+ All Categories
Home > Documents > Exergetic Optimization of Power Generation...

Exergetic Optimization of Power Generation...

Date post: 29-Jul-2020
Category:
Upload: others
View: 3 times
Download: 1 times
Share this document with a friend
67
International Journal of Chemical Engineering Exergetic Optimization of Power Generation Systems Guest Editors: Pouria Ahmadi, Halil S. Hamut, Ahmadreza Ghaffarizadeh, Pedram Hanafizadeh, and Esmaiil Ghasemisahebi
Transcript
  • International Journal of Chemical Engineering

    Exergetic Optimization of Power Generation Systems

    Guest Editors: Pouria Ahmadi, Halil S. Hamut, Ahmadreza Ghaffarizadeh, Pedram Hanafizadeh, and Esmaiil Ghasemisahebi

  • Exergetic Optimization of PowerGeneration Systems

  • International Journal of Chemical Engineering

    Exergetic Optimization of PowerGeneration Systems

    Guest Editors: Pouria Ahmadi, Halil S. Hamut,Ahmadreza Ghaffarizadeh, Pedram Hanafizadeh,and Esmaiil Ghasemisahebi

  • Copyright © 2016 Hindawi Publishing Corporation. All rights reserved.

    This is a special issue published in “International Journal of Chemical Engineering.” All articles are open access articles distributed underthe Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, providedthe original work is properly cited.

  • Editorial Board

    Jerzy Bałdyga, PolandMostafa Barigou, UKGino Baron, BelgiumGiuseppe Caputo, ItalyRaghunath V. Chaudhari, USAJean-Pierre Corriou, FranceSébastien Déon, FranceDonald L. Feke, USAJinlong Gong, ChinaThomas R. Hanley, USAMichael Harris, USA

    Xijun Hu, Hong KongM. G. Ierapetritou, USAKonstantinos Kakosimos, QatarDilhan M. Kalyon, USAIftekhar A. Karimi, SingaporeBhaskar Kulkarni, IndiaDeepak Kunzru, IndiaJanez Levec, SloveniaJose C. Merchuk, IsraelSubrata Mondal, IndiaBadie I. Morsi, USA

    Sohail Murad, USADmitry Murzin, FinlandDoraiswami Ramkrishna, USAJose Alberto Romagnoli, USAEvangelos Tsotsas, GermanyToshinori Tsuru, JapanJunwu Wang, ChinaTapio Westerlund, FinlandJaime Wisniak, IsraelKing Lun Yeung, Hong Kong

  • Contents

    Exergetic Optimization of Power Generation SystemsPouria Ahmadi, Halil S. Hamut, Ahmadreza Ghaffarizadeh, Pedram Hanafizadeh,and Esmaiil GhasemisahebiVolume 2016, Article ID 3962847, 2 pages

    Exergy and Exergoenvironmental Analysis of a CCHP System Based on a Parallel Flow Double-EffectAbsorption ChillerAli MousafarashVolume 2016, Article ID 2370305, 8 pages

    Exergy and Environmental Impact Assessment between Solar Powered Gas Turbine and ConventionalGas Turbine Power PlantAli Rajaei, Hasan Barzegar Avval, and Elmira EslamiVolume 2016, Article ID 8323859, 8 pages

    Performance Assessment of a Hybrid Solar-Geothermal Air Conditioning System for ResidentialApplication: Energy, Exergy, and Sustainability AnalysisYasser Abbasi, Ehsan Baniasadi, and Hossein AhmadikiaVolume 2016, Article ID 5710560, 13 pages

    Exact Optimum Design of SegmentedThermoelectric GeneratorsM. Zare, H. Ramin, S. Naemi, and R. HosseiniVolume 2016, Article ID 6914735, 11 pages

    Power Prediction and Technoeconomic Analysis of a Solar PV Power Plant by MLP-ABC andCOMFAR III, considering Cloudy Weather ConditionsM. Khademi, M. Moadel, and A. KhosraviVolume 2016, Article ID 1031943, 8 pages

    Modeling and Assessment of a Biomass Gasification Integrated System for Multigeneration PurposeShoaib Khanmohammadi, Kazem Atashkari, and Ramin KouhikamaliVolume 2016, Article ID 2639241, 11 pages

  • EditorialExergetic Optimization of Power Generation Systems

    Pouria Ahmadi,1 Halil S. Hamut,2 Ahmadreza Ghaffarizadeh,3

    Pedram Hanafizadeh,4 and Esmaiil Ghasemisahebi5

    1Fuel Cell Research Lab (FCReL), Simon Fraser University (SFU), Vancouver, BC, Canada2Technological Research Council of Turkey, Kocaeli, Turkey3University of Southern California, Los Angeles, CA, USA4University of Tehran, Tehran, Iran5Florida International University, Miami, FL, USA

    Correspondence should be addressed to Pouria Ahmadi; [email protected]

    Received 19 May 2016; Accepted 19 May 2016

    Copyright © 2016 Pouria Ahmadi et al.This is an open access article distributed under the Creative Commons Attribution License,which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

    With increasing global population and dwindling energysources, generation of energy in a cost-effective manner withminimum waste and environmental footprint becomes oneof the greatest challenges of our time. Thus, there is anincreasing need formore capable and intelligent use of energysources by incorporating enriched designs and optimizedalgorithms to enhance the sustainability of energy systemsthrough innovative solutions. In this regard, themethods andtools for novel analyses and evaluation of energy systems toimprove their efficiency and reduce their cost and environ-mental impact become imperative and require significantattention.

    Recently, exergy has become a new distinct disciplinefor system design, analysis, optimization, and performanceevaluation; and its use has been expanded drastically. Manyresearchers and practicing engineers refer to exergy methodsas powerful tools for analyzing, assessing, designing, improv-ing, and optimizing systems and processes. Exergy analysisappears to be an important tool to industry in (a) addressingthe impact of energy resource utilization on the environmentand economics, (b) furthering the goal of more efficientenergy resource utilization, (c) determining locations, types,and true magnitudes of wastes and losses, (d) revealingwhether or not and how much it is possible to design moreefficient energy systems by reducing the inefficiencies, and (e)providing a sustainable development as a result of sustainablesupply of energy resources. Exergy analysis is a method thatuses the conservation of mass and conservation of energy

    principles together with the second law of thermodynamicsfor the analysis, design, and improvement of energy systems.The exergy method is a useful tool for furthering the goal ofmore efficient energy resource use, for it enables the locations,types, and true magnitudes of wastes and losses to be deter-mined. Many engineers and scientists suggest that the ther-modynamic performance of a process is best evaluated byperforming an exergy analysis in addition to or in place ofconventional energy analysis because exergy analysis appearsto provide more insights and to be more useful in efficiencyimprovement efforts than energy analysis.

    In the following, a brief overview and summary of theindividual contributions are given.

    The first contribution in this issue from S. Khanmoham-madi et al. (University of Guilan, Rasht, Iran) is titled “Mod-eling and Assessment of a Biomass Gasification IntegratedSystem for Multigeneration Purpose.” This paper focuses onthe accuratemodeling of biomass gasification process and theoptimal design of amultigeneration system (heating, cooling,electrical power, and hydrogen as energy carrier) to take theadvantage of this clean energy. In the process of gasificationmodeling, a thermodynamic equilibrium model based onGibbs energy minimization is used. The results show thatwith exergy efficiency as an objective function this parametercan increase from 19.6% in the base case to 21.89% in theoptimized case. Also, for the total cost rate of the system asan objective function, it can decrease from 154.4 $/h to 145.1$/h.

    Hindawi Publishing CorporationInternational Journal of Chemical EngineeringVolume 2016, Article ID 3962847, 2 pageshttp://dx.doi.org/10.1155/2016/3962847

    http://dx.doi.org/10.1155/2016/3962847

  • 2 International Journal of Chemical Engineering

    The paper by M. Khademi et al. (Islamic Azad University,South Tehran Branch, Tehran, Iran) is titled “Power Predic-tion and Technoeconomic Analysis of a Solar PV Power PlantbyMLP-ABC andCOMFAR III, consideringCloudyWeatherConditions.” The authors try to predict the output power ofa 3.2 kW PV power plant using the MLP-ABC (multilayerperceptron-artificial bee colony) algorithm. Experimentaldata (ambient temperature, solar radiation, and relativehumidity) were gathered at five-minute intervals fromTehranUniversity’s PV Power Plant from September 22, 2012, to Jan-uary 14, 2013. A detailed economic analysis is also presentedfor sunny and cloudy weather conditions using COMFARIII software. A detailed cost analysis indicated that the totalinvestment payback period would be 3.83 years in sunnyperiods and 4.08 years in cloudy periods. The results showedthat the solar PV power plant is feasible from an economicpoint of view in both cloudy and sunny weather conditions.

    The paper “Exact Optimum Design of Segmented Ther-moelectric Generators” by M. Zare et al. (Amirkabir Univer-sity of Technology, Tehran, Iran) highlights the importanceof thermoelectric generator for power generation. This studymainly focuses on the employment of exact method fordesign and optimization of STEGs and comparison of exactand approximate results. Thus, using new, highly efficientthermoelectricmaterials, four STEGs are proposed to operatein the temperature range of 300 to 1300 Kelvins. Designand performance characteristics of the optimized generators,including maximum conversion efficiency and length ofelements, are calculated through both exact and approximatemethods. The comparison indicates that the approximatemethod can cause a difference up to 20% in the calculationof some design characteristics despite its appropriate resultsin efficiency calculation. The results also show that themaximum theoretical efficiency of 23.08% is achievable usingthe new proposed STEGs.

    The paper by Y. Abbasi et al. (University of Isfahan,Isfahan) is entitled “Performance Assessment of a HybridSolar-Geothermal Air Conditioning System for ResidentialApplication: Energy, Exergy, and Sustainability Analysis.”This paper investigates the performance of a ground sourceheat pump that is coupled with a photovoltaic system toprovide cooling and heating demands of a zero-energyresidential building. Exergy and sustainability analyses havebeen conducted to evaluate the exergy destruction rate andSI of different compartments of the hybrid system.The resultsshow that the exergetic efficiency of the solar-geothermal heatpump system does not exceed 10 percent, and most exergydestruction takes place in photovoltaic panel, condenser, andevaporator. Although SI of PV system remains constant dur-ing a year, SI of GSHP varies depending on cooling and heat-ing mode.The results also show that utilization of this hybridsystem can reduce CO

    2emissions by almost 70 tons per year.

    Exergy and exergoenvironmental analysis of a CCHP sys-tembased on a parallel flowdouble-effect absorption chiller isconducted by A. Mousafarash (Shahid Rajaee Teacher Train-ing University, Tehran, Iran). A CCHP system is comprisedof a gas turbine, a heat recovery steam generator, and adouble-effect absorption chiller. Exergy and exergoeconomicanalyses are conducted as a potential tool to assess the system.

    The results show that exergy efficiency of the CCHP systemis higher than the power generation system and the cogen-eration system. In addition, the results indicate that whenwaste heat is utilized in the heat recovery steam generator,the greenhouse gasses are reduced when the fixed poweroutput is generated. In addition, an increase in gas turbineinlet temperature increases the system exergy efficiency anddecreases the total exergy destruction rate consequently.

    The last paper of this special issue by A. Rajaei et al.(Power and Water University of Technology, Tehran, Iran)is titled “Exergy and Environmental Impact Assessmentbetween Solar Powered Gas Turbine and Conventional GasTurbine Power Plant.” In this paper a comprehensive com-parison between these two systems in terms of energy, exergy,and environmental impacts is carried out. To evaluate theeffects of energy resources relevantly, exergy destruction ratesare categorized into two types: renewable and nonrenewablewhich expresses how much green the cycles are. Nonrenew-able exergy destruction and loss are reduced compared to GTwith the recuperator cycle by 34.89% and 47.41%, respectively.They defined a renewable factor to evaluate resources qualityandmeasure how green an exergy loss or destruction or a sys-tem as a whole is. Reduction in CO

    2, NOx, and CO compared

    to GT with the recuperator cycle by 49.92%, 66.14%, and39.77%, respectively, is in line with the renewable factor valueof around 55.7 which proves the ability of the proposed greenmeasure to evaluate and compare the cycles’ performance.

    This special issue tried to shed light on the importance ofexergy analysis for better design, better efficiency, and betterassessment of power generation systems. The exergy analysishas been extended to include environmental, economical,and societal considerations. Environmental issues such as airpollution, global warming, and recycling have been linked toexergy. In this regard, somemethods such as “exergoecology”and “exergoenvironment” have been proposed. We are confi-dent that there will be more advancements in this field whichwill be seen in the coming years. Although exergy analysis hashelped to design more efficient energy systems, the connec-tion between economy and environment is necessary as well.

    Acknowledgments

    We would like to express our sincere thanks to all thereviewers for the time they spent on the review process of thisspecial issue.

    Pouria AhmadiHalil S. Hamut

    Ahmadreza GhaffarizadehPedram Hanafizadeh

    Esmaiil Ghasemisahebi

  • Research ArticleExergy and Exergoenvironmental Analysis of a CCHP SystemBased on a Parallel Flow Double-Effect Absorption Chiller

    Ali Mousafarash

    Mechanical Engineering Department, Shahid Rajaee Teacher Training University (SRTTU), Tehran 16788 15811, Iran

    Correspondence should be addressed to Ali Mousafarash; [email protected]

    Received 3 November 2015; Revised 27 March 2016; Accepted 14 April 2016

    Academic Editor: Halil S. Hamut

    Copyright © 2016 Ali Mousafarash. This is an open access article distributed under the Creative Commons Attribution License,which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

    A combined cooling, heating, and power (CCHP) systemwhich produces electricity, heating, and cooling is modeled and analyzed.This system is comprised of a gas turbine, a heat recovery steam generator, and a double-effect absorption chiller. Exergy analysis isconducted to address the magnitude and the location of irreversibilities. In order to enhance understanding, a comprehensiveparametric study is performed to see the effect of some major design parameters on the system performance. These designparameters are compressor pressure ratio, gas turbine inlet temperature, gas turbine isentropic efficiency, compressor isentropicefficiency, and temperature of absorption chiller generator inlet.The results show that exergy efficiency of theCCHP system is higherthan the power generation system and the cogeneration system. In addition, the results indicate that when waste heat is utilizedin the heat recovery steam generator, the greenhouse gasses are reduced when the fixed power output is generated. Accordingto the parametric study results, an increase in compressor pressure ratio shows that the network output first increases and thendecreases. Furthermore, an increase in gas turbine inlet temperature increases the system exergy efficiency, decreasing the totalexergy destruction rate consequently.

    1. Introduction

    Fossil fuels release harmful gases to the atmosphere; inaddition, they have limited resources that will be exhaustedin the early future. Such a fact makes the world face a seriouscrisis in the 21st century. An increase in earth temperatureand seriousness of greenhouse gases may burden extra costson industries and the economy of those countries withhigh per capita consumption. Due to fossil fuel depletion,increasing fuel prices, and energy demand the use of highefficiencies power plants is very important. In traditionalpower generation systems a large amount of heat is lost byexhaust gases. Consequently using of waste heat increasespower plant’s efficiency. The combined cooling, heating, andpower (CCHP) is a system that can produce power, heating,and cooling from a common energy source such as naturalgas, oil, or sun. In a CCHP system, waste heat drives heatingand cooling devices. The waste heat can be used for spaceheating, domestic hot water production, or production ofsteam. The waste heat can be used for cooling by driving arefrigeration system like an absorption chiller. The overall

    energy efficiency of a trigeneration plant can attain 80%[1]. Through the absorption chiller and heat recovery steamgenerator in these systems, the extra heat releasing from thegas turbine can provide the needed cryogenic and thermalenergies of a given site and supply the electricity without anyseparate consumption of fuel.

    In recent years, economy is not the only matter; builtenvironment is important too. Numerous studies have beencarried out to reduce the greenhouse gas emissions and therehave been several efforts worldwide to come up with plansand strategies for global warming mitigation. Nowadays,environmental impact of a plant is a design considerationbeside the plants’ economy. Furthermore, due to energyresources shortages, systems are designed to utilize the energysources as efficient as possible. Economy, environment, andsustainability of energy resources are the basic criteria for anyenergy systems. By the advent of the exergy definition, exergyefficiency has become popular since it has a close relationwith sustainability. Furthermore, because exergy evaluatesthe exact value of the extractable work from a stream orresource, it is more suitable for economic evaluation and

    Hindawi Publishing CorporationInternational Journal of Chemical EngineeringVolume 2016, Article ID 2370305, 8 pageshttp://dx.doi.org/10.1155/2016/2370305

    http://dx.doi.org/10.1155/2016/2370305

  • 2 International Journal of Chemical Engineering

    analysis. Hence, the exergy-economic and environmentalassessment and modeling approach is an acceptable methodfor analyzing and designing the energy systems.

    Exergy efficiency stands for energy sources managementbut linked with the economy of the plant and has a directrelationship with environmental emission. Since then it isalways subjected to optimization. Other objectives are costof the plant and emission. Nowadays, carbon taxes andemission cost are evaluated and implemented in plant costconsiderations. Other emissions like NO

    𝑥, SO𝑥, and CO

    which are classified as toxic or hazard gases have their owncosts and taxes as well. To evaluate the exact plant cost theseissues must add to the total cost of the plant.

    Havelský [2] analyzed the problem of energy efficiencyevaluation of cogeneration systems for combined heating,cooling, and power production and presented equations forenergy efficiency and primary energy savings. Athanasoviciet al. [3] offered a unified comparison method for thethermodynamic efficiency of combined heat and powerplants. A comparison between separate and combined energyproduction processes has been studied by using this analysismethod.Minciuc et al. [4] proposed amethod for the analysisof triple generation systems and established some limitingthermodynamic boundaries for optimum performance oftriple generation systems combined with absorption chiller.

    Sahoo [5] performed economic energy for a combinedpower and heat system. Huicochea et al. [6] analyzed the-oretically the thermodynamic performance of a trigenera-tion system formed by a microturbine and a double-effectwater/LiBr absorption chiller and evaluated that at differentoperating conditions. Ahmadi et al. [7] carried out energyand exergy analyses, environmental impact assessments,and related parametric studies for a trigeneration system.Their results show that trigeneration exhibits higher exergyefficiencies and lower environmental impacts compared totypical combined heat and power systems or gas turbinecycles.

    Al-Sulaiman et al. [8] indicated that using the trigen-eration plant compared with the power cycle eventuatedefficiency gain of more than 22%. They also demonstratethe maximum efficiency is 74% for the trigeneration system,71% for CHP system, and 46% for net electricity generation.Amrollahi et al. [9] performed thermodynamic analysis ofpostcombustion CO

    2capture in a natural gas-fired power

    plant. Rezaie and Rosen [10] have reviewed district energysystems and possible future developments. They discussedvarious assortments, definitions, and applications of districtcooling and heating and described elements of a districtenergy system.

    In this research study, exergy and environmental impactassessment are performed for a trigeneration system basedon a parallel flow double-effect absorption chiller modeledby thermodynamic equations. The parametric evaluations ofchanges on selected design parameters (compressor pressureratio, gas turbine inlet temperature, gas turbine isentropicefficiency, compressor isentropic efficiency, and temperatureof absorption chiller generator inlet) on exergy and energyefficiencies were evaluated.

    2. Energy Analysis

    In this part, the CCHP cycle is modeled using EES software,by thermodynamic equations. To determine energy of differ-ent lines, it is required to identify thermodynamic parametersof the cycle through modeling its components. Modeling ofeach component is performed in terms of the first law andmass-energy balance law.Next, exergy of various points in thecycle, shown in Figure 1, is calculated and exergy efficiencyand destruction are computed by writing the exergy balancefor every component of the cycle.

    2.1. Gas Turbine Cycle. Gas turbine cycle was modeled basedon first law of thermodynamics. As shown in Figure 1,the air enters the compressor at ambient conditions (point1); hot air then enters a combustion chamber where fuelis injected to increase its temperature at point 3. Next,the flue gas generated from combustion in the combustionchamber is extracted (point 3) and the power is producedby passing this gas from gas turbine (point 4). Gas turbinecycle wastes typically occur in three main componentsincluding compressor, combustion chamber, and gas turbine.To calculate irreversibility computations for each component,it is required to consider each of them as a control volume.Energy balance and the governing equations of this cyclecomponents are as follows.

    Air compressor:

    𝑇2= 𝑇1(1 +

    1

    𝜂𝑐

    (𝑟(𝛾𝑎−1)/𝛾

    𝑎

    𝑐− 1)) ,

    �̇�𝑐= �̇�𝑎𝐶𝑝𝑎(𝑇2− 𝑇1) ,

    (1)

    where �̇�𝑎is air mass flow rate, 𝜂

    𝑐is air compressor isentropic

    efficiency, 𝛾𝑎is specific heat ratio, 𝑟

    𝑐is compressor pressure

    ratio, and 𝐶𝑝𝑎

    is considered a function of temperature asfollows [11]:

    𝐶𝑝𝑎(𝑇) = 1.048 − (

    1.83𝑇

    104) + (

    9.45𝑇2

    107)

    − (5.49𝑇

    3

    1010

    ) + (7.92𝑇

    4

    1014

    ) .

    (2)

    Combustion chamber:

    �̇�𝑎ℎ2+ �̇�𝑓LHV = �̇�

    𝑔ℎ3+ (1 − 𝜂CC) �̇�𝑓LHV,

    𝑃3

    𝑃2

    = (1 − Δ𝑃CC) ,

    �̇�𝑔= �̇�𝑎+ �̇�𝑓.

    (3)

    Gas turbine:

    𝑇4= 𝑇3(1 − 𝜂GT (1 − 𝑟

    (1−𝛾𝑔)/𝛾𝑔

    GT )) ,

    �̇�GT = �̇�𝑔𝐶𝑝𝑔 (𝑇3 − 𝑇4) ,

    �̇�net = �̇�GT − �̇�𝑐,

    (4)

  • International Journal of Chemical Engineering 3

    where ̇𝑚𝑓is fuel mass flow rate, �̇�

    𝑎is air mass flow rate, �̇�

    𝑔

    is combustion gases mass flow rate, LHV is the fuel lowerheating value, 𝜂CC is combustion chamber efficiency, 𝛾𝑔 iscombustion gases specific heat ratio, 𝑟GT is gas turbine pres-sure ratio, and𝐶

    𝑝𝑔is considered a function of temperature as

    follows [11]:

    𝐶𝑝𝑔(𝑇) = 0.991 + (

    6.997𝑇

    105) + (

    2.712𝑇2

    107

    )

    − (1.2244𝑇

    3

    1010

    ) .

    (5)

    2.2. Heat Recovery Steam Generator (HRSG). The consideredsingle pressure HRSG consists of an economizer and anevaporator to produce steam. The supply water enters firstto the economizer and its temperature rises up to saturationtemperature. Then, it enters to the evaporator and vaporquality approaches 1 at a constant temperature and pressure.Some of the vapor enters to absorption chiller and theremaining is used in heat applications.The energy balance forthe assumed HRSG is as follows.

    Evaporator:

    �̇�𝑔𝐶𝑝𝑔(𝑇𝑎− 𝑇𝑏) = �̇�

    36(ℎ37− ℎ36) . (6)

    Economizer:�̇�𝑔𝐶𝑝𝑔(𝑇4− 𝑇𝑎) = �̇�

    37(ℎ38− ℎ37) ,

    PP = 𝑇𝑎− 𝑇38,

    AP = 𝑇38− 𝑇37,

    (7)

    where 𝐶𝑝𝑔

    is combustion gases specific heat at constantpressure and the pinch point (PP) is defined as the differencebetween the temperature of the gas at the entrance of theevaporator (𝑇

    𝑎) and the saturation temperature (𝑇

    38) and the

    approach point (AP) is the temperature differences betweenthe water leaving the economizer (𝑇

    37) and the saturation

    temperature (𝑇38).

    2.3. Double-Effect Absorption Chiller. In the consideredCCHP system in this study, a Li-Br parallel flow double-effectabsorption chiller is modeled. It must be noted that, duringmodeling of this chiller, the hot water output flowing fromhigh-temperature generator (point 6) was used for heatingthe convection flowof thewater and lithiumbromide solutionto increase the chiller performance. Doing so, coefficientperformance of the proposed model increases to about 0.1.Each component of the chiller is assumed as a controlvolume and their mass-energy balance and thermodynamicequations are expressed as follows [7]:

    ∑�̇�in = ∑�̇�out,

    ∑ (�̇�𝑥)in = ∑(�̇�𝑥)out ,

    �̇� − �̇� = ∑ (�̇�ℎ)out −∑(�̇�ℎ)in ,

    (8)

    where �̇� is working fluid mass flow rate and 𝑥 is mass con-centration of Li-Br in the solution.

    2.4. Assumptions. Several assumptions have been used tosimplify the model:

    (i) All the processes are done at steady state.(ii) Natural gas is the fuel used in the combustion cham-

    ber.(iii) The dead state is 𝑃

    0= 1.01 bar and 𝑇

    0= 293.15K.

    (iv) Air and combustion products are assumed to be ideal-gas mixtures.

    3. Exergy Analysis

    Exergy in a system of ideal machines is defined as themaximum theoretical expedient work that may be receivedfrom energy. Frankly, exergy is not summarized in a singleprocess and could be diminished as a result of irreversibility.In this way, it is possible to separately scrutinize each portionof the cycle and to attain the share of each element in theoverall energy loss of the cycle. Concerning gas turbinepower plants, with respect to any input fuel or flow intothe power plant, the maximum capacity of the power plantcan be calculated via exergy analysis. Exergy of matter flowcan be categorized into its major constituents comprisingkinetic, potential, physical, and chemical exergies. In thispaper, kinetic and potential exergies are ignored due totheir dispensable rates. Physical exergy is defined as themaximum theoretical useful work acquired whilst a systeminteracts with an equilibrium state [12]. Chemical exergy isconnected with the departure of the chemical composition ofa system from its chemical equilibrium. Chemical exergy isan imperative part of exergy in the combustion process [13].Using the first and second laws of thermodynamics, we havethe following exergy balance:

    ̇Ex𝑄+∑

    in�̇�𝑖ex𝑖= ∑

    out�̇�𝑜ex𝑜+ ̇Ex𝑊+ ̇Ex𝐷, (9)

    where ex is total specific exergy and ̇Ex𝐷is exergy destruction

    rate; other terms in this equation are defined as follows [14]:

    ̇Ex𝑄= (1 −

    𝑇0

    𝑇𝑖

    ) �̇�𝑖,

    ̇Ex𝑊= �̇�,

    exph = (ℎ − ℎ0) − 𝑇0 (𝑠 − 𝑠0) ,

    ̇ex = ̇exph + ̇exch,

    (10)

    where 𝑇 is absolute temperature (K) and subscripts 𝑖 and 0refer to ambient conditions. The mixture chemical exergy isattained using the following relations [15]:

    exchmix = [𝑛

    𝑖=1

    𝑋𝑖exch𝑖 + 𝑅𝑇

    0

    𝑛

    𝑖=1

    𝑋𝑖ln𝑋𝑖] . (11)

    The following relation is used to compute fuel exergy [14]:

    𝜉 =

    ex𝑓

    LHV𝑓

    . (12)

  • 4 International Journal of Chemical Engineering

    Compressor

    Combustionchamber

    Gas turbineNet power

    HTCHTG

    LTC

    SHE

    LTG

    SHE

    ABSEVP

    Fuel

    Expansionvalve

    Expansionvalve

    Throttlingvalve

    Throttlingvalve

    1

    2 3

    4

    For heatingpurpose

    Feed water

    5

    7

    6

    23 24

    22

    21

    20

    25

    26

    8

    18

    17

    27

    16

    15

    28

    29

    3130

    14

    33 32

    13

    12

    34 35 11

    10

    9

    19

    ECO

    EVP

    a

    b

    38

    36

    37HRS

    G

    Cooling water

    Cooling water

    Chilled water

    Wp

    Wp

    Figure 1: Schematic of the CCHP system.

    For most regular gaseous fuels, the ratio of chemical exergyto lower heating value is generally close to 1. While the mainfuel used in power plants is methane, we have [14]

    𝜉CH4

    = 1.06. (13)

    4. Exergoenvironmental Analysis

    Of the advantages of combined heat and power systems,one can name economization in fuel consumption, reducingthe contaminators, and, finally, decreasing environmentalcosts. Fuel saving, which is the consequence of no need

  • International Journal of Chemical Engineering 5

    to another heat generator (such as steam boiler in separategeneration), and using the clean fuels such as natural gasare considered the essential factors in decreasing pollutionproduced by these systems. The environmental benefits ofcombined power and heat systems use less fuel with higherefficiency, consequently leading to less air pollution. Com-bustion process in a gas turbine occurs with generating largeamount of extra air, since the obtained output power highlydepends on the mass flow of the turbine. Gas turbine isamong the least pollutant fossil fuel consuming equipment inpower generation.Themain pollutants of the gas turbines arenitrogen oxides, carbon monoxide, and carbon dioxide. Thegenerated nitrogen oxide (gr per kg of the fuel) from combus-tion chamber is obtained using the following equation [13]:

    𝑚NO𝑥

    =0.15 × 10

    16

    𝜏0.5 exp (−71100/𝑇PZ)

    𝑃0.05

    3(Δ𝑃3/𝑃3)0.5

    ,

    𝑚CO =0.179 × 10

    9 exp (7800/𝑇PZ)𝑃2

    3𝜏 (Δ𝑃

    3/𝑃3)0.5

    .

    (14)

    Here 𝜏 is the residence time in the combustion zone (assumedconstant here at 0.002 s), 𝑇PZ is the primary zone combustiontemperature,𝑃

    3is the combustor inlet pressure, andΔ𝑃

    3/𝑃3is

    the nondimensional pressure drop in the combustion cham-ber [13]. Using the equation of combustion as well as obtainedvalues for the nitrogen oxides and carbon monoxide, theamount of carbon dioxide emission will be achieved.

    5. Results and Discussion

    Figure 2 presents the charts of energy efficiency, exergyefficiency, and the amount of carbon dioxide emissions perunit of output power for the gas turbine, CHP, and CCHPcycles. It is known that the levels of energy efficiency andexergy efficiency increase with the promotion of gas turbinecycle to CHP and CCHP cycles but the amount of carbondioxide emissions per unit of output power declines. Increaseof CCHP cycle’s energy efficiency is much more than itsexergy efficiency, because the exergy flow rate of heat transferis less than the heat rate. In Figure 3, exergy loss is plotted foreach of the components of the cycle. According to the chart itis determined that the combustion chamber has the highestrate of irreversibility among other components, and this isdue to the chemical reactions taken place in the combustionchamber as well as a large temperature difference betweenthe working fluid and the flame. After combustion chamber,recovery boiler has the most exergy loss.

    5.1. Effect of Varying Compressor Pressure Ratio. Accordingto Figure 4, the exergy efficiency for the CCHP cycle isfirst increased and then decreased. Initially, due to theincreased inlet temperature to the combustion chamber andthe reduction of the input fuel, efficiency increases. But at acertain pressure ratio, compressor work rate will excess thefuel reduction rate and leads to reduced exergy efficiency.Figure 5 investigates the changes in the amount of carbondioxide per unit of output power (including electricity, heat,

    CO2 emission (kg/kwh)Exergy efficiency (%)

    CHP

    Energy efficiency (%)

    CCHPGT

    1

    0.8

    0.6

    0.4

    0.2

    0

    Figure 2: Energy efficiency, exergy efficiency, and normalized CO2

    emission for CCHP, CHP, and gas turbine cycles.

    10000

    8000

    6000

    4000

    2000

    0Exe

    rgy

    destr

    uctio

    n ra

    te (k

    w)

    Com

    pres

    sor

    Com

    busti

    on ch

    ambe

    r

    Gas

    turb

    ine

    HRS

    G

    Hig

    h ge

    nera

    tor

    Low

    cond

    ense

    r

    Evap

    orat

    or

    Abso

    rber

    Low

    gen

    erat

    or−

    high

    cond

    ense

    r

    Figure 3: Exergy destruction rate for each component of the system.

    and cold) compared to the increased compressor pressure.It is observed that, with increasing the pressure ratio ofcompressor in the desired trigeneration system, the amountof carbon dioxide emissions per unit of output increases,which is due to decrease of heat energy obtained from therecovery boiler.

    5.2. Effect of Varying Gas Turbine Inlet Temperature. Gasturbine inlet temperature is one of the most importantdecision-making parameters in the trigeneration system onthe basis of gas turbine. The increase of this temperaturecan increase the net output of work. Energy balance ofthe combustion chamber shows that the increase of inlettemperature to the gas turbine will increase the input fuel.As it can be observed in Figure 6, with the increase ofinlet temperature to gas turbine, the exergy efficiency ofcogeneration cycle will increase. This increase is due to thefact that an increase in the gas turbine inlet temperaturewill lead to the fact that the rate of network increase in gas

  • 6 International Journal of Chemical Engineering

    5 10 15 200.35

    0.36

    0.37

    0.38

    0.39

    0.4

    11000

    12000

    13000

    14000

    15000

    16000

    Exer

    gy effi

    cien

    cy

    Exergy efficiencyExdtot

    rc

    ̇

    Exd t

    ot(k

    W)

    Figure 4: Variation with compressor pressure ratio of exergy effi-ciency and total exergy destruction rate.

    5 10 15 200.23

    0.25

    0.27

    0.29

    0.31

    Nor

    mal

    ized

    CO

    2em

    issio

    n (k

    g/kw

    h)

    rc

    Figure 5: Variation with compressor pressure ratio of normalizedCO2emission.

    turbine excesses the rate of the increased generated heat inthe combustion chamber. This increase is because of the factthat, with increasing gas turbine inlet temperature, the rate ofnetwork increase of gas turbine excesses the rate of increase inthe amount of heat generated in the combustion chamber. Inaddition, according to Figure 6, the carbon dioxide emissionsper unit of output power are reduced.

    5.3. Effect of Varying Gas Turbine Isentropic Efficiency. Theisentropic efficiency of the gas turbine is among the importantparameters of the design and is indicative of how far the gasturbine performance is from a reversible process. As shown inFigure 7, by increasing the isentropic efficiency of gas turbine,the exergy efficiency of the cycle increases and its exergy lossis reduced.

    5.4. Effect of Varying Absorption Generator Temperature. Thetemperature of the generator in the double-effect absorptionchiller is indeed similar to the temperature of the saturatedvapor exhausted from the recovery boilers and is related tothe recovery boiler pressure. Boiler steam pressure recovery

    1000 1100 1200 1300 1400 15000.24

    0.26

    0.28

    0.3

    0.32

    0.36

    0.4

    0.44

    GTIT (K)

    Exer

    gy effi

    cien

    cy

    Exergy efficiency

    Nor

    mal

    ized

    CO

    2em

    issio

    n (k

    g/kw

    h)

    Normalized CO2 emission

    Figure 6: Variation with gas turbine inlet temperature of exergy ef-ficiency and normalized CO

    2emission.

    0.8 0.82 0.84 0.86 0.88 0.90.34

    0.36

    0.38

    0.4

    0.42

    10000

    11750

    13500

    15250

    17000Ex

    ergy

    effici

    ency

    Exergy efficiencyExdtot

    𝜂g

    ̇

    Exd t

    ot(k

    W)

    Figure 7: Variation with gas turbine isentropic efficiency of exergyefficiency and total exergy destruction rate.

    is one of the important design parameters. By increasingthe temperature of the exhausting saturated vapors fromthe recovery boilers, the amount of heat from the recoveryboiler is reduced. And the cooling rate of absorption chillerincreases. But the rate increase of absorption chiller coolingis much smaller than the rate of heat recovery boiler. Thus,as it can be seen in Figure 8, the exergy efficiency increaseswith increase of saturated steam temperature, because theexergy related to heat obtained from the recovery boiler andthe exergy of cooling in the absorption chiller increase dueto increase of saturated steam temperature. The coefficientof performance (COP) for the absorption chiller is achievedthrough dividing the cooling obtained from evaporator bythe heat consumed in the generator. Hence, by increasing theabsorption chiller generator temperature, the amount of heatused in the generator reduces and the cooling produced fromthe chiller evaporator increases; as shown in Figure 9, theperformance ratio of chiller improves.

  • International Journal of Chemical Engineering 7

    150 154 158 162 166 1700.383

    0.387

    0.391

    0.395

    12125

    12175

    12225

    12275

    Exer

    gy effi

    cien

    cy

    Exergy efficiencyExdtot

    Tgen (∘C)

    ̇

    Exd t

    ot(k

    W)

    Figure 8: Variation with absorption generator temperature of exer-gy efficiency and total exergy destruction rate.

    150 154 158 162 166 1701.5

    1.55

    1.6

    1.65

    COP

    Tgen (∘C)

    Figure 9: Variation with absorption generator temperature of ab-sorption chiller COP.

    6. Conclusions

    A comprehensive thermodynamic modeling was carriedout for a trigeneration system based on a double-effectabsorption chiller. This study shed light on the importanceof integrated energy system in order to achieve higher exergyefficiency and lower emission compared to single generationenergy systems. Exergy analysis showed that the combustionchamber and the heat recovery boiler have the most exergydestruction compared to other components. This is mainlydue to the large temperature difference for the heat transferin both listed components and the combustion reaction inthe combustion chamber. System performance significantlyis affected by changes in pressure ratio compressor, inlettemperature to gas turbine, and isentropic efficiency ofthe high-temperature generator. According to the figuresobtained from the previous section, the following conclusionscan be listed:

    (i) Exergy efficiency of the CCHP cycle is more thanCHP and gas turbines cycles.

    (ii) Exergy loss in the absorption chiller is less than otherCCHP components.

    (iii) With the increase in compressor pressure ratio, exergyefficiency for the entire CCHP cycle is first increasedand then decreased and emissions of carbon dioxideincrease as well.

    (iv) Exergy efficiency of the CCHP cycle increases withthe increase of gas turbine isentropic efficiency.

    (v) CCHP cycle produces less carbon dioxide per unitoutput power compared to CHP and gas turbinecycles.

    (vi) Exergy efficiency of the CCHP, CHP, and gas turbinecycles increases with the increasing of the gas turbineinlet temperature.

    (vii) Exergy loss of the CCHP cycle decreases with increas-ing the high-temperature absorption chiller tempera-ture, but its exergy efficiency increases in this process.

    Nomenclature

    Cp: Specific heat at constant pressure (kJ/kg K)ex: Specific exergy flow (kJ/kg)̇Ex: Exergy flow rate (kW)̇Ex𝐷: Exergy destruction rate (kW)

    ℎ: Specific enthalpy (kJ/kg)LHV: Lower heating value (kJ/kg)�̇�: Mass flow rate (kg/s)𝑃: Pressure (bar)Δ𝑃: Pressure drop (bar)�̇�: Heat rate (kW)𝑅: Gas constant (kJ/kg K)𝑠: Specific entropy (kJ/kg K)𝑇: Temperature (K)�̇�: Work rate (kW)AP: Approach pointCHP: Combined heat and powerHTC: High temperature condenserHTG: High temperature generatorSHE: Solution heat exchangerLTC: Low temperature condenserLTG: Low temperature generatorABS: AbsorberECO: EconomizerEVP: EvaporatorHRSG: Heat recovery steam generatorPP: Pinch point.

    Greek Symbols

    𝛾: Specific heat ratio.

    Subscripts

    𝐶: CompressorCC: Combustion chamber𝐷: Destruction

  • 8 International Journal of Chemical Engineering

    ex: Exergy𝑓: Fuel𝑔: Combustion gasesGT: Gas turbine𝑖: Inlet condition.

    Superscript

    ch: Chemical rate.

    Competing Interests

    The author declares that there are no competing interests.

    References

    [1] F. A. Al-Sulaiman, I. Dincer, and F. Hamdullahpur, “Exergyanalysis of an integrated solid oxide fuel cell and organicRankine cycle for cooling, heating and power production,”Journal of Power Sources, vol. 195, no. 8, pp. 2346–2354, 2010.

    [2] V. Havelský, “Energetic efficiency of cogeneration systems forcombined heat, cold and power production,” InternationalJournal of Refrigeration, vol. 22, no. 6, pp. 479–485, 1999.

    [3] V. Athanasovici, O. Le Corre, G. Brecq, and M. Tazerout,“Thermoeconomic analysis method for cogeneration plants,” inProceedings of ECOS Netherlands, pp. 157–164, 2000.

    [4] E. Minciuc, O. Le Corre, V. Athanasovici, M. Tazerout, and I.Bitir, “Thermodynamic analysis of tri-generation with absorp-tion chillingmachine,”AppliedThermal Engineering, vol. 23, no.11, pp. 1391–1405, 2003.

    [5] P. K. Sahoo, “Exergoeconomic analysis and optimizationof a cogeneration system using evolutionary programming,”Applied Thermal Engineering, vol. 28, no. 13, pp. 1580–1588,2008.

    [6] A. Huicochea, W. Rivera, G. Gutiérrez-Urueta, J. C. Bruno, andA.Coronas, “Thermodynamic analysis of a trigeneration systemconsisting of a micro gas turbine and a double effect absorptionchiller,” Applied Thermal Engineering, vol. 31, no. 16, pp. 3347–3353, 2011.

    [7] P. Ahmadi, M. A. Rosen, and I. Dincer, “Greenhouse gasemission and exergo-environmental analyses of a trigenerationenergy system,” International Journal of Greenhouse Gas Con-trol, vol. 5, no. 6, pp. 1540–1549, 2011.

    [8] F. A. Al-Sulaiman, I. Dincer, and F. Hamdullahpur, “Energyanalysis of a trigeneration plant based on solid oxide fuel celland organic Rankine cycle,” International Journal of HydrogenEnergy, vol. 35, no. 10, pp. 5104–5113, 2010.

    [9] Z. Amrollahi, I. S. Ertesvåg, and O. Bolland, “Thermodynamicanalysis on post-combustion CO

    2capture of natural-gas-fired

    power plant,” International Journal of Greenhouse Gas Control,vol. 5, no. 3, pp. 422–426, 2011.

    [10] B. Rezaie andM.A. Rosen, “District heating and cooling: reviewof technology andpotential enhancements,”Applied Energy, vol.93, pp. 2–10, 2012.

    [11] H.Kurt, Z. Recebli, andE.Gedik, “Performance analysis of opencycle gas turbines,” International Journal of Energy Research, vol.33, no. 3, pp. 285–294, 2009.

    [12] I. Dincer and M. A. Rosen, “Energy, environment and sustain-able development,”Applied Energy, vol. 64, no. 1–4, pp. 427–440,1999.

    [13] P. Ahmadi and I. Dincer, “Exergoenvironmental analysis andoptimization of a cogeneration plant system using MultimodalGenetic Algorithm (MGA),” Energy, vol. 35, no. 12, pp. 5161–5172, 2010.

    [14] A. Mousafarash and P. Ahmadi, “Exergy and exergo-economicbased analysis of a gas turbine power generation system,” inProgress in Exergy, Energy and the Environment, chapter 7,Springer, 2014.

    [15] A. Bejan, G. Tsatsaronis, and M. Moran, Thermal Design andOptimization, John Wiley & Sons, New York, NY, USA, 1996.

  • Research ArticleExergy and Environmental Impact Assessment betweenSolar Powered Gas Turbine and Conventional Gas TurbinePower Plant

    Ali Rajaei,1 Hasan Barzegar Avval,2 and Elmira Eslami1

    1Power and Water University of Technology, Tehran, Iran2Energy Optimization Research and Development Group (EORDG), Tehran, Iran

    Correspondence should be addressed to Ali Rajaei; [email protected]

    Received 17 December 2015; Revised 12 April 2016; Accepted 14 April 2016

    Academic Editor: Halil S. Hamut

    Copyright © 2016 Ali Rajaei et al.This is an open access article distributed under theCreativeCommonsAttribution License, whichpermits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

    Recuperator is a heat exchanger that is used in gas turbine power plants to recover energy from outlet hot gases to heat up the airentering the combustion chamber. Similarly, the combustion chamber inlet air can be heated up to temperatures up to 1000 (∘C)by solar power tower (SPT) as a renewable and environmentally benign energy source. In this study, comprehensive comparisonbetween these two systems in terms of energy, exergy, and environmental impacts is carried out. Thermodynamic simulation ofboth cycles is conducted using a developed program in MATLAB environment. Exergetic performances of both cycles and theiremissions are compared and parametric study is carried out. A new parameter (renewable factor) is proposed to evaluate resourcesquality andmeasure how green an exergy loss or destruction or a system as awhole is. Nonrenewable exergy destruction and loss arereduced compared to GT with recuperator cycle by 34.89% and 47.41%, respectively. Reductions in CO

    2

    , NO𝑥

    , and CO comparedto GT with recuperator cycle by 49.92%, 66.14%, and 39.77%, respectively, are in line with renewable factor value of around 55.7which proves the ability of the proposed green measure to evaluate and compare the cycles performances.

    1. Introduction

    Recuperation as one of the conventional optimizationenhancements in gas turbine cycles by preheating inlet airentering combustor which decreases fuel consumption ratedramatically leads to less greenhouse gas emissions.Theotherway refers to hybridizing gas cycle with solar power. Advan-tages of combining solar thermal power with power gen-eration systems are reviewed by Jamel et al. [1]. Renewablesources integrationwith power cycles with the aim of increas-ing total exergy efficiency based on different scenarios isperformed by them.

    Several studies are conducted on energy and exergyanalysis of hybrid solar gas cycles [2]. Solar power toweras a central receiver system recently has been built in bothdemonstrational and commercial projects all over the world[3]. Schwarzbözl et al. [4] using advanced software tools car-ried out design optimization and performance prediction of

    the solar tower gas turbine power plants.Their project provedfeasibility of solar tower integration with conventional gasturbine power plant. It is proved that hybrid solar gas turbinecycles are more efficient in terms of CO

    2emission prevention

    compared to conventional gas cycle with recuperator.Comparing energy systems often is performed through

    measuring environmental characteristics and performancein terms of energy and exergy analysis [2]. Thermodynamicmodeling, second-law based thermodynamic analysis, andmultiobjective optimization of a gas turbine power plant withand without recuperator are conducted [5, 6].

    In this paper, two scenarios are defined based on differentheat sources to preheat the air inlet to combustor. First isa conventional gas turbine cycle with recuperator and thesecond is a solar power tower coupled with a gas turbinewhere central receiver plays the same role as the recuperator.In order to find inefficiencies in both cycles, exergy analysis isperformed by simulating the cycles usingMATLABprogram.

    Hindawi Publishing CorporationInternational Journal of Chemical EngineeringVolume 2016, Article ID 8323859, 8 pageshttp://dx.doi.org/10.1155/2016/8323859

    http://dx.doi.org/10.1155/2016/8323859

  • 2 International Journal of Chemical Engineering

    Exergoenvironmental analysis tool by predicting emis-sions rate helps designing a more sustainable cycle. Environ-mental impacts including CO

    2, NO𝑥, and CO are measured

    through the developed code. SO𝑥which is prevented by pre-

    operations in all gas cycles is considered negligible in model-ing.

    This analysis is aimed at quantitatively addressing theimpact of renewable and nonrenewable sources on environ-ment by introducing renewable factor. In research studies tothe authors’ knowledge, all sources are considered the same.Losses and destructions from various sources are equivalentin common exergy analysis. However, losses and destructionsfrom renewable resources are different from nonrenewableresources since all exergy flows have impacts on environ-ment. In the present work, a new measure is introducedand renewable and nonrenewable loss and destructions arecalculated to show the real effect of using renewable resourcesin environmental impacts reduction.

    The Present study highlights exergy and exergoenviron-mental analysis of both mentioned cycles by measuring theirexergy destructions throughout the cycle and comparingtheir total exergy efficiencies in order to reach a better insight:

    (i) Tomodel a new arrangement of new hybrid gas cycle.(ii) To conduct exergy and exergoenvironmental analysis

    in order to find inefficiencies.(iii) To propose renewable factor which helps in compar-

    ing renewable and nonrenewable sources quantita-tively and more accurately.

    2. System Description and Assumptions

    In this research paper, two scenarios are presented. Thefirst one includes heliostat solar field, central receiver, andpower generation system while the second one comprises arecuperator instead of prime solar system.

    Figure 1(a) demonstrates SPT cycle designed similarlybased on SOLGATE project cycle [4] in which the solarhybrid gas turbine system functions by first concentratingsolar energy from a heliostat field (solar field) to a receivermounted on top of a tower acting as a convective/radiativeheat exchanger. These irradiations are converted into heatabsorbed by the air coming from compressor. Preheated airenters combustor in order to be mixed with the fuel wherethe combustion chamber closes the temperature gap betweenthe receiver outlet temperature (800–1000∘C at design point)and the turbine inlet temperature (950–1300∘C) and providesconstant turbine inlet conditions despite fluctuating solarinput. The solar power tower technology is used with con-centration ratios up to 1000 suns to achieve the high receivertemperatures. More detailed information about the receiverdevelopment and test results with receiver temperatures upto 960∘C can be found in [7].

    Tomodel and compare two cycles, thermodynamicmod-eling of both systems is carried out. Systems are analyzed attheir design point using provided data and average yearlyDNI for solar system. Then exergy analysis and emissioncalculations are carried out and systems’ performances arecompared.

    In the second scenario recuperator is used as a replace-ment of mentioned solar part in first cycle. Several assump-tions are made in order to render the analyses in a traceableway considered tomodel the cycles in the present studywhichare listed below:

    (1) All the processes are assumed to work under steady-state condition.

    (2) Combustion products and air stream are consideredideal gas.

    (3) Natural gas enters combustor as fuel.(4) Dead state is 𝑃

    0= 1.01 bar and 𝑇

    0= 293.15K.

    3. Formulation

    The present study performed exergy and exergoenviron-mental analysis both on each cycle where in the first onesolar receiver, as external source, and in the second onerecuperator, as internal source, are considered.

    3.1. Recuperator. The energy balance equation for recupera-tor which is shown in Figure 1 is as follows:

    �̇�air (ℎ3 − ℎ2) = �̇� (ℎ5 − ℎ6) 𝜂recup. (1)

    Recuperator efficiency is usually 95–97% and in many casesis considered 100%. Here 97% percent is assumed based onan average value in similar GT cycles [5]:

    𝑃3

    𝑃2

    = (1 − Δ𝑃recup) , (2)

    where pressure drop through the recuperator is considered3% of the inlet pressure for both flow streams and throughthe combustion chamber is 3% of the inlet pressure [5].

    3.2. Solar System. As shown in Figure 1, central receiver hastwo input streams, solar irradiations and compressed airwhich gets warmer by absorbing the heat coming from solarrays. In this analysis �̇� is the transferred heat rate as

    �̇� =𝐻out − 𝐻in𝜂rec, (3)

    where𝐻out and𝐻in are outlet and inlet stream enthalpy:

    �̇�rec = �̇�∗�̇�air,

    Solar share =�̇�rec

    �̇�𝐹∗ LHV + �̇�rec

    .

    (4)

    Solar share shows renewable heat source contribution intoconventional fossil fuel cycles and is defined as below:

    Solar share =�̇�rec

    �̇�natural gas + �̇�rec∗ 100, (5)

    where Q̇natural gas is the supplied heat by fuel:

    �̇�natural gas = ̇𝑚𝐹LHV. (6)

  • International Journal of Chemical Engineering 3

    Compressor Gas turbine

    Combustor

    1

    2

    3

    5

    6

    Central receiver4 Fuel

    Heliostat field Power tower

    (a)

    Compressor Gas turbine

    Combustor

    1

    2

    4

    Fuel

    5

    G

    Recuperator

    Stack

    3

    6

    7

    (b)

    Figure 1: Schematic diagram of (a) GT-solar cycle and (b) GT-recuperator cycle.

    And Q̇rec is the heat released from irradiations into centralreceiver:

    �̇�rec = 𝜂field𝜂rec�̇�sol,total. (7)

    One can write

    �̇�sol,total = 𝐴 ∗ DNI. (8)

    DNI is defined as direct normal irradiance which variesrelated to the geographical situation and a constant annualaverage value for a certain location is assumed.

    3.3. Exergy Analysis. Exergy analysis is a powerful tool inreferring exergy destructions in a power cycle while thesewastes cannot be seen through energy analysis [8].

    It is worth mentioning that four concepts are demon-strated in the present study. ExF and ExP are the fuel andproduct exergy rate, respectively, and also the exergy loss(ExL) is defined as the useful exergy which is wasted to theenvironment with no converting to the work and exergydestruction (ExD) due to irreversibilities.

    To find the appropriate relation between these concepts,one may write

    ExF = ExP + ExD. (9)

    This should be written for all components as shown schemat-ically in Table 1 to calculate the exergy balance in each ofthem.Considering if the component is assumed adiabatic, theexergy loss would be zero.

  • 4 International Journal of Chemical Engineering

    Table 1: Components exergy balance.

    Component ExF ExP ExDF

    1 2

    Solar receiver

    Qrec

    Ex1

    +𝑄rec

    𝜂field(1 −𝑇0

    𝑇sun) Ex

    2

    ExD = ExF − ExP − 𝑄(1 −𝑇sun

    𝑇0

    )

    Exloss = 𝑄(1 −𝑇

    𝑇0

    )

    𝜂ex =ExPExF

    1

    2

    W2

    Compressor

    Ex1

    +𝑊2

    Ex2

    ExD = Ex2 − Ex1 −𝑊2𝜂ex =

    Ex2

    Ex1

    +𝑊2

    Q

    Hot line

    Cold line

    Recuperator

    12

    3 4

    Ex1

    − Ex2

    Ex4

    − Ex1

    ExD = ExF − ExP = 𝑄(1 −𝑇

    𝑇0

    )

    𝜂ex =ExPExF

    Combustion chamber

    1 2

    Q

    F ̇mf

    ExF + Ex1 Ex2

    ExD = ExF − ExP − 𝑄(1 −𝑇

    𝑇0

    )

    Exloss = 𝑄(1 −𝑇

    𝑇0

    )

    𝜂ex =ExPExF

    1

    2

    ̇WT

    Gas turbine

    Ex1

    − Ex2

    �̇�𝑇

    ExD = Ex1 + Ex2 − �̇�𝑇𝜂ex =

    �̇�𝑇

    Ex1

    + Ex2

    In this research study, input exergy is supplied from twodifferent sources shown in Figure 1. The solar input exergy isdefined as below:

    Exsol =𝑄rec𝜂field(1 −𝑇0

    𝑇sun) . (10)

    3.4. Exergoenvironmental Analysis. Although many studiesin the literature are conducted based on integration meth-ods between solar power and conventional power plantswhich mainly are focused on energy and exergy analysis,there is no attention to environmental issues. The presentstudy highlights greenhouse gas emissions reduction throughexergoenvironmental analysis which is conducted on bothscenarios. It is considered that CO and NO

    𝑥are pollutant

    emissions in grams per kilogram. The appropriate equationsfor these pollutants are as follows [9]:

    �̇�NO𝑥

    =

    0.15𝐸16𝜏0.5 exp (−71100/𝑇pz)𝑃0.05

    3

    (Δ𝑃3/𝑃3)

    ,

    �̇�CO =0.179𝐸99 exp (7800/𝑇pz)𝑃2

    3

    𝜏 (Δ𝑃3/𝑃3),

    (11)

    where 𝜏 is the residence time in combustion zone (it isassumed constant and is equal to 0.002 s), 𝑇pz is the primaryzone combustion temperature, 𝑃

    3is the combustor inlet

    pressure, and Δ𝑃3/𝑃3is the nondimensional pressure drop in

    the combustion chamber.Accordingly CO

    2is calculated as below [6]:

    𝜀 =

    �̇�CO2

    �̇�net. (12)

    4. Results and Discussion

    4.1. Single GT, GT-Recuperator, and GT-Solar PerformanceComparison. In terms of exergy and environmental impacts,three mentioned cycles are compared. Exergy efficiency andCO2emission for three mentioned cycles are presented in

    Figure 2. Exergy efficiency for the GT-solar is the least andfor the recuperator is the most. It is a clear result of efficiencydefinition and the vast difference between solar input exergyand fuel exergy. Solar exergy due to high temperature valueof its resource is much higher in comparison to fuel exergy.However, solar energy implementation reduces the naturalgas consumption rate dramatically and so the emission forthis cycle is about half the size of the conventional cycles. Due

  • International Journal of Chemical Engineering 5

    EfficiencyGT

    0.3584580461.5939

    GT-REC0.3939

    1.450625

    GT-solar0.2683425720.726554604

    0

    0.2

    0.4

    0.6

    0.8

    1

    1.2

    1.4

    1.6

    1.8

    CO2 emission(kg/s)

    Figure 2: Efficiency-emission for different scenarios.

    7%

    77%

    16%

    CompressorCombustorGas turbine

    Figure 3: Exergy destruction distribution in GT cycle.

    to higher efficiency in recuperator relative to single GT cycle,emission and fuel flow rate are lower. For cycle with singlesources of exergy or energy, efficiency and CO

    2emission are

    often correlated inversely.Exergy flow in these three different cycles shows similar

    behavior. In Figure 3 exergy destruction rates in single GTare shown. As it is presented combustor is the greatest exergydestructor by 77 percent of overall destruction rate. Similarlyin GT-recuperator cycle, it is also presented the same trend.

    67 percent of overall exergy destruction is related to com-bustor inGT-recuperator. 10 percent reduction in destructionis due to higher temperature inlet to the combustor whichreduced the combustion rate. If we consider the recuperatoras another internal source of exergy, the overall destructionrate in cycle resources is 71 percent in GT-recuperator cyclewhich is shown in Figure 4.

    GT-solar has shown a similar trend by 71 percent ofexergy destruction in solar part (from sun to air flow) and 23percent in combustor. In fact 94 percent of exergy destruction

    CompressorCombustor

    Gas turbineRecuperator

    8%

    67%

    21%4%

    Figure 4: Exergy destruction distribution in GT-recuperator cycle.

    CompressorCombustor

    Gas turbineSolar receiver

    4%

    23%

    2%

    71%

    Figure 5: Total exergy destruction distribution in GT-solar cycle.

    is related to exergy or energy resources conversion partswhich has the highest value among other cycles. Figure 5shows destruction distribution in GT-solar cycle.

    Energy resources destruction percentages of total in threecycles are presented and compared in Figure 6 and show thesame trend as exergy efficiency. So onemay conclude that thecycle with the less exergy destruction in energy resources isthe most efficient cycle.

    4.2. Renewable Resources versus Nonrenewable Resources. Interms of exergy, GT-solar hybrid is the worst cycle. Exergydefinition by itself does not provide an insight into theresources types.

    The earth receives solar energy daily and continuouslyand it is absorbed, transformed, rejected, and stored invarious types of energy or phenomena. On the other hand,fossil fuels are not energy resources on the plant except forhuman being. In fact what we are using as fossil fuels are outof the earth, usually ecology, and are the only human beingimpact or footprint on the environment. So any destruction

  • 6 International Journal of Chemical Engineering

    7871

    94

    GT GT-REC GT-solar

    Figure 6: Contribution of exergy destruction in resource conver-sion components in different cycles.

    or losses due to fossil fuels can be considered as pollution orimpacts on environment.

    Here, to give our resources a meaning in destruction,we define renewable and nonrenewable exergy destructionand losses. Exergy losses are important due to the factthat streams with exergy can potentially cause changes inenvironment because of their exergy. Both single GT andGT-recuperator cycles are purely nonrenewable. However, in GT-solar cycle sources are different. To calculate the renewableand nonrenewable exergy destruction and losses rates in GT-solar cycle, we use the following method.

    Exergy comes from two different sources, sun and naturalgas. We define resource distribution factor as follows:

    𝑓renewable =(ΔExair)rec

    (ΔExair)rec + (ΔExflue gas)comb. (13)

    Then we assume that exergy of working fluid is the algebraiccombination of various resources. Now we can provide thefollowing equations for exergy destruction and losses:

    (ExL)non-renwable = (1 − 𝑓renewable) (ExL)total ,

    (Exdi)non-renwable = (1 − 𝑓renewablei) (Exdi)total .(14)

    Furthermore, exergy destruction in solar system is con-sidered purely renewable and destruction in combustor isconsidered purely nonrenewable. Implementing equationsand definitions presented above, nonrenewable destructiondistribution is presented in Figure 7.

    Figure 8 shows the value of nonrenewable destructionand losses in different cycles. Implementing nonrenewablelosses and destructions, the main advantage of the GT-solarcycle is quantitatively measured. Nonrenewable losses whichare impacts of human beings activities on environment havetheir least value in GT-solar cycle.

    GT-solar cycle parameters are summarized in Table 2.In this table, parameters like solar share, exergy inputs,

    8%14%

    78%

    CompressorCombustorGas turbine

    Figure 7: Nonrenewable exergy destruction distribution in GT-solar cycle (kW).

    0

    2000

    4000

    6000

    8000

    10000

    12000

    GT GT-REC GT-solar

    Nonrenewable exergy destruction (kW)Nonrenewable exergy loss (kW)

    Figure 8: Nonrenewable exergy destruction and losses in differentcycles.

    efficiency, and destruction of different components are pre-sented. Data are assumed based on project SOLGATE [4].

    In addition tomentioned analysis, NO𝑥and CO emission

    are predicted for different cycles. Results are tabulated inTable 3. Due to lowest fuel flow rate in GT-solar cycle,emissions are lowest values. NO

    𝑥in GT-recuperator is higher

    thanGT cycle because of higher combustor inlet temperature.CO emission shows an opposite trend.

    5. Conclusions

    Different cycles are presented and compared according toexergy and environmental analyzing tools. Although GT-solar cycle is the worst according to exergy analysis, its mainadvantages over other conventional cycles is highlightedwhen resource valued exergy analysis is used.

    In addition, the above analysis shows that resourceconversion processes are the most destructive ones in thecycle. Furthermore, the cycle exergy efficiency is directlycorrelated to resource destruction contribution in the cycle.

  • International Journal of Chemical Engineering 7

    Table 2: Performance parameters of GT-solar cycle.

    Parameter ValuePressure ratio 14TIT (∘C) 1080𝜂comp (%) 0.835𝜂GT (%) 0.93Combustor inlet temperature (∘C) 800Receiver efficiency (%) 0.94Field efficiency (%) 0.55Receiver pressure drop 0.03𝜂recup (%) 0.97

    Exergy efficienciesCompressor (%) 0.93Combustor (%) 0.86Gas turbine (%) 0.97Receiver (%) 0.41

    Exergy destruction ratesCompressor (kW) 908.53Combustor (kW) 4973.28Gas turbine (kW) 504.89Receiver (kW) 15374.38

    Overall cycle parametersSolar share (%) 0.56𝑓renewable .557Total exergy loss (kW) 7310Total exergy efficiency (%) 0.268Total exergy destruction (kW) 21761.09Solar input exergy (kW) 26200Fuel flow rate (kg/s) 0.264Air flow rate (kg/s) 33.63Predicted NO

    𝑥

    emission (kg/s) 1.27𝐸 − 10Predicted CO emission (kg/s) 0.0108

    Table 3: NO𝑥

    and CO emissions.

    NO𝑥

    (kg/s) CO (kg/s)GT 3.5478𝐸 − 10 0.02GT-REC 3.7395𝐸 − 10 0.0179GT-SOL 1.2663𝐸 − 10 0.0108

    Total exergy destruction in GT-solar cycle is higherthan other cycles. However, nonrenewable destruction is thelowest for GT-solar among different scenarios. As nonre-newable destructions and losses have significant impacts onthe environment, the best advantage of renewable resourcesand hybrid GT-solar cycle is minimizing the impacts on theenvironment. NO

    𝑥, CO, and CO

    2emissions are also reduced

    significantly by using solar hybrid cycle.

    Nomenclature

    𝐴: Area, m2DNI: Direct normal irradiance, W/m2ex: Specific exergy, kJ/kg

    Ex: Exergy, kJExd: Exergy destruction, kJ𝑓: Resource distribution factorGT-REC: Gas turbine cycle with recuperatorGT-SOL: Gas turbine cycle with solar receiverℎ: Specific enthalpy, kJ/kgLHV: Lower heating value, kJ/kg�̇�: Mass flow rate, kg/h𝑃: Pressure, bar�̇�: Heat transfer, kJ/kg𝑠: Specific entropy, kJ/kgKTIT: Turbine inlet temperature, ∘C𝑇: Temperature, ∘C.

    Greek Letters

    𝜀: CO2emission per net output power, kgCO

    2

    /MWh𝜂: Efficiency𝜂field: Heliostat field efficiency𝜂rec: Receiver efficiency.

    Subscripts

    0: Dead statecomb: Combustorcomp: CompressorD: DestructionF: FuelGT: Gas turbinei: Indexin: InletL: Lossout: OutletP: Productrec: Receiverrecup: Recuperatorsol: Solar.

    Competing Interests

    The authors declare that they have no competing interests.

    References

    [1] M. S. Jamel, A. Abd Rahman, andA.H. Shamsuddin, “Advancesin the integration of solar thermal energywith conventional andnon-conventional power plants,” Renewable and SustainableEnergy Reviews, vol. 20, pp. 71–81, 2013.

    [2] C. Xu, Z. Wang, X. Li, and F. Sun, “Energy and exergy analysisof solar power tower plants,” Applied Thermal Engineering, vol.31, no. 17-18, pp. 3904–3913, 2011.

    [3] O. Behar, A. Khellaf, and K. Mohammedi, “A review of studieson central receiver solar thermal power plants,” Renewable andSustainable Energy Reviews, vol. 23, pp. 12–39, 2013.

    [4] P. Schwarzbözl, R. Buck, C. Sugarmen et al., “Solar gas turbinesystems: design, cost and perspectives,” Solar Energy, vol. 80, no.10, pp. 1231–1240, 2006.

    [5] P. Ahmadi and I. Dincer, “Thermodynamic and exergoenvi-ronmental analyses, and multi-objective optimization of a gas

  • 8 International Journal of Chemical Engineering

    turbine power plant,” Applied Thermal Engineering, vol. 31, no.14-15, pp. 2529–2540, 2011.

    [6] P. Ahmadi, H. Barzegar Avval, A. R. Ghaffarizadeh, and M. H.Saidi, “Thermo-economic-environmental multiobjective opti-mization of a gas turbine power plant with preheater using evo-lutionary algorithm,” International Journal of Energy Research,vol. 35, no. 5, pp. 389–403, 2011.

    [7] P. Heller, M. Pfänder, T. Denk et al., “Test and evaluation of asolar powered gas turbine system,” Solar Energy, vol. 80, no. 10,pp. 1225–1230, 2006.

    [8] I. Dincer andM.A. Rosen,Energy, Environment and SustainableDevelopment, Elsevier, Amsterdam, The Netherlands, 2007.

    [9] N. K. Rizk and H. C. Mongia, “Semianalytical correlations forNOx, CO, and UHC emissions,” Journal of Engineering for GasTurbines and Power, vol. 115, no. 3, pp. 612–619, 1993.

  • Research ArticlePerformance Assessment of a Hybrid Solar-Geothermal AirConditioning System for Residential Application: Energy,Exergy, and Sustainability Analysis

    Yasser Abbasi, Ehsan Baniasadi, and Hossein Ahmadikia

    Department of Mechanical Engineering, Faculty of Engineering, University of Isfahan, Hezar Jerib Avenue,Isfahan 81746-73441, Iran

    Correspondence should be addressed to Ehsan Baniasadi; [email protected]

    Received 4 December 2015; Revised 7 January 2016; Accepted 12 January 2016

    Academic Editor: Pouria Ahmadi

    Copyright © 2016 Yasser Abbasi et al. This is an open access article distributed under the Creative Commons Attribution License,which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

    This paper investigates the performance of a ground source heat pump that is coupled with a photovoltaic system to provide coolingand heating demands of a zero-energy residential building. Exergy and sustainability analyses have been conducted to evaluate theexergy destruction rate and SI of different compartments of the hybrid system. The effects of monthly thermal load variationson the performance of the hybrid system are investigated. The hybrid system consists of a vertical ground source heat exchanger,rooftop photovoltaic panels, and a heat pump cycle. Exergetic efficiency of the solar-geothermal heat pump system does not exceed10 percent, and most exergy destruction takes place in photovoltaic panel, condenser, and evaporator. Although SI of PV systemremains constant during a year, SI of GSHP varies depending on cooling and heating mode. The results also show that utilizationof this hybrid system can reduce CO

    2emissions by almost 70 tons per year.

    1. Introduction

    Theenergy consumption for residential applications is almostone-third of the world’s primary energy demand, while it israpidly increasing due to population growth and improve-ment in human life standards [1, 2]. Currently most ofthe required energy in this sector is supplied by high-temperature sources to meet low-temperature heating needs.These energy crises besides environmental degradation ofearth, global warming, and depletion of natural resourceshave encouraged researchers to investigate the possibility ofusing environmentally benign energy resources to drive lowexergy systems, that is, solar systems, ground source heatexchangers, and so forth, with working temperatures close toenvironment temperature. Low exergy systems are basicallyair conditioning systems that utilize low grade energy ofsustainable sources to provide heating and cooling effects ata temperature close to room temperature [3].

    As a promising approach in energy conservation, heatpumps can be combined with renewable energy sources toprovide a low exergy cooling and heating system. Among the

    renewables, geothermal, wind, and solar are more adoptableto sustainable buildings. Most of the research and devel-opments in renewable energy based systems for residentialapplication are conducted to provide hot water, heating,cooling, and ventilation by heat pumps or vapor-powercycles [4–6]. Ground source heat pumps (GSHP), integratedwith certain types of low-temperature distribution system,have been identified as the most efficient and ecofriendlyheating and cooling technology for various climates. Thesesystems are energy efficient and they are designed basedon the relatively constant temperature of the ground tosupply heating during the winter and cooling during thesummer. Vertical closed-loop systems are the most efficient,though themost expensive, configuration because the subsoillevel of temperature increases and stabilizes with depth[7–9]. Analyses of GSHP have been widely conducted inliterature from energetic and exergetic points of view [10–13].Integration of ground source heat pumps with photovoltaicsystem is a promising option to supply electricity, hot water,and heating and cooling effects for off-network communitiesand remote areas [14–16].

    Hindawi Publishing CorporationInternational Journal of Chemical EngineeringVolume 2016, Article ID 5710560, 13 pageshttp://dx.doi.org/10.1155/2016/5710560

    http://dx.doi.org/10.1155/2016/5710560

  • 2 International Journal of Chemical Engineering

    Combination of different renewable energy sources tomeet the demands of a sustainable building is widely studied.Li et al. [17] described a rooftop hybrid heat pump systemthat uses wind and solar energy to provide hot water, heating,and cooling from energy, exergy, and environmental pointof view. Mikati et al. overviewed a small-scale distributedpower system that contains photovoltaic arrays, small-scalewind turbines, and an electric grid connection [18]. Dai etal. conducted an experimental study to evaluate the effectof operation modes on the heating performance of a solarassisted ground source heat pump system (SAGSHPS) [19].Moreover, different concepts of solar assisted heat pumpsystems with ground heat exchanger are simulated accordingto IEA SHC Task44/HPP Annex38 reference conditionsusing TRNSYS software.The dependency of system efficiencyon seasonal performance factor and possible shortening ofthe ground heat exchanger by minimum temperature atthe ground heat exchanger inlet are evaluated [20]. Theperformance of a new system for cooling of solar PV panelscalled Ground-Coupled Central Panel Cooling System (GC-CPCS), which is in operation at the Energy Park of RajivGandhi Proudyogiki Vishwavidyalaya (RGPV), is studiedby Sahay et al. [21]. Exergy analysis of photovoltaic systemhas been conducted broadly. Sobhnamayan et al. [22] haveinvestigated an optimized solar photovoltaic thermal (PV/T)water collector based on exergy concept. Exergy analyses ofphotovoltaic (PV) and photovoltaic/thermal (PV/T) systemswere presented by Saloux et al. [23]. Gholampour et al.[24] have evaluated the performance of the PV/UTC andUTC systems by introducing energy efficiency as a functionof electrical-to-thermal ratio number and also the secondlaw efficiency. Exergy and economic evaluation of thermalphotovoltaic (PV/T) water based collectors for differentclimates in Iran have been conducted by Jahromi et al. [25].

    In this study an exergy analysis is conducted to investigatethe performance of an integrated PV-GSHP system forspace heating and cooling of a remote building. A generalarrangement schematic view of the system is illustrated inFigure 1. The required area of SPV panels and GSHP neededlength are calculated for the hybrid air conditioning systemof a 200m2 building in a remote area. The effect of differentclimates on system performance is investigated based on themeteorological data of three cities of Iran (Isfahan, Yazd,and Shahrekord). It is assumed that the building structureis identical for all climate case studies; however the coolingand heating loads, solar irradiation, and ground depth tem-perature are different. The analysis is based on the monthlyaveraged energy demands of the building. It is assumed thatheat and electricity can be stored during daytime. An energy,exergy, and sustainability analysis is conducted to evaluate thefeasibility of utilizing solar assisted ground source heat pump(GSHP) for air conditioning purposes.

    2. System Analysis

    2.1. Heating and Cooling Load. A remote building with200m2 area located in Isfahan (elevation: 1590m) is consid-ered to study the performance of an integrated geothermalheat pump and photovoltaic system that provides heating and

    Battery groups

    Solar irradiation Photovoltaic pa

    nel

    N

    (electricity storage)Heat pump

    unit

    Gro

    und

    sour

    ce h

    eat e

    xcha

    nger

    Figure 1: Schematic viewof the solar assistedGSHPair conditioningsystem.

    cooling loads. The system performances are compared fordifferent cities of Iran including Yazd (elevation: 1216m) andShahrekord (elevation: 2061m). Figure 1 shows a schematicview of the residential building and the solar assisted geother-mal heat pump.The heating, cooling, and hot water demandsof the building are calculated based on outdoor designconditions of each city on an hourly basis.

    2.2. System Description. Figure 3 shows a flow diagram of theintegrated solar assisted GSHP system that operates as an off-grid energy system for the specified residential building. Itconsists of three main loops.

    (1) The ground loop delivers heat energy (in coolingmode) to ground sublayers or takes heat energy (inheating mode) from the ground. A circulating pumpcirculateswater, as aworking fluid, in the loop (stream1). Heat is exchanged with the ground via a networkof 𝑛 number of GSHXs with overall efficiency of 𝜂

    𝑔,𝑥.

    The ground temperature 𝑇𝑔is almost constant during

    a year.(2) The primary loop is basically a Rankin refriger-

    ation cycle that consists of two heat exchangerswith exchangeable functions depending on coolingor heating season. In heating mode the first heatexchanger takes heat from the ground loop as anevaporator, while the other heat exchanger deliversheat to the secondary loop as a condenser. In coolingmode the first heat exchanger delivers heat to theground loop as a condenser and the other extractsheat from the secondary loop as an evaporator.A compressor pressurizes refrigerant R-134a in theprimary loop. A 4-way valve is adopted to switch

  • International Journal of Chemical Engineering 3

    cooling and heating mode functions by reversing therefrigerant flow direction.

    (3) The secondary loop exchanges heat via a fan-coilheat exchanger with the air conditioned space. Apump is used to circulate water through the loop.The photovoltaic system supplies the required electricpower of pumps, compressor, and the fan-coil. Thissystem includes PV panels, convertor, and batteries.The batteries store the generated electricity by the PVsystem during daytime.

    3. Energy and Exergy Analyses

    The following assumptions are considered for calculatingenergy and exergy of the streams:

    (a) All of the processes are steady.

    (b) Potential and kinetic energy of the streams are negli-gible and no chemical reactions exist.

    (c) The compressor mechanical and electrical efficienciesare 80% and 70%, respectively.

    (d) Air is an ideal gas and its specific heat is constant.

    (e) The dead state conditions are selected as 𝑇0= 10∘C

    and 𝑃0= 101.325 kPa.

    (f) The thermodynamic properties of water, air, and R-134a are calculated using the EES software package.

    (g) The mass flow rate calculations are made by EESsoftware.

    The case studies are also performed based on the assumptionsin Table 1.

    3.1. Ground Source Heat Pump. Based on the aforementionedassumptions, mass, energy, and exergy balance equationsare applied to find the output power, heat gain, rate ofexergy destruction, and energy and exergy efficiencies. Thegoverning equations are as follows [26, 27]:

    𝑑

    𝑑𝑡(𝑀CV) = ∑

    in�̇� −∑

    out�̇�,

    𝑑

    𝑑𝑡(𝐸CV) = �̇� + �̇� +∑

    in�̇�ℎ −∑

    out�̇�ℎ,

    𝑑

    𝑑𝑡(ΦCV) = [∑�̇�𝑖 (1 −

    𝑇0

    𝑇𝑖

    )] + [�̇� + 𝑃0

    𝑑

    𝑑𝑡(∀CV)]

    +∑in�̇�𝜓 −∑

    out�̇�𝜓 − �̇�CV,

    (1)

    where exergy of any stream (𝜓) is defined as

    𝜓 = (ℎ − ℎ0) − 𝑇0(𝑠 − 𝑠0) +

    𝑉2

    2+ g𝑧. (2)

    Table 1: Main assumptions for analysis (Isfahan case study, monthof January).

    Parameter ValueGeneral parametersDesign temperature 22.5 (∘C)Dead state temperature 10 (∘C)Ground temperature 17 (∘C)Thermal load 10.1 (kW)Solar irradiance 0.2 (kWm−2)Battery efficiency 70%Power conversion efficiency 18%GSHX parametersWorking fluid WaterInlet temperature 5 (∘C)Outlet temperature 15 (∘C)Soil resistance 230 (kW−1m ∘C)Ground pump efficiency 80%Ground heat exchanger efficiency 80%Heat pump parametersEvaporator pressure 200 (kPa)Condenser pressure 800 (kPa)Refrigerant R-134aCondenser efficiency 80%Evaporator efficiency 80%Compressor efficiency 80%Expansion valve efficiency 80%Room heater parametersWorking fluid WaterInlet temperature 20 (∘C)Outlet temperature 30 (∘C)Fan-coil heat exchanger efficiency 80%Fan-coil pump efficiency 80%

    3.1.1. Heat Transfer Process in Fan-Coil. Therate of exergy thatis delivered to room due to thermal (Φ̇load) is

    Φ̇load = �̇�load (1 −𝑇0

    𝑇𝑑

    ) , (3)

    where �̇�load is the heating or cooling load of the buildingand 𝑇

    𝑑is indoor design temperature of the building. The

    irreversibility rate in the air conditioning heat exchanger is

    �̇�fan-coil = Φ̇load ± �̇� (𝜓in − 𝜓out) . (4)

    3.1.2. Compression Process. In the hybrid cycle, the inputexergy required for compression process, either in pumpsor in compressor, is delivered from the photovoltaic systemwith energy efficiency of 15 percent. By neglecting frictionalheating, the rate of irreversibly for compression process is

    �̇�pump = �̇�pump + �̇� (𝜓in − 𝜓out) . (5)

    The irreversibility due to energy conversion deficiency inelectric motors can be written as

    �̇�electric-motor = �̇�PV (1 − 𝜂𝑝,𝑒) . (6)

  • 4 International Journal of Chemical Engineering

    −5

    0

    5

    10

    15

    20

    25

    30

    35

    40

    45

    50

    Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

    Yazd_T_GYazd_T_EShahrekord_T_G

    Shahrekord_T_EIsfahan_T_GIsfahan_T_E

    Tem

    pera

    ture

    (∘C)

    (a)

    0

    5

    10

    15

    20

    Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec

    Load

    s (kW

    )

    Shahrekord_CoolingYazd_CoolingIsfahan_Cooling

    Shahrekord_HeatingYazd_HeatingIsfahan_Heating

    (b)

    Figure 2: Monthly variations of environment and ground temperature for different cities (a) and corresponding cooling and heating loadscalculated with available software (b).

    3.1.3. Evaporator and Condenser. Exergy balance for thisprocess is given by

    �̇�CV = ∑in�̇�𝜓 −∑

    out�̇�𝜓. (7)

    Thus evaporator or condenser lost exergy is

    �̇�𝑒,𝑐= (�̇�1𝜓1,in + �̇�2𝜓2,in) − (�̇�1𝜓1,out + �̇�2𝜓2,out) . (8)

    3.1.4. Throttling Process. The exergy loss rate �̇�CV in thethrottling valve is

    �̇�tr = �̇� (𝜓in − 𝜓out) . (9)

    3.1.5. Ground Source Heat Exchanger. The exergy rate that isextracted from ground Φ̇geo is

    Φ̇geo = �̇�geo (1 −𝑇0

    𝑇geo) , (10)

    where �̇�geo is the exchanged heat between the ground andthe working fluid in the heat exchanger loop and 𝑇geo is theaverage ground temperature in a specific depth.

    The ground temperature 𝑇geo is a function of severalparameters. It can be calculated using the following equation:

    𝑇geo = 𝑇mean + 𝐴 cos(𝜔 (𝑡 − 𝑡

    0) −

    𝑧

    𝑑) × 𝑒−𝑧/𝑑

    , (11)

    where𝑇mean is annual average temperature (∘C),𝐴 is temper-

    ature wave magnitude (∘C), 𝜔 is temperature wave frequency[2𝜋/(365×24 hours)], 𝑡

    0is time for the warmest day of a year

    (hour), 𝑧 is ground depth (m), and 𝑑 = √2𝛼/𝜔, in which 𝛼 isheat conductivity of soil (m2/hour).

    The pipe length of GSHX is calculated by

    𝐿GSHX =�̇�geo

    𝑇geo − 𝑇𝑊,𝐺

    1

    𝑅tot, (12)

    where 𝑅tot is the total thermal resistance of soil, pipe, andwater and 𝑇

    𝑊,𝐺is the mean temperature of water flowing

    through ground source heat exchanger. Considering physicalproperties of polyethylene pipe, soil, and water the totalthermal resistance is 𝑅tot ≈ 230 kW/m

    ∘C.The exergy destruction rate in the heat transfer process is

    �̇�GSHX = Φ̇geo + �̇� (𝜓in − 𝜓out) . (13)

    3.2. Photovoltaic System. Solar Irradiance is ameasure of howmuch solar power can be delivered at a specific location.Figure 4 illustrates the monthly solar irradiation averagedover 22 years for different cities. Figure 4 provides theinformation on the available solar irradiation in case of usingPV panel with sun tracking, based on [28]. This informationis then used to calculate the average daily power generationfrom the photovoltaic system in each month.

    The actual energy input from solar radiation may bedefined as below [23]:

    �̇�solar = 𝐴𝐼𝑠, (14)

    where 𝐼𝑠is solar irradiance intensity and is 𝐴 photovoltaic

    panel net area.

  • International Journal of Chemical Engineering 5

    1

    2

    3

    (2) Evaporator (cooling mode)

    Condenser (heating mode)

    4

    Compressor

    g1

    g2

    g3

    r1

    r2

    r3r4

    h3

    h2

    h1

    g (ground flow)r (refrigerant flow)h (home flow)

    Ground loop pump

    GSHX

    Expansion valve

    Secondary loop pump

    (1) Evaporator(heating mode) Condenser(cooling mode)

    Fan-coilheat exchanger

    4-wayvalve

    Con

    vert

    or an

    d co

    ntro

    ller

    Solar

    PV pa

    nel

    (1) GSHX water cycle(2) Refrigerant flow cycle(3) Home water cycle(4) Electricity circuit

    Figure 3: Flow diagram of the integrated solar assisted GSHP system.

    The input exergy of solar radiation is given by [29]

    Φ̇in,solar = (1 −4

    3(𝑇0

    𝑇𝑠

    ) +1

    3(𝑇0

    𝑇𝑠

    )

    4

    ) 𝐼𝑠𝐴, (15)

    where 𝑇𝑠is the sun temperature and is taken as 5777K. The

    exergy balance for the PV module can be written to find theassociated irreversibility as follows [30–32]:

    Φ̇in,solar = �̇�PV + �̇�PV. (16)

    It is shown that PV output exergy can be calculated as

    �̇�PV = 𝑉𝑚𝐼𝑚, (17)

    where 𝑉𝑚is PV voltage and 𝐼

    𝑚is generated current.

    The energy conversion efficiency of PV module can bedefined as the ratio of the net electrical output power to theinput energy as below:

    𝜂pce =𝑉𝑚𝐼𝑚

    𝐼𝑠𝐴. (18)

    3.3. Overall System Analysis. The input exergy to the hybridcycle is received from the geothermal source (Φgeo) and pho-tovoltaic system (ΦPV). The desired exergy that is deliveredto the house isΦload. Therefore, the second low efficiency for


Recommended