FORM-Ienvironmentclearance.nic.in/writereaddata/Online/...NABL Accredited Testing Laboratory ISO...

FORM-I

for

PROPOSED DYES MANUFACTURING UNIT

of

M/s. SHREE SAI INDUSTRIES

Survey No. 358, Vaduchi Mandir Road, Village: Lunej,

Taluka: Khambhat, Dist: Anand – 388 620 (Guj.)

NABL Accredited Testing Laboratory

ISO 9001:2008 Certified Company

Aqua-Air Environmental Engineers P. Ltd.

403, Centre Point, Nr. Kadiwala School, Ring

Road, Surat - 395002

Prepared By:











Prepared By:

APPENDIX I

FORM 1 (I) Basic Information

Sr.

No.

Item Details

1. Name of the Project/s M/s. Shree Sai Industries

2. S. No. in the Schedule 5(f)

3. Proposed capacity / area / length /

tonnage to be handled/command

area/lease area/number of wells to be

drilled

Production Capacity: 65 MT/Month

Total Area: 2400 m2

4. New/Expansion/Modernization New

5. Existing capacity/area etc. Not Applicable

6. Category of project i.e. ‘A’ or ‘B’ ‘A’ (Located Outside of Notified Industrial Estate)

7. Does it attract the general condition?

If yes, please specify.

No.

8. Does it attract the specific condition?

If yes, please specify.

No.

9. Location

Plot/Survey/Khasra No. Survey No. 358, Vaduchi Mandir Road

Village Lunej

Tehsil Khambhat

District Anand –388 620

State Gujarat

10. Nearest railway station/airport along

with distance in kms.

By road distance:

Nearest Railway Station: Khambhat (Cambay) = 5 km

(approx.)

Nearest Airport: Vadodara = 83 km (approx.)

11. Nearest Town, city, District

Headquarters along with distance in

kms.

By road distance:

Nearest Town: Khambhat = 5 km (approx.)

Nearest District Head Quarter: Anand = 57 km (approx.)

12. Village Panchayats, Zilla Parishad,

Municipal corporation, Local body

(Complete postal addresses with

telephone nos. to be given)

Village: Lunej, Taluka Khambhat, Dist. Anand,

Gujarat.

13. Name of the applicant M/s. Shree Sai Industries

14. Registered address Survey No. 358, Vaduchi Mandir Road, Village: Lunej,

Taluka: Khambhat, Dist: Anand – 388 620 (Guj.)

15. Address for correspondence:

Name Mr. Suresh Motiram Patel

Designation (Owner/Partner/CEO) (Proprietor)

Address 132, Karma Estate, Trikampura Patia, Phase-III, GIDC

Vatva, Ahmadabad-382445

Pin Code 382445

E-Mail [email protected]

Telephone No. Mob.: +91 9825047043

Fax No. --

16. Details of Alternative Sites examined,

if any location of these sites should be

shown on a topo sheet.

No

17. Interlinked Projects No

18. Whether separate application of

interlinked project has been

submitted?

No interlinked project has been submitted.

19. If Yes, date of submission Not applicable

20. If no., reason Not applicable

21. Whether the proposal involves

approval/clearance under: If yes,

details of the same and their status to

be given.

(a) The Forest (Conservation) Act,

1980?

(b) The Wildlife (Protection) Act,

1972?

(c) The C.R.Z Notification, 1991?

No

22. Whether there is any Government

order/policy relevant/relating to the

site?

No

23. Forest land involved (hectares) No

24. Whether there is any litigation

pending against the project and/or

land in which the project is propose to

be set up?

(a) Name of the Court

(b) Case No.

(c) Orders/directions of the Court,

if any and its relevance with the

proposed project.

No

(II) Activity

1. Construction, operation or decommissioning of the Project involving actions, which

will cause physical changes in the locality (topography, land use, changes in water

bodies, etc.)

Sr.

No.

Information/Checklist confirmation Yes

/No?

Details thereof (with approximate

quantities / rates, wherever possible)

with source of information data

1.1 Permanent or temporary change in land

use, land cover or topography including

increase in intensity of land use (with

respect to local land use plan)

No Proposed activity will be carried out at

Survey No. 358, Vaduchi Mandir Road,

Village: Lunej, Taluka: Khambhat, Dist:

Anand – 388 620 (Guj.) which is NA Land.

1.2 Clearance of existing land, vegetation

and buildings?

No Minor site clearance activities shall be

carried out to clear shrubs and weed.

1.3 Creation of new land uses? No Proposed activity will be carried out at

Survey No. 358, Vaduchi Mandir Road,

Village: Lunej, Taluka: Khambhat, Dist:

Anand – 388 620 (Guj.) which is NA Land.

1.4 Pre-construction investigations e.g. bore

houses, soil testing?

No --

1.5 Construction works? Yes Plant Layout is attached as Annexure: 2.

1.6 Demolition works? No --

1.7

Temporary sites used for construction

workers or housing of construction

workers?

No --

1.8 Above ground buildings, structures or

Earthworks including linear structures,

cut and fill or excavations

Yes Plant Layout is attached as Annexure: 2.

1.9

Underground works including mining or

tunneling?

No --

1.10 Reclamation works? No --

1.11 Dredging? No --

1.12 Offshore structures? No --

1.13 Production and manufacturing Yes List of Products is attached as Annexure: 1

and manufacturing process is attached as

Annexure: 3.

1.14 Facilities for storage of goods or

materials?

Infrastructure

Yes Dedicated storage area for storage of Raw

Materials and finished products, solvents,

etc. shall be provided.

1.15

Facilities for treatment or disposal of

solid waste or liquid effluents?

Yes For Facilities for treatment or disposal of

liquid effluents, please referred Annexure: 5.

For Hazardous waste detail, please refer

Annexure: 6.

1.16 Facilities for long term housing of No --

operational workers?

1.17 New road, rail or sea traffic during

construction or operation?

No --

1.18 New road, rail, air waterborne or other

airports etc?

No Site is well connected by road.

1.19 Closure or diversion of existing

transport routes or infrastructure

leading to changes in traffic

movements?

No --

1.20 New or diverted transmission lines or

pipelines?

No --

1.21

Impoundment, damming, converting,

realignment or other changes to the

hydrology of watercourses or aquifers?

No --

1.22 Stream crossings? No --

1.23

Abstraction or transfers or the water

form ground or surface waters?

Yes Raw water requirement is met through

Tankers or Ground Water.

1.24

Changes in water bodies or the land

surface affecting drainage or run-off?

No --

1.25

Transport of personnel or materials for

construction, operation or

decommissioning?

Yes Transportation of personnel or raw

material and products will be primarily by

road only.

1.26 Long-term dismantling or

decommissioning or restoration works?

No --

1.27 Ongoing activity during

decommissioning which could have an

impact on the environment?

No --

1.28

Influx of people to an area in either

temporarily or permanently?

No --

1.29 Introduction of alien species? No --

1.30 Loss of native species of genetic

diversity?

No --

1.31 Any other actions? No --

2. Use of Natural resources for construction or operation of the Project (such as land, water,

materials or energy, especially any resources which are non-renewable or in short supply):

Sr.

No

Information/checklist confirmation Yes/

No?

Details there of (with approximate

quantities/rates, wherever possible) with

source of information data

2.1 Land especially undeveloped or

agriculture land (ha)

No --

2.2 Water (expected source & competing

users) unit: KLD

Yes Water requirement will be met through

the Water Tankers or Ground Water.

Detailed water balance is given as

Annexure: 4.

2.3 Minerals (MT) No --

2.4

Construction material -stone,

aggregates, sand / soil (expected source

MT)

Yes Company shall use Sand, Stone, Cement

and Structural Steel for Construction as

required.

2.5 Forests and timber (source - MT) No --

2.6

Energy including electricity and fuels

source, competing users Unit: fuel (MT),

energy (MW)

Yes Power required from MGVCL will be 60 HP

D. G. Set: 20 HP

Fuel

Imported Coal/PNG Gas/Agro Waste/Bio

Coal: 1 MT/Day

HSD: 5 Liter/Hr

2.7 Any other natural resources (use

appropriates standard units)

No --

3. Use, storage, transport, handling or production of substances or materials, which could be

harmful to human health or the environment or raise concerns about actual or perceived

risks to human health.

Sr.

No.

Information / Checklist confirmation Yes/

No?


quantities / rates wherever possible) with


3.1 Use of substances or materials, which are

hazardous (as per MSIHC rules) to human

health or the environment (flora, fauna,

and water supplies)

Yes

Please refer Annexure: 8.

3.2 Changes in occurrence of disease or

affect disease vectors (e.g. insect or

water borne diseases)

No --

3.3 Affect the welfare of people e.g. by

changing living conditions?

No --

3.4

Vulnerable groups of people who could

be affected by the project e.g. hospital

patients, children, the elderly etc.,

No

--

3.5 Any other causes No --

4. Production of solid wastes during construction or operation or decommissioning

MT/month)

Sr.

No.

Information/Checklist confirmation Yes/

No?


quantities / rates, wherever possible)

with source of information data

4.1 Spoil, overburden or mine wastes No --

4.2

Municipal waste (domestic and or

commercial wastes) No --

4.3

Hazardous wastes (as per Hazardous

Waste Management Rules)

Yes Please refer Annexure: 6

4.4 Other industrial process wastes Yes Please refer Annexure: 6

4.5 Surplus product No --

4.6

Sewage sludge or other sludge from

effluent treatment

Yes Please refer Annexure: 6

4.7 Construction or demolition wastes Yes Construction waste shall be utilized for

leveling & land filling in the premises.

4.8 Redundant machinery or equipment No --

4.9 Contaminated soils or other materials No --

4.10 Agricultural wastes No --

4.11 Other solid wastes Yes Please refer Annexure: 6

5. Release of pollutants or any hazardous, toxic or noxious substances to air (Kg/hr)

Sr.

No.


No?


quantities/rates, wherever possible) with


5.1 Emissions from combustion of fossil

fuels From stationary or mobile sources

Yes Details of flue & process gas emission are

attached as Annexure: 7

5.2 Emissions from production processes Yes Details of emission from process are

attached as Annexure: 7.

Details of Air Pollution Control measures

are attached as Annexure: 7

5.3 Emissions from materials handling

including storage or transport.

Yes All liquid raw materials shall be procured in

bulk tankers and shall be transferred

through a closed circuit pipe lines by

pumps.

Solid raw material shall be handled in

closed charging rooms with proper

ventilation and charged through close

pipeline into reactors.

5.4 Emissions from construction activities Yes Utmost care will be taken during

including plant and equipment construction activity and water sprinklers

shall be utilized whenever necessary.

5.5

Dust or odours from handling of

materials including construction

materials, sewage and waste

Yes All the waste shall be stored in

designated places and shall be

transported to TSDF or Incineration Site

in their own approved closed vehicles.

5.6 Emissions from incineration of waste No --

5.7 Emissions from burning of waste in

open air (e.g. slash materials,

construction debris)

No --

5.8 Emissions from any other sources No --

6. Generation of Noise and Vibration, and Emissions of Light and Heat:

Sr.

No.


No?

Details there of (with approximate

Quantities /rates, wherever possible) With

source of source of information data

6.1

From operation of equipment e.g.

engines, ventilation plant, crushers

Yes The Noise level will be within the

prescribed limit. At noisy areas adequate

preventive & control measures will be

taken. No significant noise, vibration or

emission of light & heat from the unit.

6.2 From industrial or similar processes Yes All machinery / equipment shall be well

maintained, shall have proper foundation

with anti vibrating pads wherever

applicable and noise levels will be within

permissible limits.

Acoustic enclosures shall be provided for

DG set.

6.3 From construction or demolition No --

6.4 From blasting or piling No --

6.5 From construction or operational traffic No --

6.6 From lighting or cooling systems No --

6.7 From any other sources No Acoustic enclosures shall be provided for

DG set.

7. Risks of contamination of land or water from releases of pollutants into the ground or

into sewers, surface waters, groundwater, coastal waters or the sea:

Sr.

No


No?


quantities / rates, wherever possible) with


7.1

From handling, storage, use or spillage

of hazardous materials

Yes All the raw material shall be stored

separately in designated storage area and

with safely. Bund walls shall be provided

around raw materials storage tanks for

containing any liquid spillage.

Other materials shall be stored in bags /

drums on pallets with concrete flooring and

no spillage is likely to occur. Please refer

Annexure : 8.

7.2

From discharge of sewage or other

effluents to water or the land

(expected mode and place of

discharge)

Yes Sewage is disposed of through septic tank &

soak pit & to be done through same way

after proposed expansion.

7.3

By deposition of pollutants emitted to

air into the land or into water

No --

7.4 From any other sources No --

7.5 Is there a risk of long term build up of

pollution in the environment from

these sources?

Yes

--

8. Risks of accident during construction or operation of the Project, which could affect

human health or the environment:

Sr.

No

Information/Checklist confirmation

Yes/

No?




8.1 From explosions, spillages, fires etc.

from storage, handling, use or

production of hazardous substances

Yes The risk assessment will be carried out and

all mitigative measures shall be taken to

avoid accidents.

8.2 From any other causes No Not applicable

8.3 Could the project be affected by natural

disasters causing environmental damage

(e.g. floods, earthquakes, landslides,

cloudburst etc)?

No --

9. Factors which should be considered (such as consequential development) which could lead

to environmental effects or the potential for cumulative impacts with other existing or

planned activities in the locality

Sr.

No.


No?




9.1 Lead to development of supporting.

laities, ancillary development or

development stimulated by the project

which could have impact on the

environment e.g.:

* Supporting infrastructure (roads,

power supply, waste or waste water

treatment, etc.)

housing development

extractive industries

supply industries

other

Yes Please refer Annexure: 9.

9.2

Lead to after-use of the site, which

could have an impact on the

environment

No --

9.3 Set a precedent for later developments No --

9.4 Have cumulative effects due to

proximity to Other existing or planned

projects with similar effects

No --

(III) Environmental Sensitivity

Sr.

No

Information/Checklist confirmation Name /

Identity

Aerial distance (within 5 km). Proposed

Project Location Boundary.

1 Areas protected under international

conventions national or local

legislation for their ecological,

landscape, cultural or other related

value

No No protected area within 5 km from the

proposed project site.

2 Areas which are important or sensitive

for Ecological reasons - Wetlands,

watercourses or other water bodies,

coastal zone, biospheres, mountains,

forests

Yes Sabarmati River – appox. 24 Km away from

project site.

3 Areas used by protected, important or

sensitive species of flora or fauna for

breeding, nesting, foraging, resting,

over wintering, migration

No --

4 Inland, coastal, marine or

underground waters

Yes Sabarmati River – appox. 24 Km away from

project site.

5 State, National boundaries No --

6 Routes or facilities used by the public

for to recreation or other tourist,

pilgrim areas.

No --

7 Defense installations No --

8 Densely populated or built-up area Yes Khambhat - appox. 5 Km away from

project site.

9 Areas occupied by sensitive man-

made land community facilities)

No --

10 Areas containing important, high

quality or scarce resources (ground

water resources, surface resources,

forestry, agriculture, fisheries,

tourism, tourism, minerals)

No

--

11 Areas already subjected to pollution

or environmental damage. (those

where existing legal environmental

standards are exceeded)

No --

12 Are as susceptible to natural hazard

which could cause the project to

present environmental problems

(earthquakes, subsidence ,landslides,

flooding erosion, or extreme or adverse

climatic conditions)

No --

(IV) Proposed Terms of Reference (TOR) for EIA studies are attached as Annexure: XI.

“I hereby give undertaking that, the data and information given in the application and

enclosures are true to the best of my knowledge and belief and I am aware that if any part of

the data and information submitted is found to be false or misleading at any stage the project

will be rejected and clearance given, if any, to the project will be revoked at our risk and cost”.

Date: Jan. 17, 2018

Place: Khambhat

Stamp and Signature of Applicant

Date: 17-Jan-2018

NOTE:

1. The projects involving clearance under Coastal Regulation Zone Notification, 1991 shall

submit with the application a C.R.Z. map duly demarcated by one of the authorized agencies,

showing the project activities, w.r.t. C.R.Z. (at the stage of TOR) and the recommendations of

the State Coastal Zone Management Authority (at the stage of EC). Simultaneous action shall

also be taken to obtain the requisite clearance under the provisions of the C.R.Z. Notification,

1991 for the activities to be located in the CRZ.

2. The projects to be located within 10 km of the National Parks, Sanctuaries, Biosphere

Reserves, Migratory Corridors of Wild Animals, the project proponent shall submit the map duly

authenticated by Chief Wildlife Warden showing these features vis-à-vis the project location

and the recommendations or comments of the Chief Wildlife Warden thereon (at the stage of

EC).

3. All correspondence with the Ministry of Environment & Forests including submission of

application for TOR/Environmental Clearance, subsequent clarifications, as may be required

from time to time, participation in the EAC Meeting on behalf of the project proponent shall be

made by the authorized signatory only. The authorized signatory should also submit a document

in support of his claim of being an authorized signatory for the specific project.

ANNEXURES

Sr.

No.

Content

1 List of products with production capacity and raw materials

2 Plot layout

3 Brief manufacturing process, chemical reaction and mass balance

4 Details of water consumption and waste water generation

5 Details of effluent treatment plant

6 Details of hazardous/solid waste generation, management and disposal mode

7 Details of air pollution sources and control measures

8 Details hazardous chemical storage facility

9 Socio - Economic impacts

10 Proposed Terms of References

11 GIDC Plot Allotment Letter

12 GIDC Water Supply Letter

13 Toposheet

ANNEXURE-I

LIST OF PRODUCTS WITH THEIR PRODUCTION CAPACITY

Sr.

No.

Name of the

Products CAS no. /CI no.

Quantity

MT/Month End-use of products

1 Acid Green-16 12768-78-4

15

Textile Industries &

Lather Industries, Ink

Industries, etc.

2 Acid Red-52 3520-42-1

3 Acid Blue-1 116-95-0

4 Acid Blue-7 3486-30-4

5 Acid Blue-9 2650-18-2

50 6 Acid Blue-15 5863-46-7

7 Acid Violet-17 4129-84-4

8 Acid Violet-49 1694-09-3

TOTAL 65

RAW MATERIAL CONSUMPTION:

Sr.

no.

Name of the

Products

Name of the Raw

Materials CAS no. /CI no.

Quantity

MT/Month

1 Acid Green-16

Naphthalene 91-20-3 4.17

Sulfuric acid 7664-93-9 10.94

Soda 1310-73-2 10.8

DEA 127-19-5 6.25

Formaldehyde (37%) 50-00-0 2.3

sulphanilic acid 121-57-3 0.1

MnSO2 7785-87-7 4.17

Sodium Dichromate 7789-12-0 1.15

Oxalic Acid 6153-56-6 1.7

Salt 7647-14-5 5.21

2 Acid Red-52

Benzaldehyde

disulfonic acid 88-39-1 0.7

Diethyl meta

aminophenol 91-68-9 0.9

H2SO4 98% 7664-93-9 3.8

Salt 7647-14-5 4.4

Soda 1310-73-2 0.07


HCl 30 % 7647-01-0 1

3 Acid Blue-1

Benzaldehyde

disulfonic acid 1008-72-6 4.8

Diethyl aniline 91-66-7 5.3

H2SO4 98% 7664-93-9 7.15

Soda ash 1310-73-2 1

Sodium Sulfate 7757-82-6 11

Dichromate 7778-50-9 1

4 Acid Blue-7

Benzaldehyde

disulfonic acid 1008-72-6 4

Ethyl benzyl aniline 92-59-1 6.4

H2SO4 98 % 7664-93-9 6.8

C.Lye 1310-73-2 4.44

Sodium Sulfate 7757-82-6 2.12

Acetic Acid 64-19-7 2.84

Lead peroxide 1309-60-0 2.52

MnSO4 10034-96-5

Salt 7647-14-5 12.4

5 Acid Blue-9

Ethyl Benzyl Aniline

Sulfonic Acid 101-11-1 11.10

Ortho Benzaldehyde

sulfonic acid 1008-72-6 3.99

Soda ash 1310-73-2 2.40

H2SO4 98% 7664-93-9 4.79

Oxalic Acid 6153-56-6 2.60


Salt 7647-14-5 21.88

6 Acid Blue-15

Ethyl benzyl aniline

sulfonic acid 101-11-1 55

Di ethyl meta toluene 91-67-8 10.42

C.Lye 1310-73-2 5.6

Copper sulphate 7758-99-8 0.9

Sodium thiosulphate 7772-98-7 6.25

7 Acid Violet-17


sulfonic acid 101-11-1 75

C.Lye 1310-73-2 7.7

Formaldehyde 50-00-0 7


Di ethyl Aniline 91-66-7 12.7

hydrogen peroxide 7722-84-1 8.7

8 Acid Violet 49


sulfonic acid 101-11-1 76.5

C.Lye 1310-73-2 8

Formaldehyde 50-00-0 7


Di methyl Aniline 91-66-7 11.8

hydrogen peroxide 7722-84-1 9

ANNEXURE-II

PLANT LAYOUT

ANNEXURE-III

MANUFACTURING PROCESS DESCRIPTION

1. Acid Green 16:

Manufacturing Process:

In M.S. reactor Naphthalene and Sulphuric Acid is mixed for reaction. Then add soda ash and

filter it. Wet cake formed is Naphthalene Disulfonic Acid will be used for further procedure and

effluent goes to ETP. Now in another M.S lead bonded jacketed vessel take Diethyl aniline,

formaldehyde and sulphanilic acid. Add Soda ash to this mass and filter it. Effluent goes to ETP.

Now mix this wet cake with previously prepared wet cake of Naphthalene Disulfonic Acid, also

add water and sulphuric acid. Once this mass is oxidized using water, Sodium dichromate, oxalic

acid, sulfuric acid and soda ash; it is salted with common salt and filtered. Wet cake obtained

now is dried in dryer, pulverized in ball mill as per required standard and packed for sale.

Chemical Reaction:

Mass Balance:

Stage-1

Input Qty (kg) Output Qty (kg)

Naphthalene 40 Naphthalene di Sulphuric acid 44

Sulfuric acid 50 Effluent 109

Soda 63

Total 153 Total 153

Stage-2


DEA 60 Filtrate 198

Formaldehyde (37%) 22 Effluent 200

sulphanilic acid 1

Water 250

MnSO4 40

Soda 25

Total 398 Total 398

Stage-3


Naphthalene di Sulphuric

acid

44 Stage-3 542

Filtrate 198

Sulfuric Acid 50

Water 250

Total 542 Total 542

Stage-4


Stage-3 542 Product 96

Water 100 Effluent 577

Sodium Dichromate 11 Losses 66

Oxalic Acid 16

Sulfuric Acid 5

Soda 15

Salt 50

Total 739 Total 739

2. Acid Red 52


Benzaldehyde-1, 3-disulfonic acid and diethyl Meta Amino phenol condensation, the products

with sulfuric acid dehydration, and sodium dichromate oxidation, and finally isolated as sodium

salt. Filter it and make slurry and spry dried it.

Chemical Reaction:

Mass Balance:

Stage:1


Water 4000 Stage-1 1500

Benzaldehyde disulfonic

acid

500 Effluent 3830

Diethyl meta aminophenol 650

H2SO4 98% 180

Total : 5330 5330

Stage:2



Stage-1 1500 Effluent 3600

Evaporate 170

Total : 4500 4500

Stage:3




H2SO4 2665

Salt 800

Total : 9195 9195

Stage:4


Water 3200 Acid Red 52 7480


Soda 50

Sodium Dichromate 150

HCl 30 % 730

Salt 2500

Total : 8280 8280

3. ACID BLUE 1


Benzaldehyde-1, 3-disulfonic acid and N,N-diethyl Aniline (2 More) condensation and oxidation

with dichromate, and then turn it into sodium sal. And spray dry it.

Chemical Reaction:

Mass Balance:


Water 6000 Acid Blue 1 1050


acid

500 Effluent 6015

Diethyl aniline 555 Evaporate 2100

H2SO4 98% 750

Soda ash 100

Sodium Sulfate 1155

Dichromate 105

Total : 9165 9165

4. ACID BLUE 7


Benzaldehyde-1, 3-disulfonic acid and N-benzyl-N-Ethyl Aniline (2 more) condensation and

oxidation with lead peroxide in presence of acetic acid, convert into sodium salt and spry dry it.

Chemical Reaction:

Mass Balance:




acid

500 Effluent 5840

Ethyl benzyl aniline 800 Evaporate 2100

H2SO4 98 % 850

C.Lye 555

Sodium Sulfate 265

Acetic Acid 355

Lead peroxide 315

Salt 1550

Total : 9190 9190

5. ACID BLUE 9


Ortho-Benzaldehyde sulfonic acid and ethyl benzyl aniline sulfonic acid (EBASA) condensation,

oxidation with sodium dichromate in presence of oxalic acid, and then the product into the

ammonium salt or sodium salt and spray dry it.

Chemical Reaction:

Mass Balance:


Water+ ICE 2000 Acid Blue 9 6260

Ethyl Benzyl Aniline

Sulfonic Acid

1390 Evaporation loss 1850

Ortho Benzaldehyde

sulfonic acid

500

Soda ash 300

H2SO4 98% 600

Oxalic Acid 325

Sodium Dichromate 255

Salt 2740

Total : 8110 8110

6. ACID BLUE 15


Ethyl benzyl aniline sulfonic acid (EBASA) condensation, and then (a) oxidation as dimer water

molecules (hydrol), again with N-N-diethylmeta toludine condensation, oxidation with

hydrogen peroxide in presence of copper sulphate and translated into sodium salt, spray dry it.

Chemical Reaction:

Mass Balance:




sulfonic acid

3900 Evaporation loss 8360

Di ethyl meta toluene 750

C.Lye 400

Ice 1200

Copper sulphate 60

Sodium thiosulphate 450

Total : 11960 11960

7. ACID VIOLET 17



molecules (hydrol), again with N-N-diethyl Aniline condensation, oxidation with hydrogen

peroxide in presence of copper sulphate and translated into sodium salt, spray dry it.

Chemical Reaction:

Mass Balance:


Water 4950 Acid Violet 17 2600


sulfonic acid

3900 Evaporate 9380

C.Lye 400

Formaldehyde 360

Ice 1200

Copper sulphate 60

Di ethyl Aniline 660

hydrogen peroxide 450

Total : 11980 11980

8. ACID VIOLET 49



molecules (hydrol), again with N-N-dimethyl Aniline condensation, oxidation with hydrogen

peroxide in presence of copper sulphate and translated into sodium salt, spray dry it.

Chemical Reaction:

Mass Balance:


Water 4840 Acid Violet 49 2550


sulfonic acid

3900 Evaporate 9260

C.Lye 400

Formaldehyde 360

Ice 1200

Copper sulphate 60

Di methyl Aniline 600

hydrogen peroxide 450

Total : 11810 11810

ANNEXURE-4

DETAILS OF WATER CONSUMPTION & WASTE WATER GENERATION

SR.

NO.

DESCRIPTION EXISTING

WATER CONSUMPTION

(KL/Day)

WASTE WATER

GENERATION (KL/Day)

1 Process 7.1 4.7

2 Boiler 1 0.1

3 Cooling 1 0.3

4 Washing 0.5 0.5

Total Industrial 9.6 5.6

5 Domestic* 2 1.6

6 Gardening 1 --

Grand Total 12.6 7.2

* Domestic waste water will be disposed through septic tank & soak pit.

Water Balance Diagram:

Source: Water Tanker

Water Requirement: 12.6 KLD

Domestic

2 KLD

Process

7.1 KLD

Cooling

Tower

1 KLD

Gardening

1 KLD

4.7 KLD 0.3 KLD

ETP: 5.6 KLD

Washing

0.5 KLD

0.5 KLD 1.6 KLD

Septic

tank & Soak

Pit

Boiler

1 KLD

0.1 KLD

Spray Dryer: 5.6 KLD

ETP Sludge and Spray

Dryer Sludge to TSDF site

ANNEXURE-5

DETAILS OF ETP, SPRAY DRYER

EFFLUENT TREATMENT PLANT (ETP).

First all wastewater streams of wastewater shall be collected in Collection Cum

Neutralization Tank-01 (CNT-01). where the continuous addition and stirring of Lime

solution is done to maintain neutral pH of wastewater from Lime Dosing Tank (LDT-01) as

per requirement by gravity. Mixer (M-01) is provided at bottom of the CNT-01 to keep all

suspended solids in suspension and to provide proper mixing.

Then after, neutralized wastewater shall be pumped to Filter Press-01 (FP-01) where, Poly

shall be added from Ploy Dosing Tank (PDT-01) with help of Poly Dosing Pump to increase

efficiency of Sludge dewatering. Dewatering of sludge shall be carried out in FP-01 before

storage in HWSA and ultimate disposal to TSDF. Clear effluent from FP-01 shall be collected

in Primary Treated Effluent Sump-01 (PTES-01). Then it will be pumped to Spray Dryer for

further treatment. Solids from SD-01 shall be storage in HWSA and ultimate disposal to

TSDF.

SIZE OF TANKS

S.N

. Name of unit

Size (m x m x

m) No. MOC/ Remark

Flow = 5.6 KLD(Proposed)

1 Collection cum Neutralization Tank-

01 (CNT-01) 10 KL 1 RCC M25

2 Filter Press-01 (FP-01) 5 KL/D 1 MS+PP

3 Treated Effluent Sump-01 (TES-01) 15 KL 1 RCC M25

4 Lime Dosing Tank (LDT-01) 500 lit 1 HDPE

5 Poly dosing Tank (PDT-01) 100 Lit 1 HDPE

6 Spray Dryer (SD-01) 10 KL/D 1 SS316

Process Flow Diagram:

ANNEXURE-6

DETAILS OF HAZARDOUS/SOLID WASTES GENERATION AND DISPOSAL MODE

SR.

NO.

TYPE OF WASTE CATEGOR

Y NO.

QUANTITY

(MT/MONTH)

DISPOSAL MODE

1 ETP Sludge 34.3

15 Collection, Storage, Transportation and sent

to common TSDF site for disposal.

2 Used Oil 5.1 0.1 Collection, Storage, Transportation and sell to

GPCB registered reprocess or/refiner.

3 Discarded

Drums/Container

s /Bags

33.1 10 Collection, Storage, Decontamination,

Transportation & sell to GPCB authorized

Vendor.

4 Spray Dryer Salt 34.3 18 Collection, Storage and sent to common TSDF

site for disposal.

5 Sodium Sulphate

Solution from

Scrubber

26.1 30 Collection, Storage and sell to end users

having Rule 9 Permission.

ANNEXURE-7

DETAILS OF HAZARDOUS CHEMICALS STORAGE AND HANDLING

Power Requirement & Fuel Requirement

Power required from MGVCL will be 60 HP

D. G. Set: 20 HP

Fuel

Imported Coal/PNG Gas/Agro Waste/Bio Coal: 1 MT/Day

HSD: 5 Liter/Hr

Flue Gas Emission:

Sr.

No.

Stack/Vent

attached to

Stack

Height

(meter)

Stack

Diameter

(meter)

Fuel name &

Quantity

Type of

Emission APCE

1. Boiler (0.8 TPH) 12 0.3

Agro waste /

Biofuel

(1 MT/Day) PM

SO2

NOx

Multicyclone

Separator

and Dust

Collector

2

D.G. Set

(Capacity – 20

HP)

11 0.1 Diesel

(5 Liter/hr)

Adequate

Stack Height

Process Gas Emission:

Sr.

No.

Stack/Vent

attached to

Stack

Height

(meter)

Stack

Diameter

(meter)

Type of

Emission APCE

1. Reaction Vessel 11 0.1 SO2

Two Stage

Alkali

Scrubber

ANNEXURE-8

DETAILS OF HAZARDOUS CHEMICALS STORAGE AND HANDLING

Sr.

No.

Name of the material Type of

hazard

Kind of

Storage

Max. Quantity to be

stored (MT)

No. of Tanks drums

or carboys

1 Sulfuric Acid Toxic Drum 5 25

2 Caustic Soda Toxic Drum 3 15

3 Sodium Sulfate Toxic Drum 3 15

4 Caustic Lye Toxic Drum 5 25

5 Di ethyl meta toluene Toxic Drum 4 20

6 Diethyl Aniline Toxic Drum 4 20

7 Hydrogen Peroxide Toxic Drum 3 15

ANNEXURE-10

SOCIO - ECONOMIC IMPACTS

1) EMPLOYMENT OPPORTUNITIES

The manpower requirement is expected to generate some permanent jobs and secondary jobs

for the operation and maintenance of plant. This will increase direct/indirect employment

opportunities and ancillary business development to some extent for the local population. This

phase is expected to create a beneficial impact on the local socio-economic environment.

2) INDUSTRIES

Require raw materials and skilled & unskilled laborers will be utilized maximum from local area.

The increasing industrial activity will boost the commercial and economical status of the locality,

to some extent.

3) PUBLIC HEALTH

The company will regularly examine, inspects and tests its emission from sources to make sure

that the emission will keep below the permissible limit. Hence, there will not be any significant

change in the status of sanitation and the community health of the area, as sufficient measures

will be taken under the EMP.

4) TRANSPORTATION AND COMMUNICATION

Since the existing site is having proper linkage for transport and communication, the

development of this project will not cause any additional impact.

In brief, as a result of the proposed expansion project, there will be no adverse impact on

sanitation, communication and community health, as sufficient measures will be proposed to be

taken under the EMP. Hence, proposed expansion project is not expected to make any significant

change in the existing status of the socio - economic environment of this region.

ANNEXURE – 11

PROPOSED DRAFT TERMS OF REFERENCE

1. Project Description

Justification of project.

Promoters and their back ground

Project site location along with site map of 10 km area and site details providing various

industries, surface water bodies, forests etc.

Project cost

Project location and Plant layout.

Infrastructure facilities

Water source and utilization including water balance.

List of Products & their production capacity

Details of manufacturing process of products

List of hazardous chemicals

Storage and Transportation of raw materials and products.

2. Description of the Environment and Baseline Data Collection

Micrometeorological data for wind speed, direction, temperature, humidity and rainfall in 5 km

area.

Other industries in the impact area

Prevailing environment quality standards

Existing environmental status vis a vis air, water, noise, soil in 10 km area from the project site.

Ground water quality at 5-6 locations within 10 km.

Complete water balance

3. Socio Economic Data

Existing socio-economic status, land use pattern and infrastructure facilities available in the study

area were surveyed.

4. Impacts Identification and Mitigatory Measures

• Identification of impacting activities from the proposed expansion project during construction

and operational phase.

• Impact on air and mitigation measures including green belt

• Impact on water environment and mitigation measures

• Soil pollution source and mitigation measures

• Noise generation and control.

• Hazardous/Solid waste quantification and disposal.

• Control of fugitive emissions

5. Environmental Management Plan

• Details of pollution control measures

• Environment management team

• Proposed schedule for environmental monitoring including

6. Risk Assessment

• Objectives, Philosophy and methodology of risk assessment

• Details on storage facilities

• Process safety, transportation, fire fighting systems, safety features and emergency capabilities to

be adopted.

• Identification of hazards

• Consequence analysis

• Recommendations on the basis of risk assessment done

• Disaster Management Plan.

7. Information for Control of Fugitive Emissions

8. Information on Rain Water Harvesting

9. Green Belt Development plan

ANNEXURE – 12

COPY OF LAND POSSESSION / PLOT ALLOTMENT DOCUMENT

CERTIFICATE FOR THE LAND USED FOR INDUSTRIAL PURPOSE.

ANNEXURE – 13

COPY OF COMMON TSDF MEMBERSHIP LETTER

ANNEXURE – 14

GOOGLE MAP

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