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AFWAL-TR-83-2048 (ESL-TR-83-65) FUEL EFFECTS ON GAS TURBINE ENGINE COMBUSTION R. ERNST, D. ANDREADIS PRATT & WHITNEY AIRCRAFT GOVERNMENT PRODUCTS DIVISION UNITED TECHNOLOGIES CORPORATION P 0 BOX 2691 WEST PALM BEACH, FLORIDA 33402 M JUNE 1983 FINAL REPORT FOR PERIOD 31 SEPTEMBER 1981 - 1 JANUARY 1983 4. APPROVED FOR PUBLIC RELEASE; DISTRIBUTION UNLIMITED A' AERO PROPULSION LABORATORY LU AIR FORCE WRIGHT AERONAUTICAL LABORATORIES S.. AIR FORCE SYSTEMS COMMAND L" WRIGHT-PATTERSON AIR FORCE BASE, OHIO 45433 64 '*I , ° ' " . " , ' *o "I "m " . , ° -• " ' - ° -" . -" ." - " ." . °
Transcript
Page 1: Effect of fuel gas to GT

AFWAL-TR-83-2048

(ESL-TR-83-65)

FUEL EFFECTS ON GAS TURBINE ENGINE COMBUSTION

R. ERNST, D. ANDREADIS

PRATT & WHITNEY AIRCRAFTGOVERNMENT PRODUCTS DIVISIONUNITED TECHNOLOGIES CORPORATIONP 0 BOX 2691WEST PALM BEACH, FLORIDA 33402

M JUNE 1983

FINAL REPORT FOR PERIOD 31 SEPTEMBER 1981 - 1 JANUARY 1983

4.APPROVED FOR PUBLIC RELEASE; DISTRIBUTION UNLIMITED

A'

AERO PROPULSION LABORATORY

LU AIR FORCE WRIGHT AERONAUTICAL LABORATORIESS.. AIR FORCE SYSTEMS COMMAND

L" WRIGHT-PATTERSON AIR FORCE BASE, OHIO 45433

64'*I , ° ' " . " , ' *o "I "m " . , ° -•

"

' -°

- " . - " . " - " . " . °

Page 2: Effect of fuel gas to GT

NOTICE

When Government drawings, specifications, or other data are used for anypurpose other than in connection with a definitely related Government procure-ment operation, the United States Government thereby incurs no responsibilitynor any obligation whatsoever; and the fact that the government may have formu-lated, furnished, or in any way supplied the said drawings, specifications, orother data, is not to be regarded by implication or otherwise as in any mannerlicensing the holder or any other person or corporation, or conveying any rightsor permission to manufacture use, or sell any patented invention that may in anyway be related thereto.

This report has been reviewed by the Office of Public Affairs (ASD/PA) andis releaseable to the National Technical Information Service (NTIS). At NTIS,it will be available to the general public, including foreign nations.

This technical report has been reviewed and is approved for publication.

S* . UTRUD, Project Engineer ARTHUR V. CHURCHILL, Chief

Fue s Branch Fuels Branch

Fuels and Lubrication Division Fuels and Lubrication Division

FOR THE CC.,tIANDER

.' BENITO P. BOTTERI, Assistant Chief

Fuels and Lubrication DivisionAero Propulsion Laboratory

"If your address has changed, if you wish to be removed from our mailing list,or if the addressee is no longer employed by your organization please notify

*AFWAL/POSF, W-PAFB OH 45433 to help us maintain a current mailing list".

Copies of this report should not be returned unless return is required bysecurity considerations, contractual obligations, or notice on a specificdocument.

4'%P.% %

Page 3: Effect of fuel gas to GT

UNCLASSIFIEDSECURITY CLASSIFICATION OF THIS PAGE (When DateFntered),

II&AEITATflLIREAD INSTRUCTIONSREPORT DOCUM NTATION PAGE RE COMPLETIORMum.7 naua~.'BEFORE COMPLETING FORM

I. REPORT NUMBER 2 .2 GOVT ACCESSION NO. 3. RECIPIENT'S CATALOG NUMBER

AFWAL-TR-83-2048, ESL-TR-&3-65 3 1

4. TIfLE (and Subtitle) S. TYPE OF REPORT & PERIOD COVERED

FUEL EFFECTS ON GAS TURBINE Final Report for PeriodENGINE COMBUSTION 3] Sep8l - 1 Jan R3

6. IfRFORMING OG. REPORT NUMBER

P#WA/GPD-FR-166167. AUTHOR(s) S7 ONTRACT OR GRANT NUMBER(s)

R. C. Ernst F33615-81-C-2092D. Andreadis

9. PERFORMING ORGANIZATION NAME AND ADDRESS 10. PROGRAM ELEMENT. PROJECT. TASK

Pratt & Whitney Aircraft AREA & WORK UNIT NUMBERS

, Government Products Division PE 62203FP. 0. Box 2691 Project No. 3048, Task 304805West Palm Beach, FL 33402 Work Unit 30480521

II. CONTROLLING OFFICE NAME AND ADDRESS 12. REPORT DATE

Aero Propulsion Laboratory (AFWAL/POSF) June 1983AF Wright Aeronautical Laboratories (AFSC) 3. NUMBER OF PAGES

Wright-Patterson AFB, OH 45433 7814. MONITORING AGENCY NAME & ADDRESS(It different from Controlling Office) IS. SECURITY CLASS. (ofthis report)

-UNCLASSIFIED

)So. DECL ASSIFICATIONDOWN GRADING

SCHEDULE

16. DISTRIBUTION STATEMENT (of this" Report)

Approved for public release; distribution unlimited.

S. ;17. DISTRIBUTION STATEMENT (of the abstract entered in Block 20, if different from Report)

a, IS. SUPPLEMENTARY NOTES

-Additional funding was received from the Engineering Sciences Branch, Engineering Services Labo-

ratory, HQ Air Force Engineering Services, Tyndall Air Force Base.

*, , 19. KEY WORDS (Continue on reverse aide it recessary and identity by block number)

Atomization, vaporization, statistical analysis, pressure-atomizing and air-blast nozzles, hydrogencontent, fuel droplet size, multicyclic aromatics, sensitivity, fuel property effects, rig data.

20 ABSTRACT (Continue on reverse side It necessary and Identify by block number)

The objective of this study was to develop and/or improve correlations of fuel properties andengine design with combustion performance and hot section durability. The data base consistedprimarily of fuel effect data obtained over the past four years under a number of DoD contracts.

DD JAN73 1473 EDITION OF I NOV 65 IS OBSOLETE UNCLASSIFIEDSECURITY CLASSIFICATION OF THIS PAGE (When Dete Entered)

. ,a",.. . . . .".". . " . . " ' ' " °• • - . . ' ". . - .,%-S'S. . . ' *. ,3 V . .• - , . * , " -. . . . - - . . , . , . " , . , , , , . " .

Page 4: Effect of fuel gas to GT

!-'- '~-0. UNCLASSIFIED

sECURITY CLASSIFV *TIO OF THIS PAGE(Whmn Da*a Enaeid)

Z*h aprahtknwsTtifrt eeo fuel effect correlations for specific combustor configura-tions, then to tie together these correlations using engine design parameters; thereby allowingprediction of fuel effects in any current or future aircraft gas turbine combustion system. In mostcases statistical analysis was used to identify the correlating variables. The relationships developed

- for individual combustors were then correlated with combustor design and operating parametersthat were influenced by fuel differences.

UNCLASSIFIEDSECURITY CLASSIFICATION OF 'rule PAGE(WItan Date Enterod)

Page 5: Effect of fuel gas to GT

FOREWORD

This final technical report was prepared by United Technologies Corporation, Pratt &Whitney Aircraft (P&WA), Government Products Division (GPD) under Contract F33615-81-C-2092 for the Air Force Wright Aeronautical Laboratories/Aero Propulsion Laboratory, Wright-Patterson Air Force Base, Ohio. The report documents work conducted during the period

21 September 1981 through 1 January 1983. Mr. T. A. Jackson was the Air Force ProgramMonitor through May 1982 and Mr. J. S. Stutrud was the Air Force Program Monitor throughthe remainder of the program. Mr. R. C. Ernst was the P&WA Program Manager.

The authors wish to acknowledge the contributions of S. A. Mosier, Fuels Technology

Manager and A. I. Masters, Head of Fuel Technology for their guidance and technicalcontributions.

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Page 6: Effect of fuel gas to GT

CONTENTS

Section pae

I SUMMARY ........................................................................... 1

II INTRODUCTION ..................................................................... 3

III FUEL EFFECTS CORRELATIONS ........................................... 5

A. Fuel Property Correlation Approach ................................... 5

B. Altitude Ignition Limits ................................................... 5

1. Pressure Atomizing Nozzles .......................................... 7

2. Airblast Nozzles ......................................................... 83. Combustor Altitude Ignition Correlations ........................ 8

C. Groundstart, Combustion Efficiency, Pattern Factor andLean Blowout ............................................................... 9

D. Smoke and Radiation ..................................................... 15,.

1. Smoke .................................................................... 152. Solid Particulates ...................................................... 203. Radiation and Combustor Liner Temperature .................. 20

IV ENGINE DESIGN AND OPERATING CHARACTERISTICSCORRELATIONS ..................................................................... 53

A. Altitude Relight Correlations ............................................ 53B. Combustion Efficiency Correlations .................................... 59C. Groundstarting Correlations .............................................. 63D. Combustor Pattern Factor Analysis .................................... 67E. Smoke Emissions ............................................................ 70F. Combustor Liner Metal Temperatures ................................. 73

V CONCLUSIONS AND RECOMMENDATIONS ............................. 76

REFERENCES ......................................................................... 78

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Page 7: Effect of fuel gas to GT

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LIST OF ILLUSTRATIONS

1 Relationship of TF30 Combustor Operating Parameter to FuelCharacteristic Parameter ............................................................ 21

,.

2 Effect of Combustor Operating Parameter on TF30 Relight Altitude .. 21

3 Relationship of TF33 Combustor Operating Parameter to FuelCharacterization Parameters ....................................................... 22

4 Effect of Combustor Operating Parameter on TF33 Relight Altitude .. 22

5 Relationship of F100 Combustor Operating Parameter to Fuel* Characteristic Parameter ............................................................. 23

6a Effect of Combustor Operating Parameter on F100 Altitude Relight ... 24

6b Effect of Combustor Operating Parameter on F100 Altitude Relight ... 24

6c Effect of Combustor Operating Parameter on F100 Altitude Relight ... 24

7 Relationship of Combustor Operating Parameter to Fuel CharacteristicParameter - F101 ................................................................... 25

8 Relationship of Combustor Operating Parameter to Fuel CharacteristicParameter - J79-17C ............................................................... 25

9 F100 Groundstart Data Correlation ............................................... 26

10 TF33 Groundstart Data Correlation ............................................. 27

11 TF30 Groundstart Data Correlation .............................................. 2

12 F101 Groundstart Data Correlation ............................................... 29

13 J79-17C Groundstart Data Correlation (3.18 kg/s Air Flow) .............. 30

14 TF41 Groundstart Data Correlation (0.79 kg/s Air Flow) .................. 31

15 F100 Combustion Efficiency at Idle ............................................. 32

16 TF33 Combustion Efficiency at Idle ............................................ 32

17 TF30 Combustion Efficiency at Idle ............................................ 33

18 FI01 Combustion Efficiency at Idle ............................................. 33

19 J79-17C Combustion Efficiency at Idle .......................................... 34

20 TF41 Combustion Efficiency at Idle ............................................ 34

vi

Page 8: Effect of fuel gas to GT

LIST OF ILLUSTRATIONS (Continued)

Figure Page

21 F100 Pattern Factor at SLTO ..................................................... 35

22 TF33 Pattern Factor at SLTO .................................................... 35

23 TF30 Pattern Factor at SLTO .................................................... 36

24 J79-17C Pattern Factor at SLTO ................................................ 36

25 F101 Pattern Factor at SLTO ..................................................... 37

26 TF41 Pattern Factor at SLTO ................................... 37

27 Effect of Vaporization Index on J79-17C Lean Blowout Fuel-Air Ratio 38

28 Effect of Vaporization Index on TF33 Lean Blowout Fuel-Air Ratio ... 38

29 Smoke Point vs Hydrogen Content for the F100, TF33, F101, andJ79-17C Test Fuels ................................................................... 39

30 F100 Smoke Number/Fuel Property Correlation ............................. 40

31 TF33 Smoke Number/Fuel Property Correlation ............................ 41

32 TF30 Smoke Number Correlation ................................................. 42

33 F101 Smoke Number/Fuel Property Correlation ............................. 43

34 J79-17C Smoke Number/Fuel Property Correlation ......................... 44

35 TF41 Smoke Number/Fuel Property Correlation ............................ 45

36 Correlation of Particulate Concentration With SAE Smoke Number ... 46

37 F100 Liner Temperature Correlation ............................................ 47

38 TF33 Liner Temperature Correlation ............................................ 48

39 TF30 Liner Temperature Correlation ........................................... 49

40 F101 Liner Temperature Correlation ............................................ 50

41 J79-17C Liner Temperature Correlation ........................................ 51

42 TF41 Liner Temperature Correlation ........................................... 52

43 Basic Altitude Relight Correlation With J79-17C Data ..................... 55

44 TF30 Altitude Relight Correlation ............................................... 56

vii

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Page 9: Effect of fuel gas to GT

.. -r. 7 w q 2 . 6.

UST OF ILLUSTRATIONS (Continued)

Figure Page

45 TF33 Altitude Relight Correlation ............................................... 56

46 Pressure Atomizing Fuel Nozzle Altitude Relight Correlation ............. 57

47 Airblast Fuel Nozzle Altitude Relight Correlation ............................ 58

48 Evaluation of Fuel Effects on Altitude Relight Performance .............. 60

49 Idle Combustion Efficiency vs Vaporization Index ..................... 61

50 Idle Combustion Efficiency Sensitivity vs Engine Correlation Parameter 63

51 Groundstart Correlation at Two Values of Vaporization Index ........... 65

4' 52 Sensitivity of Groundstart Fuel-Air Ratio to Vaporization Index ........ 66

53 Pattern Factor Correlations vs Vaporization Index .......................... 68

54 Pattern Factor Sensitivity vs Base Pattern Factor ........................... 69

55 Smoke Number vs Hydrogen Content Correlation Results ................. 71

56 Smoke Number Fuel Sensitivity vs Base Value of Smoke Number ..... 72

V 57 Liner Severity Parameter vs Hydrogen Percentage at SLTO ............. 74

58 Liner Severity Parameter at 14.5% Hydrogen ................................ 75

vi

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Page 10: Effect of fuel gas to GT

UST OF TABLES

Table Page

1 Correlation of Fuel Effects ......................................................... 1

2 Fuel Properties and Correlating Parameters .................................. 10

3 Groundstart Data Correlations (Single Variable Linear RegressionSummary Coefficient of Determination r2) ..................................... 11

4 Combustion Efficiency at Idle (Single Variable Linear RegressionSummary Coefficient of Determination r2) ..................................... 12

5 Pattern Factor at SLTO (Single Variable Linear Regression SummaryCoefficient of Determination r 2) ................................................... 12

6 Combustion Efficiency Correlation at Idle Coefficient of Determinationr2 ............................................................................................ 13

7 Coefficients of Determination for Smoke Number as a Function ofRelative Hydrogen Content and Droplet Size at Cruise Power Level .. 16

8 Coefficients of Determination for Smoke Number as a Function ofRelative Hydrogen Content and Droplet Size ................................ 16

9 Term Coefficients for Relative Hydrogen Content and Droplet Size .... 17

10 Analysis of the Statistical Significance of Relative Droplet Size andHydrogen Content on Smoke Number .......................................... 19

11 Results of Fuel Properties Correlation With Idle Combustion Efficiency 60

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Page 11: Effect of fuel gas to GT

SYMBOLS

B Mass transfer numberCOP Combustor operating parameter

. ,, Specific heat at constant pressure, cal/gK6 Diameter, midq Quenching distancedt Droplet lifetime, sE Evaporation ratef/a Fuel-air ratioFCP Fuel characterization parameterH Heat of combustionH2 Hydrogen concentration, %k Fuel nozzle constantL Latent heat of vaporizationLSP Liner severity parameter

Massm Mass fractionP Pressure, kPa or MPaAP Pressure differential, kPaPF Combustor pattern factorPr Prandtl number

. Q Heat content, cal/gr Coefficient of determinationr Stoichiometric ratioRe Reynolds numberSLTO Sea level take-off conditionsSMD Sauter mean diameter, micronsT Temperature, KTu Turbulence intensity, % = 100 (u'/V)* u Root mean square of the fluctuating velocity, m/sU Velocity, m/sV Primary Zone Volume, m3

VI Vaporization indexW Flow ratez Dropsize distribution factor

Sensitivity factor6 Specific gravity17C Combustion efficiencyK Thermal conductivity

', p Dynamic viscosity, kg/m-sv Kinematic viscosity, m2/sp Density, kg/m 3

a Surface tension, N/m0 Equivalence ratio

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Page 12: Effect of fuel gas to GT

'iSYMBOLS (Continued)

i Subscripts

a Aird Droplet

' 'f Fuelg Gas

i Initial conditionsL Combustor liner

., ,ox oxygenSp nozzle prefilmer lip: -. pri Combustor primary zone

s Droplet surface' v fuel vapor

3 Combustor inlet4 Combustor exit

FX.

i-aSusrita Airw

dDrple

f ue

g GasIntilcodtin

LiuiL obutr ie

* x xye

.:.nzlepr.lmr:ipr-omutr rmryzn

- role.1rfc

.,'a-a .

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Page 13: Effect of fuel gas to GT

SECTION I

SUMMARY

This study was undertaken with the objective of preparing a correlative model of the effectof fuel properties on the performance and life of United States Air Force gas turbine engine hotsections. The data base used in constructing the model consisted primarily of fuel effect datawhich has been obtained over the past few years under a number of Department of Defensecontracts.

The approach taken in the study was to first develop fuel effect correlations for specificcombustor configurations, then to tie together these correlations using engine design parame-ters, thereby allowing prediction of fuel effects in any current or future aircraft gas turbinecombustion system. More specifically, the approach consisted of using statistical analysis tocorrelate the dominant fuel properties which affect combustor operation for individualcombustors. The approach then consisted of cross correlating the individual combustorrelationships against those combustor design and operating parameters that were found toinfluence their response to fuel differences.

All of the fuel relationships developed can be divided into two groups as follows:

* Those that are related to fuel vaporization and its effect on the rate the fuelignites and burns

* Those tied to fuel chemistry and its effect on smoke generation andradiation.

Table 1 lists the fuel effects which have been correlated and the correlating parameterswhich were found to provide the best correlations. The first column in Table 1 lists the primaryperformance and operating factors which were evaluated. The second column lists the fuelrelated factors which were determined to influence individual combustors. The third columnlists the specific correlations which were developed for the individual combustors studied, andthe last column identifies the basis for generating the fuel effects to allow prediction of fuelrelated changes in performance and operation of any combustor.

TABLE 1. CORRELATION OF FUEL EFFECTS

Parameter Governing Combustor Correlation Basis for GeneralizedAffected Factor Used Correlation

Altitude Relight Spark quenching Fuel Characteristic Parameter Relative change in COP withdistance (FCP) Combustor Operating FCP

Parameter (COP)

, Groundstart Fuel vaporization Vaporization Index (VI) Priiary zone operating con-ditions

Combustion Efficiency Fuel vaporization Vaporization Index (VI) Combustion efficiency corre-lation parameter (Ref. 15)

Pattern Factor Fuel vaporization Vaporization Index (VI) Relative sensitivity

Smoke and Fuel composition Hydrogen Content Relative sensitivityParticulates

Liner Temperature Fuel composition Hydrogen Content Relative sensitivity(Radiation)

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Page 14: Effect of fuel gas to GT

The fuel characteristic parameter and combustor operating parameter used to predictaltitude relight performance were developed from Ballal and Lefebvre's equation for ignition ofheterogeneous mixtures in a flowing stream (Reference 7). The vaporization index wasdeveloped as a relative measure of the tendency of the fuel spray to vaporize. It was selectedover several other atomization-related parameters which were evaluated and contains fuel

S10 property terms which account for relative drop size, relative heat transfer to the droplet and10 -relative volatility of the fuel.

Smoke and radiation-related parameters were found to correlate well with hydrogencontent. The effect of fuel atomization and naphthalene concentration on smoke formation werealso evaluated. It appeared that atomization might have a secondary effect at some conditions;but, the effect was too small relative to the data scatter to obtain a correlation. Somewhatsurprisingly, naphthalene was also shown to have no greater effect on smoke than would bepredicted from the change produced in hydrogen concentration. Naphthalene concentration didappear to have a secondary effect on ignition, but this effect was also too small relative to thedata scatter to correlate.

A number of approaches to generalizing the individual combustor relationships wereevaluated. Generally, correlation of fuel effects against combustor operating parameters was not

very successful. In most cases, the best correlations were empirical correlations of the sensitivityof the performance effect to fuel property variations, against the value of the performanceparameter with some reference fuel (usually JP-4). For example, the sensitivity of smokenumber to hydrogen content for most combustors correlates very well with the value of thesmoke number with JP-4. Pattern factor and combustion efficiency show similar trends, but amore complete combustion efficiency correlation was obtained using Odgen and Carrier'scorrelation parameter (Reference 15). An exception to the general trend was the groundstartcorrelation which was based on primary-zone equivalence ratio and primary-zone entranceconditions.

In most cases, reasonably good data correlations have been obtained. Examination of the

correlations provides good insight into the nature and extent of the effect of fuel propertyvariations on engine performance and operation. There is reason to believe that much of thedata scatter found in the correlations is due more to inaccuracies in the basic data than to errorsor incompleteness in the correlations. Further improvements in the correlations will require (1)improved instrumentation, (2) testing over an even wider range of fuel properties (particularlyviscosity and hydrogen content) than previous testing, and (3) fuel effects testing in speciallyinstrumented complete engine systems.

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Page 15: Effect of fuel gas to GT

SECTION 11

INTRODUCTION

Over the past decade the cost of petroleum-based fuels has risen dramatically. Fuelavailability is no longer dependable, as illustrated by the petroleum shortages of 1973 and 1979.During the same period, the increasing use of highly aromatic crude oil has resulted in adeterioration of jet fuel quality. To offset these problems, increasing consideration is being givento broadening specifications to reduce the cost and improve the availability of both thepetroleum-based fuels in use today and the shale- and tar sands-derived fuels of the future.

A number of experimental evaluations to determine the effect of potential fuel changes onaircraft engine performance and operability have been sponsored by the Air Force and Navyover the past few years. These studies have provided a wealth of data for the particular enginesand engine components which have been tested. The objective of the "Fuel Effects on GasTurbine Engine Combustion" study has been to use this data base to develop correlations of fueleffects on combustor performance and hot section durability and to relate these correlations toengine design parameters so that these parameters may be universally applied to any current orfuture aircraft gas turbine combustion system. Together, the correlations developed constitute amodel which will be used to:

* Conduct trade-off studies of engine performance and life with fuel cost andavailability.

a Guide preparation of new or modified fuel specifications.

0 Provide rapid evaluation of a deviate fuel in emergency situations.

0 Reduce, and, in some cases eventually eliminate, the time and cost ofqualifying a new fuel.

* Act as a design tool for new or modified combustion systems to betteraccommodate future fuels.

The "Fuel Effects on Gas Turbine Engine Combustion" program had been originallyplanned to consist of two Tasks. Task I was to consist of developing quantitative relationshipsbetween combustor operating characteristics and fuel properties and developing a comprehen-sive plan for combining the relationships into a generalized working model. This report presentsthe results of the Task I effort. Task II, which has not been undertaken, was to consist ofcompleting the generalization of the relationships obtained in Task I and organizing them into acohesive package which may be programmed as a computer model of existing combustors, andused as a design tool for future combustors.

The development of the Task I relationships was conducted in two steps: (1) determinationof fuel sensitivity correlations for individual combustors and (2) correlation of the fuel affectedcombustor design and operating parameters to obtain a generalized fuel effect model which maybe applied to any conventional combustor. Relationships were developed for:

* Altitude ignition limits0 Groundstart ignition capability0 Combustion efficiency* Pattern factor

3

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Page 16: Effect of fuel gas to GT

.. .v:. . .. . . -

• Smoke" Peak combustor wall temperature.

The fuel sensitivity study was accomplished by correlating the preceding performancecharacteristics with parameters based on fuel properties reflecting known or suspectedcombustion trends. The correlations were based primarily on statistical analyses of fuel effectsdata from references 1 through 5. Statistical analyses were used to (1) compare variouscorrelation parameters to select the most appropriate one, (2) show the validity of the selectedcorrelation and (3) provide an expression of fuel sensitivity which could be used in the

-- development of the generalized fuel effect model. The fuel sensitivity model is described indetail in Section III.

The generalized fuel effect model consists of correlations of the sensitivity of the fuel effectto variations in some basic combustor design or operating parameter, e.g., the air loadingparameter (0), (Reference 6). Separate correlations were developed for each of the performancerelationships listed above. The development of the model is discussed in Section IV.

The fuel effect correlations developed under Task I have been based entirely on data takenfrom experimental combustor component test data, rather than full-scale engine tests.Experience has shown that there may be significant performance shifts between component andfull-scale engine data. While the fuel effect correlations developed in Task I are believed toaccurately reflect fuel trends, they must be anchored to baseline engine data to predict engineperformance. The computer model planned for Task II was to have provisions for anchoring thefuel effect relationships to baseline engine data.

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Page 17: Effect of fuel gas to GT

SECTION III

FUEL EFFECTS CORRELATIONS

A. FUEL PROPERTY CORRELATION APPROACH

The development of fuel correlations for specific combustors is described in this section.

Correlations were developed for altitude ignition, groundstart, combustion efficiency, patternfactor, smoke, and peak combustor wall temperature. The correlation approach taken was toutilize regression analyses to select the fuel property parameter which produced the beststatistical result. Generally, the correlation equations were in the form:

y = Ao + AIX

where:

Y Y represents the observed engine parameter (e.g., smoke, groundstart fuel-air ratio, pattern factor),

" X represents the fuel properties correlation parameter,

* A represents the sensitivity of the observed engine parameter to variation ofthe fuel properties correlation parameter.

Note that X is a fuel correlation parameter that may consist of one or many fuel-relatedvariables; for example, fuel viscosity, fuel density, fuel hydrogen content or a combinedparameter which combines several fuel properties which relate to the physical processesinvolved.

For determination of the most applicable correlating parameter, two methods were used.In some cases the correlation was expanded to include a second term. The equation then takesthe form:

Y = A. + AIX, + A2X2.

Comparison of the degree of correlation with the expanded equation to the originalequation indicated the desirability of including the additional term. In other cases, a number ofsingle variable relationships were developed and compared on the basis of the correlationcoefficients. In all cases, a single variable relationship was selected as being the most applicable.

B. ALTITUDE IGNITION LIMITS

For some engines, altitude ignition appears to be the single most significant combustorperformance variable affected by fuel property variations. A model was developed to correlatethe effect of fuel properties on altitude relight performance using rig data from the F100, TF33,TF30, F101 and J79 combustors. The model is based on an ignition equation formulated byBallal and Lefebvre (Reference 7) and was originally developed for the TF30 combustor underan NAPC sponsored contract (Reference 8).

The ignition model is based on the assumption that mixing rates and chemical kinetics areinfinitely fast and that the sole criterion for successful ignition is an adequate concentration offuel vapor in the ignition zone, i.e., the process is independent of chemical reaction kinetics andis evaporation controlled. It is assumed that the igniter discharge creates a region of inflamed

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Page 18: Effect of fuel gas to GT

gas that must grow to a minimum volume to sustain combustion and propagate throughout thecombustor. The growth of the inflamed region is determined by conflicting processes of fuelvapor production and external heat loss. Thus, the model provides a criteria for ignition basedon quenching distance in terms of mass transfer number, the initial fuel droplet diameter, andaerothermal parameters which depend on combustor operating conditions.

For turbulent flowing mixtures:

d 0.32 Prp [(SMD) 3 (Tu/100) U ;,dq - Zoln (I+B) p p (Reference 7) (1)

Where: dq = Quenching distancePra = Prandtl number (air)pf = Density (fuel) kg/m 3

SMD = Sauter mean diameter (microns)Tu = Percentage turbulence intensity = 100 (u'/U)u' = Root-mean-square value of the fluctuating velocity m/sU = Free stream air velocity m/sZ = Drop size distribution factor (considered to be constant)0 = Equivalence ratioB = Mass transfer number (stoichiometric)

= Dynamic viscosity (air) kg/m.s

Based on this equation, the ignition model was formulated by eliminating all constants andexplicitly combining fuel properties into a single parameter referred to as the fuel characteriza-tion parameter (FCP).

pF (SMD)'FCP= In (I+B) (2)

a,.

The aerothermal combustor parameters, which vary with altitude and Mach number, weresimilarly grouped together in a term referred to as the combustor operating parameter (COP).

=.Pr. (Tu/10)-'U '• -. . COPPa A. °3

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Page 19: Effect of fuel gas to GT

By use of these terms, the variation in atomization quality from one nozzle design toanother is removed. The impact of the fuel type is expressed through the process of evaporatingmass transfer. Following the convention of Spalding (Reference 9), the rate of evaporative masstransfer is related to the fuel droplet diameter and mass transfer number which is the ratio ofthe energy available for vaporization to the energy required. This mass transfer number is givenby:

B=-m.H/r + cp(Tg - T,)B " -(4)

Where: m. = Fractional mass concentration of oxygenH = Heat of combustion (cal/g)

r = Stoichiometric ratioc = Specific heat at constant pressure (cal/g. K)Y = Combustor inlet temperature (K)T,, = Initial boiling point temperature (K)

' Q = Heat conducted from gas per unit mass crossing the phase boundary(cal/g)Q = La + cpl (T.- T)= Lo + cpV (TS - T,)

L. = Latent heat of vaporization at the droplet surface temperature (cal/g)c = Specific heat of the liquid (cal/g.K)-c = Initial liquid temperature

eP. C = Specific heat of the vapor.Lo = Latent heat of vaporization at temperature TO

1. Pressure Atomizing Nozzles

To calculate the FCP for a particular combustor, the fuel spray droplet Sauter meandiameter (SMD) must be determined for the particular combustion system of interest. TheTF30 and TF33 combustor systems employ pressure atomizing fuel nozzles. An empiricalcorrelation parameter for this type atomizer (Reference 10) was used to estimate the fuel spraydroplet diameter, i.e.:

SMD = kW 2 a v-2 0 a P60 .40

.. (5)

where: k = constant (dependent on fuel nozzle design)Wf = Fuel flow (kg/s)Vf = Kinematic viscosity (m2/s)

.. O = Surface tension (N/m)

APf = Pressure drop in the fuel nozzle passage

From equation (1), separating the terms dependent on combustor aerodynamics from thosewhich are dependent only on fuel physical properties, the following mathematical expressionsfor FCP and COP are obtained:

A .9

FCP = (6)f

COP - Pr, (Tu/1000 Uh W r7'S' p APf (7)

7

4.:..:.:% %-- .---- :: --. -,:... ,:.. ------. ,

Page 20: Effect of fuel gas to GT

2. Aiblast Nozzles

The F100 and FI01 engines employ airblast atomizing fuel nozzles. Shanawany andLefebvre's correlation parameter for this type of atomizer (Reference 11) was used to estimatethe relative fuel spray droplet diameter.

= 1,+ [00 ( .' (- D-)' D ' + 0 15 ( A RD o

V MD- IL Wa- [0p 3(Du 2 40a Pfof(8)

where: D = Prefilmer lip diameter (in)a = Air flowrate (kg/s).

Since the second term in equation (8) is relatively small, in comparison to the first term,and the product of the air density times the square of the air free stream velocity is directlyproportional to the pressure drop across the fuel nozzle system, equation (8) becomes

SMD = 0.073 ( p , -p -.6 -., D.4) 6, + W'')a o(9)

Separating the terms dependent on combustor aerodynamics from those which aredependent only on fuel physical properties and eliminating the constants, (including Dp) thefollowing mathematical expressions for airblast nozzles are obtained:

Of 6fFCP n= ln(+B) (10)

COP = Pr.(Tu/100) 5 U5(l + Wi/W.)'5

p8 p A P.9 (11)

.. 3. Combustor Altitude Ignition Correlations

Fuel physical properties and ignition data from TF30, TF33, F100, F101 and J79-17Cengines were used to generate a fixed relationship between COP and FCP, as shown in Figures 1,3, 5, 7, and 8, respectively. * For the TF30, TF33 and F100 engines, the COP is calculated fromthe windmilling conditions as defined on the windmill map. The map relates flight Machnumber and altitude to compressor discharge conditions. The relationship between COP andaltitude for the TF30, TF33 and F100 is shown in Figures 2, 4 and 6, respectively. The values ofCOP for the F101 and J79 engines were calculated directly from the altitude relight test results(Reference 2 and 3).

The data generally show a linear relationship between COP and FCP. There is some datascatter, particularly with the F100 engine at maximum and minimum airflows. Nevertheless, the

expected trend towards decreasing ignition capability with increasing FCP was evident.Combustor systems which employ airblast rather than pressure atomizing fuel nozzles tend to be

.4- less sensitive to changes in fuel properties as indicated by the low slopes of the F100 and F101COP vs FCP curve. Note that the absolute values of COP and FCP are functions of combustordesign parameters which vary substantially from engine-to-engine. Consequently, directcomparison of FCP and COP values is meaningless and one must instead compare the effect ofrelative changes in FCP on the altitude ignition limit.

Because of the large number of figures appearing in this section, all figures have been placed at the end of the section.

8

...

Page 21: Effect of fuel gas to GT

C. GROUNDSTART, COMBUSTION EFFICIENCY, PATTERN FACTOR AND LEANBLOWOUT

The processes affecting groundstart, combustion efficiency and burner temperature" uniformity (pattern factor) are primarily fuel spray atomization and evaporation. The processes

are influenced by the size of the droplets formed by the spray nozzle, the heat transferred to thefuel droplet, and the volatility of the fuel. The correlating parameters for groundstart,combustion efficiency and pattern factor were selected to evaluate the relative importance ofdroplet size and vaporization rate. From a comparison of these parameters, the one which bestcorrelated the fuel data for all of the engines considered was selected.

The correlative parameters used in the data analysis included fuel recovery temperature,relative droplet size, the Spalding mass transfer number and several expressions which

- combined droplet size and mass transfer number. Analysis of the evaporation of a single dropletwould suggest that the droplet lifetime is proportional to the square of the droplet diameterdivided by a function of the mass transfer number, i.e.,

pD2

dto In(1 + B) (12)

This relationship follows from simplifying and eliminating fuel-independent terms fromthe following equations:

MD = T A

.5,

Er = 21D-K--in (1 +B)(1 + 0.25Re6)c P. D(Reference 7)

where: MD = Droplet mass (kg)D = Droplet diameter (microns)Ef = Fuel evaporation rate (kg/s)ReD = Droplet Reynolds numberKa = Air thermal conductivity (J/m -.s K)

then the droplet lifetime, dt is:

MD (ir/6)(pr)D '

= 2rD(K/cd),ln(1+B)(1 + 0.25Re '5))

Equation (12) is based on a single droplet. The average lifetime for an array of dropletswould be proportional to this expression (using SMD for D) if the number of droplets remainedconstant as SMD changed and the relative size distribution remained unchanged. Based onthese assumptions, an expression termed the vaporization index (VI) was defined:

'- 6 (SMD/SMD ,t) 2

V = In(1 +B) (13)

=where 6 is the fuel specific gravity and the subscript "ref" indicates a reference value based onJP-4. The fuel property variations are thus included in the equations which define the averagedroplet diameter and the mass transfer number. The appropriate operational characteristics of

" the fuel nozzle are also included in the droplet diameter term.

94

Page 22: Effect of fuel gas to GT

Two additional correlation expressions were evaluated to explore changing the relativeimportance of SMD and B, i.e.,

I 6(SMD/SMDw)VI3 In(l +B) (14)

6(SMD/SMD ,) 3

V13 = ln(1 + B). (15)

A complete list of correlating parameters is given in Table 2.

*. TABLE 2. FUEL PROPERTIES AND5, CORRELATING PARAM-

ETERS

*10% Recovery Temperature (RT)

90% Recovery Temperature (RT)

5Mas Transfer Number (B)(Based on 10% or 90% Recovery Temperature)

Relative Spray Droplet Size

Vaporization Index (VI)(Based on 10% or 90% Recovery Temperature)(Relative SMD term to the first, second, or

third power)

Correlations were compared for the F100, TF33, TF30, F101, J79-17C and TF41 engines. A

-% computer program entitled Statistical Applications for Engineers (SAFE) was used to generatecorrelation coefficients for each correlating parameter. The correlating parameters were defined

SI, as the independent variables in a single-variable linear regression analysis. They are used torelate fuel property changes to changes in groundstart fuel-air ratio, efficiency, and patternfactor, the dependent variables in the regression analysis. These regression analysis results werethen examined for cause/effect relationships. A good correlation was judged to be one whichwould indicate a significant cause/effect relation with a coefficient of determination (r2 ) of morethan 0.40. This is a somewhat arbitrary number, however, and is strongly influenced by therange of fuel properties upon which the data are based. For example, the larger the range ofSMD and B in the VI correlation, the greater the r2 for a given instrumentation error.

-- ,.

.10

0%

0%%

Page 23: Effect of fuel gas to GT

7I.&

The correlation results from the ground start, combustion efficiency and pattern factoranalysis are shown in Tables 3, 4 and 5. Groundstart results are shown for three different airflows for the FI00, TF33 and TF30 engines, but data for only one airflow were available for theother engines. Combustion efficiency was only correlated at the idle power point as efficiencylosses at other power points were generally too low to measure.

TABLE 3. GROUNDSTART DATA CORRELATIONS (SINGLE VARIABLE LINEARREGRESSION SUMMARY COEFFICIENT OF DETERMINATION r2)

CorrelationParameter FIO0*#* TF33*** TF30*** FIO J79-17C** TF41I

10% Recovery 0.6658/(0.9213)* 0.0561 . ...Temperature 0.0919/(0.8538) 0.2954

" 0.00611(0.3434) 0.3327

. Relative Spray Droplet 0.9878 0.4510 0.6047 0.2563 0.9172/0.7773 0.4062/0.28250.6422/(0.9090) 0.8468 0.84050.4309/(0.5323) 0.8030 0.9856

Mass Trans. Number 0.5677/(0.9421) 0.0912 0.3453 0.1649 0.7687/0.8111 0.3101/0.1720(10% RT) 0.0970/(0.9230) 0.2644 0.6973

0.0136/(0.4656) 0.3333 0.7255

Vaporization Index 0.8605/(0.9503) 0.2733/(0.9454) 0.6025 0.2471 0.9417/0.6614 0.4533/0.279910% RT 0.3753/(0.8897) 0.6874 0.8489(SMD/SMD.JP 4):1 0.1844/(0.4622) 0.6534 0.9799

Vaporization Index 0.8209 0.2672/(0.9696) 0.5986 0.2514 0.9395/0.7260 0.3457/0.265410% RT 0.3290/(0.8950) 0.6433 0.8635(SMD/SMD.J, 4)

2 0.1527/(0.4723) 0.6283 0.9835

Vaporization Index 0.1336/(0.8668)10% RT 0.4298(SMDW/SMDJ, 4)' 0.4487

Note * ( ) Indicates one point was eliminated to improve the correlati,,n**Data shown for standard day/cold day

S**Valu are given at three different air flows.

Selection of the most desirable correlating parameter from those evaluated is not obvious.All of the correlating parameters achieve some degree of correlation for some variables and someengines, and none of them do a good job in all cases. Selection of the optimum correlation is

confused by:

" An apparent high degree of data scatter in some cases

* The inherent interrelationship of fuel viscosity and vapor pressure whichmakes separation of droplet size and volatility effects difficult.

In general, it can be seen from Tables 3, 4, and 5 that the best correlations were mostconsistently achieved using the parameter which included both relative droplet size and masstransfer number, i.e., vaporization index. Vaporization index using droplet size to the 2.0 power

a' was selected on the basis of having the best basis in theory since there was no clear-cutnumerical advantage over the other two VI parameters.

Page 24: Effect of fuel gas to GT

TABLE 4. COMBUSTION EFFICIENCY AT IDLE (SINGLE VARIABLE LINEAR RE-GRESSION SUMMARY COEFFICIENT OF DETERMINATION r2)

CorrelationParameter F100 TF33 TF30 Fl0l J79-17C TF41

90% Recovery, 0.9216 0.0895/(0.6674)- 0.07965/(0.0987) 0.0411 0.0662 0.0563Temperature (RT)

Relative Spray Droplet 0.636 0.5069/(0.7295) 0.1025/(0.3077) 0.7273 0.1449 0.0818

Mass Trans. Number 0.9261 0.3472 0.1041/(0.1263) 0.1760 0.0866 0.0062

Vaporization Index 0.7748 0.5822/(0.8276) 0.0982/(0.2744) 0.6767 0.1345 0.100690% RT(SMD/SMDP4)3

Vaporization Index 0.8291 0.5557/(0.8164) 0.1008 0.6691 0.1480 0.094690% RT

(SMDf/SMDP 4 )2

Vaporization Index 0.8939 0.5144/(0.7966) 0.103210% RT(SMDSMD,,)'

Note ( ) indicates one point was eliminated to improve correlation.

TABLE 5. PATTERN FACTOR AT SLTO (SINGLE VARIABLE LINEAR REGRESSIONSUMMARY COEFFICIENT OF DETERMINATION r2)

CorrelationParameter FIO0 TF33 TF30 F1I J79-17C TF41

90% Recovery, 0.5976/1(0.7103)* 0.7766 0.3908 0.2920 0.0398 0.0967Temperature (RT)

Relative Spray Droplet 0.3985/(0.9416) 0.1568 0.0338 0.5193 0.0145 0.1117

Mass, Trans. Number 0.6000/(0.7451) 0.7234 0.0757 0.3230 0.0160 0.130690% RT

Vaporization Index 0.4143/(0.9351) 0.2214 0.0476 0.4506 0.0061 0.136490% RT

(SMDWSMD,.,)

Vaporization Index 0.4650/(0.9290) 0.2158 0.0602 0.5018 0.0101 0.133490% RT(SMDASMD ,.)2

Vaporization Index 0.5232/(0.9023) 0.3046 0.0562 0.4426- 10% RT*_, (SMD/SMD1e4)'

Note' ( ) Indicates one point was eliminated to improve the correlation.

Gas turbine fuels are complex mixtures of many hydrocarbon compounds. Their volatilityis generally expressed in terms of the fraction of the fuel which can be distilled at a giventemperature. Frequently, when a single temperature is needed to describe the relative volatilityof the fuel, the 50"( distillation temperature is used. In combustion, however, the lighter fuelfractions within the fuel tend to influence ignition (particularly under lean conditions), whilethe heavier fractions would be expected to have more influence on pattern factor and,

4 12

Page 25: Effect of fuel gas to GT

combustion efficiency. To determine if the selection of the distillation fraction had a significanteffect on the accuracy of the vaporization index (VI) correlation, both the 10(,( and 90'1distillation temperatures were used to compute the VI for correlation of combustion efficiency.The results are compared in Table 6. The 90("; temperature showed an improved correlationover the 10', temperature for the F100, but a poorer agreement with the F101. In other cases,the differences were insignificant. The lack of a clear-cut distinction is blamed on data scatterand the inherent relationship between the 10 % and 90 %'i distillation temperatures in most fuels.For lack of a clear rumerical difference, the 10 " distillation temperature was selected for use inthe VI for correlation of ignition data, and the 90" distillation temperature was selected for VIcorrelations of combustion efficiency and pattern factor.

TABLE 6. COMBUSTION EFFICIENCY CORRELA-TION AT IDLE COEFFICIENT OF DETER-MINATION r2

Vaporization Index Vaporization IndexCombustors 10% Recovery Temp. 90% Recovey Temp.

FI00 0.5831 0.7748TF33 0.8060 0.5822TF30 0.0587 0.0982FI1 0.7413 0.6767J79 0.1452 0.1345

TF41 0.1116 0.1006

Plots illustrating groundstart, combustion efficiency and pattern factor correlations areshown in Figures 9 through 26. The dotted lines in these curves represent the 95 % confidenceband. For any value of the correlation parameter, e.g. VI, the interval about the Y axis betweenthe dotted lines represents the true value of Y with 95% confidence.

A good correlation was obtained for the groundstart fuel air ratio as a function of VI. Thelarger value of VI indicates a reduced tendency to vaporize, and as a result, a larger total fuel

y. flow rate is required to generate the same level of fuel vapor. The data from idle combustionefficiency show a high degree of correlation, with efficiency decreasing slightly with an increasedVI. The VI is an increasing function of fuel viscosity and a decreasing function of fuel volatility.Pattern factor data also show a good degree of correlation. While the degree of change in patternfactor is small, the potential impact on turbine life is significant.

Changes in the combustor lean blowout limits would be expected to be correlateable withfuel droplet size and volatility. Fuel flammability limits would also affect lean blowout, butno significant fuel differences would be expected and flammability limit data were not availablefor the various test fuels.

An excellent correlation of lean blowout limit with VI was obtained using J79-17Cgroundstart lean blowout data (Figure 27). Unfortunately data for the other engines studiedeither showed no significant fuel effect or excessive data scatter when correlated with VI, e.g.,see Figure 28. Assessment of the blowout data for specific combustors may be summarized asfollows:

0 J79-17C - Good correlation of groundstart data indicates significant fueleffect. Excessive data scatter in altitude blowout data.

0 J79-17A - Excessive data scatter in both groundstart and altitude leanblowout.

% 13

"%%

**•C °* ,.. ' - •* - . - - C -..~, , . ". . .. O o. . o . . o % ,* , .. , -. °.%' . . -o . • • • .J * %,- % % % , '., , . .-

Page 26: Effect of fuel gas to GT

*~~-77 7- .* *-. .. . *t -* N U %

F100 - No groundstart blowout data. Altitude blowout data show excessivedata scatter.

" F101 - Groundstart and altitude data both show considerable data scatterand blowout values are suspiciously high. Fuel effect on groundstart issmall.

• TF33 - No groundstart data. Altitude data show considerable scatter.

• TF41 - Fuel effect is small. Lack of fuel temperature data preventscalculation of VI.

• TF30 - Limited data indicates small effect.

-Because so few correlations of blowout were formulated for specific combustors, no

attempt was made to correlate fuel effects with engine design variables.

14

Page 27: Effect of fuel gas to GT

D. SMOKE AND RADIATION

Whereas most of the combustor operating parameters affected by the fuel may be relatedto fuel physical properties, smoke and flame radiation have generally been linked to changes infuel chemistry. Under some conditions, fuel physical property variations may also affect smokeand radiation, but these conditions appear to be primarily at low power operating points wheresmoke and the effect of radiation on combustor life are not of significant concern. The impact offuel physical properties on smoke formation was investigated to a limited extent, but failing tofind a quantitative correlation, only chemical effects were considered in the radiationcorrelations.

1. Smoke

Carbon particles are commonly formed in the primary zones of gas turbine combustors. Tosome extent, these particles are consumed in the lean combustion zone downstream of theprimary zone. Depending on the rate of formation and growth and the extent of subsequentoxidation, some fraction of these particles are emitted from the combustor. Particles, whosediameter is approximately equivalent to the wavelength of visible light or smaller, will follow thestreamlines of the flow through the turbine and will be exhausted from the engine as smoke.Larger particles may impinge on the turbine blades and vanes, eroding the surface, andcontributing to reduced turbine life.

The influence of the fuel on the formation of smoke may be exerted through both the fuelchemistry and those physical properties which influence fuel-air mixture preparation. Somestudies have shown that hydrogen content alone provides a valid basis avr correlating chemicaleffects, while other studies have indicated that the presence of multicyclic compounds such asnaphthalenes, indans and tetralins cause smok* iv excess of their effect on reduced hydrogencontent. The approach taken in this study wj Aiz to correiate the cumulative effect of changesin hydrogen content and relative droplet size with only those fuels that had relatively low total

Sconcentrations of naphthalenes, indans and tetralins (less than 10 % by volume) and then torepeat the correlations including the fuels which contained higher concentrations of theseconstituents for comparison.

The correlations were generated using the Statistical Applications for Engineers (SAFE)computer program and involved a multi-variable linear equation of the following form:

y = c + ax ...ax,, for i = 1,2...n(16)

where: xi = fuel propertiesai = coefficient of xi termn = total number of correlating parameters.

Comparison of the correlation coefficients for correlations with and without fuelscontaining high concentrations of naphthalenes, indans and tetralins is summarized in Table 7.Had the multicyclic compounds shown a consistent significant increase in smoke, correlationsincluding these fuels would have shown an appreciable reduction in the correlation coefficients.It can be seen, however, that there is actually little change; indicating that on the average, thefuels containing multicyclic components generate approximately the same amount of smoke atany given hydrogen content.

154C.

Page 28: Effect of fuel gas to GT

TABLE 7. COEFFICIENTS OF DETERMINATIONFOR SMOKE NUMBER AS A FUNCTIONOF RELATIVE HYDROGEN CONTENTAND DROPLET SIZE AT CRUISE POWERLEVEL

Fuels With Naphthalene Plus Indans4 Engines and Tetralin Less Than 10% By Wt. All Fuels

F100 0.9195 0.9504TF33 0.7332 0.7967FI01 0.6330 0.7115J79 0.9285 0.9019

TF41 0.2272 0.2614

Correlations were also developed to statistically evaluate the importance of fuel propertieson smoke formation. Physical property effects were evaluated through inclusion of relative dropsize with hydrogen content in the smoke correlations. Coefficients of determination (r2) andterm coefficients (a i) for smoke number versus an optimized correlation of hydrogen content andrelative drop size are compared in Tables 8 and 9. All of the r2 values are above 0.50. indicatinggood correlation. However, comparison of term coefficient for relative drop size and hydrogencontent generally indicates a weaker dependence of smoke number on droplet size than onhydrogen content.

TABLE 8. COEFFICIENTS OF DETERMINA-TION FOR SMOKE NUMBER AS AFUNCTION OF RELATIVE HYDRO-GEN CONTENT AND DROPLET SIZE

Power Levels FIO0 TF33 FIO1 J79 TF41

*-. Cruise 1 0.9504 0.7967 0.7145 0.9019 0.2614, j: Cruise 2 - 0.8966 - - -

SLTO 0.6132 0.7800 0.5159 0.4591 0.5455Dash 0.3783 - 0.5552 0.5552 0.2638

;.'

,4%..

16

W

5

Page 29: Effect of fuel gas to GT

C4

C4

C4 i

oo

z4 -

C-)

00

Q -

z

%, .,o *

c~E..i:. 17

Page 30: Effect of fuel gas to GT

.. . . . .. .~~- . - . ...- . . ..-.- - " - - : - . - --. - -. .t. ,

The SAFE program was also used to identify those parameters in the regression analysiswhich were statistically significant in correlating smoke number. In Table 10, the T-valueindicates the relative statistical significance and the T(95,N) is a reference minimum value forclear statistical significance.

It can be seen that in all but two out of fifteen cases where hydrogen content and relativedroplet size are considered together, the T-value is higher for hydrogen content than for relativedrop size and in only one of fifteen cases is the T-value for relative drop size higher than

Correlation Coefficientwhere T -value Er n1Err i 1,...n (17)

T(.95, N) = Students t distribution at 95 percentile and number of data points.

Furthermore, in general, the correlation coefficient was somewhat improved when droplet sizewas removed from the correlation.

*In some cases, it appears that the droplet size dependence, while small, may be real. Inother cases, the droplet size correlation does not even follow expected trends (negative a,). Whileit is concluded that droplet size may in some cases have a second order effect on smoke, therewas insufficient data to reliably quantify the effects.

* One recent report has suggested that smoke point might provide a better correlation ofsmoke than hydrogen content (Reference 13). The average correlation coefficient for 17 cases forcorrelation of smoke point with smoke number was 0.531, while the average correlationcoefficient for hydrogen content with smoke number was 0.535 for the same 17 cases. Both are

% acceptable with insignificant differences. The close agreement between the two correlations is*- probably due to the inherent correlation of hydrogen content with smoke point as shown in

Figure 29.

The final correlations of hydrogen content with smoke number for all of the cases studiedare shown in Figures 30 through 35.

'18

* , ' , ." "Z " '.". ,".". ."" ", " " -" '.' -.,'' " ,''""" . """, .""" " "." " .." "-' . , . ," " ' ' ..'-18""

Page 31: Effect of fuel gas to GT

C- N

vs C4 6! C4 C

Q_ C1 N NC

t-: C4-5 CIS N C4 C4

A~~c 0 0 i.0ie e

w~ C4

w co

14 C4i r:c4

<0 g Al e

.5 C.) .i

IMF I. ,

5% 2l

Q 19

Page 32: Effect of fuel gas to GT

L. Solid Particulates

.o

In general, the availability of particulate data is more limited than smoke data; however,there is an inherent correlation between the two. Figure 36 illustrates TF33, F100 and TF30-measured particulate levels versus smoke number. The figure also shows a correlation betweensmoke number and particulates taken from Reference 14. Reference 14 gives an upper and lowerbound for the correlation and the solid line shown is an average between the two. Smoke shouldcorrelate perfectly with particulate concentration if (1) average particle size remains constant orchanges linearly with smoke number, and (2) the particle size distribution remains constant. Itcan be seen that the two measurements correlate reasonably well. The data scatter is probablydue more to the accuracy of the relatively difficult measurement than in errors due to thecorrelation.

3. Radiation and Combustor Liner Temperature

Any changes in the combustor process which results in a change in the heat transfer to thecombustor liner will affect combustor life. Any effect of fuel property variations on thecombustion process and the resultant liner temperatures is, therefore, of primary concern.

While the convective heat load from the combustion process has not been found to changesignificantly, changes in fuel chemistry (hydrogen content) have been found to affectcombustion by producing a more luminous flame and hence a higher radiative heat load. Theimpact of hydrogen content on the combustion process and the sensitivity of the liner metaltemperature to radiative heat transfer were determined by normalizing the liner metaltemperature rise to the gas temperature rise. Both temperature rises are referenced to thecompressor discharge temperature. The normalized temperature ratio is defined analytically as:

% Tl,(m. )- T3Liner Severity Parameter (LSP) = T - T 3 (18)

where: T 3 = Compressor discharge temperatureT = Maximum liner temperature

L(max)T 4 = Combustor exit temperature.

Correlations of Liner Severity Parameter (LSP) versus hydrogen content were generatedfor the F100, TF33, TF30, F101, J79 and TF41, as shown in Figures 37 through 42. A goodcorrelation was obtained for the LSP as a function of hydrogen content. The trend toward

increased radiation with decreasing hydrogen content is evident for all of the combustorsstudied.

20

,S. •~ ** ,*/.\-4~~ , ~-~%-- ~ - ~ . . U

-. -,...- ,-"-.W.'-

Page 33: Effect of fuel gas to GT

,%

50

,Fu, F( e Low ArOmat~cJPS. T, 278K

oW. :4NO 1

q " , (.) No 6 T, 278K

U ~A No?7

,25? 0s [ NO 8

•v LOW AromatC JPS. 1. 238K

20 Y NO I T, 253K

WJUNo a T. 26CK

. 18 kq,. (fels are Characle ized

rn Relerence 51

q (T, Fuel IntlI Temperature)

10

OW

0, 05 0,1 t; 08 00

Cl hod,, {ha~sl..IOl. I',mla~teCI~l

- Figure 1. Relationship of TF30 Combustor Operating Parameter to Fuel CharacteristicParameter

W. 127 kg/s W, 189 kg/S

W. 2 52 kg/s

E 9 3 4 kg/s

%/

W /

05 10 15 20 25 30 35 40 45 0 55

Combufslor Operaltnq Pafamelw

" Figure 2. Effect of Combustor Operating Parameter on TF30 Relight Altitude

21

,W -q. ,'1*,-'..''' ' .,,., - ';," ;..,,,-...- ."', .- .. ' %.; - ., - , '' ';

Page 34: Effect of fuel gas to GT

2.0

S..- ,

A F u e l L e g e n d

S0 JP-4 Baseline

*Z .IP-4 (Shale

OA E9 Blend No. I

A. Blend Na. 20.1 .0 B le n d N o . 3

* .% I.W. 4.03 kg/s C : Blend No. 4

, J P -4 R e -b a s e li n e

-A (Fuels are Characterized inW. 2.01 kg/s Reference 1)

0.5

r 0.25 0.30 0.35 0.40 0.45

Fuel Characteristic Parameter

Figure 3. Relationship of TF33 Combustor Operating Parameter to Fuel% Characterization Parameters

W, 2.01 kg/s W. 5.04 kg/s

W kEs1 12

a

9 W , 80 g/s

6

0 0 5 1.0 1.5 2.0

Combustor Operating Parameter

%Figure 4. Effect of Combustor Operating Parameter on TF33 Relight Altitude

22

v,,,- .-. , *,', (,4.*, 5, .: . '. "..s .,- ,' -. " .." .," -. ,,' .- ,... -' ~. -. ~... ..-.- • . . - .. . . .

Page 35: Effect of fuel gas to GT

1200

Fl Mend0

1 iOO 0jP4 Bswinb

SBlend NO-

Blenid No. 2

1000 Bln o

in Reference 1

900 0

Soo

0.34 ko/s

00

55 - 500

0.2 k9/s~gl

(D 0.34 kg/S

(30.43 kg/s

0.57 IK919

400

4.40

Fuelamte Chjtwll Fuel

StWa

Re~atO~i~P FIO Coab~tT 0prting paraee

Figure parameter

23

Page 36: Effect of fuel gas to GT

12 12

W, 10 gi6

9 W, 7.6 10 kgs

, W. 0.23 k/

W0 50 0k/

W, 034 kq/%

6

SW 0 46 kg W. 0.23 kkg/

W5 1.0 .10 1 kk/s

I W* 03k/ I

0 200 400 M S00 1000 0 200 400 600 NO 1000 1200

C ombusor Operaming Pamer Combustor Operating Parameter

Figure 6a. Effect of Combustor Figure 6b. Effect of Combustor

Operating Parameter on Operating Parameter on

FO0 Altitude Relight FIO0 Altitude Relight

Combuatof Air Flow W- 0.57 kg/s

12 W, 6.93 - 10 ' kg/s

W, 6.3 10 3

kg/S

E '

5.67' 10' kg/s

'9

.aV~s, 0 200 400 60 O 1 20

Combustor Oper-tnOg Parameter

Figure 6c. Effect of CombustorOperating Parameter on

FIO0 Altitude Relight

24

Page 37: Effect of fuel gas to GT

600 7Fuel Legend

12 9' ~I 11 2. JP-8

10 23E500 4 3. JP-8 + Gulf Mineral Seal Oil, GMSO

CIS4. JP-8 + 2040 Solvents6 5. JP-8 + Xylene Bottoms

~400 6. JP-8 + Xylene BottomsC7. JP-8 + 2040

8. JP-4 + 2040

0300 x Fuel Number JPRange of Test Data11JP4+Xen

12 P4Xylene and GMSOE 200 (Fuels are characterized In

o Reference 2)

40 50 60 70Fuel Characteristic Parameter

Figure 7. Relationship of Combustor Operating Parameter to Fuel CharacteristicParameter - FI01

-'Fuel Legend

JP-4

90. <)JP-8 Seal Oil800 urrwAir low JP-8 Solvent

0 W - .9 k9/8 JP-8 Xylene0 JP-8 Xylene

700 x W - .00 q/tJP-8 SolventJP-4 SolventJP-4 Solvent

L? NO -JP-4 XyleneJP-4 Xylene

5W - JP-4 Xylene and Seal Oil

(Fuels are Characterized4W in Reference 3)

x300-

W. 2.267 kg/s200 L

00 o00 700 am 90 1000 1100

Fuel CherecWeiti~c Pwamot

* Figure 8. Relationship of Combu stor Operating Parameter to Fuel CharacteristicParameter -J79-17C

25

W.I

Page 38: Effect of fuel gas to GT

'.

0.250 kg/s Airflow

y = -10.4 + 39.396x

12.0 r2 0.8209-?,Fuel Legend

A JP-4

03 10.0 B JP-4 (Shale)Er IC Blend No. 1

S D Blend No. 2E Blend No. 3

•8.0 -F Blend No. 4

"', (Fuels are Characterized4In Reference 1)

6.0

F!

0.4 0.5 0.6 0.7Vaporization Index

0.480 kg/s Air Flow 9.0 0.960 kg/s AIr Flow

7.0 11

8.0 y - +2.831

60 B E +9.213xy -0.0675 .. 4723

+r 2 , 0.4723X. E 7.0 F

45.0 -r 2 0.8950U5.0 U.

E E~~ 6.00*O

4.0 A

5.0

V 0.4 0.5 0.6 0.7 0.4 0.5 0.6 0.7Vaporization Index Vaporization Index

Figure 9. FIOO Groundstart Data Correlation

26

NO'

.t.

Page 39: Effect of fuel gas to GT

S... . . - • :. . ' ., . .. , - . -. ." .

50.0 - 2.020 kg/s Air Flow

y = 0.9083 + 73.632xr2 0 .9 6 9 6 Fuel Legend

-C A JP-4 Re-baseline

0L o B JP-4 (Shale)~.40C Blend No. 1

40.0 - D Blend No.2U. B / E Blend No. 3iE F Blend No. 4

- (Fuels are Characterized/ in Reference 1)

30.0 A

0.4 0.5 0.6 0.7

Vaporization Index

3.530 kql9 Air Flow 80.0 5.050 kg/s Air Flow

60.0 y = 30.366 + 39.651x 0

r2 = 0.T433 r2 = 0.6283

EEB E

27

'oA'

4. 0.0

E 0. 0.5 06 0.E. . . .

440.

Figure 10. TF33 Groundstart Data Correlation

* 27%

Page 40: Effect of fuel gas to GT

70. 0.91 kg/s Air Flow70.0

a -G Fuel Legend* /A No. I T F -= 278K

.2 _/H B No. 4 TF - 278KU C No. 5 TF - 278K

60.0 D No. 6 TF - 278Ky 35.89 +,,3.9x E No. 7 TF- 278K-=35.894+ 13.961X F No. 8 TF 278K

L. _ r2 = 0.5985 G No. 1 TF - 253K.4,. H No. 5 TF = 238K

-- C) I I No. 6 TF = 266KJ(Fuels are CharacterisdV In Reference 5)

0 50.0

LaI

1.0 1.5 2.0 2.5

Vaporization Index

1.81 kg/s Air Flow 35.0 2.72 kg/ls Air Flow40.0 /1 / /r'".

y = 10.121 + 13.759x

= 0.8535 y 2.217 + 14.132xIr 2 0.9M

; 25.0c

.30.0A F

U.

c 15.020.0 I I, I .. I

1.0 1.5 2.0 2.5 1.0 1.5 2.0 2.5

Vaporization Index Vaporization Index

Figure 11. TF30 Groundstart Data Correlation

28Z,0 N

Page 41: Effect of fuel gas to GT

y 16.783 + 1 1.298x Fuel Legend

36.0 r2 =0.2514 A JP-4

G # 0, B JP-832. 01C JP-8 Gulf Mineral Seal Oil

z 2. D JP-8 2040 Solvent

.2po~pM E JP-8 Xylene Bottoms.n280F J- Xylene Bottomscc K 801 " G JP-8 2040

.01 -H JP-4 20401I JP-4 2040

L= 24.0 L 0 J JP-4 Xylenefoow in K JP-4 Xylene

0000 po - 000 L JP-4 Xylene and GMSO*~20.0 0 - CM DF

N 2D2 0 JP-4

(3 (Fuels are Characterized'I16.0 N in Referenice 2)

0.4 0.6 0.8 1.0 1.2Vaporization Index

Figure 12. F101 Groundstart Data Correlation (1.15 kg/s Air Flow)

29

Page 42: Effect of fuel gas to GT

Cold Day

-'12.0 y = 2.446 + 5.262x

r2 -0.7260 "*Cf

S10.0

.2k.0h 8.

(5 .0 J- ovn

AJP-4XeeF JP-8 Xln

.0 1.0 2. GJP-8 Solent

Ff D JP-8 Solvent

K JP-4 Xytene

F JP-8 Xylane

Vaporization Index HJ- ovn

J PP-Xle

K P- y.n

Stndr Da L JP- Xyen an Sea Oil. .. ....... * ~ ~ ~

Page 43: Effect of fuel gas to GT

Cold Day12.

y B. .163 + 2.445xm r2 = 0.2654

-" . ., s-

8..F of

IL G0.

C

/B8.0 Fuel Legend

A JP-4• B JP-4 + 2040

"9-0.4 0.8 1.2 C JP-4 + 2040Vaporization Index E JP-4 + Xylene

F JP-4 + Xylene and GMSOG JP-8

H JP-8 + 2040I JP-8 + 2040J JP-8 + Xylene

Standard Day K JP-8 + Xylene12.0 L JP-8 + GMSO

(Fuels are CharacterizedIn Reference 4)

y =7.283 + 3.093x

o r2 0.3457 0-

10.0 0.8 I

F

-'8.0B

0.4 0.8 1.2Vaporization Index

!A" Figure' I.I. TF41 Groundstart Data Correlation (0.79 kg/s Air Flow)

31. . . . . .....

b-?.* _t'....

Page 44: Effect of fuel gas to GT

Fuel Legend

98.0 A JP-4980B JP-4 (Shale)

C Blend No.65

D Blend No. 6

E. Bln o

S97.0

Y 98.51 - 1.91ex *

r2 =0.8292

IF0.5 0.6 0.7 0.8 0.9 1.0

Vaporization Index

Figure 15. FPOO Combustion Efficiency at Idle

Fuel Legend

A JP-4

B JP-4 (Shale)*64.0 C Blend No. 5

E Blend No.?7Bt F Blend No. 8

~63.0

I .~ y - 67.339 - 4.76x62.0r2 0.8154

61.0

F

F.04 0.6 0.8 1.0 1.2 1.4

Vaporization index

Figure 16. TF33 Combustion Efficiency at Idle

32

kQ 41..pt A.

Page 45: Effect of fuel gas to GT

.- %

~. .

96.0 Fuel Legend

A No. 1B No. 2C No. 3

-''D No. 4E No. 5 Low Aromatic jp-5F No. 6 Fuel Oil No. 2

;9 95.0 CGN.7Hydrocracked Gas oil

CF

"-Y = 95-678- 0.8355x

94.0 A r2 = 0.1008

1.0 1.1 1.2 1.3 1.4 1.5Vaporization Index

Figure 17. TF30 Combustion Efficiency at Idle

~~~99.3 I-

Fuel Legend

J. 99.2 A JP-4B JP-8

- C JP-8 + Gult Mineral Seat Oil (GMSO)99.1 "D JP-8 + 2040 Solvent

% W E JP-8 + Xylene BottomsC F JP-8 + Xylene Bottoms

G JP-8 + 204099.0E H JP-4 + 2040u' o I JP-4 t 2040

DJ JP-4 Xylene98.9 K JP-4 + Xylene

G L JP-4 + Xylene and GMSOy = 99.54 - 0.6048X M DF2

98.8 r2 - 0.6691

0.5 0.75 1.0 1.25

Vaporization Index

I'gur" I,' . F01 (fombustion Efficiency at Idle

33

.,.. .. .- .. . .- .... ,.., .- ...... '. .. -. ...... ...- .. -........... - '..- ,

Page 46: Effect of fuel gas to GT

IA

96.0 Fuel Legend

B JP-8

94.0 C JP-8 + Seal Oillot BD JP-8 + Solvent

E JP-8 + XyleneF JP-8 + Xylene

y =93.908 - 1.205x G JP-8 + Solvent- 93.0 r2 = 0. 1480 H JP-4 + Solvent

w I JP-4 + SolventM J JP-4 + Xylene

92.0K JP-4 + Xylene920*L JP-4 + Xylene and Seal Oil

M DF2

0

r0.2 0.6 1.0 1.4 1.8 2.2

Vaporization Index

Figaure 19. J79-1I7C Combustion Efficiency at Idle

98.0H

970 y 93.361 1 2.66X Z970 r2

=0.0946 0 Fuel Legend

A JP-4B JP-4 +2040

*C JP-4 + 2040E JP-4 + Xylene

L F JP-4 + Xylene and GMSO

94.0 CG JP-8

4G H JP-8 + 2040

'-K JP-8 + Xylene

93.0 BL JP-8 + GMSO

r 0.8 O 0.9 1.0

Vaporization Index

Figure 20. TF41 Combustion Efficiency at Idlep1 34

Page 47: Effect of fuel gas to GT

.... • - - -. -.,

-

0.20

y = 0.1657 + 0.0353x

r2 =0.9290 E/

- - Fuel LegendE

A JP-4/- B JP-4 (Shale)

,* C Blend 5N ' D Blend6

0.18 A/6 E Blend 7o1 ,i I I I B d

0.5 0.6 0.7 0.8

Vaporization Index

Figure 21. FlO0 Pattern Factor at SLTO

0.11

E y = 0.0738 + 0.0171x

0.10 r2- 0.2158

Fuel LegendU.

" oA JP-400 F B JP-4 (Shale)Q. B C Blend 5

D Blend 6

0.08 E Blend 7F Blend 8A

0.4 0.6 0.8 1.0 1.2 1.4

Vaporization Index

Figure 22. TF33 Pattern Factor at SLTO

35

-9"", , .,. , ,. " """" €"""""''" ''""' ''''' .,X...q'''"''' , .¢'.

Page 48: Effect of fuel gas to GT

0.14

0.10

0.08 A No, I

0.0% a NO. .0 2

%f D04 O% 1 0

"o . 2E ' o. Aor0.0 F ati 6 Lo ro0G0 NO. 6Fuel Oil NO 2r.G4

* 1.0' 7 N o. 8r c k G a s o il jrp .

1.0 N 0, 8Diego Fuel Marine _1.1 112or~t 1 .4.4)rz n ne .

__Figur"e

23. TP30 Pattern atra L,

0.4 Fuel Leend

8~ o -8 + SaioS0.3 Ovn

E JP-8 +Sletu.F jp.8 + Y enm + Solvent

+Solvent

0.4 y aoial Index 2.0jq

104

p iure 24. J79-17C P -nattern Factor at SLTO0

36

., .4..

Page 49: Effect of fuel gas to GT

Fuel Legend

A JP-40.36 y -0.1407 + 0.146x " B JP-8

r= 0.5018 C JP-8 + Gulf Mineral Seal Oil0.32 D JP-8 + 2040 Solvent

E JP-8 + Xylene BottomsF JP-8 + Xylene BottomsG JP-8 + 2040

o 0.28 F H JP-4 + 2040e I JP-4 + 2040

E. -- ;000 J JP-4 + Xylene0.24 -- K JP-4 + Xylene

L JP-4 + Xylene and GMSOA M DF2

0.20 H

0.16

0.4 0.6 0.8 1.0 1.2

Vaporization Index

Figure 25. FI1 Pattern Factor at SLTO

0.4

y 0.3498 - 0.0669x Fuel Legend

S,, o r2 = 0.1334 A JP-4"*%b tb,4,B JP-4 + 2040

FKmamamm C JP-4 + 2040D JP-4 + Xylene

.0.3 B : E JP-4 + XyleneF JP-4 + Xylene and GMSOG JP-8

E.I H JP- + 20401 JP-8 + 2040

J JP-8 + Xylene BottomsK JP-8 + Xylene BottomsL JP-8 + Gulf Mineral Seal Oil

0.2

0.5 0.6 0.7 0.8 0.9

Vaporization Index

Figure 26. TF41 Pattern Factor at SLTO

37

. . .... ...

Page 50: Effect of fuel gas to GT

L~47-

0.010/y = 0.9223 + 5.508 x /Fuel Legendr2 = 0.9346 / M A JP-4

0. /1 B JP-80.C JP-8 + Seal oil

G D JP-8 + SolventB Yl. E JP-8 + Xylene

o F JP-8 + Xylene0.006/ G JP-8 + Solvent

m//H JP-4 + SolventC//I JP-4 + Solvent

/ FJ JP-4 + XyleneK JP-4 +Xylene

0.004 L JP-4 +Xylene and Seal CHIAKHL M DF2

A.0.0 1.0 2.0

Vaporization Index

Figure 27. Effect of Vaporization Index on J79-1 7C Lean Blowout Fuel-Air Ratio

AA,-

y .37 - 0.4

4 3A JP-4 Re-baseliner2=020 B JP-4 (Shale)

c 0.020 C Blend No. 13D Blend No. 2

-IBE E Blend No. 3y 7 F Blend No. 4

0.010t

0.4 0.6 0.8Vaporization Index

Figure 28. Effect of Vaporization Index on TF33 Lean Blowout Fuel-Air Ratio

38

Page 51: Effect of fuel gas to GT

40

.4 30

4.0

-. .200

0 00

0F100/TF33 Fuels (Ref 1)

o J79 Fuels (Ref 3)

F1l61 Fuels (Ref 2)

1112 13 14 15Hydrogen Content - % wt

Figure 29. Smoke Point vs Hydrogen Content for the P100, TF33, FIOI, and J79-17C Test Fuels

* 39

9..~~~~PJ . **4 4.<.. . .

Page 52: Effect of fuel gas to GT

%. - .1. .

32.0. Cruise

28.0 y = 55.99 - 3.052xF r2 r 0.9251

24.0-- ,Fuel Legend

1 0. A JP-420.0 B JP-4 (Shale)E ,C Blend 5

D Blend 616.0 E Blend 7

F Blend 8(Fuels are characterized

12.0 In Reference 1)

12.0 13.0 14.0 15.0

Hydrogen Content - % wt

* ':..-.Dash

- 22.0 60.o SLTO

20.0,9.82 - 4.902C y 33.521 r2 0 .5288

1.141x

2 0.00.z

12.0 13.0 14.0 15.0 12.0 13.0 14.0

*. .. : Hydrogen Content - % wt Hydrogen Content - % wt

[ = Figure 30. FlOG Smoke Number/Fuel Property Correlation

_ 40

*,.. ,- -

,E -E4" F>/-IZ

tZ ,_' , ","., ' ',,.,,. -. -... i.,_. .. -. . ,- . .. . .• ,~i° Il l i ~ i i i - '- '- ? - i -- t ".,' " "- " ,. .-.-.' .. ,..",.-o-. CqI

l i l l : " : : i : " ' ' i , ' l - . e , - % , , , " l , '

Page 53: Effect of fuel gas to GT

Cruise 1

F y = 179.48 - 11.73x Fuel Legend

r= 0.936540.0 AJ-

B JP-4 (Shale)A C Blend 5E_ D Blend 6z 30.0 -- %E Blend 7

0 F Blend 8Ec 20.0

A

10.0 \

12.0 13.0 14.0 15.0

Hydrogen Content - % wtFD 256886

Cruise 2 70.0 SLTO

50.0 F % y = 169.35 - 10.53x

r- 0.9299 e.EFY = 113.94 - 5.408x

F r2 = 0.7236~40.0E !! . zz 40.0

0 .E 30.0 0

40.010

% A,% 20.0

% B

12.0 13.0 14.0 15.0 12.0 13.0 14.0 15.0Hydrogen Content - % wt Hydrogen Content - % wt

Figure 31. TF33 Smoke Number/Fuel Property Correlation

41

Page 54: Effect of fuel gas to GT

Ds

14.0

12.0

G A.

z' 2 3 1. 310.0

E0r2 =0.3258

8.0D

12.8 13.0 13.2 13.4 13.8 13.8 A No. 1Hydrogen Content - % wt B No. 2

SLTO C NO.3D No. 4E No. 5

16.0 F No.6A .. G No. 7

15.0 G -

1.0 Gy =-55 .513 - 3 161x-N.< r2 4..410

2z0 13.0

F E

12.0 00

11.0 D

12.8 13.0 13.2 13.4 13.6 13.8Hydrogen Content - % wt

%I.:

Figure 32. TF30 Smoke Number Correlation

42

'I.v

%; : ;.-,-.", ;2: ', , . :,, ,'.. .. : .:,.; .: ' . .-- '--- -. z ',.''. .. ..... -. ,.... .,.. :. .. .. .. ... . . . , m,, .r a.. ,,1.;, t .- . ' ,', "". La ,, '.L ", ,. 1

Page 55: Effect of fuel gas to GT

Fuel Legend

3.4 A JP-4Cruise B JP-8

C JP-8 + Gulf Mineral Seal Oil

3.0 D D JP-8 + 2040 SolventFe y =7.919 - 0.4386x E JP-8 + Xylene Bottoms

% 0.6175 F JP-8 + Xylene Bottoms,2.6 G H JP-4 + 2040

E I JP-4 +20403 41 J JP-4 + Xylene

*) 2.2 NK JP-4 + Xylene0J L JP-4 Xylene and GMSO

Co c M 2D1.8

1.4 A

1.4

12.0 13.0 14.0 15.0

Hydrogen Content - % wt

d 6.0 Dash ST

y 1.2-049x5.0 y =9.796 - 0.4687xry 2 0.3629 D 0.4. r2

=0.3979

-0.3629 0%

~~~. 4.4.0m~ml

E E 3. C~~.EE lM% %.. Co

2.0

12.0 13.0 140B. 20 1. 40 1.

ml2.0

2.40

120 1.0 1. 15. 12'' . 3.0 14. 5~~.0-.

Figur 33. FI mk Nm..u rpryCorlto

Page 56: Effect of fuel gas to GT

Fuel Legend

ii40.0 Cruise A JP-4

8 JP-4 (Repeat). cP-8F.lD JP-8 + Se

^^ v y 494.29 -6.258x E JP..8 + Solvent40.0 C.U341 A JP-4 yln

EB JP-4 (Reet_____

T JP-8 + Solvent20.0 1 JP-4 + Solvent

94 . J JP-4 + Solvent

FK K JP-4 + XyleneE0. G %J 6% LJP-8 + Xylene

10.0 M JP-4 + Xylene and Seal OIl:' . N DF2

0.0-12.0 13.0 14.0 15.0

%,t Hydrogen Content - % wt

Dash.20.0

SLTO" 40.0 I

E Y 99.3 - 5.93x

y= 33.90- 2.05x r- 0.4W

r2 = 0.4 100

"L % -' 10.02

10 20.0 L

A B 10.0 G

0.0 A

12.0 13.0 14.0 15.0120 3. 140 50Hydrogen Content - % wt Hydrogen Content - % wt

Figure 34. J79-17C Smoke Number/Fuel Property Correlation

44

° °ft '

.-

.,..

e , ' ' ' o , " € ." - " ..-

,. ." -. ' ,

" " h . - . - . o

" " ,

' ' " " ' ' '

Page 57: Effect of fuel gas to GT

Cruise

50.0Jy =10 1.157 -5.488x Fuel Legend

r= 0.2816 A JP-4

40.0 BE JP-4 + 2040

E C JP-4 + 2040n

30. HBD JP-4 + Xylene +GSE ftflta E JP-4 + Xylene00

440 H JP-8 + 2040.113-8 + 2040

J JP-8 + Xylene20.0 KK .11-8 + Xylene

L JP-8 + GMSO

F 12.0 13.0 14.0 15.0

Hydrogen Content -% wt

Dash 700SLTO

y =85.67-3.4071x

50.0 r 2 =0.2707 6.

c D y =111.57-5-.149lx

p45.0 % 0.2

B 50.0

.J1

40.0

co 40.0L

35.0E F A

% 30.0

12.0 13.0 14.0 15.0 12.0 13.0 14.0 15.0Hydrogen Content - % tHydrogen Content - %wt

Figure 35. TF41 Smoke Number/Fuel Property Correlation

45

.. - . ... ... .. . . . . . . ,..-.

Page 58: Effect of fuel gas to GT

Legendso F100 Rig Ref 1

TF33 Rig Ref 1

40 TF30 Rig Ref 5

i' Prediction from Ref 14

,30 E

200I 0

20

S..

,., 10 0: , . mltm

0 10 20 30 40 50 60 70SAE Smoke Number

Figure 36. Correlation of Particulate Concentration With SAE Smoke Number

4.

46

Page 59: Effect of fuel gas to GT

0.55 Cruise

y = 0.7388-0.0268xF r2

= 0.27970o5o

Fuel Legend

4%A JP-40.45 S% JP-4 (Shale)

C Blend 5C Dled

D Blend 7

7~0.40 F Blend 8

0.35 E

0.30L

12.0 13.0 14.0 15.0 'SLTOHydrogen Content - % wt_________

y =0.465-0.0074xDash r2 = 0.6878

1' 0.38 ~ =O O x0.38 FF r2 0.6432 .

0.37 1- 0.37EIN-

I.-. AIDI0.36 ~30.38

0.35 0.35 \

12.0 13.0 14.0 15.0 IF 12.0 13.0 14.0 15.0

~0Hydrogen Content - % wt Hydrogen Content - % wt

V.

4 Figure 37. PIOO Liner Temperature Correlation

% 47

Page 60: Effect of fuel gas to GT

1.2 Cruise I

y = 2.86-0.1596xF r2 - 0.9813

1.0

*Fuel Legend

, 0.8 A JP-4B JP-4 (Shale)i > C Blend 5

D Blend 6

0.6 E Blend7KF Blend 6

0.4

r 12.0 13.0 14.0 15.0.

Hydrogen Content - % wt

Cruise 2

y =2.356-0.1104x SLTO1.2 r2 - 0.9129 0.86 ___

F y - 1.15-0.0oxr2 -0.4117

F 081.1 ,,

~. EI~ 0.7E~' 1.0

0.9 0.74

0.8 A 0.70.

0.7 I0.66

12.0 13.0 14.0 15.0 12.0 13.0 14.0 15.0

' Hydrogen Content -% wt Hydrogen Content - % wt

Figure 38. TF33 Liner Temperature Correlation

48

* °

'4 °

,,, ' . -' "1 ' ', -.. -. .. -... .. " ... . ' 2,::i. *- .. .:, " :",. ** -*."..*z .:.". -." .:" :",.-. "-", - -. . ..'" -"-.... .

Page 61: Effect of fuel gas to GT

Dash - Low Pressure

0.4

%H %%

.4

40.4

0.4 = .7688O.0263x /%%

r 2 = 0 .7 2 8 B % % E DF u e l L e g e n d0.40 '

412 13. B No. 2r1. 30 13.2 13.4 13.6 13.8 C No. 3Hydrogen Content - % tD No. 4

E No. 5F No. 6

Dash - High Pressure G No. 70.55 H No. 8

*4 Y = 0.81346--ov02xr= 0.9146

0.54 G

0.53-

0.52 E

0.51%%

12.8 13.0 13.2 13.4 13.6 13.8a Hydrogen Content - % wt

Figure 39. TF30 Liner Temperature Correlation

.449

Page 62: Effect of fuel gas to GT

Cruise0.38

0Fuel Legend

F y - 0.4585-0.0092X A JP4F\ 0.2378 Bj-., B ,JP-8/. C JP-8 + Gulf Mineral Seal Oil

." D JP-8 + 2040 Solvents

0.34 E JP-8 + XYlene BottomsMF JP-8 + Xylene Bottoms

E' G JP-8 + 2040A H JP-4 + 2040

LI JP-4 + 2040J JP-4 + XyleneK JP-4 + XyleneL JP-4 + Xylene and GMSO

0.30 M DF2

* 12.0 13.0 14.0 15.0

" Hydrogen Content - % wt

Dash SLTO0.50 F

FD 0.48 D

0.48 y - 0.6549-0.0161x - 0.6726-0.0188xr2 - 0.3327 r2 - 0.3664

0.46

,,I~ . 46 0 4

0

0.42

0.40L 0.40

. 12.0 13.0 14.0 15.0 12.0 13.0 14.0 15.0

Hydrogen Content - % wt Hydrogen Content - % wt

Figure 40. F101 Liner Temperature Correlation

50

,0

Page 63: Effect of fuel gas to GT

Cruise

0.4 y = 0.82-0.0438x Fuel Legendr2 = 0.4542 A J 5P-4

k F A8 JP-40.3 C JP-8. HD JP-8 + Seal Oil

%%-, - E JP-8 + SolventI. F JP-8 + Xylene

K G JP-8 + XyleneV-0.2 A H JP-8 + Solvent

I JP-4 + Solvent-:=B J JP-4 + Solvent

K JP-4 + Xylene0.1 L JP-4 + Xylene

M JP-4 + Xylene and Seal Oil

N DF2

12.0 13.0 14.0 15.0

Hydrogen Content - % wt

Dash SLTO0.72 0 y = 1.234-0.0324x,: 072O. E' f =0.40024

E y 1.23-0.046xr 2 =0.2406r' = 0 H79 53 H

*60.68 % 2 =075G

.8 K %%% q

'.0.64

D I-r 0.80Nr- 44 0~0.60 S

K 4

F12.0 13.0 14.0 15.0 12.0 13.0 14.0 1.

SHydrogen Content - % wt Hydrogen Content - % wt

~Figure 41. J79-17C Liner Temperature Correlation

.15

.4. ."A N'-".. ',,,.- -...- '. .'.;. .;

Page 64: Effect of fuel gas to GT

'lux It- C t - r ., . C. e. e . 47- . . 1 s .r~.

1.0 H

B JP4 + 2040y ,-y 1.442-0.0669x C JP4 + 2040

; .. 0.8 E JP 4 + Xylen e,-F JP.4 + Xylens and GMSO",-'zG JP-8

-0 . 7 Sos H JP-8 + 2040"-I JP8 + 2040

r DJ JP-8 + Xyhe"0.0-D K JP-8 + XyleneL JP-8 + GMSO

12.0 139.0 14.0 15.0

Hydrogen Content - % wt

'i " - LTODa0h 0.68

00.72

D y - 0.8216-0.0139x• *:', • i - 0.49100.70 B He;-+.2040

Y -y , 0.90 3-J0.0217X 4

DB o..+Xyen-S.~r 0. K.77 AP Xltz L.6 0.64 +GS

D ° .

0.6

12.0 13.0 14.0 15.0 12.0 13.0 14.0 15.0Hydrogen Content - % wt

Hydrogen Content0-0%1Wt

Fiur 42 1LnrTmeaueCreain

I

4:.

":-:':Figure 42. TF4I Liner Temperature Correlation

....

52

$P

Page 65: Effect of fuel gas to GT

SECTION IV

• -. ENGINE DESIGN AND OPERATING CHARACTERISTICS CORRELATIONS

A. ALTITUDE RELIGHT CORRELATIONS

The evaluation of fuel property effects on altitude relight capability was presented inSection III-B, where the correlation groups of fuel characteristic parameter (FCP) andcombustor operating parameter (COP) were developed. The original objective was to separatethe various parameters of interest into the two groups, i.e.: (1) fuel properties, and (2) combustorgeometry and operating condition terms.

The problem which arises from this approach is that the FCP term contains the Sautermean diameter (SMD) of the fuel spray, and the SMD contains engine design as well as fuelproperty variables. The manner in which the fuel properties affect SMD varies, depending onthe type of fuel nozzle employed in the design. For this reason, the engines were separated intothe three following classes depending on the fuel nozzle type:

1. Pressure atomizing2. Airblast3. Hybrid.

The fuel effect data which were used for this portion of the study were taken from F100,F101, TF30, TF33, and J79 combustor tests. The F100 and F101 utilize forms of airblast fuelnozzles, the TF30 and TF33 use pressure atomizing fuel nozzles, and the J79-17C is a hybriddesign. The FCP and COP which is used in each of these three groups depends on the fuel nozzletype. The pressure atomizing and airblast designs utilize the previously defined (Section III-B)equations to predict SMD and hence, FCP and COP.

The general equation for COP has been modified from the earlier equation to account forthe variation in COP with engine airflow. The resultant equations are:

pf(SMD) 15

r r - In(1 + B) (19)

. Pr,(Tu/100)5 U 5

P.' A W. (20)

*v. where:

pf fuel density g/ccSMD Sauter mean diameter m-

B Spalding mass transfer numberPra Air Prandtl numberTu Turbulence intensity %U Air velocity m/sPa Air density g/cc

Air viscosity N/m 2 .sEquivalence ratio

W. Combustor air flow kg/s

For fuel nozzles where a usable correlation of SMD vs fuel properties was not available, (eg.J79-17C), this equation set may be used directly. The results of the previous fuel effects

53

* *:

% 5e S

iI~S~* *S'& * * 4 ~ 4 **** *

Page 66: Effect of fuel gas to GT

correlation are shown in Figure 43. The data scatter which is observed is typical of the results forthe altitude relight data. This figure may be used directly to evaluate fuel effects for a designwhere the user is aware of the effect of the properties on the SMD.

For a design where an equation for SMD as a function of fuel properties is available e.g.,pressure atomizing and airblast fuel nozzles, the various fuel properties may be introduced intoFCP and COP directly.

For pressure atomizing fuel nozzles, the resulting equations are:

.3 .9

FCP - n(1 + B) (21)

= Pr.(Tu/100) "5 U'5 W-37CO P .6 .0 Ap 6WP.5 $ AP W (22)

where:•f = fuel kinematic viscosity m2 /saf = fuel surface tension N/mAPf = fuel pressure drop kPaWf = fuel flowrate kg/s.

Test data from the TF30 and TF33 are shown in Figures 44 and 45. The figures are basedon COP from Figures 1 and 3 divided by the air flowrate. The two curves were normalized withreference to JP-4 fuel properties and plotted in Figure 46. A regression equation is shown whichcan be used to evaluate the fuel properties effects on altitude relight capability for pressureatomizing fuel nozzle combustors. The majority of the data are within ± 10% of the regressionline.

The same approach was used for the airblast fuel nozzle designs where the SMD wasrelated to fuel properties and operating conditions. This yielded the following equations:

FCP = fn(l + B) (23)

= Pr(Tu/100)'5 U5 (1 + Wf/Wa) .5

CP AP, (24)

These equations were applied to the F100 and F101 altitude relight data. The data fromthe F100 tests were significantly more scattered than the F101. The same trend was basicallyobserved but the scatter was excessive for use in this correlation. The F101 data showed thetypical 10 to 15% scatter and were used as representative of airblast fuel nozzle behavior. Theresults are shown in Figure 47. These data should be used to define the fuel properties effects onaltitude relight for alrblast fuel nozzle combustors.

54

, 8

Page 67: Effect of fuel gas to GT

'. . .. - .

1.2

1.0

0.

00

00

* 0. 8

0.7

P, 0 0 w0.8 f( M / M~ p4).

.o.

1.0 .2 .4 16 18 2. 20

0.7 0C~b,

Figure~~~~PrTu 43.)0 Baiuliue eih 05eainWt J9cDt

Pa 05 Ma 4i 55

Page 68: Effect of fuel gas to GT

-. ". ". "- ..... -. '. - - . ." ." " . - . ," ] < -. . ". ' .

, 16 Fuel Legend

0 Low Aromatic JP5. T, - 278K.14 VNo.1

0. 0No. 4S 12 No. 6 Tf = 278K

12 1,-No. 7

1 Low Aromatic JP5. T, = 238K-, .10 0 T% " No. I T, = 253K

Q- No. 8 Tf = 266K

8S

00 6

'4I I I I I I

0.5 0.6 0.7 0.8 0.9 1.0Fuel Characteristic Parameter (FCP)

Figure 44. TF30 Altitude Relight Correlation

0.40

0 40 Fuel Legend

JP4 Baseline

IL 0.30 * Blend No. 3

Blend No. 4

0

0.200.25 0.30 0.35 0.40 0.45

Fuel Characteristic Parameter (FCP)

Figure 45. TF33 Altitude Relight Correlation

9.5" d" "t ' - + ', * " ',-' q-, '+* * '. -, ''.' .". .' ,'. , ' '. " '. ," ".5-6

' " ",%,,-.".". •" * ,",•• ," , . ." ' ''. " " ,-,' -. ". " 5," " . A . . " , - '•"•.. " "-•,. .-. _A

Page 69: Effect of fuel gas to GT

*Legend

E11 0 TF30

131 TF33

1.0

N00.9

El (DEl

0 0.8

0.0o o

0.7 (0

0.6

COP FCP/ < ~w= 1.27-0.27 <FC ".

0.5

0.4

1.0 1.2 1.4 1.6 1.8 2.0 2.2

FCP/(FCP)"

Figure 46. Pressure Atomizing Fuel Nozzle Altitude Relight Correlation

57

- 11I *, 9 . . = j .* o .*,- o t .. = :o ***. .* *:.c. - "- " h • * .* .". . . ... .

Page 70: Effect of fuel gas to GT

.. 1.

-q

00

1.3.--

• 1.2-

%:4 1.1

0,

0.9 0

00 -- 0i 000 0.8

0 0 0.7

FCP = Pf 1.15 Of 0.9

0.6 In (1+8)

COP = Pr, (Tu/100) .5 U0 .5 (1 + Wt/W) S

0.5 . -. 5 AP. 0 .

0.4

0.31 I I I I I I, 1.0 1.1 1.2 1.3 1.4 1.5 1.6

FCP/(FCP),"

-U" Figure 47. Airblast Fuel Nozzle Altitude Relight Correlation

trA.6

V%

Page 71: Effect of fuel gas to GT

The application of these three altitude relight correlations to evaluation of the effects offuel properties variations on the altitude relight capability of a given engine is illustrated belowwith reference to Figure 48:

1. For a given engine design and known altitude relight limit on a baselinefuel, calculate the baseline fuel properties and engine parameters.

2. For the appropriate fuel nozzle type, calculate the baseline values of FCP

and COP.

3. For the new fuel properties, calculate the value of FCP.

4. Using the appropriate fuel effects on altitude relight curve, with the valuesof FCP and COP for the baseline fuel and FCP for the new fuel, calculatethe new value of COP.

5. Using the engine performance map or cycle data, relate the change in COPto changes in relight altitude for a given flight condition.

This procedure is typical of the approach towards evaluation of the effect of variations infuel properties on not only altitude ignition, but several other engine operating parameters.

B. COMBUSTION EFFICIENCY CORRELATIONS

The effect of fuel properties on relative combustion efficiency is most noticeable at idleconditions. At power levels above this, the combustion improves towards essentially 100%efficiency and no measurable fuel effects are observed.

Based on evaluation of the relationships between combustion efficiency at idle and variousfuel properties parameters, the data are best correlated with the vaporization index (VI):

V P f(SMD/SMD .f) 2VIa ln(1 +B) (25)

Excellent correlations were obtained with data from the F100, TF33, and F101. The datafrom the TF30, J79 and TF41 showed significant scatter, but consistent trends were identified.

The fundamental principle is that the idle efficiency is controlled by the ability of the finalportion of the fuel spray to vaporize rapidly enough to react before leaving the combustor. For

.4 this reason, the mass transfer number in VI is evaluated at the appropriate 90% recoverytemperature. As the value of VI increases, the tendency to vaporize decreases and thecombustion efficiency should also decrease.

This last statement leads to selection of the slope of the regression of efficiency versusvaporization index as the correlation parameter for engine variables. The appropriate resultsfrom the fuel properties correlations are shown in Table 11.

.5

3 59

............................. ;.q-.v 5 v/

,;...~ ... ..- , , - .* .. ', , . .':- q--.:-.......* . . . *... ... ..:.'.. .;';....._. ,.'... ' .... , , : , ,.,.,= ,,.,, ,_-._- - .. -.,' ._ _ _ _ _ -. . ... . . . . .

Page 72: Effect of fuel gas to GT

[Baseline Engine

I Baseline Fuel

BaeieEngine Cycle Parameters

I aew Fuel Properties 1

New Fuel Charerth Parameter j

Naew Combusto r Parameter

Ne uCha erCnistionsrmee

ERTo E Cobs orret ION

WITH IDLE COMBUS-

Combustion Slope ofEfficiency on Efficiency ys

Engine Base Fuel Vaporisation IndexF101 99 -0.60F100 97.5 -1.92TF30 96.5 -0.83J79-17C 93.0 -1.21

%TF33 65.0 -4.76TF41 96.0 2.66

From this table, one obvious conclusion is that the TF41 data show a trend counter to theother fuel effects data. This trend also cannot be supported by theory. These data weretherefore omitted from the combustion efficiency correlation.

60

.1'. 2.

Page 73: Effect of fuel gas to GT

Evaluating the behavior of the three engines with very good statistical correlations yields:

Engine Base Efficiency Slope

F101 99 -0.60F100 97.5 -1.92TF33 65.0 -4.76

The trend which is observed is that the lower values of base efficiency are also more sensitive tofuel properties. This is a logical conclusion in that high efficiency implies greater time toaccommodate the slower fuel vaporization.

These data are shown in Figure 49. The solid bars represent the range of data which was

used in the regression analysis and the slope is the same as generated by that analysis. The linesdrawn over the bars represent the data correlation which would be required under theassumption that the slope is proportional to inverse base efficiency. As can be observed, the onlydata which require modification from the computer generated slopes are the two sets for whichlarge scatter was present in the data, and it is problematic as to which curve fit actuallyrepresents the true behavior. Typical data scatter is indicated on the J79 curve.

Engine (R2)

F101 (0.67)

54 95F100 (0.83)

TF30 (0.10)o90 -J- 17C (0.15)

" 851

. 80

•o7570

"- 656TF33

(0.82)

600 0.5 1.0 1.5 2.0 2.5

Vaporization Index

Figure 49. Idle Combustion Efficiency us Vaporization Index

61

•. .,'..,,..%,...*-..--..-.,.. .-, .....*..-. .. ...,.... .,.... . .. *.*..-./ . .. . -. .,........ .. --.. ,---,.. ,...-,,.-,~ 9*.~.. -.... .*.* * N

Page 74: Effect of fuel gas to GT

To correlate the sensitivity of idle efficiency versus vaporization index as a function of theengine parameters, an equation for idle efficiency is introduced. This equation, developed inreference (15), is:

Q, - loglog( 100) f (1.42 + 0) log 0.068, [-W'- . (10_. ,T3-=#_os)

+ (2 - 2.500) (26)

Where: Q' = Combustion efficiency correlation parame-ter

i. c = idle combustion efficiency %0 = primary zone equivalence ratioW a = primary zone airflow kg/sV = primary zone volume m3

P = combustor pressure kPaT 3 = inlet temperature. K

The results of this equation plotted against the derived slopes of efficiency versusvaporization index are shown in Figure 50. An excellent correlation is observed for these data.The correlation as presented here may be used to evaluate the effects of fuel propertiesvariations on idle combustion efficiency as follows:

1. For a given engine with known efficiency on a baseline fuel, calculate thebase value of the vaporization index (VI):

V p= pf(SMD/SMD,. 4)2

VI In(1 + B) (27)

2. Calculate the correlation parameter from:

Q.= loglog( 100)"C (28)

3. From Figure 50 read the value of A J/A VI corresponding to Q'

4. Calculate the value of the vaporization index for the new fuel properties

5. Calculate a new value of combustion efficiency at idle from:

17 new = Y) base + - 1 -(VI,. - VI..) (29)

062

"V.

.s,

62

%*" %'. ".~.' V. .'........... ,.,.'. ." ... "'.."...... .•................. ......... ,"."•.L.... ......... " ",.'..

Page 75: Effect of fuel gas to GT

In addition to this 1)r(x.e(hire, the correlation may be used to evaluate the impact of designchanges on the sensitivity to fuel properties. To evaluate this effect the following procedure isused:

1. For a baseline and revised combustor design with known baseline idleefficiency, calculate Q' and Q'.

2. Calculate the factor:

log!og.?Igeog m (30)

3. Read the sensitivity correlation curve at this factor value to obtain the newdesign sensitivity to fuel properties. The curve should also be read at loglog (100/,c) to obtain the baseline sensitivity.

This procedure may be readily accomplished in either manual calculation or computer modes.

-5 TF33

-4 J79-17C

-.3 TF30

~F100•, -2

-1 F101

0 L I I Ij0 -0.5 -1.0 -1.5 -2.0 -2.5 -3.0

S.. a,

where:

0' = (1.42 4 .) log0.0680 jV-±€,. (10 °' 2 0 °T 3 202 ) +(2-2.50)

Figure 50. Idle Combustion Efficiency Sensitivity vs Engine Correlation Parameter

C. GROUNDSTARTING CORRELATIONS

The process of groundstarting is controlled primarily by the formation of a vapor-phasefuel-air ratio within certain limits at relatively cold inlet temperatures. The correlatingparameter for fuel properties which was selected is the vaporization index (VI) based on the10% recovery temperature. This parameter, as shown in Section III-B, yielded statisticallysignificant correlations for the F100, TF33, TF30, F101, J79-17C and TF41 engines.

63

Page 76: Effect of fuel gas to GT

S

Data from these combustors were correlated against differences in combustor design andoperating variables through an analysis of the conditions which exist in the region of the ignitionsource or primary zone. The procedure which was employed was to utilize the computer-generated correlation curves from each engine test to calculate a value of the groundstart fuel-air ratio at a uniform level of the vaporization index and then correlate these values againstcombustor operating parameters. This approach minimizes the influence of experimentaluncertainty associated with individual fuel tests on any given combustors.

The fuel properties correlations were presented in Section II. The general form of theregression equation is:

x = xo + x,. VI, (31)

Where:x = minimum fuel flow rate or minimum fuel-air ratiox. = constantxi = slopeVI = vaporization index based on 10% recovery temperature of fuel.

Data are available at several airflows for the F100, TF30 and TF33 engines and severalinlet temperatures for the F101, J79-17C and TF30 engines. The data regressions were either onfuel-air ratio or minimum fuel flowrate. Those which used fuel flow were converted to fuel-airratio.

The selected correlation parameter for engine differences is U/PT, where:

U& = air velocity at igniter, m/sP = pressure, MPa

.V T = inlet temperature, K.

The velocity at the igniter is evaluated by using the combustor cross-sectional area at the igniterlocation and the total air flow through the combustor at that point. Using this parameter, all thetest data were in the range of 0.03 to 0.29 m/MPa-K-s.

The fuel-air ratio, which was calculated at VI = 0.5 from the correlations, was corrected tothe value at the igniter by using the percentage of total airflow at that location. This is referredto as the primary zone fuel-air ratio. Thus:

()W.")( 100 )Q90 'W--' %W. in primary (32)

The results of this analysis are shown in Figure 51 for two values of the vaporization index,i.e., VI = 0.5 and 1.0. The TF41 data are not shown due to a lack of definition of the airflow

,9. splits. A definite trend of primary zone fuel-air ratio with the correlation parameter is derived.At low values of the parameter, large fuel flowrates are required and as the parameter increasesthe required fuel-air ratio decreases. The trend is consistent for all five combustors evaluatedand is statistically significant.

64

Pr

Page 77: Effect of fuel gas to GT

0.30-

TF33

0.20 Q F101 Open Symbols V = 0.5TF30 Closed Symbols VI = 1.0

0.15 =J79-17C,F100

: 0.10 0

?,0.03

0.06 0 %W1- VI 1.0

o 0.06 VI= .0N 0.05N.

20.04

0.02

0.01 10 0.5 0.10 0.15 0.20 0.25 0.30i In

U/PT MPa-K-s

.:

Figure 51. Groundstart Correlation at Two Values of Vaporization Index

To determine the influence of the vaporization index (VI) on the minimum groundstartfuel-air ratio, the difference between the values predicted for different levels of VI werecorrelated against the operation parameter, U/PT. The results are shown in Figure 52, where theratio of the primary zone fuel-air ratios at VI = 1.0 and VI = 0.5 are plotted against U/PT.

A correlation is shown where this ratio is initially quite large and decreases as theparameter increases. Beyond a level of about 0.10, the ratio again increases. Although data arenot. available beyond about 0.30, it is anticipated that the ratio will ultimately decrease orbecome asymptotic.

The low values of U/PT, i.e., below 0.10, show significant scatter in the fuel propertieseffect. Extension of the correlation lines on Figure 51 indicate a decrease in the fuel sensitivitybelow a 0.10 while the specific data points show a strong upward trend. The most likely effect isstrong dependence on fuel propeties at these difficult operating conditions.

65

Page 78: Effect of fuel gas to GT

2.0 0

6 1.8 El~ II I

5 1.6

0 TF33

.4 - 1.4 F10

12( F1011.2 0 J79-17C

1.00 0.5 0.10 0.15 . 0.25 . .35

Up-- at Igniter - .-,M,,4

FO 2M27

Figure 52. Sensitivity of Groundstart Fuel-Air Ratio to Vaporization Index

The results of this analysis may be utilized to evaluate the fuels effects as follows:

.1' * For a given engine design and groundstart conditions, calculate U/PT aspreviously described.

0 At this value of U/PT, from Figure 51 read the value of f/a for VI = 0.5 andthe sensitivity factor, P, from Figure 52.

0 For the given fuel, calculate the value of vaporization index based on the10% recovery temperature.

* Calculate the value of the primary zone f/a with this fuel from:

f/a,,- f/a(v .5) (1 + (01,- 1) . VI .5 ) )

This procedure may also be used when the groundstart capabilities on a given fuel areknown. The procedure is as follows:

" Calculate the known fuel and engine values of U/PT and Vile," Calculate the VI of the new fuel,• Read Figure 52 at U/PT to obtain#,* Calculate the new fuel groundstart fuel-air ratio.

66

k '.,,b , ';,,- :- . - . * ,. ..:,"-, .;- ,- .. ,... .;.,.' ,* 2'-s -."".','' '''- .. : v -- .,

Page 79: Effect of fuel gas to GT

D. COMBUSTOR PATTERN FACTOR ANALYSIS

Combustor pattern factor is defined as:

P. F. T4 - T4• .F -- T4.,,. : (34)

Io where:

T 4 = Combustor exit temperature, KT3 = Combustor inlet temperature, K

This index was previously correlated against fuel properties by use of the vaporization index(VI) based on the fuel 90% recovery or distillation temperature. This index was selected afteranalysis of several fuel properties' parameters. It is felt that this parameter correlates best withpattern factor since the larger amount of time required to vaporize the less volatile fuels reducesthe time available for mixing to uniform exit temperature.

A summary of the VI correlations for six combustors is shown in Figure 53. These curvesrepresent the mean data line which was obtained from the statistical regression analysis of thereported engine data as previously shown in Section III. The pattern factor data for mostengines exhibited a large degree of scatter, which is evidenced in Figure 53 by the apparentbehavior of the J79-17C and TF41 engines. The deviation in the trends is probably partially theresult of the difficulty of these tests.

The prediction of pattern factor in a combustor requires evaluation of the quantitativeeffects of fuel nozzle and swirler design, primary zone aerodynamics, and dilution jet behavioramong other parameters. As would be expected from this degree of complexity, there is littleagreement as to a design system approach to pattern factor evaluation in engine design. Anattempt to relate fuel properties to pattern factor changes through one design system or anotherwould introduce the additional uncertainties associated with the system itself.

To avoid this problem, an approach was taken which relates the effect of fuel properties onpattern factor to the level of pattern factor of a base fuel. This trend is essentially one where thecontrolling processes are represented by the base fuels correlation and as that fuel parametertrends towards less efficient combustion, the pattern factor increases. This approach eliminatesthe problems inherent in the design system.

A correlation of the sensitivity of pattern factor to the vaporization index (VI) versus thebase pattern factor in JP-4 fuel is shown in Figure 54. The data for the J79-17C and TF41 weredeleted from this correlation. A definite trend of increased fuel sensitivity as pattern factorincreases is demonstrated.

67

Page 80: Effect of fuel gas to GT

0.40

TF41I..':','.S

%Q~ ",S. --* -~l -J

0.30 T4 *m

J79... ..... o o .

-- ~ °--@°°"°e°e..o

c 0.20 F101 "

C F0100

,- .*.

0.10 --

TF30

TF33

,,00 0.50 1.00 1.50.:Vaporization Index

~Figure 53. Pattern Factor Correlations vs Vaporization Index

'8

-- "%

,,".,,

Page 81: Effect of fuel gas to GT

b. ° .,. , % ,,.. - '% . ? ,L , , , . .,- . °' > ,,. . . . ;.-.o ...' -- - ~- . . . , .-V . -

0.15

0 F101

.2

x0

0.

E0.1

0

a

0.05

0 0.10 0.20 0.30 0.40Base Pattern Factor

Figure 54. Pattern Factor Sensitivity vs Base Pattern Factor

69

Page 82: Effect of fuel gas to GT

t'he recommended procedure for evaluation of the sensitivity of the pattern factor for agiven combustor to changes in the hydrogen content of the fuel is as follows:

• For a combustor whose pattern factor is known on the base fuel, read thecurve from Figure 54 to obtain the sensitivity.

For a design with unknown base pattern factor, it is necessary to first* 4 estimate the base value using a design methodology acceptable to the user.

This estimate may then be used to enter Figure 54 and obtain the sensitivityfactor.

. For either case, the projected pattern factor on the new fuel is calculated9-. from:

PF.. = PFI.. + (APF./AVI)(VI--VIb,)i::i (35)

This value yields a representative response of pattern factor to fuel properties variations.

E. SMOKE EMISSIONS

The correlation of exhaust smoke number proceeded in a manner similar to the patternfactor results. The fuel property which was selected as most representative of the combustorresponse is the total hydrogen content of the fuel. The results of the regression analysis of thedata are shown in Figure 55. The lines are the mean value relationships from the regressions.

A trend may be observed here which follows the same behavior as previously noted, wherean increase in the smoke number on the base fuel is accompanied by an increase in thesensitivity of the smoke level to changes in the fuel hydrogen content. This effect may be used todevelop a response relationship for prediction of smoke level on proposed alternative fuels.

As with pattern factor, this approach was selected due to the current uncertaintiesassociated with any specific quantitative model for general smoke emissions. The responseanalysis is shown in Figure 56. This curve is used in a manner similar to pattern factor toevaluate the smoke level of a proposed new fuel.

:70

,..

-p

! --9-

Page 83: Effect of fuel gas to GT

60

.1k.

"-+50 N%

"Z 30

, . " F100 SLTO

0

40

TF300_ F100 Dash

SLOF100 CruiseTF30

lOF3Dah '4 F0Ds

10h % TF33 Cruise

= ° ° °,° F101 SLTO/Dash

.0 00I0I - F101 CruI se

10 11 12 13 14 15 16

" Percentage Hydrogen in Fuel

Figure 55. Smoke Number vs Hydrogen Content Correlation Results

71

., ¢-.-. " . , . .,".- ,. ..-. " -..- .. -. , .. ., - , , . . .. . .

Page 84: Effect of fuel gas to GT

00

- I-

0

E

ElC

8 Co

E) E]000L

U cJ

IW

H % v/eqn 94W

72I

%.

J , . -1; :Z.

Page 85: Effect of fuel gas to GT

& '-~., . ., .,3 *.W. *-, *b. *3. -,W * . t.1,. - ._,.-. r. , '-" ' . '.'_ - :o" - : _-77

F. COMBUSTOR LINER METAL TEMPERATURES

The effect of the fuel properties on the combustor liner temperature was correlatedthrough the use of a Liner Severity Parameter (LSP) which was defined as:

T. TL(vm) - T3

(36)

where:

T3 = combustor inlet temperatureT4 = average combustor exit temperature.

This parameter was correlated against the total hydrogen content of the fuel. A typicalcorrelation set over various engines is shown in Figure 57 at sea level takeoff (SLTO) conditions.The degree of correlation is, in general, quite good.

The use of hydrogen content as the major fuel property is not surprising. An increase in1, smoke is directly related to an increase in the radiation level to the liner walls. The degree of

correlation shown in Figure 57 is good, considering the differences in the cooling methods andeffectiveness of the various engines.

Correlation across the various engine designs was done in the same manner as for patternfactor and smoke number. A quantitative analysis which predicts the maximum metaltemperature of all combustor liner designs would require detailed data beyond the level of thatreported. Also, the quantitative prediction for proposed designs would be subject to similarconstraints.

The selected correlation approach relates the degree of fuel sensitivity to the initial valueof liner severity parameter on the base fuel. This correlation result is shown in Figure 58. Thiscorrelation is used in the same manner as previously discussed for pattern factor and smoke.

4

4773

% %.

Page 86: Effect of fuel gas to GT

k 0 J79

0.90 0

0.80

030

0 0 . 0

0.300s-

A4.130 3.

*i. 1201 -

S

'

pecnae tST

p*ur 570ie.eeiyPraltrv

f~ oe

0.14

Page 87: Effect of fuel gas to GT

Open - SLTO 0 TF41

-0.14 H - Dsh T

-0.10

-0.08-0.1206se ~ F~

-0.0

DshT

oI ,S-0.08

*0

-, 0.3 0.4 0.5 0.6 0.7 0.8

Liner Severity Parameter at 14.5%, Hydrogen

~Figure 58. Liner Severity Parameter at 14.5% Hydrogen

75

Page 88: Effect of fuel gas to GT

SECTION V

CONCLUSIONS AND RECOMMENDATIONS

Based upon the results of the analyses conducted under this program, a number ofconclusions have been drawn relative to the effect of fuel property variations on combustorperformance and on the relationship of these trends to combustor design variables.

1. At the conditions of interest for most of the engines studied, ignition,0?. combustion efficiency and pattern factor variations are controlled by fuel

atomization and vaporization. Correlations which relate vaporization rate toignition, combustion efficiency and pattern factor with good statisticalsignificance were developed.

2. The effect of fuel properties on altitude ignition are quite different for

pressure-atomizing and air-atomizing nozzles. For the fuels evaluated,increased droplet size and reduced volatility show a greater effect on

altitude relight with pressure atomizing nozzles.

3. A convenient technique for varying fuel properties to determine effectsgoverned by atomization and vaporization on combustor operation andperformance is to vary fuel inlet temperature.

4. Smoke and combustion liner radiative heating correlate well with fuelhydrogen content. Incorporation of fuel droplet size or multicyclic aromaticconcentration in the correlation did not statistically improve the correlation.

5. The sensitivity of a particular combustor to fuel property changes isgenerally proportional to the level of the performance parameter in questionwith some reference fuel. For example, the higher the combustor smokenumber found with JP-4, the more sensitive the combustor is to increased

smoke level with lower hydrogen content fuels. This observation is perhapsthe most important conclusion of the entire study and leads to twoadditional conclusions:

a. The observed performance with a reference fuel provides aconvenient basis for correlation of fuel effects, and

b. A well designed combustor with high combustion efficiency,low pattern factor, low smoke point, etc., will generallyprovide far better accommodation of broad specification oralternative fuels than more marginal combustors.

76

Page 89: Effect of fuel gas to GT

The fuel correlations developed under this program provide good insight into the extent towhich fuel properties affect the performance and operation of aircraft gas turbine engines. Thepredicted trends may be used to assess the impact of fuel property variations on gas turbinecombustor operation. On the other hand, in some cases, significant scatter in the correlated datawas found, indicating either possible inaccuracies in the test data or of second order effects thatcould not be determined. It should be pointed out that the data upon which the correlationshave been based is combustor rig data. The use of rig data to predict engine performance has

..- always presented uncertainties. The following recommendations are suggested as a means ofimproving the accuracy and applicability of the correlations.

1. Before the correlations presented in this report can be used to predictengine performance, they should be anchored to baseline engine data andthe correlation trends reconfirmed. Because of the critical effect of patternfactor on turbine life and the difficulties in obtaining valid pattern factordata from rig tests, instrumented engine data to obtain fuel related patternfactor changes are essential.

2. While the available test data are generally of a high quality, furtherimprovements in data accuracy are required if second order effects are to bedetermined. Improved data will require improved instrumentation, morecomplete instrumentation and testing at conditions which are more closelyrepresentative of full scale engine operation.

3. It should be recognized that the accuracy of the fuel correlations isenhanced by using a broad range of the key properties which affect the

'4. correlations. The fuels tested under the Reference 1 through 5 evaluationscover all of the fuel property variations likely to be encountered in theforseeable future; however, use of an even wider range of fuel properties andcomposition would help in achievement of better correlations by producingfuel effects which are larger relative to test inaccuracies.

4. In selecting fuels for future fuel effect testing, priority should be given tothose fuel properties which have been found to most significantly affectcombustor operation. Hydrogen content and viscosity are of primaryimportance. Density and volatility are of secondary importance. And thepotential second order effects of naphthalene concentration should not beignored even though these effects have not been quantified under this study.

5. Where it is difficult to obtain a sufficiently broad range of fuel propertiesthrough preparation of petroleum blends, use of pure compounds and/ortesting over a wide range of fuel combustor inlet temperatures should beconsidered.

6. It should be recognized that the combustor instrumentation is not the onlysource of data inaccuracy. In future tests, even greater care should be takento fully and accurately characterize fuel properties and composition.Judicious fuel sampling and careful fuel handling should be conducted to

.9h assure that fuel contamination has not been encountered.

7. As additional test data (engine and rig) become available, the correlationspresented here should be reexamined and updated as necessary.

77

Page 90: Effect of fuel gas to GT

REFERENCES

1. Russell, P. L., "Fuel Mainburner/Turbine Effects," AFWAL-TR-81-2081,September 1982.

2. Gleason, C. C., T. L. Oiler, M. W. Shayeson, and W. D. Bahr, "Evaluation ofFuel Character Effects on F101 Engine Combustion System," AFAPL-TR-79-2018,June 1979.

3. Gleason, C. C., T. L. Oiler, M. W. Shayeson, and M. J. Kenworthy, "Evaluationof Fuel Character Effects on J79 Smokless Combustor," AFWAL-TR-80-2092,November 1980.

4. Vogel, R. E., D. L. Troth, and A. J. Verdouw, "Fuel Character Effects onCurrent High Pressure Ratio, Can Type Combustion Systems," AFAPL-TR-79-2072, April 1980.

5. Beal, G. W., "Effect of Fuel Composition on Navy Aircraft Engine Hot SectionComponents," NAPC-PE-74C, May 1983.

6. Greenhough, V. W. and A. H. Lefebvre, "Some Applications of CombustionTheory to Gas Turbine Development," Reinhold Publishing Corporation, NewYork, 1957.

-, 7. Ballal, D. R., and A. H. Lefebvre, "Ignition and Flame Quenching of Flowing' .' Heterogeneous Fuel-Air Mixtures," Combustion and Flame, Vol. 35, pp. 155-168,',4 1979.

8. Herrin, J. R., K. 0. Longnecker, T. B. Biddle, "Alternate Test Procedure forNavy Aircraft Fuels - Phase I," N00140-80-C-0269, January 1982.

9. Spalding, D. B., "Some Fundamentals of Combustion," Vol II, Butterworth's,* Scientific Publications, London, 1955.

10. Emory, J., R. H. Dieck, and P. M. Silverberg, "Effect of Gas Turbine FuelNozzle Design and Operation on Nozzle and Combustor Performance," P&WAReport PWA-3751 to Naval Air Engineering Center, 1969.

11. Lefebvre, A. H., "Airblast Atomization," Progress in Energy Combustion Science,Vol. 6, pp. 233-261, 1979.

12. Momtchiloff, I. N., and M. M. Gibson, et al, "The Design and PerformanceAnalysis of Gas Turbine Combustion 'Chambers," Vol I., "Theory and Design

?Practice," Northern Research Engineering Corporation, December 1964.

13. Russell, P. L., "Fuel Character Effects on USAF Gas Turbine EngineAfterburners, Part I - F100 Afterburner, AFWAL-TR-82-2114, November 1982.

S, 14. Champagne, D. L., "Standard Measurement of Aircraft Gas Turbine EngineExhaust Smoke," ASME Paper No. 71-CT-88, 1971.

15. Odgers, J. and C. Carrier, "Modelling of Gas Turbine Combustors; Considerationsof Combustion Efficiency and Stability," ASME Paper No. 72-WA/GT-1, 1972.

78

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