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Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU...

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Page 1: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.
Page 2: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Dr. Walter R. Mirabella – LyondellBasell Industries

Page 3: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.
Page 4: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Bio-Fuels “Supply Chains”

Bio-Mass

Bio-Oil Bio-Ethanol

Bio-Esters Bio-HCs

Diesel Petrol

Bio-Ethers

ORIGIN

DIRECT

DERIVED

FUEL

Page 5: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Fuel-Ethers Manufacturing

Alcohols

Ethers

Olefins

Page 6: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

ALGECIRAS 54 BILBAO 74 HUELVA 50 LA CORUNA 52 PUERTOLLANO 67 TARRAGONA a 54 TARRAGONA b 71

DUNKERQUE 65 FEYZIN 84 FEYZIN 56 FOS SUR MER 612 GONFREVILLE 75

PLOCK 120 PLOCK b 204

ASPROPYRGOS 65 ASPROPYRGOS 128 CORINTH 45

PORVOO 115 PORVOO 110

FAWLEY 122 GRIMSBY 100 KILLINGHOLME 82

GELA 45 GELA 55 MILAZZO 65 PRIOLO 41 RAVENNA 150 SANNAZZARO 41 SARROCH 237

COLOGNE 31 HEIDE 12 KARLSRUHE 163 MARL 250 SCHWEDT 385 SCHWEDT 160 VOHBURG 37 WESSELING 65

BOTLEK 591 EUROPORT 98 GELEEN 138 PERNIS 153

STENUNGSUND 50

MAZYR 106 NOVOPOLOTSK 41

BOURGAS 82

KRALUPY 92

SZAZHALOMBATTA a 55 SZAZHALOMBATTA b 53 TISZAUJVAROS 31

MAZEIKIAI 80

MIDIA 35 ONESTI 100 PITESTI 40 PLOIESTI a 20 PLOIESTI b 25 PLOIESTI ??

NOVI SAD 35

BRATISLAVA 52

KREMENCHUG 24

SINES 50

ANTWERP a 183 ANTWERP b 270

SCHWECHAT 65

SISAK 24

MTBE ETBE TAME

European Fuel-Ethers Production Capacities 2010 (KT/Y)

Planned TAEE

Page 7: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

EU & Fuels: Relative Positioning

Primary Refining Capacity

Domestic Petrol Consumption

Domestic Diesel Consumption

Biodiesel Production Capacity

Fuel-Ethers Production Capacity

1° 2° 3° 4° 5° 6° 7° 8° 9° 10° 11° 12° 13° AUSTRIA GERMANY FRANCE UK SPAIN NETHER. BELGIUM SWEDEN GREECE PORTUG. FINLAND DENMARK ITALY

GERMANY ITALY FRANCE UK SPAIN NETHER. GREECE FINLAND AUSTRIA POLAND SWEDEN CZECH R. DENMARK

GERMANY ITALY FRANCE UK SPAIN NETHER. PORTUG. AUSTRIA POLAND SWEDEN CZECH R. BELGIUM IRELAND

GERMANY ITALY FRANCE UK SPAIN NETHER. FINLAND POLAND BELGIUM GREECE ROMANIA BELARUS HUNGARY

GERMANY ITALY FRANCE UK SPAIN NETHER. PORTUG. AUSTRIA POLAND SWEDEN BELGIUM GREECE BULGARIA ITALY

ITALY

Page 8: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Sarroch

Sannazzaro Ravenna

Gela

Milazzo

Priolo Refinery Fuel-Ethers Production 41 45

65

150

237

41

45

Page 9: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

LyondellBasell ETBE Production Capacity (KT/Y)

CHANNELVIEW FOS SUR MER BOTLEK

USA EU

TEXAS FRANCE NETHERLANDS

1300 700 660 650

TOTAL ETBE PRODUCTION CAPACITY = 3310 KT/Y TOTAL ETHANOL-EQUIVALENT = 1492 KT/Y

Page 10: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

ETBE: Further Enhancing ETOH Performances

Page 11: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

COPERT 2010: VOC Reductions with ETBE

Source: Emissions and Health Unit - Institute of Environment and Sustainability - EC-JRC Ispra “An assessment of the impact of ethanol-blended petrol on the total NMVOC emissions from road transport in selected countries”

EU-5, ΔVOC(ETBE-ETOH) = 26593 T/Y

Page 12: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.
Page 13: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

ETBE Reduces CO2 Emissions

HART July 2007 CE-Delft October 2007 IFEU August 2008

“Best results by far are obtained when ethanol is converted to bio-

ETBE. The use of ETBE can allow the saving of 4 times the primary energy required to produce its

fossil alternative. IFEU recommends to exploit the

whole potential of bio-ETBE”

“The use of bio-ETBE reduces refining crude-oil need and

processing intensity, requires less fuel and, implying relevant petrol composition changes, allows the reduction of carbon factor and

lesser CO2 emissions”

“This study indicated that, when bio-ETBE is used, the resulting

modification of refinery operations determine a significant reduction of greenhouse gases emissions”

Page 14: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

RED: Renewable Energy Share Mandatory National Targets 2020

EU ≥ 20 % Spain ≥ 20 %

France ≥ 23 %

Germany ≥ 18 %

Italy ≥ 17 %

UK ≥ 15 %

Netherlands ≥ 14 %

Minimum renewable energy share target by 2020 in transport = 10%

Page 15: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

RED: Renewable Energy Share Indicative Trajectory

5.2%

7.6% 8.7%

10.5% 12.9%

17%

Minimum renewable energy share target by 2020 in transport = 10%

Page 16: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Directive 2009/28/EC - 23 April 2009 on the Promotion of the Use of Energy from Renewable Sources (Quote 1)

Page 17: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Directive 2009/28/EC - 23 April 2009 on the Promotion of the Use of Energy from Renewable Sources (Quote 2)

Page 18: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Directive 2009/28/EC - 23 April 2009 on the Promotion of the Use of Energy from Renewable Sources (Quote 3)

Page 19: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

FQD: GHGs Emissions Reduction Targets - Fuels

Bio-Fuels Alternative Fuels

Reductions Flaring/Venting at Production

Carbon Capture & Storage (CCS) Electric Vehicles

Credits Purchasing (Clean Development Mechanism - CDM) 2%

2%

6%

Page 20: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Bio-Ethanol (equivalent) for Petrol: Italy 2010

National Law Mandatory Blending (3% e/e in 2010)

KT/

Y

Ethanol Equivalent to Current Italian Domestic Ethers Production Capacity

Ethanol Equivalent to Current Ethers Import into Italy

Page 21: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

Overcoming Barriers to Bio-Fuels Market Development

•  Clear and consistent legislation

•  Policies harmonisation

•  Open market

•  Technology neutrality

•  Preserving flexibility

•  Product portfolio

Page 22: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

2nd generation bio-ethanol greatly reduces CO2 impact; by conversion into ethers it can synergistically, and significantly, increase, even further, petrol global GHGs emission performance.

Bio-ethanol ethers would, in addition, improve bio-ethanol technical performances and fungibility into engines and

Page 23: Dr. Walter R. Mirabella...ETBE Reduces CO 2 Emissions HART July 2007 CE-Delft October 2007 IFEU August 2008 “Best results by far are obtained when ethanol is converted to bio-ETBE.

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