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Evaluation of Evaporative Leaks using RSD dI t I li ti and Inventory Implications David Hawkins 1 , Constance Hart 1 , Carl Fulper 1 , David Brzezinski 1 James Warila 1 James Sidebottom 2 James Brzezinski , James Warila , James Sidebottom , James Kemper 2 , Sandeep Kishan 3 , Timothy H. DeFries 3 , 1 U.S. Environmental Protection Agency, Office of Transportation and Air Quality, 2000 Traverwood Drive, Ann Arbor, MI 48105 2 Colorado Department of Public Health and Environment (CDHPE), 4300 Cherry Creek Drive South, Denver, Colorado 80246 h ( ) ld i i 3 Eastern Research Group (ERG), 3508 Far West Blvd, Suite 210, Austin,TX 78731 1
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Evaluation of Evaporative Leaks using RSD d I t I li tiand Inventory Implications

David Hawkins1, Constance Hart1, Carl Fulper1, David Brzezinski1 James Warila1 James Sidebottom2 James Brzezinski , James Warila , James Sidebottom , James Kemper2, Sandeep Kishan3, Timothy H. DeFries3, 1 U.S. Environmental Protection Agency, Office of Transportation and Air Quality, 2000 Traverwood Drive, Ann Arbor, MI 481052 Colorado Department of Public Health and Environment (CDHPE), 4300 Cherry Creek Drive South, Denver, Colorado 80246

h ( ) l d i i3 Eastern Research Group (ERG), 3508 Far West Blvd, Suite 210, Austin,TX 78731

1

B k dBackgroundMOVES evaporative rates in need of pupdate

New FuelsNew Control Systems

CRC E-77 suite of programs has dd d th d f l b d t addressed the need for lab data on

aging enhanced-evap emission vehicles with different fuels and vehicles with different fuels and implanted leaksMissing piece is how many “high” Missing piece is how many high evap vehicles exist in the fleet

2

P j t G lProject GoalsDevelop cost-effective non-intrusive Develop cost effective, non intrusive, reliable measurement tools for large volume of vehicles in field

RSD as screening methodPortable SHED (PSHED)Identify leak source(s)?Identify leak source(s)?

Better characterize the evaporative emissions inventoryemissions inventory

Fraction of “High-Evap” in LD fleetLiquid vs. Vapor Leaksq pApplication to other RSD datasetsUpdate MOVES 3

Found a Partner with Same Mission

fDiscovered Colorado Department of Public Health and Environment (CDPHE) was already working on (CDPHE) was already working on same issues with RSD’s evap detectiondetectionDeveloped Cooperative Research And Development Agreement And Development Agreement (CRADA) to partner together in project developmentp j p

4

P j t D iProject Design

RSD Screening DevelopmentHow to recruit?

RSD Measurement DevelopmentPretesting at known speeds, leak rates, and exhaust HC emissionsand exhaust HC emissions

Testing Methodology

5

RSD S i D l tRSD Screening Development

Statistical sampling Sampling is biased towards recruiting vehicles identified in higher RSD binsvehicles identified in higher RSD bins

Evaporative Index 23 (EI23)Algorithm developed for recruitmentAlgorithm developed for recruitment“Work in progress”

Evap Bins (1 8)Evap Bins (1-8)1 = lowest, 8=highest

6

Pretesting: RSD Measurement developmentDetecting Propane from Fuel Fill Door: /20 Trials(Audit Truck)g ( )

15 4.5 1.5 0.45 0.15185 55 19 6 2

Exhaust HC

Evap (scfh propane)(~ g propane / 15min)

0ppmC3 19 20 12 3 31100 20 20 17 8 4m

ph

ppmC3 20 20 17 8 46015

ppmC3 11 16 3 4 1

12 m

0ppmC3 20 15 6 2 11100

ppmC3 20 15 8 1 26015 20 6 9 4 3

34 m

ph

7

6015ppmC3 20 6 9 4 3

“Hi h” E T ti M th d l“High” Evap Testing Methodology

Testing in Denver COTesting in Denver, COLipan IM station, 2008 Ken Caryl IM station, 2009y ,

Participating vehicles receive:Participating vehicles receive:Additional “Hot” RSD readingsModified CA method leak check

Handheld HC “Sniffer” CheckPSHED for 15 min hot soak

8

/RSD Testing in I/M Lane

9

PSHED Recovery/Retentiony

Average Recovery 97 6%Average Recovery 97.6%Recovery Std. Dev. 3.3% Average Retention 95.7% R t ti Std D 2 3%Retention Std. Dev. 2.3%

1010

Participation Results at Denver IM Lanes

Lipan 2008 Ken Caryl 2009

L th f T ti 4 k 8 kLength of Testing 4 weeks 8 weeksRSD Data Points (vehicle throughput) 7,011 13,027( g )

Recruited Vehicles 196 558Participants with PSHED evaluation 87 175

Acceptance Rate 44% 31%

11

Field Testing Analysis Parameters

Ultimate goal is to relate RSD scores to evap leaks

ll l f d /Initially classified .3g/15min PSHED as a “high” evap vehicle

Evap standard 2g Hot Soak + DiurnalEvap standard = 2g = Hot Soak + DiurnalAssume 20% (.4g) attributed to Hot SoakAssume 75% of that (.3g) is in first 15 min

RSD scores stratified into 8 bins to describe emissions spread

12

PSHED vs. EI23 for the Stratified Set

EI23 is one algorithm of many in development process; and

is particularly weak at is particularly weak at detecting the influence of high

exhaust HC

13

K I ith RSDKnown Issues with RSD

f fConfounding factorsNoise (variability)E h HCExhaust HCVehicle SpeedEnvironmentEnvironment

14

PSHED vs E-77 (Lab Hot Soak)

10.000

1.0005min

) LAB DATA

0.100

0 1 2 3 4 5 6 7 8 9 10

ED

(g/1

5

MeasurementRSD

0.010

PS

HE E77NoLeak

Gas Cap LeakTop of Tank/Canister Inlet Leak

0.001

Standard = .3 g/15minMedian

15Note: Vehicle condition not reconciled with data shown (ie not checked

against surveys on recent refueling, oil changes, fluid fills, or source of leaks).

Measurement RSD Bin (1-7)

E-77-3 (PSHED) vs E-77 (Hot Soak) 1996 & later

100.000M RSDPSHED and RSD agree that

PSHED vs E-77 (Hot Soak) 1996 & later

10.000

MeasurementRSDE77NoLeakE77LeakE77cLeak.3 g/15minM di

PSHED and RSD agree that vehicle is a high (>.3g) evaporative emitter.

10.000

1.000

D (g

/15m

in) Median

1.0000 1 2 3 4 5 6 7 8 9 1015

min

) LAB DATA

0.100

0 1 2 3 4 5 6 7 8 9 10

ated

PSH

ED

0.100

0 1 2 3 4 5 6 7 8 9 10

ED

(g/1

Measurement RSD Ken Caryl

E77NoLeak

0.010

Estim

a

0.010

PS

H o ea

Gas Cap LeakTop of Tank/Canister Inlet Leak

Standard = 3 g/15min

0.001 LAB DATA0.001

M t RSD Bi (1 7)

Standard .3 g/15min

Median

16

Measurement RSD Bin (1-7)

Note: Vehicle condition not reconciled with data shown (ie not checked against surveys on recent refueling, oil changes, fluid fills, or source of leaks).

Measurement RSD Bin (1-7)

Pilot Analysis & Comparison to MOVESDraftMOVES

Rates for leaking/non-leaking

Historical CRC diurnal testing% f l ki / l ki i fl t% of leaking/non-leaking in fleet

Historical IM database OBD failure codes

Preliminary comparison of E-77 to DraftMOVESRates for leaking/non-leaking

E 77 2 programs diurnal testingE-77-2 programs diurnal testing% of leaking/non-leaking in fleet

Preliminary analysis of Colorado Program

17

y y gReconstructed population from PSHED participantsReal population of fleet driving by RSD (EI23)

How Vapor Leaks are modeled in MOVESTVV)

Average “Leaking” Vehicle

Ven

ted (

T

MOVES input is a weighted

k Vap

or

V MOVES input is a weighted average based on Leak/NoLeak %

Tan

Average “Non-Leaking” Vehicle

18

Tank Vapor Generated (TVG)

Function of Fuel RVP and Temperature

Probability of "HighEvap" Summer2009 Ken Caryl IMStation y

RSD to PSHED model

70

80of

se

t EI23 basis (RSD)

50

60

70

ract

ion

m D

atas

EI23 basisPSHED basis

( )

40

50

Evap

Fr

Ran

dom

(%) Discrepancy will improve with

development of EI and/or higher“High Evap” definition

20

30

Hig

h-E

Car

yl R

0

10

0.1 1 10.3g used in

19

0.1 1 10

Definition of High PSHED (grams)analysis

First 12-hour Heating Cycle of 3-Day Diurnal(10psi fuels removed; consistent gross canister breakthrough)25

Preliminary Comparison to MOVESModel Years 2004+

2004+

25 E77 Leaks (4 tests)E77 Weighted Emission Rate (RSD)20

E77 Leaks (4 tests)

E77 Weighted Emission Rate (RSD)

MOVES 2004 Age 4-5 Weighted Emission Rate

20

d (g

)

g ( )MOVES 2004 Age 4-5 Weighted Emission RateE77 Weighted Emission Rate (PSHED)E77 No Leak (23 tests)

15

20

ted

(g)

g g

E77 Weighted Emission Rate (PSHED)

E77 No Leak (23 tests)

y = 3.2007x15

apor

Ven

ted

This linear best-fit represents ALL E77 leaks from model years 1996 and later.

10

15

por V

ent

5

10

Tank

Va

5

10

Tank

Va

y = 0

MOVES

0

5

PSHED

RSD

MOVES

5

PSHED

RSD

20

y0 1 2 3 4 5 6

Tank Vapor Generated (g/gal)0

0 1 2 3 4 5 6Tank Vapor Generated (g/gal)

PSHED

First 12-hour Heating Cycle of 3-Day Diurnal (10psi fuels removed; consistent gross canister breakthrough)

1999 200325

Preliminary Comparison to MOVESModel Year 1999-2003

1999-200325

E77 Leaks (4 tests)E77 Weighted Emission Rate (RSD)20

25 E77 Leaks (4 tests)E77 Weighted Emission Rate (RSD)MOVES 99-03 Age 8-9 Weighted Emission Rate

y = 3.2007x

20

d (g

)

MOVES 99-03 Age 8-9 Weighted Emission RateE77 Weighted Emission Rate (PSHED)E77 No Leak (19 tests)

15

20

nted

(g)

g g

E77 Weighted Emission Rate (PSHED)E77 No Leak (19 Tests)

y 3.2007x15

apor

Ven

ted

This linear best-fit represents ALL E77 leaks from model years 1996 and later.

10

15

Vapo

r Ven

5

10

Tank

V

RSD5

10

Tank

V

RSD

0

5 RSD

MOVES

PSHED

0

5 RSD

MOVESPSHED

21

0 1 2 3 4 5 6

Tank Vapor Generated (g/gal)

0 0 1 2 3 4 5 6

Tank Vapor Generated (g/gal)

C l d S 2010Colorado Summer 2010

fDevelopment of z-score indexVehicles have multiple RSD readingsC RSD k hi h d !Can use RSDs taken at high speeds!

But, lower speed RSDs have more influence

Vehicle TestingPSHED at tech centerLSHED/6-hour Diurnal at Aurora Lab

Measure real world leak behavior in diurnal!

22

MOVES SMOVES Summary MOVES is being developed along with MOVES is being developed along with RSD methodologyMOVES inputsMOVES inputs

Curve for “non-leaking” vehiclesCalculated from Diurnal test data

Curve for “leaking” vehiclesCalculated from Diurnal test data

Fraction of “leaking” vehiclesWill be used to weigh both curves togetherAs RSD indices improve this fraction can be

23

As RSD indices improve, this fraction can be measured with RSD data

How Vapor Leaks are modeled in MOVESTVV)

Average “Leaking” Vehicle

Ven

ted (

T

MOVES input is a weighted

k Vap

or

V MOVES input is a weighted average based on Leak/NoLeak %

Tan

Average “Non-Leaking” Vehicle

24

Tank Vapor Generated (TVG)

Function of Fuel RVP and Temperature

N t StNext StepsPredictive Analysis Tools, Further y ,Analysis:

Use RSD data sets to predict fraction of high levap in a metropolitan area

Do candidate RSD data sets exist within the limitations of the measurement capabilities?limitations of the measurement capabilities?How do the PSHED results relate to OBD evap codes and can we make a link between RSD and OBD from this?

CDPHE Summer 2010 High Evap Testing

25

Develop z-score RSD indexAnalyze PSHED/LSHED data for use in MOVES

Questions?

26


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