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Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for...

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George Higgins Hutchinson — Lei Wang Simone Šuran Brunelli Jonathan Klamkin, PhD. Slides source: gitlab.com/geohh/aim August 12, 2018 Development and Startup of a Micro- Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters
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Page 1: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

George Higgins Hutchinson — Lei WangSimone Šuran Brunelli — Jonathan Klamkin, PhD.

Slides source: gitlab.com/geohh/aim

August 12, 2018

Development and Startup of a Micro-Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth

Parameters

Page 2: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Wat lies beneath?

2/15

Page 3: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Photonic Integrated Circuits (PIC): Improved LiDAR, etc.PIC:▶ Small▶ Low cost▶ No moving parts

Discrete Optics/Electronics:▶ Large▶ Expensive▶ Multiple moving parts

Image credit: NASA/W. Hrybyk, https://www.nasa.gov/feature/goddard/2016/

nasa-engineers-tapped-to- bui ld-first-integrated-photonics-modem 3/15

Page 4: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Metal Organic Chemical Vapor Deposition (MOCVD):Motivation and Theory

Figure: MOCVD process, building up anInP crystal from Indium and Phosphideprecursors as organic byproducts escape

▶ PIC require lasers,waveguides, detectors

▶ Silicon unsuitable forlasers

▶ MOCVD to buildIII-V crystals forlasers

4/15

Page 5: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Characterization Techniques for Semiconductor Materials

MOCVD requires calibration to grow crystals of precisecomposition.How do we measure out growths to improve future runs?

Separationbetween atoms in

crystal

X-RayCrystalography

Morphology,topography,

parasitic growths

Atomic ForceMicroscopy

Band gap energy(of direct band

gap crystal)

PhotoluminescenceSpectroscopy

5/15

Page 6: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Photoluminescence Spectroscopy — Theory

Laser Sample

Monochromator Photodiode array

λ p

many wavelengths

λ l ± δ

1. Laser excites sample electrons2. Sample emits light3. Monochromator removes unnecessary wavelengths4. Photodiode array counts photons at specific wavelengths

6/15

Page 7: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Photoluminescence Spectroscopy — Motivation

Figure: 1.5µm InGaAsP laserschematic, adapted from Q. Ke etal.

▶ My research goal: configurea PL setup

▶ Observing band gap helpsinterpolate actual crystalcomposition

7/15

Page 8: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

My Experimental

Laser

Sample

Monochromator

Photodiode Array

8/15

Page 9: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

PL Setup: Software Development Problems and Techniques

Lack ofequipment

documentationNeed for future

modifibility

Reverse-engineering driversand example code

Object-orientedabstract device

structure

Need forlong-termstability

Dependencymanagement

tools

9/15

Page 10: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

“Good” and “Bad” Quantum Dots under PL

“Good” dots:Tight size distribution, PL

“Bad” dots:Wide size distribution, PL.

10/15

Page 11: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Complex structures: multiple PL peaks

Substrate

Waveguide

CladdingQuantum Wells

Cladding

1180nm peak: Waveguide? 1300nm peak: Laser?

11/15

Page 12: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Structures respond differently to pump intensity changes

12/15

Page 13: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Conclusions — A Work in Progress

Hardware:▶ Photodetector: “It’s dead,

Jim.”▶ Identified potential

replacements▶ Contacted suppliers for

quotes

▶ Defective lasers troubleshot& replaced

Software:▶ Developed experimental

software for available parts▶ Software development

techniques to maximizehardware modularity

13/15

Page 14: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Future Work

▶ Short Term: Replace Photodetector▶ Develop software for data acquisition/analysis

▶ Long Term: Add mapping functionality▶ Motorized stage control▶ Adapt data acquisition/analysis software for mapping

14/15

Page 15: Development and Startup of a Micro- Photoluminescence ......Photoluminescence Setup for Semiconductor Characterization and Optimization of Growth Parameters. ... Conclusions — A

Acknowledgments

15/15

Bowers group, for providing the PL setup used in ̀ `Identifying Structures based on PL Peaks'' data collection.

This material is based on research sponsored by Air Force Research Laboratory under agreement number FA8650-15-2-5220. The U.S. Government is authorized to reproduce and distribute reprints for Governmental purposes notwithstanding any copyright notation thereon .

The views and conclusions contained herein are those of the authors and should not be interpreted as necessarily representing the official policies or endorsements, either expressed or implied, of Air Force Research Laboratory or the U.S. Government.


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