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Estimates of Near-Infrared Atmospheric Window Absorption€¦ · 2Thomas, M. E., Optical...

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JOHNS HOPKINS APL TECHNICAL DIGEST, VOLUME 28, NUMBER 3 (2010) 264 Local line absorption within the near-infrared (NIR) atmospheric windows is reasonably well characterized by the HITRAN (HIgh-resolution TRANsmission molec- ular absorption) database. Often, lasers are selected or tuned so that local line absorption is avoided. Thus, the microwindows between these lines represent the lowest absorption that can be realized. Such microwindows are dominated by continuum-type absorption. Molecules and aerosols contribute to continuum absorption. A good estimate of aerosol absorption can be obtained from knowledge of the bulk complex index of refraction of the media composing the aerosol and the size distri- bution function as input to standard computer codes (e.g., Mie theory). APPROACH The molecular species contributing to NIR contin- uum absorption are water vapor and molecular oxygen. Unfortunately, a very limited set of experimental data exists to directly determine the absorption levels, fre- quency dependence, temperature dependence, and pressure dependence within the NIR. A combination of theory and indirect experimental data (from the mid-wavelength and long-wavelength infrared) is used to estimate the NIR continuum absorption. The con- tributions from oxygen are caused by collision-induced Estimates of Near-Infrared Atmospheric Window Absorption M. E. Thomas*, K. Siegrist*, W. E. Torruellas*, J. Kang , and K. Petrillo *JHU Applied Physics Laboratory, Laurel, MD; and JHU Department of Electrical and Computer Engineering, Baltimore, MD absorption (CIA) bands located at 1.27 and 1.06 μm. The water vapor continuum is represented as far wings of the main monomer fundamental bands defining the atmospheric windows and CIA bands underly- ing each fundamental band. The resulting models are compared to a limited set of laser-based experimental data that show good agreement at these spectral points. A calculation of a water-based aerosol absorption (e.g., light fog) shows that the molecular absorption domi- nates (Fig. 1). ACCOMPLISHMENTS AND FUTURE PLANS A semi-empirical model of NIR atmospheric window absorption attributable to molecular water and oxygen is now in place at APL; the model needs experimen- tal data for completion and verification. Preliminary field experiments with a tunable fiber laser amplified to 1 kW covering the wavelength region from 1030 to 1083 nm are planned for the near future. Also, pre- liminary cavity ring-down spectroscopic measurements to identify the contribution of CIA O 2 to the optical absorption of laser light in the atmosphere at ~1050 nm have begun. Extensive measurements are planned on oxygen and water vapor that are needed to accurately character- ize the NIR molecular continuum absorption, which I ncreased understanding of low-level atmospheric absorption is essential to propagation model predictions of thermal blooming for high-energy laser performance studies. Atmo- spheric absorption is classified into two general types, gas-phase local line and continuum.
Transcript
Page 1: Estimates of Near-Infrared Atmospheric Window Absorption€¦ · 2Thomas, M. E., Optical Propagation in Linear Media: Atmospheric Gases and Particles, Solid-State Components, and

JOHNS HOPKINS APL TECHNICAL DIGEST, VOLUME 28, NUMBER 3 (2010)264

Local line absorption within the near-infrared (NIR) atmospheric windows is reasonably well characterized by the HITRAN (HIgh-resolution TRANsmission molec-ular absorption) database. Often, lasers are selected or tuned so that local line absorption is avoided. Thus, the microwindows between these lines represent the lowest absorption that can be realized. Such microwindows are dominated by continuum-type absorption. Molecules and aerosols contribute to continuum absorption. A good estimate of aerosol absorption can be obtained from knowledge of the bulk complex index of refraction of the media composing the aerosol and the size distri-bution function as input to standard computer codes (e.g., Mie theory).

APPROACHThe molecular species contributing to NIR contin-

uum absorption are water vapor and molecular oxygen. Unfortunately, a very limited set of experimental data exists to directly determine the absorption levels, fre-quency dependence, temperature dependence, and pressure dependence within the NIR. A combination of theory and indirect experimental data (from the mid-wavelength and long-wavelength infrared) is used to estimate the NIR continuum absorption. The con-tributions from oxygen are caused by collision-induced

Estimates of Near-Infrared Atmospheric Window Absorption

M. E. Thomas*, K. Siegrist*, W. E. Torruellas*, J. Kang†, and K. Petrillo†

*JHU Applied Physics Laboratory, Laurel, MD; and †JHU Department of Electrical and Computer Engineering, Baltimore, MD

absorption (CIA) bands located at 1.27 and 1.06 μm. The water vapor continuum is represented as far wings of the main monomer fundamental bands defining the atmospheric windows and CIA bands underly-ing each fundamental band. The resulting models are compared to a limited set of laser-based experimental data that show good agreement at these spectral points. A calculation of a water-based aerosol absorption (e.g., light fog) shows that the molecular absorption domi-nates (Fig. 1).

ACCOMPLISHMENTS AND FUTURE PLANSA semi-empirical model of NIR atmospheric window

absorption attributable to molecular water and oxygen is now in place at APL; the model needs experimen-tal data for completion and verification. Preliminary field experiments with a tunable fiber laser amplified to 1 kW covering the wavelength region from 1030 to 1083 nm are planned for the near future. Also, pre-liminary cavity ring-down spectroscopic measurements to identify the contribution of CIA O2 to the optical absorption of laser light in the atmosphere at ~1050 nm have begun.

Extensive measurements are planned on oxygen and water vapor that are needed to accurately character-ize the NIR molecular continuum absorption, which

Increased understanding of low-level atmospheric absorption is essential to propagation model predictions of thermal blooming for high-energy laser performance studies. Atmo-

spheric absorption is classified into two general types, gas-phase local line and continuum.

Page 2: Estimates of Near-Infrared Atmospheric Window Absorption€¦ · 2Thomas, M. E., Optical Propagation in Linear Media: Atmospheric Gases and Particles, Solid-State Components, and

ESTIMATES OF NEAR-INFRARED ATMOSPHERIC WINDOW ABSORPTION

JOHNS HOPKINS APL TECHNICAL DIGEST, VOLUME 28, NUMBER 3 (2010) 265­­­­

Figure 2. Extrapolation to NIR. (a) Note that 10–4 km–1 range is possible at 1.045 µm, which is within the tuning range of Yb:fiber laser. (b) Absorption levels are above 10–4 km–1.

For further information on the work reported here, see the references below or contact [email protected].

1Fulghum, S. F., and Tilleman, M. M., “Interferometric Calorimeter for the Measurement of Water-Vapor Absorption,” J. Opt. Soc. Am. B 8, 2401–2413 (1991).

2Thomas, M. E., Optical Propagation in Linear Media: Atmospheric Gases and Particles, Solid-State Components, and Water, Oxford University Press, New York (2006).

will require investigating the frequency, pressure, and temperature dependence (challenging because of low absorption levels). This is planned to be accomplished in collaboration with the National Institute of Stan-dards and Technology cavity ring-down facility, with APL and the Department of Electrical and Computer Engineering developing tunable fiber lasers and match-ing the lasers to a power amplifier for field experiments. CIA and far wings will be used to interpret the data. Aerosol absorption also needs to be better understood, especially because carbon-based aerosols are a concern as countermeasures against high-energy lasers. Field testing will be conducted with a kilowatt-class tunable Yb:fiber laser (Fig. 2).

Nd: YAG

1.02 1.03 1.04 1.05Wavelength (�m)

1.06 1.07 1.08 1.09A

bsor

ptio

n co

effic

ient

(1/

km)

Yb:

fibe

r la

ser

Local water vaporabsorption lines based

on HITRAN 2004

1-�m window region16.5 Torr water vapor, airbroadened to 1 atm totalpressure. T = 303 K.

Local + total continuum

Fulghum & Tilleman experimental

Water vapor continuum model only

Molecular oxygen CIA absorption

10–4

10–5

10–3

10–2

10–1

100

101

ExperimentalWater vaporcontinuum

Local water vaporabsorption lines

Abs

orpt

ion

coef

ficie

nt (

1/km

)

1.54 1.55 1.56 1.57 1.58 1.59 1.60 1.61Wavelength (mm)

1.55-�m window region12 Torr water vapor, airbroadened to 1 atm totalpressure. T = 296 K.

Local + continuum model

Experimental

Continuum model only

10–4

10–3

10–2

10–1

100

(a)

(b)Figure 1. Calculation of a water-based aerosol absorption (e.g., light fog) showing that aerosol scatter is the dominant loss mech-anism and that, in this case, aerosol absorption is less than molec-ular continuum absorption.

5,500 6,750 8,000Wave number (1/cm)

RVis = 9.7738 km

9,250 10,500

Abs

orpt

ion

coef

ficie

nt (

1/km

)

Molecular oxygen CIA absorptionWater particle absorptionWater particle extinctionMolecular Rayleigh scatteringWater vapor continuumWater vapor continuum

10–4

10–5

10–3

10–2

10–1

100

10–6


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