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Future Oil Future Oil MAXIMIZING OIL RECOVERY MAXIMIZING OIL RECOVERY EFFICIENCY AND SEQUESTRATION EFFICIENCY AND SEQUESTRATION Future Oil Recovery Efficiency 60%+ Future Oil Recovery Efficiency 60%+ EFFICIENCY AND SEQUESTRATION EFFICIENCY AND SEQUESTRATION OF CO OF CO 2 WITH “NEXT GENERATION” WITH “NEXT GENERATION” CO CO 2 -EOR TECHNOLOGY EOR TECHNOLOGY Today’s Oil Recovery Today’s Oil Recovery Presented by: Vello A. Kuuskraa, President Advanced Resources International Recovery Efficiency 33% Recovery Efficiency 33% Advanced Resources International [email protected] May 2008 JAF02742..PPT May 9, 2008 1 Advanced Resources International
Transcript

Future OilFuture Oil

MAXIMIZING OIL RECOVERY MAXIMIZING OIL RECOVERY EFFICIENCY AND SEQUESTRATIONEFFICIENCY AND SEQUESTRATION

Future OilRecoveryEfficiency60%+

Future OilRecoveryEfficiency60%+

EFFICIENCY AND SEQUESTRATION EFFICIENCY AND SEQUESTRATION OF COOF CO22 WITH “NEXT GENERATION” WITH “NEXT GENERATION” COCO22--EOR TECHNOLOGYEOR TECHNOLOGY

Today’s Oil RecoveryToday’s Oil Recovery

Presented by:

Vello A. Kuuskraa, PresidentAdvanced Resources International

RecoveryEfficiency33%RecoveryEfficiency33%

Advanced Resources [email protected]

May 2008

JAF02742..PPT May 9, 20081 Advanced Resources International

SPE DISTINGUISHED LECTURER SERIESis funded principally

through a grant of the

SPE FOUNDATIONThe Society gratefully acknowledges

those companies that support the programby allowing their professionalsby allowing their professionals

to participate as Lecturers.

JAF02742..PPT May 9, 2008

And special thanks to The American Institute of Mining, Metallurgical,

and Petroleum Engineers (AIME) for their contribution to the program.

BackgroundBackgroundBackgroundBackground

1. Status and Outlook for CO2-EOR2. “Next Generation” CO2-EOR Technology2 gy

• Increasing Oil Recovery Efficiency• Expanding CO2 Storage Capacityp g 2 g p y

3. Summary

JAF02742..PPT May 9, 20083

Large Volumes Of Domestic Oil Remain “Stranded” After Large Volumes Of Domestic Oil Remain “Stranded” After Primary/Secondary Oil RecoveryPrimary/Secondary Oil Recovery

Original Oil In-Place: 596 B Barrels*“St d d” Oil I Pl 400 B B l *“Stranded” Oil In-Place: 400 B Barrels*

Future Challenge390 Billion Barrels

Cumulative ProductionCumulative Production175 Billion Barrels

Proved Reserves21 Billion Barrels

JAF02742..PPT May 9, 20084

*All domestic basins except Deep Water GOM.Source: Advanced Resources Int’l. (2007)

U.S. COU.S. CO22--EOR ActivityEOR Activity

D k t C l

Number of CO2-EOR Projects

Natural CO2 Source

I d t i l CO S

105

Dakota CoalGasification

Plant

Antrim Gas

Industrial CO2 Source

CO2 Pipeline

LaBargeGas Plant

10 8

Antrim GasPlant

21 Currently 105 CO -EOR

JAF0199

Enid FertilizerPlant

Jackson

McElmo DomeSheep Mountain

Bravo Dome 7

11

Currently,105 CO2-EOR projects provide 250,000 B/D Affordable natural CO21994.CDR

Val VerdeGas Plants

JacksonDome

14

61

2 launched CO2-EOR activity in the 1980’sFederal tax credits

1

JAF02742..PPT May 9, 20085

(Sec.43) and state severance tax relief still encourage CO2-EORSource: Oil and Gas Journal, 2008.

Growth of COGrowth of CO22--EOR Production in the U.S.EOR Production in the U.S.22

300,000JAF2008008.XLS

200 000

250,000

cove

ry

y)

GULF COAST/OTHERMID-CONTINENTROCKY MOUNTAINSPERMIAN BASIN

150,000

200,000

ced

Oil

Re

arre

ls/d

ay

50,000

100,000

Enha

nc (b

01986 1988 1990 1992 1994 1996 1998 2000 2002 2004 2006 2008

Y

JAF02742..PPT May 9, 20086

Year

Source: Oil and Gas Journal, 2008.

Outlook For COOutlook For CO22--EOREOR

Recently updated study of applying “state-of-the-art” CO2-EOR in the U.S. indicate: 2

• 88 billion barrels of technically recoverable resource, • From 39 to 48 billion barrels of economically

recoverable resource depending on oil price and COrecoverable resource, depending on oil price and CO2costs.

Results are based on applying streamline i i l ti t 2 012 l il ireservoir simulation to 2,012 large oil reservoirs

(74% of U.S. oil production).

Previous version of the “basin studies” are available on the U.S. DOE web site. http://www.fe.doe.gov/programs/oilgas/eor/Ten_Basin-Oriented CO2 EOR Assessments html

JAF02742..PPT May 9, 20087

Oriented_CO2-EOR_Assessments.html

OneOne--Dimensional Schematic of the CODimensional Schematic of the CO2 2 Miscible ProcessMiscible Process

Miscibility is Developed in This Region(CO2 and Oil Form Single Phase)

Pure CO2 Vaporizing CO2C d i Original

CO2

2 p gOil Components Condensing

Into Oil

gOil

Direction of Displacement

JAF02742..PPT May 9, 20088

Domestic Oil Resources Technically and Domestic Oil Resources Technically and E i ll R bl /COE i ll R bl /CO EOREOREconomically Recoverable w/COEconomically Recoverable w/CO22--EOREOR

88.1

80

100

n Ba

rrels

47.4

40

60

Billio

n

2 320

40

2.30

TechnicallyRecoverable

EconomicallyRecoverable*

AlreadyProduced/

Proven

JAF02742..PPT May 9, 20089

*Assuming oil price of $70/B (real); CO2 costs (delivered to field at pressure) of $45/metric ton ($2.38/Mcf); investment hurdle rate (15%, real).

Market Demand for COMarket Demand for CO22 by the Enhanced Oil by the Enhanced Oil R I d tR I d t (1)(1)Recovery IndustryRecovery Industry(1)(1)

ns 10 000

12,000

14,00012,500

9,700

n Me

tric T

on

6,000

8,000

10,000 ,

7,500

Millio

n

2,000

4,000

,

2,800* 2,200**

Total U.S.CO2 Demand

NewLower-48

CO2 Demand

Net Lower-48From CapturedCO2 Emissions

0

JAF02742..PPT May 9, 200810

*CO2 demand in Alaska is already being met by on-going CO2-EOR projects**CO2 demand that can be met by natural CO2 and already being captured CO2 emissions.(1) Economic CO2 market demand for EOR at oil price of $70/B (real), CO2 cost of $45/mt, and ROR of 15% (real).

Sources of COSources of CO22

State/ Province State/ Province (storage location)(storage location)

Source Source (location)(location)

CO2 Supply MMcfd**CO2 Supply MMcfd**

NaturalNatural AnthropogenicAnthropogenic(storage location)(storage location) (location)(location) NaturalNatural AnthropogenicAnthropogenicTexas-Utah-New Mexico-

OklahomaGeologic (Colorado-New Mexico) Gas Processing (Texas) 1,700 110

Colorado Wyoming Gas Processing (Wyoming) 340Colorado-Wyoming Gas Processing (Wyoming) - 340Mississippi Geologic (Mississippi) 700 -Michigan Gas Processing Plant (Michigan) - 15Oklahoma Fertilizer Plant (Oklahoma) - 35Saskatchewan Coal Gasification (North Dakota) - 145

TOTAL 2 400 645TOTAL 2,400 645

* Source: 12th Annual CO2 Flooding Conference, Dec. 2006** MMcfd of CO2 can be converted to million metric tons per year by first multiplying by 365 (days per year) and then dividing by 18.9 * 103 (Mcf per metric ton).

JAF02742..PPT May 9, 200811

Are Higher Oil Recovery Efficiencies Achievable?Are Higher Oil Recovery Efficiencies Achievable?e g e O eco e y c e c es c e ab ee g e O eco e y c e c es c e ab e

Example Carbonate Field Oil Recovery Efficiencies

80%S lt C k

Jayy

Fact

or

Salt Creek

Means

Rec

over

y

Time

2003 Recovery

JAF02742..PPT May 9, 200812

Source: Three ExxonMobil Oil Fields, SPE 88770 (2004)

Time

BackgroundBackground

Means San Andres Unit

BackgroundBackground

Th M il fi ld i l t d i th• The Means oil field is located in the West Texas portion of the Permian Basin, near Midland (Andrews County) Texas.Cou ty) e as

• The field is located along the eastern edge of the Central Basin Platform.

Th fi ld di d i 1934• The field was discovered in 1934 and developed on 40-acres well spacing in the 1950s. Water injection began in 1963, using an 80-j g , gacre inverted nine-spot pattern.

• A full-scale CO2 miscible flood was initiated in 1983 in the upper zones of the Means San Andres Unit encompassing 8 500 acres and holding 230

JAF02742..PPT May 9, 200813

the Means San Andres Unit, encompassing 8,500 acres and holding 230 MMB of OOIP.

Reservoir PropertiesReservoir Properties

Means San Andres Unit

Reservoir PropertiesReservoir Properties

• The Grayburg/San Andres formations are at depths ranging

Reservoir Depth, ft* 4,400Area acres formations are at depths ranging

from 4,200 to 4,800 feet.

• Significantly, the reservoir’s oil is 29o API with a viscosity of 6 cp

Area, acres- Field 14,300- Unit 8,500Net Pay, Ft 29 API with a viscosity of 6 cp.

The minimum miscibility pressure (MMP) is 2,000 psi.

• The reservoir has a net pay of 54

- Upper San Andres 54- Total 120(e)Average Porosity, % 9%

The reservoir has a net pay of 54 feet in the Upper San Andres Flow Unit (within a 300 foot gross interval), a porosity of 9% and a

bilit f 1 t 20 d

Average Permeability, md 1Initial Water Saturation 0.29Initial Formation Volume Factor 1.04

permeability of 1 to 20 md.Initial Reservoir Pressure, psig 1,850Current Reservoir Pressure, psig 2,000Reservoir Temperature, oF 105Oil G it API 29

JAF02742..PPT May 9, 200814

Oil Gravity, oAPI 29Oil Viscosity, cp 6

COCO22--EOR DevelopmentEOR DevelopmentMeans San Andres Unit

22 pp

• The CO2-EOR WAG process was implemented as part of an integrated reservoir development plan which included infill drilling improved waterflooding, and pattern modification:

Means-San Andres

Cumulative Oil Recovery vs. CO2

Bank Size

2:1 WAG Ratio

– 205 new producers– 158 new injectors

• Currently, the project produces 10,000 B/D of il d148 000 B/D f toil and148,000 B/D of water:

– 1,300 B/D (infill/secondary)– 8,700 B/D (CO2-EOR)

• The initial plan was to inject 250 Bcf of CO2The initial plan was to inject 250 Bcf of CO2, equal to 55% HCPV, at a 2:1 WAG ratio.

• Latest CO2 injection volumes, assuming injection of 60 to 70 MMcfd (88% CO2), will be 450 t 500 B f ( 1 HCPV)

JAF02742..PPT May 9, 200815

450 to 500 Bcf (~1 HCPV).Effect of Solvent Bank Size on Oil Recovery

SummarySummary

Means San Andres Unit

SummarySummary

• The Means case study is an example of effectively l i CO EOR t hi h i it l API it ilapplying CO2-EOR to a high viscosity, low API gravity oil

reservoir with an underlying weak aquifer.

• An integrated infill drilling and CO2 WAG flood has raisedAn integrated infill drilling and CO2 WAG flood has raised oil recovery efficiency from about 25% to an expected 50%.

• Of the 25% of OOIP increase in recovery efficiency, 15% OOIP is due to CO2-EOR and 10% OOIP is due to infill development associated with CO2-EOR.

JAF02742..PPT May 9, 200816

BackgroundBackground

Salt Creek

gg

The Salt Creek Field is located in the Permian Basin of West Texas (Kent (County, Texas). With 700 million barrels of OOIP, it is one of the major oil fields located on the northeast end of the Horseshoe Atoll oil play

Salt Creek Field

Horseshoe Atoll oil play.

The field produces from a Pennsylvanian-age Canyon Reef carbonate at a depth of 6 300 feetcarbonate at a depth of 6,300 feet.

The 12,100-acre field contains two limestone build-ups, not in pressure communication.communication.

Oil production at Salt Creek began in 1950. A centerline waterflood was started in 1953.

T ti il (CO WAG) b i 1993 i th i

JAF02742..PPT May 9, 200817

Tertiary oil recovery (CO2 WAG) began in 1993 in the main pay zone (MPZ) and later expanded to the residual oil zone (ROZ) in 2000.

Reservoir PropertiesReservoir Properties

Salt Creek

Reservoir PropertiesReservoir Properties

• The Salt Creek Canyon Reef formation is a multi layered

Reservoir Interval, ft* 6,200-6,700formation is a multi-layered reservoir, with a gross interval of 250 to 300 feet, thickening to over 600 feet in the northern

Area, acres 12,100

Net Pay, Ft 100

Average Porosity, % 11

A P bilit d 20 portion of the main area.

• The oil is light (39o API, 0.53 cp viscosity) with a miscibility

f 1 800 i

Average Permeability, md 20

Initial Water Saturation 0.19

Initial Formation Volume Factor 1.2

pressure of 1,800 psi.

• The field averages 100 feet of net pay, 11% porosity and 20 md permeability (with 1 to

Initial Reservoir Pressure, psig 2,915

Current Reservoir Pressure, psig 3,150

Reservoir Temperature, oF 129 md permeability (with 1 to 2,000 md of permeability in individual flow units).

Oil Gravity, oAPI 39

Oil Viscosity, cp 0.53*Includes ROZ interval from 6,500’ to 6,700’.

JAF02742..PPT May 9, 200818

COCO22--EOR Reservoir ManagementEOR Reservoir Management

Salt Creek

COCO22 EOR Reservoir ManagementEOR Reservoir Management

• Assure reservoir pressure exceeds MMP (of 1,800 psi) in all areas of the field.Schematic of Salt Creek , p )

• Assure fluid injection (I) rates balance (or exceed) fluid withdrawal (W) rates, on both pattern and field levels.

Shut-InI ffi i W ll

Step OneStep Five

Schematic of Salt Creek Reservoir Management Process

• Stimulate wells to improve injectivity; convert producers to injectors to assure I/W fluid balance.

• Start WAG process when first breakthrough

Inefficient Wells

WAGManagement

Workovers

Simulation Models Reservoir

Step Two

Start WAG process when first breakthrough of CO2 is observed (almost immediately at Salt Creek).

• Reduce CO2 injection and increase the WAG ti th fl d t

Bottom Hole PressureManagementGeologic Model

Management

Step Three

ratio as the flood matures.

• Hold weekly meetings with field operations staff to update and optimize the WAG process at a pattern level.

Injection Profile Logs

ProductionProfile Logs

Step Four

JAF02742..PPT May 9, 200819

Production History and ExpectationsProduction History and Expectations

Salt Creek

Production History and ExpectationsProduction History and Expectations

Salt Creek Field Oil Recovery F t b P

Actual and Expected Oil Recovery (MMB)

Primary/Factor, by Process

35

30

70

60

ate

er D

ay

erce

ntCarbon Dioxide/Water-Alternating-Gas

And Infill Drilling

Totaly

Secondary CO2-EOR

OOIP 700

Cum. Recovery (2003) 370 328 42

EUR 460 340 120

• Primary and secondary oil recovery, has produced and proven 336 million barrels

20

25

15

10

40

50

30

20

Oil P

rodu

ctio

n Ra

Thou

sand

Bar

rels

Pe

Reco

very

Fac

tor,

Pe

Primary Waterflood

Waterflood Optimization

And Infill DrillingEUR 460 340 120

%OOIP 66% 48% 17%

produced and proven 336 million barrels, 48% of OOIP.

• The CO2-EOR project is expected to recover an additional 120 million barrels,

5

0

10

01950 1960 1970 1980 1990 2000 2010 2020 2030

Year

Primary Waterflood

Source: Wilkinson, J.R., ExxonMobil Production Company; et. al., SPE paper 88770,”Lessons Learned from Mature Carbonates for Application to Middle East Fields” presented at the SPE 11th Abu Dhabi

18% of OOIP.

• Production is currently 7,700 B/D oil, plus gas plant liquids.

from Mature Carbonates for Application to Middle East Fields , presented at the SPE 11 Abu Dhabi International Petroleum Exhibition & Conference, Abu Dhabi, 10-13 October 2004.

JAF02742..PPT May 9, 200820

• The EOR project plans to inject about 1,200 Bcf of CO2, equal to 0.8 HCPV for a gross CO2/oil ratio of 13 Mcf/B.

SummarySummary

Salt Creek

SummarySummary

• The Salt Creek case study demonstrates that high oil• The Salt Creek case study demonstrates that high oil recovery efficiencies, in excess of 60% of OOIP, are achievable from a multi-layer, highly heterogeneous carbonate reservoir using optimized water flooding, ca bo ate ese o us g opt ed ate ood g,infill drilling and CO2-EOR.

• The CO2-EOR project is expected to recover 17% of OOIP (in addition to a high 48% of OOIP with P/SOOIP (in addition to a high, 48% of OOIP with P/S recovery) at a gross CO2 to oil ratio of 13 Mcf/B and a net ratio estimated at about 5 Mcf/B.

• A formal CO flood tracking system (Zonal Allocation• A formal CO2 flood tracking system (Zonal Allocation Program) and weekly team meetings are used to alter CO2 injection volumes, improve vertical conformance and optimize oil production

JAF02742..PPT May 9, 200821

and optimize oil production.

Postle COPostle CO22--EOR ProjectEOR Project22 jj

The Postle CO2-EOR project, operated by Whiting Petroleum coversoperated by Whiting Petroleum, covers an area of 18,000 acres.

CO2 injection, currently at about 120 MMcfd (including recycled CO2), is into the Morrow Sandstone at 6,200 feet. CO2 is transported via a 120 mile TransPetco CO2 pipeline.

The reservoir has light oil (40o API),The reservoir has light oil (40 API), low oil viscosity (1 cp), with adequate porosity (16%) and permeability (35 to 50 md).

Incremental oil production of 6 200Incremental oil production of 6,200 B/D is up from 4,200 B/D a year ago and is expected to climb to 8,500 B/D by 2012.

JAF02742..PPT May 9, 200822

Source: Whiting Petroleum, 2008Net production numbers are in thousands of barrels of oil equivalent per day.

Development Plans Development Plans –– Postle FieldPostle Field($ in Millions)($ in Millions)( )( )

JAF02742..PPT May 9, 200823

Source: Whiting Petroleum, 2008

“Next Generation” CO“Next Generation” CO22--EOR TechnologyEOR TechnologyNext Generation CONext Generation CO22 EOR TechnologyEOR Technology

Reservoir modeling and selected field tests showReservoir modeling and selected field tests show that high oil recovery efficiencies are possible with innovative applications of CO2-EOR.

So far, except for a handful of cases, the actual performance of CO2-EOR has been less than optimum due to:due to:

• Geologically complex reservoirs• Limited process control • Insufficient CO2 injection

JAF02742..PPT May 9, 200824

Impact of Geologic Complexity on COImpact of Geologic Complexity on CO22--EOR PerformanceEOR Performance

Inability to target injected CO2 to reservoir strata with high residual oil saturation.

Hi h il t ti ti f i CO h li d d ith ll

Well 27-6 Injection ProfileRelative Location of the Water Front

• Higher oil saturation portion of reservoir is inefficiently swept;

• CO2 channeling reduced with well workover.

pth

6,350(Before) (After)368 Days

Layer 1 (High Sor, Low k)Layer 2 (Low Sor, High k)Water

Dep

1839 Days

478 Days(Breakthrough)

0 20 40 60 80 1006,900

% Injected Before0 20 40 60 80 100

% Injected After

1839 Days(Channeling in Layer 2)

0 100 200 300Distance, ft

JAF02742..PPT May 9, 200825

Source: “SACROC Unit CO2 Flood: Multidisciplinary Team Improves Reservoir Management and Decreases Operating Costs”, J.T. Hawkins, et al., SPE Reservoir Engineering, August 1996.

Source: Adapted by Advanced Resources Int’l from “Enhanced Oil Recovery”, D.W. Green and G. P. Willhite, SPE, 1998.

,

Impact of Limited Process Control on Impact of Limited Process Control on COCO22--EOR PerformanceEOR PerformanceCOCO22 EOR PerformanceEOR Performance

Injected CO2 achieves only limited contact with

Oil and Wateronly limited contact with the reservoir due to:

• Viscous fingering G i idWater • Gravity override

Addition of viscosity enhancers would improve

Water

Waterflood(High Mobility Ratio)

mobility ratio and reservoir contact. Oil and Water

Polymer

Water

yIn Water

JAF02742..PPT May 9, 200826

Source: Adapted by Advanced Resources Int’l from “Enhanced Oil Recovery”, D.W. Green and G. P. Willhite, SPE, 1998.

Viscosity Enhanced Flood(Improved Mobility Ratio)

Impact of Limited Pressure Control on Impact of Limited Pressure Control on COCO22--EOR PerformanceEOR Performance22

Analysis of past CO2fl d l h th t i

SACROC Unit 1992 Pressure Contour Map.

floods also shows that, in many cases, the CO2-EOR project was operated below miscibility pressure in y ppositions of the reservoir.

This was caused by low well operating pressures, too few injection wells, and failure to maintain a favorable fluid balance.

Crosshatch shading indicates areas below MMP (2 300 psig) and solid

JAF02742..PPT May 9, 200827

Crosshatch shading indicates areas below MMP (2,300 psig) and solid shading indicates areas below bubblepoint pressure (1,850 psig).

Impact of Insufficient COImpact of Insufficient CO22 Injection on Injection on COCO22--EOR PerformanceEOR Performance

Because of high CO2 costs and lack of process control, most older CO2 floods used too little CO2.

Means (San Andres) @ 2:1 WAG Ratio1.0

0.9

Injected CO2 vs Oil RecoverySweep Efficiency in Miscible Flooding

25

0.8

0.7

0.6

0 5 VEffic

ienc

y, E

A 20

15

cove

ry -

% O

OIP

0.8 HCPV

0.6 HCPV

0.5

0.4

0.3

0.2

5.0

2.0

3.0

1.0

V pD

1.5

0.6

Swee

p E V

at B.T. vs. M

pD

10

5ntal

Ter

tiary

Rec 0.4 HCPV

0.2 HCPV

Note: VpD is displaceable fluid pore volumes of CO2 injected.

0.1

00.20 0.5 1 2 105 5020 200100 1000500

0.10.2

Mobility Ratio, M

0403020 50100

Years

Incr

eme

JAF02742..PPT May 9, 200828

Source: Claridge, E.L., “Prediction of Recovery in Unstable Miscible Displacement”, SPE (April 1972).

Source: SPE 24928 (1992)

“Next Generation” CO“Next Generation” CO22--EOR TechnologyEOR TechnologyNext Generation CONext Generation CO22 EOR TechnologyEOR Technology

Over coming these technical barriers requires

I ti Fl d D i d W ll Pl t Addi h i t l

Over coming these technical barriers requires “next generation” CO2-EOR technology:

• Innovative Flood Design and Well Placement. Adding horizontal production wells and vertical CO2 injection wells, enabling CO2 to contact residual oil from poorly swept portions of the reservoir.

• Viscosity and Miscibility Enhancement. Adding mobility control withViscosity and Miscibility Enhancement. Adding mobility control with viscosity enhancers and lowering MMP with miscibility enhancers.

• Increased Volume of CO2 Injection. Injecting up to 1.5 HCPV of CO2.• Flood Performance Diagnostics and Control. Fully staffed technical g y

team. Uses instrumented observation wells and downhole sensors to monitor progress. Conducts periodic 4-D seismic and pressure plus zone-by-zone flow tests (among others) to “manage and control” the CO2 flood.

JAF02742..PPT May 9, 200829

“Game Changer” CO“Game Changer” CO --EOR TechnologyEOR TechnologyGame Changer COGame Changer CO22--EOR TechnologyEOR Technology

The DOE report, “Evaluating the Potential for “Game Changer”

R i f f t CO EOR fl d

g gImprovements in Oil Recovery Efficiency from CO2-Enhanced Oil Recovery”:

• Reviews performance of past CO2-EOR floods.

• Sets forth theoretically and scientifically possible advances in technology for CO2-EOR.

• Examines how much “game changer” CO2-EOR technology would increase oil recovery and CO2storage capacity. storage capacity.

Available on the U.S. DOE web site. http://www.fe.doe.gov/programs/oilgas/publications/eor_co2/G Ch D t df

JAF02742..PPT May 9, 200830

2/Game_Changer_Document.pdf

Domestic Oil Resources Technically Recoverable Domestic Oil Resources Technically Recoverable /”N t G ti ” CO/”N t G ti ” CO EOREORw/”Next Generation” COw/”Next Generation” CO22--EOREOR

“Next Generation” CO2-EOR would significantly e t Ge e at o CO2 O ou d s g ca t yimprove domestic oil recovery efficiency.

Technically Recoverable

BasinStudies

OOIP(BBbls)

FavorableReservoirs

(#)

Technically Recoverable

State-of-the-Art(BBbls)

Next Generation(BBbls)

Six Basins* 309 553 43.3 83.7

Eleven Basins** 596 1 111 88 1 ?Eleven Basins 596 1,111 88.1 ?*”Evaluating the Potential for “Game Changer” Improvements in Oil Recovery Efficiency from CO2 Enhanced Oil Recovery”, Advanced Resources International, report prepared for the U.S. DOE, Office of Oil and Natural Gas, Office of Fossil Energy, August 2005. http://www.fe.doe.gov/programs/oilgas/eor/Game_Changer_Oil_Recovery_Efficiency.html. **“Storing CO2 with Enhanced Oil Recovery” Advanced Resources International, report prepared for U.S. DOE/NETL, Office of Systems,

JAF02742..PPT May 9, 200831

Analyses and Planning, DOE/NETL-402/1312/02-07-08, February 7, 2008. http://www.netl.doe.gov/energy-analyses/pubs/Storing%20CO2%20w%20EOR_FINAL.pdf.

Integrating COIntegrating CO22--EOR and COEOR and CO22 StorageStorage

Expanding CO2 Storage Capacity: A Case Study. Large Gulf C t il i ith 340 illi b l (OOIP) i th iCoast oil reservoir with 340 million barrels (OOIP) in the main pay zone.

• Primary/Secondary Oil Recovery: 153 million barrels (45% of OOIP)

• Main Pay Zone:– Depth - - 14,000 feet

– Oil Gravity - - 33oAPI

– Net Pay - - 325 feet– Initial Pressure - - 6,620 psi

– Porosity - - 29% – Miscibility Pressure - - 3,250 psi

Another 100 million barrels (OIP) in the underlying 130 feet of

Theoretical CO2 storage capacity: 2,710 Bcf (143 million tonnes)

( ) y gresidual oil zone and an underlying saline reservoir 195 feet thick.

JAF02742..PPT May 9, 200832

Integrating CO2-EOR Storage

First, this Gulf Coast oil reservoir is produced using “state-of-the-art” CO2-EOR project design - - vertical wells, 1 HCPV of CO2(purchased and recycled CO2), and a 1:1 WAG.

Next this Gulf Coast oil reservoir is produced using “nextNext, this Gulf Coast oil reservoir is produced using next generation” CO2-storage and CO2-EOR project design.

• Gravity-stable vertical CO2 injection with horizontal wells• Gravity-stable, vertical CO2 injection with horizontal wells.

• Targeting the main pay zone, plus the transition/residual oil zone and the underlying saline aquifer.

• Injecting continuous CO2 (no water) and continuing to inject CO2 after completion of oil recovery.

JAF02742..PPT May 9, 200833

Integrating COIntegrating CO22--EOR and COEOR and CO22 StorageStorage (Cont’d)

CO2 SourceCO2 SourceOil to MarketOil to Market Production WellProduction Well

CO2Injection

CO2Injection

COCOCO2Recycled

CO2Recycled

Swept AreaSwept Area

Current Water Oil Contact

Current Water Oil Contact

Original Water

Original Water

Stage #1Stage #1

Stage #2Stage #2Unswept AreaUnswept Area

Oil BankOil Bank

JAF02742..PPT May 9, 200834

WaterOil Contact

WaterOil Contact Stage #3Stage #3TZ/ROZTZ/ROZ

Saline ReservoirSaline Reservoir

Integrating COIntegrating CO22--EOR and COEOR and CO22 StorageStorage

Integrating CO2-EOR and CO2 Sequestration shows that much more CO2 can be stored, making the additional oil produced “GREEN OIL”*.2 , g p

“State of the Art” “Next Generation”

(millions) EOR Seq Total(millions) EOR Seq. Total

CO2 Storage (tonnes) 19 76 33 109

Storage Capacity Utilization 13% 52% 24% 76%Storage Capacity Utilization 13% 52% 24% 76%

Oil Recovery (barrels) 64 180 - 180

% Carbon Neutral (“Green Oil”) 70% 100% - 160%( )*”Green Oil” means that more CO2 is injected and stored underground than the volume of CO2 contained in the produced oil, once burned.

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Weyburn Enhanced Oil Recovery ProjectWeyburn Enhanced Oil Recovery Project(An Operating Project Maximizing Oil Recovery and CO2 Storage)

• Largest CO2 EOR project in Canada:– OOIP 1.4 Bbbls

155 Mbbls incremental– 155 Mbbls incremental

• Outstanding EOR response • World’s largest geological CO2

sequestration projectq p j– 2.4 MMt/year (current)– 7 MMt to date– 23 MMt with EOR

55 MMt ith EOR/ t ti

Regina

WeyburnCanada

– 55 MMt with EOR/sequestrationWeyburn

Saskatchewan ManitobaCanadaUSA

USA

Beulah

North DakotaMontana

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CO2Beulah

Source: EnCana, 2005

SummarySummary1 CO enhanced oil recovery while still an1. CO2 enhanced oil recovery, while still an

emerging industry, has the potential to add significant volumes of future oil supply, in the U.S. and worldwide.

2. Thirty years of experience shows that CO2-EOR is a technically sophisticated and challenging process, but one that can be successful if “managed and controlled”, not just “operated”.

3. “Next Generation” CO2-EOR technologies, incorporating scientifically possible but not yet f ll d l d d ld i ifi tlfully developed advances, could significantly increase oil recovery efficiency.

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SummarySummary (Cont’d)

4 Wide scale application of CO EOR is constrained by4. Wide-scale application of CO2-EOR is constrained by lack of sufficient “EOR-Ready” CO2 supplies. A mutually beneficial link exists between CO2-EOR and new industrial sources of CO2.

5. Under a “carbon constrained world”, productively using industrial CO2 emissions for CO2-EOR will become a winning strategy.

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