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Filtration

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filtrasi adalah pemisahan dua fasa yaitu padatan dari cairannya dengan menggunakan alat
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Monroe L. Weber- Shirk School of Civil and Environmental Engineering Filtration Theory On removing little particles with big particles
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  • Filtration OutlineFilters galoreRange of applicabilityParticle Capture theoryTransportDimensional Analysis Model predictionsFiltersRapidSlowBioSandPotsRoughingMultistage Filtration

  • Filters GaloreBio SandRapid SandCartridgeBagPotCandleDiatomaceous earth filterSlow SandRough

  • Categorizing FiltersStrainingParticles to be removed are larger than the pore sizeClog rapidlyDepth FiltrationParticles to be removed may be much smaller than the pore sizeRequire attachmentCan handle more solids before developing excessive head lossFiltration model comingAll filters remove more particles near the filter inlet

  • The if it is dirty, filter it MythThe common misconception is that if the water is dirty then you should filter it to clean itBut filters cant handle very dirty water without clogging quickly

  • Filter range of applicabilitySSFCartridgeBagRSF+PotCandleDE

  • Developing a Filtration ModelIwasaki (1937) developed relationships describing the performance of deep bed filters.C is the particle concentration [number/L3]l0 is the initial filter coefficient [1/L]z is the media depth [L]The particles chances of being caught are the same at all depths in the filter; pC* is proportional to depth

  • Graphing Filter PerformanceThis graph gives the impression that you can reach 100% removalWhere is 99.9% removal?

  • Particle Removal Mechanisms in FiltersTransport to a surfaceAttachmentMolecular diffusionInertiaGravityInterceptionStrainingLondon van der Waalscollector

  • Filtration Performance: Dimensional AnalysisWhat is the parameter we are interested in measuring? _________________How could we make performance dimensionless? ____________What are the important forces?

    Effluent concentrationC/C0 or pC*InertiaLondon van der WaalsElectrostaticViscousNeed to create dimensionless force ratios!GravitationalThermal

  • Dimensionless Force RatiosReynolds NumberFroude NumberWeber NumberMach NumberPressure/Drag Coefficients(dependent parameters that we measure experimentally)

  • What is the Reynolds number for filtration flow?What are the possible length scales?Void size (collector size) max of 0.7 mm in RSFParticle sizeVelocitiesV0 varies between 0.1 m/hr (SSF) and 10 m/hr (RSF)Take the largest length scale and highest velocity to find max Re

    For particle transport the length scale is the particle size and that is much smaller than the collector size

  • Choose viscosity!In Fluid Mechanics inertia is a significant force for most problemsIn porous media filtration viscosity is more important that inertia.We will use viscosity as the repeating parameter and get a different set of dimensionless force ratiosInertia

  • GravityvporeGravity only helps when the streamline has a _________ component.horizontalvelocitiesforces Use this definition

  • Diffusion (Brownian Motion)kB=1.38 x 10-23 J/KT = absolute temperaturevporedc is diameter of the collectorDiffusion velocity is high when the particle diameter is ________.small

  • London van der WaalsThe London Group is a measure of the attractive forceIt is only effective at extremely short range (less than 1 nm) and thus is NOT responsible for transport to the collectorH is the Hamakers constant

    Van der Waals forceViscous force

  • What about Electrostatic repulsion/attraction?Modelers have not succeeded in describing filter performance when electrostatic repulsion is significantModels tend to predict no particle removal if electrostatic repulsion is significant.Electrostatic repulsion/attraction is only effective at very short distances and thus is involved in attachment, not transport

  • Geometric ParametersWhat are the length scales that are related to particle capture by a filter?______________________________________________________Porosity (void volume/filter volume) (e)Create dimensionless groupsChoose the repeating length ________

    Filter depth (z)Collector diameter (media size) (dc)Particle diameter (dp)(dc)Number of collectors!Definition used in model

  • Write the functional relationshipLength ratiosForce ratiosIf we double depth of filter what does pC* do? ___________doublesHow do we get more detail on this functional relationship?Empirical measurementsNumerical models

  • Numerical ModelsTrajectory analysisA series of modeling attempts with refinements over the past decadesBegan with a single collector model that modeled London and electrostatic forces as an attachment efficiency term (a)InterceptionSedimentationDiffusiona

  • Filtration ModelPorosityGeometryForce ratios

  • Transport EquationsBrownian motionInterceptionGravityTotal is sum of partsTransport is additive

  • Filtration TechnologiesSlow (FiltersEnglishSlow sandBiosand)First filters used for municipal water treatmentWere unable to treat the turbid waters of the Ohio and Mississippi RiversCan be used after Roughing filtersRapid (MechanicalAmericanRapid sand)Used in Conventional Water Treatment FacilitiesUsed after coagulation/flocculation/sedimentationHigh flow ratesclog dailyhydraulic cleaningCeramic

  • Rapid Sand Filter (Conventional US Treatment)SandGravelInfluentDrainEffluentWash waterAnthraciteSize(mm)0.70

    0.45 - 0.55

    5 - 60SpecificGravity1.6

    2.65

    2.65Depth(cm)30

    45

    45

  • Filter DesignFilter mediasilica sand and anthracite coalnon-uniform media will stratify with _______ particles at the topFlow rates60 - 240 m/dayBackwash ratesset to obtain a bed porosity of 0.65 to 0.70typically 1200 m/day

    smallerCompare with sedimentation

  • SandGravelInfluentDrainEffluentWash waterAnthraciteBackwashWash water is treated water!WHY?Only clean water should ever be on bottom of filter!

  • Rapid Sand predicted performanceNot very good at removing particles that havent been flocculated

  • Slow Sand FiltrationFirst filters to be used on a widespread basisFine sand with an effective size of 0.2 mmLow flow rates (2.5-10 m/day)Schmutzdecke (_____ ____) forms on top of the filtercauses high head lossmust be removed periodicallyUsed without coagulation/flocculation!Turbidity should always be less than 50 NTU with a much lower average to prevent rapid cloggingfilter cakeCompare with sedimentation

  • Slow Sand Filtration MechanismsProtozoan predators (only effective for bacteria removal, not virus or protozoan removal)Aluminum (natural sticky coatings)Attachment to previously removed particlesNo evidence of removal by biofilms

  • Typical Performance of SSF Fed Cayuga Lake Water0.050.11012345Time (days)Fraction of influent E. coli remaining in the effluentFilter performance doesnt improve if the filter only receives distilled water(Daily samples)

  • Particle Removal by Size0.0010.010.110.8110Particle diameter (m)control3 mM azideFraction of influent particles remaining in the effluentEffect of the ChrysophyteWhat is the physical-chemical mechanism?

  • Techniques to Increase Particle Attachment EfficiencyMake the particles stickierThe technique used in conventional water treatment plantsControl coagulant dose and other coagulant aids (cationic polymers)Make the filter media stickierBiofilms in slow sand filters?Mystery sticky agent present in surface waters that is imported into slow sand filters?

  • Cayuga Lake Seston ExtractConcentrate particles from Cayuga LakeAcidify with 1 N HClCentrifugeCentrate contains polymerNeutralize to form flocs

  • Seston Extract AnalysisHow much Aluminum should be added to a filter?I discovered aluminum!

    Chart2

    0.558988764

    0.170220345

    0.1087730904

    0.0075314233

    0.0061913728

    0.0060641528

    0.0047749902

    0.0023722287

    0.003014308

    0.1320693246

    coliform analysis

    Influent2

    effluent2

    total per filter4

    total per filter24

    sample MWF3

    per week72

    pumps

    ismatec tubingID (mm)Area (mm^2)flow at 100 rpm (mL/min)rpm/flow (rpm/(mL/min))desired flow (mL/min)required rpm

    org/org0.890.62211388525.418.51851851850.0541.08.6800827441

    purp/wht2.796.1136178437323.1251340.6255.2342165994

    org/red0.190.02835287370.32312.511.2863339145

    org/ylw0.510.20428206232509.7903848115

    flows

    column diameter10cm

    approach velocity10cm/hr

    column area78.5cm^2

    approach velocity0.17cm/min

    flow rate13.1mL/min

    pump rpm40.9rpm

    column height20cm

    porosity0.4

    glass beads per column2.25kg

    volume of water628mL

    residence time48min

    number of columns6

    volume of column1571mL

    glass bead height20cm

    mass of beads2592g

    volume of water for a week792L

    desired E. coli conc2per mL

    desired E. coli conc2.00E+06per liter

    cryovial concentration2.00E+09per mL

    E. coli dilution factor500

    E. coli flow rate0.157mL/min

    pump rpm2.909rpm

    E. coli conc in fridge1.00E+09per liter

    E. coli flow rate1583mL/week

    volume of cryovial bacteria0.50mL/L

    1 L will last4.42days

    Fraquil dilution500

    Azide dilution500

    CLSE

    actual CLSE conc2580mg/L

    CLSE dilution400

    flow rate0.0327mL/min

    pump rpm1.64rpm

    flow rate330mL/week

    volume (two week supply)660mL18

    Filter1 week (mg)2 weeks (mg)feed stock concentration (mg/L)CLSE concentrationmg/LCLSE fluxg/(m2/day)total CLSE appliedmgtotal CLSE appliedg/m2actually fed (mL)

    434.068.1103low0.260.62486.2469

    5170.2340.4516medium1.33.113717gives 1 m head loss266

    6851.11702.12580high6.51514819gives 1 m head loss57

    initial CLSE (mg)CLSE (g/m2)

    2170mg22

    3851mg108

    sum3132mg

    Stock concentration2580mg/L

    stock volume1.21L

    65.973mLneutralizedfor filter2

    329.867mLneutralizedfor filter3

    26.4mLdilute to660for filter4

    132mLdilute to660for filter5

    660mLdilute to660for filter6

    total volume1213.9mL

    TEP C rate20mg/cm2/day

    TEP C rate1571mg/day

    TEP C concentration83mg/L

    TEP initial application

    equal to7days

    of2.5mg/L

    therefore329.87mg

    Dilution water

    compounddilutionstock conc.stock volumemass for stockstock good for

    mL/Lg/LLgL

    KH2PO41.2534134

    MgCL2 6H2O581.1181.1

    Magnesium chloride solution: Add 81.1 g MgCl2*6H20 to 500 mL reagent grade water and then dilute to 1 L with reagent grade water

    monroe:Requires about 180 mL of 1 N NaOH to titrate 1 L to pH 7.2

    Fraquil

    compoundmolecular weightfinal molarityfinal conc.dilutionstock conc.stockstock volumemass for stockstock good fordilution500 x concentrate500 x concentrate500x concentration of synthetic feed

    g/molemole/Lg/LmL/100 Lg/LLgLmL/LmL/LmL/100 mLg/L

    CaCl22H2O147.022.50E-040.03675510367.55a0.5183.775500010050518.38CaCl22H2O

    NaNO384.991.00E-040.0084991084.99a0.542.49550001005054.25NaNO3

    MgSO47H20246.471.50E-040.03697055073.941b173.94120005002502518.49MgSO47H20

    NaHCO384.011.50E-040.01260155025.203b125.2032000500250256.30NaHCO3

    K2HPO4174.181.00E-050.00174181174.18c0.117.41810000

    Na2SiO39H2O284.21.25E-050.00355251355.25c0.135.52510000

    CuSO45H2O249.681.00E-090.000000249710.024968d0.10.002496810000

    Na2MoO42H2O241.951.50E-090.000000362910.0362925d0.10.0036292510000

    CoCl26H2O237.952.50E-090.000000594910.0594875d0.10.0059487510000

    MnCl24H2O197.912.30E-080.000004551910.455193d0.10.045519310000

    ZnSO47H2O287.544.00E-090.000001150210.115016d0.10.011501610000

    FeCl36H2O270.324.50E-080.000012164411.21644d0.10.12164410000

    Na2C10H14O8N22H2O372.245.00E-060.00186121186.12d0.118.61210000

    stocksvolumedilution

    a0.110

    b150

    c0.11

    d0.11

    I tried to make a 200x concentrated combined stock of a,b,c. It precipated when I added stock C. So we won't use stock c for our experiment.

    azide

    Desired concentration3mM

    molecular weight65.01

    concentration195mg/L0.00019503g/g0.02%

    dilution factor500

    stock97.515g/L

    42 g/100 g water @ 17C (63F)

    total azide per week154.4016134379g/week

    icp

    ICP analysis

    corrected for dilution with acid

    IDmg/Lmg/LPercent Total Solids

    Al401.4000439.16851442volatile solids56%

    Na256.5000280.6346439Al17%

    Fe17.760019.4311281Na11%

    P14.600015.973719Fe0.8%

    S14.300015.645516P0.6%

    Si11.260012.319516S0.6%

    Ca5.59406.120412Si0.5%

    Cu2.63602.88406Ca0.2%

    Zn1.15401.26268other metals0.3%

    Mg1.08801.1904341other nonvolatile solids13%

    Se0.86050.9415total2580

    Pb0.52920.5790

    Mn0.20340.2225

    Mo0.15900.1740

    Ni0.15100.1652

    Cr0.12380.1354

    Y0.09460.1035

    B0.05170.0566

    K0.02590.0283

    Cd0.01610.0176

    V0.01490.0163

    Cobdbd

    Asbdbd

    Agnc

    Nnr

    total729797

    0.8g/L

    FSS1138mg/L

    VSS1442

    TSS2580

    icp

    0

    0

    0

    0

    0

    0

    0

    0

    0

    0

    polymer

    TOC analysis on 6/8/00

    blank26mV

    standard751mV50mg TOC

    standard739mV50mg TOC

    scaling0.0695410292

    Filtered polymer solution from CEE 453

    volume0.1mL

    signal336.9mV

    335.45mV

    351.3mV

    average341.2166666667mV

    minus blank315.2166666667mV

    TOC21.9204914233mg Carbon

    TOC con219.2049142327mg TOC/L

    TOC analysis on 6/21/00

    blank20.5

    standard740.708

    standard742.782

    scaling0.0693245707

    polymermVvolume (mL)mass Cconcentration (mg/L)

    348.4035022.7455

    570.8910038.2382

    573.38710038.3383

    355.8165023.2465

    575.62310038.5385

    Gravimetric analysisVolatile solids

    stock volume100mLdish1.0611

    dish 1dish + dry solids1.0967

    tare1.0587gdish + nonvolatile1.0768

    dish + polymer1.3136gvolatile0.0199

    dish 2nonvolatile0.0157

    tare1.0584total0.03560.0356

    dish + polymer1.0615fraction volatile56%

    polymer0.258g/100 mL

    polymer2.58g/Lpolymer nameCLSE

    by measuring wet mass of gel and assuming density of 1Full nameCayuga Lake Seston Extract

    volume of gel5.5mL/100 mL

    55mL/L

    FSS1.14g/L

    VSS1.44g/L

    TSS2.58g/L

    schedule

    Eventdatetime

    begin pumping distilled water

    begin pumping azide/Fraquil,Coliforms6/155:00 PMThursday

    Sample coliforms6/16Friday

    Begin feeding polymer6/19Monday

    New azide, Fraquil, E. coli6/19Monday

  • E. coli Removal as a Function of Time and Al Application Rate pC* is proportional to accumulated mass of Aluminum in filterNo E. coli detected20 cm deep filter columns

    Chart1

    0.43702873890.4582180380.4582180380.54617320830.010.030.05-1

    0.18336476111.13982387130.68750.68750.010.030.051

    0.36362655383.16160439594.41657469595.73745769890.01

    0.46765595424.63896441514.97891247684.85059399950.01

    0.16536739373.86169730185.3729120034.0338582673

    0.28437008246.3497630442.31633928853.3825555574

    0.38958793436.28583849681.26464919772.8008919045

    0.31931878146.3089910291.26661243092.0729578819

    Horizontal bars indicate when polymer feed was operational for each filter.

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    E. coli remaining (pC*)

    print

    DateTime

    Filter123456

    head loss (cm)

    flow rate (mL/min)

    sectioninoutinoutinoutinoutinoutinout

    est. conc. (#/mL)

    sample volume (mL)000000000000

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)0.00.00.00.00.00.00.00.00.00.00.00.0

    C/Co000000

    const

    start time6/19/005:30 PM6/19/00 17:30

    headloss

    Filter123456mg/m^2

    datetimetimeadjusted timecontrolmed initial dosehigh initial dose3.9201003.9020.00100.00

    6/16/003:30 PM6/16/000.000.010.0120.0150.0140.0110.016000

    20-Jun1:26 PM6/20/000.830.0090.0120.0150.020.040.1043.239166666716.611111111183.0555555556

    20-Jun4:05 PM6/20/000.940.0090.0160.0150.0140.0450.1653.669791666718.819444444594.0972222226

    21-Jun9:05 AM6/21/001.650.0090.0130.0150.0140.0990.8056.432291666732.9861111111164.9305555555

    6/21/003:30 PM6/21/001.920.010.0180.0170.01750.12551.0317.47538.3333333334191.6666666672

    6/22/003:00 PM6/22/002.900.0090.0120.0150.0250.2651.04511.2937557.9166666667289.5833333336

    6/23/007:46 AM6/23/003.590.0090.0130.0160.0330.3630.77514.018333333371.8888888889359.4444444447

    6/23/002:55 PM6/23/003.890.0090.0120.0150.0360.4610.7715.180208333477.8472222223389.2361111117

    6/24/004:21 PM6/24/004.950.0090.0120.0150.0330.7020.82519.31312599.0416666667495.2083333337

    6/25/0011:00 AM6/25/005.730.0090.0130.0150.0510.9650.96822.34375114.5833333334572.9166666672

    6/26/004:23 PM6/26/006.950.0090.0130.0150.0960.96527.1185416667139.0694444445695.3472222223

    6/27/003:30 PM6/27/007.920.0090.0140.0150.1591.09430.875158.3333333334791.6666666672

    6/28/004:15 PM6/28/008.950.0090.0130.0150.20334.896875178.9583333334894.7916666672

    headloss

    00000.010.030.05-1

    00000.010.030.051

    00000.01

    00000.01

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    control

    3.9

    20

    100

    4

    20

    100

    end azide

    time (days)

    head loss (m)

    coli sum

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    0

    0

    0

    3.9

    20

    Total Al applied

    head loss (m)

    coli

    Filter123456145646/29/00 16:2556/25/00 11:006/20/00 9:006/21/00 15:306/23/00 7:40total Al (mmol/m2)pC*adjusted (pC*-pC*0)

    timecontrolmed initial dosehigh initial dose420100control420100timelow polymer feedtimeend polymertimeend polymertimeend azide00.4582180380

    00.36557059960.60928433270.76595744680.34816247580.34816247580.28433268860.43702873890.4582180380.4582180380.546173208300.0100.030.650.053.6-12.681251.13982387130.6816058333

    0.68750.65559440560.10680228860.07247298160.07247298160.18336476111.13982387131/3/00 10:300.015.730.031.920.053.617.393753.16160439592.7033863579

    1.89583333330.4328859060.08053691280.01510067110.00068927990.000038320.00000183040.36362655383.16160439594.41657469595.73745769891/3/00 22:300.0111.293754.63896441514.1807463771

    2.89583333330.34067796610.07389830510.00864406780.00002296340.00001049750.00001410610.46765595424.63896441514.97891247684.85059399959.950.0115.18020833343.86169730183.4034792638

    3.89236111110.68333333330.0450.20.00013750.00000423730.00009250.16536739373.86169730185.3729120034.033858267326.94791666676.3497630445.891545006

    6.90972222220.51955307260.05720670390.00000044690.00482681560.00041442360.28437008246.3497630442.31633928853.382555557430.8756.28583849685.8276204588

    7.91666666670.40776699030.14291262140.00000051780.0543689320.00158164170.38958793436.28583849681.26464919772.80089190456/23/00 16:00replace leaking tube

    8.91666666670.47938144330.18556701034.59231490160.00000049090.05412371130.00845360820.31931878146.3089910291.26661243092.0729578819

    average50%10%90%

    90%

    AMP (Al) fluxmmol/(m2/day)

    coli

    0.36557059960.34816247580.34816247580.28433268860000

    0.65559440560.07247298160.68750.68750000

    0.4328859060.00068927990.000038320.00000183040

    0.34067796610.00002296340.00001049750.00001410610

    0.68333333330.00013750.00000423730.0000925

    0.51955307260.00000044690.00482681560.0004144236

    0.40776699030.00000051780.0543689320.0015816417

    0.47938144330.00000049090.05412371130.0084536082

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    coli (1)

    0.36557059960.60928433270.7659574468

    0.65559440560.10680228860.0724729816

    0.4328859060.08053691280.0151006711

    0.34067796610.07389830510.0086440678

    0.68333333330.0450.2

    0.51955307260.05720670396.9097222222

    0.40776699030.14291262147.9166666667

    0.47938144330.18556701034.5923149016

    control

    med initial dose

    high initial dose

    time (days)

    coli (2)

    0

    0.6816058333

    2.7033863579

    4.1807463771

    Horizontal bars indicate when CLSE feed was operational for each filter.

    Horizontal bars indicate when polymer feed was operational for each filter.

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    E. coli remaining (pC*)

    0

    0

    0

    0

    0

    0

    0

    0

    0.6875

    0.6875

    0.6875

    0.6875

    0

    0

    0

    0

    1.8958333333

    1.8958333333

    1.8958333333

    1.8958333333

    0

    2.8958333333

    2.8958333333

    2.8958333333

    2.8958333333

    0

    3.8923611111

    3.8923611111

    3.8923611111

    3.8923611111

    6.9097222222

    6.9097222222

    6.9097222222

    6.9097222222

    7.9166666667

    7.9166666667

    7.9166666667

    7.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    0.4370287389

    0.458218038

    0.458218038

    0.5461732083

    0

    0

    0

    0

    0.1833647611

    1.1398238713

    0

    0

    0

    0

    0.3636265538

    3.1616043959

    4.4165746959

    5.7374576989

    0

    0.4676559542

    4.6389644151

    4.9789124768

    4.8505939995

    0

    0.1653673937

    3.8616973018

    5.372912003

    4.0338582673

    0.2843700824

    6.349763044

    2.3163392885

    3.3825555574

    0.3895879343

    6.2858384968

    1.2646491977

    2.8008919045

    0.3193187814

    6.308991029

    1.2666124309

    2.0729578819

    adjusted (pC*-pC*0)

    Total Al (mmol/m2)

    E. coli remaining (pC*-pC*clean sand)

    coli (3)

    DateTimeTime12/31/99 0:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)000000000000

    C/Co000000

    Co (#/mL)0

    coli (4)

    Date6/16/00Time3:30 PMTime6/16/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.020

    count93.035.090.062.082.058.074.027.088.023.090.019.0

    sample volume (mL)0.0200.0200.0200.0200.0200.020

    count28.043.074.033.037.030.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)4650.01575.04500.02625.04100.03300.03700.01500.04400.01500.04500.01225.0

    C/Co0.365570.609280.765960.348160.348160.28433

    Co (#/mL)4308.3333333333

    coli (5)

    Date6/20/00Time10:00 AMTime6/20/00 10:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0400.0800.0400.0800.0400.0800.0400.0800.0400.0800.0400.080

    count60.067.053.016.041.05.044.07.050.00.038.00.0

    sample volume (mL)0.0800.8000.8000.8000.8000.800

    count58.096.071.069.00.00.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1500.0781.31325.0127.31025.086.41100.086.41250.00.0950.00.0

    C/Co0.655590.106800.072470.072470.000000.00000

    Co (#/mL)1191.6666666667

    coli (6)

    Date6/21/00Time3:00 PMTime6/21/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.100.050.500.050.800.051.000.05100.000.05100.00

    count64.048.052.040.058.012.051.01.056.03.017.00.0

    sample volume (mL)0.1000.80010.00010001000

    count38.012.08.044.02.0

    sample volume (mL)100.02000.0

    count67.071.0

    sample volume (mL)

    count

    measured conc. (#/mL)1280.0430.01040.080.01160.015.01020.00.71120.00.0340.00.0

    C/Co0.432890.080540.015100.000690.000040.0000018

    Co (#/mL)993.3333333333

    coli (7)

    Date6/22/00Time3:00 PMTime6/22/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.50.0510.051000.051000.05100

    count5739503450105211441423

    sample volume (mL)0.111100010001000

    count28757591114

    sample volume (mL)200020002000

    count2026

    sample volume (mL)

    count

    measured conc. (#/mL)1140.0335.01000.072.71000.08.51040.00.0880.00.0840.00.0

    C/Co0.340680.073900.008640.000020.000010.00001

    Co (#/mL)983.3333333333

    coli (8)

    Date6/23/00Time2:55 PMTime6/23/00 14:55

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.150.0510.0510.051000.0510000.051000

    count509239373316041104033774

    sample volume (mL)0.15110001950

    count72351117

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1000.0546.7780.036.0660.0160.0820.00.1800.00.0740.00.1

    C/Co0.683330.045000.200000.000140.000000.00009

    Co (#/mL)800

    Date6/26/00Time3:20 PMTime6/26/00 15:20

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.50.080.10.0810000.081000.0810

    count4449591762063069360613

    sample volume (mL)0.1210.52000100

    count44470131

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)550387.5737.542.66666666677750787.50.0003333333862.53.6762.50.3090909091

    C/Co0.51955307260.057206703900.00000044690.00482681560.0004144236

    Co (#/mL)745.8333333333

    Date6/27/00Time3:30 PMTime6/27/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.250.080.10.0810000.0810.0810

    count72274519463706535449

    sample volume (mL)0.120.252000100

    count36271103

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)900262.5562.5925750462.50.0003333333812.5355501.0181818182

    C/Co0.40776699030.142912621400.00000051780.0543689320.0015816417

    Co (#/mL)643.75

    Monroe Weber-Shirk 2:Was zero!!! Put 1 here to get reasonable plot

    Date6/28/00Time3:30 PMTime6/28/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.250.050.010.051000.0510.0510

    count44485245564735046545882

    sample volume (mL)0.10.250.00120001

    count45452151

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)880465104018011204454.54545454547000.000476190592052.511608.2

    C/Co0.47938144330.18556701034.59231490160.00000049090.05412371130.0084536082

    Co (#/mL)970

    Monroe Weber-Shirk 2:count was zero, but 1 here to get reasonable plot

    MBD0077BC16.unknown

    MBD04311B1E.unknown

    MBD0430FE9B.unknown

    MBD005149BB.unknown

  • Slow Sand Filtration Predictions

  • How deep must a filter (SSF) be to remove 99.9999% of bacteria?Assume a is 1 and dc is 0.2 mm, V0 = 10 cm/hrpC* is ____z is ________________What does this mean?23 cm for pC* of 66Suggests that the 20 cm deep experimental filter was operating at theoretical limitfor z of 1 mTypical SSF performance is 95% bacteria removal Only about 5 cm of the filters are doing anything!

  • Head Loss Produced by Aluminum

    Chart2

    0.0140.011

    0.020.04

    0.0140.045

    0.0140.099

    0.01750.1255

    0.0250.265

    0.0330.363

    0.0360.461

    0.0330.702

    0.0510.965

    0.096

    0.159

    0.203

    3.9

    20

    Total Al applied

    head loss (m)

    print

    DateTime

    Filter123456

    head loss (cm)

    flow rate (mL/min)

    sectioninoutinoutinoutinoutinoutinout

    est. conc. (#/mL)

    sample volume (mL)000000000000

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)0.00.00.00.00.00.00.00.00.00.00.00.0

    C/Co000000

    const

    start time6/19/005:30 PM6/19/00 17:30

    headloss

    Filter123456mg/m^2

    datetimetimeadjusted timecontrolmed initial dosehigh initial dose3.9201003.9020.00100.00

    6/16/003:30 PM6/16/000.000.010.0120.0150.0140.0110.016000

    20-Jun1:26 PM6/20/000.830.0090.0120.0150.020.040.1043.239166666716.611111111183.0555555556

    20-Jun4:05 PM6/20/000.940.0090.0160.0150.0140.0450.1653.669791666718.819444444594.0972222226

    21-Jun9:05 AM6/21/001.650.0090.0130.0150.0140.0990.8056.432291666732.9861111111164.9305555555

    6/21/003:30 PM6/21/001.920.010.0180.0170.01750.12551.0317.47538.3333333334191.6666666672

    6/22/003:00 PM6/22/002.900.0090.0120.0150.0250.2651.04511.2937557.9166666667289.5833333336

    6/23/007:46 AM6/23/003.590.0090.0130.0160.0330.3630.77514.018333333371.8888888889359.4444444447

    6/23/002:55 PM6/23/003.890.0090.0120.0150.0360.4610.7715.180208333477.8472222223389.2361111117

    6/24/004:21 PM6/24/004.950.0090.0120.0150.0330.7020.82519.31312599.0416666667495.2083333337

    6/25/0011:00 AM6/25/005.730.0090.0130.0150.0510.9650.96822.34375114.5833333334572.9166666672

    6/26/004:23 PM6/26/006.950.0090.0130.0150.0960.96527.1185416667139.0694444445695.3472222223

    6/27/003:30 PM6/27/007.920.0090.0140.0150.1591.09430.875158.3333333334791.6666666672

    6/28/004:15 PM6/28/008.950.0090.0130.0150.20334.896875178.9583333334894.7916666672

    headloss

    0.010.0140.0110.0160.010.030.05-1

    0.0090.020.040.1040.010.030.051

    0.0090.0140.0450.1650.01

    0.0090.0140.0990.8050.01

    0.010.01750.12551.031

    0.0090.0250.2651.045

    0.0090.0330.3630.775

    0.0090.0360.4610.77

    0.0090.0330.7020.825

    0.0090.0510.9650.968

    0.0090.0960.9656.9534722222

    0.0090.1591.0947.9166666667

    0.0090.2038.94791666678.9479166667

    control

    3.9

    20

    100

    4

    20

    100

    end azide

    time (days)

    head loss (m)

    coli sum

    3.9

    20

    Total Al applied

    head loss (m)

    coli

    Filter123456145646/29/00 16:2556/25/00 11:006/20/00 9:006/21/00 15:306/23/00 7:40total Al (mmol/m2)pC*adjusted (pC*-pC*0)

    timecontrolmed initial dosehigh initial dose420100control420100timelow polymer feedtimeend polymertimeend polymertimeend azide00.4582180380

    00.36557059960.60928433270.76595744680.34816247580.34816247580.28433268860.43702873890.4582180380.4582180380.546173208300.0100.030.650.053.6-12.681251.13982387130.6816058333

    0.68750.65559440560.10680228860.07247298160.07247298160.18336476111.13982387131/3/00 10:300.015.730.031.920.053.617.393753.16160439592.7033863579

    1.89583333330.4328859060.08053691280.01510067110.00068927990.000038320.00000183040.36362655383.16160439594.41657469595.73745769891/3/00 22:300.0111.293754.63896441514.1807463771

    2.89583333330.34067796610.07389830510.00864406780.00002296340.00001049750.00001410610.46765595424.63896441514.97891247684.85059399959.950.0115.18020833343.86169730183.4034792638

    3.89236111110.68333333330.0450.20.00013750.00000423730.00009250.16536739373.86169730185.3729120034.033858267326.94791666676.3497630445.891545006

    6.90972222220.51955307260.05720670390.00000044690.00482681560.00041442360.28437008246.3497630442.31633928853.382555557430.8756.28583849685.8276204588

    7.91666666670.40776699030.14291262140.00000051780.0543689320.00158164170.38958793436.28583849681.26464919772.80089190456/23/00 16:00replace leaking tube

    8.91666666670.47938144330.18556701034.59231490160.00000049090.05412371130.00845360820.31931878146.3089910291.26661243092.0729578819

    average50%10%90%

    90%

    AMP (Al) fluxmmol/(m2/day)

    coli

    0.36557059960.34816247580.34816247580.28433268860000

    0.65559440560.07247298160.68750.68750000

    0.4328859060.00068927990.000038320.00000183040

    0.34067796610.00002296340.00001049750.00001410610

    0.68333333330.00013750.00000423730.0000925

    0.51955307260.00000044690.00482681560.0004144236

    0.40776699030.00000051780.0543689320.0015816417

    0.47938144330.00000049090.05412371130.0084536082

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    coli (1)

    0.36557059960.60928433270.7659574468

    0.65559440560.10680228860.0724729816

    0.4328859060.08053691280.0151006711

    0.34067796610.07389830510.0086440678

    0.68333333330.0450.2

    0.51955307260.05720670396.9097222222

    0.40776699030.14291262147.9166666667

    0.47938144330.18556701034.5923149016

    control

    med initial dose

    high initial dose

    time (days)

    coli (2)

    0

    0.6816058333

    2.7033863579

    4.1807463771

    Horizontal bars indicate when CLSE feed was operational for each filter.

    Horizontal bars indicate when polymer feed was operational for each filter.

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    E. coli remaining (pC*)

    0

    0

    0

    0

    0

    0

    0.6458333333

    0

    0.6875

    0.6875

    0.6875

    0.6875

    3.4375

    0

    1.9166666667

    0

    1.8958333333

    1.8958333333

    1.8958333333

    1.8958333333

    3.9375

    2.8958333333

    2.8958333333

    2.8958333333

    2.8958333333

    9.9548611111

    3.8923611111

    3.8923611111

    3.8923611111

    3.8923611111

    6.9097222222

    6.9097222222

    6.9097222222

    6.9097222222

    7.9166666667

    7.9166666667

    7.9166666667

    7.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    0.4370287389

    0.458218038

    0.458218038

    0.5461732083

    0

    0

    0

    0

    0.1833647611

    1.1398238713

    0

    0

    0

    0

    0.3636265538

    3.1616043959

    4.4165746959

    5.7374576989

    0

    0.4676559542

    4.6389644151

    4.9789124768

    4.8505939995

    0

    0.1653673937

    3.8616973018

    5.372912003

    4.0338582673

    0.2843700824

    6.349763044

    2.3163392885

    3.3825555574

    0.3895879343

    6.2858384968

    1.2646491977

    2.8008919045

    0.3193187814

    6.308991029

    1.2666124309

    2.0729578819

    adjusted (pC*-pC*0)

    Total Al (mmol/m2)

    E. coli remaining (pC*-pC*clean sand)

    coli (3)

    DateTimeTime12/31/99 0:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)000000000000

    C/Co000000

    Co (#/mL)0

    coli (4)

    Date6/16/00Time3:30 PMTime6/16/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.020

    count93.035.090.062.082.058.074.027.088.023.090.019.0

    sample volume (mL)0.0200.0200.0200.0200.0200.020

    count28.043.074.033.037.030.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)4650.01575.04500.02625.04100.03300.03700.01500.04400.01500.04500.01225.0

    C/Co0.365570.609280.765960.348160.348160.28433

    Co (#/mL)4308.3333333333

    coli (5)

    Date6/20/00Time10:00 AMTime6/20/00 10:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0400.0800.0400.0800.0400.0800.0400.0800.0400.0800.0400.080

    count60.067.053.016.041.05.044.07.050.00.038.00.0

    sample volume (mL)0.0800.8000.8000.8000.8000.800

    count58.096.071.069.00.00.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1500.0781.31325.0127.31025.086.41100.086.41250.00.0950.00.0

    C/Co0.655590.106800.072470.072470.000000.00000

    Co (#/mL)1191.6666666667

    coli (6)

    Date6/21/00Time3:00 PMTime6/21/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.100.050.500.050.800.051.000.05100.000.05100.00

    count64.048.052.040.058.012.051.01.056.03.017.00.0

    sample volume (mL)0.1000.80010.00010001000

    count38.012.08.044.02.0

    sample volume (mL)100.02000.0

    count67.071.0

    sample volume (mL)

    count

    measured conc. (#/mL)1280.0430.01040.080.01160.015.01020.00.71120.00.0340.00.0

    C/Co0.432890.080540.015100.000690.000040.0000018

    Co (#/mL)993.3333333333

    coli (7)

    Date6/22/00Time3:00 PMTime6/22/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.50.0510.051000.051000.05100

    count5739503450105211441423

    sample volume (mL)0.111100010001000

    count28757591114

    sample volume (mL)200020002000

    count2026

    sample volume (mL)

    count

    measured conc. (#/mL)1140.0335.01000.072.71000.08.51040.00.0880.00.0840.00.0

    C/Co0.340680.073900.008640.000020.000010.00001

    Co (#/mL)983.3333333333

    coli (8)

    Date6/23/00Time2:55 PMTime6/23/00 14:55

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.150.0510.0510.051000.0510000.051000

    count509239373316041104033774

    sample volume (mL)0.15110001950

    count72351117

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1000.0546.7780.036.0660.0160.0820.00.1800.00.0740.00.1

    C/Co0.683330.045000.200000.000140.000000.00009

    Co (#/mL)800

    Date6/26/00Time3:20 PMTime6/26/00 15:20

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.50.080.10.0810000.081000.0810

    count4449591762063069360613

    sample volume (mL)0.1210.52000100

    count44470131

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)550387.5737.542.66666666677750787.50.0003333333862.53.6762.50.3090909091

    C/Co0.51955307260.057206703900.00000044690.00482681560.0004144236

    Co (#/mL)745.8333333333

    Date6/27/00Time3:30 PMTime6/27/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.250.080.10.0810000.0810.0810

    count72274519463706535449

    sample volume (mL)0.120.252000100

    count36271103

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)900262.5562.5925750462.50.0003333333812.5355501.0181818182

    C/Co0.40776699030.142912621400.00000051780.0543689320.0015816417

    Co (#/mL)643.75

    Monroe Weber-Shirk 2:Was zero!!! Put 1 here to get reasonable plot

    Date6/28/00Time3:30 PMTime6/28/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.250.050.010.051000.0510.0510

    count44485245564735046545882

    sample volume (mL)0.10.250.00120001

    count45452151

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)880465104018011204454.54545454547000.000476190592052.511608.2

    C/Co0.47938144330.18556701034.59231490160.00000049090.05412371130.0084536082

    Co (#/mL)970

    Monroe Weber-Shirk 2:count was zero, but 1 here to get reasonable plot

    MBD0430FE9B.unknown

    MBD04311B1E.unknown

    MBD005149BB.unknown

    MBD0077BC16.unknown

  • Aluminum feed methodsAlum must be dissolved until it is blended with the main filter feed above the filter columnAlum flocs are ineffective at enhancing filter performanceThe diffusion dilemma (alum microflocs will diffuse efficiently and be removed at the top of the filter)

  • Performance Deterioration after Al feed stops?HypothesesDecays with timeSites are used upWashes out of filterResearch resultsNot yet clear which mechanism is responsible further testing required

    Chart1

    0.43702873890.4582180380.4582180380.54617320830.010.030.05-1

    0.18336476111.13982387130.68750.68750.010.030.051

    0.36362655383.16160439594.41657469595.73745769890.01

    0.46765595424.63896441514.97891247684.85059399950.01

    0.16536739373.86169730185.3729120034.0338582673

    0.28437008246.3497630442.31633928853.3825555574

    0.38958793436.28583849681.26464919772.8008919045

    0.31931878146.3089910291.26661243092.0729578819

    Horizontal bars indicate when polymer feed was operational for each filter.

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    E. coli remaining (pC*)

    print

    DateTime

    Filter123456

    head loss (cm)

    flow rate (mL/min)

    sectioninoutinoutinoutinoutinoutinout

    est. conc. (#/mL)

    sample volume (mL)000000000000

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)0.00.00.00.00.00.00.00.00.00.00.00.0

    C/Co000000

    const

    start time6/19/005:30 PM6/19/00 17:30

    headloss

    Filter123456mg/m^2

    datetimetimeadjusted timecontrolmed initial dosehigh initial dose3.9201003.9020.00100.00

    6/16/003:30 PM6/16/000.000.010.0120.0150.0140.0110.016000

    20-Jun1:26 PM6/20/000.830.0090.0120.0150.020.040.1043.239166666716.611111111183.0555555556

    20-Jun4:05 PM6/20/000.940.0090.0160.0150.0140.0450.1653.669791666718.819444444594.0972222226

    21-Jun9:05 AM6/21/001.650.0090.0130.0150.0140.0990.8056.432291666732.9861111111164.9305555555

    6/21/003:30 PM6/21/001.920.010.0180.0170.01750.12551.0317.47538.3333333334191.6666666672

    6/22/003:00 PM6/22/002.900.0090.0120.0150.0250.2651.04511.2937557.9166666667289.5833333336

    6/23/007:46 AM6/23/003.590.0090.0130.0160.0330.3630.77514.018333333371.8888888889359.4444444447

    6/23/002:55 PM6/23/003.890.0090.0120.0150.0360.4610.7715.180208333477.8472222223389.2361111117

    6/24/004:21 PM6/24/004.950.0090.0120.0150.0330.7020.82519.31312599.0416666667495.2083333337

    6/25/0011:00 AM6/25/005.730.0090.0130.0150.0510.9650.96822.34375114.5833333334572.9166666672

    6/26/004:23 PM6/26/006.950.0090.0130.0150.0960.96527.1185416667139.0694444445695.3472222223

    6/27/003:30 PM6/27/007.920.0090.0140.0150.1591.09430.875158.3333333334791.6666666672

    6/28/004:15 PM6/28/008.950.0090.0130.0150.20334.896875178.9583333334894.7916666672

    headloss

    00000.010.030.05-1

    00000.010.030.051

    00000.01

    00000.01

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    0000

    control

    3.9

    20

    100

    4

    20

    100

    end azide

    time (days)

    head loss (m)

    coli sum

    00

    00

    00

    00

    00

    00

    00

    00

    00

    00

    0

    0

    0

    3.9

    20

    Total Al applied

    head loss (m)

    coli

    Filter123456145646/29/00 16:2556/25/00 11:006/20/00 9:006/21/00 15:306/23/00 7:40total Al (mmol/m2)pC*adjusted (pC*-pC*0)

    timecontrolmed initial dosehigh initial dose420100control420100timelow polymer feedtimeend polymertimeend polymertimeend azide00.4582180380

    00.36557059960.60928433270.76595744680.34816247580.34816247580.28433268860.43702873890.4582180380.4582180380.546173208300.0100.030.650.053.6-12.681251.13982387130.6816058333

    0.68750.65559440560.10680228860.07247298160.07247298160.18336476111.13982387131/3/00 10:300.015.730.031.920.053.617.393753.16160439592.7033863579

    1.89583333330.4328859060.08053691280.01510067110.00068927990.000038320.00000183040.36362655383.16160439594.41657469595.73745769891/3/00 22:300.0111.293754.63896441514.1807463771

    2.89583333330.34067796610.07389830510.00864406780.00002296340.00001049750.00001410610.46765595424.63896441514.97891247684.85059399959.950.0115.18020833343.86169730183.4034792638

    3.89236111110.68333333330.0450.20.00013750.00000423730.00009250.16536739373.86169730185.3729120034.033858267326.94791666676.3497630445.891545006

    6.90972222220.51955307260.05720670390.00000044690.00482681560.00041442360.28437008246.3497630442.31633928853.382555557430.8756.28583849685.8276204588

    7.91666666670.40776699030.14291262140.00000051780.0543689320.00158164170.38958793436.28583849681.26464919772.80089190456/23/00 16:00replace leaking tube

    8.91666666670.47938144330.18556701034.59231490160.00000049090.05412371130.00845360820.31931878146.3089910291.26661243092.0729578819

    average50%10%90%

    90%

    AMP (Al) fluxmmol/(m2/day)

    coli

    0.36557059960.34816247580.34816247580.28433268860000

    0.65559440560.07247298160.68750.68750000

    0.4328859060.00068927990.000038320.00000183040

    0.34067796610.00002296340.00001049750.00001410610

    0.68333333330.00013750.00000423730.0000925

    0.51955307260.00000044690.00482681560.0004144236

    0.40776699030.00000051780.0543689320.0015816417

    0.47938144330.00000049090.05412371130.0084536082

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    coli (1)

    0.36557059960.60928433270.7659574468

    0.65559440560.10680228860.0724729816

    0.4328859060.08053691280.0151006711

    0.34067796610.07389830510.0086440678

    0.68333333330.0450.2

    0.51955307260.05720670396.9097222222

    0.40776699030.14291262147.9166666667

    0.47938144330.18556701034.5923149016

    control

    med initial dose

    high initial dose

    time (days)

    coli (2)

    0

    0.6816058333

    2.7033863579

    4.1807463771

    Horizontal bars indicate when CLSE feed was operational for each filter.

    Horizontal bars indicate when polymer feed was operational for each filter.

    control

    4

    20

    100

    low polymer feed

    end polymer

    end polymer

    end azide

    time (days)

    E. coli remaining (pC*)

    0

    0

    0

    0

    0

    0

    0.6458333333

    0

    0.6875

    0.6875

    0.6875

    0.6875

    3.4375

    0

    1.9166666667

    0

    1.8958333333

    1.8958333333

    1.8958333333

    1.8958333333

    3.9375

    2.8958333333

    2.8958333333

    2.8958333333

    2.8958333333

    9.9548611111

    3.8923611111

    3.8923611111

    3.8923611111

    3.8923611111

    6.9097222222

    6.9097222222

    6.9097222222

    6.9097222222

    7.9166666667

    7.9166666667

    7.9166666667

    7.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    8.9166666667

    0.4370287389

    0.458218038

    0.458218038

    0.5461732083

    0

    0

    0

    0

    0.1833647611

    1.1398238713

    0

    0

    0

    0

    0.3636265538

    3.1616043959

    4.4165746959

    5.7374576989

    0

    0.4676559542

    4.6389644151

    4.9789124768

    4.8505939995

    0

    0.1653673937

    3.8616973018

    5.372912003

    4.0338582673

    0.2843700824

    6.349763044

    2.3163392885

    3.3825555574

    0.3895879343

    6.2858384968

    1.2646491977

    2.8008919045

    0.3193187814

    6.308991029

    1.2666124309

    2.0729578819

    adjusted (pC*-pC*0)

    Total Al (mmol/m2)

    E. coli remaining (pC*-pC*clean sand)

    coli (3)

    DateTimeTime12/31/99 0:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)000000000000

    C/Co000000

    Co (#/mL)0

    coli (4)

    Date6/16/00Time3:30 PMTime6/16/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.0200.020

    count93.035.090.062.082.058.074.027.088.023.090.019.0

    sample volume (mL)0.0200.0200.0200.0200.0200.020

    count28.043.074.033.037.030.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)4650.01575.04500.02625.04100.03300.03700.01500.04400.01500.04500.01225.0

    C/Co0.365570.609280.765960.348160.348160.28433

    Co (#/mL)4308.3333333333

    coli (5)

    Date6/20/00Time10:00 AMTime6/20/00 10:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.0400.0800.0400.0800.0400.0800.0400.0800.0400.0800.0400.080

    count60.067.053.016.041.05.044.07.050.00.038.00.0

    sample volume (mL)0.0800.8000.8000.8000.8000.800

    count58.096.071.069.00.00.0

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1500.0781.31325.0127.31025.086.41100.086.41250.00.0950.00.0

    C/Co0.655590.106800.072470.072470.000000.00000

    Co (#/mL)1191.6666666667

    coli (6)

    Date6/21/00Time3:00 PMTime6/21/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.100.050.500.050.800.051.000.05100.000.05100.00

    count64.048.052.040.058.012.051.01.056.03.017.00.0

    sample volume (mL)0.1000.80010.00010001000

    count38.012.08.044.02.0

    sample volume (mL)100.02000.0

    count67.071.0

    sample volume (mL)

    count

    measured conc. (#/mL)1280.0430.01040.080.01160.015.01020.00.71120.00.0340.00.0

    C/Co0.432890.080540.015100.000690.000040.0000018

    Co (#/mL)993.3333333333

    coli (7)

    Date6/22/00Time3:00 PMTime6/22/00 15:00

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.50.0510.051000.051000.05100

    count5739503450105211441423

    sample volume (mL)0.111100010001000

    count28757591114

    sample volume (mL)200020002000

    count2026

    sample volume (mL)

    count

    measured conc. (#/mL)1140.0335.01000.072.71000.08.51040.00.0880.00.0840.00.0

    C/Co0.340680.073900.008640.000020.000010.00001

    Co (#/mL)983.3333333333

    coli (8)

    Date6/23/00Time2:55 PMTime6/23/00 14:55

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.150.0510.0510.051000.0510000.051000

    count509239373316041104033774

    sample volume (mL)0.15110001950

    count72351117

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)1000.0546.7780.036.0660.0160.0820.00.1800.00.0740.00.1

    C/Co0.683330.045000.200000.000140.000000.00009

    Co (#/mL)800

    Date6/26/00Time3:20 PMTime6/26/00 15:20

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.50.080.10.0810000.081000.0810

    count4449591762063069360613

    sample volume (mL)0.1210.52000100

    count44470131

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)550387.5737.542.66666666677750787.50.0003333333862.53.6762.50.3090909091

    C/Co0.51955307260.057206703900.00000044690.00482681560.0004144236

    Co (#/mL)745.8333333333

    Date6/27/00Time3:30 PMTime6/27/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.080.120.080.250.080.10.0810000.0810.0810

    count72274519463706535449

    sample volume (mL)0.120.252000100

    count36271103

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)900262.5562.5925750462.50.0003333333812.5355501.0181818182

    C/Co0.40776699030.142912621400.00000051780.0543689320.0015816417

    Co (#/mL)643.75

    Monroe Weber-Shirk 2:Was zero!!! Put 1 here to get reasonable plot

    Date6/28/00Time3:30 PMTime6/28/00 15:30

    Filter123456

    sectioninoutinoutinoutinoutinoutinout

    sample volume (mL)0.050.10.050.250.050.010.051000.0510.0510

    count44485245564735046545882

    sample volume (mL)0.10.250.00120001

    count45452151

    sample volume (mL)

    count

    sample volume (mL)

    count

    measured conc. (#/mL)880465104018011204454.54545454547000.000476190592052.511608.2

    C/Co0.47938144330.18556701034.59231490160.00000049090.05412371130.0084536082

    Co (#/mL)970

    Monroe Weber-Shirk 2:count was zero, but 1 here to get reasonable plot

    MBD0077BC16.unknown

    MBD04311B1E.unknown

    MBD0430FE9B.unknown

    MBD005149BB.unknown

  • Sticky Media vs. Sticky ParticlesSticky MediaPotentially treat filter media at the beginning of each filter runNo need to add coagulants to water for low turbidity watersFilter will capture particles much more efficiently

    Sticky ParticlesEasier to add coagulant to water than to coat the filter media

  • The BioSand Filter CrazePatented new idea of slow sand filtration without flow control and called it BioSandFilters are being installed around the world as Point of Use treatment devicesCost is somewhere between $25 and $150 per household ($13/person based on project near Copan Ruins, Honduras)The per person cost is comparable to the cost to build centralized treatment using the AguaClara model

  • BioSand Performance

  • BioSand PerformancePore volume is 18 LitersVolume of a bucket is ____________Highly variable field performance even after initial ripening periodhttp://www.iwaponline.com/wst/05403/0001/054030001.pdfField tests on 8 NTU water in the DR

  • Field Performance of BioSand Table 2 pH, turbidity and E. coli levels in raw and BSF filter waters in the fieldParameter rawfilteredMean pH (n =47)7.48.0Mean turbidity (NTU) (n=47)8.11.3Mean log10 E. coli MPN/100mL (n=55)1.70.6http://www.iwaponline.com/wst/05403/0001/054030001.pdf

  • Potters for Peace PotsColloidal silver-enhanced ceramic water purifier (CWP)After firing the filter is coated with colloidal silver. This combination of fine pore size, and the bactericidal properties of colloidal silver produce an effective filterFilter units are sold for about $10-15 with the basic plastic receptacleReplacement filter elements cost about $4.00What is the turbidity range that these filters can handle?How do you wash the filter? What water do you use?

  • Horizontal Roughing Filters1m/hr filtration rate (through 5+ m of media)Usage of HRFs for large schemes has been limited due to high capital cost and operational problems in cleaning the filters.Equivalent surface loading = 10 m/day

  • Roughing FiltersFiltration through roughing gravity filters at low filtration rates (12-48 m/day) produces water with low particulate concentrations, which allow for further treatment in slow sand filters without the danger of solids overload. In large-scale horizontal-flow filter plants, the large pores enable particles to be most efficiently transported downward, although particle transport causes part of the agglomerated solids to move down towards the filter bottom. Thus, the pore space at the bottom starts to act as a sludge storage basin, and the roughing filters need to be drained periodically. Further development of drainage methods is needed to improve efficiency in this area.

  • Roughing FiltersRoughing filters remove particulate of colloidal size without addition of flocculants, large solids storage capacity at low head loss, and a simple technology. But there are only 11 articles on the topic listed in

    (see articles per year)

    They have not devised a cleaning method that works

    Size comparison to floc/sed systems?

  • Multistage FiltrationThe Other low tech option for communities using surface watersUses no coagulantsGravel roughing filtersPolished with slow sand filtersLarge capital costs for constructionNo chemical costsLabor intensive operationWhat is the tank area of a multistage filtration plant in comparison with an AguaClara plant?

  • ConclusionsMany different filtration technologies are available, especially for POUFilters are well suited for taking clean water and making it cleaner. They are not able to treat very turbid surface watersPretreat using flocculation/sedimentation (AguaClara) or roughing filters (high capital cost and maintenance problems)

  • ConclusionsFilters could remove particles more efficiently if the _________ efficiency were increasedSSF remove particles by two mechanisms__________________________________________________Completely at the mercy of the raw water!We need to learn what is required to make ALL of the filter media sticky in SSF and in RSF

    PredationSticky aluminum polymer that coats the sandattachment

  • ReferencesTufenkji, N. and M. Elimelech (2004). "Correlation equation for predicting single-collector efficiency in physicochemical filtration in saturated porous media." Environmental-Science-and-Technology 38(2): 529-536.Cushing, R. S. and D. F. Lawler (1998). "Depth Filtration: Fundamental Investigation through Three-Dimensional Trajectory Analysis." Environmental Science and Technology 32(23): 3793 -3801.Tobiason, J. E. and C. R. O'Melia (1988). "Physicochemical Aspects of Particle Removal in Depth Filtration." Journal American Water Works Association 80(12): 54-64.Yao, K.-M., M. T. Habibian, et al. (1971). "Water and Waste Water Filtration: Concepts and Applications." Environmental Science and Technology 5(11): 1105.M.A. Elliott*, C.E. Stauber, F. Koksal, K.R. Liang, D.K. Huslage, F.A. DiGiano, M.D. Sobsey. (2006) The operation, flow conditions and microbial reductions of an intermittently operated, household-scale slow sand filter

  • Contact Points

  • Polymer Accumulation in a Pore

    ******http://www.lenntech.com/cartridgefilter-bagfilter.htmhttp://www.nesc.wvu.edu/ndwc/pdf/OT/TB/OT_TB_su01.pdf on DE filters*Iwasaki, T. (1937). "Some Notes on Sand Filtration." Journal American Water Works Association 29: 1591.*************Yao, K.-M., M. T. Habibian, et al. (1971). "Water and Waste Water Filtration: Concepts and Applications." Environmental Science and Technology 5(11): 1105.*******Interception is very importantLousy at removing pathogens if they havent been flocculatedA 0.1mm particle has a pC* of 100!!!!!!!!!!Either particles havent been flocculated or attachment is poor****************The operation, flow conditions and microbial reductions of an intermittently operated, household-scale slow sand filter M.A. Elliott*, C.E. Stauber, F. Koksal, K.R. Liang, D.K. Huslage, F.A. DiGiano, M.D. Sobsey. *University of North Carolina, CB 7431, Chapel Hill, NC, 27514, USA.

    Long ripening periodAfter pore volume is flushed has poor performance*http://www.iwaponline.com/wst/05403/0001/054030001.pdf***http://wedc.lboro.ac.uk/conferences/pdfs/22/Jayalat.pdfGravity roughing filter for pre-treatmentJ.M.J.C. Jayalath and J.P. Padmasiri, Sri Lanka

    Picture from http://diglib.tums.ac.ir/pub/magmng/pdf/483.pdf

    http://www.wrc.org.za/downloads/watersa/2006/Jan%2006/1728.pdf for filtration rate*Filter Mechanisms in Roughing Filters Boller, M Aqua AQUAAA, Vol. 42, No. 3, p 174-185, June 1993. 17 fig, 1 tab, 13 ref. *Filter Mechanisms in Roughing Filters Boller, M Aqua AQUAAA, Vol. 42, No. 3, p 174-185, June 1993. 17 fig, 1 tab, 13 ref. *http://www.atypon-link.com/TELF/doi/pdf/10.1680/wama.157.3.143.46664*****


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