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    1

    Energy Storage by Means of Supercapacitors:Components, Power Electronics Interfaces

    and Applications

    Dr. P. Barrade

    Laboratoire dElectronique Industrielle

    EPFL - STI ISE - LEIELD 136, Station 11

    Ch-1015 Lausanne / Switzerland

    Phone : +41 (0)21 693 2651

    Fax : +41 (0)21 693 2600

    [email protected]

    Seminar on Supercapacitors

    Dr. P. Barrade

    Summary

    Generalities on Supercapacitors Principle, technology and construction

    Electric-based model

    Sizing of a supercapacitive tank

    Energy requirements, Power availability

    Thermal considerations

    Limitations

    Power electronics converters

    Voltage equalization, Power electronics interfaces

    Applications for supercapacitors

    energy storage/energy buffer

    elevators

    hybrid vehicle

    tramways/trolley-buses

    UPS applications

    Aeronautic application

    Conclusion

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    2

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Energy storage devices

    Capacitors Dielectric (Film-Foil, Metallized film) Electrostatic

    Oxide electrolytic (Al, ta) Electrostatic

    Electrochemical capacitor

    Pseudocapacitor Faradaic

    Double layer capacitor (ECDL) Electrostatic

    Battery

    Pb

    NiCa NiMH

    Li+ Faradaic

    Fuel cell

    H2, Methanol (reforming) Energy conversion

    Flywheel Mechanical

    Superconducting Magnetic Energy Storage (SMES) Magnetic

    Seminar on Supercapacitors

    Dr. P. Barrade

    Energy storage devices

    Ragone diagram : Energy Density versus Power Density

    Generalities on Supercapacitors

    Courtesy from Montena Component SA

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    3

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Energy storage devices

    Energy density

    Seminar on Supercapacitors

    Dr. P. Barrade

    Principle, Technology and Construction

    Generalities on Supercapacitors

    +++++++

    -------

    -------

    +++++++

    1 - 3 V

    2 - 10

    discharged

    charged

    Dielectric Electrolyte Separator

    Electrodes

    Current Collectors

    C = r A/d

    W = 1/2 CU2

    A : up to 3000 m2(porous film)D : fix, ~10 er: fix, ~10U : 1 - 3 V, electrolyte decomposition voltageR : low, electrolyte

    Conventional capacitor ELCD capacitor

    Courtesy from Montena Component SA

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    4

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Principle, Technology and Construction

    Materials : Electrolyte :

    "Acqueous : high ionic conductance, high power density (1V, 1.2S*cm) KOH, H2SO4

    "Organic : high voltage, high energy density (2.5-3V, 50mS*cm) (Ex : 40mS*cm)

    Electrode"Carbon: activated carbon

    Separator"Organic: polymer (ex : 25m microporous polyolefin), paper

    "Inorganic: glas fibers, ceramics

    Current collector"Metal foil (Al, Ti, Fe)

    Courtesy from Montena Component SA

    Seminar on Supercapacitors

    Dr. P. Barrade

    Principle, Technology and Construction

    Construction

    Generalities on Supercapacitors

    Courtesy from Montena Component SA

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    5

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Main properties

    Life time : ageing mechanisms Type of aging

    "Electrical solicitations

    "Environmental (temperature, corrosive atmosphere)

    "Mechanical (vibrations, shocks)

    Electrical aging mechanisms"Ionic saturation of electrode surface

    "Increased contact resistance in the electrodes

    "Water diffusion

    "

    Impurities redox reaction"

    Electrolyte decomposition

    Life time : long life time thanks to

    Reversible physical electrostatic charging cycles

    No chemical redox reactions unlike batteries

    Low voltage solicitation

    Courtesy from Montena Component SA

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Main properties

    Cell behaviour under crushing conditions:

    Strong resistance for axial crushing

    Weak resistance for transverse crushing

    Temperature / fire

    Opening of cells in 6 min (600C without fire)

    Opening of cells in 4 min in case of direct fire exposure

    Flammable gaz emission in case of opening celle if T>500C

    gaz emission in case of opening (HCn)

    90 cells 3000F / for a 2m3 closed volume: risk of death

    Courtesy from Montena Component SA

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    6

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Supercapacitors today:

    Maximum voltage : 2.7V

    1 Million charge/discharge cycles

    ~0.01Euro/F

    From few farads to few thousand farads

    From the single component to the modules

    Courtesy from Maxwell Technologies SA

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    The main parameters of a supercapacitor (from the power electronicians pointof view) :

    The energy that can be stored :"

    Capacitance : from 1F to 3000F (and more !)

    "Maximum voltage : typically 2.5V -> 2.7V (and more ?)

    The energy efficiency :"

    Series resistor : limitation of the charging/discharging current

    The self discharge"Leakage resistor : self discharging of the component

    The classical model for a capacitor contains

    an ideal capacitor

    a series resistor

    a leakage resistor

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    7

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    The main parameters of a supercapacitor : an ideal capacitor

    "Defined by the surface of electrodes, width on ions

    a series resistor"

    Defined by the quality of carbon deposition on the aluminium current collectors

    "Defined by the electrical conductivity of the carbon

    "Defined by the ionic mobility of the electrolyte

    a leakage resistor"

    Overcharge beyond the decomposition limit of the electrolyte

    "

    Impurities redox reaction

    "Redox reaction of functional groups on the edge of carbon particles

    "Electronic conductance through the separator

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Capacitance and series resistance (ESR) Example of the BCAP0010 (Montena Component SA)

    Courtesy from Montena Component SA

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    8

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Additional parameters (specificity of supercapacitors)

    Non-constant capacitance and relaxation phenomena

    Voltage dependant capacitance Relaxation phenomena are not leakage

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Additional parameters (specificity of supercapacitors)

    Voltage dependant capacitance (due to the width of the double layer)

    How to consider?"Current capacitance

    "Energetic capacitance

    C =Co+Ku

    Cu

    !

    Q =Cu! ic =

    dQ

    dt! i

    c = C

    o+ 2Ku( )Ci

    ! "# $#

    du

    dt

    P = icu = C

    o+ Ku( )u

    du

    dt!W

    c=1

    2C

    o+4

    3Ku

    "

    #$

    %

    &'

    Cw

    ! "# $#

    u2

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    9

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Additional parameters (specificity of supercapacitors)

    Voltage dependant capacitance. Example of the BCAP0008 (MontenaComponent SA) : C=1800F, Co=1800F and K=150F/V, U=2.5V

    Really difficult to identify clearly the energy stored in a cell, depending ondefinitions

    "Only real possibility: measures!

    C 1800F 5625J

    Co+K*u 2175F 6796J +20.8%

    Ci 2550F 7968J +41.6%

    Cv 2300F 7187J +27.7%

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Additional parameters (specificity of supercapacitors)

    Relaxation phenomena

    "Due to porosity of electrodes (misopores, mesopores, macropores)

    "During a fast charge (discharge), ions will first enter (leave) into macropores,then in mesopores

    "

    Diffusion of ions in misopores is characterized by long constant times

    "During ageing process, relaxation phenomena is re-inforced by impuritiesaffecting the dimension of the pores

    "After a fast charge (discharge), non homogeneous repartition of loads on theelectrodes

    "Diffusion of the loads to reach a homogenous distribution (depends on size ofthe pores and size of the ions)

    Voltage decrease (after charge)

    Voltage increase (after discharge)

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    10

    Seminar on Supercapacitors

    Dr. P. Barrade

    Generalities on Supercapacitors

    Modelling supercapacitors :

    Additional parameters (specificity of supercapacitors)

    Voltage dependent capacitance Cu(width variation of the double layers)

    rc sub-circuits (relaxation phenomena, poreousity of electrodes)

    Seminar on Supercapacitors

    Dr. P. Barrade

    The energy stored in one single component is generally not sufficient

    Sizing of a supercapacitive tank

    For a given application, it must be found :

    the number of needed supercapacitors

    for that number, it must be defined the arrangement for the supercapacitors :"

    how many supercapacitors will be series connected in an elementary branch

    " the number of elementary branches

    The two last parameters define the maximum voltage and current that a

    supercapacitors tank can provide

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    Seminar on Supercapacitors

    Dr. P. Barrade

    To identify the number of supercapacitors, energy requirements have to be known.

    In various applications, energy requirements are not defined.

    Power requirements are often described : this is the instantaneous power that thesupercapacitors bank has to store/provide.

    Sizing of a supercapacitive tank

    Energy requirements have to be identified thanks to the instantaneous

    power requirements

    The needed energy can be obtained thanks to the link equation between theenergy Wcand the power Pc:

    Wc =

    Z Pcdt

    Seminar on Supercapacitors

    Dr. P. Barrade

    Identifying the needed energy :

    example

    Sizing of a supercapacitive tank

    For a given power profile,

    it is easy to identify by

    numerical calculation theassociated energy profile.

    The value of energy that

    must be retained is not the

    value at the end of a

    complete cycle, but the

    maximum value reached

    during the cycle (220kJ in

    the example).

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    12

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitors bank

    From the needed energy to the number of supercapacitors : the total amount of energy in a supercapacitor is defined by the equation :

    External behaviour and environment

    To use to total stored energy :

    the voltage across the component should be decreased from its maximum allowedvalue U

    Mto 0V. But that is not possible :

    " Because of the maximum current a supercapacitor can provide

    " During a discharge with a constant current, the power follows the voltage profile

    It is not possible to use the total amount of energy stored into a supercapacitor : a

    residual voltage has to be taken into account to consider that the component is

    discharged

    Wc =1

    2CUc

    2

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Energy requirements Energy stored in a supercapacitor

    Voltage discharge ratio: the minimum voltage during the discharge has to belimited for efficiency reasons

    The usable energy is then only part ofthe maximum stored energy

    Number of supercapacitors for a givenusable energy

    WM =1

    2CUM

    2

    d = 100

    Um

    UM

    Wu = WM

    1

    d2

    1002

    Ns =2 u

    CUM2

    1

    d2

    1002

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    13

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Energy requirements

    Using a 2600F/2.7V/0.4m#supercapacitor

    Example: 220kJ to store

    2600F, 2.5VTotal stored

    energy

    d=50% N=31 W=293.8kJ

    d=60%

    N=37 W=350.6kJ

    d=70%

    N=46 W=438kJ

    Ns =2Wu

    CUM2

    1

    d2

    1002

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Power availability

    Due to the series resistor of supercapacitors, energy efficiency ofsupercapacitors has to be taken into account during the sizing of thesupercapacitive tank

    Energy efficiency has an influence on the power availability

    Must be identified

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Procedure for the Exponential Charge

    Initial charge : uci=UM.di/100

    Charging voltage: Ue=UM.

    Charge is finished when: ucf=UM.df/100

    Main equations:

    c = UM

    1

    1

    di

    100

    e

    t

    RsC

    Tch = RsCln

    100 df

    100 di

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Procedure for the Exponential Charge

    Power in the series resistors

    Energy lost in the series resistors

    Taking into account Tch

    Energy stored in the supercapacitor

    Pr =1

    Rs

    UM uc

    2= Pr =

    1

    RsUM

    2

    1

    di

    100

    2e

    t

    RsC

    Wr =Z t0

    Prdt = Wr = 12CUM2

    1 di

    100

    21 e2t

    RsC

    Wr = 1

    2CUM

    2

    1

    100

    2df(200 df) di(200 di)

    Wc =1

    2Cucf

    2

    1

    2Cuci

    2= Wc =

    1

    2CUM

    2

    "df

    100

    2

    di

    100

    2#

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    15

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Procedure for the Exponential Charge

    Efficiency

    For a high efficiency

    dfand dimust be as high as possible

    Not compatible with a large range of voltage variation

    "It is mandatory to strictly control the charging/discharging current

    = Wc

    Wc+ Wr= =

    1

    200(df+ di)

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Efficiency for the charge/discharge with controlled current

    Main equation

    Charge/discharge time

    Energy lost

    Energy stored/provided

    uc = UMdi

    100+

    1

    C

    Icct

    Tch = CUM

    Icc

    df di

    100

    Wr = RsCIccUMdf di

    100

    Wc =1

    2CUM

    2

    "df

    100

    2

    di

    100

    2#

    c = UMdi

    100+

    1

    C

    Icdt

    Tch = CUM

    Icd

    f i

    100

    Wr = RsCIcdUMdf di

    100

    ChargeIcc>0 and df>di

    DischargeIcd

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Efficiency for the charge/discharge with controlled current

    Efficiency

    ChargeIcc>0 and df>di

    DischargeIcd

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    17

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Energy efficiency and power availability

    Using a 2600F/2.7V/0.4m#

    Example: 220kJ to store, +/- 40kW, with a 90% energy efficiency

    For this special application, the power availability is the main sizing criterion

    Seminar on Supercapacitors

    Dr. P. Barrade

    Example

    Energy requirements : 220kJ (61Wh)

    Power needs: +/- 40kW, with a 90% energy efficiency

    Number of needed supercapacitors (theoretical) :

    31 Scaps 2600F/2.7V

    Energy available : 220kJ (61Wh) if the voltage is kept over 50% of the maximum Total stored energy : 293.8kJ (81.6Wh)

    For practical reasons (energy efficiency, power availability) :

    36 Scaps 2600F/2.7V are chosen" to obtain a 90% energy efficiency

    " to assume the power demand

    Available energy :220kJ (61Wh) if the voltage is kept over 60.36% of the maximum

    Total stored energy : 341kJ (95Wh)

    Final choice : 1x36 series connected Scaps (2600F/2.7V) (16.9kg, 12.9l)

    Sizing of a supercapacitive tank

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    A supercapacitive tank is sized as an answer to Energy requirements

    Power requirements"Available power is limited by the series resistor of the cells

    "Available power is linked to the charge/discharge efficiency

    Efficiency means internal losses into the cells"Internal losses act mainly as a joule effect

    "Increase of temperature of the component

    Temperature of a supercapacitive tank must be taken into account for a completesizing:

    Natural cooling

    Forced cooling

    If no forced cooling possible, then increase the number of cells to maximise poweravailabilty (efficiency) and minimize losses

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Temperature of a supercapacitive tank must be taken into account for a completesizing

    Main parameters to study thermal behavior of a supercapacitor

    Density"

    Easy to identify

    Thermal conductivity"Generaly given by manufacturer, but deduced from experimental protocol that gives quite

    vague datas

    Thermal capacitance"Generaly not given by manufacturer

    A way to obtain this data is to consider that supercapacitors are made of 60% ofaluminium, 25% of carbon, and 15% of water (from a thermal point of view)

    Status at LEI: a complete evaluation will be made next summer

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: 3 cells (D-cells), mounted on a board, inside carbon fiber box.

    2D finite element simulation software"Coupling of heat transfer / fluid mechanics solvers

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: Stand-by mode, 15mn warming under sunning conditions (1000w/m2)

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: stand-by mode, inrush air speed is 0.5m/s

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during2400s (40mn), inrush air speed is 0.5m/s

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during2400s (40mn), inrush air speed is 0.5m/s

    Horizontal gradiant temperature

    For this application, forced cooling is needed, even if temperature is not stabilised

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Thermal aspects

    Example: power provided per cell is 110W, losses per cell are 11.3W (90.6%), during2400s (40mn), inrush air speed is 0.5m/s

    Horizontal gradiant temperature

    For this application, forced cooling is needed, even if temperature is not stabilised

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Limitation:

    Example of a hybrid elevator

    Supercapacitive tank plugged on the DC bus

    Sizing of a supercapacitive tank

    Grid

    AC

    DC

    Braking resistors

    DC

    AC

    DC

    DC

    Supercapacitive

    accumulator

    Permanent Magnet

    Synchronous Motor

    C

    L

    me

    mpmc

    mw1 mw2

    Shaft

    Ls

    u1, u2, u3

    i1, i2, i3

    IlUd Uc

    IsUs

    Ia

    It

    S

    Ib

    um1, um2, um3

    im1, im2, im3

    Seminar on Supercapacitors

    Dr. P. Barrade

    Limitation:

    Example of a hybrid elevator

    Shaft length: 18m, 5 floors

    Cabin mass: 800kg

    Up to 8 passengers

    Accumulator capacity: 20Wh

    Sizing of a supercapacitive tank

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    23

    Seminar on Supercapacitors

    Dr. P. Barrade

    Limitation:

    Example of a hybrid elevator

    Tests on strategies for energy management"

    Rule Based vs. Dynamic Programming

    Sizing of a supercapacitive tank

    0 20 40 60 800

    25

    50

    75Scaps Energy Profile

    Energy[kJ]

    Rules

    0 20 40 60 800

    25

    50

    75

    Energy[kJ]

    Mission

    DP

    Seminar on Supercapacitors

    Dr. P. Barrade

    Sizing of a supercapacitive tank

    Limitation:

    Example of a hybrid vehicle: Power requirements are easy to clearly identify

    Energy requirements are not so easy to identify"Need a deep knowledge on the system

    "Strongly affected by strategies for storing/supplying

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    24

    Seminar on Supercapacitors

    Dr. P. Barrade

    Series connection of supercapacitors :

    Power Electronics Converters

    Power losses in the associated power converter are related to thecharging/discharging current of the supercapacitors.

    The operating voltage (Scaps voltage) must be much more higher thanthe forward voltage caused by conduction in the needed converter

    To increase the efficiency for a given power

    Decrease the charging/discharging current in the supercapsIncreasing the total voltage of the supercaps

    A series connection of supercapacitors is required

    Seminar on Supercapacitors

    Dr. P. Barrade

    Unbalanced voltages: consequences

    There are differences between the Scaps values

    Power Electronics Converters

    Uc1

    I

    Uc2

    C1

    C2

    U

    Voltages across C1and C2will not be the same at the end of a

    charging process

    3 cases have to be considered : Ideal case : C1=C2

    Real case : C1$C2, but the supercapsmaximum voltage may not be reached

    Ideal Real case : C1$C2, but a deviceensures the voltages sharing

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    Seminar on Supercapacitors

    Dr. P. Barrade

    Unbalanced voltages: consequences

    The charging process is stopped as soon as one Scap reaches its maximumvoltage

    Power Electronics Converters

    C1=C2C2=80% of C1

    No sharing

    C2=80% of C1Sharing

    Uf (V) 5 4.5 5

    Uc1f (V) 2.5 2 2.5

    Uc2f (V) 2.5 2.5 2.5

    E (J) 6250 4500 5625

    Seminar on Supercapacitors

    Dr. P. Barrade

    Unbalanced voltages in the series connection of supercapacitors

    Because of differences between the various capacitances

    Consequences after various charge/discharge cycles

    Risks of over-voltages on several cells (those of lowest capacitance)

    As the charge must be stopped as soon as one cell reaches its maximumvoltage (that one of lowest capacitance)

    "The cell of high capacitance are far away from the full state of charge

    "The totat amount of stored energy can not be obtained

    "Needs in circuits for the voltage equalization

    Power Electronics Converters

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    26

    Seminar on Supercapacitors

    Dr. P. Barrade

    Power Electronics Converters

    Voltage equalization

    Voltage sharing solution, using power electronics solutions to offer a highefficiency.

    C1

    C2

    C3

    L1

    L2

    T1

    D1

    T2

    D2

    T'2

    D'2

    T'3

    D'3

    I

    i1

    i2

    il1

    il2

    i'2

    i3

    C1

    C2

    C3

    T1

    T2

    T3

    D2

    D3

    D1

    Np1

    Np2

    Np3

    Df

    Nf

    I

    i1

    i2

    i3Centralized flyback dc-dc

    converter with distributed

    secondary

    association of buck-boost

    dc-dc converters

    forward dc-dc converterwith distributed primary

    Seminar on Supercapacitors

    Dr. P. Barrade

    Power Electronics Converters

    Voltage Equalization

    Voltage sharing solution, using dissipativeelements offer also a high efficiency.

    High performances obtained thanks to anefficient control and management of voltageequalization processes

    Supercapacitor manufacturers are able topropose ready-to-use solutions, directlyintegrated into a modular supercapacitivetank

    Cell balancing

    Module to module balancing

    Integration of protection against short-circuits

    Voltage monitoring for external control

    "

    Up to 1kV!!!!!

    Courtesy from Maxwell Technologies SA

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    Power Electronics Converters

    Power electronics interfaces :

    During charging and discharging, the voltage across a supercapacitors bank isvarying :

    A power interface between the Scaps bank and its load has to be defined :

    Example : interface between a Scaps bank and a DC bus

    Scaps

    bank

    Power

    Converter

    DC bus

    Which topology ?

    Wc =

    1

    2CU

    c

    2I

    c = C c

    dt

    Seminar on Supercapacitors

    Dr. P. Barrade

    Power Electronics Converters

    Power electronics interfaces :

    Two solutions : using a buck or a boost topology

    Scapsbank

    BuckConverter

    DC bus

    Scaps

    bank

    Boost

    Converter

    DC bus

    Buck converter Boost converter

    The current provided by the Scaps is

    strongly discontinuous

    A maximum number of series

    connected Scaps is needed

    The current provided by the Scaps iscontinuous

    The number of series connected Scapscan be minimised

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    Power Electronics Converters

    Power electronics interfaces :

    Two solutions : using a buck or a boost topology

    Huge number

    of series connected

    Scaps :

    Large number ofactive components

    Safety problems

    High cost

    High efficiency

    Reduced number

    of series connected

    Scaps :

    reduced number of

    active components

    Low cost

    easier symetrizingprocess

    Low efficiency

    The boost topology offers more advantages

    Seminar on Supercapacitors

    Dr. P. Barrade

    Power Electronics Converters

    Power electronics interfaces :

    using a boost topology : association of a Boost and a buck converter

    Scaps

    bank

    DC bus

    Scaps

    bank

    DC bus

    When the DC voltage is nearly

    constant and can not be lower

    than that one of the Scaps

    When the DC voltage varies

    strongly and can become much

    lower than that one of the Scaps

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    Dr. P. Barrade

    Power electronics interfaces :

    Adapting the voltage-level with transformers Voltage adaptation with an intermediary AC-link with MF-transformer

    topology with resonant mode

    Power Electronics Converters

    Seminar on Supercapacitors

    Dr. P. Barrade

    Power electronics interfaces :

    Increasing efficiency with ZVT/ZCS Technology Topology : MF-AC-link with ZVT/ZCS converters

    Power Electronics Converters

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    Energy Storage / Energy Buffer

    Are supercapacitors able to store enough energy for a powering a bus ?

    0 100 200 300 400 500 600 700 800 900 1000-1

    0

    1

    2

    3

    4

    5

    6

    7

    8

    9x 10

    7

    t (s)

    Energie

    (J)

    0 100 200 300 400 500 600 700 800 900 1 0000

    10

    20

    30

    40

    50

    60

    70

    80

    90

    100

    t (s)

    Vitesse

    (km/h)

    From Bellerive to St Franois5km / 120m

    The needed energy is 84MJ (23.3kWh)

    19900 Scaps (1800F) / 7.46m3/ 7.96T

    Applications for supercapacitors

    Seminar on Supercapacitors

    Dr. P. Barrade

    Energy Storage / Energy Buffer

    Supercapacitors are not able tostore enough energy for acomplete run

    Some intermediary re-loadingstages have to be defined

    Bus

    Supercondensateurs

    DEPART

    STATION 1

    STATION 2

    STATION n

    ARRIVEE

    Applications for supercapacitors

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    Energy Storage / Energy Buffer

    7 loading stations

    4160 supercapacitors1800F/2.5V

    26x160 series connected

    total energy : 23.4MJ(6.5kWh)

    operational energy :

    17MJ (4.75kWh) Time for loading : 20s

    Current for loading :2.6kA

    1.6m3 / 1.7T

    Applications for supercapacitors

    Seminar on Supercapacitors

    Dr. P. Barrade

    Energy Storage / Energy Buffer

    The power absorbed bythe bus is the mirror of the

    power provided by thesupercapacitors

    The loading of thesupercapacitors needs toabsorb high magnitudepower on the network :

    1MW x 7 times x 20s

    Applications for supercapacitors

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    Energy Storage / EnergyBuffer

    when loading the mainsupercapacitors, theenergy is taken on fixsupercapacitors

    to prepare the coming ofthe next bus, the fixsupercapacitors have tobe re-loaded :

    10mn instead of 20s

    the power absorbed onthe network is low

    Bus Supercondensateur

    DEPART

    STATION 1

    STATION 2

    STATION n

    ARRIVEE

    Supercondensateursintermdiaires

    s1 s2

    Supercondensateursintermdiaires

    s1 s2

    Applications for supercapacitors

    Seminar on Supercapacitors

    Dr. P. Barrade

    Energy Storage / Energy Buffer

    The power provided bythe network is the sum ofthe low power absorbedby each loading station

    The power provided bythe network is the realmean power needed by thebus

    The power provided bythe network is less than100kW

    Applications for supercapacitors

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    Energy Storage / Energy Buffer

    The energy density of supercapacitors is too low for most of the applications It is often impossible to use supercapacitors are single energy storage devices to give

    the complete autonomy of a system

    Thanks to their power availability, supercapacitors are mainly used as energy buffers"To minimize power constraints on a main energy source

    "To allow an efficient energy management

    "To allow the recovery of energy when possible

    Applications for supercapacitors

    Supercapacitors are mainly used:

    - as energy buffers (hybrid systems)

    - as main energy sources for applications with reduced energy needs

    Seminar on Supercapacitors

    Dr. P. Barrade

    Applications for supercapacitors: elevators

    Variable frequency drives for elevators

    Elevators are intrinsically reversible systems

    3

    !"

    #"

    $"

    Conventional feeding

    Non-Reversible

    Efficiency increase

    Reversible front-end

    Efficiency increase

    Local accumulator

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    Applications for supercapacitors: elevators

    Solutions for allowing an efficiency increase

    Recovering of energy

    Reversible front-end

    "Solve the problem of energy recovering

    "Does not solve the problem of power fluctuations on the grid

    It is reinforced

    Local accumulator

    "Solve the problem of energy recovering

    Depends on the size of the accumulator

    Depends on the control

    "Can solve the problem of power fluctuations on the grid

    Depends on the size of the accumulator

    Seminar on Supercapacitors

    Dr. P. Barrade

    Applications for supercapacitors: elevators

    Structure and objectives

    Structure

    Objectives

    Increase of the global efficiency

    Limitation of power fluctuations on the grid

    GridAC

    DC

    Braking resistors

    DC

    AC

    DC

    DCSupercapacitive

    accumulator

    Permanent Magnet

    Synchronous Motor

    C

    L

    me

    mpmc

    mw1 mw2

    Shaft

    Ls

    u1, u2, u3

    i1, i2, i3

    IlUd Uc

    IsUs

    Ia

    It

    S

    Ib

    um1, um2, um3

    im1, im2, im3

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    Applications for supercapacitors: elevators

    Tests on an elevator

    Considered elevator

    Shaft length: 18m, 5 floors

    Cabin mass: 800kg

    Up to 8 passengers

    Accumulator capacity: 20Wh

    Seminar on Supercapacitors

    Dr. P. Barrade

    Applications for supercapacitors: elevators

    Tests on an elevator

    Experimental results

    0 20 40 60 800

    2

    4

    6

    Grid Power Profile

    Power[kW]

    Elevator

    0 20 40 60 800

    2

    4

    6

    Power[kW]

    Rules

    0 20 40 60 800

    2

    4

    6

    Power[kW]

    Mission

    DP

    0 20 40 60 800

    100

    200

    300Braking Resistor Energy Profile

    Energy[kJ]

    Mission

    Elevator

    Rules

    DP

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    Applications for supercapacitors: elevators

    Test on strategies

    Experimental results

    0 20 40 60 800

    25

    50

    75Scaps Energy Profile

    Energy

    [kJ]

    Rules

    0 20 40 60 800

    25

    50

    75

    Energy

    [kJ]

    Mission

    DP

    Seminar on Supercapacitors

    Dr. P. Barrade

    Diesel-electric trains

    Well-established technology on railways systems

    Lines of low traffic potential

    Reduced costs compared to the infrastructure costs of a line-powered trains

    Principle:

    Applications for supercapacitors: hybrid vehicle

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    Diesel-electric trains

    Main disadvantage Diesel engine has to assume all power and energy needs

    "Strong speed/torque fluctuations

    Efficiency, Emissions

    Losses into the energy transfer chain"

    Efficiency of asynchronous generator, power converters, asynchronous motors

    Use of resistors during braking modes

    Applications for supercapacitors: hybrid vehicle

    Seminar on Supercapacitors

    Dr. P. Barrade

    Diesel-electric trains

    How to increase efficiency Use of an energy storage tank

    "To minimize power constraints on diesel engine (decoupling of energy and power needs)

    "To allow the control of the diesel engine at its maximum efficiency, or switch it off

    "To enable energy recovering during braking phases

    technology ofsupercapacitors

    They are powercompatible

    Life time / number ofcycles compatibles

    It has to be checked ifthey are energycompatible!

    Applications for supercapacitors: hybrid vehicle

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    Case of study

    GTW train (Stadler Rail AG, CH) Total weight (w/o load): 67t

    Total weigth: 84t

    Diesel engine power: 2x380kW

    Max. power at the wheels: 620kW

    Max. speed: 140km/h

    Applications for supercapacitors: hybrid vehicle

    Seminar on Supercapacitors

    Dr. P. Barrade

    Case of study

    Track: Merano-Malles (north of Italia)

    Power profile

    Altitude variation

    0 2000 4000 6000 8000 10000 12000 14000 16000 18000-2000

    -1500

    -1000

    -500

    0

    500

    1000

    Wheel power for typical itinerary

    Time (s)

    Power(kW)

    InstantaneousMean

    0 2000 4000 6000 8000 10000 12000 14000 16000 180001000

    1100

    1200

    1300

    1400

    1500

    1600

    1700

    1800

    Altitude variation for a typical itinerary

    Time (s)

    Altitude(m)

    Applications for supercapacitors: hybrid vehicle

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    On-board stored energy versus diesel-engines power constraints

    Main results Reduction of required diesel generator power as a function of stored energy

    0 100 200 300 400 500 6000

    100

    200

    300

    400

    500

    600

    700

    Downsizing the maximal power of the diesel motor

    Stocked energy in the supercapcitive tank (MJ)

    Dieselmotorpowerneeded(kW)

    Applications for supercapacitors: hybrid vehicle

    Seminar on Supercapacitors

    Dr. P. Barrade

    In hybrid vehicle, supercapacitors enable

    To lower the sizing of thermal engines/batteries

    To increase efficiency

    Control of the thermal engine on its maximum efficiency map

    Energy saving during braking

    For catenary- fed vehicles

    Increased efficiency

    Limitation of power constraints on the grid

    "More vehicles on a line without modifying the infrastructures

    Applications for supercapacitors: hybrid vehicle

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    Uninterruptible Power Supplies (UPS applications)

    Compared with application with batteries, supercapacitors cannot propose anequivalent autonomy

    Thanks to their power density, Supercapacitors can offer:

    A reduced charging time (to reconfigure faster the UPS)

    A larger lifetime

    A maintenance free UPS

    Applications for supercapacitors

    IN

    AC

    DC

    DC

    AC

    DC

    DC

    OUT

    Switch

    Rectifier Inverter

    dc/dc interface

    ScapsTank

    Seminar on Supercapacitors

    Dr. P. Barrade

    Uninterruptible Power Supplies (UPS applications)

    Experimental results on a 500W UPS Batteries have been replaced by supercapacitors and their power converter

    5 Scaps 1800F, series connected

    Autonomy: 60sec for a 300W load

    0.2 0.25 0.3 0.35 0.4 0.45 0.5-400

    -200

    0

    200

    400

    Uin

    (V)

    0.2 0.25 0.3 0.35 0.4 0.45 0.5

    0

    5

    10

    15

    20

    Icap

    (A)

    0.2 0.25 0.3 0.35 0.4 0.45 0.5-400

    -200

    0

    200

    400

    t (s)

    Uout

    (V)

    0.05 0.1 0.15 0.2 0.25-400

    -200

    0

    200

    400

    t (s)

    Uout

    (V)

    0.05 0.1 0.15 0.2 0.25-40

    -30

    -20

    -10

    0

    10

    20

    t (s)

    Icap

    (A)

    Network failure Reconfiguration

    Applications for supercapacitors

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    Wind turbines

    Wind Turbine Pitch Control Systems

    Voltage Regulation and VARS Support

    Short term energy storage

    Applications for supercapacitors

    Seminar on Supercapacitors

    Dr. P. Barrade

    Application for airplanes

    New airbus A380

    16 doors per Aircraft (Basicversion)

    Electrically operated

    2 main doors in permanent use forboarding

    14 rescue doors for emergency use

    local door controller integratedwithin each passenger door

    Applications for supercapacitors

    Courtesy from Maxwell Technologies SA

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    Application for airplanes

    New airbus A380

    Requirements on AC level

    Operational requirements

    Doors Operation independent from AC electrical system

    Emergency opening even after transversal break of the fuselage

    Local energy storage

    High reliability

    Extremely high availability

    A/C System Requirements

    Minimum burden to the A/C Electrical System (max. 130VA, no peak loads)

    Minimum radiated and conducted distortion

    Maximum radiated and conducted susceptibility

    Robustness for primary power interrupts and transients

    Applications for supercapacitors

    Courtesy from Maxwell Technologies SA

    Seminar on Supercapacitors

    Dr. P. Barrade

    Application for airplanes

    Environmental and operating conditions

    Normal (severe) operating temperature -40 +60oC (+70oC)

    Average operating temperature +45 +55oC

    Ground survival temperature -55 +85oC

    Temperature gradients up to 5K per min.

    Operational shock (crash) up to 20g

    Operational vibrations (random sinus) with up to 4,1g

    Vibration frequency 2kHz down to 10Hz

    Application to water, fluids, sand and dust, fungus, fire, lightning etc.

    Environmental requirements, equipment in aircraft doors:

    Power supply with nominal 115VAC, variation range 96 130VAC

    Wild frequency network nominal 400Hz, variation range 360 800Hz

    Therefore

    HW and SW designed with assurance level A

    Failure rate of critical blocks 10-7 10-8 per flight hour

    Only achievable with overall double resp. triple redundancy

    Useful life 25 years resp. 140.000 flight hours

    No scheduled maintenance is allowed for the equipment

    Applications for supercapacitors

    Courtesy from Maxwell Technologies SA

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    Dr. P. Barrade

    Application for airplanes

    New airbus A380

    Energy storage device used for the doors: supercapacitors Normal operation mode

    Emergency operation mode

    Consists of 56 UltraCaps PC100G (C = 100F each)

    Arranged in 14 lines and 4 columns, connected by current rails

    Ctotal = 28,5 F

    Umatrixmax = 34 V

    Ucelltyp = 2,2 V, Ucellmax = 2,5 V 13.500 Ws (typ), 16.500 Ws (max)

    ESR < 50mOhm

    Total weight of Capacitors 2.200g

    Mechanical fixture with fixing grid

    Applications for supercapacitors

    Courtesy from Maxwell Technologies SA

    Seminar on Supercapacitors

    Dr. P. Barrade

    Conclusion

    For most of applications, supercapacitors are used to smooth power fluctuations on amain energy source

    Reduced energy density

    High power density

    Long lifetime

    Supercapacitive tank can be sized in a 2 steps process:

    Energy requirements: this defines mainly the number of components

    Power requirements: in order to match the required power availability

    Supercapacitors technology seems to be now mature enough for large scaleapplications

    Price

    Performances

    However: needs in strong developments in power electronics, competition withother technologies (flywheel)