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g - Biogeochemical Cycles Group 7

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    BIOGEOCHEMICAL CYCLES

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    Nutrient Cycles in Nature A biogeochemical cycle or nutrient cycle

    is a pathway by which a chemical

    element or molecule moves throughboth biotic (biosphere) and abiotic

    (lithosphere, atmosphere, and

    hydrosphere) compartments of Earth.

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    It is

    Bio because it involves the biota

    Geo because it involves the earthsrocks, soil, water and air

    Chemicalbecause it involves

    chemical nutrients undergoing

    changes as they go through the cycle

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    Patterns and Components Populations, communities all interact with the

    environment.

    A key part of the interaction is the cycling of

    nutrients through different populations and

    trophic levels in an ecosystem; and thru this

    the living and non-living world maintains

    ecological balance.

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    A nutrient cycle is composed of:

    Exchange (cycling or available) pool, the fast-

    moving part of the cycle which involves the

    trophic levels; and Reservoirs (nutrient or unavailable pool),

    where the element is accumulated or held for

    a long period of time.

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    Biogeochemical cycles always involve

    equilibrium states :

    A balance in the cycling of the element

    between compartments.

    However, overall balance may involvecompartments distributed on a global

    scale.

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    Types of Cycles There are two main types of cycles based on

    the reservoir of the element.

    Gaseous Cycle. This is when the element ismainly stored in the atmosphere or

    hydrosphere, e.g. carbon and nitrogen cycles

    Sedimentary Cycle. This is when the element

    is stored in the lithosphere a sedimentaryrocks, e.g. phosphorus and sulfur cycles

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    Systems All chemical elements in

    an organism is part of thenutrient cycle.

    Closed System. Allnutrients used by theorganism operate on aclosed system, therefore

    these chemicals arerecycled instead of beinglost.

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    Open System. The energy

    of an ecosystem occurs onan open system; the sun

    constantly gives the

    energy in the form of light

    while it is eventually used

    and lost in the form of

    heat through the trophic

    levels of food chains and

    webs.

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    Water Cycle The water or hydrologic cycle is unique

    because water exists in three phases solid,

    liquid and gas during the cycles.

    Water exists naturally at all temperatures

    which occur on earth and can easily change

    from form to another.

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    Evaporation. Heat causes liquid water to

    change to gas (water vapor) and rises to the

    atmosphere.

    Condensation. As water goes up it reaches a

    point where temperature is low and form

    droplets called clouds in a process called

    condensation.

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    Dew which forms earlymorning is condensation

    of vapor coming incontact with coldsurfaces.

    Fogs are low-lying clouds;occurs whencondensation is close tothe surface as in the caseof highlands.

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    Saturation. As more watervapor fills in the

    atmosphere, it reaches apoint where it could nolonger hold more vapor.

    This is a state calledsaturation.

    Humidity refers to theamount of moisture in theatmosphere.

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    Precipitation. Droplets of watercondense around dust particles

    (the condensation nuclei) untilthey are too large to withstandthe pull of gravity.

    When too heavy, they fall to thesurface as precipitates like snow,hailstones or rain.

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    Run-off. Precipitates reaching

    the surface move down a

    body of land as surface waterrun-off through specific paths

    as channel flow or move

    anywhere as overland flow.

    Lakes , streams , ponds and

    other forms of surface waterare manifestations of this part

    of the water cycle.

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    Percolation. Gravity and soil porosity move

    some water molecules down to thegroundwater reservoir in a process called

    percolation or infiltration.

    Capillary action. Increased pressure may

    move groundwater upward to become springs

    and artesian wells.

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    Surface and ground water all flow toward the

    sea, which supplies 90 % of all water that thatstart the process of evaporation again.

    When temperatures are too high, precipitatesmay evaporate and does not reach the

    surface.

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    Carbon Cycle In the carbon cycle, plants absorb carbon

    dioxide from the atmosphere and use it,

    together with water so photosynthesis could

    take place.

    Carbon molecules are assembled into sugar

    and other organic molecules which all living

    things need to survive.

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    Photosynthesis. Carbon molecules become

    part of molecules of carbohydrates and may

    later be changed to other organic compounds.

    The carbon becomes part of the energy

    system for ecosystems, the carbohydrates,

    lipids and hydrocarbons being forms of stored

    energy.

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    Respiration. Carbon molecules travel through

    the food chains, with decomposers at any stepof the way.

    Oxygen is taken in respiration to oxidizecarbohydrates to transfer energy in the form

    of Adenosine triphosphate (ATP) and the

    release of carbon dioxide back to the

    environment.

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    Decomposition. Carbon in animals stay in its

    bones as carbonates until they undergo

    decomposition after the death or via waste

    matter in excretion.

    Sedimentation. Bones and shells of calcium

    carbonate may accumulate in the lithosphere

    by sedimentation as sediments and fossils.

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    Combustion. Incineration (combustion) or

    burning is a form of rapid oxidation, whichreturns carbon dioxide back to the

    atmosphere.

    Fossil fuels, cloth, dead bodies, fuel return

    carbon dioxide via burning.

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    Oxygen Cycle The oxygen cycle involves three main

    reservoirs - atmosphere, biosphere, and

    lithosphere, with photosynthesis as the main

    driving factor.

    This explains that the cycles of oxygen and

    carbon dioxide are closely linked.

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    Photosynthesis.

    Oxygen is released

    during the light-dependent reactions

    when water undergoes

    photolysis.

    Respiration. Oxygen is

    removed from theatmosphere by

    respiration; carbon

    dioxide is released.

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    Decomposition. Bacteria consume oxygen

    from the environment as they work during theprocess of decomposition; carbon dioxide is

    released.

    Oxidation. The slow oxidation process of

    rusting and the rapid oxidation process of

    combustion remove oxygen from the

    environment.

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    Flux between Biosphere and Lithosphere.

    Marine organisms create calcium carbonate

    shells that is rich in oxygen; when they die

    their shells are deposited and become

    limestone rocks of the lithosphere.

    Weathering process can free oxygen from the

    lithosphere; plants also extract minerals from

    rocks and release oxygen in the process aswell.

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    Nitrogen Cycle The nitrogen cycle involves the earths

    atmosphere which is about 78 % nitrogen.

    Nitrogen is of no use by itself for most living

    things and when animals breathe it, it goes

    back out again; however, nitrogen is vital to

    life when combined with other elements.

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    Nitrogen Fixation. Gaseous nitrogen in the

    atmosphere is incorporated into the nitrogen-containing compounds and thereby brought

    into the soil and the exchange pool.

    To a small extent, the abiotic processes of

    lightning and flash photography can provide

    energy for fixation to occur.

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    Most fixation is done bythe biological activities ofnitrogen-fixing bacteria

    (e.g. Rhizobium in the rootnodules of legumes) andcyanobacteria (blue-green

    algae) of OrderNostocales.

    90 % of nitrogen in the soilcomes from biologicalorigin; the rest comes fromchemical fertilizers.

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    Ammonification. Soil

    bacteria and fungidecomposing dead

    matter utilize the

    proteins and aminoacids as source of

    food, releasing excess

    nitrogen as ammonia(NH3) and ammonium

    (NH4) in the soil.

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    Nitrification. Ammonia orammonium is oxidized by

    several species of nitrifyingbacteria in the soil.

    One group convertammonia or ammoniuminto nitrite (NO2); in turnanother group converts

    nitrites to nitrate (NO3) , aform that could be absorbedby plants

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    Absorption and Assimilation. Absorbed

    materials are utilized in cell metabolism.

    One process converts nitrogen back to

    ammonium; ammonium ions formed are

    transferred to carbon-containing compoundsto produce amino acids and other nitrogenous

    compounds.

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    Denitrification. Denitrifying bacteria

    especially in boggy, poorly aerated soil, reducethe nitrates to gaseous nitrogen, thus

    returning it to the atmospheric reservoir.

    Note that in almost every step of the cycle,

    microorganisms are involved.

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    Weathering and Erosion. Phosphates in rocks

    gets exposed to the surface and gets carried

    away by the erosive action of water.

    Leaching. Phosphorus together with otherminerals get carried by flowing water from the

    soil and gets transferred to soil and streams

    on their way to the sea.

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    Phosphorus in food chain. Phosphorus in thewater may get into the flesh of aquatic

    invertebrates, then to small vertebrates, then

    to other predators by ingestion.

    Excretion and Decomposition. Phosphorus

    within the living body can be released viaexcretion of waste; or when a dead body

    undergoes decomposition.

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    Guano (Quechua 'wanu', via Spanish) is thewaste (feces and urine) of cave dwelling

    insectivorous bats, seabirds, and seals.

    Guano manure is an effective fertilizer and

    gunpowder ingredient due to its high levels ofphosphorus and nitrogen.

    Soil that is deficient in organic matter can bemade more productive by addition of thismanure.

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    Human Interference.Human interference in

    the cycle occurs byoveruse or careless useof phosphorusfertilizers.

    This results in increasedamounts of phosphorus

    as pollutants in bodiesof water resulting ineutrophication.

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    Chemosynthesis. Plants cannot use elemental

    sulfur, so all living things depend upon

    chemoautotrophic bacteria to oxidizeelemental sulfur to sulfates, which then could

    become organic sulfur (as part of proteins)

    that goes with the food chains and webs.

    Excretion and Decomposition return sulfur

    back to the lithosphere.

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    Earth constantly receives energy

    from the sun, it's chemical

    composition is essentially fixed,

    as additional matter is onlyoccasionally added by

    meteorites.

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    END of LESSON


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