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175 ISSN 1063-7761, Journal of Experimental and Theoretical Physics, 2017, Vol. 125, No. 2, pp. 175–188. © Pleiades Publishing, Inc., 2017. Original Russian Text © A.A. Zyablovskii, A.A. Pavlov, V.V. Klimov, A.A. Pukhov, A.V. Dorofeenko, A.P. Vinogradov, A.A. Lisyanskii, 2017, published in Zhurnal Eksperimental’noi i Teoreticheskoi Fiziki, 2017, Vol. 152, No. 2, pp. 211–226. Extraordinary Light Transmission Through a Metal Film Perforated by a Subwavelength Hole Array A. A. Zyablovskii a,b, *, A. A. Pavlov a , V. V. Klimov a,d,e , A. A. Pukhov a,b,c , A. V. Dorofeenko a,b,c , A. P. Vinogradov a,b,c , and A. A. Lisyanskii f,g a Dukhov All-Russian Research Institute of Automatics, Moscow, 127055 Russia b Moscow Institute of Physics and Technology (State University), Dolgoprudnyi, Moscow oblast, 141700 Russia c Institute of Theoretical and Applied Electrodynamics, Russian Academy of Sciences, Moscow, 125412 Russia d Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991 Russia e National Research Nuclear University “MEPhI”, Moscow, 115409 Russia f Department of Physics, Queens College of the City University of New York, New York, 11367 USA g The Graduate Сеnter of the City University of New York, New York, 10016 USA *e-mail: [email protected] Received January 21, 2017 Abstract—It is shown that, depending on the incident wave frequency and the system geometry, the extraor- dinary transmission of light through a metal film perforated by an array of subwavelength holes can be described by one of the three mechanisms: the “transparency window” in the metal, excitation of the Fabry– Perot resonance of a collective mode produced by the hybridization of evanescence modes of the holes and surface plasmons, and excitation of a plasmon on the rear boundary of the film. The excitation of a plasmon resonance on the front boundary of the metal film does not make any substantial contribution to the trans- mission coefficient, although introduces a contribution to the reflection coefficient. DOI: 10.1134/S1063776117070123 1. INTRODUCTION In 1998, Ebbesen and coworkers [1, 2] discovered experimentally extraordinary light transmission (ELT) through a metal film perforated by a period array of subwavelength holes. The transmission of light was called extraordinary because the frequency depen- dence of the transmission coefficient normalized to the area of holes was nonmonotonic and exceeded unity at some frequencies. This fact attracted attention to the problem of light transmission through a periodic array of holes in a metal film [3–5], because the non- monotonic wavelength dependence of the transmis- sion coefficient cannot be explained by considering the transmission of light through subwavelength holes in an infinitely thin ideally conducting screen [6–8]. Indeed, according to the Bethe theory [6], the trans- mission coefficient of light through a circular sub- wavelength hole in an infinitely thin ideally conduct- ing screen normalized to the hole area is proportional to (d/λ) 4 , where d is the hole diameter and λ is the light wavelength. Assuming that the transmission coeffi- cient through each hole in the array is independent of the presence of other holes, the total transmission coefficient proves to be smaller than unity and mono- tonically decreases with increasing incident radiation wavelength. In the case of a finite-thickness film, the transmission coefficient is also proportional to (d/λ) 4 exp(–hImq), where k is the film thickness, q is the wavevector of a mode in a hole (see experimental [9, 10] and theoreti- cal [11] works). The maximum of the transmission coefficient is observed only if the size of the hole becomes comparable with the wavelength when the mode of the hole becomes propagating [12–14]. In this case, the transmission maximum is related to the excitation of a Fabry–Perot resonance in a single hole. For a subwavelength hole, only a monotonic decrease in the transmission coefficient is observed with increasing incident radiation wavelength [15]. To explain the ELT through subwavelength holes, different mechanisms were proposed in the literature [16–20]. The nature of this effect was qualitatively dis- cussed in [1], where ELT was explained by excitation of surface plasmons either on the front or rear bound- ary of a metal film. This explanation was based on experimental facts discovered in [1]. First, it was found that the transmission coefficient maxima were not observed for germanium films [1]. Because ger- manium has the positive permittivity in the spectral ATOMS, MOLECULES, OPTICS
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ISSN 1063-7761, Journal of Experimental and Theoretical Physics, 2017, Vol. 125, No. 2, pp. 175–188. © Pleiades Publishing, Inc., 2017.Original Russian Text © A.A. Zyablovskii, A.A. Pavlov, V.V. Klimov, A.A. Pukhov, A.V. Dorofeenko, A.P. Vinogradov, A.A. Lisyanskii, 2017, published in Zhurnal Eksperimental’noii Teoreticheskoi Fiziki, 2017, Vol. 152, No. 2, pp. 211–226.

Extraordinary Light Transmission Througha Metal Film Perforated by a Subwavelength Hole Array

A. A. Zyablovskiia,b,*, A. A. Pavlova, V. V. Klimova,d,e, A. A. Pukhova,b,c,A. V. Dorofeenkoa,b,c, A. P. Vinogradova,b,c, and A. A. Lisyanskiif,g

a Dukhov All-Russian Research Institute of Automatics, Moscow, 127055 Russiab Moscow Institute of Physics and Technology (State University), Dolgoprudnyi, Moscow oblast, 141700 Russiac Institute of Theoretical and Applied Electrodynamics, Russian Academy of Sciences, Moscow, 125412 Russia

d Lebedev Physical Institute, Russian Academy of Sciences, Moscow, 119991 Russiae National Research Nuclear University “MEPhI”, Moscow, 115409 Russia

f Department of Physics, Queens College of the City University of New York, New York, 11367 USAg The Graduate Сеnter of the City University of New York, New York, 10016 USA

*e-mail: [email protected] January 21, 2017

Abstract—It is shown that, depending on the incident wave frequency and the system geometry, the extraor-dinary transmission of light through a metal film perforated by an array of subwavelength holes can bedescribed by one of the three mechanisms: the “transparency window” in the metal, excitation of the Fabry–Perot resonance of a collective mode produced by the hybridization of evanescence modes of the holes andsurface plasmons, and excitation of a plasmon on the rear boundary of the film. The excitation of a plasmonresonance on the front boundary of the metal film does not make any substantial contribution to the trans-mission coefficient, although introduces a contribution to the reflection coefficient.

DOI: 10.1134/S1063776117070123

1. INTRODUCTION

In 1998, Ebbesen and coworkers [1, 2] discoveredexperimentally extraordinary light transmission (ELT)through a metal film perforated by a period array ofsubwavelength holes. The transmission of light wascalled extraordinary because the frequency depen-dence of the transmission coefficient normalized tothe area of holes was nonmonotonic and exceededunity at some frequencies. This fact attracted attentionto the problem of light transmission through a periodicarray of holes in a metal film [3–5], because the non-monotonic wavelength dependence of the transmis-sion coefficient cannot be explained by consideringthe transmission of light through subwavelength holesin an infinitely thin ideally conducting screen [6–8].Indeed, according to the Bethe theory [6], the trans-mission coefficient of light through a circular sub-wavelength hole in an infinitely thin ideally conduct-ing screen normalized to the hole area is proportionalto (d/λ)4, where d is the hole diameter and λ is the lightwavelength. Assuming that the transmission coeffi-cient through each hole in the array is independent ofthe presence of other holes, the total transmissioncoefficient proves to be smaller than unity and mono-

tonically decreases with increasing incident radiationwavelength.

In the case of a finite-thickness film, the transmissioncoefficient is also proportional to (d/λ)4exp(–hImq),where k is the film thickness, q is the wavevector of amode in a hole (see experimental [9, 10] and theoreti-cal [11] works). The maximum of the transmissioncoefficient is observed only if the size of the holebecomes comparable with the wavelength when themode of the hole becomes propagating [12–14]. Inthis case, the transmission maximum is related to theexcitation of a Fabry–Perot resonance in a single hole.For a subwavelength hole, only a monotonic decreasein the transmission coefficient is observed withincreasing incident radiation wavelength [15].

To explain the ELT through subwavelength holes,different mechanisms were proposed in the literature[16–20]. The nature of this effect was qualitatively dis-cussed in [1], where ELT was explained by excitationof surface plasmons either on the front or rear bound-ary of a metal film. This explanation was based onexperimental facts discovered in [1]. First, it wasfound that the transmission coefficient maxima werenot observed for germanium films [1]. Because ger-manium has the positive permittivity in the spectral

ATOMS, MOLECULES, OPTICS

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ZYABLOVSKII et al.

range of measurements,1 a conclusion was made thatplasmon properties of the film material are important.Second, it was shown experimentally that the wave-lengths of the transmission coefficient maxima lin-early depended on the array period. Third, it wasfound that the position of the transmission coefficientmaxima depended on the angle of incidence. As theangle of incidence was changed, the intensity of max-ima changed; maxima could split into two and shift.Thus, while one maximum of the transmission coeffi-cient was observed for normal incidence, the deviationfrom the normal incidence caused the splitting of themaximum into two.

Ebbesen explained all these experimental factsassuming that the transmission coefficient maximaappear due to excitation of surface plasmons. Theexcitation condition for a surface plasmon resonancecan be written in the form

(1)

where ksp(ω) is the wavevector of a surface plasmon, kτis the tangential component of the wavevector of theincident wave, Gx, y = (2π/Lx, y)ex, y is the reciprocalarray vector, ex, y are unit vectors along correspondingaxes, n and m are integers, and kL(n, m) is a vector sat-isfying the Laue condition. By neglecting the materialdispersion, |ksp| is inversely proportional to the inci-dent wavelength, and the wavelengths for which con-dition (1) is fulfilled are linearly scaled with changingthe array period Lx, y .

For normally incident light kτ = 0, the frequenciesfor pairs of numbers (n, m) and (–n, –m) at whichcondition (1) is fulfilled coincide, and degeneracy isobserved. For incidence at angles kτ ≠ 0, we have|kL(n, m)| ≠ |kL(–n, –m)| and this degeneracy is lifted.As a result, when the angle of incidence deviates fromthe normal, the transmission coefficient maximaassociated with excitation of surface plasmons splitinto two.

Although these qualitative considerations suggestthe importance of plasmon excitation, quantitativediscrepancies exceed the experimental error [1].Moreover, how plasmon excitation is related to theELT effect remains unclear.

The possible ELT mechanism providing a quanti-tative agreement in some cases was proposed in [17](see also [20, 21]), where it was shown that the trans-mission coefficient maxima are related to excitation ofthe Fabry–Perot resonance of a collective mode prop-agating simultaneously though all holes. The Fabry–

1 The transmission coefficient was measured in [1] in the spectralrange from 200 nm to 2 μm.

τω = = + +sp( ) ( , ) ,L x yn m n mk k k G G

Perot resonance excitation condition was written inthe form

(2)where r is the coefficient of reflection of the collectivemode from the inner boundary of the film, q is thecomplex wave number of the collective mode in theholes. An unusual feature of this resonance is that theeigenmode in subwavelength holes is not a propagat-ing but an evanescent mode (|exp(2iqh)| ≪ 1). Forcondition (2) to be fulfilled, the reflection coefficientshould be much greater than unity, which is possible inthe case of the incidence of an evanescent wave. It wasshown in [17] that the maximum of the reflectioncoefficient is observed when condition (1) for surfaceplasmon excitation is fulfilled. For this reason, ELTcaused by excitation of Fabry–Perot resonances isobserved at frequencies close to the excitation fre-quency of surface plasmons.

The ELT theory developed in [17] predicts theposition of only a part of transmission coefficientmaxima [1]. To explain other transmission coefficientmaxima, it is necessary to consider additional mecha-nisms.

We show in this paper that, to explain all the casesof ELT through a metal film perforated by a two-dimensional array of subwavelength holes, three dif-ferent mechanisms should be taken into account.First, this is the excitation of a Fabry–Perot resonancein holes [17], second, the excitation of a plasmon res-onance on the rear boundary of the metal film, and,third, the presence of a “transparency window” of themetal [22]. In addition, we show that excitation of aplasmon resonance on the front boundary of the metalfilm makes no contribution to the transmission coeffi-cient, although makes a contribution to the reflectioncoefficient. We show that the transmission coefficientmaxima related to excitation of the Fabry–Perot reso-nance in holes decrease with increasing film thicknessslower than the weakest decaying mode of an isolatedhole.

2. FORMULATION OF THE PROBLEM.THE DESCRIPTION

OF THE SYSTEM UNDER STUDYTo elucidate the ELT mechanisms, consider the

problem of the normal incidence of a plane electro-magnetic wave with frequency ω on a metal film withthickness h perforated by an array of cylindrical holeswith a circular cross section with diameter d. Weassume that the holes are located in the sites of a rect-angular array with boundaries coinciding with axes xand y. The array periods along axes x and y are thesame, Lx = Ly = L (Fig. 1).

The metal film is surrounded from both sides bydielectrics with permittivities ε1 and ε2. The wave isincident from the side of the first dielectric. We denote

=2 exp(2 ) 1,r iqh

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EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 177

the permittivity of the metal film by εM.2 The z-axis isdirected perpendicular to the film surface. We willmake the metal film–first dielectric interface coinci-dent with the z = 0 plane. In this case, the metal film–second dielectric interface will lie in the z = h plane.

3. PROBLEM OF THE TRANSMISSION OF ELECTROMAGNETIC WAVES THROUGH A

FINITE-THICKNESS METAL FILM WITHOUT HOLES

Note that the nonmonotonic frequency depen-dence of the transmission coefficient is observed evenfor light propagating through a continuous metal film.Consider this problem in more detail for an electro-magnetic wave with frequency ω incident normally onthe metal film. The transmission coefficient of thefilm is described by the expression [23]

(3)

Here, rM1 and rM2 are reflection coefficients of metal–first dielectric and metal–second dielectric interfaces;t1M and tM2 are transmission coefficients for metal–first dielectric and second dielectric–metal interfaces;

kzM = is the normal component of the

wavevector in metal; kz1 = and kz2 = arenormal components of the wavevector in the first andsecond dielectrics, k0 = ω/c.

Transmission coefficient (3) has a maximum at theincident light wavelength λ ≈ 500 nm (Fig. 2a). Themaximum appears because at λ ≈ 500 nm, gold has a“transparency window” when the imaginary partImkzM of the normal component of the wave numberhas a minimum (Fig. 3a) resulting in a maximum ofthe exponential in the numerator in (3).

The imaginary part ImkzM = k0Im of the nor-mal component of the wave number is independent ofthe system geometry and is determined exclusively bythe permittivity of gold (Fig. 3b). Drastic changes inthe real and imaginary parts of the gold permittivity at

2 We assume in calculations that the film is made of gold with thepermittivity taken from [22].

ω =−

1 2

1 2

exp( )( ) .

1 exp(2 )M M zM

M M zM

t t ik ht

r r ik h

ε20 Mk

ε20 1k ε2

0 2k

εM

the wavelength λ ≈ 500 nm is explained by the fact thatfor λ < 500 nm the interband transitions in gold beginto play an important role.

In the case of the normal incidence of light on a sil-ver film, the transmission coefficient maximum isobserved at the wavelength λ ≈ 300 nm (Fig. 2b). Itappears by the same reasons (Figs. 3c, 3d).

To consider the ELT problem in a metal film per-forated by a hole array, it is necessary to determine theeigenmodes of this film. Consider an infinite spacefilled with gold and perforated by a periodic array ofinfinitely long circular cylinders. Then, electric andmagnetic fields are periodic with the array period

where n and m are integers and L is the array period.

4. EIGENMODES OF A CIRCULAR CYLINDRICAL HOLE IN A CONTINUOUS

METALWe begin with expressions for the fields of eigen-

modes and eigenwavevectors of a single hole [24, 25],which we will use below. In the case of a single hole,

= + +( , ) ( , ),x y x Ln y LmE E

= + +( , ) ( , ),x y x Ln y LmH H

Fig. 1. Schematic view of a film perforated by holes.

z

zsurf ε1

εM

ε2 T = ?

h

L

d

E0

Fig. 2. Wavelength dependences of the transmission coef-ficient of gold (a) and silver (b) films without holes for nor-mally incident light.

400 500 600 700 800λ, nm

λ, nm

0.01

0.02

0.03

0.04

0.05

0.06

0.07

0.08

200 400 600 8000

0.05

0.10

0.15

0.20

0.25

0.30

T

T

(b)

(a)

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ZYABLOVSKII et al.

the problem is cylindrically symmetric and thereforeelectric and magnetic fields can be conveniently writ-ten in cylindrical coordinates E(r, ϕ, z) and H(r, ϕ, z),where r is the distance from the hole center and ϕ is therotation angle in the xy plane.

The dispersion equation describing modes of a cyl-inder with diameter d with the permittivity ε1 and per-meability μ1 located in a medium with the permittivityεM and permeability μM [24, 25] has the form

(4)

Here, n is a natural number or zero; Jn and Hn are Bes-sel and Hankel functions of order n, respectively; and are their derivatives; d is the diameter of the

⎛ ⎞μ μ−⎜ ⎟⎜ ⎟⎝ ⎠

⎛ ⎞ε ε× −⎜ ⎟⎜ ⎟⎝ ⎠

⎛ ⎞= −⎜ ⎟⎝ ⎠

11

1 1

11

1 1

222

2 2 2 2 20 1

' '( ) ( )( ) ( )

' '( ) ( )( ) ( )

1 1 .

n M nM

M n M n

n M nM

M n M n

z

M

J k d H k dk d J k d k d H k d

J k d H k dk d J k d k d H k d

qn

k k d k d

'nJ

'nH

hole mode; kM = ; k1 = ;and qz is the wavevector of the hole mode.

For the nth eigenmode of the hole, all the compo-nents of electric and magnetic fields are proportionalto the factor

(5)

For any value of n, the infinite countable set of solu-tions of Eq. (4) exists, which can be numerated with anadditional subscript m [24, 25].

The eigenmodes of the hole are separated into TMand TE modes. For n = 0, such a separation is obvious.The solutions of the equation

(6)

are TE modes, while solutions of the equation

(7)

are TM modes. For all other values of n, the rigorousseparation into TE and TM modes is impossible.

ε μ −2 20M M zk q ε μ −2 2

1 1 0 zk q

− ω + + θexp( ).zi t iq z in

μ μ− =0 0 11

0 1 0 1

' '( ) ( ) 0( ) ( )

MM

M M

J k d H k dk d J k d k d H k d

ε ε− =0 0 11

0 1 0 1

' '( ) ( ) 0( ) ( )

MM

M M

J k d H k dk d J k d k d H k d

Fig. 3. Real (solid curves) and imaginary (dashed curves) parts of the normal component of the wavevector in gold (a) and silver(c) as functions of the wavelength. Real (solid curves) and imaginary (dashed curves) parts of the permittivity of gold (b) and silver(d) as functions of the wavelength. kn = 2π/400 nm–1.

400 500 600 700λ, nm

λ, nm

λ, nm

λ, nm

8000

0.5

1.0

1.5

2.0

2.5

0

0.5

1.0

1.5

2.0

2.5

400 500 600 700 800

0

−5

−10

−15

−20

5

4

3

2

1

300 400 500 600 700 8000

1

2

3

0

1

2

3

300 400 500 600 700 800

0

−10

−20

−30

4

2

0

(a) (b)

Rekz/kn Imkz/kn

Rekz/kn Imkz/kn ImεReε

ImεReε

(c)(d)

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EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 179

Consider the case when ε1, μ1 = 1, μM = 1, and εMis the gold permittivity. The wave numbers qz of themode of a hole with diameter d = 150 nm for the wave-length λ = 645 nm and different n are presented inTable 1.

Electric and magnetic fields in modes with n = 0are independent of the angle and, therefore, suchmodes are not excited by a plane electromagnetic wavenormally incident on the hole [26].

The TE mode with n = 1 (TE11) has the smallestimaginary part Imqz part of the wavevector. In addi-tion, as shown in [26], a plane wave normally incidenton a cylindrical waveguide with walls made of an idealconductor excites only one TE11 mode. Therefore, inthe first approximation we can consider only the TE11

mode.3 The wavelength dependence of Imqz for such amode is shown in Fig. 4.

One can see from Fig. 4b that the minimum of Imqzis observed at λ ≈ 500 nm. As in the case of a film with-out holes, this minimum is related to the “transpar-ency window” of gold (Figs. 3b, 3d). As the wave-length decreases from 800 to 500 nm, the modulus ofthe real part of gold permittivity decreases (Fig. 3b),achieving a maximum near 500 nm. The decrease inthe modulus |ReεM| of the real part of permittivity leadsto the increase in the penetration depth of the field inmetal. As a result, the effective size of the holeincreases leading to the decrease in Imqz. At wave-lengths above 500 nm, the real part ReεM of the goldpermittivity almost does not change, while the imagi-nary part ImεM drastically increases (Fig. 3b). Theincrease in the imaginary part of permittivity results inthe increase in losses, thereby increasing Imqz.

Thus, the value of Imqz is determined by two fac-tors. The decrease in the modulus of the real part ofpermittivity results in the decrease in Imkz, while theincrease in the imaginary part of permittivity leads tothe increase in Imkz. For gold at λ > 500 nm, the firstfactor dominates and for λ < 500 nm, the second fac-tor dominates. As a result, at λ ≈ 500 nm, when theinfluence of these two factors becomes the same, theminimum of Imqz appears.

Note that both the minimum of the imaginary partImkz of the normal component of the wavevector ingold and the minimum of the imaginary part Imqz ofthe wavevector in the hole are observed at wavelengths

3 Modes with n ≠ 1 are excited because the modes of a periodicsystem do not coincide with the modes of a single hole. How-ever, when the distance between holes greatly exceeds the skinlayer thickness, this difference can be neglected.

close to the “transparency window” of gold. However,their positions do not exactly coincide (Fig. 5). This isexplained by the fact that Imkz depends only on themetal permittivity, while Imqz is determined fromexpression (4) and depends both on the metal permit-tivity and the permittivity of a material filling the hole,the hole diameter, the mode number, etc.

Light waves incident on a metal film perforated bya periodic array of holes can propagate both throughholes and directly through the metal. Therefore, whenthe intensities of waves propagated through holes andmetal are close, the transmission coefficient has two(or more) maxima at wavelength close to the “trans-parency window” of gold.

Table 1. Wave numbers of TE eigenmodes of a single hole

n = 0 n = 1 n = 2

qnz ≈ (0.05 + 3.3i)kn qnz ≈ (0.023 + 1.4i)kn qnz ≈ (0.0337 + 2.69i)kn

Fig. 4. Wavelength dependences of Reqz (a) and Imqz (b)for the TE11 mode (in units kn = 2π/645 nm–1). The holediameter is 100 nm (solid curves), 125 nm (dotted curves),150 nm (dash-and-dot curves). The hole diameter is100 nm (dashed curves) and the permittivity of the filmmaterial is frequency-independent and equal to the goldpermittivity at λ = 645 nm.

500 600 700 800λ, nm

λ, nm

0

0.2

0.4

0.6

0.8

500 600 700 8000

0.2

0.4

0.6

0.8

1.0

1.2

(a)

(b)

Re qz

Im qz

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Note that the field-mode distribution for a singlehole in a metal film differs from the field distributionin one of the holes for the mode of a hole array shownin Fig. 1. However, we will consider below only a prac-tically important case when the hole diameter d =100–150 nm and L = 400–600 nm. In this case, thefiled tunneling from one hole to the adjacent hole ise8 ≈ 3000 times weaker than the field on the holeitself.4 Therefore, we can assume with good accuracythat modes of a single hole coincide with modes in aperiodic array of holes.

5. LIGHT TRANSMISSION THROUGHA FINITE-THICKNESS METAL FILM

PERFORATED BY A PERIODIC HOLE ARRAY

We showed in Section 3 that the transmission coef-ficient of a metal film without holes for a TM-polar-ized wave has sharp maxima related to “transparencywindows” of metals. Consider now the problem oftransmission of an electromagnetic wave through ametal film perforated by a hole array.

5.1. Where Transmission CoefficientMaxima Come from

For a plane electromagnetic wave normally inci-dent on a metal film perforated by a periodic array ofholes, the waves reflected from and transmittedthrough the film can be expanded into a Fourier seriesin plane waves with wavevectors

(8)

4 The minimal distance between hole boundaries in this case is250 nm, while the skin layer thickness in a gold film is about30 nm.

π π= +2 2 .nm x yn mL L

k e e

Here, ez and ey are unit vectors along the x- and y-axes,n and m are integers. To find the amplitude of suchharmonics, we should determine currents on a speci-fied boundary.5

A plane electromagnetic wave incident on a metalfilm perforated by a periodic hole array excites theeigenmodes of the film. Earlier we calculated theeigenmodes of a single hole in a continuous metal.When the distance between adjacent holes greatlyexceeds the skin-layer thickness, the field from onehole does not virtually penetrate into adjacent holesand the eigenmodes of the periodic hole array can betreated as the combination of eigenmodes of separateholes. In other words, the field distribution EAH(x, y, z)in the eigenmodes of the periodic hole array can berepresented as the sum

(9)

where ESH(x, y, z) is the field distribution in the eigen-mode of a single hole. We took into account in (9) thatthe plane wave is incident normally and, as a result,the phase difference between fields in different holes iszero.

Except modes obtained by combining the eigen-modes of separate holes (9), the eigenmodes of theperiodic hole array also include modes analogous toplane waves in a metal film without holes.

To solve the ELT problem, it is necessary to findthe amplitudes of all these eigenmodes excited by thenormally incident plane wave. To do this, it is neces-sary to use the continuity conditions for tangentialcomponents of electric and magnetic fields.

If the amplitudes of eigenmodes on the frontboundary of a metal film are , then the eigenmodeamplitudes on the rear boundary of the metal film willbe exp(iqNh), where qN is the wavevector of the Nthmode of a hole. Hereafter, the subscript “N” denotessimultaneously toe subscripts (n, m) numerating theeigenmodes of the hole (see Section 4). It was shownin the previous section that the eigenmodes of a holehave different decay increments. When one of themodes decays much slower than all other modes (theTE11 mode in our case), we can assume that the ampli-

tude of this mode is exp(iq1h) and the amplitudes ofall other modes can be neglected. This approximationcannot be applied if the coefficient for some Kthmode will greatly exceed the coefficient . We willshow below that this approximation is valid for oursystem. Here, we recall that in the case of a single hole,

5 In practice, it is sufficient to know only the amplitudes of planewave which are not evanescent.

∞ ∞

=−∞ =−∞

≈ + +∑ ∑

( , , )

( , , ),

AH

SH

n m

x y z

x Ln y Lm z

E

E

(1)Nt

(1)Nt

(1)1t

(1)Kt

(1)1t

Fig. 5. Wavelength dependences of Imkz (solid curve) andImqz (dashed curve) in a hole with diameter 100 nm, kn =2π/645 nm–1.

500 600 700 800λ, nm

0

0.5

1.0

1.5

2.0

2.5

0

0.4

0.8

1.2

Im kz Im qz

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EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 181

a normally incident plane electromagnetic waveexcites only the TE11 mode (see the previous section).In the case of a hole array, because of the break of thecylindrical symmetry, only modes with n ≠ 1 can beexcited, however, their amplitudes will be small for alarge enough distance between holes. This justifies ourapproximation.

A mode with the amplitude exp(iqNh) incidenton the rear boundary of a metal film is partiallyreflected the coefficient and partially penetratesinto the dielectric. The reflected wave will be again asum of all the eigenmodes of the system with ampli-tudes exp(iqNh), where M is the number of thereflected mode. The amplitudes of eigenmodes willdecrease during propagation from the rear boundaryof the metal plane to its front boundary and will beequal to exp(i(qN + qM)h) on the front bound-ary. Assuming that the decay decrement of the TE11mode is the smallest, we can assume again that theamplitudes of all other modes of the front boundaryare zero. The TE11 mode is partially reflected back

from the front boundary with the coefficient andpartially penetrated into the dielectric under over thefilm. By repeating these considerations for thereflected wave, we finally obtain the expression for theamplitude tnm of the wave with the wavevector knmescaping from the film on its rear boundary

(10)

Here, is the amplitude of the Nth mode on thefront boundary of the metal film excited by the inci-dent plane wave with the unit amplitude, is theamplitude of a plane wave with the wavevector knm onthe rear boundary of the metal film excited by the inci-dent N mode with the unit amplitude, and and are reflection coefficients of the N mode from thefront and rear boundaries of the metal film.

It is important to emphasize that we calculatedreflection coefficients and and transmissioncoefficients and taking into account all theeigenmodes of the metal film perforated by the holearray. However, we also assume that the amplitudes ofall eigenmodes except the TE11 mode decrease to zeroduring propagation from one boundary of the metalfilm to the other.

The maxima of transmission coefficient (10) canbe observed in the following cases:

(i) If qN has a local minimum at a certain frequency.In real systems, the minima of qN appear due to thepresence of “the transparency window” in metals (seethe previous section);

(1)Nt

(2)Nr

(1) (2)N NMt r

(1) (2)N NMt r

(1)Nr

=−

(1) (2)

(1) (2)exp( ) .

1 exp(2 )N Nnm N

nmN N N

t t iq htr r iq h

(1)Nt

(2)Nnmt

(1)Nr (2)

Nr

(1)Nr (2)

Nr(1)Nt (2)

Nt

(ii) if coefficients or have maxima in fre-quency;

(iii) if the dominator of expression (10) vanishes,

(11)

This condition can be represented in the form of twoconditions for the amplitude and phase

(12)

(13)

where j is an integer. One can see from the table thatfor the film thickness h = 100 nm, the phase incursionafter the propagation of the n = 1 mode through thehole is hReqN ≈ 0.023 rad. Thus, for the n = 1 mode,

condition (13) is fulfilled when arg( ) ≈ 2πj.6

Such a mode is the “zero” Fabry–Perot resonance,when the zero number of wavelengths fits in the holelength.

To determine frequencies at which the transmis-sion coefficient maxima related to resonances in holesare observed, it is necessary to calculate the coeffi-cients of reflection of the hole mode from the hole–dielectric interface.

5.2. Calculation of the Coefficient

Consider a plane wave with the unit amplitudeincident on an infinite-thickness metal film perforatedby a periodic hole array. To find the coefficient , wewill write the continuity conditions for tangentialcomponents of electric and magnetic fields separatelyfor each Fourier harmonic. It follows from continuityconditions for the tangential component of the mag-netic field that

(14)

where H0(x, y) and Hr(x, y) are tangential componentsof the incident and reflected magnetic fields andHt(x, y) is the tangential component of the magneticfield penetrated into the film. The latter term can beexpanded in the eigenmodes of the system as

(15)

Here, H(N)(x, y) is the field distribution in the Ntheigenmode of the system and are expansion coeffi-cients.

6 Similarly, for modes with n = 0 and n = 2.

(1)Nt (2)

Nt

=(1) (2) exp(2 ) 1.N N Nr r iq h

− = (1) (2)1exp( 2 Im ) ,

| || |N

N N

h qr r

− = π(1) (2)arg( ) 2 Re 2 ,N N Nr r h q j

(1) (2)N Nr r

(1)Nt

(1)Nt

+ =0( , ) ( , ) ( , ),r tH x y H x y H x y

= ∑(1) ( )( , ) ( , ).t NN

N

H x y t H x y

(1)Nt

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By expanding H(N)(x, y), H0(x, y) and Hr(x, y) inFourier series, we pass from Eq. (14) to the equation

(16)

Here, and are Fourier expansion coefficientsfor fields Hr(x, y) and H(N)(x, y). By changing the sum-mation order in the right-hand side of (16) and takinginto account that the equality should be fulfilled forany values of x and y, we obtain the continuity condi-tion separately for each Fourier harmonic,

(17)

Similarly, we can obtain the continuity equation foreach Fourier harmonic of the tangential component ofthe electric field,

(18)

Using Eqs. (17) and (18), we can find the coeffi-cients of expansion in the eigenmodes of the systemfor the field propagated through the metal fieldboundary. To do this, it is necessary to express theFourier harmonics and of the electric field interms of the Fourier harmonics of the magnetic field,which allows one to obtain a closed system of equa-tions for coefficients .

Each Fourier harmonic of the magnetic fieldis perpendicular to the wavevector and to the cor-responding Fourier harmonic , while the electricinduction is perpendicular to the wavevector [27],

(19)

where

It follows from Eq. (19) that tangential components ofthe electric induction and magnetic field are related bythe expression

(20)

To express the continuity equations for the electricfield in terms of magnetic-field components, we will

( )( )

( )

ππδ δ +

ππ+ +

ππ= +

∑ ∑

0 0

,

,

(1) ( )

,

22exp

22exp

22exp .

n m

n m

rnm

n m

NN nm

N n m

yxi n i mL L

yxh i n i mL L

yxt h i n i mL L

rnmh ( )N

nmh

δ δ + = ∑(1) ( )

0 0 .r Nn m nm N nm

N

h t h

δ δ + = ∑(1) ( )

0 0 .r Nn m nm N nm

N

e t e

(1)Nt

rnme ( )N

nme

(1)Nt

( )Nnmh

( )Nnmk

( )Nnmd

ω× = −( ) ( ) ( ), ,N N N

n m nm nmck h d

( )π π=( ),

2 2, , .Nn m Nn m q

L Lk

= −ω

( ) ( )./

N NNnm nm

qd hc

use the equation relating the electric induction withthe electric field:

(21)

where εij are Fourier expansion coefficients of the per-mittivity. From (21), we express the tangential compo-nent of the electric field in terms of the tangentialcomponent of the electric induction:

(22)

where is a tensor inverse to the permittivity tensor

By using Eqs. (20) and (22), we rewrite the continuityequation of the tangential component of the electricfield (18) in terms of tangential components of themagnetic field,

(23)

Неre, are Fourier expansion coefficients for theNth mode, is tangential component of the mag-netic field in the reflected wave with the wavevector

(8), kz = is the normal component of thewavevector in a dielectric, and qN is the wavevector ofthe Nth mode.

Equations (17) and (23) form a closed system ofequations for coefficients . Below, we will calculatecoefficients taking into account a finite number ofFourier harmonics and a finite number of eigenmodesof the system. To define the system of equations forcoefficients , we will take into account equal num-bers of Fourier harmonics and eigenmodes of the sys-tem.

Note that Eqs. (16)–(23) neglect the excitation ofwaves with polarization different from that of the inci-dent wave. In the case of a plane wave normally inci-dent on a single hole, waves with such polarization arenot excited because of the cylindrical symmetry of theproblem.

Upon the normal incidence of a plane wave on afilm perforated by a periodic array circular holes,polarization is preserved if the polarization of the inci-dent wave is directed along one of the vectors of thisarray. In the general case, polarizations of thereflected and transmitted waves can differ from that ofthe incident wave. Polarization changes because theeigenmodes of the system differ from the modes of asingle hole and do not have the cylindrical symmetry.

∞ ∞

− −=−∞ =−∞

= ε∑ ∑( ) ( )

, ,N Nnm ij n j m l

j l

d e

−= ε( ) 1 ( )ˆ ,N Nnm nme d

−ε 1ˆ∞ ∞

− −=−∞ =−∞

ε = ε∑ ∑( ) ( )

, ,ˆ .N Nn m ij n j m l

j l

e e

−δ δ − = εε ∑

1 ( ) (1)0 0

1

ˆ( ) .r Nzn m nm N nm N

N

kh q h t

( )Nnmh

rnmh

ε −2 21,2 0 nmk k

(1)Nt

(1)Nt

(1)Nt

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EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 183

In this work, we consider the case when the dis-tance between holes greatly exceeds the skin-layerthickness and fields in different holes weakly affecteach other. As a result, polarizations of the reflectedand transmitted waves weakly differ (or do not differ atall) from polarization of the incident wave.

5.3. Calculation of Coefficients , , and

The reflected field of the Nth mode incident on thehole in metal–dielectric interface is a sum of all themodes of the system with coefficients rNM. To findcoefficients rNM (we are interested first of all in thecoefficient rN = rNN), we write the continuity conditionfor each Fourier harmonic on the boundary of tangen-tial components of electric and magnetic fields for theTM mode,

(24)

(25)

where kz = is the normal component ofthe wavevector in the dielectric, qN is the wavevector of

the Nth mode, are Fourier expansion coefficients

for the Mth mode, and is the wave amplitude in thedielectric with the tangential component of thewavevector (8).

By solving the system of equations (24), (25), weobtain the values of coefficients rNM from which the

required coefficients (or ) are equal to rNN. The

coefficient is also found from system (24), (25) and

is equal to .

6. DETERMINATION OF THE WAVELENGTHS OF TRANSMISSION COEFFICIENT MAXIMA IN THE CASE OF A SMALL-DIAMETER HOLE

6.1. Limit of Infinitesimal-Diameter Holes

Knowing the wave numbers qN of the eigenmodes

of the system and coefficients , , , and , wecan find the wave amplitude tnm with the wavevectorknm on the rear boundary of the metal film (10). How-ever, systems of equations (17), (23), and (24), (25) areinfinite systems of linear equations and do not admitan analytic solution.

(2)Nt (1)

Nr (2)Nr

+ =∑( ) ( ) ,N M tnm NM nm nm

M

h r h h

− ⎛ ⎞ε − =⎜ ⎟

⎜ ⎟ ε⎝ ⎠∑

1 ( ) ( )

1,2

ˆ ,N M tzN nm M NM nm nm

M

kq h q r h h

ε −2 21,2 0 nmk k

( )Mnmh

tnmh

(1)Nr (2)

Nr(2)Nttnmh

(1)Nt (2)

Nt (1)Nr (2)

Nr

To obtain analytic expressions for coefficients ,, , and , we consider the limit of an infinites-

imal-diameter hole (k0d → 0). In this case, the wavenumbers of all modes become identical7 and thematrix becomes diagonal with diagonal elementsequal to , which allows us to pass from systems ofequations (17), (23) and (24), (25) to two systems ofequations

(26)

(27)

and

(28)

(29)

Here, q is the wave number of hole modes in the casewhen the hole diameter tends to zero, is the mag-netic field amplitude in the reflected wave for the Nmode,

(30)

and is the magnetic field amplitude in thereflected wave,

(31)

where SnmM is a matrix with the nmMth element equal

to . It follows from Eqs. (30) and (31) that

(32)

(33)It follows from the system of equations (26), (27) that

(34)

In turn, it follows from the system of equations (28),(29) that

(35)

7 Indeed, in the limit k0d → 0 for n ≠ 0, we obtain

(k0d)/Jn(k0d) → n/k0d and (k0d)/Hn(k0d) → –n/k0d. As aresult, dispersion equation (4) no longer depends on the modenumber n.

(1)Nt

(2)Nt (1)

Nr (2)Nr

'nJ 'nH

−ε 1ˆ−ε 1M

δ δ + =0 0 ,r trn m nm nmh h

δ δ − =ε ε0 0

1,2

( )nm

r trzn m nm nm

M

k qh h

+ =( ) ref ,N tnm nm nmh h h

− =ε ε

( ) ref

1,2

( ) .nm

N tznm nm nm

M

kq h h h

trnmh

= =∑(1) ( ) (1),tr N

nm M nm nmM M

M

h t h S t

refnmh

= =∑ref ( ) ,Mnm NM nm nmM NM

M

h r h S r

( )Mnmh

−=(1) 1 ,trM nmM nmt S h

−= 1 ref .NM nmM nmr S h

ε= δ δε + ε

0 01,2

2.

nmtr M znm n mnm

M z

kh

k q

ε − ε=

ε + εref ( )1,2

1,2

.nm

NM znm nmnm

M z

q kh h

q k

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Here, εM and ε1, 2 are permittivities of the metal anddielectric, the subscript “1” corresponds to reflectionfrom the front boundary of the film and the subscript“2” to reflection from the rear boundary.

As a result, we obtain

(36)

(37)

Coefficients and rNM have maxima when the reso-nance condition

(38)is fulfilled.

However, the coefficient is nonzero only for n =m = 0, when = ω/c and therefore resonance con-dition (38) is never fulfilled for . Coefficients rNMare nonzero for arbitrary n and m and resonance con-dition (38) can be fulfilled.

For all modes with n ≠ 0, the wavevector q tends tok0 for k0d ≠ 0. Therefore, condition (38) is ful-filled when the modulus of the tangential componentof the wavevector knm (38) is

(39)

Note that for |εM| ≫ ε1, 2, the relation

(40)

takes place, where ksp is the real part of the wave num-ber of a surface plasmon on the metal–dielectricboundary. In other words, the maximum of the reflec-tion coefficient rNM is observed when the tangentialcomponent of the wavevector of the incident wave isequal to the wavevector of a surface plasmon.

Thus, reflection coefficients and (i.e.,rNN) have maxima when condition (39) is fulfilled. Inthe case of subwavelength holes, eigenmodes are eva-nescent and therefore exp(–2hImqN) → 0 withincreasing the film thickness. In this case, Fabry–Perot resonances in holes can be observed only when| | ≫ 1 (see the amplitude Fabry–Perot resonancecondition (12)). Therefore, the position of the trans-mission coefficient maxima in thick films is deter-mined by condition (39), which for |εM| ≫ ε1, 2 is closeto the excitation condition of a surface plasmon on themetal–dielectric interface.

Transmission coefficient maxima (10) can berelated not only to Fabry–Perot resonances in a hole,

−ε= δ δε + ε

(1) 10 0

1,2

2,

nmM z

M nmM n mnmM z

kt S

k q

−ε − ε=

ε + ε1 ( )1,2

1,2

.nm

NM zNM nmM nmnm

M z

q kr S h

q k(1)Mt

ε + ε =1,2 0nmM zq k

(1)Mt

00zk

(1)Mt

εM

⎡ ⎤ε ε − εω= = ⎢ ⎥ε⎣ ⎦

1,2 1,2res

( )| | Re .M

nmM

kc

k

⎡ ⎤ε εω≈ = ⎢ ⎥ε + ε⎣ ⎦

1,2res

1,2

Re ,Msp

M

k kc

(1)Nr (2)

Nr

(1,2)Nr

but also to the maxima of (the excitation coeffi-cient of a plane wave with the tangential component ofthe wavevector knm by the Nth mode on the rearboundary of the metal film). When the hole diameterk0d → 0, the coefficient is determined from the sys-tem of equations (28), (29),

(41)

Thus, the positions of maxima coincides with thatof kNM maxima.

The transmission coefficient tnm of a metal film

perforated by a hole array is proportional to (seeEq. (10)), therefore, independent of the film thick-ness, the position of transmission coefficient maximais determined by condition (38). For |εM| ≫ ε1, 2, this isthe excitation condition for a surface plasmon on themetal–dielectric boundary.

Note, however, that condition (38) is fulfilled onlyfor waves with the tangential component of thewavevector kres > (ω/c)ε1, 2. Therefore, such wavesexponentially decrease with increasing distance fromthe metal film surface and do not contribute to thetransmitted radiation intensity.

As a result, in the limit of an infinitesimal holediameter k0kd → 0, the intensity maxima of transmit-ted radiation can be related only to Fabry–Perot reso-nances in holes in the metal film. We will show belowthat, when a finite diameter of the hole is taken intoaccount, the intensity maxima of transmitted radia-tion can be related not only to Fabry–Perot reso-nances but also to the maxima of . Such maximacan be interpreted as excitation of Bloch surface plas-mons on the rear boundary of the metal film. At thesame time, coefficients have no maxima even in thecase of finite-diameter holes. Because of this, exci-tation of Bloch surface plasmons on the front bound-ary of the metal film do not give rise to transmissioncoefficient maxima. Their influence can be mani-fested in the appearance of the reflection coefficientmaxima.

6.2. The Case of Finite-Diameter HolesWe considered above the limiting case of a small-

diameter hole (k0d → 0). In the general case, coef-

ficients rNM, are found from the system of equa-tions (24), (25). This system of equations is infiniteand therefore its solution can be found only approxi-mately. To find the solution, we pass on to the finitesystem of equations

(42)

(2)Nt

(2)Nt

ε=ε + ε

(2)

1,2

2.M z

NM z

kt

q k(2)Nt

(2)Nt

(2)Nt

(1)Nt

(2)Nt

=

+ + =∑max

( ) ( ) ref

0

,M

N M tnm NM nm nm nm

M

h r h h h

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EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 185

(43)

In Eqs. (42), (43), unlike (24), (25), summation overM is performed for a finite number of modes. Thenumber Mmax of considered modes determines theaccuracy of solving the system of equations (24), (25).The contribution from all other modes is taken intoaccount in the form of the term

(44)

in Eq. (42) and the term –q in Eq. (43), where q =k0 . Here, we took into account that the eigen-wavevector of the mode qM tends to q with increasingthe mode number. Therefore, we can reduce theinfinite number of modes with numbers M > Mmax toone effective mode with the wavevector q.

The system of equations (42), (43) allows us to findcoefficients rNM, with any preliminarily specifiedaccuracy. However, it is difficult for analytic consider-ation. To find analytic expressions for positions of themaxima of coefficients rNM and , we will assumethat

at the maximum of rNM. As a result, we obtain the sys-tem of equations

(45)

(46)

We are interested in the mode reflection coefficients, of “the hole in metal–dielectric interface,”

which coincide with coefficients rNN. Therefore, wewill consider only the case of N = M. In this case,

(47)

(48)

By solving Eqs. (47), (48), we can no longer assumethat the tensor ≈ , where is the unit matrix.Indeed, in this case,

(49)

and

=

⎛ ⎞ε − − =⎜ ⎟

⎜ ⎟ ε⎝ ⎠∑

max1 ( ) ( ) ref

1,20

ˆ .M

N M tzN nm M NM nm nm nm

M

kq h q r h qh h

= +

= ∑max

ref ( )

1

Mnm NM nm

M M

h r h

refnmh

εM

(2)Nt

(2)Nt

≈∑( ) ( )

' ,M MNM nm NM nm

M

r h r h

≈∑( ) ( )

' 'M M

M NM nm M NM nm

M

q r h q r h

+ =( ) ( ) ,N M tnm NM nm nmh r h h

−ε − =ε

1 ( ) ( )

1,2

ˆ ( ) .N M tzN nm M NM nm nm

kq h q r h h

(1)Nr (2)

Nr

+ =( )(1 ) ,N tNN nm nmr h h

−ε − =ε

1 ( )

1,2

ˆ (1 ) .N tznm N NN nm

kh q r h

−ε 1ˆ −ε 1 ˆM I I

− − −⎛ ⎞π πε = − ε + ε⎜ ⎟⎝ ⎠

2 21 1 1

00 2 214 4

M Hd dL L

(50)

where εH is the permittivity in the hole. Therefore, it

seems that, when L2 ≫ d2, we can assume that ≈ and ≈ 0. However, as a rule, |εM| ≫ ε1, 2 and

coefficients and , , … prove to be of the sameorder of magnitude. For example, in the case of a goldmetal film perforated by a periodic array of holes withdiameter d = 100–150 nm and period L = 400–600 nm,

(51)

and

(52)Therefore, for d ≈ 150 nm and L ≈ 400 nm, we have| | ≈ | | ≈ | |. Therefore, in Eqs. (47), (48), alongwith , it is necessary to take into account coeffi-cients , , ….8

For each pair of values of n and m, the effective per-mittivity can be introduced as

(53)

By using the effective permittivity, the reflection coef-ficient can be written in the form

(54)

The coefficient rNN has a maximum under the reso-nance condition

(55)

Condition (55) is fulfilled when the tangential compo-nent of the wavevector knm is

(56)

In other words, the maxima of the reflection coeffi-cient rNN are observed under the condition

(57)

8 When d < 100 nm and L > 600 nm, | | ≫ | | and we can

assume approximately that ≈ , where is the unitmatrix.

− −πε ε2

1 12~ ,

4nm H

dL

−ε 100

−ε 1M

−ε 1nm

−ε 100

−ε 110

−ε 111

π = −2

2 0.022 0.11,4

dL

−ε ε ≈1| | 10.M H

−ε 100

−ε 110

−ε 111

−ε 100

−ε 110

−ε 111

−ε 100

−ε 110

−ε 1ˆ −ε 1 ˆM I I

−−⎛ ⎞

ε⎜ ⎟⎜ ⎟

ε = ⎜ ⎟⎜ ⎟⎜ ⎟⎝ ⎠

1

1 ( )

,eff ( )( , ) .

Nij ij

i jN

nm

h

n mh

ε − ε=

ε + ε1,2 eff

1,2 eff

.N zNN

N z

q kr

q k

ε + ε =1,2 eff 0.N zq k

εω= = ε −ε

2221,2

res 1,2 2 2eff

| | .nm Nk qc

k

π π= +res2 2 .x y

x y

k n mL L

e e

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It follows from Eq. (57) that the positions of max-ima of the transmission coefficient coincide withthose of the reflection coefficient rNN. Unlike the caseof an infinitesimal hole diameter, the positions ofmaxima of are independent of n and m and aredetermined by the position of the maximum of rNN. Inparticular, the transmission coefficient maximum isobserved for a wave with the zero tangential compo-nent of the wavevector. Such a wave propagates with-out decay with distance from the rear boundary of themetal film and transfers energy away from the film.

Thus, in the case of finite-thickness holes, theintensity maxima of transmitted radiation can berelated both to excitation of Fabry–Perot resonancesin holes and excitation of Bloch plasmon modes on therear boundary of the metal film.

7. COMPARISON OF ANALYTIC RESULTS WITH NUMERICAL CALCULATIONS

7.1. Transmission Coefficient SpectrumTo test the theory constructed, we compare trans-

mission coefficients of a metal film perforated by ahole array obtained from the system equations (47),

(2)Nt

(2)Nt

(48) with the results of numerical simulation using theComsol Multiphysics 5.2 software (Fig. 6).

One can see from Fig. 6 that the theory qualita-tively correctly describes all the maxima of the trans-mission coefficient. Moreover, it well enough predictsthe position and intensity of the maxima and minimaof the transmission coefficient (Fig. 6). The discrep-ancy between analytic results and numerical calcula-tions is explained by the single-mode approximationused in calculations (see Section 4.1).

7.2. Dependence of the Transmission Coefficienton the Film Thickness

We showed in the previous section that maxim of thetransmission coefficient can be related to Fabry–Perotresonances in holes, Bloch plasmon modes on the rearboundary of the metal film and “transmission win-dows” of metals. The intensities of transmission max-ima related to Fabry–Perot resonances and Bloch plas-mon modes differently depend on the film thickness.

The maxima of the transmission coefficient related toBloch plasmon modes are proportional to exp(–hImqN),where qN is the wavevector of the most slowly decayingeigenmode of the hole. In our case, this the TE11

Fig. 6. Wavelength dependences of the transmission coefficient. Solid curves correspond to numerical calculations, dotted curvesto analytic calculations. The film thickness is 100 nm, the hole diameter is 150 nm, the array period is WL = 400 (a), 450 (b),500 (c), and 550 nm (d).

500 600 700 800λ, nm

λ, nm

λ, nm

λ, nm

0

0.05

0.10

0.15

0.20

500 600 700 8000

0.05

0.10

0.15

500 600 700 8000

0.02

0.04

0.06

0.08

0.10

0.12

500 600 700 8000

0.05

0.10

0.15

T

T

T

T

(a) (b)

(c) (d)

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JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS Vol. 125 No. 2 2017

EXTRAORDINARY LIGHT TRANSMISSION THROUGH A METAL FILM PERFORATED 187

mode. In turn, the maxima of the transmission coeffi-cient related to Fabry–Perot resonances in holes areproportional to

(58)

where γ(h) is the decay decrement of the transmissioncoefficient. It follows from Eq. (58) that

(59)

Near the Fabry–Perot resonance,

and, as a result, γ(h) < ImqN.Thus, transmission coefficient maxima related to

Fabry–Perot resonance in holes decrease withincreasing the film thickness slower than the ampli-

− = −γ− 1 (2)

exp( Im ) exp( ( ) ),|1 exp(2 )|

N

N N N

h q h hr r iq h

γ = + − 1 (2)1( ) Im ln(|1 exp(2 )|).N N N Nh q r r iq hh

− �1 (2)|1 exp(2 )| 1N N Nr r iq h

tude of the most slowly decreasing eigenmode of thehole (γ(h) < ImqN).

Numerical simulations of the transmission coeffi-cient of a gold film perforated by an array of holes con-firm that the transmission coefficient maximumrelated to Fabry–Perot resonances in holes (for λ ≈650 nm) decreases much slower than all other maxima(Fig. 7a). Moreover, this maximum decreases withincreasing the film thickness slower than the ampli-tude of the most slowly decreasing eigenmode qN ofthe hole (Fig. 7b).

Different dependences of the amplitudes of trans-mission coefficient maxima related to Fabry–Perotresonances or Bloch plasmon modes on the rearboundary of the metal film on the film thickness allowus to simply determine the mechanism of the maxi-mum appearance.

8. CONCLUSIONSThe appearance of transmission coefficient max-

ima is explained be three different mechanisms. Eachmechanism dominates in a certain region of parame-ters.

First, transmission coefficient maxima appear in“the transparency window” of real metals (gold, silver,etc.), i.e., at frequencies where the absorption mini-mum is observed. The amplitude of the electromag-netic wave on the rear boundary of a metal film isequal to the sum of amplitudes of electromagneticwaves transmitted through holes in the metal film andthe amplitudes of electromagnetic waves transmittedthrough the metal. When the amplitudes of wavestransmitted through holes and metal are close, thetransmission coefficient has two (or more) maxima atwavelengths close to the “transparency window” ofthe metal.

Second, transmission coefficient maxima canappear due to excitation of Fabry–Perot resonance inholes in the metal film described in [17].

Third, transmission coefficient maxima can appeardue to excitation of Bloch surface plasmon modes onthe rear boundary of the metal film.

It was shown in our paper that excitation of plas-mon modes on the front boundary of the metal filmdoes not produce transmission coefficient maxima.

It was also shown that in the “thick” film limit (thefilm thickness h > 100 nm), transmission coefficientmaxima related to excitation of Fabry–Perot reso-nances in holes are observed at frequencies for whichthe excitation condition for surface resonances on thefront and rear boundaries of the metal film is fulfilled.

We also showed that the amplitudes of the trans-mission coefficient maxima related to excitation ofFabry–Perot resonances in holes decrease withincreasing the film thickness slower than the mostslowly decaying mode of the hole.

Fig. 7. (Color online) (a) Wavelength dependences of thetransmission coefficient. The hole diameter is 150 nm, thearray period is L = 600 nm, the film thickness is 80 nm(blue solid curve), 100 nm (green solid curve), and 120 nm(red dash-and-dot curve). (b) Dependences of the trans-mission coefficient on the film thickness at the maximumat about 650 nm. The hole diameter is 150 nm, the arrayperiod is L = 600 nm. The green curve is the decay decre-ment of the most slowly decaying eigenmode of the hole.The red and black curves show the real decay decrementfor film thicknesses 100 and 180 nm.

500 600 700 800λ, nm

0

0.05

0.10

0.15

0.20

80 100 120 140 160 180 200

0.10

1.00

0.50

0.200.30

0.15

0.70

T

log T

h, nm

(a)

(b)

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188

JOURNAL OF EXPERIMENTAL AND THEORETICAL PHYSICS Vol. 125 No. 2 2017

ZYABLOVSKII et al.

ACKNOWLEDGMENTSV.V. Klimov and A.A. Pavlov acknowledge the par-

tial support of the Russian Foundation for BasicResearch (project nos. 14-02-00290, 15-52-52006).

REFERENCES1. T. W. Ebbesen, H. J. Lezec, H. F. Ghaemi, et al.,

Nature 391, 667 (1998).2. H. F. Ghaemi, T. Thio, D. E. Grupp, et al., Phys. Rev.

B 58, 6779 (1998).3. F. J. Garcia de Abajo, Rev. Mod. Phys. 79, 1267 (2007).4. F. J. Garcia-Vidal, L. Martin-Moreno, T. W. Ebbesen,

et al., Rev. Mod. Phys. 82, 729 (2010).5. H. J. Lezec, A. Degiron, E. Devaux, et al., Science 297,

820 (2002).6. H. A. Bethe, Phys. Rev. 66, 163 (1944).7. C. J. Bouwkamp, Philips. Res. Rep. 5, 321 (1950).8. C. J. Bouwkamp, Philips. Res. Rep. 5, 401 (1950).9. T. Thio, K. M. Pellerin, R. A. Linke, et al., Opt. Lett.

26, 1972 (2001).10. T. Thio, H. J. Lezec, T. W. Ebbesen, et al., Nanotech-

nology 13, 429 (2002).11. S.-H. Chang, S. K. Gray, and G. C. Schatz, Opt.

Express 13, 3150 (2005).12. F. J. García-Vidal, E. Moreno, J. A. Porto, et al., Phys.

Rev. Lett. 95, 103901 (2005).13. A. J. L. Adam, J. M. Brok, M. A. Seo, et al., Opt.

Express 16, 7407 (2008).14. F. J. García-Vidal, L. Martín-Moreno, E. Moreno,

et al., Phys. Rev. B 74, 153411 (2006).

15. S. B. Cohn, Proc. IRE 40, 783 (1952).16. J. A. Porto, F. J. García-Vidal, and J. B. Pendry, Phys.

Rev. Lett. 83, 2845 (1999).17. L. Martín-Moreno, F. J. García-Vidal, H. J. Lezec,

et al., Phys. Rev. Lett. 86, 1114 (2001).18. U. Schroter and D. Heitmann, Phys. Rev. B 58, 419

(1998).19. Z. Ruan and M. Qiu, Phys. Rev. Lett. 96, 233901

(2006).20. E. Popov, M. Neviere, S. Enoch, et al., Phys. Rev. B

62, 16100 (2000).21. Q. Cao and P. Lalanne, Phys. Rev. Lett. 88, 057403

(2002).22. A. D. Rakic, A. B. Djurisic, and J. M. Elazar, Appl.

Opt. 37, 5271 (1998).23. O. Airy, Essex Papers (Camden Society, London,

1890).24. C. A. Pfeiffer, E. N. Economou, and K. L. Ngai, Phys.

Rev. B 10, 3038 (1974).25. J. A. Stratton, Electromagnetic Theory (McGraw-Hill,

New York, 1941), p. 526.26. L. A. Vainshtein, The Theory of Diffraction and the

Factorization Method: Generalized Wiener-HopfTechnique, Golem Series in Electromagnetics(Sovetskoe Radio, Moscow, 1966; Golem, Boulder,CO, 1969), rus. p. 155.

27. L. D. Landau and E. M. Lifshitz, Course of TheoreticalPhysics, Vol. 8: Electrodynamics of Continuous Media(Fizmatlit, Moscow, 2005; Pergamon, New York,1984), rus. p. 458.

Translated by M. Sapozhnikov


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