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Gasification to meet refinery hydrogen, electricity and steam demands: Availability vs Costs GTC Annual Conference 4 - 7 October 2009 – Colorado Springs demands: Availability vs Costs S. Arienti – Process Director Foster Wheeler Italiana - Power Division © 2009 Foster Wheeler. All rights reserved 1 Foster Wheeler Italiana Power Division
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Page 1: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: Availability vs Costs

GTC Annual Conference4 - 7 October 2009 – Colorado Springs

demands: Availability vs Costs

p g

S. Arienti – Process DirectorFoster Wheeler Italiana - Power Division

© 2009 Foster Wheeler. All rights reserved1

Foster Wheeler Italiana Power Division

Page 2: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

The feasibility study case

IGCC plant as only source to co-produce electricity, steam and hydrogen for a refinery:

250 MW electric energy (refinery back up electricity available for emergency only)

400 t/h HP steam @ 40 barg 400 °C

60,000 Nm3/h hydrogen @ 28 barg

Feedstock is pet coke from the refineryy

Natural gas available as back up fuel for the gas turbines

Slurry feed, quench type gasifiers – 120 MW nominal gas turbines

Location: far east – hot and humid atmospheric conditionsLocation: far east hot and humid atmospheric conditions

Unitary prices considered for economics:

pet coke 20 €/t

natural gas 0 14 €/Nm3 (5 $/MM BTU)natural gas 0.14 €/Nm3 (5 $/MM BTU)

hydrogen 0.17 €/Nm3

electric energy 0.08 €/kWh

HP t 15 5 €/t

© 2009 Foster Wheeler. All rights reserved2

HP steam 15.5 €/t

Page 3: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC Block flow Diagram - Base Case Configuration

© 2009 Foster Wheeler. All rights reserved3

Page 4: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC performance data

Pet coke

from refinery

Hydrogen to

refinery

HP steam to

refinery

Gross Power

Aux.

Loads

Net power to

refineryy

y yOutput

y

t/h Nm3/h t/h MWe MWe MWe

160 60,000 400 380 130 250

© 2009 Foster Wheeler. All rights reserved4

Page 5: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC availability assessment – the concepts

The spare equipment is provided for all the items whose shutdown causes the IGCC shutdown or significant capacity reduction: PUMPS & COMPRESSORS

F i IGCC ti i t i h d l d i tFew main IGCC sections require extensive scheduled maintenance and can have significant unplanned shut downs: in particular GASIFIERS and GAS TURBINES

IGCC i t i t bli h d i tIGCC maintenance program is established as an appropriate combination of the maintenance programs of these major critical components: other sections are in shadowE g : GT maintenance programE.g.: GT maintenance program

IGCC unplanned shut downs: evaluation based on statistical data of pFWI in-house data base

FWI data base includes real results from Italian operating IGCCs FWI was involved in

© 2009 Foster Wheeler. All rights reserved5

Page 6: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC availability assessment – the basis

Gasification: availability of each train 90% provided by Licensor based on existing solid gasifiers

ASU: availability 98%; becomes 99.5% by adding 12 h oxygen storage

SRU: 3x50% trains to avoid impact on IGCC availability

H d l t Hydrogen plant:

Membranes and PSA constituted by several modules in parallel

Permeate compressor is spared e eate co p esso s spa ed

Gas turbines and associated HRSG: 95% availability

Steam turbine: 97% availability

© 2009 Foster Wheeler. All rights reserved6

Page 7: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC availability assessment methodology – states definition

STATE AGasifier 1

BGasifier 2

CGasifier 3

DGasifier 4 Capacity Probability A

Gasifier 1B

Gasifier 2C

Gasifier 3D

Gasifier 4

1 1 1 1 1 100 00% 65 61% 90 00% 90 00% 90 00% 90 00%1 1 1 1 1 100.00% 65.61% 90.00% 90.00% 90.00% 90.00%2 1 1 1 0 100.00% 7.29% 90.00% 90.00% 90.00% 10.00%3 1 1 0 1 100.00% 7.29% 90.00% 90.00% 10.00% 90.00%4 1 0 1 1 100.00% 7.29% 90.00% 10.00% 90.00% 90.00%5 0 1 1 1 100.00% 7.29% 10.00% 90.00% 90.00% 90.00%6 1 1 0 0 66.66% 0.81% 90.00% 90.00% 10.00% 10.00%7 1 0 1 0 66.66% 0.81% 90.00% 10.00% 90.00% 10.00%8 0 1 1 0 66.66% 0.81% 10.00% 90.00% 90.00% 10.00%9 0 0 1 1 66.66% 0.81% 10.00% 10.00% 90.00% 90.00%

10 1 0 0 1 66.66% 0.81% 90.00% 10.00% 10.00% 90.00%11 0 1 0 1 66.66% 0.81% 10.00% 90.00% 10.00% 90.00%GASIFIER A

33%12 1 0 0 0 33.33% 0.09% 90.00% 10.00% 10.00% 10.00%13 0 1 0 0 33.33% 0.09% 10.00% 90.00% 10.00% 10.00%14 0 0 1 0 33.33% 0.09% 10.00% 10.00% 90.00% 10.00%15 0 0 0 1 33.33% 0.09% 10.00% 10.00% 10.00% 90.00%16 0 0 0 0 0.00% 0.01% 10.00% 10.00% 10.00% 10.00%

33%

HYDROGENPETCOKE

GASIFIER B33%

GASIFIER C33%

Example: 4 x 33% Gasifiers

© 2009 Foster Wheeler. All rights reserved7

GASIFIER D33%

Page 8: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC availability assessment methodology – availability calculation

Example: 4 x 33% Gasifiers

STATE Probability(Pk) (%)

Duration(hours/year)

Capacity(Ck) (%)

I 94.77% 8301.9 100.00%II 4 86% 425 7 66 66%

Capacity levels and probabilities

II 4.86% 425.7 66.66%III 0.36% 31.5 33.33%IV 0.01% 0.9 0.00%

Total 100.00% 8760.0 -

Equivalent Availability: ratio between actual syngas produced during a year and the syngas which could be produced during the year if operating all time at full capacity

EA = 100% - (100%-66.66%)x4.86% - (100%-33.33%)x0.36% - (100%-0%)x0.01% = 98.10%

© 2009 Foster Wheeler. All rights reserved8

( ) ( ) ( )

Page 9: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

The study case – Availability Block Diagram of base case

GASIFIER33%

PETCOKE 95% H2

PRODUCTION100%

GASIFIER33%

HYDROGEN

GAS TURBINE

100%

GASIFIER33%

HP STEAM5%

ELECTRIC ENERGY

GAS TURBINE& HRSG

50%

33%BYPASS

STEAMTURBINE

100%

NATURAL GASGAS TURBINE

& HRSG50%

© 2009 Foster Wheeler. All rights reserved9

Page 10: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

The study case - availability and costs for different gasifier and GT numbers

Alternative BASE - - A B - - C D

Number of Gasifiers G G G G+1 G+1 G+1 G+2 G+2 G+2Number of Gasifiers G G G G+1 G+1 G+1 G+2 G+2 G+2

Number of Gas Turbines GT GT+1 GT+2 GT GT+1 GT+2 GT GT+1 GT+2

Syngas from gasifiers 90.00% 90.00% 90.00% 98.10% 98.10% 98.10% 99.70% 99.70% 99.70%

H2 (priority) 90.67% 90.67% 90.67% 98.26% 98.26% 98.26% 99.72% 99.72% 99.72%H2 (priority) 90.67% 90.67% 90.67% 98.26% 98.26% 98.26% 99.72% 99.72% 99.72%

Syngas to GT 90.05% 90.05% 90.05% 98.14% 98.14% 98.14% 99.70% 99.70% 99.70%

Export Steam 95.00% 99.63% 99.98% 95.00% 99.63% 99.98% 95.00% 99.63% 99.98%

Export EE 94.37% 98.97% 99.32% 94.37% 98.97% 99.32% 94.37% 98.97% 99.32%p

Power Island NG operation (y/h) 823 863 866 154 161 162 25 26 26

Investment cost (M€) 951 1,053 1,155 1,002 1,104 1,206 1,053 1,155 1,257

Revenues (M€/y) 303 314 314 310 321 322 312 322 323

Costs (M€/y) 72 77 82 69 77 79 70 75 80

delta (M€/y) 231 236 232 241 244 243 242 247 243

Payback (y) 4.1 4.5 5.0 4.2 4.5 5.0 4.4 4.7 5.2

© 2009 Foster Wheeler. All rights reserved10

Page 11: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Hydrogen availability versus plant investment cost (GT+1 configuration)

© 2009 Foster Wheeler. All rights reserved11

Page 12: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Electric Energy availability versus plant investment cost (G+1 configuration)

© 2009 Foster Wheeler. All rights reserved12

Page 13: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Investment payback versus products availability

(G+1;GT+2)

(G+2;GT+1)

(G 1;GT 2)

(G GT+1)

(G+1;GT+1)

(G+1;GT+1)(G;GT+1)

( ; )

(G+1;GT)

© 2009 Foster Wheeler. All rights reserved13

Page 14: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Investment payback versus EE availability: operating cost sensitivity (G+1 configuration)

15.0

11.0

13.0

s]

9.0

y B

ack

time

[yea

rs

5.0

7.0Pay

3.094.00% 95.00% 96.00% 97.00% 98.00% 99.00% 100.00%

EE Availability

© 2009 Foster Wheeler. All rights reserved14

Natural Gas at 5.0 US$/MMBTU Natural Gas at 3.0 US$/MMBTU

Page 15: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Investment Payback versus EE availability:Electric Energy price sensitivity (G+1 configuration)

© 2009 Foster Wheeler. All rights reserved15

Page 16: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

IGCC Block Flow Diagram - Alternative Configuration (CO Shift)

Syngas split: 50%CO Shift for the syngas

fed to H2 productionH2 production based on PSA

Higher flexibility in H2/EE productionHigher investment cost (+15%)

© 2009 Foster Wheeler. All rights reserved16

Note (1): Number refers to base case (no spare)

Higher investment cost (+15%)

Page 17: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Conclusions

IGCC plant is flexible in producing the three main products: Hydrogen, Electric p p g p y g ,Energy and Steam. Membrane + PSA scheme for hydrogen production is normally applied.

Higher flexibility for hydrogen production is got in the alternative configuration with CO shift, but at higher investment cost (+15%). This scheme is also adequate for CCS by limited additional facilitiesCCS by limited additional facilities.

The study confirms that the products availability strongly depends on the number of spare main equipment (gasifiers and gas turbines).

© 2009 Foster Wheeler. All rights reserved17

Page 18: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Gasification to meet refinery hydrogen, electricity and steam demands: availability vs. costs

Conclusions

A spare gasifier is basic in order to ensure very good hydrogen availability (98.3%) and to restrain back-up fuel consumption of the gas turbines, with a favourable

b k tipayback time.

A spare gas turbine is useful to increase electric energy availability to about 99% A spare gas turbine is useful to increase electric energy availability to about 99%, and steam availability to 99.6%, with a reasonable investment payback time.

Double sparing for main equipment (gasifiers and gas turbines) implies higher investment payback time: it may be justified only in case of specific request of extremely high availability of products.

The greater the difference between product and feedstock prices, the greater the incentive to add spare components.

© 2009 Foster Wheeler. All rights reserved18

incentive to add spare components.

Page 19: Gasification to meet refinery hydrogen, electricity and steam … · 2016. 1. 25. · Gasification to meet refinery hydrogen, electri city and steam demands: availability vs. costs

Thank youThank youwww.fwc.comwww.fosterwheeler.itwww.fosterwheeler.it

[email protected][email protected]

l t @f

© 2009 Foster Wheeler. All rights reserved19

[email protected][email protected]


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