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Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center Cleveland,OH T.P. Jenkins Metrolaser, Inc. Irvine, CA S.W. Allison Oak Ridge National Laboratory Oak Ridge, TN D. E. Wolfe Penn State University University Park, PA E. H. Jordan University of Connecticut Storrs, CT 58 h International Instrumentation Symposium San Diego, CA June 5-8, 2012 . . . , ... '. . . . . -' https://ntrs.nasa.gov/search.jsp?R=20120016798 2018-08-30T08:33:01+00:00Z
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Page 1: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications

J.I. Eldridge NASA Glenn Research Center

Cleveland,OH

T.P. Jenkins Metrolaser, Inc.

Irvine, CA

S.W. Allison Oak Ridge National Laboratory

Oak Ridge, TN

D. E. Wolfe Penn State University University Park, PA

E. H. Jordan University of Connecticut

Storrs, CT

58h International Instrumentation Symposium San Diego, CA June 5-8, 2012

N~.··· . . . , ... ~ '. . . . . -' ~.

https://ntrs.nasa.gov/search.jsp?R=20120016798 2018-08-30T08:33:01+00:00Z

Page 2: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

AFRL Versatile Affordable Advanced Turbine Engines (VAATE) Project Gas Turbine Engine Sensor and Instrumentation Development

Project 1: TBC Health & Component Temperatures of Turbine Blades & Vanes

NASA GRC High-Heat­Flux Laser Facility -Proof-of-concept with easy optical access, no radiative background, no probe heating issues.

Demonstrated to 1360°C . ./

Williams International Combustor Burner Rig -Address probe/TP survivability & ability to "see" through flame.

Demonstrated to >1400°C . ./

-Probe/translate through afterburner flame. -Opportunity to test excitation/collection integrated probe.

Goal: Demonstrate thermographic phosphor (TP) based temperature measurements to 1300°C on TP/TBC-coated HPT stator on Honeywell TECH7000 demonstrator engine.

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Deca

y Ti

me

(µs)

Inte

nsity

(V)Basis for Selection of YAG:Dy

• Advantages of YAG:Dy (at least in powder form produced at high temperature) 1. Excellent temperature sensitivity from 1100° to 1700°C.

2. Higher upper temperature limit than other thermographic phosphors.

3. Short-wavelength emission at 456 nm reduces interference from background thermal radiation.

4. Nearly single exponential decay for simple, robust decay time determination.

Oe~~}' Time VS. Tern erature Calibration for YAG:Oy

100 +---------+--~---I

10 1--------~-~--1

o 200 400 600 800 1000 1200 1400 1600 1800

Temperature (0C)

Lu 11;1} n, e;....:s....;;.c....:...e _nc..:....e,-O_ e..:....c.:....;;a-",---C,-u,-rv_ e..:....s,-f;....:o_r_y'_'A....;;.G-,: Oy

Nearly monoexponential

- 15C

- 393C

- 590C

- 787C

0.01 ~_----------I

0.001 +----~~~~~----I

0.0001 +--------,-------,-------,----=:11.0.~

0.001 0.002 0.003 0.004

Time {sed

Decay Time vs. Temperature 10,000

1,000

100 -(/') :l. ----

10

1

0.1

0.01

° 400 800 1 ,200 1,600 2,000 Temperature (Kelvin)

But, will YAG:Dy coatings exhibit these desirable attributes because temperatures of coating processing restricted to much lower temperatures «1200°C) than powder processing?

Page 4: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

Coating Deposition Methods Investigated

• Binder-Based Paint Application 1. Mixture of YAG:Dy powder and ZAP binder (ZYP Coatings, Oak Ridge, TN)

2. Air-brush or paint brush application.

3. Fire to produce coating consisiting of YAG:Dy powder particles in AIP04 matrix.

- Simple, fast, & inexpensive.

- Incorporates fully crystallized phosphor powder.

• Electron-Beam Physical Vapor Deposition (EB-PVD) - E-beam evaporation of YAG:Dy ingot at Penn State.

- Most compatible for in-line industrial thermal barrier coating (TBC) deposition.

- Excellent thickness control.

- Desirable microstructure.

• Solution Precursor Plasma-Spray (SPPS) - Injection of atomized solution into plasma jet.

- Low-cost alternative to EB-PVD and conventional plasma-spray.

- Easily tailorable composition.

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Page 6: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

ZAP YAG:Dy on Plasma-Sprayed YSZ

or

+

3hr @1000°C

Coating consists of YAG:Dy powder particles in aluminum phosphate matrix.

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Inte

nsity

Page 13: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center
Page 14: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center
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Multi-Ingot EB-PVD Chamber at Penn State

HV De! WD Mdg - ::'00f.Jm-::'00 kV S:-;D q q mm ",000)

® Guns • Thermocouple Ingots (Trans-Tech):

G-v • Airfoil -Undoped 7YSZ Crucibles + Ingots • Ion Source -YAG:Dy

~~ Oxygen Supply Path • Graphite heating plate

Page 17: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center
Page 18: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center
Page 19: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

Inte

nsit

y

Effect of Heat Treatment on EB-PVD YAG:Dy

450

amorphous

YAP:Dy YAG:Dy

Time-Averaged Luminescence Emission Excitation at 355 nm

- no heat

- 24hr@1163C

- 2hr laser Ts = 1300C

-YAG:Dy slurry coating

• x XRD after 2hr I ser

10 20 30 40

28

470 490 510

Wavelength nm

so

Amorphous ~ YAP + a-A120 3 + 8-A120 3 ~ YAP + a-A120 3 (no YAG)

VAG is difficult to achieve due to non-congruent evaporation from ingot.

60

• YAP )( a-A1203

• t-YSZ

70 80

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Inte

nsity

(V)

Inte

nsity

(V)

Page 21: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center
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Inte

nsit

y

Effect of Heat Treatment on SPPS YAG:Dy

450

Time-Averaged Luminescence Emission 4F9/2 ~ 6H 15/2 Excitation at 355 nm

10

500 550 600

Wavelength nm

- no heat treat

-YAG:Dy slurry

XRD spps· 0 heat treat • YAG + YAP

• DYAM • t-YSZ

20 30 40 so 60

28

650 700

SPPS YAG:Dy coating exhibits desired YAG:Dy emission spectrum.

70 80

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Inte

nsit

yIn

tens

ity

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Inte

nsity

(V)

Inte

nsity

(V)

Inte

nsity

(V)

Inte

nsity

(V)

Page 29: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

- 50ns, 1 Ous wide

- 1ms, 100us wide

470 475 480 485 490 495 500

Wavelength nm

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Inte

nsity

(V)

Inte

nsity

(V)

Page 31: Development of YAG:Dy Thermographic Phosphor … · Development of YAG:Dy Thermographic Phosphor Coatings for Turbine Engine Applications J.I. Eldridge NASA Glenn Research Center

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