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EN EN EN
EN EN
EN
1
COMMISSION OF THE EUROPEAN COMMUNITIES
Brussels, 25.10.2006 SEC(2006) 1416
PART II
COMMISSION STAFF WORKING DOCUMENT
Monitoring of Pesticide Residues
in Products of Plant Origin
in the European Union, Norway, Iceland and Liechtenstein
2004
ANNEX 1
2
TABLE OF CONTENTS
Table A: List of all detectable substances ............................................................................... 3
Table B: Overall results of the national monitoring programmes........................................... 8
Table C: Fresh (incl. frozen) fruit and vegetables, surveillance sampling: results of the national monitoring programmes ............................................................................. 9
Table D: Cereals, surveillance sampling: results of the national monitoring programmes... 10
Table E: Fresh (incl. frozen) fruit and vegetables, enforcement sampling: results of the national monitoring programmes ........................................................................... 11
Table F: Processed products, surveillance sampling: results of the national monitoring programmes ............................................................................................................ 12
Table G: Samples with residues of more than one pesticide in fresh (incl. frozen) fruit, vegetables and cereals, surveillance and enforcement sampling ........................... 13
Table H: Pesticides found most often in the national (incl. co-ordinated) monitoring programmes in the European Union, Norway, Iceland and Liechtenstein for a) fruit and vegetables and b) cereals, as reported ............................................................. 14
Table I: Numbers of samples taken by participating States for each commodity in the EU co-ordinated programme ........................................................................................ 17
Table K: Residues of pesticides in the eight commodities as analysed in the EU Member States and EEA States ............................................................................................ 18
Table L: Results from the EU co-ordinated monitoring programme for pesticide residues for each pesticide analysed for in apples, tomatoes, lettuce, strawberries, leek, orange juice, head cabbage and rye/oats. ........................................................................... 19
Table M: Presentation of the most important pesticide-commodity combinations where residues were found (in alphabetical order) ........................................................... 22
Table N: Results of the homogeneity exercise ...................................................................... 25
Table O: Number and origin of the samples taken by country (sum of surveillance and follow-up enforcement samples, sum of fresh (incl. frozen) fruit, vegetables, cereals and processed products............................................................................... 28
Table P: Accreditation, participation in proficiency tests and implementation of the EU Quality Control Procedures of the pesticide residue laboratories .......................... 29
3
Table A: List of all detectable substances The table lists all substances analysed for, and specifies, where they were detected in one to four samples (1-4), or in five or more samples (>4). Substances are listed according to their residue definition in the EC-Directives or, for those not covered by EC-Directives, in the national legislation, e.g. "endosulfan" refers to "α-endosulfan", "β-endosulfan" and "endosulfan-sulphate”. 1-naphthylacetic acid 1-4 2,3,5-trimethacarb 2,3,6-TBA 1-4 2,4,5-T 1-4 2,4-D >4 2,4-DB 2,6-dichlorobenzamide 2-chlorethanol 1-4 2-chlorethanol, total 1-4 3,4,5-trimethacarb 3-ketocarbofuran 4,4-dibrombenzophenon 4,4-dichlorbenzophenon 1-4 4-CPA >4 abamectin, sum >4 acephate >4 acetamiprid >4 aclonifen >4 acrinathrin >4 alachlor 1-4 aldicarb, sum >4 aldrin >4 allethrin allidochlor alpha-cypermethrin >4 alphamethrin 1-4 ametryn 1-4 amidithion amidosulfuron aminocarb aminotriazol amitraz, total >4 anilazine antraquinone 1-4 aspon asulam atraton atrazine 1-4 azaconazole 1-4 azamethiphos azinphos-ethyl 1-4
azinphos-methyl >4 aziprotryne azocyclotin azolamide azoxystrobin >4 barban beflubutamid benalaxyl >4 benazolin bendiocarb, sum 1-4 benfluralin benfuracarb benodanil bensulfuron-methyl bentazone benthiavalicarb benzoximate benzoylprop-ethyl benzthiazuron beta-cyfluthrin bifenazate bifenox 1-4 bifenthrin >4 binapacryl 1-4 bioallethrin biphenyl >4 bitertanol >4 brofenprox bromacil 1-4 bromfenvinphos bromfenvinphos-methyl bromide, total >4 bromocyclen bromofenoxim bromophos bromophos-ethyl bromopropylate >4 bromoxynil 1-4 bromoxynil-heptanoat bromoxynil-methyl-ether brompyrazon
bromuconazole 1-4 bufencarb bupirimate >4 buprofenzin >4 butocarboxim sulfon butocarboxim, sum butoxycarboxim butralin buturon butylate cadusafos captafol captan >4 captan/folpet, sum >4 carbanolate carbaryl >4 carbendazim, sum >4 carbetamide carbofuran, sum >4 carbon tetrachloride carbophenothion carbosulfan 1-4 carboxin carfentrazon-ethyl cartap (hydrochoride) cekafix chinomethionat 1-4 chloanil chlorbenside chlorbenside sulfon chlorbenzilate 1-4 chlorbromuron 1-4 chlorbufam chlordane, sum (a-/g-) >4 chlordane, sum(a-/g-/oxy-) chlordecone chlordene, alpha- chlordene, gamma- chlordimeform chlordimeform hydrochloride
4
chlorfenapyr >4 chlorfenethol chlorfenprop-methyl chlorfenson >4 chlorfenvinphos >4 chlorfluazuron 1-4 chlorflurenol chlorflurenol, total chloridazon 1-4 chlormephos 1-4 chlormequat >4 chloroaniline(3-) 1-4 chloroneb chlorothalonil >4 chloroxuron 1-4 chlorpropham >4 chlorpropylate chlorpyrifos >4 chlorpyrifos-methyl >4 chlorsulfuron chlorthal chlorthal-dimethyl >4 chlorthiamid chlorthion chlorthiophos chlortoluron chlozolinate >4 cinidon-ethyl cinosulfuron cis-nonachlor cis-permethrin clodinafop-propagyl cloethocarb clofentezine >4 clomazone clopyralid 1-4 cloquintocet-methyl cloquintocet-mexyl clothianidin >4 copper compounds >4 coumaphos crimidine crotoxyfos crufomate 1-4 cyanazine 1-4 cyanidric acid cyanofenphos cyanophos cyazofamid cycloate cycloxydim cycluron
cyflufenamid cyfluthrin, sum >4 cyhalofop-butyl 1-4 cyhalothrin >4 cyhexatin, sum 1-4 cymoxanil >4 cypermethrin, total >4 cyproconazole >4 cyprodinil >4 cyprofuram cyromazine >4 cythioate daled daminozide, sum DDMU DDT, sum >4 DEF 6 deltamethrin >4 demeton-O demeton-S-methyl demeton-S-methyl-sulfone 1-4 desethylatrazin desisopropylatrazin desmedipham desmetryn diafenthiuron 1-4 dialifos 1-4 di-allate diazinon >4 dicamba dichlofluanid >4 dichlone dichlorbenil dichlorfenthion dichlorprop >4 dichlorvos >4 diclobutrazol diclofop-methyl dicloran >4 dicofol >4 dicrotophos >4 dieldrin, sum >4 diethatyl-ethyl diethofencarb >4 difenoconazole >4 difenoxuron diflubenzuron >4 diflufenican 1-4 dimefox dimefuron dimethachlor dimethenamid
dimethipin dimethirimol dimethoate, sum >4 dimethomorph >4 dimoxystrobin diniconazole >4 dinitramine dinobuton dinocap 1-4 dinoseb, sum dinoterb dioxabenzofos dioxacarb dioxathion 1-4 diphenamid diphenylamine >4 dipropetryn dipropylisocinchomeronat diquat >4 disulfoton, sum 1-4 ditalimfos 1-4 dithianon >4 dithofencarb >4 diuron >4 DMSA 1-4 DMST >4 DNOC dodemorph 1-4 dodine >4 edifenphos endosulfan, sum >4 endosulfanalkohol 1-4 endrin, sum 1-4 endrin-aldehyd EPN >4 epoxiconacole >4 EPTC esaconazole esfenvalerate >4 etacelasil etaconazole ethalfluralin 1-4 ethephon >4 ethidimuron ethiofencarb, sum 1-4 ethion >4 ethirimol 1-4 ethoate-methyl ethofumesate 1-4 ethoprophos 1-4 ethoxyquin >4 ethylene oxide 1-4
5
etofenprox >4 etoxazole etridiazole 1-4 etrimfos 1-4 famophos famoxadone >4 fenamidone 1-4 fenamiphos, sum 1-4 fenarimol >4 fenazaflor fenazaquin >4 fenbuconazole >4 fenbutatin oxide >4 fenchlorazole fenchlorim fenchlorphos, sum 1-4 fenfuram fenhexamid >4 fenitrothion >4 fenobucarb 1-4 fenoprop 1-4 fenoprop (silvex) fenothiocarb fenoxaprop fenoxaprop-p fenoxycarb >4 fenpiclonil fenpropathrin >4 fenpropidin 1-4 fenpropimorph >4 fenpyroximate >4 fenson 1-4 fensulfothion >4 fenthion, sum >4 fentin fenuron fenvalerate, total >4 fenvalerate/esfenvalerate RR&SS >4 fenvalerate/esfenvalerate RS&SR >4 fipronil >4 flampropisopropyl flamprop-methyl flazasulfuron florasulam fluazifop after hydrolysis fluazifop, total >4 fluazifop-p-butyl fluazinam >4 fluazolate flubenzimine
fluchloralin flucycloxuron flucythrinate 1-4 fludioxonil >4 flufenacet fluthiamid flufenoxuron >4 flumetralin flumioxazin fluometuron fluorochloridone fluorodifen fluoroglycofen-ethyl fluotrimazole fluquinconazole >4 flurecol-butyl flurenol flurochloridone fluroxypyr flurprimidol flurtamone flusilazole >4 flusulfamide flutolanil 1-4 flutriafol fluvalinate >4 folpet >4 fonofos 1-4 formothion fosthiazate fuberidazole 1-4 furalaxyl furathiocarb furmecyclox genite glyphosate halacrinate halofenozide haloxyfop >4 haloxyfop methyl ester haloxyfop-etotyl haloxyfop-R, total HCH, sum (a-/b) HCH, sum (a-/b-/d-/e-) >4 heptachlor, sum >4 heptachloroepoxide heptenophos 1-4 hexachlorobenzene >4 hexaconazole >4 hexaflumuron 1-4 hexazinone hexythiazox >4 hydrocyanic acid >4
hydrogen phosphide >4 hymexazol imazalil >4 imazapyr imazaquin 1-4 imazethapyr imidacloprid >4 indoxacarb >4 iodofenphos ioxynil 1-4 iprobenfos iprodione >4 iprovalicarb >4 isazofos isobenzan isocarbamid isodrin isofenphos, sum isomethiozin isoprocarb 1-4 isopropalin isoprothiolane isoproturon >4 isouron isoxaben isoxaflutole isoxathion 1-4 jodfenphos kelevan kresoxim-methyl >4 lambda-cyhalothrin >4 landrin lenacil leptophos lindane >4 linuron >4 lufenuron >4 malathion/malaoxon, sum >4 maneb group (as CS2) >4 MCPA >4 MCPB mecarbam >4 mecoprop 1-4 mefenpyr-diethyl mepanipyrim >4 mephosfolan mepiquat >4 mepronil >4 merphos metalaxyl >4 metalaxyl-M >4 metaldehyde
6
metam (-sodium) metamitron 1-4 metazachlor 1-4 metconazole 1-4 methabenzthiazuron methacrifos 1-4 methamidophos >4 methazole methfuroxam methidathion >4 methiocarb, sum >4 methomyl, sum >4 methoprene methoprotryne methoxychlor 1-4 methoxyfenozide >4 methyl isothiocyanate, sum methyl-pentachlorophenylsulfide metobromuron 1-4 metolachlor 1-4 metolcarb metosulam metoxuron metribuzin 1-4 metsulfuron-methyl mevinphos 1-4 milbemectin mirex molinate monalide monocrotophos >4 monolinuron monuron myclobutanil >4 naled naphthylacetic acid >4 napropamide 1-4 neburon nicobifen boscalid >4 nicosulfuron nicotine nitenpyram nitralin nitrapyrin 1-4 nitrofen 1-4 nitrotal-isopropyl nitrothal 1-4 norflurazon, sum novaluron nuarimol >4
o,p-dichlorbenzophenon ofurace orbencarb orthophenylphenol >4 oxadiazon 1-4 oxadixyl >4 oxamyl >4 oxasulfuron oxycarboxine 1-4 oxychlordane oxydemeton-methyl, sum >4 oxydisulfoton oxyfluorfen p,p'-dichlorbenzophenone >4 paclobutrazol paraoxon parathion >4 parathion-methyl/ paraoxon-methyl >4 parlar 26 parlar 50 parlar 62 penconazole >4 pencycuron >4 pendimethalin >4 pentachloraniline 1-4 pentachloranisole pentachlorophenol 1-4 pentachlorothioanisol permethrin >4 perthane phenkapton phenmedipham 1-4 phenothiazine phenothrin phenthoate 1-4 phorate, sum >4 phosalone >4 phosmet >4 phosmetoxon phosphamidon >4 phoxim picolinafen 1-4 picoxystrobin piperonyl butoxide >4 pirimicarb, sum >4 pirimiphos-ethyl >4 pirimiphos-methyl >4 plifenate polychlorinated terpenes, sum polychorinated terpenes
potasan pretilachlor primisulfuron prochloraz >4 prochloraz, total 1-4 procymidone >4 profenofos 1-4 profluralin profoxydim clefoxydim prohexadione-calcium 1-4 promecarb 1-4 prometon prometryn 1-4 propachlor 1-4 propafos propamocarb >4 propanil >4 propaquizafop propargite >4 propazine propetamphos propham 1-4 propham, sum propiconazole >4 propineb propoxur >4 propyzamide >4 prosulfocarb 1-4 prosulfuron prothiofos >4 prothoate pymetrozine >4 pyracarbolide pyraclofos pyraclostrobin 1-4 pyraflufen pyrazophos >4 pyrazoxyfen pyrethrins 1-4 pyridaben >4 pyridafenthion >4 pyridate 1-4 pyrifenox >4 pyrimethanil >4 pyriproxyfen >4 pyroquilon quinalphos >4 quinmerac quinoclamine quinoxyfen >4 quintozene >4 quizalofop
7
quizalofop-ethyl rabenzazole resmethrin rimsulfuron rotenone 1-4 S 421 1-4 sebuthylazine secbumeton sethoxydim silthiopham simazine simetryn spinosad >4 spiroxamine >4 sulfallate sulfotep 1-4 sulphur >4 sulprofos tau-fluvalinate >4 TBZ >4 TCNB tebuconazole >4 tebufenozide >4 tebufenpyrad >4 tebutam tebuthiuron tecnazene 1-4 teflubenzuron >4 tefluthrin 1-4 temephos TEPP terbacil 1-4
terbufos, sum terbumeton terbuthylazine 1-4 terbutryn 1-4 terbutylazine, desethyl- 1-4 tetrachlorvinphos >4 tetraconazole >4 tetradifon >4 tetrahydrophthalimide >4 tetramethrin 1-4 tetrasul thiabendazole >4 thiacloprid >4 thiamethoxam >4 thifensulfuron-methyl thiobencarb thiodicarb thiofanox, sum thiometon thionazin tiocarbazil tolclofos-methyl >4 tolylfluanid >4 tralomethrin transfluthrin trans-nonachlor trans-permethrin triadimefon/triadimenol, sum >4 tri-allate 1-4 triamiphos 1-4 triapenthenol
triasulfuron triazamate >4 triazophos >4 triazoxide tribenuron-methyl tributylphosphate trichlophenidin trichlorfon >4 trichloronat triclopyr tricyclazole tridemorph 1-4 tridiphane trietazine trifenmorph trifloxystrobin >4 triflumizole >4 triflumuron >4 trifluralin >4 triflusulfuron-methyl triforine 1-4 trimethacarb, sum trinexapac triticonazole uniconazole vamidothion, sum >4 vernolate vinclozolin, total >4 zeta-cypermethrin zoxamide 1-4
8
Table B: Overall results of the national monitoring programmes Data for pesticide residues on fresh (incl. frozen) fruit, vegetables and cereals, sum of surveillance and enforcement samples. The results including processed products are shown in the last row of the table. See explanation about the differences in monitoring results by country under chapter 4.1 of the report.
No. of samples
analysed
No. of pesticides analysed
for
No. of different
pesticides found
%found from
sought
No. of samples without
detec-table
residues
% No. of samples
with residues below or at MRL
(national or EC
MRLs)
% No. of samples
with residues
above MRL
(national or EC
MRLs)
% No. of samples
with confir-
med residues
above EC-
MRLs
%
BE 1602 181 61 34 866 54 659 41 77 4.8 42 2.6CZ 687 119 64 54 380 55 293 43 14 2.0 11 1.6DK 1502 147 76 52 838 56 622 41 42 2.8 42 2.8DE 13911 595 263 44 5439 39 7366 53 1106 8.0 474 3.4EE : : : : : : : : :EL 1693 70 15 21 1342 79 300 18 51 3.0 51 3.0ES 3858 190 79 42 2489 65 1232 32 137 3.6 120 3.1FR 4466 222 90 41 2187 49 2022 45 257 5.8 148 3.3IE 941 113 52 46 472 50 438 47 31 3.3 31 3.3IT 6688 277 129 47 4465 67 2139 32 84 1.3 64 1.0CY 312 134 39 29 171 55 114 37 27 8.7 27 8.7LV : : : : : : : : :LT 448 67 21 31 318 71 123 27 7 1.6 7 1.6LU 119 46 15 33 73 61 43 36 3 2.5 2 1.7HU 2918 148 75 51 1609 55 1254 43 55 1.9 49 1.7MT 65 141 9 6 51 78 10 15 4 6.2 2 3.1NL 2832 387 166 43 954 34 1461 52 417 14.7 223 7.9AT 1784 273 90 33 1154 65 538 30 92 5.2 38 2.1PL 719 60 41 68 358 50 347 48 14 1.9 14 1.9PT 544 134 40 30 408 75 116 21 20 3.7 19 3.5SI 666 102 42 41 395 59 254 38 17 2.6 15 2.3SK 956 78 39 50 716 75 219 23 21 2.2 15 1.6FI 1784 199 95 48 879 49 800 45 105 5.9 94 5.3SE 2067 228 96 42 1089 53 877 42 101 4.9 101 4.9UK 2416 184 92 50 1458 60 917 38 41 1.7 40 1.7NO 2094 211 74 35 1312 63 755 36 27 1.3 27 1.3IS 293 41 24 59 146 50 133 45 14 4.8 14 4.8
LI 30 48 1 2 26 87 4 13 0 0.0 0 0.0TOTAL 55395 169
(Average)69
(Average) 41
(Av.)29595 53 23036 42 2764 5.0 1670 3.0
Total incl. processed
60450 33607 55.6 23997 39.7 2846 4.7 1723 2.9
9
Table C: Fresh (incl. frozen) fruit and vegetables, surveillance sampling: results of the national monitoring programmes
The results including processed products are shown in the last row of the table.
No. of
samples analysed
No. of pesticides analysed
for
No. of different pesticides
found
% found from
sought
No. of samples without detec-table
residues
% No. of samples
with residues below or at MRL (national
or EC MRLs)
% No. of samples
with residues
above MRL
(national or EC MRLs)
% No. of samples
with confir-
med residues
above EC-
MRLs
%
BE 1595 181 61 34 863 54 655 41 77 4.8 42 2.6CZ 612 119 64 54 327 53 273 45 12 2.0 9 1.5DK 1341 147 76 52 716 53 583 43 42 3.1 42 3.1DE 13033 595 263 44 5011 38 6957 53 1065 8.2 457 3.5EE : : : EL 1624 70 15 21 1273 78 300 18 51 3.1 51 3.1ES 3396 190 79 42 2078 61 1191 35 127 3.7 110 3.2FR 2891 222 90 41 1514 52 1265 44 112 3.9 79 2.7IE 853 113 52 46 408 48 416 49 29 3.4 29 3.4IT 6413 277 129 47 4217 66 2112 33 84 1.3 64 1.0CY 312 134 39 29 171 55 114 37 27 9 27 9LV : : : LT 272 67 21 31 177 65 92 34 3 1 3 1LU 102 46 15 33 56 55 43 42 3 2.9 2 2.0HU 2897 148 75 51 1591 55 1251 43 55 1.9 49 1.7MT 59 141 9 6 45 76 10 17 4 7 2 3NL 2756 387 166 43 909 33 1436 52 411 14.9 221 8.0AT 1760 273 90 33 1131 64 537 31 92 5.2 38 2.2PL 581 60 41 68 323 56 249 43 9 1.5 9 1.5PT 492 134 40 30 372 76 100 20 20 4.1 19 3.9SI 605 102 42 41 345 57 243 40 17 2.8 15 2.5SK 890 78 39 50 658 74 211 24 21 2.4 15 1.7FI 1584 199 95 48 804 51 689 43 91 5.7 82 5.2SE 1760 228 96 42 877 50 806 46 77 4.4 77 4.4UK 2348 184 92 50 1450 62 859 37 39 1.7 38 1.6NO 1956 211 74 35 1220 62 710 36 26 1.3 26 1.3IS 270 41 24 59 131 49 126 47 13 4.8 13 4.8
LI 26 48 1 2 22 85 4 15 0 0.0 0 0.0TOTAL 50428 169
(Average)69
(Average) 41
(Av.)26689 53 21232 42 2507 5.0 1519 3.0
Total incl. processed
55440 30665 55 22188 40 2587 4.7 1572 2.8
10
Table D: Cereals, surveillance sampling: results of the national monitoring programmes
No. of samples analysed
No. of pesticides analysed
for
No. of different pesticides
found
% found from
sought
No. of samples without detec-table
residues
% No. of samples
with residues below or at MRL (national
or EC MRLs)
% No. of samples
with residues
above MRL
(national or EC MRLs)
% No. of samples
with confir-
med residues
above EC-
MRLs
%
BE 7 29 3 10 3 43 4 57 0 0.0 0 0.0CZ 28 114 2 2 26 93 2 7 0 0.0 0 0.0DK 161 117 5 4 122 76 39 24 0 0.0 0 0.0DE 410 456 24 5 246 60 160 39 4 1.0 2 0.5EE : : : : : : : : : : : :EL 69 39 0 0 69 100 0 0 0 0.0 0 0.0ES 336 88 6 7 316 94 15 4 5 1.5 5 1.5FR 330 156 8 5 162 49 160 48 8 2.4 8 2.4IE 64 112 5 4 51 80 13 20 0 0.0 0 0.0IT 275 223 10 4 248 90 27 10 0 0.0 0 0.0
CY 0 0 0 0 0 0 0 0 0 0.0 0 0.0LV : : : : : : : : : : : :LT 50 60 3 5 47 94 3 6 0 0.0 0 0.0LU 16 46 0 0 16 100 0 0 0 0.0 0 0.0HU 21 25 2 8 18 86 3 14 0 0.0 0 0.0MT 6 141 0 0 6 100 0 0 0 0.0 0 0.0NL 51 385 5 1 40 78 11 22 0 0.0 0 0.0AT 24 209 2 1 23 96 1 4 0 0.0 0 0.0PL 104 54 34 63 15 14 84 81 5 4.8 5 4.8PT 50 134 3 2 35 70 15 30 0 0.0 0 0.0SI 57 71 5 7 46 81 11 19 0 0.0 0 0.0
SK 66 76 5 7 58 88 8 12 0 0.0 0 0.0FI 137 158 6 4 61 45 72 53 4 2.9 4 2.9SE 232 43 8 19 185 80 46 20 1 0.4 1 0.4
UK 68 32 6 19 8 12 58 85 2 2.9 2 2.9NO 138 135 6 4 92 67 45 33 1 0.7 1 0.7
IS 15 : : : 15 100 0 0 0 0.0 0 0.0
LI 4 48 0 0 4 100 0 0 0 0.0 0 0.0
TOTAL 2719 123 6 5 1912 70 777 29 30 1.1 28 1.0
11
Table E: Fresh (incl. frozen) fruit and vegetables, enforcement sampling: results of the national monitoring programmes
No. of
samples analysed
No. of samples without detec-table
residues
% No. of samples
with residues below or at MRL (national
or EC MRLs)
% No. of samples with
residues above MRL (national or EC MRLs)
% No. of samples
with confir-
med residues
above EC-MRLs
%
BE 0 0 0 0 0 0 0.0 0 0.0CZ 39 21 54 17 44 1 2.6 1 2.6DK 0 0 0 0 0 0 0.0 0 0.0DE 461 177 38 247 54 37 8.0 15 3.3EE : : : : : : : : :EL 0 0 0 0 0 0 0.0 0 0.0ES 126 95 75 26 21 5 4.0 5 4.0FR 1245 511 41 597 48 137 11.0 61 4.9IE 18 7 39 9 50 2 11.1 2 11.1IT 0 0 0 0 0 0 0.0 0 0.0
CY 0 0 0 0 0 0 0.0 0 0.0LV : : : : : : : : :LT 112 80 71 28 25 4 3.6 4 3.6LU 1 1 100 0 0 0 0.0 0 0.0HU 0 0 0 0 0 0 0.0 0 0.0MT 0 0 0 0 0 0 0.0 0 0.0Nl 25 5 20 14 56 6 24.0 2 8.0
AT 0 0 0 0 0 0 0.0 0 0.0PL 32 20 63 12 38 0 0.0 0 0.0PT 2 1 50 1 50 0 0.0 0 0.0SL 4 4 100 0 0 0 0.0 0 0.0SK 0 0 0 0 0 0 0.0 0 0.0FI 63 14 22 39 62 10 15.9 8 12.7
SE 75 27 36 25 33 23 30.7 23 30.7UK 0 0 0 0 0 0 0.0 0 0.0
NOR 0 0 0 0 0 0 0.0 0 0.0ICE 8 0 0 7 88 1 12.5 1 12.5
LIECH 0 0 0 0 0 0 0.0 0 0.0
TOTAL 2211 963 44 1022 46 226 10.2 122 5.5
12
Table F: Processed products, surveillance sampling: results of the national monitoring programmes
No. of
samples analysed
No. of samples without detec-table
residues
% No. of samples
with residues
below or at MRL
(national or EC MRLs)
% No. of samples
with residues
above MRL (national or EC MRLs)
% No. of samples
with confir-
med residues
above EC-
MRLs
%
BE 125 98 78 26 21 1 0.8 0 0.0CZ 35 31 89 4 11 0 0.0 0 0.0DK 102 81 79 20 20 1 1.0 1 1.0DE 152 123 81 29 19 0 0.0 0 0.0EE : : : : : : : : :EL 356 200 56 154 43 2 0.6 1 0.3ES 30 17 57 13 43 0 0.0 0 0.0FR 65 59 91 6 9 0 0.0 0 0.0IE 54 51 94 3 6 0 0.0 0 0.0IT 646 467 72 162 25 17 2.6 0 0.0
CY 13 10 77 3 23 0 0.0 0 0.0LV : : : : : : : : :LT 0 0 0 0 0 0 0.0 0 0.0LU 46 42 91 4 9 0 0.0 0 0.0HU 0 0 0 0 0 0 0.0 0 0.0MT 0 0 0 0 0 0 0.0 0 0.0Nl 374 239 64 121 32 14 3.7 8 2.1
AT 73 50 68 18 25 5 6.8 5 6.8PL 60 35 58 25 42 0 0.0 0 0.0PT 31 30 97 1 3 0 0.0 0 0.0SI 215 169 79 46 21 0 0.0 0 0.0
SK 77 71 92 6 8 0 0.0 0 0.0FI 372 302 81 68 18 2 0.5 2 0.5
SE 196 159 81 35 18 2 1.0 0 0.0UK 588 456 78 132 22 0 0.0 0 0.0NO 43 42 98 1 2 0 0.0 0 0.0
IS 19 17 89 2 11 0 0.0 0 0.0LI 6 6 100 0 0 0 0.0 0 0.0
TOTAL 3678 2755 75 879 24 44 1.2 17 0.5Total incl baby food
5012 3976 79 956 19 80 1.6 53 1.1
13
Table G: Samples with residues of more than one pesticide in fresh (incl. frozen) fruit, vegetables and cereals, surveillance and enforcement sampling
No. of
samples analysed
2 3 4 5 6 7 8 and more
No. of samples
with multiple residues
%
BE 1602 128 66 41 19 7 5 3 269 16.8CZ 687 117 68 42 22 8 7 1 265 38.6DK 1502 140 94 53 13 10 2 2 314 20.9DE 13911 1909 1158 816 470 314 185 323 5175 37.2EE : : : : : : : : : :EL 1693 41 21 5 3 1 1 0 72 4.3ES 3858 159 70 31 1 0 261 6.8FR 4466 547 320 150 78 25 12 7 1139 25.5IE 941 107 48 15 3 1 0 174 18.5IT 6688 520 251 126 69 29 9 5 1009 15.1CY 312 33 13 4 7 1 2 1 61 19.6LV : : : : : : : : : :LT 448 30 8 2 1 0 41 9.2LU 119 11 4 0 1 0 16 13.4HU 2918 188 128 58 13 1 3 0 391 13.4MT 65 3 0 3 4.6Nl 2832 414 281 185 111 78 35 74 1178 41.6AT 1784 171 86 46 32 17 8 3 363 20.3PL 719 41 32 21 23 13 11 12 153 21.3PT 544 20 15 4 7 1 0 2 49 9.0SI 666 33 10 4 2 3 0 1 53 8.0SK 956 44 10 8 1 0 63 6.6FI 1784 252 137 66 18 7 2 1 483 27.1SE 2067 279 127 54 25 5 0 2 492 23.8UK 2416 295 153 73 28 21 1 2 573 23.7NO 2094 188 96 32 4 2 0 322 15.4IS 293 25 24 14 4 0 67 22.9LI 30 0 0 0.0TOTAL 55395 5695 3220 1850 955 544 283 439 12986 23.4% 10.3 5.8 3.3 1.72 0.98 0.51 0.792
14
Table H: Pesticides found most often in the national (incl. co-ordinated) monitoring programmes in the European Union, Norway, Iceland and Liechtenstein for a) fruit and vegetables and b) cereals, as reported
Country Pesticides found most often.
a) Fruit and vegetables b) Cereals BE Chlorpropham, Phenylphenol-ortho,
Bromide, Chlormequat, Propamocarb, Maneb group, Iprodione, Imazalil, Prochloraz and Ethephon
Pirimiphos-ethyl, Pirimiphos-methyl and Lindane.
CZ Phenylphenol ortho-, Maneb group, Imazalil, Bromide, Benomyl group, Thiabendazol, Procymidone, Endosulfan, Biphenyl and Chlormequat
Chlorpyriphos-methyl and Malathion
DK Chlormequat, Imazalil, Maneb-group, Chlorpyriphos, Pyrimethanil, Iprodione, Procymidone, Thiabendazole, Tolyfluanid and Endosulfan
Chlormequat, Pirimiphos-methyl, Deltamethrin, Mepiquat and Chlorpyriphos-methyl
DE Bromide, Maneb group, Benonmyl group, Cyprodinil, Procymidone, Chlorpyriphos, Tolyfluanid, Imidacloprid, Iprodione and Chlormequat
Bromide, Chlormequat, Pirimiphos-methyl, Maneb group, Ethephon, Fenpiclonil, Piperonyl butoxide, Fluroxipyr, Barban and Desmethrin
EE Data not reported. Data not reported.
EL Maneb group, Chlorpyriphos, Benomyl group, Captan, Procymidone,Endosulfan, Phosalone, Bifenthrin, Azoxystrobin and Chlorothalonil
None
ES Chlorpyriphos, Procymidone, Imazalil, Malathion, Maneb group, Chlortalonil, Dicofol, Endosulfan, Methidathion and Captan+Folpet
Malathion,Pirimiphos-methyl, Propyconazol, Bromopropylate, Deltamethrin and Diphenconazol
FR Maleic Hydrazide, Thiabendazol, Benomyl Group, Chlorpyriphos-ethyl, Imazalil, Maneb Group, Bromide, Iprodione, Procymidone and Endosulfan
Dichlorvos, Malathion, Pyrimiphos methyl, Deltamethrin, Chlorpyriphos methyl, Bifenthrin, Chlorpyriphos ethyl and Parathion-ethyl
IE Thiabendazole, Benomyl group, Iprodione, Captan, Chlorpyrifos, Tolyfluanid, Tebuconazole, Prochloraz, Malathion and Myclobutanil
Pirimiphos-methyl, Malathion, Deltamethrin, Chlorpyriphos methyl, and Thiabendazole
IT Chlorpyriphos, Procymidone, Malathion, Parathion-methyl, Chlorothalonil, Vinclozolin, Phosalone, Diazinon, Dichlofluanid and Fenitrothion
Chlorpyriphos, Malathion, Pirimiphos-methyl, Methyl, Diazinon, Dimethoate Parathion-methyl, Fenitrothion, Azinphos-ethyl and Azinphos-methyl
CY Chlorpyriphos, Maneb group, Cypermethrin, Endosulfan, Diphenylamine, Imazalil, Thiabendazol, Methamidophos, Chlorothalonil and Procymidone
None
15
Country Pesticides found most often. a) Fruit and vegetables b) Cereals
LV Data not reported. Data not reported.
LT Procymidone, Chlorpyriphos, Iprodione, Fenvalverate, Malathion, Chlorpyriphos-methyl, Phosalone, Tolylfluanid, Imazalil and Vinclozolin
Chlorpyriphos, Diazinon and Malathion
LU Iprodione, Maneb group, Pyrimethanil, Folpet, Procymidone, Tolylfluanid, Tolclophos-methyl Azoxystrobin Fenarimol and Oxadixyl
None.
HU Vinclozolin,Fosethyl-aluminium, Procymidone, Maneb group, Azoxystrobin, Iprodione, Dimethoate, Benomyl group, Folpet and Captan
None.
MT Cyprodinil, Dimethoate, Imazalil, Chlorpyriphos-ethyl Chlorpyriphos-methyl Dichlofluanid Iprodione and Oxadixyl
None.
NL Chlormequat, Propamocarb, Maneb group, Benomyl group, Iprodione, Imazalil, Chlorpyriphos-ethyl, Thiabendazol, Procymidone and Cyprodinil
Dichlorvos, Pirimiphos-methyl, Malathion, Piperonyl-butoxide and Chlorpropham
AT Maneb group, Procymidone, Cyprodinil, Fludioxonil, Chlorpyriphos, Imidacloprid, Iprodione, Endosulfan, Azoxystrobin and Benomyl group
Pirimiphos-methyl, and Malathion
PL Lindane, Maneb group, Dieldren, Aldicarb, Methomyl, Endrin, HCH, Heptaclor, Nitrofen and Aldrin
Methomyl, Aldicarb, Methiocarb, Bromide, Lindane, Azinphos-methyl, HCH, Heptachlor, Captan and Dieldrin
PT Maneb group, Captan, Diphenylamine, Phosmet, Diazinon, Benomyl group, Chlorpyriphos, Folpet, Dicofol and Phosalone
Malathion, Pirimiphos-methyl and Dichlorvos
SI Maneb group, Diphenylamine, Fenhexamid, Diazinon, Cyprodinil, Captan, Benomyl group, Oxydemeton-methyl, Thyophanate-methyl and Phosalone
Chlorpyriphos-methyl, Malathion, Benomyl group, Diazinon and Pirimiphos-methyl
SK Maneb group, Phenylphenol- ortho, Chlorpyriphos, Imazalil, Biphenyl, Thiabendazol, Procymidone, Iprodione, Endosulfan and Chlorothalonil
Chlorpyriphos-methyl, Chlorpyriphos, Pirimiphos-methyl, Azoxystrobin and Deltamethrin
FI Chlormequat, Dithianon, Hydrogen phosphide, Bromide, Diquat, Benomyl group, Maleic-hydrazide, Imazalil and Maneb group
Hydrogen cyanide, Chlormequat, Glyphosate, Bromide, Pirimiphos-methyl and Endosulfan
16
Country Pesticides found most often. a) Fruit and vegetables b) Cereals
SE Maneb group, Bromide, Diquat, Ethoxyquin, Maleic-hydrazide, Imazalil, Thiabendazol, Benomyl group, Chlormequat and Phosphine
Chlormequat, Mepiquat, Glyphosate, Phosphine, Bromide, Pirimiphos-methyl, Chlorpyriphos-methyl and Deltamethrin
UK 2,4-D, Chlorpropham, 2-phenylphenol Benomyl group, Captan, Chlorpyriphos, Chlormequat, Cypermethrin, Azoxystrobin and Chlorothalonil
Chlormequat, Mepiquat, Glyphosate, Pirimiphos-methyl, Malathion and Chlorpyriphos-methyl
NO Chlormequat, Diquat, Maneb group, Imazalil, Phenylphenol-ortho, Propamocarb, Thiabendazol, Iprodione, Dithianon and Benomyl group
Glyphosate, Chlormequat, AMPA, Malathion, Pirimiphos-methyl and Chlorpyriphos
IS Imazalil, Thiabendazol, Phenylphenol-ortho, Chlorpyriphos, Methidathion, Malathion, Procymidone, Dicofol, Dimethoate and Iprodione
None
LI Maneb group None
EU, NOR,
ICE and LIE
Maneb group, Chlorpyriphos, Imazalil, Procymidone, Benomyl group, Iprodione, Thiabendazol, Chlormequat, Bromides and Phenylphenol, ortho-
Pirimiphosmethyl, Malathion, Chlorpyriphos-methyl, Chlormequat, Deltamethrin, Chlorpyriphos, Glyphosate, Bromides, Dichlorvos and Mepiquat
17
Table I: Numbers of samples taken by participating States for each commodity in the EU co-ordinated programme
Number of samples taken by commodity
Country
Recommended number of
samples (for each
commodity) Apples Tomatoes Lettuce Strawberries Leek Orange
juice Head
cabbage Rye/ Oats
BE 12 58 36 166 38 35 30 30 7CZ 12 30 33 16 14 14 13 13 10DK 12 118 70 27 30 23 21 23 46DE 93 791 781 741 1383 123 130 227 180EE 12 : : : : : : : :EL 12 18 43 19 18 27 12 16 18ES 45 45 45 45 48 37 30 46 45FR 66 295 200 206 112 123 65 62 106IE 12 90 25 72 27 6 32 16 12IT 65 693 457 226 214 7 11 56 2CY 12 18 30 18 20 0 13 0 0LV 12 : : : : : : : :LT 12 22 38 9 16 6 0 13 8LU 12 5 13 15 13 13 12 12 10HU 12 12 12 12 21 12 0 11 12MT 12 : : : : : : : :NL 17 106 120 159 153 44 18 42 6AT 12 12 12 12 12 0 11 12 13PL 45 71 51 47 68 50 60 65 46PT 12 63 85 74 23 71 45 65 27SI 12 58 35 58 46 12 32 20 26SK 12 15 17 10 11 12 13 12 14FI 12 126 80 94 124 17 15 38 44SE 12 198 81 45 55 30 29 30 45UK 66 144 300 108 99 72 72 72 68
Total EU 25
613 2988 2564 2179 2545 734 664 881 745
NO 12 122 86 105 116 28 40 33 46IS 12 20 12 14 4 4 0 4 4LI 12 3 3 3 3 3 0 0 0
Total EU 25
and EEA
649 3133 2665 2301 2668 769 704 918 795
Note : Estonia, Latvia and Malta did not participate in the co-ordinated programme in 2004.
18
Table K: Residues of pesticides in the eight commodities as analysed in the EU Member States and EEA States
Number of samples analysed
Without detectable residues
% With residues below or at
MRL (national or EC-MRL)
% With residues above MRL
(national or EC-MRL)
%
BE 400 189 47 196 49 15 3.8CZ 143 100 70 42 29 1 0.7DK 358 224 63 129 36 5 1.4DE 4356 1791 41 2460 56 105 2.4EE : : : : : : :EL 171 146 85 20 12 5 2.9ES 341 271 79 69 20 1 0.3FR 1169 616 53 527 45 26 2.2IE 280 134 48 140 50 6 2.1IT 1666 1026 62 624 37 16 1.0CY 99 61 62 36 36 2 2.0LV : : : : : : :LT 112 86 77 22 20 4 3.6LU 93 65 70 27 29 1 1.1HU 92 59 64 31 34 2 2.2MT : : : : : : :NL 648 272 42 355 55 21 3.2AT 84 47 56 36 43 1 1.2PL 458 201 44 249 54 8 1.7PT 453 343 76 94 21 16 3.5SI 287 144 50 139 48 4 1.4SK 104 70 67 31 30 3 2.9FI 538 290 54 243 45 5 0.9SE 513 341 66 161 31 11 2.1UK 935 580 62 349 37 6 0.6NO 576 405 70 167 29 4 0.7IS 62 41 66 21 34 0 0.0LI 15 15 100 0 0 0 0.0
Total 13953 7517 54 6168 44 268 1.9
19
Table L: Results from the EU co-ordinated monitoring programme for pesticide residues for each pesticide analysed for in apples, tomatoes, lettuce, strawberries, leek, orange juice, head cabbage and rye/oats.
Pesticide Total No.
of samples
No. of samples without residues
No. of samples
with residues
below or at MRL
% No. of samples with
residues above MRL
%
Acephate 12054 11999 51 0.42 4 0.03
Aldicarb 6860 6801 58 0.85 1 0.01
Azinphos-methyl 12151 11907 244 2.01 0 0.00
Azoxystrobin 11520 11086 432 3.75 2 0.02
Benomyl group 8815 8147 638 7.24 30 0.34
Bromopropylate 12408 12334 58 0.47 16 0.13
Chlorothalonil 12393 12043 341 2.75 9 0.07
Chlorpyriphos 13062 12458 601 4.60 3 0.02
Chlorpyriphos-methyl 12932 12865 67 0.52 0 0.00
Cypermethrin 12469 12358 110 0.88 1 0.01
Cyprodinil 10998 9964 1025 9.32 9 0.08
Deltamethrin 12462 12380 81 0.65 1 0.01
Diazinon 12685 12612 68 0.54 5 0.04
Dichlofluanid 12676 12623 53 0.42 0 0.00
Dicofol 11274 11247 14 0.12 13 0.12
Dimethoate 12941 12795 129 1.00 17 0.13
20
Pesticide Total No. of
samples
No. of samples without residues
No. of samples
with residues
below or at MRL
% No. of samples with
residues above MRL
%
Diphenylamine (reported for apples, only)
2331 1986 345 14.80 0 0.00
Endosulfan 12592 12173 397 3.15 22 0.17
Fenhexamid 7957 7490 467 5.87 0 0.00
Captan+ Folpet (Sum) 13683 12988 685 5.01 10 0.07
Imazalil 11779 11719 58 0.49 2 0.02
Iprodione 12398 11488 903 7.28 7 0.06
Kresoxim-methyl 10754 10564 190 1.76 1 0.01
Lambda-cyhalothrin 11554 11413 138 1.19 3 0.03
Malathion 12854 12768 86 0.67 0 0.00
Maneb-group 6149 5259 852 13.86 38 0.62
Mecarbam 11037 11033 4 0.04 0 0.00
Methamidophos 12054 12022 22 0.18 10 0.08
Metalaxyl 12539 12381 157 1.25 1 0.01
Methidathion 12475 12463 11 0.09 1 0.01
Methiocarb 8169 8139 28 0.34 2 0.02
Methomyl 6641 6486 149 2.24 6 0.09
Myclobutanil 11098 10888 207 1.87 3 0.03
Omethoate 7544 7539 5 0.07 0 0.00
21
Pesticide Total No. of
samples
No. of samples without residues
No. of samples
with residues
below or at MRL
% No. of samples with
residues above MRL
%
Oxydemeton-methyl 7345 7279 35 0.48 31 0.42
Parathion 12613 12594 18 0.14 1 0.01
Permethrin 11604 11583 18 0.16 3 0.03
Phorate 10401 10399 2 0.02 0 0.00
Pirimiphos-methyl 12558 12484 73 0.58 1 0.01
Procymidone 12738 11833 891 6.99 14 0.11
Propyzamide 11306 11238 67 0.59 1 0.01
Spiroxamine 6734 6732 2 0.03 0 0.00
Thiabendazol 10168 9939 227 2.23 2 0.02
Tolylfluanid 11085 10191 890 8.03 4 0.04
Triazophos 11038 11035 3 0.03 0 0.00
Vinclozolin 12622 12462 155 1.23 5 0.04
22
Table M: Presentation of the most important pesticide-commodity combinations where residues were found (in alphabetical order)
Pesticide Detected most
often in % of
samples of that
commo-dity1
MRL exceeded
most often in
% of samples of that
commo-dity
Maximum residue found in mg/kg
Acephate Lettuce 1.68 Strawberries 0.13 2.80 (Lettuce; EC-MRL: 1)
Aldicarb Leek 4.81 Strawberries 0.07 0.089 (Strawberries; EC-MRL: 0.05)
Azinphos-methyl
Apples 7.27 None 0.49 (Apples; EC-MRL: 0.5)
Azoxystrobin Strawberries 12.84 Lettuce 0.11 11.85 (Lettuce; EC-MRL: 3)
Benomyl group Apples 20.42 Strawberries 1.49 2.59 (Orange Juice; EC-MRL2: 5)
Bromopropylate Tomatoes 1.48 Apples 0.28 1.50 (Tomatoes; EC-MRL3: 1)
Chlorothalonil Tomatoes 7.09 Lettuce 0.43 14.20 (Lettuce; EC-MRL: 0.01)
Chlorpyriphos Apples 16.38 Lettuce 0.05 0.51 (Tomatoes; EC-MRL: 0.5)
Chlorpyriphos-methyl
Apples 1.16 None 1.40 (Rye/Oats; EC-MRL: 3)
Cypermethrin Lettuce 3.36 Tomatoes 0.04 1.50 (Lettuce; EC-MRL: 2)
Cyprodinil Strawberries 33.97 Strawberries 0.17 3.30 (Lettuce; EC-MRL: not set)
Deltamethrin Lettuce 2.53 Lettuce 0.05 1.47 (Lettuce; EC-MRL: 0.5)
Diazinon Apples 1.82 Lettuce 0.10 0.34 (Lettuce; EC-MRL: 0.02)
Dichlofluanid Strawberries 0.98 None 0.70 (Head Cabbage; EC-MRL: 5)
Dicofol Tomatoes 0.69 Apples 0.27 1.10 (Tomatoes; EC-MRL: 1)
1 Percentages in this column include samples at or below the MRL and exceeding the MRL 2 MRL applies for oranges. See chapter 4.1.4 about applicability of MRLs for processed products. 3 MRL applies since 25 October 2004
23
Pesticide Detected most often in
% of samples of that
commo-dity1
MRL exceeded
most often in
% of samples of that
commo-dity
Maximum residue found in mg/kg
Dimethoate Lettuce 3.91 Apples 0.34 4.30 (Head Cabbage; EC-MRL: 1)
Diphenylamine Apples 14.80 None 4.80 (Apples; EC-MRL: 5)
Endosulfan Tomatoes 9.11 Strawberries 0.66 1.40 (Strawberries; EC-MRL: 0.05)
Fenhexamid Strawberries 22.37 None 3.40 (Strawberries; EC-MRL: 5)
Captan+ Folpet (Sum)
Apples 14.64 Lettuce 0.23 7.00 (Lettuce; EC-MRL: 2)
Imazalil Orange Juice 5.01 Lettuce 0.05 1.06 (Apples; EC-MRL: 5)
Iprodione Lettuce 22.72 Leek 0.56 105.9 (Lettuce; EC-MRL: 10)
Kresoxim-methyl
Strawberries 8.52 Lettuce 0.05 1.00 (Strawberries; EC-MRL: 1)
Lambda-cyhalothrin
Lettuce 3.68 Tomatoes 0.09 1.10 (Lettuce; EC-MRL: 1)
Malathion Strawberries 1.32 None 2.40 (Rye/Oats; EC-MRL: 8)
Maneb-group Lettuce 22.03 Lettuce 1.42 15.00 (Lettuce; EC-MRL: 5)
Mecarbam Rye/Oats 0.37 None 0.033 (Apples; EC-MRL: 0.05)
Methamidophos Lettuce 0.84 Lettuce 0.30 7.70 (Lettuce; EC-MRL: 0.2)
Metalaxyl Lettuce 4.93 Tomatoes 0.04 0.88 (Lettuce; EC-MRL: 1)
Methidathion Apples 0.14 Cabbage 0.12 0.22 (Apples; EC-MRL: 0.3)
Methiocarb Rye/Oats 2.53 Strawberries 0.11 0.30 (Strawberries; EC-MRL: not set)
Methomyl Lettuce 6.83 Strawberries 0.40 2.00 (Lettuce; EC-MRL:2)
Myclobutanil Strawberries 7.52 Lettuce 0.17 0.33 (Strawberries; EC-MRL: 1)
24
Pesticide Detected most often in
% of samples of that
commo-dity1
MRL exceeded
most often in
% of samples of that
commo-dity
Maximum residue found in mg/kg
Omethoate Lettuce 0.17 None 0.035 (Lettuce; EC-MRL: 0.2)
Oxydemeton-methyl
Lettuce 3.01 Lettuce 1.50 2.20 (Lettuce; EC-MRL: 0.05)
Parathion Rye/Oats 1.51 Lettuce 0.05 0.54 (Lettuce; EC-MRL: 0.05)
Permethrin Leek 1.72 Lettuce 0.16 0.38 (Lettuce; EC-MRL: 0.05)
Phorate Tomatoes 0.10 None 0.002 (Tomatoes; EC-MRL: 0.05)
Pirimiphos-methyl
Rye/Oats 8.49 Rye/Oats 0.13 7.90 (Rye/Oats; EC-MRL: 5)
Procymidone Tomatoes 14.76 Apples 0.31 21.10 (Lettuce; EC-MRL: 5)
Propyzamide Lettuce 3.15 Strawberries 0.05 0.54 (Lettuce; EC-MRL: 1)
Spiroxamine Strawberries 0.13 None 0.017 (Strawberries; EC-MRL: 0.05)
Thiabendazol Apples 8.07 Rye/Oats 0.20 4.40 (Apples; EC-MRL: 5)
Tolylfluanid Strawberries 20.61 Leek 0.15 5.00 (Lettuce; EC-MRL: not set)
Triazophos Rye/Oats 0.48 None 0.004 (Rye/Oats; EC-MRL: 0.02)
Vinclozolin Lettuce 5.55 Tomatoes 0.17 6.00 (Lettuce; EC-MRL: 5)
25
Table N: Results of the homogeneity exercise
Max. residue
found in a single unit
Commodity Pesticide Country Number of single units analysed in
each composite
sample
Homogen-eity factor
of each composite
sample (mg/kg)
Samples taken from single
producer
Apples Azinphos-methyl NO 10 2.22 0.08 Yes Apples Azinphos-methyl NL 20 2.8 0.11 No Apples Azinphos-methyl NL 20 3.3 0.08 No Apples Benomyl NL 20 1.4 0.12 No Apples Benomyl NL 20 2.7 0.2 No Apples Bifenthrin NL 20 3.1 0.06 No Apples Bitertanol CR 13 2.3 0.03 Yes Apples Captan NL 20 2.2 0.27 No Apples Captan NL 20 2.5 0.07 No Apples Captan NL 20 5.3 0.14 No Apples Carbaryl FI 8 2.26 0.3 No Apples Carbaryl NL 20 4.4 0.13 No Apples Carbendazim CR 20 2.23 0.296 Yes Apples Carbendazim CR 20 n.a. <LOD Yes Apples Chlorpyriphos AU 5 1.4 0.042 Yes Apples Chlorpyriphos GR 5 3.17 0.73 Yes Apples Chlorpyriphos GR 5 3.67 0.11 Yes Apples Chlorpyriphos GR 6 2 0.1 Yes Apples Chlorpyriphos CR 20 3.55 0.071 Yes Apples Chlorpyriphos NL 20 5.3 0.14 No Apples Chlorpyriphos NL 20 7.4 0.17 No Apples Diazinon GR 10 7.2 0.36 Yes Apples Diphenylamine AU 6 1.5 2.954 Yes Apples Diphenylamine NO 10 1.69 3 Yes Apples Diphenylamine NL 20 1.8 1.8 No Apples Diphenylamine NL 20 2.1 0.93 No Apples Diphenylamine NL 20 2.1 2.7 No Apples Diphenylamine NL 20 2.6 1.7 No Apples Ethoxyquin NL 20 6.1 1 No Apples Fenoxycarb NL 20 4.2 0.2 No Apples Iprodione NL 20 2.3 0.05 No Apples Pencycuron NL 20 11.5 1.1 No Apples Phosalone GR 5 1.86 0.13 Yes Apples Phosalone GR 5 3 1.38 Yes Apples Phosalone GR 6 2.06 0.64 Yes Apples Phosalone GR 6 2.21 0.53 Yes Apples Phosalone SK 10 2.72 0.596 No Apples Phosalone NL 20 2.7 0.07 No Apples Phosmet FI 6 2.55 0.24 No Apples Phosmet NL 20 3.4 0.16 No Apples Propargite NL 20 5 0.16 No Apples Propargite NL 20 5.2 3.3 no
26
Max. residue
found in a single unit
Commodity Pesticide Country Number of single units analysed in
each composite
sample
Homogen-eity factor
of each composite
sample (mg/kg)
Samples taken from single
producer
Apples Teflubenzuron CR 13 1.78 0.141 yes Apples Thiabendazole FI 10 1.71 0.2 no Apples Thiabendazole NL 20 3.7 3.3 no Apples Tolylfluanid CR 13 1.67 0.035 yes Apples Triadimenol CR 13 n.a. <LOD yes
Head cabbage Difenoconazole AU 6 1.88 0.299 yes Leek Tebuconazole CR 6 3.07 0.08 yes
Lettuce Acephate NL 10 4.6 0.66 no Lettuce Captan NL 10 3.8 0.14 no Lettuce Cypermethrin IE 10 1.54 1.97 yes Lettuce Cyprodinil NL 10 5.2 3 no Lettuce Deltamethrin AU 10 1.16 0.067 yes Lettuce Deltamethrin IE 10 2.95 0.18 yes Lettuce Diazinon GR 2 1 0.02 yes Lettuce Dichlofluanide NL 10 1.8 0.05 no Lettuce Difenoconazole AU 10 2.3 0.069 yes Lettuce Dimethoate AU 10 1.84 0.094 yes Lettuce Dimethoate NL 10 3.3 0.08 no Lettuce Endosulfan GR 3 1.42 0.08 yes Lettuce Endosulfan HU 5 1.78 0.084 yes Lettuce Endosulfan NL 10 2.9 0.14 no Lettuce Fenitrothion FI 8 2.85 0.13 no Lettuce Fludionoxil NL 10 5.6 4.3 no Lettuce Folpet AU 10 1.6 0.305 yes Lettuce Iprodione NL 10 2 1.4 no Lettuce Iprodione IE 10 2.44 0.31 yes Lettuce Iprodione NL 10 2.8 2.3 no Lettuce Metalaxyl NL 10 2.8 0.16 no Lettuce Metalaxyl NL 10 3.1 0.05 no Lettuce Metalaxyl AU 10 n.a. <LOD yes Lettuce Methamidophos GR 2 1.19 1.75 yes Lettuce Methamidophos GR 3 1.25 5.04 yes Lettuce Methamidophos GR 3 1.42 3.74 yes Lettuce Methamidophos NL 10 2.6 0.05 no Lettuce Oxadixyl NL 10 1.8 0.45 no Lettuce Oxydemeton-methyl FI 6 1.59 0.28 no Lettuce Pencycuron NL 10 1.8 0.8 no Lettuce Pencycuron NL 10 6.6 1.1 no Lettuce Permethrin HU 5 1.3 0.26 yes Lettuce Permethrin HU 5 1.65 0.32 yes Lettuce Pirimicarb NL 10 5 0.5 no Lettuce Procymidone CR 10 1.34 0.479 yes Lettuce Procymidone CR 10 1.71 0.345 yes Lettuce Procymidone NL 10 1.8 15.3 no Lettuce Procymidone NL 10 3.3 0.66 no Lettuce Tolylfluanid CR 10 2.82 0.434 yes
27
Max. residue
found in a single unit
Commodity Pesticide Country Number of single units analysed in
each composite
sample
Homogen-eity factor
of each composite
sample (mg/kg)
Samples taken from single
producer
Peaches Cyprodinil SV 8 1.5 0.06 no Peaches Cyprodinil SV 8 1.64 0.15 no Peaches Diazinon SV 8 1.75 0.01 no Peaches Phosalone SV 8 1.57 0.09 no
Tomatoes Alpha-endosulfan CR 10 2.63 0.084 yes Tomatoes Alpha-endosulfan CR 10 2.8 0.014 yes Tomatoes Alpha-endosulfan CR 10 4.4 0.022 yes Tomatoes Beta-endosulfan CR 10 2.42 0.029 yes Tomatoes Beta-endosulfan CR 20 3.67 0.187 yes Tomatoes Beta-endosulfan CR 20 4.15 0.083 yes Tomatoes Captan CR 20 n.a. <LOD yes Tomatoes Carbendazim CR 20 3.02 0.13 yes Tomatoes Chlorthalonil SK 10 3.71 0.059 no Tomatoes Dimethoate GR 10 n.a. <LOD yes Tomatoes Endosulfan GR 5 2.17 0.13 yes Tomatoes Endosulfan sulphate CR 10 1.89 0.017 yes Tomatoes Endosulfan sulphate CR 20 2.55 0.092 yes Tomatoes Endosulfan sulphate CR 20 3.5 0.084 yes Tomatoes Iprodione SK 10 1.71 0.157 no Tomatoes Procymidone CR 10 1.8 0.063 yes Tomatoes Procymidone CR 10 2.3 0.046 yes Tomatoes Procymidone CR 20 3.54 0.105 yes Tomatoes Tolylfluanid FI 10 1.93 0.11 no
28
Table O: Number and origin of the samples taken by country (sum of surveillance and follow-up enforcement samples, sum of fresh (incl. frozen) fruit, vegetables, cereals and processed products
Country Total
number of
samples taken
Samples taken per 100,000 inhabi-tants
No. of domes-
tic samp-
les taken
% No. of samples
from OMS
% No. of samples
from TCs
% Origin not
known
%
BE 1766 17 990 56 265 15 329 19 182 10.3CZ 791 8 241 30 416 53 134 17 DK 1624 30 485 30 587 36 529 33 23 1.4DE 14337 17 5195 36 5648 39 2179 15 1315 9.2EE : : : : : : : : : :EL 2049 18 1624 79 21 1 404 20 ES 3888 9 3888 10 0 0 0 0 FR 4568 8 3307 72 669 15 592 13 IE 1036 25 278 27 388 37 275 27 95 9.2IT 7407 13 6679 90 227 3 501 7
CY 325 43 290 89 6 2 29 LV : : : : : : : : : :LT 448 13 240 54 188 42 20 4 LU 165 36 57 35 94 57 14 8 HU 2918 29 2123 73 568 19 227 8 MT 65 16 51 78 6 9 8 12 NL 3416 21 1215 36 835 24 1004 29 362 10.6AT 1912 23 839 44 572 30 501 26 PL 917 2 784 85 81 9 52 6 PT 589 6 501 85 70 12 18 3 SI 967 48 507 52 375 39 85 9
SK 1047 19 564 54 309 30 93 9 81 7.7FI 2171 41 370 17 872 40 929 43 SE 2355 26 635 27 741 31 979 42
UK 3123 5 1129 36 860 28 1134 36 NO 2207 48 856 39 764 35 587 27
IS 323 110 62 19 147 46 114 35 LI 36 104 36 10 0 0 0 0
TOTAL 60450 13 32946 54.5 14709 24.3 10737 17.8 2058 3.4
29
Table P: Accreditation, participation in proficiency tests and implementation of the EU Quality Control Procedures of the pesticide residue laboratories
Country
No. of
laboratories Accreditation Participation in
proficiency tests Implementation of EU
Quality Control Procedures (QC procedures)
BE 3 Accredited by BELTEST
FAPAS and EU PT46
All three laboratories are reported as fully implementing from 80 to 100 % of the QC procedures, remaining percentage partly implemented.
CZ 1 Accredited by CAI FAPAS and EU PT6
At least 60 % of the QC procedures are reported fully implemented; remaining percentage partly implemented.
DK 2 (1 main lab performs 100% of sampling analyses. Second lab does confirmation)
Accredited by DANAK
FAPAS In both laboratories full implementation from 70 to 90 % of the QC procedures is reported, remaining percentage partly implemented.
DE 34 Accredited by SAL and AKS
FAPAS, EU PT5, NFA 5 and other national PT
Different status of the application of QC procedures: full implementation reported between 60% and 100% with most of the remainder partially implemented.
EL 8 1 accredited by E.Sy.D
4 Labs participated in EU PT6
80 % of QC procedures reported fully implemented, the remaining percentage being partly implemented.
ES 16 4 ENAC accredited laboratories (doing approx. 50 % of the analyses).
National PT– EU PT6
For the 4 accredited labs full implementation is reported of all QC procedures, part implementation for remaining 12 labs.
FR 7 5 laboratories, which performed 84 % of the analyses, are fully accredited by COFRAC
BIPEA6- FAPAS- EU PT5
Different status of the application of QC procedures: full implementation between 60% and 90% reported; most of remaining percentage is partly implemented.
IE 1 Accredited by INAB FAPAS- EU PT5 70 % of the QC procedures are reported fully implemented –mainly compliant with remainder.
4 European Proficiency Test 5 Proficiency tests organised by the National Food Administration of Sweden 6 Proficiency tests organised by the Bureau Interprofessionnel d’Etudes Analitiques
30
Country
No. of laboratories
Accreditation Participation in proficiency tests
Implementation of EU Quality Control Procedures
(QC procedures)
IT 30 18 laboratories are accredited by ISS-ORL and SINAL and analysed 75% of the monitoring samples
The 18 accredited labs participated in EU PT6, FAPAS and/or national PT
Implementation level not reported for 21 labs. For the other 9 labs, reported implementation between 50% and 80% of QC procedures and partial implementation of remainder.
CY 1 Accredited by ESYD
FAPAS and EU PT6.
60 % of the QC procedures are reported fully implemented –remainder are partly implemented.
LT 1 Accredited by DAP FAPAS Most (at least 80%) of the EU QC procedures are reported as not implemented.
LU 1 Accredited by OLAS
FAPAS- EU PT6 At least 80 % of the QC procedures are reported fully implemented; remainder partly implemented.
HU 11 Accredited by NIPH 8 labs participated in EU PT 6 or FAPAS.
60 % of the QC procedures are reported fully implemented –remainder are partly implemented.
MT 1 (in Italy) Accredited by SINAL
Two Italian national PT
All of the QC procedures are repored fully implemented.
NL 1 Accredited by RvA FAPAS, EU-pesticide residues.
All of the QC procedures are reported fully implemented
AT 4 Accredited by BMWA and AKS
EU PT5 - other national PT - FAPAS
All or at least 90% of the QC procedures are reported fully implemented in 3 labs. No information reported on the 4th lab.
PL 16 8 labs accredited by PCA
8 labs participated in national PTs – the other 8 did not participate in 2004.
Between 50 and 70 % of the QC procedures are reported fully implemented –remainder are partly implemented for accredited labs, with 30% of procedures not implemented by the non-accredited labs.
PT 4 One accredited by IPAC
Two of the labs participated in FAPAS- EU PT6
Varied level of reported implementation, up to 100% for one lab. Others have implementation from 60 to 90%, with remaining % partially implemented.
SI 2 Accredited by SA FAPAS and EU PT6
At least 90% of the QC procedures reported fully implemented, the remainder partially.
SK 1 Accredited by SNAS
FAPAS and EU PT6
70% of the QC procedures reported fully implemented, the remainder partially.
31
Country
No. of laboratories
Accreditation Participation in proficiency tests
Implementation of EU Quality Control Procedures
(QC procedures)
FI 2 Accredited by FINAS
FAPAS and EU PT6
Between 60 and 80 % of the QC procedures reported fully implemented, the reminder partially.
SE 1 Accredited by SWEDAC
FAPAS and EU PT6
70 % of the QC procedures reported fully implemented, the remainder partially.
UK 3 Accredited by UKAS
FAPAS and EU PT6
All reported fully implemented
NO 1 Accredited by NA FAPAS and EU PT6
More than 80 % of the QC procedures reported fully implemented, the remainder partially.
IS 2 One laboratory is accredited by SWEDAC (performing 5% of analyses)
FAPAS Approx. 90% of the QC procedures reported fully implemented, 10% not implemented
LI 1 Accredited by DACH
Not reported At least 90 % of the QC procedures reported fully implemented, remainder partially.
