FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UCHA 501 IOC Subject Name Inorganic Chemistry
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 3 -- -- -- 3 Theory 40 60 100
Hours 3 -- -- -- 3 Practical -- -- --
Pre-requisites:
Before studying Inorganic chemistry, all students have basic knowledge of inorganic and organic compounds, periodic table, molecular structure, Molecular orbital theories and knowledge related to UG level chemistry.
Learning Outcome:
Knowledge of reactions and mechanism of coordination compounds.
Introduction and classification of organometallic compounds.
Understanding of structure and bonding in organometallic compounds.
Knowledge of principle, types and prevention of corrosion.
Theory syllabus
Unit Content Hrs
1 Reaction mechanism of coordination compounds
Substitution reaction of square planar complexes
Reaction of Platinum II complexes, the trans effect, theories of trans effect, use of synthesis in trans effect and analysis
Substitution reaction in octahedral complexes, Possible mechanism reactions, Ligand displacement reaction in octahedral complexes, acid hydrolysis, Base Hydrolysis
Electron transfer reaction, mechanism of redox reaction, mechanism of
substitution in square planar complexes
15
2 Organo Metallic Compounds
Definition
Types of O.M.C.
Classification
Nomenclature of O.M.C
Structure and bonding in dihapto and metal olefins complexes. e.g. Ziese’s salt complexes, Ferrocene structure
O.M.C. of Li and Al complexes
15
3 Corrosion
Principle of corrosion
Types of corrosion (i) Wet corrosion (ii) Galvanic corrosion (iii) Atmospheric corrosion
15
(iv) Pitting corrosion (v) Inter granual corrosion (vi) Dezincification
Prevention of corrosion: Inhibitors- Definition, type and use of inhibitors.
Text Books
1 Valance and molecular structure by Cartmell and Flower.
2 Text book of Inorganic Chemistry by Durent and Durent.
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UCHA 502 ORC Subject Name Organic Chemistry
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 3 -- -- -- 3 Theory 40 60 100
Hours 3 -- -- -- 3 Practical -- -- --
Pre-requisites:
Before studying organic chemistry, all students have basic knowledge of general organic chemistry. Students should have the deep knowledge about the elementary organic chemistry at the UG level.
Learning Outcome:
Understanding of stereochemistry and conformational analysis of various organic compounds.
Knowledge of disaccharides and their structure determination.
Understanding the chemistry of isoprenoids.
Understanding substitution reactions at saturated carbon.
Understanding the mechanism and stereochemistry of nucleophilic aliphatic substitution reactions.
Introduction, types and mechanism of elimination reactions
Theory syllabus
Unit Content Hrs
1
Stereochemistry
Conformational analysis of mono and di substituted cyclohexane’s
Molecular asymmetry as illustrated by allenes and diphenyls
Isomerism of oximes.
Determination of geometrical isomerism of Aldoxime.
Determination of geometrical isomerism of Ketoxime(Beckmann’s transformation)
15
2 Carbohydrates
Introduction of Disaccharides
Structure determination of (1) Sucrose (2) Maltose (3) Lactose
15
Isoprenoids
Classification
General methods of structure determination
Isoprene rule
Constitution of Citral and α-Terpeneol and their synthesis
3 Nucleophilic substitution at saturated carbon atom
The reaction mechanism
Stereochemistry of nucleophilic substitution
Scope of nucleophilic substitution
Stereochemistry of SN1 and SN2 reaction
15
Relative reactivity in substitution
Solvent effect variation at carbon site
Relative leaving group activity
Neighboring group participation
Competitive reactions. Elimination E1,E2 and E1cb mechanisms
Text Books
1 Organic chemistry by Morrison & Boyd VthEdition
2 Advance organic chemistry by R.K.Bansal.
Reference Books
1 Organic chemistry by I.L.Finar Vol I &.II VthEdition
2 Organic chemistry by pine, Hendrikson, Cram and Hammond IVthedition...
3 Advanced organic chemistry by Jerry March.
4 Stereo chemistry: conformation and mechanism VIth edition by P.S.Kalsi.
5 Organic chemistry of natural product Vol: I & II by Gurdeep R. Chatwal.
6 Advanced organic chemistry by Arun Bahal and B.S. Bahal.
7 Organic chemistry Vol, I, II, III by S.M.Mukherjee, S.P.Singh, R.P.Kapoor.
8 Stereo Chemistry by Nasipuri.
GANPAT UNIVERSITY
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UCHA 503 PHC Subject Name Physical Chemistry
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 3 -- -- -- 3 Theory 40 60 100
Hours 3 -- -- -- 3 Practical -- -- --
Pre-requisites:
Before learning Physical chemistry, student should aware about basic principles and theories of physical chemistry, thermodynamics, solutions, electrochemical cells, polymers and other UG level chemistry.
Learning Outcome:
Understanding of electromotive force and related phenomena.
Knowledge of statistical thermodynamics and partition function.
Understanding of macromolecules and their chemistry.
Knowledge of determination of molecular masses of macromolecules.
Theory syllabus
Unit Content Hrs
1 Electro Motive Force
Chemical Cell: Without Transference with Transference Verification of Concentration cell and it’s EMF equation.
Electrolyte concentration cell Concentration cell without transference, Concentration cell with transference
Electrode concentration cell
Amalgam concentration cell, Gas Concentration Cell
Liquid –Liquid junction potential Application of EMF measurements Determination of
Degree of hydrolysis of salt
Solubility of sparingly soluble salt
Stability constant of complex,
Dissociation constant of weak acid,
Numerical
15
2 Statistical Thermodynamics
Introduction
Combination and permutation
Probability
Sterling approximate formula (No Derivation)
Type of Statistics - Maxwell-Boltzmann - Bose-Einstein Statistics - Fermi-Dirac Statistics
15
Partition Function - Transnational Partition function - Rotational Partition function - Vibrational Partition function
Numerical
3 Macromolecules
Classification of Polymers
Tactility of polymers. ( Optical Isomers)
Polymerization reaction with example - Addition Polymerization. ( Polyethylene, Polystyrene, PVC) - Condensation Polymerization (Nylon-66, Dacron)
6 Physical Chemistry by R.A. Albern and R.J.Silby, John Wiley 1995.
7 Physical Chemistry by G.H. Barrow, 5th edn, Mac Graw Hill, 1988,6thedn, 1996.
8 Physical Chemistry by W.J.Moore, 4thedn, Orient Longmans 1969.
GANPAT UNIVERSITY
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UCHA 504 SAC Subject Name Structural Analytical Chemistry
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 3 -- -- -- 3 Theory 40 60 100
Hours 3 -- -- -- 3 Practical -- -- --
Pre-requisites:
Before learning analytical chemistry, student should aware about basic principles and theories of analytical chemistry, basics of spectroscopy, basics of volumetric analysis, and other UG level chemistry.
Learning Outcome:
Concept of symmetry and group theory.
Knowledge of point groups and multiplication tables.
Introduction, principle and applications of NMR spectroscopy.
Principle and applications of acid-base titration.
Theory syllabus
Unit Content Hrs
1 Symmetry of molecules
Symmetry elements & symmetry operations
Multiplications of symmetry operations
Multiplication table for C2v, C3v, C2h point groups only
Classification of schoonflies point groups
Determination of schoonflies point groups natations
Symmetry & optical activity
Symmetry property of orbital’s for C2v, C3v, C2h point groups
15
2 NMR spectroscopy
Introduction
Proton magnetic resonance (1H NMR) spectroscopy
Equivalent and non equivalent protons
Nuclear shielding & de-shielding
Chemical shift & molecular structure
Spin-spin splitting and coupling constant
Intensity of signal, Simplification of complex spectra
Interpretations of PMR spectra Simple organic molecule such as ; (1) Ethyl bromide (2) Ethanol (3) Acetaldehyde (4) 1,1,2-Try bromo ethane (5) Ethyl acetate (6) Toluene (7) Acetophenone (8) Iso propyl Benzene (9) Acetic acid (10) Phenitol
15
Numericals
3 Acid- base titration
Construction of titration curves
Feasibility of titration of poly protic acid
Analysis of mixture of acid & base
Differential titration of alkalis
Gran’s plot
Buffers , buffer level , buffer range & buffer capacity
15
Text Books
1 Chemical application of group theory by F.A.Cotton
2 Chemical bonding and introduction by K.C.Patel, R.D.Patel and Raval
Reference Books
1 Application of group theory to chemistry by Bhattacharya
2 Symmetry in chemistry by Jafle and Orchin
3 Advance inorganic chemistry by cotton & Wilkinson
4 Basic principles of spectroscopy by R.Chand
5 Organic chemistry Vol. 1 by S.M.Mukherji, S.P.Shingh, Kapoor
6 Spectroscopy organic compounds VIth edition by P.S.kalsi
7 Organic chemistry by Morrison and Boyd
8 Spectrometric identification of organic compounds IVth edition by Silverstain, Bassler and Morrill.
9 Application of absorption spectroscopy of organic compounds by John R. Dyer
10 Spectroscopic method in organic chemistry Vth edition by Dudley H. Williams & Ian Fleming
11 Physical methods for chemist Ruwssell S. Drago
12 Organic spectroscopy by Williams & Kemp
13 Organic spectroscopy by V.R.Dani
14 Qualitative Analysis R.A.Day & A.L.Underwood
15 Analytical Chemistry G.D. Christain
16 Fundamentals of Analytical Chemistry D.A.Skoog, D.M. West & F.J.Holler
17 Principales of Analytical Chemistry J.H. Kennedy
Classification of Dyes - According to constitution - According to method of coloring the fibres
Optical Brightners
15
2 Synthesis and uses
Congo Red
Eosin
Alizarin
Crystal violet
Indigo
Sefronine –T
Methylene Blue
Ereochrom Black –T
Rhodamine
Rosanilin
15
Text Books
1 Synthetic Dyes by Venkatramanan
2 Synthetic Dyes by G.R.Chatwal
Reference Books
1 Synthetic Dyes and Drugs by O.P.Agrawal
2 Synthetic Dyes by O. D. Tyagi & M. Yadav
3 Sanshlesit Rangako, Granth Nirman Board
GANPAT UNIVERSITY
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UENA506NMN Subject Name
Nanomaterials and Nanotechnology
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 2 -- -- -- 2 Theory 40 60 100
Hours 2 -- -- -- 2 Practical -- -- --
Pre-requisites:
Before studying nanomaterials and nanotechnology, all students have basic knowledge of general chemistry, structural chemistry and spectroscopy.
Learning Outcome:
Knowledge of preparation of nanomaterials.
Analysis of nanomaterials.
Knowledge of SEM, STM and TEM techniques.
Understanding the use of XRD, Auger emission spectroscopy and STM techniques.
Applications of nanomaterials.
Theory syllabus
Unit Content Hrs
1 Introduction and preparation
Introduction to Nanomaterials, Optical, magnetic and chemical properties of Nanomaterials,
Preparation of Nanoparticles: Chemical Approaches: Chemical reduction; Sonochemical
Synthesis; Sol-Gel Synthesis; Self-assembly. Physical Approaches: Aerosol spray; Gas
Condensation; Laser vaporization and Vapour deposition; Sputtering.
Characterization techniques for Nanomaterials-I
Particle size Analyzer (Laser scattering), Optical Microscopy: Scanning Electron
Microscopy
(SEM), Transmission Electron Microscopy (TEM), Scanning Tunnel Microscopy (STM).
15
2 Characterization techniques for Nanomaterials-II
X-ray Diffraction (XRD), Auger Emission Spectroscopy, Electron Spectroscopy for Chemical analysis (ESCA)
Application of Nanomaterials:
Applications Solar energy conversion and catalysis, Polymers with a special architecture, Liquid crystalline systems, Applications in displays and other devices, Advanced organic materials for data storage, Photonics, Chemical and biosensors,
Nan medicine and Nan biotechnology.
15
Reference Books
1 Introduction to Nanotechnology: Charles P. Poole, Jr. and Frank J. Owens; Wiley Student
Edition, 2008
2 Nanobiotechnology, Concepts, Applications and perspectives: C. M. Niemeyer and C. A.
Mirkin,WILEY-VCH, Verlag GmbH & Co, 2004.
3 Nanostructures and Nanomaterials: Synthesis, Properties and Applications: G. Cao, ICP,
London, 2004
4 Nanotechnology - Molecularly Designed Materials: G. M. Chow and K. E. Gonslaves;
(American chemical society)
5 Optical Properties of semiconductor nanocrystals: S. P. Gaponenko, Cambridge University
Examination of Chemicals (Phenolphthalein) used in Bribe Trap cases
Analysis of Adulterated Food
Introduction of Toxicology
Classification of Toxicology
Extraction of Poisons
Analysis of Poisons
15
Reference Books
1 Forensic science in criminal investigation and trials, 4th edition by Dr.B.R.Sharma, Universal
law Publishing co. pvt. ltd.
GANPAT UNIVERSITY
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UENA506ENG Subject Name ENGLISH – V
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit 2 -- -- -- 2 Theory 40 60 100
Hours 2 -- -- -- 2 Practical -- -- --
Pre-requisites:
Students should have basic knowledge of English Language and grammar.
Students should have ability to speak and write correct sentences in their day to day language.
Students should be familiar with correct usage of language.
Learning Outcome:
Development of presentation skills and personality development.
Drafting of advertisements for various purpose.
Development of communication skills.
Theory syllabus
Unit Content Hrs
1 Great Expectations by Charles Dickens 08
2 Great Expectations by Charles Dickens 08
3 Presentation Skills & Personality Building Finding out about Environment, Preparing Text, Element of body language, Use of Visual Aids in Presentation Grooming etiquettes Avoiding boredom factors in a presentation
09
4 Drafting an advertisement Essentials of drafting an advertisement Advertisement for Job Recruitment Advertisement Marketing a Product
05
Reference Books
1 Great Expectations by Charles Dickens
2 Business Communication by Urmila Rai & S. M. Rai
3 Business Communication by Rodha Doctor and Aspi Doctor
GANPAT UNIVERSITY
FACULTY OF SCIENCE Programme Bachelor of SCIENCE Branch/Spec. CHEMISTRY
Semester V Version 1.0.0.0
Effective from Academic Year 2015-16 Effective for the batch Admitted in July 2013
Subject code UPCA 507 PRA Subject Name
Practical Module-V
Teaching scheme Examination scheme (Marks)
(Per week) Lecture(DT) Practical(Lab.) Total CE SEE Total
L TU P TW
Credit -- -- 6 -- 6 Theory -- -- --
Hours -- -- 12 -- 12 Practical -- 200 200
Pre-requisites:
Before performing these practicals, students have basic knowledge of laboratory chemicals, organic and inorganic compounds and their properties, chemical kinetics and conductometry, apparatus and instruments which are used in performing chemistry practicals.
Learning Outcome:
Practical knowledge of determination of metals using gravimetric and volumetric analysis.
Synthesis of various inorganic compounds.
Separation and qualitative analysis of organic compounds.
Conductometric titrations and colorimetric estimations.
Determination of order of reactions.
Practical syllabus
Inorganic Chemistry Practical
(A) Alloy (Minimum three) 1) Brass alloy ------- Zn (Gravimetric) and Cu (Volumetric) 2) German silver alloy ------Ni (Gravimetric) and Cu (Volumetric) 3) Bronze alloy ------Sn (Gravimetric) and Cu (Volumetric) (B) Synthesis by convention method (Minimum Seven) 1) Ferrous Sulphate or Green vitriol (FeSO4 7H2O) 2) Sodium cobaltinitrate Na3 [Co(NO2)6] 3) Tetra amine cupric Sulphate 4) Hexa thio urea plumbous nitrate 5) Cuprous chloride 6) Tetra oxalato Ferrate 7) Tetra oxalato Chromate 8) Sodium Thio Sulphate from Na2SO3
Organic Chemistry Practical
Qualitative Analysis (Minimum 10) Analysis of an organic mixture containing two components using water, NaHCO3, NaOH, HCl for Separation /or using distillation process for separation and identification with the Preparation of Suitable derivatives. Soluble Components:- Oxalic Acid, Succinic Acid, Resorcinol, Urea, Thio Urea Separation of two components from Organic Mixture Such as…. Solid-Solid ------Mixture
Solid- Liquid -------Mixture Liquid-Liquid ------ Mixture [Liquid component must be neutral in nature]
Physical Chemistry Practical
[A] Instruments: (Minimum 06) 1. To determine normality and amount of HCl and CH3COOH in the given solution by Conductometry titration against 0.2N (exact) NaOH solution. 2. To determine the solubility product and solubility of sparingly soluble salts PbSO4 by Conductometry. 3. To determine Normality and amount of each acid in the given mixture of HCl + CH3COOH by pH metrically. 4. To determine the strength of strong and weak acid in a given mixture by Potentiometric titration using 0.1 N NaOH 5. To determine the concentration of Nickel in the given solution by Colorimetric estimation. 6. To determine the concentration of unknown solution from given KMnO4 solution by Calorimetry. [B] Kinetics & Distributions: (Minimum 04) 7. To determine the order of the reaction between K2S2O8 and KI. 8. To determine the order of the reaction between H2O2 and HI. 9. To determine the distribution coefficient of Iodine between CCl4/CHCl3.& water at a given temperature. 10. To study the distribution of Benzoic acid between Benzene and water at room temperature and prove the dimerization of Benzoic acid in Benzene.
