polarize all cathodic
areas up to the open circuit potential of the
anodic area, corrosion is arrested. (Bever, 1986)
The theoretical consideration indicate that the
basis for cathodic protection is relatively simple
not difficult to understand. However, practical
designs for various applications can vary
considerably based on the type of structure to be
protected and the conditions encountered.
It is also obvious that the rate of corrosion could
be reduced if every bit of the exposed metal could
be made to collect current. Direct current is
forced onto all the surface of the metal thereby
shifting the potential of the metal in the active
(negative) direction, when the amount of current
flowing is properly adjusted, it will overpower
the corrosion current discharging from the
anodic areas on the metallic structure and there
will be a net flow onto the surface at these points.
The entire surface then will be cathodic and the
corrosion rate will be reduced.
To begin with; what is Corrosion? Generally
corrosion is the deterioration of material, usually
metals due to its reaction its environment. It is a
natural process that occurs because metal dislike
remaining as metal, but prefers its equilibrium
state i.e. its Ore.
There are three essential elements necessary for
corrosion to occur:
Water
Contaminants in the water (e.g. salts)
Oxygen
Corrosion is primarily electrochemical in nature,
where the chemical reaction is accompanied by a
passage of electrical current due to difference in
electrical potential between different areas of the
substrate. Corrosion can either be atmospheric or
immersed corrosion. The corrosion process
involves:
(1) Removal of electrons – oxidation of the metal
(i.e. anodic reaction). Fe = 2Fe++ + 4e-
(2) Consumption of these electrons by some
other reduction reaction (i.e. cathodic reaction),
O2 + 2H2O + 4e- = 4OH- ; 2H2O + 4e- = H2 + 2OH-.
Both electrochemical reactions are necessary for
corrosion to occur.
True, corrosion has been a threat to investment
as it has caused loss of billions of dollars on a
global scale. This led to researches into methods
of combating or at least reducing the act and
effect of corrosion on metallic structures
submerged or buried.
TECHNICAL OBJECTIVES
This research aims to:
Analyze the necessary parameters in
designing cathodic protection system.
Analyze the possible advantages of
using a cathodic protection system in
Nigerian Waters.
Prove and establish the importance of
cathodic protection in pipelines, ship
hulls and other metallic parts of a
dredger.
WATER RESISTIVITY
In water, resistivity is one of the main factors
influencing corrosion. However, because oxygen
dissolves better in brackish water, steel will
usually corrode more rapidly in brackish water
than in normal seawater. Similarly, corrosion rate
in well-oxygenated water is normally higher than
in warmer water. This can be illustrated in the
“Evans diagram” for neutral oxygenated water.
Higher corrosion rate is also expected in
turbulent water where the diffusion of oxygen is
faster.
CORROSION PREVENTION
The principal methods for preventing or at least
reducing corrosion are:
Application of coating
The use of cathodic prevention method.
Alloying is also another viable method.
COATING OF METALS
Coatings normally are intended to form a
continuous film of an electrically insulating
material over the metallic surface to be
protected. The function of such a coating is to
isolate the metal from direct contact with the
surrounding electrolyte (preventing the
electrolyte from connecting the metal) and to
interpose such a high electrical resistance that
the electrochemical reaction cannot readily occur
(Peabody, 1967).
In reality, all coatings, regardless of overall
quality, contain holes formed during applications,
transportation, and installation or in service as a
result of degradation of the coating, stresses, or
movement of the ship (or Dredger). Coating
degradation in service also can lead to
disbonding from the metal surface, further
exposing metal to the environment. A high
corrosion rate at a holiday or within a disbanded
region can result in a leak, crack or rupture of
vessel, even when the coating effectively protects
a high percentage of the structure surface.
The primary function of coating on a cathodically
protected surface is to reduce the surface area of
exposed metal, thereby reducing the current
necessary to cathodically protect the metal. This
is accomplished by shifting the potential of the
metal in the negative direction by use of an
external power source (referred to as impressed
current cathodic protection) or by utilizing a
sacrificial anode. Thus, coating is often best used
in the presence of cathodic protection.
ALLOYING
Metals can be alloyed to change their corrosion
behavior. Stainless steel is a very good example;
here chromium is added to the steel to enhance
its corrosion resistance properties. This works
because chromium in the metal forms a
passivating layer similar to that of aluminum.
GALVANIC SYSTEM OF CATHODIC PROTECTION
When two metals having different energy level or
potential are coupled together, current will flow
from one metal to other. This is so because
nature has endowed each metallic substance with
a certain natural energy level or potential. The
direction of positive current flow will be from the
metal with more or most negative potential
through the electrolyte to that which is more
positive. Corrosion occurs at the point where
positive current leaves the metal surface,
(Bushman et al, 2005). A dry cell battery is a
typical example of a corrosion cell.
As mentioned by Peabody (2001), the corrosion
cell results from contact of dissimilar metals. In
such a cell, one metal is active with respect to the
other and corrode. With galvanic anodes, this
effect is taking advantage by purposely
establishing a dissimilar metal cell strong enough
to counteract corrosion cell.
The table below shows a galvanic energy series
for metals, where Magnesium has the highest
energy and Gold has the least energy.
Table 1: A Galvanic Energy Series Table for Metals Energy Level in Volts Vs Cu-Cus04 Electrode
How Galvanic Anode Works
When steel is electrically connected to a metal
higher in the electrochemical series and both are
Incr
easin
g En
ergy
Le
vel
Aluminum - 1.1Zinc - 1.1Steel - 0.6Steel in concrete with Ct - 0.5Steel in concrete without Ct - 0.1Copper - 0.1Carbon + 0.4Silver + 0.5Platinum + 0.9Gold + 1.2
bare in a common electrolyte such as the earth or
water, the more active metal is corroded and
discharges current in the process. Magnesium,
aluminum and zinc are such metals. If the amount
of current needed for a CP application is known,
anode system can be designed using sufficient
anode material to produce the desired current
output continuously over a desired number of
years. The corrosive nature of the underground
environment may cause self-corrosion of the
anode material. Electrical currents produced by
this corrosion do not result in producing CP
current.
Figure 3: Sacrificial Anode CP System in Seawater (Baxter and Britton, 2006)
Characteristics of Zinc Anodes
They are usually long slender shaped to achieve
low resistance and practical current output at the
usual low driving voltage between anode and
protected structure. Packaged magnesium and
zinc anodes (anode and backfill furnished as a
complete unit ready for installation) are standard
with most suppliers.
CATHODIC PROTECTION WITH IMPRESSED CURRENTTo be free of the limited driving voltage
associated with galvanic anodes, current from
some outside power source may be impressed on
the steel parts by using a ground bed and a
power source. The most common power source is
the rectifier. This is a device which converts
alternating current (A.C.) to electric power to low
voltage direct current (D.C.) power. (Fontana,
1987)
Fig 4: Principle of Cathodic Protection with Impressed Current (Baxter and Britton, 2006)
SELECTION OF THE TYPE OF CATHODIC
PROTECTION SYSTEM
According to Washington’s Department of the
Army Technical Manual (1985), before deciding
which type - galvanic or impressed current
cathodic protection system - will be used and
before the system is designed, certain
preliminary data must be gathered. They include:
Physical dimensions of structure to be protected,
drawing of structure to be protected, electrical
isolation, short circuits, electrolyte resistivity
survey, current requirement, coating resistance,
protective current required, the need for cathodic
protection and structure versus electrolyte
potential survey.
CRITERIA FOR CATHODIC PROTECTION
Various criteria have been developed over the
years that permit a determination of whether
adequate protection is achieved. Those criterions
in more common usage involve measuring the
potential between the pipeline and earth
(Peabody, 2001).
Basically potential criterion is used to evaluate
the changes in structure potential with respect to
the environment that are caused by cathodic
protection current flowing to the structure from
the surrounding soil or water.
The steel-to-water potential can be measured
measuring the voltage between the steel and a
reference electrode placed directly over the steel
surface. The most common electrode used for
this purpose is a copper-copper sulphate
reference electrode, (CSE). The potential is
referred to as “ON” potential if the measurement
is made with the cathodic protection system
energized. The “OFF” or “INSTANT OFF” potential
estimates the polarized potential when the
measurement is made within one second after
simultaneously interrupting the current output
from all cathodic protection current sources and
any other current sources affecting that portion
of the measured steel.
CASE STUDY: A study was done on JEPH
KEBBI INTERNATIONAL LIMITED. Jeph Kebbi
international limited is a private company
incorporated in Nigeria in 1983, they provide
design construction, installation, operation,
maintenance, dredging and marine services to
Nigerian energy, oil and gas industries. Jeph
Kebbi International is located along Chevron
Clinic road Opposite D.B.S off N.P.A Express way,
Delta, Warri. It was observed that the company
uses a cathodic protection system in addition to
coating on its dredgers steel parts (e.g. Abigail 2)
to protect it from corrosion. This article will
show why this method was chosen.
DESIGN PARAMETERS AND
METHODOLOGY
Cathodic protection systems are designed to
maintain the metallic structure (e.g. pipe) within
an electrochemical potential range (-850mV to
1150mV) that prevents surface corrosion at the
expense of a less noble metal (anode). The
system must be monitored weekly to ensure the
efficiency of the system.
MATERIALS: A single packed zinc anode, low-
carbon steel pipe (steel pipe chosen since steel
forms a major part of the dredger), Wooden test
post, 2.5mm PVC cable, Voltmeter, Bolts and nuts,
Drafting tape, Copper-copper sulphate electrode
(CSE), Grades 320 and 640 of Emery paper/cloth.
Coating material: A two-layer-cold-applied
polyethylene tape with trade name Polyken tape
was used on the pipe surface, in other to achieve
a homogenous pipe surface and to separate the
steel pipe from the environment. The first layer is
for corrosion prevention while the second is for
mechanical protection.
Steel pipe
TABLE 2: Pipe Characteristics
Type Low-carbon steel pipeLength 2.5metresDiameter 0.102meters (4 inches)Thickness 0.002mCoating material Polyethylene (Polyken
tape black & white)
A single packaged Zinc anode: The zinc anode
was completely packaged in a porous sack bag
with a coke breeze as the chemical backfill
surrounding the entire length.
Characteristics: Weight 17kg, length 102cm
(1.02m) and its diameter with the backfill being
10cm (0.1m). Zinc having an electrode potential
of -0.76 volts which is greater than iron
(0.44volts) will corrode preferentially and faster
than iron. Other anode systems that could be
used are magnesium anode and aluminum anode.
PVC cable: A 2.5mm PVC cable of thickness was
also used. The cable has a length of 30 yards and
was divided into three equal parts for the anode
and the pipe connections.
Test post: A treated wood with 4 x 4 inch
dimensions was used in the design of the test
post. After the fabrication, it was painted to
prevent it from degradation. The test post has a
box where the cables from the pipe and anode
were displayed and connected for taking of
readings and monitoring.
Bolt and Nut: Bolts and nuts of the same low
carbon steel material with the steel pipe were
also used for the attachment of cables to the pipe.
Voltmeter: A digital voltmeter was used for
taking or measuring potential differences in volts.
Copper-copper sulphate electrode (CSE): This is
an instrument that helps in the measurement of
the potential between the pipeline and earth (i.e.
pipe to soil or water potential).
DESIGN CALCULATION
Pipe data:
Length of pipe, L or h = 2.5metres
Diameter of pipe, D = 0.102metres
Radius of pipe, r = D/2 = 0.102/2 = 0.051metres
Thickness of the pipe, t = 0.002metres
Total surface area of cylindrical pipe (TSA)TSA = Area of the cylindrical pipe + Area of 2
circular surfaces present.
=2 .π .r .h + 2. π . r2 or 2 . π . r (h + r ) (3.1)
Thus TSA = 2 x 3.142 x 0.051 x (2.5 + 0.051)
= 0.78486m2
Cross-sectional area of pipe (A)
A = (R–t)π 2 (3.2)
A = 3.142 (0.051 – 0.002)2
A = 7.5439 X 10-3m2
Linear (Ohmic) resistance of pipe, Rs
Rs = (Ls x L)/A (3.3)
Ls = resistivity of steel pipe = 1.8 x 10-7 m)Ώ
L = length of pipe = 2.5metres
A = Cross sectional area = 7.5439 x 10-3 m2
Rs = (1.8 x 10-7 x 2.5) 7.5439 x 10-3 = 6.0 x 10-5 Ώ
Coating leakage resistance of pipe, Rc
Leakage resistance, Rc, refers to the total
resistance of the structure-electrolyte interface,
including the Ohmic resistance of any applied
surface coating(s).
Rc = Rp/πDL (3.4)
Rp = coating resistance = 15,000m2Ώ
Rc = 15,000/(3.142 x 0.051 x 2.5)
Rc = 37443.37 Ώ
Attenuation factor, α
Electrical losses in a conductor are caused by
current flow in the conductor. It is a factor that
influences general current distribution on the
surface of the steel pipe. Assuming 50%
attenuation, = (Rs/Rc)α 0.5 (3.5)
= {(6.0 x 10α -5)/37443.37}0.5 = 4.003 x 10-5
Pipeline characteristics resistance, RkRk = {Rs x Rc}0.5 (3.6)
Rk = (6.0 x 10-5 x 37443.37)0.5
Rk = 1.5Ώ
Surface area, SASA = πDL (3.7)
SA = 3.142 x 0.051 x 2.5 = 0.4006m2
Total current requirement, I
I = SA x Cd x f (3.8)
Cd = current density = 0.015A/m2 = 15mA/m2
f = Safety factor = 1.5
I = 0.4006 x 0.015 x 1.5
I = 0.009 or 9.0x10-3 Amperes
Resistivity of water: The seawater resistivity, ρ
(ohm·m), is a function of the seawater salinity
and temperature. In open sea, salinity does not
vary significantly and temperature is the main
factor. It is recommended that design of cathodic
protection systems in such locations is based on
resistivity measurements reflecting annual mean
value and the variation of resistivity with depth.
Resistivity, = ∑ /N or R/(L/A)ρ ρ (3.9)
Table 3: Resistivity of Some Typical WatersWater ( cm)ρ ΏPure water 20,000,000Distilled water 500,000Rain water 20,000Tap water 1000-5000River water (brackish) 200Sea water coastal 30Sea water open sea 20-25
The current output from an anodeFrom Roberge’s hand book on corrosion (2000),
the current from an anode can be estimated using
the Dwight’s equation:
i = (2 . π . E . L ) / [ ρ . In . (8 . LD − 1)](3.10)
Where, i = the current in Amperes (A)
E = design driving voltage of zinc anode = -0.25v
L = anode length in cm = 50cm
= water resistivity (ohm-cm) = 200 -cmρ Ώ
D = anode diameter in cm = 5cm
π = 22/7 = 3.142
Substituting the above values into equation;
I = (2 x 3.142 x 0.25 x 50) {200x ln [8 x(50/5)-1]} = 0.09amperes
Life Expectancy of an AnodeAccording to Bushman et al (2005), anode life can
be calculated using:
Anode Life = [Faraday Consumption Rate (Ampere Hours/Pound)/No. of Hours per Year] x Anode Weight (lbs) x Anode Efficiency x Utilization Factor/Anode Current in Amperes
The utilization factor is usually assumed to be
0.85. The equation may then be reduced to
simpler form by substituting the constant factors:
Life expectancy for magnesium, Lm = (48.5 W/I)
Life expectancy for zinc, Lz =(32.5W/I)
Where, W = Anode metal weight in pounds
I = Current output in milli-amperes
LM = magnesium anode life, years
LZ = zinc anode life, years
Inputting values into the re-written formula:
Life for zinc = (32.5 x 37.48)/(0.09 x1000)
(where 17kg = 37.48Ib) = 13.5 years
DESIGN PROCEDURESInstallation point survey: During this survey,
care was taken to ensure that no other metallic
structure(s) is around the location to avoid loss
of current to the structure(s) or issues of stray
current; also soil resistivity test was carried out.
Cable attachment: Two points were marked for
cable attachment (each 150millimeters apart
from centre of the low carbon steel pipe). Two
bolts and nuts were attached to each of the points
by manual arc welding. After welding operation,
the welded joint was freed of welding electrode
slag and visually inspected for weld integrity.
Pipe coating: The coating material used is a field-
applied coating called Polyken tape. This is a
cold-applied two layer coating system, though a
primer may sometimes be needed. The adhesive
wrap is softer and bonds intimately with the pipe
surface; this ensures proper corrosion
prevention and the polyethylene wrap used
provides great resistance to mechanical stresses
due to handling, backfill, etc.
Preheat: Temperature of pipe surface was
increased to about 50C above normal room
temperature by exposure to midday sunshine.
Inspection: Visual inspection was carried out on
the coated pipe to ensure:
A near perfect bonding/adhesion between
the pipe and the coating
No cracks or holes in the coating
No kinks, gaps or voids noticed.
Test post design and installation: This is the
cathodic protection monitoring point. The test
post is a wooden box where all readings
associated with the cathodic protection is taken.
Design from a treated of wood with 4x4 inch
dimensions, the test post has a box where cables
from the pipe and anode were displayed and
connected for readings. It also has a long bar of
wood which is treated to avoid degradation, then
it was buried close to the installation.
Complete system Installation: After all the
above mentioned processes were completed,
then the complete system was installed. The
complete system comprises of the coated pipe
with the protruding cables attached to it, the
single packaged anode with its own cable and the
test post with points for cable display.
The system was set up where the two cables from
the coated pipe were displayed in the box of the
test post as P1 and P2 respectively. The cable
from the anode was also displayed as A in the
same box. Then another cable of the same
material was used to loop one of the pipes (P1) to
the anode A, thereby setting up a complete
electrical system. The potential was taken
immediately after looping using resistivity meter.
Cathodic Protection (CP) MONITORING
The potential reading was taken using a
resistivity meter. The pipe length was divided
into five points (1 – 5). The potentials at these
different points were then taken from the test
post and recorded using the resistivity meter by
placing the meter on the different points, each
showing its own specific reading. One terminal
was connected to the cable of the meter while the
other was then placed on the connection to
obtain the readings. The cathodic protection
system was monitored for days after installation.
RESULTS AND DISCUSSION
Resistivity Results: The results were computed
using the Microsoft Excel Program to give the
table below:
TABLE 4: Resistivity Readings
S/n
Spacing a(cm) Resistivityρ = 2π aR (ohm−cm)
1 110 199.502 120 200.483 130 201.624 140 199.355 150 201.03
Total 1001.98
Average resistivity, = /Nρ Σ ρ
Where, N = 5
= Total resistivity readings = 1001.98 ohm-Σ ρ
cm
= 1001.98/5 = 200.396 ohm-cmΡ
The resistivity value used for current output from
the anode = 200.396 ohm-cm.
TABLE 5: Corrosivity Ratings
Resistivity ( cm)Ώ Corrosivity rating 0 – 2000 Severe
2000 - 10,000 Moderately Corrosive10,000 – 30,000 Mildly CorrosiveAbove 30,000 Not likelySource: Donald J.D, (1985).
The resistivity values obtained falls within the 0 -
2000 cm range. Therefore, the environmentΏ
that the pipe was submerged is highly corrosive.
As observed, with the resistivity it can distribute
current freely and generally around the pipe.
Measured Voltage & Current of Anode
The measured voltage value = -0.24Volts. This is
the driving voltage of anode obtained after
system installation. The measured current can be
calculated from the measured voltage using the
Dwight’s equation.
i = (2. π . E . L ) / [ρ . In . (8 . LD − 1)]Where, i = the current in Amperes (A),
E = the measured driving voltage = -0.24v,
L = anode length in cm = 50cm,
= soil resistivity (ohm-cm) = 200.396 -cmρ Ώ
D = anode diameter in cm = 5cm,
π = 22/7 = 3.142
Substituting the above values into equation;
I = (2 x3.142 x 0.24 x 50) {200.396 x ln[( 8 x 50/5)- 1]} = 0.0861amperes
The design voltage of the anode was 0.25Volts̶
while the design anode current output was 0.09A
while the measured voltage of the anode after
installation was 0.24Volts while measured anode
current output was 0.0861Amperes. From the
above, it is obvious that there was a small
reduction in both the measured voltage and
current values. If the design and measured values
are analyzed using statistical measures (F – test),
there will be no significant changes in the values.
Therefore, it can be deduced that the installation
was in good working condition. However, these
reductions could be as a result of the measuring
instruments and method of measuring.
The voltage value was obtained using the
resistivity meter. In the course of measuring, an
error may have occurred leading to loss due to
error in the measuring instrument.
Resistivity Variations in the Electrolyte Between the Anode and CathodeFrom the pipe-to-water potential readings
obtained, it is observed that the readings are
highest in the middle of the pipe section; this is
due to anode positioning. Areas of low resistivity
attracted a higher current density, with current
flowing preferentially along the path of least
resistance. After installation, the potential
reading was poor; this was partly because the
PVC coated copper cable was damaged. To
correct this current loss to the environment, the
cable was replaced.
Pipe Length and Number of Anode
The pipe length used was 2.5 metres and number
of anode is one (1). It was a single packaged zinc
anode with the following dimensions;
weight17kg, length 50cm and its diameter with
the backfill being 5cm. The pipe length used was
small. From the design calculations therefore, a
single anode of standard dimensions was enough
to protect the buried pipe length. Additional
anodes can be used to achieve a homogenous
ionic current flow in cases of long pipes.
LIFE OF THE ANODEThe calculated life of anode was 13.5yrs using a
utilization factor of 85%.
Then 85% of 13.5 = 11.5years. This means that
before the 12th year of the anode life, the anode
must be changed because it cannot effectively
protect the steel after the 11.5th year.
Pipe PotentialThe pipe potential reading was taken and
recorded as:
TABLE 6: Pipe Potential Reading
Distances along the pipe length at different points (metres)
Potential readings at each of the five points (milliVolts)Day 1
Day 2
Day 3
Day 4
0.000 -794 -834 -856 -8600.600 -838 -868 -868 -9101.100 -860 -886 -886 -9361.650 -870 -892 -880 -9422.200 -880 -890 -890 -940
Apart from the first two points on the pipe length,
the other points have values within the stipulated
-850mV to 1150mV for the first week; this means
that the pipe was well coated and that the
Polyken tape coating was working efficiently.
After some days more reading were taken and
there was an improvement in the values
observed. The point zero which had -794mV
value in the first day increased to -838mV. Also
along the pipe length there was an obvious
improvement in the potential readings, this
means that polarization of the entire system has
taken place and the zinc anode cathodic
protection system was protecting the submerged
pipe fully.
From the above measurements, it was observed
that the steel pipe readings met the standard -
850 to -1150mV. From the above observation, it
can be deduced that the submerged low-carbon
steel pipe was “fail safe”.
CONCLUSION
As can be seen from the chapters discussed, to
design an effective corrosion control system for
buried/submerged metallic structure, it is
important to have a good understanding of the
soil and water conditions (acidity/salinity,
resistivity, etc.) that the structure will be
subjected to, then the best design and installation
of the of corrosion control measures suitable for
those conditions can be achieved.
The corrosion protection provided by the
polyethylene tape coating on the steel pipe was
complemented by the zinc anode galvanic
cathodic protection system ensuring greater and
effective protection of steel parts. The zinc anode
used was able to protect the submerged low-
carbon steel pipe despite the low driving voltage
of zinc anode. Thus the low carbon steel pipe
coated with polyethylene tape was “fail safe”
indicating that cathodic protection system for
corrosion prevention is a necessary use for
structures experiencing corrosion.
RECOMMENDATIONSFrom the observations made during the project
work, the following are the recommendations;
That the zinc-anode type should be used
for soil low resistivity (less than 2000
Ohm-cm) because of zinc anode’s low
driving voltage.
That the best coating system with its
application method must be selected in
order to achieve maximum protection of
the buried and submerged metallic
structure.
That the coated pipe and the galvanic
anode must be carefully installed to avoid
any form of damage on any of the system.
Constant monitoring of the system should
be done to take weekly readings of the
potential to ensure that the recommended
standard (850mV to -1150mV) is always
achieved.
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