+ All Categories
Home > Documents > Effect of Thermo‐Plastic Treatment on Structure and Corrosion Properties of High Nitrogen...

Effect of Thermo‐Plastic Treatment on Structure and Corrosion Properties of High Nitrogen...

Date post: 08-Aug-2018
Category:
Upload: sep-publisher
View: 217 times
Download: 0 times
Share this document with a friend

of 10

Transcript
  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    1/10

    JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013 www.mejournal.org

    19

    EffectofThermoPlasticTreatmenton

    StructureandCorrosionPropertiesofHigh

    NitrogenCrSteelsVeraV.Berezovskaya

    Instituteofmaterialscienceandmetallurgy,UralFederalUniversitynamedafterthefirstPresidentofRussiaB.N.

    Yeltsin/Professor

    ul.Mira,19,Yekaterinburg,620002,Russia

    [email protected]

    AbstractEffectofagingonstructureandcorrosionpropertiesinhighstrength austenitic Crsteels alloying with nitrogen Cr21N1

    andCr18Ni2N1hasbeeninvestigated.Structureofthesteels

    and kinetics of austenite decomposition during the

    treatment was studiedby Xray diffraction, TEManalyses

    and electric resistance measurements. The highest valuesof

    strength, micro hardness, corrosion rate and relative

    strength reduction as far as brittle intergranular fracture

    wereobservedattheearlystageofaustenitedecomposition

    at the aging. The formation of nitrides CrN as well

    martensitestressinducedtookplaceinthesteels.According

    to resistormeter investigationsofnitrogen steelsincompare

    withcarbonsteelCr18C1attheearlystageofaging(350C)the metastable ordered clusters enriched with chromium

    and nitrogen were formed. Growths of aging temperature

    up to 500C led to dissolve the carbides or nitridesbut at

    600 C discontinuous precipitations were observed nearby

    thegrainboundaries.

    Effectofagingcombinedwithcoldplasticdeformation(CPD)

    at an 824 % reductionby two schemes,before and after

    aging at 350C, on structure and related corrosion

    propertiesofsteelCr18Ni2N1hasbeenstudied.CPDatan8

    12 % reductionbefore aging at 350C was shown to thrice

    decreasing of corrosion rate of the steel as compared to the

    undeformed state.A thermoplastic treatmentby thesecondscheme with using CPD at an 20% reduction after aging at

    350 C is found to be more effective: the corrosion rate

    decreased by an order and strength reduction decreased

    morethanbyfourfoldascomparedtotheundeformedstate.

    KeywordsAustenite Decomposition; Ordered Clusters; StressMartensite;

    Lattice Parameter; Stress Corrosion Cracking; Cold Plastic

    Deformation.

    Introduction

    Highnitrogensteels(HNS)duetotheirmorestrength

    and corrosion resistant than in other austenitic steels

    with carbon are widely used in power machine

    building,shipbuildingandotherfieldsofengineering.In the nearest future [19] after perfecting their

    manufacturing technology they are expected willbe

    applied in abigger industrial scale. One of the main

    directions of investigations to solve these problems is

    searching a way to increase their resistance to stress

    corrosioncracking(SCC)bothbyefficientalloyingand

    optimizationofstrengtheningprocedure.

    Well known that nitrogen includes a significant

    contribution in hardening of solid solution and grain

    boundaries as well as in strain and precipitation

    hardening. According to data from work [2],

    realization of these factors at appropriate degree of

    coldplasticdeformation(CPD)canprovideextremely

    high strength for this class of steels up to 3600 MPa.

    However in a certain structural state they are

    subjected to SCC in corrosive environment [10, 11] so

    in this case expedient to use them after strengthening

    notmorethenupto0.2=1400MPa.

    Materials and Procedure

    The highstrength lowcarbon steels with highnitrogen content (0.91.0%) Cr21N1 and Cr18Ni2N1

    have been investigated to study mechanism and

    kinetics of austenite decomposition and clearing up

    CPD influence on structure and corrosion properties

    of steels. Kinetics of decomposition of the

    oversaturatedsolidsolutioninHNSwascarriedout

    as compared with high carbon steel Cr18C1. Their

    chemicalcompositionispresentedinTable1,firsttwo

    of them were producedby nitrogen pressure casting,

    homogenization at 1250 C and rolling with further

    quenching in water afterbeing exposed for one and

    half an hour at 1200 C. The high carbon steel was

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    2/10

    www.mejournal.org JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013

    20

    manufacturedby standard technology and quenched

    from the same temperature in oil to put the austenite

    structure. The specimens prepared for testing were

    agedat300500Cfortwohoursandat600Cforan

    hour.

    TABLEICHEMICALCOMPOSITIONOFSTEELS

    The general corrosion and SCC tests were performed

    ina3.5%NaClaqueoussolutionasitdescribedinthe

    work [10]. Fractographic studies of fracture surface

    after SCC were examined on a JSM35C scanning

    electronmicroscopeandmetallographicexamination

    onaNeophot32opticalmicroscope.

    Theelectricresistancemeasurementswerecarriedout

    to investigate the kinetics of solid solution

    decomposition [12]. Xray diffraction analysis was

    carried out on a DRON3 diffractometer with cobalt

    radiation and a radiation filter. The austenite andmartensitecontentsinthesteelswereestimatedusing

    the method of homologous pairs by comparing the

    integratedintensitiesofthe(110)and(111)lines[13].

    The structure of austenite and the type, morphology,

    and size of additional phases were investigated by

    transmission electron microscopy on an EMV100L

    electronmicroscope.

    Results and Discussion

    Mechanical properties of high nitrogen steels werefollowing: yield strength (0.2) is 650 and 610 MPa;

    specific elongation () is 21 and 18% after quenching

    and0.2=780 and 820 MPa; =5 and 9% in aged state

    respectively in Cr21N1 and Cr18Ni2N1 steels. The

    highest growth of strength, corrosion rate and

    susceptibilitytoSCCin3.5%NaClwasobservedafter

    aging at 350 C [14]. The fracture of specimens was

    brittle and intergranular in this case (Fig. 1, a) while

    the destruction was not associated with nitrides,

    located along the grainboundaries. After overaging

    the resistance to SCC increased and the intergranularfracture was replaced to quasicleavage including

    related to colonies of discontinuous decomposition of

    solid solution (Fig. 1,b). Theinvestigatedsteels had

    a good passivity in all structural states due to high

    contentofchromiuminsolidsolution,howeveratthe

    stage of active corrosion the sharp acceleration of

    corrosion was observed after aging at 350 C ininvestigatedsteels(Table2,line2).

    FIG.1FRACTURESURFACEAFTERSCCOFCR18NI2N1STEEL

    SUBJECTEDOFAGINGAT350(a)AND600C(b)

    After quenching from 1200 C an austenite and

    carbideswithsurfacemartensite werenotedincarbon

    steel as well as in nitrogen steels (Fig. 2, a,b). The

    structure of high nitrogen steels varied with rising of

    aging temperature identically with some more

    stability of austenite in nickelfree steel. The

    microstructure of nitrogen steels aged at 350 C was

    almost similar to quenched one (Fig. 2, c),but after

    agingat600Citwasratherdifferent(Fig.2,d).

    Martensitesoftwomorphologieswithdifferentlattice

    parameters aT=0.287 nm and a=0.291 nm was

    discovered in steel Cr18Ni2N1. As it was shown

    earlier [15] it was the thin dispersive martensite (T)

    onthegrainboundariesandannealingtwins(Fig.2,b,

    c) and lensformed stressinduced martensite () in

    the middle of grain (Fig.2, d), which formed

    respectively from austenite depleted and enriched

    with chromium and nitrogen. The same picture was

    found after SCC. The results of Xray diffractionanalysesareshowninTable2.

    Steel

    grade

    Contentinthesteel,wt%

    C N Mn Si P S Cr Ni

    Cr21N1 0.020 1.021 0.19 0.42 0.015 0.010 21.45

    Cr18Ni2N1 0.008 0.899 0.30 0.27 0.020 0.010 17.86 2.00

    Cr18C1 0.920 0.63 0.79 0.025 0.023 18.30

    30 m

    15 m b

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    3/10

    JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013 www.mejournal.org

    21

    TABLEIIPHASECOMPOSITIONANDCORROSIONPROPERTIESOFTHECR18NI2N1STEELAFTERVARIOUSTREATMENT

    of

    treatmentSchemeoftreatment

    Contentofphases,%*

    m,

    g/m2h st,%Intheinitialstate AtthesurfaceoffractureafterSCC

    AgingwithoutCPD

    1 Quenchingfrom1200 95 5 0 62 26 12 2,0 352 1200 +350,2h 95 5 0 58 22 20 30,0 37

    3 1200 +400 95 5 0 62 22 16 8,0 34

    4 1200 +600 50 44 6 28 64 8 1,0 29

    5 1200 +700 0 100 0 0 100 0 0,5 21

    CPD

    before

    aging

    6 1200 +8%CPD+350,2h 89 5 6 10,0

    7 1200 +12%CPD+350,2h 87 5 8 11,0

    8 1200 +20%CPD+350,2h 50 15 35 40 15 45 55,0 42

    9 1200 +24%CPD+350,2h 80 7 13 50,0

    10 1200 +20%CPD 95 5 0 0,3

    CPD

    afteraging 11 1200 +350,2h+20%CPD 95 5 0 95 5 0 2,5 10

    12 1200 +400 +20%CPD 95 5 0 0,3

    13 1200 +600 +20%CPD 50 50 0 0,8

    14 1200 +700 +20%CPD 0 100 0 0,4

    *Withoutexcessphases.

    FIG.2 ICROSTRUCTUREOFSTEELSCR18C1(),CR21N1(B)QUENCHEDANDCR18NI2N1(C,D)AGEDAT350AND600C

    30 m

    30 m d

    c30 m

    20 m b

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    4/10

    www.mejournal.org JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013

    22

    According to comparison of SCC tests and Xray

    diffractionresultsthecorrelationbetweenthevalueof

    relative strength reduction (/K) and quantity of

    stressinduced martensite, formed directly during the

    tests, is observed in high nitrogen steels. Thebiggest

    portionofmartensiteinstructureofsteelwasnotedafteragingat350C.

    By transmission electron microscopy of thin foils the

    evolution of structure in steel Cr18Ni2N1 under the

    aging was studied. The structure of quenching steel

    consisted of austenite (Fig. 3, ac), ratherbig particles

    ofnitridesCr2Nretainedafterheatingalongthegrain

    boundaries and not more than 5% of Tphase as a

    result of martensitic transformation in depleted

    austenite near the nitrides (Fig. 3, df). The nitride

    Cr2Nhasahexagonalcrystallinestructurewithlattice

    parametersa=0.4805nm,c=0.4480nm. Thecrystalsof

    surface martensite formed at electrolytic polishing of

    foilcouldbeseenaswell(Fig. 3,g).

    After aging at 350 and 400Cbesides andphase

    ultra dispersive nitrides CrN with FCC crystalline

    ordered structure and lattice parameteraCrN=0.415 nm

    formed from a supersaturated solid solution due to

    homogeneous isomorphic decomposition were

    observed (Fig.4,ac). The crystals of martensite

    were found as well. Both phases CrN and were

    noticednearbytheextinctioncontoursintheplacesoffoilbending(Fig. 4, df). After 2hour aging at 500C

    besides Tphase in the settlement of discontinuous

    decompositiononthegrainboundaries(Fig.5,ac)the

    singlecrystalsofmartensitewerediscovered(Fig.5,

    d). At temperature 600 C fresh portions of

    discontinuousdecompositionsettlementsconsistingof

    nitridesCr2NandTmartensitewasobserved(Fig.6).

    The electric resistance of the steels Cr21N1,

    Cr18Ni2N1 and Cr18C1 has been measured

    depending on time of aging in isothermal conditions

    at 300, 400 and 500 C (Fig. 7). These dependences

    wereshowntobethesameforhighnitrogenandhigh

    carbonsteels.Attheinitialstagesofprocess(36h)we

    can see a sharp electric resistance decrease which

    becomesbigger as the temperature of aging grows.

    The effect of aging depends on a super saturation

    degreebyinterstitialatomsofaustenitequenchedbut

    at the same content of carbon and nitrogen (about

    0.9%) its displayed stronger in high nitrogen steels.

    Withtheincreasingofthetemperatureatthisstageof

    aging a differencebetween the curves reduced and

    they practically coincided at 500 C. The stress

    recoveryattheheatingwasresponsiblefordecreaseof

    electricresistanceofthesteels(sharpdecreaseofR/R

    preagingstage).

    At a longer time of heating it was an increase of

    electric resistance most pronounced at 300C. This

    stage continued not more than 7 hours at 300 C, 4

    hoursat400Cand1hourat500Candassociatedwith the separation of the solid solution with

    chromium (as well carbon in carbon steel) during

    these exposuresbecause of the conductivity electrons

    are scatteredby these enriched in chromium clusters

    [16](sharpincreaseofR/Rstage1).

    Longer aging influenced on the curves character

    differently depending on the temperature of aging. It

    is necessary notice a stabilizing of decomposition of

    austenite in carbon steel at 300 and 400 C and in

    nitrogensteels

    only

    at

    300

    C.

    It

    is

    connected

    with

    the

    formingofcarbidesincarbonsteel,butnotcompleting

    of nitrides formation in nitrogen steels. It needs to

    continue the heatingand further slow increasing of

    electric resistance which observed at 400 C in these

    steels confirmed it. This process associated with the

    orderinginchromiumenrichedclusterswithnitrogen

    that was able at an exposure at this temperature or

    understresses(nearbytheextinctioncontoursFig.4,

    a) if exposure was not enough. Thus the formation of

    carbides or nitrides characterized with unchanging or

    slowincreasing

    of

    R/R

    stage

    2.

    Decreasing of electric resistance at 500 C hasbeen

    shown in all investigated steels and was connected

    with dissolving of clusters enriched in chromium

    (slow decreasing of R/R accordingly in carbon and

    nitrogensteelsstage3).

    Effectofcoldplasticdeformationonthephasecontent

    and corrosion properties of the steel Cr18Ni2N1 is

    presented in Table 2. CPD at an 824% reduction was

    combined with aging at 350 Cby two ways:before

    (lines 610 in Table 2) and after aging (lines 1114) as

    compared to the undeformed state (lines 15). It

    follows from Tab. 2 that CPD at 812% reduction

    before aging at 350C decreases to thrice a corrosion

    rate in spite of some increasing of martensite

    content. On the contrary CPD at 20% reduction

    increases nearly twice the corrosion ratebecause of

    considerable depleting of austenite and as

    consequence increasing ofTmartensite content after

    strain aging. Furthermore this treatment condition

    negativelyinfluencedontheSCCofthisnitrogensteel

    and increased ofmartensite content if to compare

    withundeformedstate(lines2and8).Itisknown[17]

    thatalowlevelofstresses(trthresholdstress)

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    5/10

    JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013 www.mejournal.org

    23

    FIG.3STRUCTUREOFQUENCHEDSTEEL CR18NI2N1:ASUBGRAINSTRUCTUREOFAUSTENITE;BSELECTEDAREAELECTRON

    DIFFRACTIONPATTERNTAKENFROMREGION(A);CKEYPATTERN;DSTRUCTUREOFGRAINBOUNDARY;ESELECTED

    AREAELECTRONDIFFRACTIONPATTERNTAKENFROMREGION(D);FKEYPATTERN;GSURFACEMARTENSITE

    FIG.4.STRUCTUREOFAGEDAT350 STEELCR18NI2N1:AHOMOGENEOUSDECOMPOSITIONOFAUSTENITE;BSELECTED

    AREAELECTRONDIFFRACTIONPATTERNTAKENFROMREGION(D);CKEYPATTERN;DEXTINCTIONCONTOURSANDMARTENSITE;ESELECTEDAREAELECTRONDIFFRACTIONPATTERNTAKENFROMREGION(D);FKEYPATTERN

    Zone axis [ 433

    ]

    e

    a

    313

    133

    000

    422

    220Zone axis [

    111 ]

    202

    c

    d

    110 , 200Cr2N

    211

    321

    310

    020

    121, 220Cr2N

    Zone axis [

    201 ]

    Zone axis [001]Cr2N

    Zone axis [ 131

    ]

    fg

    111

    a b

    111CrN111

    200

    200CrN

    111 rN

    200

    200CrN

    111

    111 CrN

    131 CrN

    131

    Zone axis [ 110

    ] CrN Zone axis [

    101 ] CrN

    c

    000

    d e

    112

    Zone axis [ 521

    ]

    Zone axis [ 010

    ]Cr2N004

    204

    200113

    202

    321

    112

    Zone axis [

    111 ]

    Zone axis [113]

    110131

    000

    f420 Zone axis [ 521

    ]

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    6/10

    www.mejournal.org JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013

    24

    FIG. 5 STRUCTURE OF AGED AT 500 STEEL CR18NI2N1: A GRAIN BOUNDARY; B SELECTED-AREA ELECTRON DIFFRACTION

    PATTERN TAKEN FROM REGION (A); C KEY PATTERN; D MARTENSITE ; E SELECTED-AREA ELECTRON DIFFRACTION PATTERNTAKEN FROM REGION (D); F KEY PATTERN

    FIG. 6 STRUCTURE OF AGED AT 600 STEEL CR18NI2N1: GRAIN BOUNDARY; B SELECTED-AREA ELECTRON DIFFRACTION

    PATTERN TAKEN FROM REGION (A); C KEY PATTERN

    does not considerably increase the corrosion current

    atSCCofironbutahighlevelofthem(tr)causes

    a significant growth of this one (Fig. 8). And taking

    intoconsiderationthesametodelayedfailure[18,19]

    mechanism of SCC, when the main depolarization

    process is hydrogen ions (H+) discharge on the

    ordered clusters to atoms (H), they become the

    effective sub micro cathodes in electrochemical

    process on the surface of the steel. The atoms of

    hydrogen can join to molecules (H2) significantly

    increasing their size and level of stresses in the

    clusters. That is why the stressmartensite can be

    formedfromthoselocalareasofstructure.

    After 24% reduction the austenite has more stabilitythan after 20% reductionbecause of strain recovery,

    thats confirmedby dependence of micro hardnessfrom deformation degree (Fig.9). Fig. 10 shows the

    structure of deformedbefore aging at 350 C steel

    with the electron diffraction pattern where

    martensitecanbenoted.

    Zone axis [

    101 ]

    Zone axis [

    811 ]

    a b c

    011, 110

    211 200, 002

    211

    202

    120

    401000

    Zone axis

    [ 011

    ]

    Zone axis [010]Cr2N

    202

    ,

    211

    331

    151

    011

    200

    531

    022

    711

    Zone axis [

    101 ]

    Zone axis

    [

    611 ]

    000

    d ef

    a b c

    200

    011

    211

    110

    203Cr2N, 112

    222, 404Cr2N

    Zone axis [ 110

    ]

    Zone axis [ 011

    ]

    102

    Zone axis [ 010

    ]Cr2N

    000

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    7/10

    JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013 www.mejournal.org

    25

    FIG.7.KINETICSOFELECTRICRESISTANCECHANGEININVESTIGATEDSTEELSCR21N1(1),CR18NI2N1(2) CR18C1(3)DURING

    THEAGINGAT:A300;B400;C500

    a

    b

    c

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    8/10

    www.mejournal.org JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013

    26

    FIG.10STRUCTUREOFDEFORMEDATAN8%REDUCTIONBEFOREAGINGAT350 STEELCR18NI2N1: MARTENSITE;B

    SELECTEDAREAELECTRONDIFFRACTIONPATTERNTAKENFROMREGION(A);CKEYPATTERN

    FIG. 8 POLARIZATION DIAGRAM OF CORROSION AT SCC:

    O2ABC CATHODE CURVE; FE/FE2+X11 AND FE/FE2+X22 ANODECURVESATADIFFERENTSTRESS

    200

    250

    300

    350

    400

    450

    500

    0 11 20 24

    , %

    HV100

    FIG.9

    DEPENDENCE

    OF

    THE

    MICRO

    HARDNESS

    ON

    THE

    DEGREEOFCPDPRECEDEDTHEAGINGAT350 INSTEEL

    CR18NI2N1

    Treatment with CPD at 20% reduction after aging at

    350Cisfoundtobemoreeffective:thecorrosionrate

    decreasedbyanorderandthereductionofstrengthat

    SCC was about a quarter of magnitudes of

    undeformed state. This positive influence of CPD is

    probably connected with breaking the order in

    metastable clusters which could be acceptors of

    discharged hydrogen and nucleus of stressinduced

    martensiteatSCC.

    Conclusion

    The structure of quenched steels Cr21N1, Cr18Ni2N1

    andCr18C1

    with

    high

    content

    of

    nitrogen

    and

    carbon,

    respectively 1.021, 0.899 and 0.920% consists of

    metastable austenite with nitrides or carbides settled

    downthegrainboundaries.Alsoasmallcontentof

    phase takes place near the nitrides/carbides or as a

    resultofpolishing.

    Twostagesofdecompositionofausteniteattempering

    were shown to be in nitrogen steels by electric

    resistance: separation of the solid solution with

    chromiumfollowedbyorderingoftheseclusterswith

    nitrogenwhichinducedbytimeexposureorstresses.

    The highest hardness, corrosion rate and stress

    corrosion cracking susceptibility in HNS were

    observed at the second stage of aging. This structural

    state characterized of ordered enriched with

    chromium and nitrogen clusters which had an ability

    totransformintoastressinducedmartensite.

    Coldplasticdeformationat812%reductionpreceding

    the aging at 350 C is shown to decrease three times

    thecorrosionrateofthesteelCr18Ni2N1ascompared

    to the undeformed state. The role of CPD at this

    degree consists of accelerating of nitrides CrNprecipitation without intermediate stage of ordering

    i

    -Fe/Fe2+

    i1 i2

    1 - tr

    2 - tr

    -O2

    -H+/HA

    B

    Cx2

    1

    2

    1

    310

    200

    110, 020

    002

    222

    220

    113

    000

    Zone axis [100 ]

    Zone axis [ 011

    ]

    Zone axis [ 031

    ]

    311

    a b c

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    9/10

    JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013 www.mejournal.org

    27

    clusters. A thermoplastic treatmentby 20% CPD after

    agingat350Cismoreeffectivebecauseofdestroying

    already formed ordered clusters, which are the main

    reasonofhighsusceptibilitytoSCC.

    ACKNOWLEDGMENT

    TheauthorwishestothankMansurS.Khadyevforhis

    helpinexperimentalprocedure.

    This work was carried out and is running now with

    the financial support of Russian Foundation for Basic

    Research,grantsN070300062aandN110300065.

    REFERENCES

    [1] Stein G., Hucklenbroich I. Manufacturing and

    Applicationsof High NitrogenSteels.HNS2003.High

    Nitrogen Steels. Editors: Markus O. Speidel, ClaudiaKowanda, Markus Diener. Zzich: Institute of

    Metallurgy,SwissFederalInstituteofTechnology,ETH,

    2003:2130.

    [2] Speidel M. O., Mingling ZhengCui. HighNitrogen

    AusteniticStainlessSteels.InthesamebookHNS2003:

    6373.

    [3] SvyazhinA.G.NitrogenofWidePurposes.Production,

    Treatment,Properties.InthesamebookHNS2003:43

    52.

    [4] Hnnen H., Talonen J., Romu J. et al. Summary ofRecentReasearchonNAlloyingofSteelsinFinland.In

    thesamebookHNS2003:3141.

    [5] Dong Han, Lin Qizeng, Rong Fan et al. Development

    and Applications of Nitrogen Alloyed Stainless Steels

    inChina.InthesamebookHNS2003:5361.

    [6] Saller G., Aigner H. High Nitrogen Alloyed Steels for

    NonMagnetic Drill Collars. In the same book HNS

    2003:129138.

    [7] Gcmen Alkan. Development of high Nitrogen 12%

    ChromiumSteelsforGasTurbineDiskApplications.InthesamebookHNS2003:113128.

    [8] KIM Yong Hwan, KIM Kwang Yuk, LEE Yong Deuk.

    NitrogenAlloyed,MetastableAusteniticStainlessSteel

    for Automotive Structural Applications. In the same

    bookHNS2003:149158.

    [9] Colombie V., Montserrat X., Brown G. et al. Nitrogen

    Alloyed Austenitic Stainless Steels for Wire and Cable

    Applications.InthesamebookHNS2003:199210.

    [10] Berezovskaya V. V., Kostina M. V., Blinov E. V., et al.

    Corrosion Properties of Austenitic CrMnNiN Steelswith Various Manganese Concentration. Izv. Ross.

    Akad. Nauk, Ser. Met., 2008, 1: 3641. [Russian

    Metallurgy(Metally),2008,1:2933].

    [11] Kostina M. V., Bannykh O. A., Blinov V. M.,

    Berezovskaya V. V., et al. Effect of Chemical

    Composition and Heat Treatment on the Corrosion

    Properties in High Nitrigen IronBased AlloysContaining1524%Cr.Izv.Ross.Akad.Nauk,Ser.Met.,

    2001, 3: 2634. [Russian Metallurgy (Metally), 2001, 3:

    243250].

    [12] Bannykh O. A., Berezovskaya V. V., Effect of heat

    treatment conditions on the structure and

    physicomechanical and chemical properties of an Ni

    CrCuTi maraging steel. Izv. Ross. Akad. Nauk, Ser.

    Met.,2007,3:4047.[RussianMetallurgy(Metally),vol.

    2007,3:201208].

    [13] Gorelik S. S., Skakov Yu. A., Rastorguev L. N. Xray

    diffraction and electronoptical analyses. Moscow:

    MISIS,2002.358pp.

    [14] BannykhO.A.,BlinovV.M.,BerezovskayaV.V.,etal.

    EffectoftheMartensiteTransformationinFeCrN

    Alloys on Their Stress Corrosion Cracking. Izv. Ross.

    Akad. Nauk, Ser. Met., 2005, 4: 2631. [Russian

    Metallurgy(Metally),2005,4:310314].

    [15] BerezovskayaV.V.,GolyakovI.V.,BannykhO.A.etal.

    EffectofColdPlasticDeformationontheStructureand

    Corrosion Resistance of Austenitic Aging 0Kh18N2A

    Alloy. Izv. Ross. Akad. Nauk, Ser. Met., 2006, 5: 2932.[RussianMetallurgy(Metally),2006,5:390393].

    [16] LivshitsB.G.,KraposhinV.S.,LinetskiyYa.L.Physical

    PropertiesofMetals.Moscow:Metallurgiya,1980.320

    pp.

    [17] Isaev N. I. Theory of corrosion processes. Moscow:

    Metallurgiya,1997.368pp.

    [18] Nelson H. G., Williams D. P. Stress Corrosion and

    Hydrogen Embrittlement of Iron Base Alloys //R.

    StaehleandSpeidel,eds.1977:390404.

    [19] BerezovskayaV. V.DelayedFailure of Maraging Steels

    in Environment. Advances in Chemistry Research.

    Volume 6. Editors: James C. Taylor.Chapter 7. N.Y.,

    USA,NovaSciencePublishersInc.2011:219244.

    Vera. V. Berezovskaya was born

    04.04.1949.

    Engineer, Physics of Metals, Ural

    Polytechnic Institute (Sverdlovsk,

    USSR),1971;

    PhD,MetalScienceandHeatTreatment,

  • 8/22/2019 Effect of ThermoPlastic Treatment on Structure and Corrosion Properties of High Nitrogen CrSteels

    10/10

    www.mejournal.org JournalofMetallurgicalEngineering(ME)Volume2Issue1,January2013

    28

    UralPolytechnicInstitute,1985;

    Assoc. of Prof., Metallurgical Department of Ural State

    Technical University, Yekaterinburg (former Ural

    PolytechnicInstitute,Sverdlovsk),1996;

    Doctorofscience,MetalScienceandHeatTreatment,Baikov

    Institute of Metallurgy and Materials Science, RussianAcademyofScience,Moscow,Russia,2004;

    Professor, Metallurgical Department of Ural State Technical

    University,Yekaterinburg,2005;

    Currently Professor, Institute of Metal Science and

    Metallurgy of Ural Federal University named after the first

    PresidentofRussiaB.N.Yeltsin.

    The main area of scientific interest is relationshipbetween

    structureandfractureofstainlessandhighstrengthsteelsat

    cavitations,delayedfailureandstresscorrosioncracking.

    She is a LECTURER at the Ural Federal University onfollowing subjects: Material Science; Theory of corrosion,

    corrosionresistant materials and coatings, from 1991 and

    Advanced Materials and Technologies from 2010. She has

    about200publications,themainofthemare:

    Berezovskaya V. V. Structural Factors Governing Steel

    ResistanceduringOperationinCorrosiveMediaunder

    Cavitation Conditions. Metallovedenie i Termicheskaya

    ObrabotkaMetallov,1987,11:5056[MetalScienceandHeat

    Treatment. 1987. V.29,I.1112:863869].

    Berezovskaya V. V. Delayed Failure of Maraging Steels in

    Environment. Advances in Chemistry Research. Volume 6.

    Editors: James C. Taylor. Chapter 7. N.Y., USA, Nova

    SciencePublishersInc.2011.219244.

    Berezovskaya V. V., Savrai R. A., Merkushkin E. A.,

    Makarov A. V. Structure and Mechanical Properties of newhighnitrogen CrMn Steels Containing Molybdenum. Izv.

    Ross. Akad. Nauk, Ser. Met., 2012, 3: 3139. [Russian

    Metallurgy(Metally),2012,5:380388].

    Her current research interests lie in the area of High

    Nitrogen Steels, their structure, mechanical, physical and

    chemicalproperties.

    Dr. Berezovskaya supervises the contracts and grants,

    preparedtwoMasters(2010,2011)andthePhD(2002).Sheis

    Member of New York Academy of Sciences (New York,

    USA,1996);

    Member of Association of Russian Metallurgists (Moscow,

    Russia2002).

    Shehas

    Honorary title Hero of Labor of regional importance

    (Sverdlovskayaarea,Russia,2003);

    Diploma of the Ministry of Education and Science for her

    significant contribution to the training of highly qualified

    specialists(Russia,2011).


Recommended