DISTRIBUTION PARTNERS FOR COSMETIC … · In Phase A, premix gum and glycerin and add to water. Mix...

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The information above is provided in good faith, is believed to be accurate but without warranty, implied or expressed. All formulations are provided as a starting pointfor lab scale projects only and results may vary due to procedure, raw material, and equipment variations. Reproducibility and scale-up must be carried out and confirmed by the customer. Gelest, Inc. makes no warranty, expressed or implied that the suggested use infringes on any patent. Preservative recommendations are not provided.

DISTRIBUTION PARTNERS FOR COSMETIC INGREDIENTS:

USA

CA SPECIALITIES LTD. PARADIGM SCIENCE INC. PO BOX 9 67 BEAVER AVENUE 712 WILSON STREET ANNANDALE, NJ 08801 CHESTER, SC 29706 Phone: 908-238-0204 Phone: 803-581-5800 Fax: 908-235-4209 Fax: 803-581-5802 Email: [email protected] Email: [email protected] Website: www.paradigmscience.com Website: www.ca-specialities.com

ROSS ORGANIC INC. 9770 BELL RANCH DRIVE SANTE FE SPRINGS, CA 90670 Phone: 562-236-5700 Fax: 562-236-5737 Email: [email protected] Website: www.rossorg.com

CANADA FRANCE & LUXEMBOURG

FORTE INGREDIENTS INC. PhDs – Dr. Hubert Plantefève 4 LONGHOPE PLACE 2 DOMAINE DE BRAMESCHHOF TORONTO, ON M2J 1Y2 8290 KEHLEN Phone: 647-344-1677 LUXEMBOURG Email: [email protected] Phone: 00352-661-51-33-62 Website: www.forteingredients.ca Email: [email protected] Website: www.phds-sourcing.com

KOREA JAPAN

SHINWOO ICT CO., LTD. AZMAX CO. LTD. #1907, DAERYUNG TECHNO TOWN 15 CHA, MATSUDA YAESUDORI, BLDG F8 224-5, GWANYANG-DONG, DONGAN-GU, 1-10-7 HATCHOUBORI, CHOU-KU ANYANG-SI, GYEONGGI-DO, KOREA 431-060 TOKYO 104-0032 Phone: 82-31-423-4545 Phone: 81-3-5543-1630 Fax: 82-31-423-4777 Fax: 81-3-5543-0312 Email: [email protected] Email: [email protected]

Website: www.azmax.co.jp

Copyright © 2014 Gelest, Inc.

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Table of Contents

SkinCare Moisturizer with Vertasil® TM-VE1 ............................................................................................................................4

Moisturizer with SPF and SiBrid® DE-12 .......................................................................................................................5

Dry Skin Cream (W/O) with SiBrid® DE-23 ...................................................................................................................6

Pomegranate Body Lotion with SiBrid® DiEthicones .....................................................................................................7

Cleansers After Shave Gel for Men with Vertasil® TM-L01 & SiBrid® DE-12 ...................................................................................8

Cleanser with Vertasil® VAN-07 ...................................................................................................................................9

Body Wash with SiBrid® DE-12 & SiQube® Q1850 ....................................................................................................... 10

Cleansing Milk with Vertasil® TM-L01 ........................................................................................................................ 11

Eyeshadows Frost Eye Shadow with SS Treated Pigments & SiBrid® DE-23 ..................................................................................... 12

Long Wearing Eye Shadow with SR Pigments & SiBrid® DE-23 .................................................................................... 13

Foundations Powder Cream Concealer with ML Pigments ............................................................................................................. 14

Satin Feel Foundation with SiBrid® DE-12 & SS Treated Pigments ............................................................................... 15

Velvety Concealer with Hydrosperse (HS) Pigments .................................................................................................. 16

Cucumber Smoothie Color Correcting Primer with Vertasil® TM-L01, SiBrid® DE12, & SiBrid® PM-212 .......................... 17

Gloss Lipstick with SiBrid® DE-15 & PM-212 ............................................................................................................... 18

Lipsticks Lipstick with SiBrid® TM-081 ..................................................................................................................................... 19

Super Shine Lip Gloss with SiBrid® PM-212 & TM-181 ................................................................................................ 20

Mascara & Eyeliners Eyeliner with Hydrosperse (HS) Pigments ................................................................................................................. 21

Waterproof Mascara with Super Durable (SR) Pigments ............................................................................................ 22

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Moisturizer with Vertasil® TM-VE1

Vertasil® TM-VE1, a unique hybrid fluid, is created by adding a small siloxane segment to vitamin E. In skin care, it provides a rich feel with softening and moisturizing properties.

INCI Name Ingredient Supplier Wt%

Phase A Water (Aqua) Deionized Water q.s. Carbomer Carbopol ®Ultrez 10 Lubrizol 0.20

Phase B

Butylene Glycol Polysorbate -60 Disodium EDTA

Tween™ 60

Croda

4.00 1.00 0.05

Water Tromethamine

Deionized Water Tris Amino®

Dow

3.00 1.00

Phase C Octyldodecyl Stearate Tocopheryloxypropyl Trisiloxane Stearic Acid Glyceryl Stearate Sorbitan Stearate

Phase D Water (Aqua) Preservative Fragrance

Ceraphyl® ODS Vertasil® TM- VE1 Emersol® 132 Cerasynt® SD Span™ 60

Deionized Water

ISP Gelest Emery ISP Croda

9.00 5.00 2.00 1.00 1.00

q.s. q.s. q.s.

Total 100

Procedure:

Combine Phase A and disperse until thickened while heating to 75OC.

Combine Phase B and add to Phase A.

Combine Phase C and heat to 80OC under a slow stir.

At 75OC, add Phase C to Phase AB and slowly homogenize until emulsified.

Continue to mix while cooling.

At 35OC, add Phase D and cool to RT while mixing. Rev 2 (07232013) FORMULA GCA2-98-1

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Moisturizer with SPF and SiBrid® DE-12

SiBrid® DiEthicone DE-12 fluid is a light emollient that is an exceptional vehicle for pigment wetting and dispersions. It is compatible with organic compounds, including sunscreens, and provides improved spreading and blending to formulations.


Phase A Polydiethylsiloxane

SiBrid® DE-12

Gelest

7.00

Titanium Dioxide Sunscreen Grade Titanium Dioxide 5.00 Phase B Water (Aqua) Deionized Water q.s. Magnesium Sulfate 0.20 Butylene Glycol 6.00 Preservatives q.s. Phase C Ethylhexyl Methoxycinnamate Escalol® 557 Ashland 7.50 Octyldodecyl Stearate Ceraphyl® ODS ISP/Ashland 5.10 PEG/PPG 10/1 Cetyl Dimethicone Abil® EM 90 Evonik 5.00 Myristyl Methicone AM-114 Gelest 2.50 Beeswax White Beeswax 1.00 Hydrogenated Castor Oil Castor Wax® MP80 Vertellus 0.50

Total 100

Procedure:

Disperse Phase A using a three roll mill.

Combine Phase C and heat to 85OC. Cool to 70OC while mixing.

Add Phase A to Phase C under slow homogenization.

Combine first two ingredients in Phase B and stir until dissolved.

Add remaining ingredients to Phase B and mix while heating Phase B to 70OC.

At 70OC, slowly add Phase B to Phase AC and homogenize until emulsified.

Mix for an additional 5 minutes while holding heat.

Cool to 30OC with paddle blade. Rev 2 (072313)

FORMULA GCA1-57-1

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Dry Skin Cream (W/O) with SiBrid® DE-23

SiBrid® DE-23 is a rich emollient that provides a rich, cushiony, and substantive feel to skincare products.


Phase A

Water (Aqua) Magnesium Sulfate Butylene Glycol Preservative

Deionized Water q.s. 0.2 6.0 q.s.

Phase B

Cyclopentasiloxane Polydiethylsiloxane PEG-9 Polymethylsiloxyethyl Dimethicone Cyclopentasiloxane (&) Dimethicone/Vinyl Dimethicone Crosspolymer

DC® 245 Fluid SiBrid® DE-23 KF 6038

USG 103

Dow Corning Gelest Shin-Etsu

Shin-Etsu

15.0 10.0

4.0

3.0

Phase E Laureth-7 Preservative

Rhodasurf ®L-7/90

Rhodia

0.5 q.s.

Total 100

Procedure:

Premix Phase A under propeller blade.

Combine Phase B and homogenize slowly until homogenous.

Premix Phase E and add to Phase B. Homogenization until blended.

Slowly add Phase A to Phase BC under slow homogenization.

Homogenize strongly for an additional 5 minutes. Rev 1 (03262013)

FORMULA GJH2-64-1

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Pomegranate Body Lotion with SiBrid® DiEthicones

As an emollient, SiBrid® DE-15 provides a non greasy, light, and breathable feel to skin care products and can be used to reduce the tackiness of natural oils in formulations. SiBrid® DE-12 is soluble in common skincare ingredients such as Caprylic/Capric Triglyceride and solubilizes Vitamin E completely into the oil phase.


Phase A Water (Aqua) Deionized Water q.s. Xanthan Gum Glycerin

Van Zan® RT Vanderbilt 0.20 2.00

Phase B Caprylic/ Capric Triglyceride Helianthus annuus (Sunflower) Seed Oil Polydiethylsiloxane Polydiethylsiloxane Tocopherol Laureth-7 Polyglyceryl-2 Sesquiisostearate

Phase C Ammonium Acryloydimethyltaurate/ VP Copolymer

Sunflower Oil

SiBrid ® DE-15 SiBrid ® DE-12 Vitamin E Rhodasurf®L-7/90 Hostacerin® DGI

Aristoflex®

Gelest Gelest DSM Rhodia Clariant

Clariant

5.00 4.00

3.00 0.50 0.50 1.50 2.50

0.80

Phase D Fragrance Preservative

Pomegranate 2300

Vanessence/ Paradigm Science

q.s.

q.s.

Total 100

Procedure:

In Phase A, premix gum and glycerin and add to water. Mix under high speed until gum is hydrated and dispersed.

Premix Phase B and slowly add to Phase A. Mix under high speed to emulsify.

Add Phase C and mix until thickened.

Add Phase D and mix until dispersed.

Adjust pH to 5.5 if necessary. Rev 1 (042514)

FORMULA LF2-089

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After Shave Gel for Men with Vertasil® TM-L01 & SiBrid® DE-12

Vertasil TM-L01 can be used as a cyclomethicone replacement and is especially effective when combined with SiBrid® DE-12 in products geared for men. The multiifunctional Vertasil TM-L01 siloxane base provides emolliency while the limone segment cleans and refreshes the skin.


Phase A Water (Aqua) Deionized Water q.s. Isopropyl Alcohol Carbomer Tetrasodium EDTA Populus tremuloides (Aspen) Bark Extract Lavendula angustifloria (Lavender) Flower Extract Calendula officinalis (Calendula) Extract Citrus limonum (Lemon) Peel Extract Thymus vulgaris (Thyme) Extract

Isopropanol Carbopol® 940

Lubrizol

10.00 0.3-0.50

0.10 0.40 0.50 0.50 0.50 0.50

Phase B Methylcyclohexenyl Isopropyl Trisiloxane Prunus Amygdalus Dulcis (Sweet Almond) Oil Sesamum Indicum (Sesame) Seed Oil Simmondsia Chinensis (Jojoba) Seed Oil Polglyceryl-3 Oleate Polydiethylsiloxane Tocopherol Bisabolol Olive Oil PEG-7 Esters Phase C Sodium Hydroxide Fragrance Blue 1 Red 40 Preservative Water (Aqua)

Vertasil® TM-L01

Caprol® 3GO Sibrid® DE-12 Vitamin E Olivem 300 Esters

NaOH (25% Soln) Burberry-Type FD&C Blue 1 Soln FD&C Red 40 Soln

Deionized Water

Gelest

Abitec Gelest DSM Hallstar

Emerald Emerald

4.00 3.00 3.00 3.00 1.90 1.00 0.50 0.25 0.10

q.s. q.s. q.s. q.s. q.s. q.s.

Total 100

Procedure:

In Phase A, premix water and isopropyl alcohol under propeller blade. Slowly add Carbomer and mix at 800-1000 rpm for 15 minutes or until hydrated. Add remainder of Phase A and continue mixing a 300 rpm.

Premix Phase B under propeller blade. Slowly add Phase B to Phase A and mix until emulsified at 800-1000rpm.

In Phase C, adjust Phase AB to pH of 5.5-6.0. Reduce speed to 400-600 rpm. In order, add remainder of Phase C to Phase AB and mix until dispersed and uniform.

Rev 1 (042114) FORMULA LF2-067

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Cleanser with Vertasil® VAN-07

Vertasil® VAN-07 is derived from the essential oil of tarragon and is tipped with a short emollient silicone tail. In a cleanser, it can replenish stripped oils leaving the skin feeling smooth and hydrated.


Phase A Water (Aqua) Deionized Water q.s. Carbomer Carbopol ®Ultrez 10 Lubrizol 0.20 Butylene Glycol Polysorbate 60 Disodium EDTA Water (Aqua) Tromethamine

Tween™ 60


Croda

Dow

4.00 1.00 0.05 3.00 1.00

Phase B Octyldodecyl Stearate Bis(Methoxyphenylpropyl)/ Butyl Dimethicone Stearic Acid Glyceryl Stearate Sorbitan Stearate

Ceraphyl® ODS Vertasil® VAN-07

Emersol® 132 Cerasynt® SD Span™ 60

ISP Gelest

Emery Ashland/ISP Croda

9.00 5.00

2.00 1.00 1.00

Phase C Fragrance Preservative Water (Aqua)

Body Wash 4167/2

Deionized Water

Vanessence/Paradigm

q.s.

q.s. q.s.

Total 100

Procedure:

Combine water and carbomer and heat to 75OC under homogenization.

Add the next three ingredients in order. Combine remaining ingredients and mix until clear. Add to batch and continue mixing.

Under propeller blade, heat Phase B to 80-85OC.

At 75OC, add Phase B to Phase A and slowly homogenize until emulsified and uniform.

Cool under mixing.

At 30OC, add Phase C and mix until dispersed. Rev 2 (07232013) FORMULA GCA2-99-1

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Body Wash with SiBrid® DE-12 & SiQube® Q1850

Add SiBrid® DE-12 DiEthicone to cleansers to produce a silky and hydrated afterfeel in products that strip the skin of natural oils. In bodywashes, SiQube® Q1850 acts as a conditioning agent that leaves a smooth feel on skin without the need to incorporate a large oil phase into the formula.


Phase A Water (Aqua) Deionized Water q.s. Acrylates Copolymer Carbopol® Aqua SF1 Lubrizol 8.50 Sodium Lauryl Sulfate Sodium Hydroxide Cocamidopropyl Betaine Phase B Glycerin Polysilsesquioxane Steardimonium Chloride

Stepanol® WA-EXTRA

Mirataine® BET C30

SiQube® Q1850

Stepan

Rhodia

Gelest

30.00 q.s.

10.00

2.50 0.25

Phase C Helianthus annuus (Sunflower) Seed Oil Polydiethylsiloxane

Sunflower Oil

SiBrid® DE-12

Gelest

2.00

1.00 Phase D Fragrance Preservative Citric Acid

Amber & Pomegranate 2300/2

Vanessence/ Paradigm Science

q.s.

q.s. q.s.

Sodium Chloride q.s.

Total 100

Procedure:

Mix water and copolymer under propeller blade until dispersed.

Add SLS and mix slowly until dispersed.

Adjust pH to 6.5-6.8 to thicken.

Add cocamidopropyl betaine and mix slowly.

Predisperse Phase B using shear. Add to Phase A and continue mixing.

Add Phase C to Phase AB and mix well.

In order, add Phase D ingredients and adjust pH to 5.5, if needed.

Add sodium chloride to thicken batch and mix well. Rev 2 (07232013)

FORMULA LF1-019

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Cleansing Milk with Vertasil® TM-L01 Vertasil® Limonenyl Trisiloxane TM-L01 is a hybrid fluid derived from Limonene, a natural solvent found in citrus rinds, and siloxane. In cleansers, toners, and in makeup removers, it can be used as multifunctional ingredient-- a “green” solvent and a cyclopentasiloxane (D5) replacement-- that will leave behind a non oily, yet soft and silky after feel.


Phase A Water (Aqua) Deionized Water q.s. Acrylates/C10-30 Alkyl Acrylates Crosspolymer

Carbopol ® Ultrez 20

Lubrizol 0.40

Sodium Hydroxide Propandiol Actives Phase B Methylcyclohexenyl Isopropyl Trisiloxane

Sodium Hydroxide Soln (25%) Zemea®

Vertasil® TM-L01

DuPont Tate & Lyle

Gelest

q.s. 2.00 q.s.

10.00 Isopropyl Myristate Tocopherol Polyglyceryl-3 Oleate Polysorbate 80

Liponate® IPM Vitamin E PGO-3 Tween™ 80

Lipo DSM Lipo Croda

5.00 0.75 2.00 0.50

Phase C Red 40 Fragrance Preservative Sodium Hydroxide Citric Acid Water (Aqua)

FD&C Red 40 in Water Grapefruit & Wheatgrass NaOH Solution (25%) Citric Acid Soln (25%) Deionized Water

Emerald The Lebermuth Co.

q.s.

0.40 0.50 q.s. q.s. q.s.

Total 100

Procedure:

Sift Carbopol onto surface of water and allow to hydrate. Mix under propeller blade until dispersed. Adjust pH to 5.5 to thicken. Continue to mix until uniform. Add remainder of Phase A.

Combine Phase B. Slowly add to Phase A and emulsify .

In order, add Phase C ingredients and adjust pH to 5.5 if needed. Rev 1 (041014)

FORMULA LF2-068

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Frost Eye Shadow with SS Treated Pigments & SiBrid® DE-23

The skin feel of eye shadow made with Stearyl Triethoxysilane (SS) treated pigments is exceptionally moist and soft. The long chain stearylsilane is effective in improving compressibility of pigments and pearls while improving skin adhesion.


Phase A Talc (&) Stearyl Triethoxysilane Titanium Dioxide (&) Stearyl Triethoxysilane

Talc SS Titanium Dioxide SS

Gelest Gelest

17.00 8.00

Manganese Violet (&) Stearyl Triethoxysilane Carmine (&) Stearyl Triethoxysilane (&) Methicone Zinc Stearate Nylon-12 Benzoic Acid Phase B Mica & Titanium Dioxide (&) Ferric Ferrocyanide (&) Stearyl Triethoxysilane

Manganese Violet SS

Carmine SS-H

Zinc Stearate 921-G Orgasol® 2002D

Cloisonne™ Violet SS surface treated

Gelest Gelest Brenntag Lipo BASF/Gelest

7.00

7.00

3.80 3.00 0.20

49.00

Phase C Polydiethylsiloxane

SiBrid® DE-23

Gelest

2.00

Octyldodecyl Stearate

Ceraphyl® ODS Ashland/ISP 2.00

Phase D Fluorophlogopite (&) Titanium Dioxide(&) (&) Stearyl Triethoxysilane

Sachet Sparkling White SS surface treated

Sandream/ Gelest

1.00

Total 100

Procedure: Combine Phase A and mix 3 x 15 seconds on high speed in an Osterizer blender.

Add Phase B and blend 2 x 15 seconds on low speed.

Premix Phase C. Dropwise, add to batch and mix 3 x 15 sec on low speed.

Add Phase D and blend 2 x 15 sec on low speed.

Press into pans. Rev 1 (03262013)

FORMULA LD2-68-1

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Long Wearing Eye Shadow with SR Pigments & SiBrid® DE-23

In eyeshadows, Polymethylsilsesquioxane (&) Trimethylsiloxysilicate (SR) treated pigments improve wear and skin adhesion due to low oil absorption and better H2O repellancy. SR treated pigments and pearls greatly increase compressibility of powders without increasing the tendency for glazing.


Phase A Mica (&) Polymethylsilsesquioxane (&) Trimethylsiloxysilicate

Iron Oxides (&) Polymethylsilsesquioxane (&) Trimethylsiloxysilicate

Sericite SR

Black Iron Oxide SR

Gelest

Gelest

30.0

4.0

Iron Oxides (&) Polymethylsilsesquioxane (&) Trimethylsiloxysilicate Iron Oxides (&) Polymethylsilsesquioxane (&) Trimethylsiloxysilicate Talc (&) Polymethylsilsesquioxane (&) Trimethylsiloxysilicate Zinc Stearate Nylon-12 Benzoic Acid Phase B Polydiethylsiloxane

Red Iron Oxide SR

Yellow Iron Oxide SR

Talc SR

Zinc Stearate 921-G Orgasol®2002D

SiBrid® DE-23

Gelest Gelest Gelest Brenntag Lipo Gelest

3.0

3.0

53.3

3.0 2.0 0.2

1.0 Octyldodecyl Stearate Ceraphyl® ODS Ashland/ISP 0.5

Total 100

Procedure:

Mix Phase A for 3 x 15 seconds on high speed .

Add Phase B and Mix for another 3 x 15 seconds.

Press into pans. Rev 1 (03262013)

FORMULA GCA1-75-1

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Powder Cream Concealer with ML Pigments Dimethicone PEG-3 Laurate (ML) treated pigments allow for higher pigment loading due to low oil absorption and excellent wetting properties. This high coverage formula applies like a cream, yet has the dry feel of a powder.


Phase A Ethylhexyl Palmitate Tribehenin

Ceraphy®l 368 Syncrowax™ HRC

Ashland/ISP Croda

12.04 4.50

C30-45 Alkyl Methicone AMS C-30 Dow Corning 4.50 C20-40 Alcohols Performacol™ 425 New Phase

Technologies 0.25

Benzoic Acid Ascorbyl Palmitate

0.10 0.05

Phase B

Ethylhexyl Palmitate Polyglyceryl-3 Diisostearate

Ceraphyl® 368 Cithrol™ PG3D2

Ashland/ISP Croda

20.60 1.00

Quaternium-18 Hectorite Bentone® 38V Elementis 0.20 Titanium Dioxide (&) Dimethicone PEG-3 Laurate

Titanium Dioxide ML Gelest 19.80

Iron Oxides (&) Dimethicone PEG-3 Laurate Iron Oxides (&) Dimethicone PEG-3 Laurate Iron Oxides (&) Dimethicone PEG-3 Laurate Talc (&) Dimethicone PEG-3 Laurate Mica (&) Dimethicone PEG-3 Laurate

Yellow Iron Oxide ML

Red Iron Oxide ML

Black Iron Oxide ML

Talc ML

Serecite ML

Gelest

Gelest

Gelest

Gelest

Gelest

2.52

0.84

0.18

18.62

15.00

Total 100

Procedure:

Combine Phase A and heat to 80OC under stirring.

Add Phase B and mix on three roll mill to disperse.

Reheat to 70OC and pour. Rev 1 (03262013) FORMULA LF1-029

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Satin Feel Foundation with SiBrid® DE-12 & SS Treated Pigments

Gelest’s Stearyl Triethoxysilane (SS) treated pigments and SiBrid® DE-12 promote easier spreading and blending on skin while providing an exceptionally soft and moist afterfeel to liquid foundations. SiBrid® DE-12 DiEthicone is an excellent vehicle for wetting and dispersing pigments.


Phase A Water (Aqua) Deionized Water 49.10 Magnesium Sulfate Phase B

0.20

Butylene Glycol Benzoic Acid

6.00 0.20

Phase C

Polydiethylsiloxane Sibrid® DE-12 Gelest 5.00 Cyclopentasiloxane Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone Cyclopentasiloxane & C30-45 Alkyl Cetearyl Dimethicone Crosspolymer

Phase D Laureth-7

DC 245 Fluid KF 6038

Velvesil 125

Rhodasurf L-7/90

Dow Corning Shin-Etsu

Momentive

Rhodia

5.00 3.00

10.00

0.50

Phase E Polydiethylsiloxane Titanium Dioxide (&) Stearyl Triethoxysilane Talc (&) Stearyl Triethoxysilane Iron Oxides (&) Stearyl Triethoxysilane Iron Oxides (&) Stearyl Triethoxysilane Iron Oxides (&) Stearyl Triethoxysilane

Sibrid® DE-12 Titanium Dioxide SS Talc SS Yellow Iron Oxide SS Red Iron Oxide SS Black Iron Oxide SS

Gelest Gelest Gelest Gelest Gelest Gelest

12.00

8.00 4.10 1.20 0.50 0.20

Total 100

Procedure: Mix Phase A under propeller blade. Premix Phase B while warming to dissolve.

Add Phase B to Phase A and stir. Premix first three ingredients in Phase C. When uniform, add remaining ingredient and slowly homogenize.

Add Phase D to Phase C and homogenize.

Premill Phase E. Add Phase E to Phase CD and homogenize until dispersed.

Add Phase AB to Phase CDE and continue homogenizing until emulsified.

Increase speed and homogenize for additional 5 minutes. Rev 2 (07232013)

FORMULA GCA2-22-1

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Velvety Concealer with Hydrosperse (HS) Pigments

In water based systems, Hydrosperse (HS) pigments disperse easily without high shear, develop fully in color and tinting strength, and show reduced color flotation.


Phase A Water (Aqua) Polysorbate 60 Magnesium Aluminum Silicate Sodium Lithium Magnesium Silicate Phase B

Deionized Water Tween™ 60 Veegum® Laponite® XLG

Croda RT Vanderbilt Rockwood

q.s. 0.10 0.70 0.30

Titanium Dioxide (&) Disodium Carboxyethyl Siliconate Iron Oxides (&) Disodium Carboxyethyl Siliconate Iron Oxides (&) Disodium Carboxyethyl Siliconate Iron Oxides (&) Disodium Carboxyethyl Siliconate Talc (&) Disodium Carboxyethyl Siliconate Phase C Butylene Glycol Cellulose Gum Polysorbate 60 Preservative Phase D Potassium Cetyl Phosphate Phase E Polydiethylsiloxane Ethylhexyl Palmitate Glyceryl Stearate Sorbitan Stearate Preservative

Titanium Dioxide HS Yellow Iron Oxide HS Red Iron Oxide HS Black Iron Oxide HS Talc HS

CMC7H3SF Tween™ 60

Amphisol® K

SiBrid® DE-12 Ceraphy® 368 Cerasynt® SD Span™ 60

Gelest Gelest Gelest Gelest Gelest

Aqualon Croda

DSM

Gelest ISP ISP Crods

16.00 1.60 0.60 0.16 1.64

6.00 0.10 0.40 q.s.

2.00

12.00 5.00 1.50 1.00 q.s.

Total 100

Procedure:

In order, add Phase A ingredients to water and homogenize while heating to 70OC.

Once hydrated, add Phase B and continue mixing.

In Phase C, premix butylene glycol and gum, add to Phase AB, and homogenize. Add remainder of Phase C to Phase ABC.

Slowly mix Phase D into batch until dissolved and continue homogenization at 80

OC. Combine Phase E and heat to 80

OC. Slowly add Phase E to Phase ABCD.

Homogenize for 15 minutes at 80OC. Cool under mixing to 30

OC.

Rev 1 (03262013)

FORMULA GCA2-35-1

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Cucumber Smoothie Color Correcting Primer with Vertasil® TM-L01, SiBrid® DE12, & SiBrid® PM-212

Banish embarrassing facial redness and and soften those worry lines and wrinkles over your cyclopentasiloxane (D5) concerns. Gelest’s Limoneyltrisiloxane, Vertasil® TML-01, as used in this Cucumber Smoothie Primer, can provide similar light weight, non oily feel during application with more substantive and silkier after feel than cyclopenasiloxane. This primer can be used alone as a soft focus and color correcting serum or as a primer under makeup.


Phase A Dimethicone/Vinyl Dimethicone Crosspolymer Polydiethylsiloxane Methylcyclohexenyl Isopropyl Trisiloxane Lauryl Phenylpropyl Methicone Tocopherol Actives

Sibrid® DE12 Vertasil® TM-L01 Sibrid®PM-212 Vitamin E

Gelest Gelest

Gelest DSM

q.s.

15.00 15.00

2.00 1.00 q.s.

Phase B

Polydiethylsiloxane Chromium Oxide Green (&) Stearyl Methicone Phase C Mica (&) Titanium Dioxide (&) Iron Oxides (&) Stearyl Methicone Nylon-12 (&) Sodium Hylauronate Methyl Methacrylate Crosspolymer Fragrance Preservative

SiBrid® DE-12 Chromium Oxide Green SS

SpectraFlex® Soft Focus Gold SS Orgasol® Hydra

Cucumber & Green Tea

Gelest Gelest

Gelest/ Sun Chemical Lipo

The Lebermuth Co

1.00 0.10

2.50

2.50 2.50 0.20

q.s.

Total 100

Procedure:

Mix Phase A under propeller blade.

Predisperse Phase B. Add Phase B to Phase A and mix until uniform.

In order, add Phase C to Phase AB and mix until dispersed and uniform.

Rev 1(041414)

FORMULA LF-080

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Gloss Lipstick with SiBrid® DE-15 & PM-212

In lipstick applications, with its high refractive index, SiBrid® PM-212 creates gloss without excessive tack and helps to prevent feathering, while SiBrid® DE-15 DiEthicone provides slip and glide.


Phase A Pigment Castor Oil Phase B Triisostearyl Citrate

Crystal®O Schercemol® TISC

Vertellus

Lubrizol

10.2 9.0

20.0 Polydiethylsiloxane SiBrid® DE-15 Gelest 10.0 Laurylphenylpropyl Methicone Octyldodecanol Castor Oil Euphoria Cerifera (Candelilla) Wax Microcrystalline Wax Ozokerite Copernicia Cerifera (Carnauba)Wax Preservatives

SiBrid® PM-212 Eutanol® G Crystal ®O Candelilla Wax, Refined

Microcrystalline Wax SP19 Ozokerite 170D Carnauba Wax #1

Gelest BASF/Cognis Vertellus Frank B. Ross

Strahl & Pitsch Frank B. Ross Strahl & Pitsch

10.0 10.0

8.5 7.0

3.5 2.0 1.5

q.s.

Phase C Mica (&) Titanium Dioxide (&) Silica (&) Stearyl Triethoxysilane Antioxidants

SS Treated Timiron® Splendid Red

Gelest/EMD

8.0 8.00

q.s.

Total 100

Procedure:

Disperse Phase A using a roller mill.

Combine Phase B and heat to 80-85OC under propeller blade.

Once Phase B is melted, add Phase A and mix for 45 minutes or until dispersed. Add Phase C and stir until dispersed.

Cool under propeller blade to 70-75OC. Pour into mold. Rev 2 (07232013)

FORMULA GCA1-83-1

P a g e | 19


Lipstick with SiBrid® TM-081

In lipsticks, SiBrid® TM-081 helps to achieve a lighter, more comfortable feel in addition to creating initial slip and improving glide on application.


Phase A Pigment Castor Oil Phase B Triisostearyl Citrate

Crystal® O Schercemol® TISC

Vertellus

Lubrizol

7.50 7.50

37.80 Octyldodecyl Stearate Euphoria Cerifera (Candelilla) Wax Castor Oil Caprylyl Methicone Microcrystalline Wax Ozokerite Antioxidants Preservatives Phase C Mica

Ceraphyl®ODS Candelilla Wax

Crystal®O SiBrid® TM-081 Microcrystalline Wax SP19 Ozokerite 170D

Ashland/ISP Frank B. Ross

Vertellus Gelest Strahl & Pitsch Frank B. Ross

10.80 7.60

6.70 5.40 3.80 2.15

q.s. q.s.

8.00

Total 100

Procedure:

Disperse Phase A using a roller mill.

Combine Phase B and heat to 80OC. Once melted, slowly stir under propeller blade.

Add Phase A and continue stirring for 45 minutes or until dispersed.

Add Phase C and stir until dispersed and desired pouring temperature is reached.

Pour into mold.

Rev 1 (03262013)

FORMULA GCA1-19-3

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Super Shine Lip Gloss with SiBrid® PM-212 & TM-181

In lip products, SiBrid® PM-212 provides shine while ensuring comfortable wear. The addition of SiBrid® TM-181 gels the oil to suspend pigments while providing a rich and substantive feel.


Phase A Triisostearyl Citrate Schercemol® TISC Lubrizol q.s. Laurylphenylpropyl Methicone SiBrid® PM-212 Gelest 20.00 Stearyl Methicone Preservatives Phase B Red 7 Lake/CI 15850 in Polydiethylsiloxane Phase C Mica (&) Titanium Dioxide (&) Silica (&) Stearyl Triethoxysilane

SiBrid® TM-181

SiBrid® DE-15

SS Treated Pearl

Gelest

Gelest

Gelest/EMD

5.00 q.s.

q.s. q.s.

0.50

Total 100

Procedure:

Disperse Phase B using a roller mill.

Combine Phase A and stir under propeller.

Add Phase B and continue stirring until dispersed.

Add Phase C and stir until dispersed and uniform . Rev 2 (07232013)

FORMULA GJH2-48-1

P a g e | 21


Eyeliner with Hydrosperse (HS) Pigments

Gelest’s Hydrosperse(HS) surface treated pigments disperse without milling to give fine pigment particle size and full color development.


Phase A Water (Aqua) Deionized Water 69.49 Butylene Glycol Preservative Phase B Water Tromethamine Phase C


Dow

6.00 0.30

4.00 1.00

Shellac

Mantrose-Haeuser 1.00

Phase D Hydroxyethylcellulose

Natrosol ™250 MR

Hercules

0.50

Phase E Iron Oxides (&)Disodium CarboxyethylSiliconate

Black Iron Oxide HS

Gelest

10.00

Phase F Cera Alba Cetyl Alcohol Sorbitan Stearate Copernica Cerifera (Carnauba) Wax Hydrogenated Polyisobutene Preservative Phase G Preservative Water (Aqua)

White Beeswax Alfol™ 16 Span™ 60 Carnauba Wax Panalane® H-300E

Deionized Water

Sasol Croda

Lipo

4.00 1.25 1.00 0.50 0.50 0.10

q.s. q.s.

Total 100

Procedure: Combine Phase F and heat to 85-90

OC. Combine Phase A and heat to 50

OC. Premix

Phase B and add to Phase A. Add Phase C to Phase AB and stir slowly until dissolved.

Add Phase D to Phase ABC and homogenize while increasing heat to 80OC.

At 80OC, add Phase E to Phase ABCD and heat to 85-90

OC while homogenizing.

When Phase ABCDE and Phase F reach 85-90OC, add Phase F to Phases ABCDE

under homogenization. Hold temperature and mix for additional 15 minutes. Cool to 45

OC and add Phase G. Continue to cool to 30

OC.

Rev 1 (03262013)

FORMULA GCA2-40-2

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Waterproof Mascara with Super Durable (SR) Pigments

Super Durable (SR) surface treated pigments increase water resistance and adhesion to lashes while reducing smudging.


Phase A Isododecane Permethyl ® 99A Presperse 23.05 Polyethylene A-C® Polyethylene 6A Honeywell 11.00 Euphoria Cerifera (Candelilla) Wax Candelilla Wax Frank B. Ross 4.50 Polyglycerol-3 Diisostearate Prisorine™ 3700 Croda 0.25 Benzoic acid

0.20

Phase B Pentaerythrityl Rosinate Hercules 2.00 Isododecane Permethyl Fluid 99A Presperse 2.00 Phase C Zinc Stearate Silica Silylate Phase D Isododecane Iron Oxide (&) Polymethyl silsesquioxane (&) Trimethylsiloxysilicate Phase E Petroleum Distillates & Distearyldimonium Hectorite

Zinc Stearate 921-G SIS6962.1M20

Permethyl® 99A Black Iron Oxide SR

Bentone Gel® SS-71

Brenntag Gelest

Presperse Gelest

Elementis

1.00 12.00

8.00 12.00

35.00

Total 100

Procedure:

Combine Phase B in a closed vessel and stir slowly until uniform.

Combine Phase D and mill using high shear agitation.

Combine Phase A in a closed vessel. Heat to 95OC with stirrring until clear.

Add Phase B with stirring.

Add Phase C and homogenize until dispersed.

Add Phase D and homogenize until dispersed.

Add Phase E and homogenize until dispersed.

Stir with sidesweep agaiation while cooling to 30OC. Rev 1 (03262013)

FORMULA GCA1-83-1

P a g e | 23


Additional Gelest Literature

Gelest 5000-A Silicon Compounds: Silanes & Silicones Detailed chemical properties and reference articles for over 1500 compounds. The 608 page catalog of silane and silicone chemistry includes scholarly reviews as well as detailed application information

Reactive Silicones – Forging New Polymer Links The 60 pages brochure describes reactive silicones that can be formulated into coatings, membranes, cured rubbers and adhesives for mechanical, optical, electronic and ceramic applications. Information on reactions and cures of silicones as well as physical properties shortens product development time for chemists and engineers.

Silicone Fluids – Stable Inert Media Design and Engineering properties for conventional silicone fluids as well as thermal. Fluorosilicone, hydrophilic and low temperature grades are presented in a 24 page selection guide. The brochure provides data on thermal, rheological, electrical, mechanical and optical properties for silicones. Silicone fluids are available in viscosities ranging from 0.65 to 2,500,000 cSt.

For additional product information on Gelest’s PCS Technology:

24 | P a g e


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