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FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place of Synthetic Organic Dyes) SYNTHETIC ORGANICS CHEMICALSCategory: 5(f) Of Located at: Plot No. C-1 B / 68, 100 Shed Area, G.I.D.C. Estate, Vapi- 396195. Dist.: Valsad (Gujarat)
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Page 1: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

FOR

THE PROPOSED CHANGE IN PRODUCT PROFILE

(Manufacturing of Organic Titanates in place of

Synthetic Organic Dyes)

“SYNTHETIC ORGANICS CHEMICALS”

Category: 5(f)

Of

Located at:

Plot No. C-1 B / 68, 100 Shed Area, G.I.D.C. Estate,

Vapi- 396195. Dist.: Valsad (Gujarat)

Page 2: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 2 Manufacturing : Synthetic Organic Chemicals

1. EXECUTIVE SUMMARY

Name of the Project: M/s. Skyline Polycat Pvt. Ltd.

(Formerly known as M/s. Ambica Polychem)

Location: Plot No. C-1 B/68 , 100 Shed Area, G.I.D.C Estate, Vapi- 396195. Dist:Valsad

(Gujarat)

Project

M/s. Skyline Polycats Pvt. Ltd.(previously known as Ambica Polichem) is and existing unit at Plot No. C-1

B/68, 100 Shed Area, G.I.D.C Estate, Vapi- 396195. Dist:Valsad, Gujarat since 1998.

The unit is manufacturing Synthetic Organic Chemicals (i.e. Synthetic Organic Dyes) @ 1.6 TPM.

The unit is having Consolidated Consent and Authorization under The water Act, The Air Act and The

Hazardous wastes Rules from Gujarat Pollution Control Board.

Due to non viability of manufacturing existing product the company decided to discontinue the same

and propose to manufacture new product as Organic Titanates @ 400 TPM with required installation of

additional plant and machinery in the existing infrastructure.

The project for manufacturing Organic Titanets covered under the category 5 (f) “Synthetic Organic

Chemicals” as per EIA notifications 2006.

Total Project Cost: Rs. 5.00 Crore

Applicability of EIA notification – 2006

As per the EIA notification- 2006 as amended: proposed products are covered under the Category-5(f)–

“Synthetic Organic Chemicals”.

Manufacturing of “Synthetic Organic Chemicals” for the unit located within the notified industrial area is

covered under Category –B, but due to the applicability of General Conditions this project is categorized

as Category-A and applied to MoEF for obtaining Environmental Clearance.

Project Proponent

Indian Private Limited Firm comprising 2 directors

Small Scale Unit

LIST OF FINISHED PRODUCTS (Existing, Proposed and Total)

Sr. No.

Products Name Production Capacity (TPM)

Existing Proposed Total

1. Synthetic Organic Dyes (i.e. (Dark Red 2 B, Navy Blue 3G, Yellow 7 GL)

1.60 -1.60 0.00

2. Organic Titanates i) Tetra isopropyl Titanate (TiPT), ii) Tetra n-Butyl Titanate (TnBT) iii) Tetra Ethyl Titanate (TET)

0.00 200.00 200.00

3. TiPT Derivatives 0.00 200.00 200.00

4. Ammonium Chloride as By product during manufacturing of Organic Titanets

0.00 155.00 155.00

Page 3: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 3 Manufacturing : Synthetic Organic Chemicals

Resource Requirement

Raw material Consumption

Sr.

No.

Name of the product Raw Materials RM

Consumption

(MT/Month)

01. Organic Titanates

i) Tetra isopropyl Titanate (TiPT)

ii) Tetra n-Butyl Titanate (TnBT)

iii) Tetra Ethyl Titanate (TET)

Titanium tetra Chloride 138.00

Isopropyl alcohol 57.00

N-Butyl alcohol 58.00

Ethyl alcohol 54.00

Ammonia 50.00

02 Tetra isopropyl Titanate (TiPT) Derivatives Acetylacetone 10.00

Denatured Alcohol 16.00

Phosphate Ester 16.00

Triethanolamine 4.00

Ethylacetoacetate 8.00

Isopropylamine 4.00

Monoethylene Glycol 4.00

Diethylene Glycol 4.00

2Ethyl Hexyl Alcohol 9.00

Iso-octyl Alcohol 9.00

n-Hexane 16.00

Utilities

Components Proposed Resources availability

Power 200 KVA Will be sourced from Dakshin Gujarat Vij Co. Ltd.

Fresh Water 6.00 KL/day Will be sourced from GIDC water supply dept.

Fuel Natural Gas / LDO for Thermic Fluid heater

1.50 KL/Day (Thermopack -2Nos. 2 LAKH K. CAL/HR. )will be installed (LDO/GAS)

Fuel (HSD) for D.G.Set 50 lit/Hr. Will be sourced from Local dealer

Water and Waste Water Management

Total Fresh Water requirement is 6.0 KL/day & Water supply will be met from GIDC water supply dept.

There is no generation of industrial Waste Water.

Domestic waste water (2.0 KL/day) will be disposed off through Septic Tank.

Air Emission and its Control Measures

The company proposes to install two no. of Thermic Fluid Heaters having capacity 2 Lac K.Cal/Hr. each

and Natural Gas/ LDO is used as fuel. Adequate stack height and stack monitoring facilities will be

provided as per rule.

The company shall install 125 KVA capacity of D.G. Set, as stand by. It will be used only during power

failure. Adequate stack height and stack monitoring facilities will be provided as per rule.

The scrubber will be provided as APCD to control the fugitive & process emission causing pollution of

work place air. The main pollutants of the scrubber will be ammonia and hydrochloric acid.

Page 4: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 4 Manufacturing : Synthetic Organic Chemicals

Hazardous Wastes and its Management

Types of Waste

& Category

Source of

Generation

Quantity

(Proposed) Storage Method Method of Disposal

Used oil (5.1)

From plant

and

machineries

10 L/Month Will be stored in drums

Will be sold to registered refiners/ sent to TSDF site

Empty drums (33.3)

Raw material

consumed 25 Nos/Month Will be stored at a separate storage area

Will be reused for packing /sold to authorized scrap vendor

Spent Solvent (20.2)

From process If generated

Will be stored in storage tank

Will be sold out to its recyclers

Distillation Residue (20.3)

From process If generated

Will be stored in storage tank

To TSDF

Hazardous Raw Materials as Per MSIHC Rules

Sr. No.

Name of the Products

Storage Details Max Storage

Quantity

Threshold Quantity

MT

MSIHC/ MAH*

Applicability Type

Nos. Size Condition

1. Ammonia Cylinder 5 2KL Ambient 10 KL 50 Yes

2. Ethanol MS Tank 1 10 KL Ambient 10 KL 1500 Yes

3. Hexane MS Tank 1 10 KL Ambient 10 KL 1500 Yes

4. n-Butyl Alcohol MS Tank 1 10 KL Ambient 10 KL 2500 Yes

5. TiCl4 MS Tank 2 5 KL Ambient 10 KL NA Yes

6. Iso Propyl Alcohol MS Tank 1 10 KL Ambient 10 KL 1500/10000 Yes

7. Acetylacetone Drum 10 200 Lit Ambient 2.0 KL 2500/20000 Yes

8. Phosphate Ester Drum 5 200 Lit Ambient 1 KL NA No Info.

9. Triethanolamine Drum 5 200 Lit Ambient 1 KL 1000/5000 Yes

10. Ethylacetoacetate Drum 2 200 Lit Ambient 0.4 KL NA No Info.

11. Isopropylamine Drum 2 200 Lit Ambient 0.4 KL 1000/5000 Yes

12. Monoethylene Glycol Drum 2 200 Lit Ambient 0.4 KL NA Yes

13. Diethylene Glycol Drum 1 200 Lit Ambient 0.2 KL NA Yes

14. 2Ethyl Hexyl Alcohol Drum 5 200 Lit Ambient 1 KL NA Yes

15. Iso-octyl Alcohol Drum 5 200 Lit Ambient 1 KL NA No Info.

Note: Threshold Quantity as per Sch-2&3 of MSIHC Rules

Page 5: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 5 Manufacturing : Synthetic Organic Chemicals

2. INTRODUCTION

(i) Identification of Project and proponent.

(ii) Name of the project Proponent: M/s. Skyline Polycats Pvt. Ltd.

M/s. Skyline polycats Pvt. Ltd. located at Plot No. C-1 B / 68, 100 Shed Area, G.I.D.C. Estate, Vapi-

396195. Dist.: Valsad (Gujarat). is manufacturing “Synthetic Organic Dyes” which is used in the process

of Dyeing of fabrics and home furnishings products.

Due to non viability of manufacturing existing product the company decided to discontinue the same

and propose to manufacture new product as Organic Titanates @ 400 TPM with required installation

of additional plant and machinery in the existing infrastructure.

The company has been promoted by two Directors. Details related to them are given below:

Sr. No. Name of Directors Residential Address

1. Shri Kailash S. Patil 104, H-II, Matoshree Bungalow,

Chanod Colony, GIDC,

Vapi – 396 195.

Dist. Valsad (Gujarat).

2. Smt. Sandhya K. Patil 104, H-II, Matoshree Bungalow,

Chanod Colony, GIDC,

Vapi – 396 195.

Dist. Valsad (Gujarat).

(iii) Brief description of nature of the Project

M/s. Skyline Polycats Pvt. Ltd. proposes the expansion of their production by addition of new products

at Plot No. C-1 B / 68, 100 Shed Area, G.I.D.C. Estate, Vapi-396195. Dist.: Valsad (Gujarat).

The proposed expansion project involves the production of “Organic Titanates” which are Synthetic

Organic Chemicals, For the proposed expansion project, the company intends to procure the available

latest technology for manufacturing the products listed in under mentioned table.

The industrial sector in the past years has seen a drastic boom and also the keeping in mind the

globalization trend, we have identified the demand for the proposed products and with continuous R

& D found that it can be developed in-house and produce commercially for domestic market as well as

an eye more on export markets.

As per the EIA notification‐ 2006 as amended the proposed expansion project involves the production

of “Organic Titanates” which falls under item no. “5(f) – Synthetics organic Chemicals industries as

per the EIA notification- 2006, hence required Prior Environmental Clearance.

(iv) Need for the project and its importance to the country and or region

The proposed project will provide a potential growth opportunity for the already running business of

the company. The industrial sector in the past years has seen a drastic boom and also the keeping in

mind the globalization trend, we have identified the demand for the proposed products and it can be

developed in-house and produce commercially for domestic market as well as an eye more on export

markets. Its export and also increase the foreign revenue. The products are now well established and

acceptable in the international markets.

Page 6: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 6 Manufacturing : Synthetic Organic Chemicals

(v) Demand –Supply Gap

The products have very high demand for used as modifiers for plastics, metals, glass, coating materials,

etc., and as catalysts for chemical reactions.

(vi) Imports vs. Indigenous production

Proposed products manufacturing in the country will be very much economical compare to Imports of

the same and also the export of the same will earn extra revenue generation for our county.

(vii) Export Possibility / Domestic / export Markets

There is a huge demand of Organic Titanets compounds in the export market. Our products are

widely used and are in demand in the domestic Chemical industry.

(viii) Employment Generation (Direct and Indirect) due to the project

There will be very good opportunity of employment generation directly and indirectly due to

proposed expansion.

Page 7: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 7 Manufacturing : Synthetic Organic Chemicals

3. PROJECT DISCRIPTION

(i) Type of Project including interlinked and interdependent projects, If any :

The proposed project is interdependent project of the company.

(ii) Location (map showing general location, Specific location, and project boundary & project site

layout) with coordinates:

The map showing general location, specific location and project boundary and project site layout of

M/s.Skyline Polycats Pvt. Ltd. Located at Plot No. C-1 B / 68, 100 Shed Area, G.I.D.C. Estate, Vapi-

396195. Dist.: Valsad (Gujarat).

Fig. 3.1: Location map showing the Project site and inter-state boundary with 10 kms radius

Page 8: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 8 Manufacturing : Synthetic Organic Chemicals

(iii) Profile of Project Site:

Sr. No. Nearest Infrastructure Feature Distance from Project Site

1 Geographical Position Lat.: 20.349245° N, Long.: 72.937579° E

2 Elevation above Sea Level 36 Meters (Approx.)

3 Nearest Village Chanod – 1 Km

4 Nearest Town Vapi – 2.0 Km

5 Nearest National Highway NH-8: 2.0 (Approx.)

6 Nearest State Highway SH#:2.5 (Approx. )

8 Nearer RW Station Vapi- 2.0 (Approx.)

9 Nearest Airport Daman 12 Km NW (Approx.)

Surat 86.5 Km NW (Approx.)

10 Nearest Surface water

Resource/Reservoir

Damanganga River 6 Km S (Approx.)

Madhuban Dam 22 Km SE (Approx.)

11 Forest Land Reserve Forest 8.55 Km W (Approx.)

Protected Forest 12.00 Km NE (Approx.)

12 Location of Archaeologically

/Historically important places

Silvassa 3.0 Km (Approx.)

Daman 12 Km (Approx.)

13 National Park/Sanctuary or

Ecologically sensitive Area Nil

14 National or State Boundary Interstate – UT of D&NH 2.5 Km E (Approx.)

UT of D&D 3.0Km E (Approx.)

15 Tourist Places

Silvassa- 2.5 Km E (Approx.)

Daman- 3.0 Km W (Approx.)

Tithal (Valsad)25.00 Km NW (Approx.)

Plot site Area Statement:

Area Statement Area After Proposed

Expansion (in m2)

Total Area 855.00

Construction Area 450.00

Open Land Area 250.00

Greenbelt Area 155.00

Page 9: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 9 Manufacturing : Synthetic Organic Chemicals

(iv) Site Layout Plan:

Page 10: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 10 Manufacturing : Synthetic Organic Chemicals

(v) Details of alternate sites considered and the basis of selecting the proposed site, particularly

the environmental considerations gone into should be highlighted :

The proposed activity will be accommodated in the existing plot within the GIDC Notified

Industrial area having proper industrial infrastructure hence alternate site consideration is not

envisaged.

(vi) Size or magnitude of operation :

As per the proposed project cost the project is covered under Small Scale category of

manufacturing industries, it comes under SSI.

(vii) Project description with process details (a schematic diagram/ flow chart showing the

project layout components of the project etc. should be given):

Detailed project description with process details –

LIST OF FINISHED PRODUCTS

Sr. No.

Products Name Production Capacity (TPM)

Existing Proposed Total

1. Synthetic Organic Dyes (i.e. (Dark Red 2 B, Navy Blue 3G, Yellow 7 GL)

1.60 -1.60 0.00

2. Organic Titanates i) Tetra isopropyl Titanate (TiPT) ii) Tetra n-Butyl Titanate (TnBT) iii) Tetra Ethyl Titanate (TET)

0.00 200.00 200.00

3. Tetra isopropyl Titanate (TiPT) Derivatives 0.00 200.00 200.00

4. Ammonium Chloride as By product during manufacturing of Organic Titanets

0.00 155.00 155.00

INFRASTRUCTURE, MACHINERIES, EQUIPMENT & TECHNOLOGIES

Within the existing premises with required minor civil work for manufacturing of proposed

products will be done.

Within the existing premises and infrastructure the installation of some additional plant and

machineries will be required.

MANUFACTURING PROCESS

The company is using the latest available process technology for the production. This section

includes the manufacturing process of the product, chemical reactions, and material mass

balance for the product.

01. Product: Tetra isopropyl Titanate (TiPT)

a. Manufacturing Process:

Chilled Titanium Tetra chloride one mole is reacted with 4 mole of isopropyl alcohol at

ambient temperature to form Tetra isopropyl Titanate in a closed reactor. During the

reaction Hydrochloric acid gas is liberated which is reacted with Ammonia gas to form

Ammonium Chloride after the completion of reaction the mass is filtered Ammonium

Chloride crystals are separated out as by product and product is recovered by applying

vacuum distillation to remove free alcohol. Then the product is packed and dispatched.

Page 11: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 11 Manufacturing : Synthetic Organic Chemicals

Molecular Formula: C12H28O4Ti

CAS No. : 546-68-9

Molecular Weight:- 284.26

Raw material norms for 1 MT of Tetra isopropyl Titanate

Titanium Tetra chloride : 670.00 kgs

Isopropyl alcohol : 845.00 kgs

Ammonia : 240.00 kgs

Remark : Ammonium chloride is recovered as by product (753.00 kgs.)

b. Process Flow Diagram

c. Chemical Reaction:

+ 4NH3Ti

Cl

Cl

Cl

Cl C

CH3

OHH

CH3

+4 + 4NH4Cl

Titanium Tetra chloride Isopropyl alcohol Tetra Isopropyl titanate Ammonium Chloride

C

CH3

H)4(O

CH3

Ti+

Ammonia

02. Product: Tetra n-Butyl Titanate (TnBT)

a. Manufacturing Process:

Chilled Titanium Tetra chloride one mole is reacted with 4 mole of n-Butyl alcohol at ambient

Product: Tetra isopropyl Titanate (TiPT)

Packing & Dispatch

Raw Material:

Titanium Tetra chloride

REACTOR

By-product:

Ammonium chloride

Raw Material:

Ammonia

MIXER

FILTRATION

VACUUM DISTILLATION

Recovered back to process:

Iso Propyl Alcohol & Hexane

CHILLER

Raw Material:

Iso Propyl Alcohol, Solvent Hexane

Page 12: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 12 Manufacturing : Synthetic Organic Chemicals

temperature to form Tetra n-Butyle Titanate in a closed reactor. During the reaction chloride

is liberated which is reacted with Ammonia gas to form Ammonium Chloride after the

completion of reaction the mass is filtered, Ammonium Chloride crystals are separated out as

by product and product is recovered by applying vacuum to remove free n-butyl alcohol if

any. Then the product is packed and dispatched.

Chemical Formula: Ti(OC4H9)4

Molecular Formula: C16H36O4Ti

CAS No. : 5593-70-4

Molecular Weight:- 340.34

Raw material norms for 1 MT of Tetra n-Butyl Titanate

Titanium Tetra chloride : 560.00 kgs

N-Butyl alcohol : 870.00 kgs

Ammonia : 200.00 kgs

Remark : Ammonium chloride is recovered as by product (629.00 kgs.)

b. Process Flow Diagram

c. Chemical Reaction:

Ti

Cl

Cl

Cl

Cl 4 (CH3 -CH2

-CH2 CH2 - OH)+ 4NH3 Ti (O - CH 2 - CH2 - CH2 - CH3) 4 + 4NH4Cl

Titanium

Tetra Chloride

n -ButyI

Alcohol

Ammonia Tetra n-Butyl titanateAmmonium Chloride

+

Product: Tetra n-Butyl Titanate (TnBT)

Packing & Dispatch

Raw Material:

n-Butyl Alcohol, Solvent Hexane

REACTOR

By-product:

Ammonium chloride

Raw Material:

Ammonia

MIXER

FILTRATION

VACUUM DISTILLATION

Recovered back to process:

n-Butyl Alcohol & Hexane

Raw Material:

Titanium Tetra chloride CHILLER

Page 13: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 13 Manufacturing : Synthetic Organic Chemicals

03. Product: Tetra Ethyl Titanate (TET)

a. Manufacturing Process:

Chilled 4 mole of Ethyl Alcohol is reacted with one mole of Titanium Tetra chloride at

ambient temperature to form Tetra Ethyl Titanate in a closed reactor.Hexane is used as

solvent medium. During the reaction Hydrochloric acid gas is liberated which is reacted with

anhydrous Ammonia gas to form Ammonium Chloride.After completion of reaction the

mass is filtered and Ammonium Chloride crystals are separated out as by-product and

product is passed through vacuum distillation to separate Hexane. Recovered Hexane is

reused back in process. Then product is packed and dispatched.

Chemical Formula: Ti(OC2H5)4

Molecular Formula: C8H20O4Ti

CAS No.: 3087-36-3

Molecular Weight:- 228.11

Raw material norms for 1 MT of Tetra Ethyl Titanate

Titanium Tetra chloride : 830.00 kgs

Ethyl Alcohol : 810.00 kgs

Ammonia : 300.00 kgs

Remark : Ammonium chloride is recovered as by product (935.00 kgs.)

b. Process Flow Diagram

c. Chemical Reaction:

TiCl4 + 4(OH-CH2-CH3) + 4NH3 Ti+-(O-CH2-CH3)4 + 4NH4Cl

Titanium Tetra chloride Ethyl Alcohol Ammonia Tetra Ethyl Titanate Ammonium Chloride

Product: Tetra Ethyl Titanate (TET)

Packing & Dispatch

Raw Material:

Ethyl Alcohol + Hexane (as

Solvent)

REACTOR

By-product:

Ammonium chloride

Raw Material:

Ammonia

MIXER

FILTRATION

VACUUM DISTILLATION Recovered and Reused

Ethyl alcohol and Hexane

Raw Material:

Titanium Tetra chloride CHILLER

Page 14: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 14 Manufacturing : Synthetic Organic Chemicals

04. Product: Tetra isopropyl Titanate (TiPT) derivatives

a. Manufacturing Process:

Required quantity of Tetra IsoPropyl Titanates (TiPT) and Acetylacetone / Denatured

Alcohol / Phosphate Ester / Triethanolamine / Ethylacetoacetate / Isopropylamine /

Monoethylene Glycol / Diethylene Glycol / 2Ethyl Hexyl Alcohol / Iso-octyl Alcohol are

mixed in a closed reactor as per specific/required ratio, the quality checked as per

specification and then packed in containers and dispatched.

• Raw material will be consumed as per the required properties of the final product.

• During the process there will not be any waste generation and process gas

emission.

b. Process Flow Diagram

c. Chemical Reaction: Mixing and Blending

(vi) Raw material required along with estimated quantity, likely source, marketing area of final

products/s, mode of transport of raw Material and finished product :

Detailed raw material requirement along with estimated quantity, likely source, marketing are of final

products mode of transport of raw material and finish product

Product: Derivatives of Tetra isopropyl Titanate (TiPT)

Packing & Dispatch

Raw Material:

Tetra IsoPropyl Titanates (TiPT)

(quantity as per required derivative

and customer specification and

applications)

MIXING IN A REACTOR

QUALITY CONTROL

Raw Material:

Acetylacetone / Denatured Alcohol / Phosphate Ester/

Triethanolamine / Ethylacetoacetate / Isopropylamine

/ Monoethylene Glycol / Diethylene Glycol / 2Ethyl

Hexyl Alcohol / Iso-octyl Alcohol

(Compound and quantity as per required derivative

and specific applications)

Page 15: FOR - Welcome to Environmentenvironmentclearance.nic.in/writereaddata/Online/TOR/0_0_30_Sep...FOR THE PROPOSED CHANGE IN PRODUCT PROFILE (Manufacturing of Organic Titanates in place

Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 15 Manufacturing : Synthetic Organic Chemicals

Raw material requirements:

Product-wise list of Raw-materials

Sr.

No.

Name of the product Raw Materials RM

Consumption

(MT/Month)

01. Organic Titanates

iv) Tetra isopropyl Titanate (TiPT)

v) Tetra n-Butyl Titanate (TnBT)

vi) Tetra Ethyl Titanate (TET)

Titanium tetra Chloride 138.00

Isopropyl alcohol 57.00

N-Butyl alcohol 58.00

Ethyl alcohol 54.00

Ammonia 50.00

02 Tetra isopropyl Titanate (TiPT) Derivatives Acetylacetone 10.00

Denatured Alcohol 16.00

Phosphate Ester 16.00

Triethanolamine 4.00

Ethylacetoacetate 8.00

Isopropylamine 4.00

Monoethylene Glycol 4.00

Diethylene Glycol 4.00

2Ethyl Hexyl Alcohol 9.00

Iso-octyl Alcohol 9.00

n-Hexane 16.00

Marketing area of final products:

The products are used in Augmenting adhesives, Plasticizer and various coatings and Catalyst for esterification, trans-esterification and polymerization reaction. The company has a wider customer base and to cater to the increased market demand, the company proposes expansion by way of switching over to new proposed product.

Transport of Raw material and Finish products:

Sr. No.

Name of Raw material Storage Capacity

Mode of Transport

Means of Storage

Source

1. Ammonia 10 KL By Road Cylinder From Manufacturer & Dealer

2. Ethanol 10 KL By Road MS Tank From Manufacturer & Dealer

3. Hexane 10 KL By Road MS Tank From Manufacturer & Dealer

4. n-Butyl Alcohol 10 KL By Road MS Tank From Manufacturer & Dealer

5. TiCl4 10 KL By Road MS Tank From Manufacturer & Dealer

6. Iso Propyl Alcohol 10 KL By Road MS Tank From Manufacturer & Dealer

7. Acetylacetone 2.0 KL By Road Drum From Manufacturer & Dealer

8. Phosphate Ester 1 KL By Road Drum From Manufacturer & Dealer

9. Triethanolamine 1 KL By Road Drum From Manufacturer & Dealer

10. Ethylacetoacetate 0.4 KL By Road Drum From Manufacturer & Dealer

11. Isopropylamine 0.4 KL By Road Drum From Manufacturer & Dealer

12. Monoethylene Glycol 0.4 KL By Road Drum From Manufacturer & Dealer

13. Diethylene Glycol 0.2 KL By Road Drum From Manufacturer & Dealer

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Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 16 Manufacturing : Synthetic Organic Chemicals

Sr. No.

Name of Raw material Storage Capacity

Mode of Transport

Means of Storage

Source

14. 2Ethyl Hexyl Alcohol 1 KL By Road Drum From Manufacturer & Dealer

15. Iso-octyl Alcohol 1 KL By Road Drum From Manufacturer & Dealer

16. Denatured Alcohol 1 KL By Road Drum From Manufacturer & Dealer

(vii) Resource optimization/ recycling and reuse envisaged in the project , if any , should briefly outlined :

The raw materials packed in drums and stored in the warehouse.

By adoption continuous improvement in technology and process the reduction in process waste

generation will be achieved.

Efficient handling of raw materials the wastages of raw materials will be reduced.

(viii) Availability of water its source, Energy/power requirement and source should be given:

Availability of water its source, Energy/power required and its source.

Water Requirement

Sr. No. Particulars Quantity

Liters per day

1. Domestic 2000.00

2. Industrial

Process 0.00

Boiler 0.00

Cooling 3000.00

Washing 0.00

Sub Total Industrial 3000.00

Gardening 1000.00

Total 6000.00

Source: Fresh water requirement will be catered from GIDC water supply dept.

Energy Requirements and its source:

Sr. No. Particulars Proposed Source

1 Heat

Requirement

2-4 lac K.

Cal/Hr

2 nos. Of Thermic Fluid Heaters will be

installed.

Power Requirements and its source:

Sr.

No. Particulars Proposed Source

1 Power –Electricity requirement 200 Kw DGVCL

The unit is having existing power connection of 75 KW

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Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 17 Manufacturing : Synthetic Organic Chemicals

(ix) Quantity of waste to be generated (liquid and solid) and scheme for their Management/disposal:

Quantity of waste to be generated (liquid and solid) and scheme for their Management/ disposal.

Quantity of Waste Water (liquid waste) generation and its management :

Sr. No. Particulars Quantity

Liters per day

1. Domestic 1500.00

2. Industrial

Process 0.00

Boiler 0.00

Cooling 500.00

Washing 0.00

Sub Total Industrial 500.00

Gardening 0.00

Total 2000.00

The waste water generated from domestic is disposed off through adequate soak pit and septic tank.

There is no generation of process and washing waste water during proposed industrial activities.

Industrial waste water in the form cooling tower blow down will be used for plantation within the

premises only.

Hence, there is no discharge of treated effluent.

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Expansion Project 18 Manufacturing : Synthetic Organic Chemicals

Water Balance Diagram:

Utility Emission & Control Measures:

Sr.

No. Particulars

Fuel / Power & its

Qty

Probable Pollutants

& Limits Control Measures

1.

Thermic Fluid Heater -

2Nos.

(2 LAKH K. CAL/HR.)

NG /

LDO: 1.50 KL/Day

PM <150 mg/Nm3

SO2 < 100 ppm

NOx< 50 ppm

Common Chimney ht:

15 m

Diameter: 300 mm

2.

D.G. Set

Capacity: 125 KVA with

Acoustic enclosure

HSD: 50 Lts/Hr

PM <150 mg/Nm3

SO2 < 100 ppm

NOx< 50 ppm

Chimney ht: 11 m

Diameter: 200 mm

Utility Emission & Control Measures:

There will not be any direct process gas emission during manufacturing of proposed products;

however to control the generated fugitive emission during manufacturing scrubber with under

mentioned specifications will be provide.

Sr.

No. Particulars Scrubbing media

Probable Pollutants

& Limits Control Measures

1. Fugitive emission control

system Alkali and water

HCl <20 mg/Nm3

NH3 <175 mg/Nm3 Scrubber

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Expansion Project 19 Manufacturing : Synthetic Organic Chemicals

Quantity of Solid Waste generation and its management :

Types of Waste

& Category

Source of

Generation

Quantity

(Proposed) Storage Method Method of Disposal

Used oil (5.1)

From plant

and

machineries

10 L/Month Will be stored in drums

Will be sold to registered refiners/ sent to TSDF site

Empty drums (33.3)

Raw material

consumed 25 Nos/Month Will be stored at a separate storage area

Will be reused for packing /sold to authorized scrap vendor

Spent Solvent (20.2)

From process If generated

Will be stored in storage tank

Will be sold out to its recyclers

Distillation Residue (20.3)

From process If generated

Will be stored in storage tank

To TSDF

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Prefeasibility Report-Annexure M/s. Skyline Polycats Pvt. Ltd.

Expansion Project 20 Manufacturing : Synthetic Organic Chemicals

(x) Schematic representations of the feasibility drawing which give information of EIA purpose:

A schematic representation of the feasibility drawing

Resource requirements • Raw Material: Sourced from Manufacturer / Traders of the

same. • Land: Expansion in Existing premises, At GIDC, Vapi. • Water: will be sourced through GIDC water supply. • Power: power will be sourced through Dakshin Gujarat Vij Co.

Ltd. • Fuel : Local delear

Env. Mgt. Plan (EMP)

Air Pollution Control Measures: Air Pollution control system

will be provided due to process emissions

Greenbelt Area: 33% of the Total Area will be developed.

Health & Safety measures will be followed properly

Soak pit/ Septic Tank

No Process waste will be generated.

Flue Gas emissions: Adequate chimney height will be provided.

Fugitive emission: Will be controlled by installation of adequate Scrubbing system.

Type of Industry Existing unit mfg. of “Synthetic Organic

Chemicals”

Site Location: The company located at Plot No. C-1

B/68, GIDC, Vapi. Dist-Valsad. Gujarat.

Public consultation: Not required as the project is located in

notified Industrial Zone

Submission of Form-1 and Pre-Feasibility

Report & Draft TOR

Proposed Activity: The proposed expansion project

involves the production of "Synthetic Organic Compounds"

Type of category as per EIA notification: Synthetic Organic Chemicals

(Category -5(f)-A due to GC applicability

Presentation before the EAC for TOR

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Expansion Project 21 Manufacturing : Synthetic Organic Chemicals

4. SITE ANALYSIS

4.0 Site Analysis

(i) Connectivity:

The project is located in notified Industrial Estate of Vapi which is very well connected to National

Highway no.8, Western Railways. And the nearest air port (Mumbai) and port are 150 KM away from

the project site by road.

(ii) Land Form, Land use and Land ownership:

The plot is belongs to GIDC, Vapi and company has purchased the same from GIDC and the Land is in

the Notified Industrial area GIDC, Vapi. The letter Notified Industrial Area is enclosed as Annexure.

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Expansion Project 22 Manufacturing : Synthetic Organic Chemicals

(iii) Topography (along with map) :

Topography map showing the elevation of the study area below.

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Expansion Project 23 Manufacturing : Synthetic Organic Chemicals

(iv) Existing land use pattern (agriculture, non-agriculture, forest , water bodied ( including area under

CRZ)), shortest distances from the periphery of the project to periphery of the forest, national park,

wild life sanctuary , eco sensitive areas, water bodies (distance from the HFL of the river), CRZ . In

case of notified industrial area, a copy of Gazette notification should be given:

o The existing land is located in the notified industrial area and a copy of a letter mentioning

gazette notification is enclosed.

o Shortest distances from the periphery of the project to periphery of the forest, national park,

wild life sanctuary , eco sensitive areas, water bodies (distance from the HFL of the river), CRZ

are as under :

Sr. No. Nearest Infrastructure Feature Distance from Project Site

1 Geographical Position Lat.: 20.38° N, Long.: 72.94 ° E

2 Elevation above Sea Level 36 Meters (Approx.)

3 Nearest Village Chanod – 1 Km

4 Nearest Town Vapi – 2.0 Km

5 Nearest National Highway NH-8: 2.0 (Approx.)

6 Nearest State Highway SH#:2.5 (Approx. )

8 Nearer RW Station Vapi- 2.0 (Approx.)

9 Nearest Airport Daman 12 Km NW (Approx.)

Surat 86.5 Km NW (Approx.)

10 Nearest Surface water

Resource/Reservoir

Damanganga River 6 Km S (Approx.)

Madhuban Dam 22 Km SE (Approx.)

11 Forest Land Reserve Forest 8.55 Km W (Approx.)

Protected Forest 12.00 Km NE (Approx.)

12 Location of Archaeologically

/Historically important places

Silvassa 3.0 Km (Approx.)

Daman 12 Km (Approx.)

13 National Park/Sanctuary or

Ecologically sensitive Area Nil

14 National or State Boundary Interstate – UT of D&NH 2.5 Km E (Approx.)

UT of D&D 3.0Km E (Approx.)

15 Tourist Places

Silvassa- 2.5 Km E (Approx.)

Daman- 3.0 Km W (Approx.)

Tithal (Valsad)25.00 Km NW (Approx.)

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Expansion Project 24 Manufacturing : Synthetic Organic Chemicals

(v) Existing Infrastructure:

GIDC Industrial Estate, Vapi has the entire available infrastructure like water, electricity, roads, rail,

transportation, availability of raw material and drainage system.

(vi) Soil classification:

General soil classification of the area is as under:

Soil Characteristics & Land use classification: The study area is located from outer part of Dadra.

Northern part of the site location fully development for settlement with cropping pattern.

Eastern part of the site location for Loamy, clay, Red soil.

The project site around 10 km radius mixed soil type for Basalt soil, Clay soil, this type of soil not

suitable for cultivation purpose,

This land suitable for industrial development -100%

The Damanganga River is located from 0.5 km distance on the site location, this river both side of

mixed soil type (Sand, clay, Basaltic soil)

(vii) Climate data from secondary sources:

Rainfall Data :

The project site location receives annual rainfall of 2010 – 1200 to 1300 mm in 35 rainy days with

coefficient of variation of 65 %. There is large spatial and temporal variation in rainfall of the study

area. The low rainfall areas receiving less than 500 mm rainfall are comprised of Kutch district and

western parts of Banaskantha and Patan district and parts of Jamnagar, Rajkot and Surendranagar

districts. These are also characterized by arid climate. The high rainfall (> 1400 mm) receiving areas

(Project site, Dang, Valsad, Navsari and Surat, Dadra & Nagar Haveli and Daman & Diu) are

characterized as sub humid climate. The rest part of the state receives rainfall between 500-1000 mm

and generally fall under semi-arid climate. Considering the abnormality of weather particularly rainfall

during the monsoon period. The observed and predicted rainfall was then analyzed for its validity.

Temperature Data:

The site location is located in the southern part of Gujarat. The secondary data was collected from free

data of Worldclim.org year of 2010. The project site temperature regime for medium to high level

temperature (30-32 °C) during the seasonal months (June to Sep).

(viii) Social Infrastructure available:

Social Infrastructure in Valsad district is as under :

Education : There are 990 primary and 161 secondary and higher secondary Table 5: List of

Educational Institutes schools in the district Educational Total§ With over 1,250 seats, there are 6 ITIs

offering several industrial training Institutes programs which includes, fitting, armature & motor

rewinding, Primary School 990 electrician, information technology and electronic system maintenance

Secondary School etc 166 Higher Secondary School One Government polytechnic College is present in

the district offering courses in civil, chemical, electrical, mechanical and plastic engineering, ITI’s 6

with an intake capacity of 360 Polytechnic 1 College With 120 seats, there is one Degree Engineering

College present in Pharmacy College 2 Valsad offering engineering courses in mechanical and chemical

Engineering 1 branches College§ Located in Vapi, G. M. Bilakhia Pharmacy College has an intake

Management 1 College capacity of 60 students per year Other Colleges* 8 Rofel Institute of

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Expansion Project 25 Manufacturing : Synthetic Organic Chemicals

Management studies in Valsad offers full time MBA *Other Colleges: Arts, Commerce, Science, B. Ed

and Law College course and takes 120 students per annum Source: Department of Education, 2007 28

Health: There are 43 primary healthcare centres, 10 community healthcare centres, 10 Government

and 1 Municipal hospital present in the district. Valsad has several private specialized hospitals to

provide a comprehensive range of tertiary and secondary care services backed by state-of- the- art

technology and trained medicos§ A multi-specialty 21st Century Hospital, (branch of Nadkarni Group

of Hospitals) is present in Vapi, giving services in general and laparoscopic surgery, trauma, orthopedic

and urology etc. the hospital is one of the few centers in India offering Uterine Thermochoice thermal

Balloon Therapy for Dysfunctioning Uterine Bleeding (DUB) patients. Beside this, several private

hospitals such as, Kasturba Hospital, Bhatia General Hospital, and Adarsh Hospital are also present in

Valsad 29.

Tourism: Tourism Built in 1742, the Fire Temple at Udawada, which is also known Fire Temple as

Mecca for the Parsi community in India, makes the city a famous pilgrimage center throughout the

world§ Dharampur is surrounded on three sides by the Sahyadri Mountains which grace the town with

pleasant climate throughout the year§ The collection at the Lady Wilson Museum in Dharampur

includes tribal art and art crafts that highlights the local culture. Besides this, District Science Centre is

also present in Valsad Proximity of Valsad with Daman & Diu, has increased the graph of tourist flow in

the district.

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Expansion Project 26 Manufacturing : Synthetic Organic Chemicals

5. Planning Description

5.0 Planning Brief.

(i) Planning Concept (Type of industries, facilities, transportation etc) Town and Country Planning

/Development authority Classification:

There is a cluster of numerous large-scale, medium-scale and small-scale industries, engaged in

manufacture of variety of products, for example pharmaceuticals, dyes and chemicals, paper mills,

paints, plastics, packaging, textiles, specialilty chemicals and others in the Gujarat Industrial

Development Corporation (GIDC) notified area of Vapi.

(ii) Population Projection:

Not applicable

(iii) Land use planning (breakup along with green belt etc):

The existing and proposed expansion project is located within the Notified Industrial Area by

Government of Gujarat and due to the proposed project there will not be any change in the land use

pattern of the region.

Plot Area Statement:

Area Statement Area After Proposed

Expansion (in m2)

Total Area 855.00

Construction Area 450.00

Open Land Area 250.00

Greenbelt Area 155.00

(iv) Assessment of Infrastructure demand (Physical & Social) :

There is no need for any infrastructure demand in terms of physical or social needs for proposed expansion.

(v) Amenities/ Facilities:

GIDC notified industrial area of Vapi has the entire available infrastructure like water, electricity, roads, rail, transportation, availability of raw material and drainage system.

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Expansion Project 27 Manufacturing : Synthetic Organic Chemicals

6. Infrastructure Details

6.0 Proposed Infrastructure:

(i) Industrial Area (Processing Area).

The proposed infrastructure to manufacture products will be built with standard engineering design

considering all the relevant parameters related to environment, health and safety. Lay out plan is

enclosed.

(ii) Residential Area (Non Processing Area) :

No residential area is involved in the proposed expansion project.

(iii) Green Belt:

Green belt area will be provided and maintain at the tune of 18% of the total land area as the project

site is within the developed industrial area

(iv) Social Infrastructure:

Facilities like road and communication are good. One can be sure of the uninterrupted power supply

and adequate water.

Rail and Road- The nearest railway station is Vapi in the western railway, Mumbai-Ahmadabad route.

See train table pg 56. From Vapi road transport is easily available. From Mumbai it is about 3 hours

drive while Surat (120 km) is almost 2 hours drive away. By Air Mumbai is the nearest Airport, well

connected to Vapi by road. As Local Transport Unmetered autorichshaws are the common mode of

local transport. Share auto rickshaws are available.

(v) Connectivity (Traffic and Transportation Road/ Rail/ Metro/ Water ways etc) :

The project site is very well connected by road through National Highway no. 8, western railways.

(vi) Drinking Water management (Source & Supply of water) :

Water requirement will be fulfilled through GIDC water supply.

(vii) Sewerage System:

GIDC has provided sewerage system to dispose the sewage effluent.

(viii) Industrial Waste Management:

There is no any process waste water generation only Industrial waste water @ 500 lit/day in the form of cooling tower blow down will be used for plantation within the premises and no waste

water will be discharged outside company premises.

(ix) Solid Waste Management:

Types of Waste

& Category

Source of

Generation

Quantity

(Proposed) Storage Method Method of Disposal

Used oil (5.1)

From plant and

machineries 10 L/Month Will be stored in drums

Will be sold to registered refiners/ sent to TSDF site

Empty drums (33.3)

Raw material

consumed 25

Nos/Month Will be stored at a separate storage area

Will be reused for packing /sold to authorized scrap vendor

Spent Solvent (20.2)

From process If generated

Will be stored in storage tank

Will be sold out to its recyclers

Distillation Residue (20.3)

From process If generated

Will be stored in storage tank

To TSDF

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Expansion Project 28 Manufacturing : Synthetic Organic Chemicals

(x) Power Requirement & Supply / Source:

Power requirement for proposed project will be taken from DGVCL.

7. Rehabilitation and Resettlement (R&R) Plan:

(i) Policy to be adopted (Central/ State) in respect of the project affected persons including home

oustees, land oustees and landless laborers (a brief outline to be given):

There will be no rehabilitation and resettlement undertaken as labours and workers from local &

nearby areas for the proposed construction activity which will be minor as the proposed expansion

activity is to be undertaken at the existing site.

8. Project Schedule & Cost Estimates:

(i) Likely date of start of construction and likely date of completion (Time schedule for the project to be

given) :

After obtaining Environmental clearance and Consent to Establish from GPCB, the company shall start

the proposed construction and commissioning of the project.

(ii) Estimated project cost along with analysis in terms of economic viability of the project:

Estimated project cost along with the analysis in terms of economic viability of the project

Plant & Machinery, Pipeline & Fittings, Electrical Installation, Safety systems, etc. are the major heads

considered in the Capital Cost Projection for the proposed expansion project. Environment Protection

has also been considered in planning the Cost Projection, which will include Green belt development,

safety systems, etc.

Capital Cost Projection

Sr.

No. Purpose

Cost

(Rs. In Lakhs)

1. Land 50.00

2. Building and Civil Works 35.00

3. Plant & Machinery and other fittings 350.00

4. Environmental protection measures 65.00

TOTAL : 500.00

The existing and proposed investment will be made by company only.

The company will provide budgetary provision for the recurring expenses for environmental issues

while planning the allocation of funds during the annual budgetary planning.

Recurring Cost per annum

Sr. No. Component Proposed

(Rs. in Lacs/annum)

1. Environment & Safety Management System 5.00

2. Greenbelt Maintenance 1.00

3. Enterprise social contribution 2.50

Total 8.50

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Expansion Project 29 Manufacturing : Synthetic Organic Chemicals

9. Analysis of Proposal (Final Recommendations):

(i) Financial and social benefits with special emphasis on the befit to the local people including tribal

population, if any, in the area:

Proposed expansion activity will provide benefits to the local people in terms of financial and social

welfare.

Local people will get direct financial benefit by way of employment.

Local people will get some contracts of supply and services to get indirect income.

Company will contribute in improving education and health facilities in nearby area.

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Expansion Project 30 Manufacturing : Synthetic Organic Chemicals

Proposed Scrubber System

The detail of the scrubber provided for removal of contaminant from the fugitive is given below as

schematic presentation.


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