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General Organic Chemistry (GOC)

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General Organic Chemistry (GOC) Fundamental Concepts of Organic Chemistry 1. Which of the following alkanes has neither secondary nor tertiary hydrogen? A. iso-Butane B. iso-Pentane C. Pentane D. neo-Pentane Answer. D 2. How many cyclic isomers is possible for C 6 H 12 ? A. 3 B. 2 C. 4 D. 5 Answer. D 3. Which of the following Group is used as Anti Freeze in Motor Radiator? A. Alcohol B. Ketone C. Alkane D. Alkyne Answer. 4. An electrophile is a/an A. Lewis base B. Lewis acid C. electron deficient species D. Both A and B Answer. B 5. Geometrical isomerism exist due to the presence of A. single bond between C and C B. double bond between C and C C. triple bond between C and C D. All the above
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Page 1: General Organic Chemistry (GOC)

General Organic Chemistry (GOC)

Fundamental Concepts of Organic Chemistry1. Which of the following alkanes has neither secondary nor tertiary hydrogen?

A. iso-ButaneB. iso-PentaneC. PentaneD. neo-Pentane

Answer. D

2. How many cyclic isomers is possible for C6H12?A. 3B. 2C. 4D. 5

Answer. D

3. Which of the following Group is used as Anti Freeze  in Motor Radiator?A. AlcoholB. KetoneC. AlkaneD. Alkyne

Answer.

4. An electrophile is a/anA. Lewis baseB. Lewis acidC. electron deficient speciesD. Both A and B

Answer. B

5. Geometrical isomerism exist due to the presence ofA. single bond between C and CB. double bond between C and CC. triple bond between C and CD. All the above

Answer. B

6. In the case of o-chlorophenol there existA. intramolecular hydrogen bondingB. intermolecular covalent bondingC. no hydrogen bondingD. both inter and intramolecular hydrogen bonding

Page 2: General Organic Chemistry (GOC)

Answer. A

7. In isopentane the number of secondary carbon atom isA. 1B. 2C. 3D. 0

Answer. A

8. Carbocation (carbonium ion) isA. a set of carbon atomsB. an electrophileC. a free radicalD. a nucleophile

Answer. B

9. Carbonium ions contain only ___electrons around the carbon core.A. 2B. 6C. 5D. 9

Answer. B

10. Carboxylic acids are isomeric withA. AminesB. EstersC. AldehydesD. acid anhydrides

Answer. B

11. Two or more compounds having the same number and kind of atoms and same molecular weight are calledA. IsobarsB. IsotonesC. IsomersD. Isochors

Answer. C

12. The process of separating a racemic mixture into optical isomers is known asA. DissolutionB. IsomerisationC. ResolutionD. Pasteurization

Answer. C

Page 3: General Organic Chemistry (GOC)

13. Sulphur trioxide isA. a Lewis baseB. a baseC. nucleophileD. an electrophile

Answer. D

14. In neopentane the number of primary carbon atoms areA. 4B. 5C. 2D. 1

Answer. A

15. Which of the following type of isomerism is found in the members of the same homologous series?A. Functional isomerismB. Position isomerismC. MetamerismD. None of these

Answer. C

16. Hetrolytic fission results in the formation ofA. ElectrophileB. free radicalsC. electrophile and nucleophileD. electrons

Answer. C

17. In acetylene C-C-H bond angle isA. 144 degreeB. 180 degreeC. 90 degreeD. 96 degree

Answer. B

18. The forces between the molecules of a non-polar compounds areA. Van der Walls forcesB. ionic bondingC. hybrid forcesD. dipole forces

Answer. A

Page 4: General Organic Chemistry (GOC)

19. Carbanions are isoelectronic withA. ethersB. alcoholsC. aminesD. carboxylic acids

Answer. C

20. Diethyl amine and methylk propylamines areA. metamersB. tautomersC. dynamic isomersD. optical isomers

Answer. A

21. The number of possible metamers of pentonone areA. 5B. 1C. 3D. 6

Answer. C

22. The tetrahedral nature of the carbon was given byA. Vant HoffB. LewisC. Le Bell and Vant HoffD. None of the above

Answer. C

23. Decomposition of a compound by the action of heat is known asA. decompositionB. knockingC. smeltingD. pyrolysis

Answer. D

24. The most volatile amongst the following isA. p-nitrophenolB. m-nitrophenolC. o-nitrophenolD. none of these

Answer. A

Page 5: General Organic Chemistry (GOC)

25. Different arrangement of atoms that can be converted into one another by rotation about single bonds are calledA. trans-isomersB. conformationC. enantiomersD. None of these

Answer. B

26. A nucleophile is aA. Lewis baseB. Lewis acidC. neither a Lewis acid nor a Lewis baseD. both A & B

Answer. A

27. Chain isomers differ w.r.t.A. position of substituentB. position of functional groupC. chemical effectD. root word

Answer. D

28. Alcohols are isomeric withA. ketonesB. ethersC. aminesD. acids

Answer. B

29. The total no. of possible isomers of ethane areA. 10B. 20C. 4D. Infinite

Answer. D

30. Which of the following carbonium ions is the most stable?A. triphenyl methylB. diphenyl methylC. benzylD. All the above

Answer. A

Page 6: General Organic Chemistry (GOC)

31. Liquids whose molecules are held together by hydrogen bonds are calledA. associated liquidsB. aprotonic solventsC. primary liquidD. hydrated liquids

Answer. A

32. In substitution reactions of tertiary halide, the ionisation of halogen atom as negative ion is facilitated byA. electron attracting groupB. electron repelling groupC. free radicalD. All the above

Answer. B

33. Which of the following represents the iso-butyl radical?A. EthaneB. MethaneC. EthyneD. Benzene

Answer. D

34. Which of the following has zero dipole moment?A. 1-ButeneB. cis-2-ButeneC. trans-2-ButeneD. 2-Methyl-1-propene

Answer. C

35. Which of the following alkanes has neither secondary nor tertiary hydrogen?A. iso-ButaneB. iso-PentaneC. PentaneD. neo-Pentane

Answer. D

36. The no. of possible isomers of 1, 2-dichloroethane areA. 2B. 3C. 4D. Infinite

Answer. A

Page 7: General Organic Chemistry (GOC)

37. The IUPAC name of isoprene is A. 1, 3-ButadieneB. 2-Methyl-1, 3-butadieneC. 2-Methyl-1-buteneD. 3-Methyl-1-butene

Answer. B Isoprene

38. Which of the following compounds is chiral?A. 2-chloro-2-methyl butaneB. 3-chloro hexaneC. 2-chloro pentaneD. 1-chloro pentane

Answer. C

39. Which of the following compounds contains maximum number of tertiary hydrogen atoms?A. n-HexaneB. 2-2-Dimethyl butaneC. 2, 3-Dimethyl butaneD. 2-Methyl pentane

Answer. C

40. The IUPAC name of crotyl chloride isA. 1-Chloro-1-buteneB. 1-Chloro-2-buteneC. 2-Chloro-2-buteneD. 3-Chloro-1-butene

Answer. B

41. The secondary suffix in the IUPAC names of ketones isA. -alB. -oneC. -olD. –oate

Answer. B

42. Which of the following is optically active?A. isobutyl alcoholB. sec butyl alcoholC. tert butyl alcoholD. p-butyl alcohol

Page 8: General Organic Chemistry (GOC)

Answer. B

43. IUPAC name of propargyl alcohol isA. Prop-2-yn-1-olB. Prop-2-en-1-olC. Prop-1-en-2-olD. Prop-1-yn-2-ol

Answer. A

44. The number of pi bonds in isoprene isA. 2B. 3C. 1D. 0

Answer. A

45. Molecules that are not superimposable on their mirror images areA. AchiralB. SymmetricC. AsymmetricD. Chiral

Answer. D

46. IUPAC name of propargyl alcohol isA. Prop-2-yn-1-olB. Prop-2-en-1-olC. Pro-1-en-2-olD. Prop-1-yn-2-ol

Answer. A

47. In iso-octane (2, 2, 4-trimethylpentane), the number of tertiary hydrogen atoms isA. OneB. TwoC. ThreeD. Four

Answer. A

48. Paraffins is the common name used forA. AlkanesB. AlkenesC. AlkynesD. Arenes

Answer. A

Page 9: General Organic Chemistry (GOC)

49. In iso-octane (2, 2-4-trimethylpentane), the number of primary hydrogen atoms isA. 12B. 15C. 13D. 14

Answer. B

50. Which of the following molecules does not contains any secondary hydrogen atom?A. n-PentaneB. neo-PentaneC. neo-HexaneD. iso-Pentane

Answer. B

51. Diastereomers are a pairA. stereoisomers that cannot be separated from each otherB. stereoisomers that are not minor image of each otherC. stereoisomers that have identical chemical propertiesD. stereoisomers that are minor image of each other

Answer. B

52. Which of the following have zero dipole moment?A. 2 methyl propaneB. trans-2-buteneC. cis-2-buteneD. butane-1

Answer. B

53. All the members of a homologous series have sameA. Molecular massB. Molecular formulaC. Empirical formulaD. General molecular formula

Answer. C

54. The IUPAC name of allylene isA. PropyneB. PropeneC. 2-ButyneD. 1-Butyne

Answer. C

Page 10: General Organic Chemistry (GOC)

55. Which of the following is the functional isomer of methyl acetate?A. Ethyl acetateB. Propanoic acidC. Ethyl formateD. Propanone

Answer. B

56. Which of the following compounds contains maximum number of tertiary hydrogen atoms?A. n-HexaneB. 2-2-DimethylbutaneC. 2, 3-DimethylbyteneD. 2-Metylpentane

Answer. C

57. What is not true about homologous series?A. All the members have similar chemical propertiesB. They have identical physical propertiesC. They can be represented by a general formulaD. Adjacent members differ in molecular mass by 14

Answer. B

58. Optical activity in a compound can be detected by means ofA. VoltmeterB. PotentiometerC. AmmeterD. Polarimeter

Answer. D

59. Which of the following compounds has least dipole moment?A. 1, 2-DichlorobenzeneB. 1, 3-DichlorobenzeneC. 1, 4-DichlorobenzeneD. All have same dipole moment

Answer. C

60. An example of conjugated diene isA. 1, 4-PentadieneB. 1, 5-HexadieneC. 1, 2-ButadieneD. 1, 3-Pentadiene

Answer. D

Page 11: General Organic Chemistry (GOC)

61. Number of sec-H atoms in iso-butane isA. 1B. 9C. 4D. None

Answer. D

62. Homolytic Fission is :A. SymmetricalB. UnsymmetricalC. BothD. None

Answer. A

63. Alcohols are resistant to oxidation :A. PrimaryB. SecondaryC. TertiaryD. All

Answer. C

64. When alcohol is dehydrated ar 140 ͦC the produxt obtnd is : A. EthaneB. Diethyl etherC. IodoformD. None 

Answer. B

65. _____ are formed in homolytic bond fission :A. Free radicalsB. IonsC. Both A & BD. None

Answer. A

66. The factors which favor homolytic fission are :A. Electro negativity difference is less or zeroB. Gaseous stateC. Light & ElectricityD. All of the above

Answer. D

Page 12: General Organic Chemistry (GOC)

67. Unsymmetrical bond fission is favored in :A. HomolysisB. HeterolysisC. BothD. None

Answer. B

68. Direction of polar reactions is from :A. Nucleophile to electrophileB. Electrophile to nucleophileC. Source to sinkD. Both A & C

Answer. D

69. Which of the following is nucleophile :A. Cl –B. H2OC. NH3D. All

Answer. D

70. In tertiary Alcohols one C having OH group is attached to mainly how many more C :A. 1B. 2C. 3D. 4

Answer. C

71. In combustion of methane the amount of energy released is :A. 891 kJ/molB. 892 kJ/molC. 893 kJ/molD. None

Answer. A

72. Which of the following is electrophile :A. Cl2

B. Cl-C. Br2

D. Both A & C

Answer. D

Page 13: General Organic Chemistry (GOC)

73. Out of the following which reacts with alkanes in presence of ultra violet rays :A. ChlorineB. BromineC. IodineD. FlourineE. Both A & BF. Both C & DG. All

Answer. E

74. The step in which chlorine free radical reacts with methane and a methyl free radical is obtained is termed as :A. InitiationB. PropagationC. TerminationD. NoneAnswer. B

75. Combustion of alkanes is highly ____ so it requires ____ for initiation :A. Endothermic & nothingB. Exothermic & nothingC. Endothermic & flameD. Exothermic & spark

Answer. D

76. Which of the following reaction is not synthetically important :A. Free radical reaction of alkanesB. Halogenation of alkanesC. Both A & BD. None

Answer. C

77. During dehydrohalogenation of alkyl halides the hydrogen is removed from the C which is attached to :A. RB. XC. R or XD. None

Answer. A

Page 14: General Organic Chemistry (GOC)

78. The catalysts used for dehydration of alcohol are :A. Al2O3

B. H2SO4

C. H3PO4

D. All

Answer. D

79. The temperature required for primary alcohol to form ethene is :A. 150 ͦCB. 180 ͦCC. 140-170 ͦCD. All of the above

Answer. D

80. The catalytic hydrogenation of alkenes is at 1-5 atm pressure and giving 120kJ/mol per double bond and giving ______ compound :A. UnsaturatedB. SaturatedC. Depends upon given conditionsD. None

Answer. B

81. The catalysts used for catalytic hydrogenation of alkenes are :A. Pt,Pd,NiAl2O3B. Pt, Pb, Raney NickleC. Pt,Pd,NiD. None

Answer. C

82. For hydration of ethene the intermediate compound is :A. Methyl hydrogen sulphateB. Ethyl Hydrogen SulphateC. Ethyl hydrogen NitrateD. None

Answer. B

83. For hydration of alkanes the optimum temperature is :A. 140 oCB. 100 oCC. 80 oCD. None

Answer. B

Page 15: General Organic Chemistry (GOC)

84. As the bromine reaches near the alkenes which becomes polarized :A. AlkeneB. Bromine MoleculeC. Both A & BD. None

Answer. B

85. 1% dilute alkaline KMnO4 solution is a :A. Strong oxidizing agentB. Mild oxidizing agentC. Weak oxidizing agentD. None

Answer. B

86. Polymerization of ethane at 400 oC and 100 atm Pressure produces :A. PolyethaneB. PolyethyleneC. PolyethanolD. None

Answer. B

87. Markovnikov's rule follow :A. Addition of unsynnetrical reagent to an unsymmetrical alkeneB. Addition of unsynnetrical alkene to an unsymmetrical alkeneC. Addition of unsynnetrical reagent to an unsymmetrical reagentD. Addition of unsynnetrical alkene to an unsymmetrical alkane

Answer. C

88. Butene can have:A. Geometrical isomerismB. 2-position isomersC. Both A & BD. All structural isomers

Answer. C

89. Geometrical isomerism is shown by :A. AlkanesB. AlkenesC. AlkynesD. Both A & C

Answer. B

Page 16: General Organic Chemistry (GOC)

90. Anthracene has how many benzene rings?A. 2B. 3C. 4D. 5

Answer. B

91. Pentane has how many isomers :A. 2B. 3C. 4D. 5

Answer. B

92. Oxidation of alkenes in presence of hot KMnO4 solution the products obtained can be :A. KetonesB. Carboxylic acidsC. Carbon dioxideD. All

Answer. D

93. All sp2 orbitals in benzene ring are :A. in different planesB. In same planesC. CoplanarD. Both B & C

Answer. D

94. Diffused or delocalized electron cloud is formed by overlapping of :A. one 2py & one 2pz orbitalsB. Both 2pz orbitalsC. Any 2 orbitalsD. None

Answer. B

95. The stability of benzene ring is compared with :A. CyclohexeneB. 1,3 cyclohexadieneC. 1,3,6 cyclohexatrieneD. None

Answer. D

Page 17: General Organic Chemistry (GOC)

96. In kekule’s structure the bond lengths between different carbons are as :A. Between C1-C4B. Between C2-C5C. Between C3-C6D. None

Answer. D

97. During halogenation, nitration, Friedal craft’s reactions of benzene the direction of reaction is :A. Benzene ring to electrophileB. Electrophile to benzene ringC. Benzene ring to nucleophileD. Nucleophile to benzene ring

Answer. A

98. The acylation of benzene ring produces :A. Methy benzeneB. Ethyl BenzeneC. AcetophenoneD. Alky BenzeneAnswer. C

99. Which of the followoing are electrophile :A. AlCl3B. FeBr3C. H2SO4D. Both a & bE. All

Answer. E

100. The characteristic of SN2 reactions are :A. Change of hybridization from sp3 tetrahedral to sp2 planarB. Attack of weak leaving groupC. Removal of NucleophileD. Both a & cE. All

Answer. D

101. The order of SN2 reactions for primary alkyl halides is :A. 1B. 2C. 3D. 4

Answer. B

Page 18: General Organic Chemistry (GOC)

102. There is another site present on alkyl halides on which nucleophile can attack during B-Elimination reaactions :A. a-HB. b-HC. a-CD. b-C

Answer.

42-The rate of E1 reactions depend upon :a)The concentration of substrateb)Conc. Of nucleophilec)Conc of substrate as well as nucleophiled)None

43-Which one of the following is not a nucleophile :a)H2Ob)H2Sc)BF3d)NH3

44-The benzene molecule contains :a)Three double bondsb)two double bondsc)One double bondd)Delocalized pi electron charge

45-During nitration of benzene active nitrating agent is :a)NO3b)NO2+c)NO2-d)HNO3

46-Formula of chloroform is :a)CH3Clb)CCl4c)CH2Cl2d)CHCl3

47-Optimum temperature for the fermentation is :a)25-35 oCb)35-45 oCc)15-25 oCd)None

48-The product obtained after re-Distilation of 95% alcohol in presence of CaO is called :a)rectified spiritb)Absolute alcohol

Page 19: General Organic Chemistry (GOC)

c)Methyleted spiritd)None

49-For denaturation of alcohol which can be used :a)Methanolb)Ethanolc)Pyridined)Acetonee)Allf)All except ethanol

50-When NH3 reacts with alcohol then the catalyst used is :a)ZnCl2b)ThO2c)Pyridined)None

51-Which reaction is correct :a)2C2H5OH + 2Na ------> 2C2H5ONa + H2b) 2C2H5OH + 2Na ------> 2C2H5ONa + H2Oc) 2C2H5OH + 2Na ------> 2C2H5OONa + H2d) 2C2H5OH + 2Na ------> 2C2H5ONaH + HO

52-Upon oxidation of 2-methyl 2 propanol the product obtained is :a)Ethanalb)Propanonec)2-Methylpropaned)None53-When ethanol reacts with Phospho pentachloride then the products include :a)HClb)HOClc)H3PO3d)None

54-The formulae for iodoform is :a)CHI3b)CHBr3c)CH2OHId)None

55-The reason why phenol is more acidic is :a)Delocalization of electronic cloud of benzene ringb)Ka = 1.3 x 10^-10c)delocaliztion of ?ve charge in ringd)Both b & ce)All

56-Phenol reacts with dilute HNO3 at 25oC to give :

Page 20: General Organic Chemistry (GOC)

a)TNTb)Picric acidc)Both a & bd)None

57-Rectified spirit contains alcohol about :a)14%b)95%c)12%d)20%

58-Esterification of alcohols is___ with removal of water :a)Irreversibleb)Reversiblec)Maybe bothd)None

59-CH3COCH2CH3 is ;a)2Propanoneb)Butanonec)Acetophenoned)None

60-The IUPAC name of (CH3)2 CH CH2 OH is :a)2,3methyl 2 propanolb) 2,4methyl 2 propanonec) 1,3ethyl 3 propanold) 2,3methyl 1 propenol61-In industry for preparation of formaldehyde the optimal conditions are :a)Pt-Asbestosb)300oCc)Bothd)None

62-Acetaldehyde is prepared in the laboratory by the oxidation of ethyl alcohol with :a)Alkaline sodium dichromate solutionb)Acidfied KMnO4 Solutionb)Alkaline KMnO4 Solutiond)None

63-Acidified aqueous hydrolysis of acetaldehyde cyanohydrin gives :a)2-Hydroxypropanoic acidb)Lactic acidc)alpha hydroxyl acid containing one C more than starting aldehyde or ketoned)All

64-Which one of the following is a good source of Cyanide ion :a)HCN

Page 21: General Organic Chemistry (GOC)

b)KCNc)NH4CNd)LiCN

65-Tryosine has ____ taste :a)Sweetb)Sourc)Cheesed)None

66-Which of the following pair of amino acids have sec. amino group :a)Glycine & Prolineb)Histidine & Glutamic acidc)Lysine & valined)Proline & Histidine

67-The acidic character of amino acid is due to :a)COOHb)COO-b)NH2c)NH3+

68-The catalyst used in the reaction of a-bromoacid with ammonia is :a)Kb)Pc)Lid)H

69-During strecker synthesis the intermediate compound obtained is :a)Ammonium ionb)Ammonium Chloridec)Ammonium nitriled)None

70-There is a peptide molecule which is said to have molecular mass 11,312,it is termed as :a)Polypeptideb)Proteinc)Both a & bd)None

71-Addition polymerization is catalyzed by :a)Thermal decomposition of organic peroxidesb)Photochemical decomposition of organic peroxidesc)Bothd)None

72-Condensation polymerization involves the removal of :a)Water

Page 22: General Organic Chemistry (GOC)

b)Methanolc)Ethanold)Alle)Both a & b

73-Polysterene is used in :a)Pipesb)Gramophone recordsc)Clothingd)Cosmetic bottles

74-Plyamide resisns include :a)Nylon -6,9b)Nylon -3,6c)Nylon -9,9d)Nylon- 6.6

75-Glucose is also termed as :a)Dextroseb)Grape Sugarc)Blood Sugard)Alle)Both b & c

76-Amylopectin has glycosidic linkages as :a)1,2b)1,4c)1,2 & 1,4d)1,4 & 1,6

77-Woody trees are generally ___% celloluse :a)10%b)20%c)30%d)40%e)None

78-The saponification number for glycerol triplemitate is :a)206b)208c)210d)212

79-In DNA the sugar is :a)1-Deoxyriboseb)2-Deoxribosec)3-Deoxyribosed)None

Page 23: General Organic Chemistry (GOC)

80-The acid chloride strength is of the order of :a)CH3COOCl > CH3COOCl2 > CH3COOCl3 > CH3COOCl4b) CH3COOCl < CH3COOCl2 > CH3COOCl3 < CH3COOCl4c) CH3COOCl < CH3COOCl2 <CH3COOCl3 <CH3COOCl4d) CH3COOCl <CH3COOCl2 ,CH3COOCl3 > CH3COOCl4

(Acetic acid, HC2H3O2 Ka = 1.8?10?5 

Chloroacetic acid, HC2H2ClO2 Ka = 1.4?10?3 

Dichloroacetic acid, HC2HCl2O2 Ka = 5.5?10?2 

Trichloroacetic acid, HC2Cl3O2 Ka = 3.0?10?1 )

81-The steps for the formation of ester are :a)3b)4c)5d)None

82-In reaction with SOCl2 which two atoms get polarized due to presence of Chloride ion :a)C of CH3 and Ob)Alpha   C  and O with alpha Cc)Alpha C and adjacent O on its rightd)Polarization is not possible

83-The efficient method to obtain carboxylic acid is :a)Methyl Ketone to Carboxylic acidb) Acetaldehyde to Carboxylic acidc) Formaldehyde to Carboxylic acidd)None

84-In holoform reaction carboxylic acid contains ____ C atoms than starting aldehyde and ketone :a)Moreb)Moderatec)Lessd)None

85-2,4 DNPH are usually :a)liquidsb)Crystalline solidsc)gasesd)None

86-Sodium borohydride reduces :a)C=O

Page 24: General Organic Chemistry (GOC)

b)C-Cc)C-Hd)None

87-During oxidation of aldehydes the H atom attached to ___ is oxidized :a)Methylb)Carbonyl groupc)Cd)None

88-The alkoxide ion is protonated with __ to give an alcohol :a)H3O+b)H2Oc)OH-d)MH4OH

89-During oxidation of ketones :a)The carbon atom joined to the __ number of H is usually oxidized :a)Smallerb)mediumc)greaterd)None

90-In case of symmetrical ketones ___ C atoms adjacent to the carbony group is oxidized :a)Oneb)Twoc)Threed)Four

91-During oxidation of unsymmetrial ketones the carbonyl group goes with:a)Larger alkyl groupb)Smaller alkyl groupc)Separatesd)None

92-Formula for tollen?s reagent is :a)Ag(NH3)2b)AgNH3c)AgNH2OHd)[Ag(NH3)2]OH

93-In tollen?s test alongwith silver mirror we get :a)H2Ob)NH3c)Bothd)None

94-Fehling solution is :

Page 25: General Organic Chemistry (GOC)

a)An alkaline solution containing cupric tartrate complex ionb) An acidic solution containing cupric tartrate complex ionc) An alkaline solution containing cupric citrate complex iond)None95-Formalin is :a)40% formaldehyde in 50 % waterb) 30% formaldehyde in60 % waterc) 20% formaldehyde in 70 % waterd) 40% formaldehyde in 52 % water

96-Acetone reacts with HCN to form a cyanohydrin,it is an example of :a)Electrophilic additionb)Nucleophilic additionc)Nucleophilic substitutiond)Electrophilic substation

97-Oxalic & Malonic acids are also called as :a)Propanedioic and Etahnedioic acidb)Ethanedioic and Propanedioic acidc)Bothd)None

98-Pthalic acid has how many benzene rings :a)1b)2c)3d)4

99-Ethanol forms formic acid by forming an intermediate product of :a)Aldehydeb)Ethanalc)Methanald)None100-Tollen?s reagent is a :a)Strong oxidizing agentb)Mild oxidizing agentc)Weak oxidizing agentd)None

101-Alkanenitriles will give corresponding carboxylic acids on reaction with :a)Acidsb)Alkaliesc)Bothd)None

102-When carboxylic acids are obtained from oxidation of primary alcohols then the intermediate producs formed are:a)Ketones

Page 26: General Organic Chemistry (GOC)

b)Aldehydesc)Can be both of the aboved)None

103-When H atom of carboxylic acids is involved in the reactions then one thing will must be formed :a)Hydrogen gasb)H2Oc)Respective Saltsd)All

104-During protonation of carboxylic acid in formation of an ester the carboxylic acid at as :a)Electrophileb)Nucleophilec)Can act as bothd)None

105-The correct formulae for ester is :a)CH3COOC2H5b) CH3COC2H5c) CH3COOC2H5Od) CH2COOC2H5

106-The third step of esterification is :a)Protonation of carboxylic acidsb)Attack of alcoholc)Elimination of H+d)Hydrogen ion transfer

107-The formula for acetamide is :a)CH3COONH2b) CH3COONH3c) CH3CONH2d) CH3COONH

108-Which one of the following is a strong acid :a)Phenolb)Ethanoic acidc)ChloroEthanoic acidd)Alcohol

109-The Abbreviation for glutamic acid is :a)Glab)Glyc)Alad)None

110-Which of the following is a non-polar amino acid :

Page 27: General Organic Chemistry (GOC)

a)Glycineb)Alaninec)Valined)All111-Carboxylate ion gives the ____ character to amino acid :a)Acidicb)Basicc)Neutrald)None

112-Which of the following are required for Strecker?s synthesis :a)HCNb)Aminec)Formaldehyded)Both a & ce)All

113-The compound formed due to addition of CN is called :a)Amideb)Aminec)Imined)Nitrile

114-The unsaturated amino acids are :a)Histidineb)Glycinec)Lysined)None

115-The secondary amino acids according to your text book are :a)1b)2c)3d)4

116-The cyclic amino acid is :a)Glycineb)Alaninec)Valined)Proline

117-The aliphatic amino acids mentioned in your text book are :a)10b)9c)8d)7

118-Which of the following derivative can not be dorectky prepared from acetic acid :

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A)Acetamideb)Acetyl Chloridec)Acetic Anhydrided)Ethyl acetate

119-Which of the following is not a fatty acid :a)Propanoic acidb)Acetic Acidc)Pthalic Acidd)Butanoic Acid

120-Acetamide is prepared by :a)Heating Ammonium acetateb)Heating methyl cyanidec)Heating ethyl acteated)The hydrolysis of methyl cyanide

121-Photochemical decomposition of organic peroxides to give free radicals usually :a)Stops the reactionb)Initiates the free radical polymerizationc)Catalyzes the free radical polymerizationd)Nothing happens

122-Condensation polymerization reaction takes place :a)At one side of chainb)At both sides of the chainc)Both are the possibilitiesd)None

123-Condensation polymerizations are generally ___ in nature :a)Neutralb)Acidicc)Basicd)ionic

124-Alcohols which can be used in condensation polymerization for formation of polyester resins are :a)Mono-olsb)Di-olsc)Tri-olsd)Tetra-ols

125-The substitude of sucrose(cane sugar) is is :a)Fructoseb)Dextrosec)Glucosed)None126-Deep blue colour with iodine is given by :

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a)Amyloseb)Amylppectinc)Starchd)glycogen

127-Natural starch can have __ amylose and __ amylopectin :a)15% & 85%b)25% & 95%c)Both are possibled)None128-Which of the following forms the branched structure :a)Amyloseb)Amylopectinc)Glycogend)Both b & c

129- Celloluse is special characteristic of :a)Plant kingdomb)Marine lifec)Bothd)None

130-Celloluse is a polymer of :a)alpha D glucoseb)Beta D Glucosec)Glucosed)None

131-The structure of general protein is :a)Quartenaryb)Tertiaryc)Secondaryd)Primary

132-The sequence of amino acids combined in a peptide chain is reffered to as :a)Primary Structureb)Secondary structurec)Tertiary Structured)None

133- Main type of secondary structure of proteins are :a)Alpha Helixb)Beta Strandc)Both d)None134-Hydrophobic interactions are present in ___ of proteins:a)Primary structureb)Secondary structure

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c)Tertiary structured)None

135-____ also considered as primary building blocks :a)Fatty Acidsb)Glycerolsc)Sterolsd)Both a & be) All136-The polyunsaturated glycerides would have ___ M.P & B.P :a)Highb)Mediumc)Lowd)None137-Sterols,Vitamin D and terpenes are termed as :a)Compund lipidsb0Associated lipidsc)Derived lipidsd)Both b & ce)All

138-The rate of deterioration depends upon ___ of fats or oils :a)Saturationb)Unsaturationc)Bothd)None

139-The quantity in miligrams(mg) taken for identification of characteristic of fat or oil per specific given amount of fat or oil is of : a)Acid Number & Iodine Numberb)Saponification number and iodine numberc)Acid number & Saponification numberd)Acid number140-____ belong to sterols :a)Ergosterolb)Hormones of adrenal cortexc)Cholesterold)Both a & ce)All

141-Ergosterol can be converted into :a)Ergocalciterolb)Vitamin D1c)Bothd)None

142-Cholesterol is precursor of :a)Ergosterol

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b)Steroid Hormonesc)Vitamin D2d)None143-Aromatic compounds are part of :a)Homocyclic compoundsb)Heterocyclic compoundsc)Bothd)None

144-Which of the following is an isomerase :a)Phosphoglyceromutasesb)Phospho transferasec)Proteased)Fumarase

145-During incineration the temperature ranges from :A)900-1000b)1000-1100c)800-1000d)None146-The recycling of plastics is done by :a)Reprocessingb)Depolymerizationc)Transformationd)All147-The main pollutant of leather tanneries in the waste water is due to the salt of :a)Leadb)Barium Sulphatec)Alumd)Nickle sulphate

148-A single chloride free radical can destroy how many ozone molecules :a)100b)100000 c)10000d)10149-Which clogs the gills of a fish :a)Mgb)Cac)Ald)None

150-The ozone layer is ___ high :a)15-40 km highb)25-28 km highc)30 km highd)All

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Answer Key :

1-a

2-c

3-b

4-a

5-d6-b7-d8-d9-c10-a11-d12-e13-b14-d15-c16-a17-d18-d19-b20-c21-b22-b23-b24-b

25-b

26-c27-c28-b29-b30-b31-d32-d33-b34-d35-d36-a37-c38-e39-e40-b41-b42-a43-c44-d45-b46-d47-a48-b49-f50-b51-a52-d53-a54-a55-d56-d57-b

Page 33: General Organic Chemistry (GOC)

58-b59-b60-a61-d62-d63-d64-b65-c66-d67-b68b69c70b71c72e73d74-d75-d76-d77-e78-b79-b80-c81-b

82-b83-a84-c85-b86-a87-b88-b89-a90-a91-b92-d93-c94-a95-d96-b97-b98-a99-b100-b

101-c102-b

103-c104-b105-a106-d107-c108-c109-b110-d111-b112-d113-d114-a115-b116-d117-d118-a119-c120-a

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121-c122-b123-d124-b125-a126-a127-a128-d129-a130-b131-b132-a133-c134-c135-e136-c137-d138-b139-c140-e141-a142-b143-c144-a145-a146-d147-c148-b149-c150-b


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