Handbook of Thermodynamic Diagrams VOLUME4

LIBRARY OF PHYSICO-CHEMICAL PROPERTY DATA

Handbook ofThermodynamic

Diagrams

Volume 4

InorganicCompounds and

Elements


Handbook of Vapor PressureVolume 1: C1 to C4 Compounds (Product #5189)Volume 2: C5 to C7 Compounds (Product #5190)Volume 3: C8 to C28 Compounds (Product #5191)Volume 4: Inorganic Compounds and Elements (Product #5394)

Carl L. Yaws

Handbook of ViscosityVolume 1: C1 to C4 Compounds (Product #5362)Volume 2: C5 to C? Compounds (Product #5364)Volume 3: C8 to C28 Compounds (Product #5368)

Carl L. Yaws

Handbook of Thermal ConductivityVolume 1: C1 to C4 Compounds (Product #5382)Volume 2: C5 to C7 Compounds (Product #5383)Volume 3: C8 to C28 Compounds (Product #5384)

Carl L. Yaws

Handbook of Thermodynamic DiagramsVolume 1: C1 to C4 Compounds (Product #5857)Volume 2: C5 to C7 Compounds (Product #5858)Volume 3: C8 to C28 Compounds (Product #5859)Volume 4: Inorganic Compounds and Elements (Product #5860)

Carl L. Yaws

Each of the above series contains data for more than 1,000 organic compounds, including hydrocar-bons, oxygenates, halogenates, nitrogenates, sulfur compounds, and silicon compounds. The data are pre-sented in graphs for vapor pressure, viscosity, thermal conductivity, or thermodynamics as a function oftemperature and are arranged by carbon number and chemical formula to enable the engineer to quicklydetermine values at the desired temperatures. Select series include wide ranges of inorganic compoundsand elements.

Handbook of Transport Property Data (Product #5392)Carl L. Yaws

Comprehensive data on viscosity, thermal conductivity, and diffusion coefficients of gases and liquidsare presented in convenient tabular format.

Physical Properties of HydrocarbonsVolume 1, Second Edition (Product #5067)Volume 2, Third Edition (Product #5175)Volume 3 (Product #5176)Volume 4 (Product #5272)

R. W. Gallant and Carl L. Yaws

The four-volume series provides chemical, environmental, and safety engineers with quick and easyaccess to vital physical property data needed for production and process design calculations.

Thermodynamic and Physical Property Data (Product #5031)Carl L. Yaws

Property data for 700 major hydrocarbons and organic chemicals, including oxygen, nitrogen, fluorine,chlorine, bromine, iodine, and sulfur compounds, are provided.



Diagrams

Volume 4


Elements

Carl L. Yaws

Gulf Publishing CompanyHouston, Texas

Handbook of Thermodynamic Diagrams, Volume 4

Copyright © 1996 by Gulf Publishing Company, Houston,Texas. All rights reserved. Printed in the United States ofAmerica. This book, or parts thereof, may not be reproduced inany form without permission of the publisher.

Gulf Publishing CompanyBook DivisionP.O. Box 2608 � Houston, Texas 77252-2608

1 0 9 8 7 6 5 4 3 2 1

Printed on Acid-Free Paper (¥)

Library of Congress Cataloging-in-Publication Data

Yaws, Carl L.Handbook of thermodynamic diagrams : volume and

enthalpy diagrams for major organic chemicals andhydrocarbons / Carl L. Yaws.

p. cm.—(Library of physico-chemical property data)Includes bibliographical references.Contents: v. 1. C1 to C4 compounds — v. 2. C5 to C7

compounds — v. 3. C8 to C28 compounds — v. 4. Inorganiccompounds and elements.

ISBN 0-88415-857-8 (v. 1 : alk. paper). — ISBN0-88415-858-6 (v. 2 : alk. paper). — ISBN 0-88415-859-4(v. 3 : alk. paper). — ISBN 0-88415-860-8 (v. 4 : alk. paper)

1. Thermodynamics—Tables. 2. Hydrocarbons—Tables. 3. Organic compounds—Tables. I. Title.II. Series.QD504.Y36 1996660'.2969'0223—dc20 96-36328

CIP

IV

CONTENTS

Preface vii

Thermodynamic Graphs for Inorganic Compounds and Elements 1

References 344

Appendix A: Equations for Thermodynamic Properties 346

Appendix B: Peng-Robinson Equation of State for Thermodynamic Properties 347

Appendix C: Examples for Thermodynamic Diagrams 349

Appendix D: Critical Constants and Acentric Factor for Inorganic Compoundsand Elements 351

Appendix E: Heat Capacity for Inorganic Compounds and Elements 357

Compound List by Formula 363

Compound List by Name 366

Computer Program for Thermodynamic Properties 369

CONTRIBUTORS

Mei Han Graduate student, Chemical Engineering Department, LamarUniversity, Beaumont, Texas 77710, U.S.A.

Sachin D. Sheth Graduate Student, Chemical Engineering Department, LamarUniversity, Beaumont, Texas 77710, U.S.A.

Carl L. Yaws Professor, Chemical Engineering Department, Lamar University,Beaumont, Texas 77710, U.S.A.

ACKNOWLEDGMENTS

Many colleagues and students have made contributions and helpful comments over theyears. The author is grateful to each: Jack R. Hopper, Joe W. Miller, Jr., C. S. Fang, K. Y. Li,Keith C. Hansen, Daniel H. Chen, Fu-Ming Tsuo, Jeng-Shia Cheng, San-Min Chou, J. W. Via,III, P. Y. Chiang, H. C. Yang, Xiang Pan, Xiaoyan Lin, Duane G. Piper, Jr., Li Bu, Sachin D.Nijhawan, Sachin D. Sheth, and Mei Han.

The author wishes to acknowledge special appreciation to his wife (Annette) and family(Kent, Michele, Chelsea, and Brandon; Lindsay and Rebecca; and Matthew and Sarah).

The author wishes to acknowledge that the Gulf Coast Hazardous Substance Research Cen-ter provided partial support to this work.

DISCLAIMER

This handbook presents a variety of thermodynamic and physicalproperty data. It is incumbent upon the user to exercise judgment inthe use of the data. The author and publisher do not provide anyguarantee, express or implied, with regard to the general or specificapplicability of the data, the range of errors that may be associatedwith any of the data, or the appropriateness of using any of the datain any subsequent calculation, design, or decision process. Theauthor and publisher accept no responsibility for damages, if any,suffered by any reader or user of this handbook as a result of deci-sions made or actions taken on information contained herein.

Vi

PREFACE

Thermodynamic property data are important in many engineering applications in the chemi-cal processing and petroleum refining industries. The objective of this book is to provide theengineer with such data. The data are presented in thermodynamic diagrams (graphs) coveringa wide range of pressures and temperatures to enable the engineer to quickly determine valuesat points of interest. The contents of the book are arranged in the following order: graphs, ref-erences, and appendixes.

The graphs are arranged by carbon number and chemical formula to provide ease of use.English units are used for the property values. For those involved in SI and metric usage, eachgraph displays a conversion factor to provide the SI and metric units.

The graphs provide wide coverage for volume and enthalpy as a function of temperature andpressure, including the following:

• two-phase region for saturated liquid and vapor• superheated gas region for gases above saturation temperature• subcooled liquid region for liquids below saturation temperature• supercritical region for temperatures and pressures above critical point

The graphs for enthalpy also contain lines of constant entropy to permit engineering usage for2nd law problems such as adiabatic expansion and compression of fluids.

The coverage encompasses a wide range of compounds (total = 343). The coverage of inor-ganics is comprehensive: carbon oxides, such as carbon monoxide and carbon dioxide; nitro-gen oxides, such as nitric oxide and nitrous oxide; sulfur oxides, such as sulfur dioxide and sul-fur trioxide; hydrogen oxides, such as water and hydrogen peroxide; ammonias, such as ammo-nia and ammonium hydroxide; hydrogen halides, such as hydrogen chloride and hydrogen flu-oride; sulfur acids, such as sulfuric acid and hydrogen sulfide; hydroxides, such as sodiumhydroxide and potassium hydroxide; silicon halides, such as trichlorosilane and silicon tetra-chloride; ureas, such as urea and thiourea; cyanides, such as hydrogen cyanide and cyanogenchloride; hydrides, such as silane and diborane; sodium derivatives, such as sodium chlorideand sodium fluoride; aluminum derivatives, such as aluminum borohydride and aluminum flu-oride; and many other compound types. Many elements (total = 82) are covered: hydrogen,nitrogen, oxygen, helium, argon, neon, chlorine, bromine, iodine, fluorine, sulfur, phosphorous,aluminum, lead, tin, mercury, sodium, magnesium, silicon, antimony, boron, iron, chromium,cobalt, titanium, tantalum, silver, gold, platinum, radon, uranium, and many others.

For most compounds, the range of coverage for pressure is from 10 to 10,000 psia. Very lim-ited experimental data are available at pressures above 1,000 to 2,000 psia. Thus, values at thehigher pressures should be considered rough approximations. Values at lower pressures aremore accurate.

The graphs are based on the Peng-Robinson equation of state (1) as improved by Stryjek andVera (2, 3). The equations for thermodynamic properties using the Peng-Robinson equation ofstate are given in the appendix for volume, compressibility factor, fugacity coefficient, residualenthalpy, and residual entropy. Critical constants and ideal gas heat capacities for use in theequations are from the data compilations of DIPPR (8) and Yaws (28, 29, 30).

Vii

The literature has been carefully searched in construction of the graphs. References forsources used in preparing the work are given in the section following the graphs near the endof the book.

For the graphs, some of the compounds may undergo thermal decomposition (reaction) atthe higher temperatures. For such cases of thermal decomposition, the graphs are useful forascertaining property values of the pure compound which is contained in the reaction mixture.Chemistry handbooks and DIPPR (8) notes may be used for specifics regarding thermaldecomposition.

A list of compounds is given near the end of the book to aid the user in quickly locatingcompounds of interest from knowledge of the chemical formula or name.

An executable computer program, complete with data files, is available for calculation ofthermodynamic properties. For information on the program, contact Carl L. Yaws, Ph.D., P. O.Box 10053, Beaumont, Texas 77710, phone/fax (409) 880-8787.

vm



Diagrams

Volume 4


Elements

This page intentionally left blank

Ag SILVER

I AgCI SILVER CHLORIDE

I Agl SILVER IODIDE

Al ALUMINUM

AIB3H12 ALUMINUM BOROHYDRIDE

AIBr3 ALUMINUM BROMIDE

A1CI3 ALUMINUM CHLORIDE

AIF3 ALUMINUM FLUORIDE

AII3 ALUMINUM IODIDE

I AI2O3 ALUMINUM OXIDE

AI2S3O12 ALUMINUM SULFATE

AT ARGON

I As ARSENIC |

AsBr3 ARSENIC TRIBROMIDE

AsCI3 ARSENIC TRICHLORIDE

AsF3 ARSENIC TRIFLUOR1DE

AsF5 ARSENIC PENTAFLUORIDE

AsH3 ARSINE

Asl3 ARSENIC TRIIODIDE

As2O3 ARSENIC TRIOXIDE

At ASTATINE

Au GOLD

[~B BORON

BBr3 BORON TRIBROMIDE

BCI3 BORON TRICHLORIDE

BF3 BORON TRIFLUORIDE

BH2CO BORINE CARBONYL

BH3O3 BORIC ACID

B2D6 DEUTERODIBORANE

B2H5Br DIBORANE HYDROBROMIDE

B2H6 DIBORANE

B3N3H6 BORINE TRIAMINE

B4H10 TETRABORANE

B5H9 PENTABORANE

B5H11 TETRAHYDROPENTABORANE

B10H14 DECABORANE

Ba BARIUM

Be BERYLLIUM

BeB2H8 BERYLLIUM BOROHYDRIDE

BeBr2 BERYLLIUM BROMIDE

BeCI2 BERYLLIUM CHLORIDE

I BeF2 BERYLLIUM FLUORIDE

Bel2 BERYLLIUM IODIDE

__Bi BISMUTH

BiBr3 BISMUTH TRIBROMIDE

BiCI3 BISMUTH TRICHLORIDE

BrF5 BROMINE PENTAFLUORIDE

Br2 BROMINE

_C CARBON

CCI2O PHOSGENE

CF20 CARBONYL FLUORIDE

I CH4N2O UREA

CH4N2S THIOUREA

CNBr CYANOGEN BROMIDE

CNCI CYANOGEN CHLORIDE

CNF CYANOGEN FLUORIDE

CO CARBON MONOXIDE

COS CARBONYL SULFIDE

COSe CARBON OXYSELENIDE

CO2 CARBON DIOXIDE

CS2 CARBON DISULFIDE

CSeS CARBON SELENOSULFIDE

C2N2 CYANOGEN

C3S2 CARBON SUBSULFIDE

Ca CALCIUM

CaF2 CALCIUM FLUORIDE

CbF5 COLUMBIUM FLUORIDE

Cd CADMIUM

I CdCI2 CADMIUM CHLORIDE

CdF2 CADMIUM FLUORIDE

Cdl2 CADMIUM IODIDE

CdO CADMIUM OXIDE

GIF CHLORINE MONOFLUORIDE

CIF03 PERCHLORYL FLUORIDE

CIF3 CHLORINE TRIFLUORIDE

CIF5 CHLORINE PENTAFLUORIDE

CIHO3S CHLOROSULFONIC ACID

CIHO4 PERCHLORIC ACID

CI02 CHLORINE DIOXIDE

CI2 CHLORINE

CI2O CHLORINE MONOXIDE

CI207 CHLORINE HEPTOXIDE

Co COBALT

I CoCI2 COBALT CHLORIDE

CoNC3O4 COBALT NITROSYL TRICARBONYL

Cr CHROMIUM

CrC6O6 CHROMIUM CARBONYL

CrO2CI2 CHROMIUM OXYCHLORIDE

Cs CESIUM |

CsBr CESIUM BROMIDE

CsCI CESIUM CHLORIDE |

CsF CESIUM FLUORIDE

Csl CESIUM IODIDE

Cu COPPER

CuBr CUPROUS BROMIDE

CuCI CUPROUS CHLORIDE

CuCI2 CUPRIC CHLORIDE

Cul COPPER IODIDE

DCN DEUTERIUM CYANIDE

D2 DEUTERIUM

D20 DEUTERIUM OXIDE

Eu EUROPIUM

F2 FLUORINE

F2O FLUORINE OXIDE

_Fe IRON

FeC5O5 IRON PENTACARBONYL

FeCI2 FERROUS CHLORIDE

I FeCI3 FERRIC CHLORIDE

I Fr FRANCIUM

Ga GALLIUM

I GaCI3 GALLIUM TRICHLORIDE

I Gd GADOLINIUM |

Ge GERMANIUM

GeBr4 GERMANIUM BROMIDE

GeCI4 GERMANIUM CHLORIDE

GeHCI3 TRICHLORO GERMANE

GeH4 GERMANE

Ge2H6 DIGERMANE

Ge3H8 TRIGERMANE

HBr HYDROGEN BROMIDE

HCN HYDROGEN CYANIDE

HCI HYDROGEN CHLORIDE

HF HYDROGEN FLUORIDE

_H1 HYDROGEN IODIDE

HNO3 NITRIC ACID

H2 HYDROGEN

H2O WATER

H2O2 HYDROGEN PEROXIDE

H2S HYDROGEN SULFIDE

H2SO4 SULFURIC ACID

H2S2 HYDROGEN DISULFIDE

H2Se HYDROGEN SELENIDE

H2Te HYDROGEN TELLURIDE

H3NO3S SULFAMIC ACID

He HELIUM-3

He HELIUM-4

Hf HAFNIUM

Hg MERCURY

HgBr2 MERCURIC BROMIDE

HgCI2 MERCURIC CHLORIDE |

Hgl2 MERCURIC IODIDE

IF7 IODINE HEPTAFLUORIDE

12 IODINE

I In INDIUM ~

_lr IRIDIUM

_K POTASSIUM

KBr POTASSIUM BROMIDE

KCI POTASSIUM CHLORIDE |

KF POTASSIUM FLUORIDE

_KI POTASSIUM IODIDE

KOH POTASSIUM HYDROXIDE

Kr KRYPTON

La LANTHANUM

I Li LITHIUM

I LiBr LITHIUM BROMIDE

I LiCI LITHIUM CHLORIDE

LiF LITHIUM FLUORIDE

I Lil LITHIUM IODIDE

Lu LUTECIUM

Mg MAGNESIUM |

MgCI2 MAGNESIUM CHLORIDE

MgO MAGNESIUM OXIDE

Mn MANGANESE

[ MnCI2 MANGANESE CHLORIDE

Mo MOLYBDENUM

MoF6 MOLYBDENUM FLUORIDE

MoO3 MOLYBDENUM OXIDE

NCI3 NITROGEN TRICHLORIDE

ND3 HEAVY AMMONIA

NF3 NITROGEN TRIFLUORIDE

NH3 AMMONIA

NH3O HYDROXYLAMINE

I NH4Br AMMONIUM BROMIDE

I NH4CI AMMONIUM CHLORIDE

I NH4I AMMONIUM IODIDE

NH5O AMMONIUM HYDROXIDE

NH5S AMMONIUM HYDROGENSULFIDE

NO NITRIC OXIDE

NOCI NITROSYL CHLORIDE

NOF NITROSYL FLUORIDE

NO2 NITROGEN DIOXIDE

N2 NITROGEN

N2F4 TETRAFLUOROHYDRAZINE

N2H4 HYDRAZINE

N2H4C AMMONIUM CYANIDE

N2H6CO2 AMMONIUM CARBAMATE

N2O NITROUS OXIDE

N2O3 NITROGEN TRIOXIDE

N204 NITROGEN TETRAOXIDE

N205 NITROGEN PENTOXIDE

I Na SODIUM

NaBr SODIUM BROMIDE

NaCN SODIUM CYANIDE

NaCI SODIUM CHLORIDE

I NaF SODIUM FLUORIDE

Nal SODIUM IODIDE

NaOH SODIUM HYDROXIDE

Na2SO4 SODIUM SULFATE

Nb NIOBIUM

Nd NEODYMIUM

Ne NEON

Ni NICKEL

NiC4O4 NICKEL CARBONYL

NiF2 NICKEL FLUORIDE

Np NEPTUNIUM

02 OXYGEN

O3 OZONE

Os OSMIUM

OsOF5 OSMIUM OXIDE PENTAFLUORIDE

OsO4 OSMIUM TETROXIDE - YELLOW

I OsO4 OSMIUM TETROXIDE-WHITE ~

_P PHOSPHORUS-WHITE

PBr3 PHOSPHORUS TRIBROMIDE

PCI2F3 PHOSPHORUS DICHLORIDE TRIFLUORIDE

PCI3 PHOSPHORUS TRICHLORIDE

PCI5 PHOSPHORUS PENTACHLORIDE

PH3 PHOSPHINE

PH4Br PHOSPHONIUM BROMIDE

PH4CI PHOSPHONIUM CHLORIDE

PH4I PHOSPHONIUM IODIDE

POCl3 PHOSPHORUS OXYCHLORIDE

PSBr3 PHOSPHORUS THIOBROMIDE

PSCI3 PHOSPHORUS THIOCHLORiDE

P406 PHOSPHORUS TRIOXIDE

P4O10 PHOSPHORUS PENTOXIDE

P4S10 PHOSPHORUS PENTASULFIDE

Pb LEAD

PbBr2 LEAD BROMIDE

PbCI2 LEAD CHLORIDE

PbF2 LEAD FLUORIDE

Pbl2 LEAD IODIDE

PbO LEAD OXIDE

PbS LEAD SULFIDE

Pd PALLADIUM

Po POLONIUM

_Pt PLATINUM

Ra RADIUM

Rb RUBIDIUM

RbBr RUBIDIUM BROMIDE

RbCI RUBIDIUM CHLORIDE

RbF RUBIDIUM FLUORIDE

Rbl RUBIDIUM IODIDE

Re RHENIUM

Re2O7 RHENIUM HEPTOXIDE

Rh RHODIUM

Rn RADON

Ru RUTHENIUM

RuF5 RUTHENIUM PENTAFLUORIDE

_S SULFUR

SF4 SULFUR TETRAFLUORIDE

SF6 SULFUR HEXAFLUORIDE

SOBr2 THIONYL BROMIDE

SOCI2 THIONYL CHLORIDE

SOF2 SULFUROUS OXYFLUORIDE

SO2 SULFUR DIOXIDE

S02CI2 SULFURYL CHLORIDE

SO3 SULFUR TRIOXIDE

S2C12 SULFUR MONOCHLORIDE

Sb ANTIMONY

SbBr3 ANTIMONY TRIBROMIDE

SbCI3 ANTIMONY TRICHLORIDE

SbCIS ANTIMONY PENTACHLORIDE

SbH3 STIBINE

Sbl3 ANTIMONY TRIIODIDE

Sb203 ANTIMONY TRIOXIDE

Sc SCANDIUM

Se SELENIUM

SeCI4 SELENIUM TETRACHLORIDE

SeF6 SELENIUM HEXAFLUORIDE

SeOCI2 SELENIUM OXYCHLORIDE

SeO2 SELENIUM DIOXIDE

_Si SILICON

SiBrCI2F BROMODICHLOROFLUOROSILANE

SiBrF3 TRIFLUOROBROMOSILANE

I SiBr2CIF DIBROMOCHLOROFLUOROSILANE

SJCIF3 TRIFLUOROCHLOROSILANE

SiCI2F2 DICHLORODIFLUOROSILANE

SiCI3F TRICHLOROFLUOROSILANE

SJCI4 SILICON TETRACHLORIDE

SiF4 SILICON TETRAFLUORIDE

SiHBr3 TRIBROMOSILANE

SiHCI3 TRICHLOROSILANE

I SiHF3 TRIFLUOROSILANE

SiH2Br2 DIBROMOSILANE

SiH2CI2 DICHLOROSILANE

SiH2F2 DIFLUOROSILANE

SiH2I2 DIIODOSILANE

SiH3Br MONOBROMOSILANE

SiH3CI MONOCHLOROSILANE

SiH3F MONOFLUOROSiLANE

SiH3I IODOSILANE

SiH4 SILANE

SiO2 SILICON DIOXIDE

Si2CI6 HEXACHLORODISILANE

Si2F6 HEXAFLUORODISILANE

Si2H5CI DISILANYL CHLORIDE

Si2H6 DISILANE

Si2OCI3F3 TRICHLOROTRIFLUORODISILOXANE

Si2OCI6 HEXACHLORODISILOXANE

Si2OH6 DISILOXANE

Si3CI8 OCTACHLOROTRISILANE

Si3H8 TRISILANE

Si3H9N TRISILAZANE

Si4H10 TETRASILANE

Sm SAMARIUM

Sn TIN

I SnBr4 STANNIC BROMIDE ~

SnCI2 STANNOUS CHLORIDE

SnCI4 STANNIC CHLORIDE

SnH4 STANNIC HYDRIDE

Snl4 STANNIC IODIDE

_Sr STRONTIUM

SrO STRONTIUM OXIDE

Ta TANTALUM

Tc TECNNETIUM

Te TELLURIUM

TeCI4 TELLURIUM TETRACHLORIDE

TeF6 TELLURIUM HEXAFLUORIDE

_Ti TITANIUM

TICI4 TITANIUM TETRACHLORIDE

_TI THALLIUM

TIBr THALLOUS BROMIDE

_TII THALLOUS IODIDE

Tm THULIUM

I U URANIUM

UF6 URANIUM FLUORIDE

_V VANADIUM

VC4 VANADIUM TETRACHLORIDE

VOCI3 VANADIUM OXYTRiCHLORIDE

_W TUNGSTEN

WF6 TUNGSTEN FLUORIDE

Xe XENON

D. Y. and D. B. Robinson, Ind. Eng. Chem. Fundam., 15 (No. 1), 59 (1976).

I Zn ZINC

ZnCI2 ZINC CHLORIDE

ZnF2 ZINC FLUORIDE

ZnO ZINC OXIDE

ZnSO4 ZINC SULFATE

_Zr ZIRCONIUM

ZrBr4 ZIRCONIUM BROMIDE

ZrCI4 ZIRCONIUM CHLORIDE

1. Peng, D. Y. and D. B. Robinson, Ind. Eng. Chem. Fundam., 15 (No. 1), 59 (1976).2. Stryjek, R. and J. H. Vera, Can. J. Chem. Eng., 64, 323 (1986).3. Stryjek, R. and J. H. Vera, Can. J. Chem. Eng., 64, 334 (1986).4. SELECTED VALUES OF PROPERTIES OF HYDROCARBONS AND RELATED COMPOUNDS,

Thermodynamics Research Center, TAMU, College Station, TX (1977, 1984).5. SELECTED VALUES OF PROPERTIES OF CHEMICAL COMPOUNDS. Thermodynamics Research

Center, TAMU, College Station, TX (1977, 1987).6. Ambrose, D., VAPOUR-LIQUID CRITICAL PROPERTIES. National Physical Laboratory, Teddington,

England, NPL Report Chem 107 (Feb., 1980).7. Nesmeyanov, A. N., VAPOR PRESSURE OF THE CHEMICAL ELEMENTS. Elsevier, New York, NY

(1963).8. Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS.

Parts 1, 2, 3 and 4, Supplements 1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).9. Simmrock, K. H., R. Janowsky and A. Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES. Vol.

II, Parts 1 and 2, Dechema Chemistry Data Series, 6000 Frankfurt/Main, Germany (1986).10. INTERNATIONAL CRITICAL TABLES. McGraw-Hill, New York, NY (1926).11. Braker, W. and A. L. Mossman, MATHESON GAS DATA BOOK. 6th ed., Matheson Gas Products,

Secaucaus, NJ (1980).12. CRC HANDBOOK OF CHEMISTRY AND PHYSICS. 66th - 75th eds., CRC Press, Inc., Boca Raton,

FL (1985-1994).13. LANGE'S HANDBOOK OF CHEMISTRY. 13th and 14th eds., McGraw-Hill, New York, NY (1985,

1992).14. PERRY'S CHEMICAL ENGINEERING HANDBOOK. 6th ed., McGraw-Hill, New York, NY (1984).15. Kaye, G. W. C. and T. H. Laby, TABLES OF PHYSICAL AND CHEMICAL CONSTANTS. Longman

Group Limited, London, England (1973).16. Raznjevic, Kuzman, HANDBOOK OF THERMODYNAMIC TABLES AND CHARTS. Hemisphere

Publishing Corporation, New York, NY (1976).17. Vargaftik, N. B., TABLES ON THE THERMOPHYSICAL PROPERTIES OF LIQUIDS AND GASES.

2nd ed., English translation, Hemisphere Publishing Corporation, New York, NY (1975, 1983).18. Lyman, W. J., W. F. Reehl and D. H. Rosenblatt, HANDBOOK OF CHEMICAL PROPERTY

ESTIMATION METHODS. McGraw-Hill, New York, NY (1982).19. Reid, R. C., J. M. Prausnitz and B. E. Poling, THE PROPERTIES OF GASES AND LIQUIDS. 3rd ed.

(R. C. Reid and T. K. Sherwood), 4th ed., McGraw-Hill, New York, NY (1977, 1987).20. Kirk, R. E. and D. F. Othmer, editors, ENCYCLOPEDIA OF CHEMICAL TECHNOLOGY. 3rd ed.,

Vols. 1-24, John Wiley and Sons, Inc., New York, NY (1978-1984).21. CONDENSED CHEMICAL DICTIONARY. 10th (G. G. Hawley) and llth eds. (N. I. Sax and R. J.

Lewis, Jr.), Van Nostrand Reinhold Co., New York, NY (1981,1987).22. Verschueren, K., HANDBOOK OF ENVIRONMENTAL DATA ON ORGANIC CHEMICALS. 2nd ed.,

Van Nostrand Reinhold, New York, NY (1983).23. Lewis, R. J., Sr., HAZARDOUS CHEMICALS DESK REFERENCE. 2nd ed., Van Nostrand Reinhold,

New York, NY (1991).24. Boublick, T., V. Fried and E. Hala, THE VAPOUR PRESSURES OF PURE SUBSTANCES. 1st and 2nd

eds., Elsevier, New York, NY (1975, 1984).25. Ohe, S., COMPUTER AIDED DATA BOOK OF VAPOR PRESSURE. Data Book Publishing Company,

Tokyo, Japan (1976).

344

26. Hultgren, R., P. D. Desai, D. T. Hawkins, M. Gleiser, K. K. Kelley and D. D. Wagman, SELECTEDVALUES OF THE THERMQDYNAMIC PROPERTIES OF THE ELEMENTS. American Society forMetals, Metals Park, OH (1973).

27. Simmrock, K. H., R. Janowsky and A. Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES. Vol.II, Parts 1 and 2, Dechema Chemistry Data Series, 6000 Frankfurt/Main, Germany (1986).

28. Stull, D. R. and H. Prophet, JANAF THERMOCHEMICAL TABLES. 2nd edition, NSRDS-NBS 37, USGovernment Printing Office, Washington, DC (June, 1971).

29. Wagman, D. D. and others, NBS TABLES OF CHEMICAL THERMODYNAMIC PROPERTIES. J.Phys. Chem. Ref. Data, H, Supplement No. 2 (1982).

30. Chase, M. W. and others, JANAF THERMOCHEMICAL TABLES. 3rd edition, Parts 1 (Al-Co) and 2(Cr-Zr), J. Phys. Chem. Ref. Data, 14, Supplement No. 1 (1985).

31. Kelley, K. K., CONTRIBUTIONS TO THE DATA ON THEORETICAL METALLURGY. Bureau ofMines Bulletin 584, US Government Printing Office, Washington, DC (1960).

32. Wicks, C. E. and F. E. Block, THERMODYNAMIC PROPERTIES OF 65 ELEMENTS - THEIROXIDES. HALIDES. CARBIDES. AND NITRIDES. Bureau of Mines Bulletin 605, US GovernmentPrinting Office, Washington, DC (1963).

33. Barin, I. and O. Knacke, THERMOCHEMICAL PROPERTIES OF INORGANIC SUBSTANCES.Springer-Verlag, New York, NY (1973).

34. Yaws, C. L. and others, Solid State Technology, 16, No. 1, 39 (1973).35. Yaws, C. L. and others, Solid State Technology, 17, No. 1, 47 (1974).36. Yaws, C. L. and others, Solid State Technology, H, No. 11, 31 (1974).37. Yaws, C. L. and others, Solid State Technology, 18, No. 1, 35 (1975).38. Yaws, C. L. and others, Solid State Technology, 21, No. 1, 43 (1978).39. Yaws, C. L. and others, Solid State Technology, 24, No. 1, 87 (1981).40. Yaws, C. L. and others, J. Ch. I. Ch. E., 12, 33 (1981).41. Yaws, C. L. and others, J. Ch. I. Ch. E., H, 205 (1983).42. Yaws, C. L. and others, Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984).43. Yaws, C. L., PHYSICAL PROPERTIES. McGraw-Hill, New York, NY (1977).44. Yaws, C. L., THERMODYNAMIC AND PHYSICAL PROPERTY DATA. Gulf Publishing Co.,

Houston, TX (1992).45. Yaws, C. L. and R. W. Gallant, PHYSICAL PROPERTIES OF HYDROCARBONS. Vols. 1 (2nd ed.),

2 (3rd ed.), 3, and 4, Gulf Publishing Co., Houston, TX (1992, 1993, 1993, 1995).46. Yaws, C. L., HANDBOOK OF VAPOR PRESSURE. Vol. 4 - Inorganic Compounds and Elements, Gulf

Publishing Co., Houston, TX (1995).

345

Appendix A

Equations for Thermodynamic Properties

EnthalpyT

H = Href + ( C dT

EntropyT

S = Sreff + I cp/ dT- R

(1)

Internal Energy

U=H-PV (3)

Helmholtz Energy

Gibbs Energy

G = H - T S (5)(5)

Parameters

Cp = heat capacity of ideal gas (6)

Href , Sref - reference state for ideal gas (7)

Tref ,Pr e f = reference temperature , reference pressure (8)

, A5resid = residual enthalpy , residual entropy (9)

346

Appendix B

Peng-Robinson Equation of State for Thermodynamic Properties

Equation of State

p - RT _ _ a _ (1)V - b V(V + b) + b(V - b) v '

Volume

(b _ ) V2 + ( a/p _ 3b2 _ 2b) V + (b3 + —I)2 - ab/p ) = 0 (2)

Compressibility Factor

Z3 - (1 - B)Z2 + (A - 3B2 - 2B)Z - (AB - B2 - B3) =0 (3)

Fuaacity Coefficient

m*-«-i-i*(*-*)-^i*(z:g:£a (4)Residual Enthalpy

= 1 _ z + —— (1 + — ln/-Z -0.414B

Hresid = 1 _ z+ (1 + D/)ln/Zl+ 2.414B) (5)

Residual Entropy

- -ln(z -B) + z-0.414B)Parameters

a = aca (7)

ac = 0 . 4 7 2 4 R T e P c (8)

b = 0.

a = [1 + m(l - r ) ] 2 (10)

= 0.37464 + 1.54226Q - 0 .26992Q 2 (original PR)

/n = see Stryjek , Vera (modified PR)

347

A = aP/R2T2 = 0.45724aPr/T2 = 0.45724 (13)

(p/p )B = bP/RT = 0.07780Pr/Tr = 0.07780 c(14)

(15)

348

Appendix C

Examples for Thermodynamic Diagrams

Example 1 - Vessel Pressure

A vessel containing gaseous chlorine (C12) at 395 psia and 200 F is exposed to a fire in the process area.The temperature in the vessel is 800 F when the fire is extinguished. Estimate the final pressure in the vessel.

Since the vessel size does not change appreciably, this situation maybe approximated by a constant volumeprocess. Using the thermodynamic diagram, the initial volume is about 0.20 f t3/ lb . At this same volume and finaltemperature, the pressure is:

Pc~. = 900 psia

Example 2 - Reactor Size

A batch reactor is to contain 1,000 Ib of chlorine (C12) at 200 psia and 400 F. Estimate the reactor size.

Using the thermodynamic diagram, the volume is about 0.61 ftA3/lb at these conditions. Substitution of thisinto the equation below for the reactor size provides:

Reactor Size = (LOOP Ifr) (0.61 f t3 / l f r ) = 610 ft"3

Example 3 - Process Vessel Size

A process vessel is to contain 300 Ib of at 300 psia and 600 F. Estimate the process vessel size.

Using the thermodynamic diagram, the volume is about 0.51 ftA3/lb at these conditions. Substitution of thisinto the equation below for the process vessel size provides:

Vessel Size = (300 Ib) (0.51 ft3/lb) = 153 ft3

Example 4 - Heat Exchanger Duty

Chlorine (C12, 30,000 Ib/hr) at 100 psia and 200 F is heated to 800 F and then fed to a plug-flow reactor.Estimate the heat exchanger duty necessary to accomplish the heating.

Substitution of mass flow and enthalpies from the thermodynamic diagram into the equation below provides:

Heat Exchanger Duty = mass flow (H, - H.1 = (30.000 lb/hr)(85 - 10) BTU/lb

= 2.25 million BTU/hr

349

Example 5 - Compression

Chlorine (C12, 20,000 Ib/hr) at 10 psia and 0 F is compressed to 700 psia. Estimate the change in enthalpyfor the compression assuming adibatic and reversible conditions (constant entropy).


Enthalpy Change = mass flow (H, - H,) = r20.000 lb/hr)(80 - (-10)) BTU/lb

= 1.8 million BTU/hr

This change in enthalpy represents energy that is required to accomplish the compression under adibaticand reversible conditions. Under operating conditions, the actual energy that is required for the compression willbe somewhat more depending on the efficiency.

Example 6 - Expansion

Chlorine (C12, 30,000 Ib/hr) at 600 psia and 750 F is expanded to 20 psia. Estimate the change in enthalpyfor the expansion assuming adibatic and reversible conditions (constant entropy).


Enthalpy Change = mass flow (H, - H,) = (30.000 lb/hr)(0 - 75) BTU/lb

= - 2.25 million BTU/hr

This change in enthalpy represents energy that is available from the expansion under adibatic and reversibleconditions. Under operating conditions, the actual energy that is available for the expansion will be somewhat lessdepending on the efficiency.

350

Appendix D

CRITICAL PROPERTIES AND ACENTRIC FACTOR FOR INORGANIC COMPOUNDS AND ELEMENTS*

Carl L. YawsLamar University, Beaumont, Texas

NO FORMULA

1 Ag2 AgCl3 Agl4 Al5 ALB3H126 AlBr37 ALC138 ALF39 ALI310 A120311 Al2S301212 Ar13 As14 AsBr315 AsCl316 AsF317 AsF518 AsH319 Asl320 As20321 At22 Au23 B24 BBr325 BC1326 BF327 BH2CO28 BH30329 B2D630 B2H5Br31 B2H632 B3N3H633 B4H1034 B5H935 B5H1136 B10H1437 Ba38 Be39 BeB2H840 BeBr241 Bed 242 BeF243 Bel 244 Bi45 BiBr346 BiC1347 BrF548 Br249 C50 CC12051 CF2052 CH4N2053 CH4N2S54 CNBr55 CNCl56 CNF57 CO58 COS

NAME

SILVERSILVER CHLORIDESILVER IODIDEALUMINUMALUMINUM BOROHYDRIDEALUMINUM BROMIDEALUMINUM CHLORIDEALUMINUM FLUORIDEALUMINUM IODIDEALUMINUM OXIDEALUMINUM SULFATEARGONARSENICARSENIC TR I BROMIDEARSENIC TRICHLORIDEARSENIC TRI FLUORIDEARSENIC PENTAFLUORIDEARSINEARSENIC TRI IODIDEARSENIC TRI OX IDEASTATINEGOLDBORONBORON TRIBROMIDEBORON TRICHLORIDEBORON TRI FLUORIDEBORINE CARBONYLBORIC ACIDDEUTERODIBORANEDIBORANE HYDROBROMIDEDIBORANEBORINE TRIAMINETETRABORANEPENTABORANETETRAHYDROPENTABORANEDECABORANEBARIUMBERYLLIUMBERYLLIUM BOROHYDRIDEBERYLLIUM BROMIDEBERYLLIUM CHLORIDEBERYLLIUM FLUORIDEBERYLLIUM IODIDEBISMUTHBISMUTH TRIBROMIDEBISMUTH TRICHLORIDEBROMINE PENTAFLUORIDEBROMINECARBONPHOSGENECARBONYL FLUORIDEUREATHIOUREACYANOGEN BROMIDECYANOGEN CHLORIDECYANOGEN FLUORIDECARBON MONOXIDECARBONYL SULFIDE

MWg/mol

107.868143.321234.77326.98271.510266.694133.34083.977407.695101.961342.15439.94874.922314.634181.280131.917169.91477.945455.635197.841210.000196.96710.811250.523117.16967.80640.83761.83333.718106.56627.67080.50153.32363.12665.142122.221137.3279.01238.698168.82079.91847.009262.821208.980448.692315.338174.896159.80812.01198.91666.00760.05676.122105.92261.47045.01628.01060.076

TFK

1234.00728.15825.15933.00209.15390.15465.701313.15464.152325.001043.2083.80

1090.15306.15255.15267.25193.35156.28419.15585.95575.151337.332348.15228.15166.15146.05136.15458.15

168.95107.65214.95153.25226.35

372.751000.151560.15396.15763.15678.151073.15761.15544.15491.15503.15211.75265.904247.00145.37161.89405.85454.15331.15266.65

68.15134.35

TBK

2485.001837.151779.152329.15319.05529.45453.151810.15658.653253.15

87.28885.00493.15403.55329.45220.35210.67676.15730.35607.003120.004133.00364.85285.65173.35209.15

179.87289.45180.65323.75289.25331.55340.15486.151907.002744.00363.15747.15760.15

760.151698.15734.15714.15313.55331.904203.00280.71188.58465.00536.00334.65286.00227.1781.70223.00

TcK

7480.00

7151.00513.77763.00629.00

983.005335.00

150.861673.15789.01654.00530.21357.73373.00

4398.00

581.00451.95260.90340.03

293.74466.98289.80521.20466.66568.45547.13

4620.001220.001178.00470.00584.156810.00455.00297.00705.00854.00

449.00368.51132.92378.80

PCbar

5066.0

5458.0

28.9026.35

...

48.98223.0066.4059.1287.8141.1364.13

...

48.6638.7149.8555.03

32.1743.6140.5336.3438.8446.4141.29

57.16103.352230.056.7457.6090.5082.30

59.9079.0034.9963.49

3Vc

cm /mo I

58.20

39.00

310.00261.45

408.00

74.5934.90270.69252.00137.55198.14132.50

50.30

272.00265.99123.61140.74

208.01243.93173.10326.72273.67285.10301.82

79.40302.00261.70187.31135.0018.80190.22141.00218.00248.00

163.00106.2693.10135.10

Pc ,g/cm3

1.8534

0.6918

0.86030.5100

0.9993

0.53562.14681.16230.71940.95900.85750.5883

3.9158

0.92100.44050.54850.2902

0.16210.43690.15980.24640.19480.22140.2158

2.63201.48571.20500.93371.18380.63890.52000.46810.27550.3069

0.37710.42360.30090.4447

Zc

0.474

0.358

0.1410.132

...

0.2910.0560.2740.2740.2740.2740.274

...

0.2740.2740.2840.274

0.2740.2740.2910.2740.2740.2800.274

0.2740.2870.0740.2850.3290.3370.287

0.2620.2740.2950.272

(j)

0.150

...

0.3990.660

...

0.0000.121

0.006

...

0.1510.430

0.125

0.1191.5660.2010.283

0.359

0.320

0.0660.097

SOURCE

1,62212,213,6,101,10

2,7,10

114,5,102,7,212,10,212,212,21

234,54,5,64,52,10,21113,2112,213,211,142,212,212,8,142,212,72,4,54,52332,733,62,62,62,6,21

11111212,2111

* A computer program, containing data for all compounds, is available for a nominal fee (Carl L. Yaws, Box 10053, Lamar University,Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be accessed by other software.

351

NO FORMULA

59 COSe60 C0261 CS262 CSeS63 C2N2

. p7c966

AA PaF967 phFl

68 Cd60o PHP l 970 CDF271 CD12T) CDO73 CIF74 CIF0375 CIF376 CIF577 CIH03S78 CIH0479 CI0280 C1281 C12082 C1207OT

01 )

85 CoNc30486 Cr

07 CrC606prpXnA

88 Cr02Cl289 Cs90 CsBr

O1 Cscl

Op Csf

93 CSI

94 CuO1 CURC

96 CUCl

97 CUCL2

99 DCN100 D2101 D20in? FU103 F2104 F20105 Fe106 FeC505my For IPins Eon 7109 Fr

110 Ga111 GaCl31 19 PH113 Ge]

114 GeBr4115 GeCl4116 GeHCl3117 GeH4118 Ge2H6119 Ge3H8120 HBr121 HCN122 HCI123 HF124 HI125 HN03126 H2127 H20

NAME

CARBON OXYSELENIDECARBON DIOXIDECARBON DISULFIDECARBON SELENOSULFIDECYANOGENPADQnkT CIIQCIH FinC

CALCIUM

COLOBIUN FLORIDECADMIUMp ADMIUM CHLORIDECADMTIUM FLURIDE

C ADM HIM IODIDECADMIUM OXIDE

CHLORINE MONOFLUORIDEPERCHLORYL FLUORIDECHLORINE TRI FLUORIDECHLORINE PENTAFLUORIDECHLOROSULFONIC ACIDPERCHLORIC ACIDCHLORINE DIOXIDECHLORINECHLORINE MONOXIDECHLORINE HEPTOXIDEpOQAI T

COBOA T CHLORIDECOBALT NITROSYL TRICARBONYLPADBONYL

CHROMIUM CORBONYL

CHROMIUM OXYCHLORIDECESIUMCESIUM BROMIDE

CESIUM FLORIEDCESIUM IODIDECOPPERCUPPROUS BROMIDE

CUPROUS CHLORIDECADMIUM CHLORIDE

DEUTERIUM CYANIDEDEUTERIUMDEUTERIUM OXIDEEUROPIUM

FLUORINEFLUORINE OXIDEIRONIRON PENTACARBONYLFERROUS CHLORIDE

ECDDTP puinoincEDAUPTI IM

GALLIUMGALLIUM TRICHLORIDE

GERMANIUM BROMIDEGERMANIUM CHLORIDETRICHORD GERMANEGERMANED I GERMANETRI GERMANEHYDROGEN BROMIDEHYDROGEN CYANIDEHYDROGEN CHLORIDEHYDROGEN FLUORIDEHYDROGEN IODIDENITRIC ACIDHYDROGENWATER

MW/mol

106.97044.01076.143

123.03752.035

100.16540.07878.075

187.898

112.411183.316

150.3087AA 99n128.410

54.451102.44992.448

130.445116.525100.45867.45270.90586.905

182.90158.933

1 9O 839

179 971

51 996

220.059

154.900132.905212 809168.358151.904259.810

63.546IAX Ain

OQ OOO

1XA AS1ion A'jn28.0344.032

20.031ici oxc

37.99753.99655.847

195.89919A 7191A9 9DC,

997 flfin

69.723176.0811^7 y^n79 Am

392.226214.421179.97676.642

151.268225.89480.91227.02636.46120.006

127.91263.013

2.01618.015

TF

K

216.58161.58197.95238.75977 51

1 1 -ic ic

IAOI on7/p /LC

594.05Q/ 1 1C

707 mXCQ 1C

128.15125.41190.15

193.15171.95213.55172.12157.15182.15

1 7AP. 1 11 nnn 1 c.

9A9 119isn 11

A97 A1

176.65301.65ono 11010 11O1A 11ROA 11

1357.77777 117n7 nnonA 11070 <c

261.1518.73

276.96mos is

53.5349.25

1808.15252.15OA1 11177 117nn 11302.91350.90

11P.7 111911 An299.25223.65202.05107.26164.15167.55186.34259.91158.97189.79222.38231.55

13.95273.15

TB

K

251.25194.70319.37358.75252.15

1 7A9 nn9snA in

/QQ 1C

1043.15i9An 119n9A 111 nAO 1 i1R79 11

172.65226.49284.65260.05427.00385.00284.05239.12275.35351.95

OCTQ nn1797 1C

717 119j>/ n on

A9A 11

390.25963.15

1177 111177 11119A 111117 11

3150.001A9p. 1C

1 7A7 1 119AA 111 ADO 1 1

299.3523.65

374.5517A9 nn

84.95128.55

3000.00378.15

1 9OO 1 11O9 11070 nn

2517.00474.15

1 77n nn7191 nn462.15357.15348.15185.00304.65383.95206.45298.85188.15292.67237.55356.15

20.39373.15

TcK

406.58304.19552.00576.53399.90

2291.00

282.32368.40459.39415.90700.00631.00465.00417.15444.68565.78

1A7 Aft

626.332048.10

5123.00

9A71 nn9nm nn

482.6338.35

643.89inn nn

144.31215.10

9340.00607.20

7620.00694.00

AAnn nn740.00574.00559.78308.00491.01616.37363.15456.65324.65461.15423.85520.0033.18

647.13

PCbar

86.3073.8179.0374.1263.03

...

79.0153.7077.7952.6085.0038.60

108.2877.1174.9450.90

59.99116.50

...

113.5616.64

219.41

52.1549.501015035.24

38.20

44.1739.5746.2155.5046.6747.0585.5253.9183.0964.8583.1068.9013.13

220.55

Vc

cmVmol

107.3294.00

160.00177.18144.52

37.90

81.39161.00134.52230.40195.00168.0097.83

123.75135.16253.23

237.81316.40

61.00

96.8160.2656.30

66.2097.6028.00

392.52

75.30263.00

381.66330.45275.96140.00239.68298.44100.26138.5981.0269.00

121.94145.0064.1555.95

Pc 3g/cm

0.99670.46820.47590.69440.3601

2.9660

0.66900.63630.68720.56620.59760.59800.68950.57300.64300.7223

0.65130.4201

1.0417

0.28960.06690.3558

0.57400.55321.99450.4991

0.92590.6695

1.02770.64890.65220.54740.63110.75690.80700.19500.45000.28991.04900.43460.03140.3220

Zc

0.2740.2740.2760.2740.274

...

0.2740.2820.2740.3500.2850.1240.2740.2750.2740.274

0.2740.216

...

0.2740.3140.231

0.2880.2700.3660.274

0.174

0.2740.2740.2740.3030.2740.2740.2840.1970.2490.1170.2880.2310.3050.229

w

0.2280.108

...

0.173

0.2160.3010.0500.3560.069

...

...

-0.140.368

0.059

-0.30

0.458

0.151

0.0690.4100.1320.3830.0380.714-0.220.345

SOURCE

3,21

13,213,634 C»•>1

3,6

2

2,21122,6,1011112,212,214 C,5

3 01,212 1 C,4,53 7,'

2,7,212,6

T

4,5,6

1T

2,21114 1 A

1*1°

1

2,613,213 7,'

4 c,54,5,6

4 C,54 1 A.

»->,6

2,212,212,2112,212,21

1111111


352

NO FORMULA NAMEMWg/mol

Tc

KPCbar 3

Vc Pc 3cm3/mol g/cm3 SOURCE

128 H202 HYDROGEN PEROXIDE129 H2S HYDROGEN SULFIDE130 H2S04 SULFURIC ACID131 H2S2 HYDROGEN DISULFIDE132 H2Se HYDROGEN SELENIDE133 H2Te HYDROGEN TELLURIDE134 H3N03S SULFAMIC ACID135 He HELIUM-3136 He HELIUM-4137 Hf HAFNIUM138 Hg MERCURY139 HgBr2 MERCURIC BROMIDE140 HgCl2 MERCURIC CHLORIDE141 Hgl2 MERCURIC IODIDE142 IF7 IODINE HEPTAFLUORIDE143 12 IODINE144 In INDIUM145 Ir IRIDIUM146 K POTASSIUM147 KBr POTASSIUM BROMIDE148 KCl POTASSIUM CHLORIDE149 KF POTASSIUM FLUORIDE150 KI POTASSIUM IODIDE151 KOH POTASSIUM HYDROXIDE152 Kr KRYPTON153 La LANTHANUM154 Li LITHIUM155 LiBr LITHIUM BROMIDE156 LiCl LITHIUM CHLORIDE157 LiF LITHIUM FLUORIDE158 Lil LITHIUM IODIDE159 Lu LUTECIUM160 Mg MAGNESIUM161 MgCl2 MAGNESIUM CHLORIDE162 MgO MAGNESIUM OXIDE163 Mn MANGANESE164 MnCl2 MANGANESE CHLORIDE165 Mo MOLYBDENUM166 MoF6 MOLYBDENUM FLUORIDE167 Mo03 MOLYBDENUM OXIDE168 NC13 NITROGEN TRICHLORIDE169 ND3 HEAVY AMMONIA170 NF3 NITROGEN TRIFLUORIDE171 NH3 AMMONIA172 NH30 HYDROXYLAMINE173 NH4Br AMMONIUM BROMIDE174 NH4CI AMMONIUM CHLORIDE175 NH4I AMMONIUM IODIDE176 NH50 AMMONIUM HYDROXIDE177 NH5S AMMONIUM HYDROGENSULFIDE178 NO NITRIC OXIDE179 NOCl NITROSYL CHLORIDE180 NOF NITROSYL FLUORIDE181 N02 NITROGEN DIOXIDE182 N2 NITROGEN183 N2F4 TETRAFLUOROHYDRAZINE184 N2H4 HYDRAZINE185 N2H4C AMMONIUM CYANIDE186 N2H6C02 AMMONIUM CARBAMATE187 N20 NITROUS OXIDE188 N203 NITROGEN TRIOX IDE189 N204 NITROGEN TETRAOXIDE190 N205 NITROGEN PENTOXIDE191 Na SODIUM192 NaBr SODIUM BROMIDE193 NaCN SODIUM CYANIDE194 NaCl SODIUM CHLORIDE195 NaF SODIUM FLUORIDE196 Nal SODIUM IODIDE

34.01534.08298.07966.14880.976129.61697.0953.0164.003

178.490200.590360.398271.495454.399259.893253.809114.818192.22039.098119.00274.55158.097166.00356.10683.800138.9066.94186.84542.39425.939133.845174.96724.30595.21040.30454.938125.84395.940209.930143.938120.36520.05571.00217.03133.03097.94353.491144.94335.04651.11230.00665.45949.00546.00628.013104.00732.04544.05678.07144.01376.01292.011108.01022.990102.89449.00858.44241.988149.894

272.72187.68283.46183.45209.15224.15478.00

1.011.76

2506.15234.29510.15550.15532.15278.65386.75429.752719.15336.351003.151044.001153.15996.15679.00115.781193.15453.69820.15887.151143.15719.151936.15923.15985.153105.001519.15923.152895.15290.151068.15246.15199.1566.36195.41306.25

793.20

194.15391.15112.15213.55139.15261.9563.15111.65274.69309.15

182.33170.00261.90303.15370.981020.00836.851073.951269.00924.15

423.35212.80610.00337.15232.05271.15

3.204.22

5960.00629.73592.15577.15627.15277.15458.392323.004450.001037.001656.151688.871775.151597.151600.00119.803643.001597.001583.151655.151954.151444.152535.001376.001691.153873.202392.001463.155081.15309.151424.15344.15239.75144.09239.72383.00669.15612.00678.05

730.15 216.84373.53 89.63925.00 64.00542.39411.10438.04

3.315.20

88.3683.4471.93

1.172.28

77.70 0,98.49 0,

177.03 0.139.83 0,112.24 0.138.73 0,225.00 0,72.50 0,57.30 0,

437834605540473172159343431504160699

0.2780.2840.1470.2740.2740.274

0.3080.302

0.3600.083

-0.47-0.39

1735.00 1608.0 56.35 3.5597 0.628 -0.16

1078.10 100.00447.53 41.26819.15 116.54

6730.00 2432.0

247.10 1.0518 0.274 ---155.00 1.6375 0.265 0.11782.60 1.3900 0.359 ---

2223.00 162.12 209.00 0.1871 0.183 -0.18

3470.00 180.00 625.00 0.1193 0.39 -0.12

209.35 55.029511.00 5460.04085.00 1722.5

91.20 0.9189 0.288 0.00036.50 3.8056 0.252 ---47.00 0.1477 0.238 -0.04

5950.00 33.91 209.50 0.1924 0.014 0.214

9620.00 --- 38.30 2.5050 ---498.12 50.30 225.58 0.9306 0.274

564.00 62.10 206.90 0.5818 0.274388.40 125.71233.85 45.30405.65 112.78574.00 175.18

70.38 0.2850 0.274118.75 0.5979 0.277 0.12672.47 0.2350 0.242 0.25274.64 0.4425 0.274 0.694

882.00 16.40 --- 3.920

306.45121.38267.77217.15294.0077.35198.95386.65304.85331.45184.67275.15302.22320.151156.001663.821769.151738.151982.721577.15

180.15440.65352.67431.35126.10309.35653.15491.32

64.8591.19112.78101.3333.9437.10146.92109.47

57.70 0139.30 071.24 082.49 090.10 0213.00 0158.00 0102.24

.5200 0.250 0.585

.4699 0.347 0.307

.6879 0.274 ---

.5577 0.233 0.849

.3109 0.292 0.040

.4883 0.307 0.223

.2028 0.427 0.3140.4309 0.274

309.57 72.45 97.37 0.4520 0.274 0.142425.00 69.90 195.00 0.3898 0.386 0.431431.15 101.33 82.49 1.1154 0.233 1.007515.51 64.33 182.56 0.5917 0.274 ---2573.00 354.64 116.00 0.1982 0.192 -0.104287.00 192.52 398.00 0.2585 0.215 -0.802900.003400.00 355.00 266.00 0.2197 0.334 0.1345530.00 531.96 185.00 0.2270 0.214 -1.11

1112,212,62,21

114,51333,62,2114,5,64,512122114,5,6123224,54,5

14.5

3,62,21

12,2111121,10

12,5113,21

1112,2121111,9,21

11112


353

NO FORMULA NAMEMWg/mol

PCbar

vccm /mo L 3g/cm3 SOURCE

197 NaOH SODIUM HYDROXIDE 39.997 596.00198 Na2S04 SODIUM SULFATE 142.043 1157.00199 Nb NIOBIUM 92.906 2750.15200 Nd NEODYMIUM 144.240 1289.15201 Ne NEON 20.180 24.55202 Ni NICKEL 58.693 1728.15203 NiC404 NICKEL CARBONYL 170.735 248.15204 NiF2 NICKEL FLUORIDE 96.690 1723.15205 Np NEPTUNIUM 237.000 913.15206 02 OXYGEN 31.999 54.3620703 OZONE 47.998 80.15208 Os OSMIUM 190.230 3306.15209 OsOFS OSMIUM OXIDE PENTAFLUORIDE 301.221 332.95210 Os04 OSMIUM TETROXIDE - YELLOW 254.228 329.15211 Os04 OSMIUM TETROXIDE - WHITE 254.228 315.15212 P PHOSPHORUS - WHITE 30.974 317.25213 PBr3 PHOSPHORUS TRI BROMIDE 270.686 233.15214 PC12F3 PHOSPHORUS DICHLORIDE TRIFLUORIDE 158.874 265.15215 PC13 PHOSPHORUS TRICHLORIDE 137.332 181.15216 PC15 PHOSPHORUS PENTACHLORIDE 208.237 433.15217 PH3 PHOSPHINE 33.998 139.37218 PH4Br PHOSPHONIUM BROMIDE 114.910219 PH4CL PHOSPHONIUM CHLORIDE 70.458 244.65220 PH4I PHOSPHONIUM IODIDE 161.910 291.65221 POCL3 PHOSPHORUS OXYCHLORIDE 153.331 274.33222 PSBr3 PHOSPHORUS THIOBROMIDE 302.752 311.15223 PSCL3 PHOSPHORUS THIOCHLORIDE 169.398 236.95224 P406 PHOSPHORUS TRIOXIDE 219.891 295.65225 P4010 PHOSPHORUS PENTOXIDE 283.889 693.15226 P4S10 PHOSPHORUS PENTASULFIDE 444.555 561.15227 Pb LEAD 207.200 600.61228 PbBr2 LEAD BROMIDE 367.008 646.15229 PbCl2 LEAD CHLORIDE 278.105 774.15230 PbF2 LEAD FLUORIDE 245.197 1128.15231 Pbl2 LEAD IODIDE 461.009 675.15232 PbO LEAD OXIDE 223.199 1163.15233 PbS LEAD SULFIDE 239.266 1387.15234 Pd PALLADIUM 106.420 1828.05235 Po POLONIUM 209.000 527.15236 Pt PLATINUM 195.080 2041.55237 Ra RADIUM 226.000 973.15238 Rb RUBIDIUM 85.468 312.46239 RbBr RUBIDIUM BROMIDE 165.372 955.15240 RbCl RUBIDIUM CHLORIDE 120.921 988.15241 RbF RUBIDIUM FLUORIDE 104.466 1033.15242 Rbl RUBIDIUM IODIDE 212.372 915.15243 Re RHENIUM 186.207 3459.15244 Re207 RHENIUM HEPTOXIDE 484.410 569.15245 Rh RHODIUM 102.906 2237.15246 Rn RADON 222.000 202.15247 Ru RUTHENIUM 101.070 2607.15248 RuF5 RUTHENIUM PENTAFLUORIDE 196.062 359.65249 S SULFUR 32.066 388.36250 SF4 SULFUR TETRAFLUORIDE 108.060 149.15251 SF6 SULFUR HEXAFLUORIDE 146.056 222.45252 SOBr2 THIONYL BROMIDE 207.873 220.95253 SOC12 THIONYL CHLORIDE 118.971 172.00254 SOF2 SULFUROUS OXYFLUORIDE 86.062 162.65255 S02 SULFUR DIOXIDE 64.065 200.00256 S02C12 SULFURYL CHLORIDE 134.970 222.00257 S03 SULFUR TRIOXIDE 80.064 289.95258 S2C12 SULFUR MONOCHLORIDE 135.037 193.15259 Sb ANTIMONY 121.757 903.78260 SbBr3 ANTIMONY TRIBROMIDE 361.469 369.75261 SbCl3 ANTIMONY TRICHLORIDE 228.115 346.55262 SbClS ANTIMONY PENTACHLORIDE 299.021 275.95263 SbH3 STIBINE 124.781 185.15264 Sbl3 ANTIMONY TRIIODIDE 502.470 440.15265 Sb203 ANTIMONY TRIOXIDE 291.512 929.15

1663.15 2820.00 253.31 200.00 0.2000 0.216

5115.003384.0027.09

2415.00315.652013.15

44.40 26.53 41.70 0.4839 0.300 -0.04

508.40 32.39 357.53 0.4775 0.274 ---

90.17161.854880.00373.65403.15403.15553.45448.45283.15349.25433.00185.41311.45246.15335.45378.65448.15398.15446.25

154.58 50.43 73.40 0.4360 0.288 0.022261.00 55.73 89.00 0.5393 0.229 0.227

993.75711.00457.02563.15646.15324.75501.76322.30539.70602.15

83.2953.9940.4856.70

300.00 0.9023 0.274 ---257.17 0.6178 0.274 ---260.00 0.5282 0.315 0.234

65.36 113.32 0.3000 0.274 0.03662.26 183.57 0.6260 0.274 ---49.14 149.42 0.4716 0.274 1.6477.61 158.40 1.0221 0.27451.66 265.54 0.5774 0.274 ---

638.82 48.57 299.58 0.5654 0.274714.86 52.08 312.69 0.7032 0.274

.15,15

787.152024.001187.151227.151566.151145.151745,1554,3385.001235.003980.001809.00978.001625.151654.151681.151577.155915.00635.553940.00211.354500.00600.15717.82233.15209.25412.65348.75228.90263.13342.55317.90411.151898.00548.15493.40413.15255.15674.151698.15

1291.00 232.005400.00 861.30

0.59493.20 2.2232 0.179 ---

6983.00 --- 759.10 0.2570 ---

2111.10 134.00 247.00 0.3460 0.189

32.10 5.8008

377.40 63.00 140.001.58570.281

1313.00364.00318.69661.75567.00371.25430.75545.00490.85659.375070.00

182.0852.2237.6064.8963.6359.2878.8446.1082.0762.75

158.00158.77198.52232.32203.00142.65122.00224.00127.08239.38

0.20290.68060.73570.89480.58610.60330.52510.60250.63000.5641

0.2640.2740.2820.2740.2740.2740.2690.2280.256

0.262

0.215

0.2450.1760.422

0.274

794.00 48.20662.54 39.42440.35 73.06

270.00 0.8449 0.197 0.171382.86 0.7810 0.274 ---157.20 0.7938 0.314

1,7

4,54,5

4,52,212,92,7

14,52,9

312,10,212,5,21

112,212,102,7,211,21

12,212,21114,5,6

233334,54,54,5,64,54,5,6

2224,5,6

4,52.64,52,9

2,7,10,21,152,211,212,21

112,214.5,6

12,8,217,21

3


354

NO FORMULA

267 Se268 SeC 14269 SeF6270 SeOCl2?71 <!(»np272 Si273 SiBrCl2F274 SiBrF3275 SiBr2ClF276 SiClF3277 SiCl2F2278 SICL3F279 SiCl4280 SiF4281 SiHBr3282 SiHCl3283 SiHF3284 SiH2Br2285 SiH2Cl2286 SiH2F2287 SiH2l2288 SiH3Br289 SiH3Cl290 SiH3F291 SiH3l292 SiH4PO7 c i np

294 Si2Cl6295 SJ2F6296 Si2H5Cl297 Si2H6298 Si20Cl3F3299 Si20Cl6300 Si20H6301 Si3Cl8302 Si3H8303 Si3H9N304 S14H10TAC Cm

306 Sn307 SnBr4308 SNCL2

309 SnCl4310 SnH4•zi i

zip Cr

314T-

•Z1C ff>

71 A To717 ToPlA

318 TeF6•zin T;

320 TiCl4Tpl Tl

•z.pp T 1 Dr•IpX T I |

•ZpA Tm

•zpc M

326 UF67P7 \l

328 VC14329 VOC13330 U331 UF6332 XeTITf VU

7T/ V*

NAME

crAUnTtlM

SELENIUMSELENIUM TETRACHLORIDESELENIUM HEXAFLUORIDESELENIUM OXYCHLORIDECPI CMIIIM ninvinc

SILICONBROMOO I CHLOROFLUOROS I LANETRIFLUOROBROMOSILANED I BROMOCHLOROFLUOROS I LANETRIFLUOROCHLOROSILANEDICHLOROOIFLUOROSILANETR I CHLOROFLUOROS I LANESILICON TETRACHLORIDESILICON TETRAFLUORIDETRIBROMOSILANETRICHLOROSILANETRIFLUOROSILANEDIBROMOSILANEDICHLOROSILANEDIFLUOROSILANEDIIODOSILANEMONOBROMOSILANEMONOCHLOROSILANEMONOFLUOROSILANE1 00 OS I LANESI LANE^TI irnu ninYinpHEXACHLOROOISILANEHEXAFLUOROOISILANEDISILANYL CHLORIDED I SI LANETRICHLOROTRIFLUORODISILOXANEHEXACHLORODISILOXANEDISILOXANEOCTACHLOROTRISILANETRISILANETRISILAZANETETRASILANE

TINSTANNIC BROMIDECTfluunnc ruinDTncSTANNIC CHLORIDESTANNIC HYDRIDEcTAkiutr irmtncCTDnUT HIM

TAUTAI 1 IM

TCI 1 IIDTIIU TCTDAPill HDTrtC

TELLURIUM HEXAFLUORIDETT TAUTI IU

TITANIUM TETRACHLORIDE

TUAI 1 Al 1C DDOMTPlC

URANIUM FLUORIDE

VANADIUM TETRACHLORIDEVANADIUM OXYTR I CHLORIDETUNGSTENTUNGSTEN FLUORIDEXENON

MWg/mol

LL OC.A

78.960220.771192.950165.865im oco

28.086197.893164.985242.345120.533136.988153.442169.896104.079268.805135.45286.089189.909101.00768.098283.910111.01366.56250.108158.01432.117An nRA

268.887170.16196.66362.219235.524284.88778.218367.87892.320107.335122.421icn ?An118.710438.3261RO 615

260.521122.742626 328

87 APnm7 Aio1Rn OAROR nnn1O7 AnnPAO A11

241.590If flan

189.691on/. IRIPRA PR7•ZTI poo

1Aft O7/"3iu noo

352.019Cn n/ •}

192.752173.299183.840297.830131.2901T7 ft/ ft

oo ort£.

TFK

1R1A 1«>

494.15

238.45281.65A1^ 1^

1685.00160.85202.65173.85131.15133.45152.35204.30186.35199.65144.95141.75202.95151.15

272.15179.25155.05

216.1588.15

i on? rift

271.95254.55

140.65

239.95128.95

155.95167.45179.55

It/ C 1C

505.08304.15mo o">242.95123.25/ 17 At

•incn i«;P7rr? 1 1;•ipon 1 1PA7fl 1l>

7OO A A

AO7 !•»

235.351O/ 1 11

249.05^77 1 177-7 1C71-7 ic

1 01 o 1C

1/ no 1C

342.35O1OT 1C

247.45193.653695.15272.65161.36

1ftO7 1C

1 7QO 1 C

TBK

P7nn nn930.00464.65227.35441.15con ic3513.80308.55231.45332.65203.15241.35285.35330.00178.35384.95305.00178.15343.65281.45195.35422.65275.55242.75175.15318.55161.00

pen* pn

412.15254.25314.70259.00315.89408.75257.75484.55326.25321.85373.151 07/ nn2995.00477.85ROA 1C

386.15220.85AO1 1C

1A7CI n.n

cczc nncnnn nnio0c nnAAC 1C

234.55•7//P ftft

409.001 7/ c nnmop m1 noA 1 cPP1O 1C/ me nn328.85TAAC nn425.00400.005645.00290.45165.03

1//C> f\n

7ncc nn

TcK

1766.00743.95368.80706.80

5159.00497.17375.28535.27330.54390.93460.49507.00259.00610.00479.00291.02550.00449.00318.21660.00454.00396.65286.28515.00269.70

660.96411.33506.89432.00508.78655.58416.86775.41525.15518.20599.30

7400.00764.82

619.85358.52

/. ft/ n nn

380.18AAnn nn638.00

505.80

697.00636.0014756.0468.56289.74

PCbar

380.0061.0544.7577.47

537.0038.2737.5439.3235.2535.9537.2435.9337.1947.0241.7039.9553.0044.3047.5966.8856.4448.4346.8869.4148.43

29.1130.1641.5851.3026.7727.9036.1924.7033.7031.6529.68

43.43

41.2453.42

34.47

46.61

46.60

60.3049.96

46.7558.40

vccm3/mol

62.30277.61187.74207.84

233.00295.93227.73310.14213.61247.69281.72326.00165.00350.00268.00165.93246.00228.00152.31232.00177.00174.00139.12160.00132.70

517.27310.64277.73198.00433.00535.21262.41714.99354.94372.91460.01

115.10401.12

342.37152.88

251.23

340.00

250.00

268.00290.0033.90228.32118.00

Pc 3g/cm

1.26740.79531.02780.7981

0.12050.66870.72450.78140.56430.55310.54470.52120.63080.76800.50540.51880.77200.44300.44711.22380.62720.38250.36020.98760.2420

0.51980.54780.34800.31420.54390.53230.29810.51450.26010.28780.2661

1.03141.0928

0.76090.8028

0.9616

0.5579

1.4081

0.71920.59765.42301.30441.1126

Zc

0.1610.2740.2740.274

0.2920.2740.2740.2740.2740.2740.2740.2780.2850.3240.2810.2740.2850.2710.2740.2830.2650.2560.2740.2590.287

0.2740.2740.2740.2830.2740.2740.2740.2740.2740.2740.274

0.274

0.2740.274

0.274

0.299

0.277

0.2790.274

0.2740.286

0)

...

0.2320.385

0.203

0.177

0.136

0.097

0.102

...

...

...

0.284

0.318

0.186

0.000

SOURCE

4 cf->4,5,62,212,212,21

1,173,212,212,212,212,212,2111,182,111,192,212,111,202,212,112,113,122,212,111,16

2,212,212,21

2,212,212,212,212,212,212,214 c,->4,5,62,2152,212,21

4 C,->

4 C,•>4 C,->4 C Aj-*,02

2,214 C £1^1°14 C

,->

4 c,J4 C,->2,10A C.*»•>11,214.5,62,21

4 c,->4 c

,->


355

NO

33577A•z-z-7

•7Tft

•Z7Q

•z/n•7/1

7/5

•Z/T

FORMULA

Zn7nf*l ">

7r>CO

~Jnf\7nCnA

7r>

7r»Di»/.

7rrl L

7rfL

NAME

ZINC7TUP PUinDTDC

7 1 UP ci i inDTitc

7 IMP ?lll FATP

7TDPOIJ II IM

7TDpnkJTIIM DDftUirtC

zIRCONIUM CHLORIDE

7TDrnuTiiu inninc

MU

g/

651XA1/vz

P.1

1A1O1

Ain57.7.CQQ

mo I

.3905OC•7077no/c/557

o/nfiTC

*»/ 5

TFK

692.70AT.P. m

1 1AC ic55/Q 5f>cm nn

5150 ic757. 1C71 n 1C.775 1C

TB

K

1181.innc.1770

AC. Oft

AinArtA7fj/

15ir

1r

ftrt

ir

1C

1C

Tc PCK bar

3170.00 2904.0

QPI15 nn

3VC PC 3cm /mo I g/cm Zc u

33.00 1.9815 0.364 0.078 1

... ... ...1

SOURCE

5 f. I6


NOTE:

1. Sources for the property data are:

1. Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS. Parts 1, 2, 3 and 4, Supplements1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).

2. Ohe, S., COMPUTER AIDED DATA BOOK OF VAPOR PRESSURE. Data Book Publishing Company, Tokyo, Japan (1976).3. PERRY'S CHEMICAL ENGINEERING HANDBOOK. 6th ed., McGraw-Hill, New York, NY (1984).4. Nesmeyanov, A. N., VAPOR PRESSURE OF THE CHEMICAL ELEMENTS. Elsevier, New York, NY (1963).5. CRC HANDBOOK OF CHEMISTRY AND PHYSICS. 66th - 75th eds., CRC Press, Inc., Boca Raton, FL (1985-1994).6. Simmrock, K. H., R. Janowsky and A. Ohnsorge, CRITICAL DATA OF PURE SUBSTANCES. Vol. II, Parts 1 and 2, Dechema

Chemistry Data Series, 6000 Frankfurt/Main, Germany (1986).7. CONDENSED CHEMICAL DICTIONARY. 10th (G. G. Hawley) and 11th eds. (N. I. Sax and R. J. Lewis, Jr.), Van Nostrand

Reinhold Co., New York, NY (1981,1987).9. LANCET HANDBOOK OF CHEMISTRY. 13th and 14th eds., McGraw-Hill, New York, NY (1985, 1992).10. Reid, R. C., J. M. Prausnitz and B. E. Poling, THE PROPERTIES OF GASES AND LIQUIDS. 3rd ed. (R. C. Reid and T. K.

Sherwood), 4th ed., McGraw-Hill, New York, NY (1977, 1987).11. Rabinovich, V. A., editor, THERMOPHYSICAL PROPERTIES OF GASES AND LIQUIDS, translated from Russian, U. S. Dept.

Commerce, Springfield, VA (1970).12.13.14.15.16.17.18.19.20.21.

Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,

C.C.C.C.C.C.C.C.C.

L.L.L.L.L.L.L.L.L.

andandandandandandandandand

others,others,others,others,others.others.others,others,others,

SolidSolidSolidSolidSolidSolidJ. Ch.J. Ch.

StateStateStateStateStateStateI. ChI. Ch

Technology, 1,6, No.Technology, 17. No.Technology, V7, No.Technology, 18, No.Technology, 21., No.Technology, 24, No.. 12., 12, 33 (1981).. E., 14, 205 (1983)

1,1,111,1,1,

.Ind. Eng. Chem. Process Des. Dev.,

3947, 31354387

23,

(1973).(1974).(1974).(1975).(1978).(1981).

48 (1984).Estimated.

2. Very limited experimental data for critical constants and acentric factor are available for inorganic compounds as comparedto the more abundant experimental data which are available for organic compounds. Thus, the estimates for these substances shouldbe considered rough approximations in the absence of experimental data.

356

Appendix E

HEAT CAPACITY FOR INORGANIC COMPOUNDS AND ELEMENTS**Carl L. Yaws, Mei Han and Sachin D. Sheth

Lamar University, Beaumont, Texas

NO

12345678910111213141516171819202122232425262728293031323334353637383940414243444546474849505152535455565758

FORMULA

AgAgClAglAlAIB3H12AlBr3ALC13ALF3ALI3AL203AILS3012ArAsAsBr3ASC13AsF3AsF5AsH3As13As203AtAuBBBr3BC13BF3BH2COBH303B2D6B2H5BrB2H6B3N3H6B4H10B5H9B5H11B10H14BaBeBeB2H8BeBr2BeCl 2BeF2BeI2BiBiBr3B1C13BrF5Br2CCC120CF20CH4N20CH4N2SCNBrCNCLCNFCOCOS

NAME

SILVERSILVER CHLORIDESILVER IODIDEALUMINUMALUMINUM BOROHYDRIDEALUMINUM BROMIDEALUMINUM CHLORIDEALUMINUM FLUORIDEALUMINUM IODIDEALUMINUM OXIDEALUMINUM SULFATEARGONARSENICARSENIC TRIBROMIDE*ARSENIC TRICHLORIDEARSENIC TRIFLUORIDEARSENIC PENTAFLUORIDE*ARSINEARSENIC TRI IODIDE*ARSENIC TRI OX IDEASTATINEGOLDBORONBORON TRIBROMIDEBORON TRICHLORIDEBORON TRIFLUORIDEBORINE CARBON YLBORIC ACIDDEUTERODIBORANE*DIBORANE HYDROBROMIDE*DIBORANEBORINE TRIAMINETETRABORANE*PENTABORANETETRAHYDROPENTABORANE*DECABORANEBARIUMBERYLLIUMBERYLLIUM BOROHYDRIDEBERYLLIUM BROMIDEBERYLLIUM CHLORIDEBERYLLIUM FLUORIDEBERYLLIUM IODIDEBISMUTHBISMUTH TRIBROMIDEBISMUTH TRICHLORIDEBROMINE PENTAFLUORIDEBROMINECARBONPHOSGENECARBONYL FLUORIDEUREATHIOUREACYANOGEN BROMIDECYANOGEN CHLORIDECYANOGEN FLUORIDECARBON MONOXIDECARBONYL SULFIDE

C

24-182414

3934370-41-362021686339743171352924-12382422-290213119-38-66-48

P = A +

A

.710

.821

.351

.490

—.535.535.104.626.081.900.786.882.784.784.648.312.578.126.020.288.282.195.762.444.487.568.800.184.932.984.941.873.121

-47.121

20—.4396.512

-4-2

-1131

22

662727-7202317213121262920

—.229.329.564.403.933

—.314.183.169.353.747.640.250.530.562.270.132.556.913

1415

224961095511292

-121111101116555

25

4

BT + CT2 + DT3 + E

B

.1400E-03

.5954E-01

.0083E-01

.1700E-02

—.0117E-01.0117E-01.3453E-01.4809E-02.5255E-01.4427E+00.OOOOE+00.2885E-03.9075E-02.9075E-02.2752E-01.2752E-01.2579E-04.4809E-02.0334E-01.0277E-10.7145E-03.1650E-01.4855E-01.9076E-01.1814E-01.7067E-01.OOOOE+00.7067E-01.7067E-01.7067E-01.0750E-01.6949E-01.6949E-01.6949E-01

—.6930E-02.4118E-02

—.7593E-014.2397E-01141

73461822717-69

.2467E+00

.5521E-01

.0125E-02

—.8865E-02.9339E-01.9172E-02.9494E-02.7972E-01.9853E-02.3180E-01.2204E-01.7072E-02.1915E-01.5002E-02.5807E-03.2794E-02

C

3.8800E-06-1.0527E-03-9.4018E-11-7.9280E-05

—-3.2271E-04-3.2271E-04-8.9929E-04-4.3607E-11-1.0383E-03-1.6840E-030. OOOOE+003.5916E-15-6.9453E-05-6.9453E-05-1.4842E-04-1.4842E-041.2295E-04-4.3607E-11-2.6126E-123.6271E-133.7682E-06-1.4732E-04-2.0938E-04-2.6142E-04-8.7099E-05-6.8997E-050. OOOOE+00-6.8997E-05-6.8997E-05-6.8997E-05-5.9547E-04-3.3162E-04-3.3162E-04-3.3162E-04

—-3.4202E-05-6.4462E-05

—-1.0617E-03-9.7917E-04-3.5145E-03-1.0232E-036.4912E-13

—-1.4984E-04-5.9604E-04-8.5027E-05-6.4040E-05-2.3242E-04-2.4575E-057.9000E-05-1.7193E-04-1.0251E-04-1.6822E-04-8.3145E-052.0130E-05-9.7014E-05

T4 <CP -

D

0. OOOOE+001.1270E-061.7495E-134.9600E-08

—2.2542E-072.2542E-079.6363E-077.6722E-147.5410E-077.0100E-070. OOOOE+00-3.5942E-183.5616E-083.5616E-087.6110E-087.6110E-08-1.3416E-077.6722E-144.3024E-15-5.5948E-16-2.6406E-098.5905E-081.3632E-071.6467E-072.2344E-081.2108E-080. OOOOE+001.2108E-081.2108E-081.2108E-083.0827E-075.6690E-085.6690E-085.6690E-08

—3.9641E-084.0254E-08

—1.1042E-061.0995E-064.7410E-061.0716E-06-1.0388E-15

—1.2946E-074.0800E-076.2796E-082.8510E-081.4224E-07-2.8140E-080. OOOOE+007.4203E-087.0456E-081.1457E-074.9592E-08-1.2227E-085.0943E-08

joule/g-mol K, T

E

0. OOOOE+00-4.6103E-10-1.2153E-160. OOOOE+00

—-5.7081E-11-5.7081E-11-3.9456E-10-5.0239E-17-2.0346E-100. OOOOE+000. OOOOE+001.2807E-21-6.6261E-12-6.6261E-12-1.4160E-11-1.4160E-114.1378E-11-5.0239E-17-2.6100E-183.1852E-196.8561E-13-1.8326E-11-3.3271E-11-3.8875E-111.2182E-13-7.6892E-130. OOOOE+00-7.6892E-13-7.6892E-13-7.6892E-13-6.4789E-117.8563E-127.8563E-127.8563E-12

—-1.7649E-11-9.2384E-12

—-4.3793E-10-4.7325E-10-2.4784E-09-4.2815E-106.1496E-19

—-4.2087E-11-1.0308E-10-1.6556E-11-4.9877E-12-3.3087E-111.4023E-110. OOOOE+00-1.3867E-11-1.8400E-11-2.9210E-11-1.1885E-112.2617E-12-1.0615E-11

TMIN

298298298298--1001002982982985510029829829829829880298273298298298298100100298293100100100298298298298--298298--298298298298298--2982981003011001008027329810029860100

- K)

TMAX PHASE

1234 solid728 solid420 solid933 solid-- gas

1500 gas1500 gas727 solid464 solid1273 solid900 solid1500 gas1090 solid2000 gas2000 gas2000 gas2000 gas1500 gas419 solid548 solid575 solid1336 solid1700 solid1500 gas1500 gas1500 gas1500 gas303 solid6000 gas6000 gas6000 gas1500 gas1500 gas1500 gas1500 gas

-- solid643 solid1556 solid

-- solid761 solid676 solid501 solid753 solid545 solid-- solid

1000 solid1500 gas1500 gas1700 solid1500 gas1500 gas400 solid1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas

** A computer program, containing data for all compounds, is available for a nominal fee (Carl L. Yaws, Box 10053, LamarUniversity, Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be accessed by other software.

357

= A + B T + C T2 + D T3 + E T4 (CP - joule/g-mol K, T - K>

NO

5960616263646566676869707172737475767778798081828384858687888990919293949596979899100101102103104105106107108109110111112113114115116117118119120121122123124125

FORMULA

COSeC02CS2CSeSC2N2C3S2CaCaF2CbF5CdCdCl2CdF2Cdl2CdOGIFCIF03CIF3CIF5CLH03SCLH04CL02CL2CL20CL207CoCoCl2CONC304CrCrC606Cr02CL2CsCsBrCsCLCsFCslCuCuBrCuClCuCL2CulDCN02d20EuF2F20FeFeC505Fed 2Fed 3FrGaGaCl3GdGeGeBr4GeCt4GeHCl3GeH4Ge2H6Ge3H8HBrHCNHClHFHIHN03

NAME

CARBON OXYSELENIDE*CARBON DIOXIDECARBON DISULFIDECARBON SELENOSULFIDE*CYANOGENCARBON SUBSULFIDECALCIUMCALCIUM FLUORIDECOLUMBIUM FLUORIDECADMIUMCADMIUM CHLORIDECADMIUM FLUORIDECADMIUM IODIDECADMIUM OXIDECHLORINE MONOFLUORIDEPERCHLORYL FLUORIDECHLORINE TRI FLUORIDECHLORINE PENTAFLUORIDECHLOROSULFONIC ACIDPERCHLORIC ACIDCHLORINE DIOXIDECHLORINECHLORINE MONOXIDECHLORINE HEPTOXIDE*COBALTCOBALT CHLORIDECOBALT NITROSYL TRICARBONYL*CHROMIUMCHROMIUM CARBONYLCHROMIUM OXYCHLORIDE*CESIUMCESIUM BROMIDECESIUM CHLORIDECESIUM FLUORIDECESIUM IODIDECOPPERCUPROUS BROMIDECUPROUS CHLORIDECUPRIC CHLORIDECOPPER IODIDEDEUTERIUM CYANIDE*DEUTERIUMDEUTERIUM OXIDEEUROPIUMFLUORINEFLUORINE OXIDEIRONIRON PENTACARBONYL*FERROUS CHLORIDEFERRIC CHLORIDEFRANCIUMGALLIUMGALLIUM TRICHLORIDEGADOLINIUMGERMANIUMGERMANIUM BROMIDEGERMANIUM CHLORIDETRICHORD GERMANE*GERMANEDIGERMANE*TRIGERMANE*HYDROGEN BROMIDEHYDROGEN CYANIDEHYDROGEN CHLORIDEHYDROGEN FLUORIDEHYDROGEN IODIDENITRIC ACID

A

21.91227.43720.46121.46132.265

—21.92453.980

—22.21766.944

——40.376

22.56713.20021.38615.53021.76573.22030.48227.21325.608110.48919.83260.29176.35219.044251.66761.37532.16348.53045.85746.68577.71722.63549.83138.27763.32050.62625.96731.15933.30824.30927.40816.65525.91386.03051.56462.34234.05127.824118.41038.58114.28987.75369.39724.939-15.22421.86763.47830.16925.76629.24429.08529.77019.755

B

9.2794E-024.2315E-021.2299E-011.2299E-011.1687E-01

—1.4644E-025.8600E-02

—1.2301E-023.2217E-02

——8.7027E-03

4.7581E-022.3797E-012.2286E-014.3077E-012.7543E-01O.OOOOE+003.9797E-023.0426E-021.1593E-013.9797E-021.6736E-026.1086E-028.9853E-021.5064E-021.1009E-058.9853E-02O.OOOOE+001.0837E-022.2096E-021.7744E-02-1.9833E-016.2760E-031.6610E-023.4969E-023.4880E-021.1966E-023.7969E-02-1.2796E-02-4.6722E-038.2843E-031.2928E-021.3539E-01-2.9321E-028.9853E-021.4293E-011.1506E-01-4.3909E-02-3.2136E-14O.OOOOE+00-5.0836E-034.8727E-027.3780E-021.3977E-012.5068E-013.0554E-013.0554E-013.0554E-01-8.0274E-033.7969E-02-1.2615E-039.6118E-04-7.4945E-031.3415E-01

-9-1-1-1-1

1-3

-8-1

-4-6-2-3-6-304-3-1431-2-2-5-20-7-1141-6

C

.7014E-05

.9555E-05

.6184E-04

.6184E-04

.4171E-04

—.1410E-14.8180E-05

—.8357E-13.2143E-14

——.5035E-16

.3572E-05

.5150E-04

.3105E-04

.4695E-04

.3639E-04

.OOOOE+00

.5262E-06

.3353E-05

.7038E-04

.5262E-06

.6244E-14

.8571E-16

.4575E-05

.4696E-06

.0497E-08

.4575E-05

.OOOOE+00

.4433E-15

.3165E-13

.8485E-15

.9279E-04

.5835E-16

.5590E-14O.OOOOE+00

-1-1-1233

.6050E-05

.2465E-14

.2416E-05

.4964E-05

.4878E-05

.9790E-157.0701E-06

-11

-2-21240-3-7-1-2-3-4-4-41

-11-42-6

.8807E-04

.1358E-04

.4575E-05

.6346E-04

.7739E-12

.8935E-04

.2017E-17

.OOOOE+00

.7104E-16

.5912E-05

.0615E-04

.0098E-04

.4090E-04

.0678E-04

.0678E-04

.0678E-04

.6731E-05

.2416E-05

.1210E-06

.4705E-06

.0687E-05

.1116E-05

D

5.0943E-083.9968E-091.0199E-071.0199E-079.2703E-08

—-1.4961E-171.5630E-08

—1.3385E-151.4595E-17

——4.2302E-19

3.9963E-081.2324E-072.2357E-074.4026E-072.0259E-07O.OOOOE+00-3.2447E-081.5961E-081.1417E-07-3.2447E-08-4.9839E-17-1.9975E-19-2.8140E-081.1830E-091.0276E-10-2.8140E-08O.OOOOE+008.4228E-181.7225E-16-2.0046E-18-4.6011E-07-1.3498E-199.4279E-17O.OOOOE+00O.OOOOE+001.4700E-17-3.2240E-09-1.5015E-08-2.2602E-08-3.9528E-18-1.6302E-081.2034E-07-9.5921E-08-2.8140E-082.3592E-07-2.7316E-15-7.9906E-07-2.1331E-20O.OOOOE+002.7645E-195.7125E-086.8167E-081.2907E-072.1707E-072.6063E-072.6063E-072.6063E-07-7.4730E-09-3.2240E-094.9676E-096.7830E-09-1.1963E-08-1.2343E-08

E

-1.0615E-11-2.9872E-13-2.4444E-11-2.4444E-11-2.3760E-11

—7.1522E-21O.OOOOE+00

—-7.4720E-19-6.3455E-21

——-1.4057E-22

-9.4968E-12-2.2897E-11-5.5964E-11-1.1080E-10-4.6684E-11O.OOOOE+001.3089E-11-2.7021E-12-2.8420E-111.3089E-112.5032E-207.7177E-231.4023E-11-2.0476E-13-7.8280E-141.4023E-11O.OOOOE+00-3.4349E-21-8.2107E-207.7924E-221.6255E-104.0395E-23-4.9688E-20O.OOOOE+00O.OOOOE+00-6.2634E-212.2610E-123.3248E-124.4864E-121.3976E-215.9789E-12-2.8760E-113.0427E-111.4023E-11-7.9693E-111.5522E-187.9673E-103.6846E-24O.OOOOE+00-7.1448E-23-1.6010E-11-1.6121E-11-3.0523E-11-5.2003E-11-6.1884E-11-6.1884E-11-6.1884E-118.3068E-132.2610E-12-2.4963E-12-2.1975E-122.1010E-121.1106E-11

TMIN

10050100100298--298298--298298----2982981002982983002985050298502982981002982931002982982982982982982982983002981001001002981002982981002982982983032982982982982981002002002002001005050100100

TMAX

15005000150015001500

--7371400

--594841----

12001500150015001500150030315001500150015007001013150021763631500300908743976894135765370390686115001500200011001500150010331500950577300252035116231213150015001500150015001500150015001500150015001500

PHASE

gasgasgasgasgasgassolidsolidsolidsolidsolidsolidsolidsolidgasgasgasgasgasgasgasgasgasgassolidsolidgassolidsolidgassolidsolidsolidsolidsolidsolidsolidsolidsolidsolidgasgasgassolidgasgassolidgassolidsolidsolidliquidsolidsolidsolidgasgasgasgasgasgasgasgasgasgasgasgas


358

= A + B T + C T2 + D T3 + E T4 <CP - joule/g-mol K, T - K)

NO

126127128129130131132133134135136137138139140141142143144145146147148149150151152153154155156157158159160161162163164165166167168169170171172173174175176177178179180181182183184185186187188189190191192

FORMULA

H2H20H202H2SH2S04H2S2H2SeH2TeH3N03SHeHeHfHgHgBr2HgCl2HgI2IF712InIrKKBrKClKFKIKOHKrLaLiLiBrLiClLiFLi ILuMgMgCL2MgOMnMnCl2MoMoF6Mo03NC13ND3NF3NH3NH30NH4BrNH4CLNH4INH50NH5SNONOClNOFN02N2N2F4N2H4N2H4CN2H6C02N20N203N204N205NaNaBr

NAME

HYDROGENWATERHYDROGEN PEROXIDEHYDROGEN SULFIDESULFURIC ACIDHYDROGEN DISULFIDE*HYDROGEN SELENIDE*HYDROGEN TELLURIDE*SULFAMIC ACIDHELIUM-3HELIUM-4HAFNIUMMERCURYMERCURIC BROMIDEMERCURIC CHLORIDEMERCURIC IODIDEIODINE HEPTAFLUORIDEIODINEINDIUMIRIDIUMPOTASSIUMPOTASSIUM BROMIDEPOTASSIUM CHLORIDEPOTASSIUM FLUORIDEPOTASSIUM IODIDEPOTASSIUM HYDROXIDEKRYPTONLANTHANUMLITHIUMLITHIUM BROMIDELITHIUM CHLORIDELITHIUM FLUORIDELITHIUM IODIDELUTECIUMMAGNESIUMMAGNESIUM CHLORIDEMAGNESIUM OXIDEMANGANESEMANGANESE CHLORIDEMOLYBDENUMMOLYBDENUM FLUORIDEMOLYBDENUM OXIDENITROGEN TRICHLORIDEHEAVY AMMONIA*NITROGEN TRI FLUORIDEAMMONIAHYDROXYLAMINEAMMONIUM BROMIDEAMMONIUM CHLORIDEAMMONIUM IODIDEAMMONIUM HYDROXIDEAMMONIUM HYDROGENSULFIDENITRIC OXIDENITROSYL CHLORIDENITROSYL FLUORIDE*NITROGEN DIOXIDENITROGENTETRAFLUOROHYDRAZINEHYDRAZINEAMMONIUM CYANIDE*AMMONIUM CARBAMATENITROUS OXIDENITROGEN TRIOXIDENITROGEN TETRAOXIDENITROGEN PENTOXIDESODIUMSODIUM BROMIDE

2533363395834341292020253166525638342123734394566-42025-868411641251931-815422141303034

A

.399

.933

.181

.878

.486

.617

.878

.878

.000

.786

.786

.703

.106

.584

.426

.286

.537

.150

.506

.347

.837

.390

.680

.982

.603

.100

.786

.815

.997

.390

.417

.725

.903

.104

.801

.946

.000

.292

.233

.715

.680

.322

.253

.57418.7323321953460

3328273229122352

232829631441

.573

.935

.159

.757

.291

...

—.227.551.551.791.414.422.630.812

—.219.509.587.710.791.654

B

2.0178E-02-8.4186E-038.2657E-03-1.1216E-023.3795E-01-1.1216E-02-1.1216E-02-1.1216E-02O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+00-1.4350E-022.9288E-021.3494E-013.4249E-015.0269E-011.3931E-021.7573E-025.7739E-037.1983E-021.1766E-015.8380E-021.4422E-02-1.0541E-014.6870E-01O.OOOOE+006.6944E-033.3378E-01-1.5919E-012.3397E-021.3208E-012.8091E-026.2760E-032.2569E-022.2965E-012.4690E-015.4688E-021.7706E-016.9371E-034.1131E-012.3631E-011.7432E-01-1.2581E-021.5505E-01-1.2581E-021.0340E-01-2.5788E-031.1150E-017.1764E-02

...

—-2.3626E-027.5899E-027.5899E-02-7.4294E-04-4.5993E-033.0609E-019.1270E-029.1270E-02

—6.1984E-021.6895E-012.2719E-011.2317E-014.4228E-024.4400E-02

C

-3.8549E-052.9906E-056.6420E-055.2578E-05-3.8078E-045.2578E-055.2578E-055.2578E-05O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+001.2908E-056.0558E-12-3.1212E-04-8.7036E-04-7.1344E-04-2.0953E-05-2.4686E-11-3.4328E-17

—-2.9798E-04-8.1210E-053.8443E-152.6297E-04-1.0706E-03O.OOOOE+00-2.6336E-16-1.3341E-034.3042E-04-1.3477E-14-2.0239E-046.6308E-14-6.3338E-17-2.4620E-05-4.2858E-04-3.7660E-04-7.7529E-05-3.2746E-046.4610E-17-6.0261E-04-3.7096E-04-2.1734E-048.8906E-05-1.4305E-048.8906E-05-5.8693E-051.3674E-05O.OOOOE+00-7.8705E-14

...

—5.3156E-05-9.4410E-05-9.4410E-058.1722E-051.3004E-05-3.1077E-042.9042E-052.9042E-05

—-3.7989E-05-1.8161E-04-2.2740E-04-5.9937E-054.6243E-09-4.6524E-05

D

3.1880E-08-1.7825E-08-6.9944E-08-3.8397E-082.1308E-07-3.8397E-08-3.8397E-08-3.8397E-08O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+00-1.0022E-143.9829E-071.0951E-064.5817E-071.4362E-084.5400E-142.3440E-20

—2.6546E-075.0100E-08-3.7237E-18-2.3479E-079.4200E-07O.OOOOE+002.4699E-192.4813E-06-4.2500E-071.5769E-171.6126E-07-8.7334E-174.0169E-202.2489E-083.7372E-071.9830E-076.7461E-082.9913E-07-2.9498E-204.0311E-073.0598E-071.1642E-07-7.1783E-085.3741E-08-7.1783E-081.0557E-08-3.2219E-08O.OOOOE+009.6400E-17

...

—-3.7858E-086.0476E-086.0476E-08-8.2872E-08-5.4759E-091.3914E-07-7.1858E-08-7.1858E-08

—6.9671E-099.9662E-081.0698E-071.1842E-08-9.2264E-122.1650E-08

E

-8.7585E-123.6934E-122.0951E-119.0281E-12-4.6878E-119.0281E-129.0281E-129.0281E-12O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+00O.OOOOE+006.1505E-18-1.9638E-10-5.3193E-10-1.0835E-10-3.5950E-12-3.1151E-17-5.5160E-24

—-8.5845E-11O.OOOOE+001.2824E-217.9064E-11O.OOOOE+00O.OOOOE+00-8.2601E-23-1.6521E-091.5943E-10-6.6511E-21-4.8053E-114.1888E-20-8.7163E-24-7.7607E-12-1.2269E-10O.OOOOE+00-2.2097E-11-1.0323E-104.5417E-24-1.0025E-10-9.4632E-11-2.2436E-111.8569E-11-5.8443E-121.8569E-111.5150E-122.8462E-11O.OOOOE+00-4.2746E-20

...

—9.1197E-12-1.5054E-11-1.5054E-112.4424E-112.9239E-13-2.2235E-112.5093E-112.5093E-11

—8.1421E-13-2.1975E-11-1.9223E-11-8.1522E-136.8903E-15O.OOOOE+00

THIN

25010010010010010010010029310010029823429829829829810029829829829820029829850100298100298298298298298298298200298298298298298100100100100200273458298----501001005050100100100--10010050200298200

TMAX

1500150015001500150015001500150030315001500308630514550563150015004291809336100710001130954522620011414548238831121742200092398780099092328901500106820001500150015001500293700824----

15001500150015001500150015001500

--15001500150060003711000

PHASE

gasgasgasgasgasgasgasgassolidgasgassolidliquidsolidsolidsolidgasgassolidsolidsolidsolidsolidsolidsolidsolidgassolidsolidsolidsolidsolidsolidsolidsolidsolidsolidsolidsolidsolidgassolidgasgasgasgasgassolidsolidsolidliquidsolidgasgasgasgasgasgasgasgassolidgasgasgasgassolidsolid


359

<CP - joule/g-mol K, T - K)

NO

193194195196197198199200201202203204205206207208209210211212213214215216217218219220221222223224225226227228229230231232233234235236237238239240241242243244245246247248249250251252253254255256257258259

FORMULA

NaCNNaClNaFNalNaOHNa2S04NbNdNeNiN1C404NiF2Np0203OsOsOFSOs04Os04PPBr3PC12F3PC13PC15PH3PH4BrPH4CIPH4IPOC13PSBr3PSC13P406P4010P4S10PbPbBr2PbCl2PbF2Pbl2PbOPbSPdPoPtRaRbRbBrRbClRbFRblReRe207RhRnRuRuF5SSF4SF6SOBr2SOC12SOF2S02S02C12S03S2C12Sb

NAME

SODIUM CYANIDESODIUM CHLORIDESODIUM FLUORIDESODIUM IODIDESODIUM HYDROXIDESODIUM SULFATENIOBIUMNEODYMIUMNEONNICKELNICKEL CARBONYL*NICKEL FLUORIDENEPTUNIUMOXYGENOZONEOSMIUMOSMIUM OXIDE PENTAFLUORIDEOSMIUM TETROXIDE - YELLOWOSMIUM TETROXIDE - WHITEPHOSPHORUS - WHITEPHOSPHORUS TR I BROMIDEPHOSPHORUS DICHLORIDE TRI FLUORIDE*PHOSPHORUS TRICHLORIDEPHOSPHORUS PENTACHLORIDEPHOSPHINEPHOSPHONIUM BROMIDE*PHOSPHONIUM CHLORIDE*PHOSPHONIUM IODIDE*PHOSPHORUS OXYCHLORIDEPHOSPHORUS THIOBROMIDEPHOSPHORUS THIOCHLORIDEPHOSPHORUS TRI OX IDEPHOSPHORUS PENTOXIDEPHOSPHORUS PENTASULFIDELEADLEAD BROMIDELEAD CHLORIDELEAD FLUORIDELEAD IODIDELEAD OXIDELEAD SULFIDEPALLADIUMPOLONIUMPLATINUMRADIUMRUBIDIUMRUBIDIUM BROMIDERUBIDIUM CHLORIDERUBIDIUM FLUORIDERUBIDIUM IODIDERHENIUMRHENIUM HEPTOXIDERHODIUMRADONRUTHENIUMRUTHENIUM PENTAFLUORIDESULFURSULFUR TETRAFLUORIDESULFUR HEXAFLUORIDETHIONYL BROMIDETHIONYL CHLORIDESULFUROUS OXYFLUORIDESULFUR DIOXIDESULFURYL CHLORIDESULFUR TRIOXIDESULFUR MONOCHLORIDEANTIMONY

A

68.39936.71018.36048.877-31.800-8.04023.72336.37220.786-13.15769.83072.258

—29.52631.46723.556

—24.58524.5854.40056.75820.69627.21325.70132.96462.03461.94262.03723.91163.32227.454-26.2489.600

-25.52523.55277.78160.76054.94075.31241.45546.43424.22520.29224.25020.92013.73648.53448.11659.62348.53424.695113.26621.96620.79421.966

—25.63915.486-7.93448.49134.83818.63929.63718.55322.46651.24022.343

7611894-60281

-813

2211424-1-1-1-131385299

B

.7953E-04

.2770E-02

.6682E-01

.2054E-02

.4550E-01

.3400E-01

.0166E-03

.8306E-02

.OOOOE+00

.7626E-01

.9853E-02

.0293E-02

—.8999E-03.4982E-02.8493E-03

—.4934E-01.4934E-01.2200E-01.0427E-01.7099E-01.4066E-01.7099E-01.4201E-02.4201E-02.4201E-02.4201E-02.2446E-01.6822E-01.3554E-01.7464E-01.9230E-01.3950E+00.7404E-03.2048E-03

4.1535E-0261115252511-81261

-36

-73511132118

.4425E-02

.9665E-02

.5330E-02

.0263E-02

.7488E-03

.0418E-02

.3764E-03

.0920E-02

. 6681 E- 02

.0669E-02

.0418E-02

.2079E-02

.1004E-02

.7522E-03

.8782E-01

.0042E-02

.9576E-15-2760E-03

—.9870E-03.1315E-01.1224E-01.0815E-01.4750E-01.9505E-01.4735E-02.9713E-01.1981E-01.1549E-01.9538E-03

C

0. OOOOE+00-6.6670E-05-3.1756E-04-3.1542E-15-3.0665E-03-2.2370E-03-2.2179E-171.6672E-040. OOOOE+00-7.0013E-04-2.4575E-055.2390E-17

—3.8083E-056.7966E-054.0482E-17

—-3.3236E-04-3.3236E-04-2.5300E-04-1.6430E-04-7.8406E-04-3.9532E-04-7.8406E-041.3216E-041.3216E-041.3216E-041.3216E-04-5.0571E-04-2.5688E-04-5.4132E-04-1.2429E-031.3880E-03-6.9192E-03-2.9945E-142.1995E-131.4883E-14-9.8385E-13-3.7105E-136.9602E-14-3.9829E-16-7.4914E-172.7009E-12-9.8794E-17-3.7799E-153.5243E-06-5.0051E-15-4.8316E-152.2230E-04-8.4558E-162.2393E-06-3.3492E-032.6411E-174.4438E-185.4587E-16

—4.7860E-06-4.4453E-04-6.4878E-04-1.4791E-04-1.7837E-04-2.5689E-049.2903E-06-4.2391E-04-9.0842E-05-1.6270E-04-8.4656E-15

D

0. OOOOE+002.8000E-082.7570E-073.5205E-185.0706E-062.1350E-061.0763E-20-1.3166E-070. OOOOE+008.2194E-07-2.8140E-08-2.7624E-20

—-3.2629E-08-8.4157E-08-2.6647E-20

—2.1344E-072.1344E-072.2765E-071.1542E-075.6105E-072.8032E-075.6105E-07-1.1915E-07-1.1915E-07-1.1915E-07-1.1915E-073.4836E-071.7681E-073.7986E-078.1470E-07-3.6600E-069.9713E-064.4267E-17-3.1856E-16-1.9009E-171.4615E-155.1367E-16-8.9876E-173.2805E-195.1613E-20-4.4052E-156.0617E-204.0654E-18-7.7226E-095.6215E-185.2698E-18-1.8584E-071.0369E-18-7.2768E-107.2466E-06-1.5094E-20-1.9112E-21-4.7849E-19

—-9.5700E-102.9083E-073.7509E-079.4987E-089.4399E-081.5983E-07-2.9885E-082.7784E-072.5503E-081.0449E-079.6707E-18

00-8-1-20

-130-314

826

-5-5-7-2-1-7-13333-8-4-9-10-5-218-7-24-9-12

-1-16-2-25-48-5221

0-7-8-2-1

E

.OOOOE+00

.OOOOE+00

.3700E-11

.4126E-21

.9200E-09

.OOOOE+00

.7590E-24

.8858E-11

.OOOOE+00

.7096E-10

.4023E-11

.9116E-24

—.8607E-12.7205E-11.0441E-24

—.0476E-11.0476E-11.1400E-11.9670E-11.4442E-10.1695E-11.4442E-10.2843E-11.2843E-11.2843E-11.2843E-11.7607E-11.4843E-11.6538E-11.9988E-10.OOOOE+00.3678E-09.4109E-20.6938E-19.8300E-21.9884E-19.6034E-19.2208E-20.5043E-23.2204E-23.6616E-18.2748E-23.5696E-21.3452E-12.2585E-21.0526E-21.8308E-11.5189E-22.3708E-14.8789E-09.9416E-24.7806E-25.4756E-22

—.OOOOE+00.1213E-11.1524E-11.2463E-11.8111E-11

-3.7838E-111-6.0937E-11.7857E-11

-7.9208E-13-2-3.4709E-11.9802E-21

TMIN

2982002002986059298298100298100298--5050298--29829831298100100100100100100100402981002982030298298298298298298298298298298298298283283298283298298298298298--273298100298100298100100100298298

TMAX PHASE

835 solid1074 solid1200 solid933 solid592 solid458 solid2740 solid1135 solid1500 gas630 solid1500 gas1723 solid

-- solid1500 gas1500 gas1877 solid

-- gas1500 gas1500 gas317 solid1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas1500 gas325 solid560 solid601 solid640 solid768 solid613 solid680 solid762 solid1387 solid1823 solid527 solid2043 solid973 solid312 solid953 solid988 solid1048 solid913 solid3453 solid318 solid2239 solid3000 gas1308 solid

-- solid1500 gas1500 gas1500 gas1500 gas2000 gas1500 gas1500 gas1500 gas1500 gas1500 gas903 solid


360

= A + B T + C T2 + D T3 + E T4 (CP - joule/g-mol K, T - K)

NO

260261262263264265266267268269270271272273274275276277278279280281282283284285286287288289290291292293294295296297298299300301302303304305306307308309310311312313314315316317318319320321322323324325326

FORMULA

SbBr3SbCl3SbClSSbH3Sbl3Sb203ScSeSeCl4SeF6SeOCl2Se02SiSiBrCl2FSiBrF3SiBr2ClFSiClF3SiCl2F2SiCl3FSiCUSiF4SiHBr3SiHCl3SiHF3SiH2Br2SiH2Cl2SiH2F2SiH2l2SiH3BrSiH3ClSiH3FS1H3ISiH4Si 02Si2Cl6Si2F6Si2H5ClSi2H6Si20Cl3F3Si20Cl6Si20H6Si3Cl8Si3H8Si3H9NSi4H10SmSnSnBr4SnCl2SnCl4SnH4SnI4SrSrOTaTcTeTeCl4TeF6TiTiCl4TlTlBrTUTmUUF6

NAME

ANTIMONY TR I BROMIDEANTIMONY TRICHLORIDEANTIMONY PENTACHLORIDE*STIBINEANTIMONY TRI IODIDEANTIMONY TRIOXIDESCANDIUMSELENIUMSELENIUM TETRACHLORIDE*SELENIUM HEXAFLUORIDE*SELENIUM OXYCHLORIDE*SELENIUM DIOXIDESILICONBROMOD I CHLOROFLUOROS I LANE*TR I FLUOROBROMOS I LANE*D I BROMOCHLOROFLUOROS I LANE*TR I FLUOROCHLOROS I LANEDICHLORODIFLUOROSILANE*TRI CHLOROFLUOROS I LANESILICON TETRACHLORIDESILICON TETRAFLUORIDETRIBROMOSILANETRICHLOROSILANETRIFLUOROSILANEDIBROMOSILANEDICHLOROSILANEDIFLUOROSILANEDIIODOSILANEMONOBROMOSILANEMONOCHLOROSILANEMONOFLUOROSILANEIODOSILANESI LANESILICON DIOXIDEHEXACHLORODISILANE*HEXAFLUORODISILANE*DISILANYL CHLORIDE*D I SI LANETRICHLOROTRIFLUORODISILOXANE*HEXACHLORODISILOXANE*DISILOXANE*OCTACHLOROTRISILANE*TRISILANE*TRISILAZANE*TETRASILANE*SAMARIUMTINSTANNIC BROMIDE*STANNOUS CHLORIDESTANNIC CHLORIDE*STANNIC HYDRIDE*STANNIC IODIDESTRONTIUMSTRONTIUM OXIDETANTALUMTECNNETIUMTELLURIUMTELLURIUM TETRACHLORIDETELLURIUM HEXAFLUORIDE*TITANIUMTITANIUM TETRACHLORIDETHALLIUMTHALLOUS BROMIDETHALLOUS IODIDETHULIUMURANIUMURANIUM FLUORIDE*

A

71.96563.682106.95313.05871.12879.91423.76515.98735.672-6.93435.838

—10.43546.87626.67357.82626.81640.89649.69831 .67218.03229.30224.93913.82025.76021.5836.36727.01010.7457.8303.6109.48528.887-7.170103.55976.97548.88127.353101.56696.36537.295141.06547.29581.08593.01513.22421.58946.41567.78138.67237.10281.17022.21718.33425.02021.75719.163138.909-5.93322.15867.91443.70441.63148.36725.10438.834-4.133

B

1.2259E-017.1912E-027.1912E-021.2924E-018.8701E-027.1546E-024.5187E-033.0200E-023.1545E-015.1224E-011.4750E-01

—4.6948E-022.1385E-012.6781E-012.1385E-012.6781E-012.1385E-012.1385E-013.1545E-012.7359E-012.5068E-012.5068E-012.3386E-011.7618E-011.7618E-011.9374E-011.7618E-011.9428E-011.9428E-011.9169E-011.9428E-011.7546E-022.5900E-013.1545E-012.7359E-011.9428E-011.9208E-012.1385E-013.1545E-011.9208E-013.1545E-011.9208E-011.9208E-011.9208E-017.5137E-021.8159E-023.1545E-013.8744E-023.1545E-011.7546E-021.5062E-011.3891E-021.4155E-012.4853E-038.3680E-032.1966E-02-7.9020E-095.1224E-011.0284E-026.6801E-02-1.6590E-012.9706E-021.3891E-026.2760E-03-9.8635E-025.1224E-01

C

1.6687E-09-1.0441E-04-1.0441E-04-1.3034E-04-1.4010E-10-1.8105E-144.9739E-17-1.7122E-11-5.0601E-04-6.4878E-04-1.7837E-04

—-5.7687E-05-3.2354E-04-3.7339E-04-3.2354E-04-3.7339E-04-3.2354E-04-3.2354E-04-5.0601E-04-3.5566E-04-3.4090E-04-3.4090E-04-2.7143E-04-1.6179E-04-1.6179E-04-1.6805E-04-1.6179E-04-1.9487E-04-1.9487E-04-1.7363E-04-1.9487E-041.4919E-04-3.3460E-04-5.0601E-04-3.5566E-04-1.9487E-04-5.8767E-05-3.2354E-04-5.0601E-04-5.8767E-05-5.0601E-04-5.8767E-05-5.8767E-05-5.8767E-05-8.6053E-05-3.1578E-12-5.0601E-044.4328E-13-5.0601E-041.4919E-04-2.7687E-132.4603E-16-2.2247E-041.7796E-174.2956E-182.1203E-143.0372E-11-6.4878E-042.1941E-15-3.5178E-055.4479E-044.6309E-145.1273E-111.4555E-162.6870E-04-6.4878E-04

-366622-33339

D

.4808E-12

.7050E-08

.7050E-08

.6840E-08

.5303E-13

.1989E-17

.5288E-20

.2998E-14

.5370E-07

.7509E-07

.4399E-08

—3.3872E-08222222

.2226E-07

.4125E-07

.2226E-07

.4125E-07

.2226E-07

.2226E-073.5370E-07222177771181

-11321-323-33-3-3-3653-73-12-31-7-2-2

.1540E-07

.1707E-07

.1707E-07

.5566E-07

.0860E-08

.0860E-08

.1483E-08

.0860E-08

.0614E-07

.0614E-07

.3890E-08

.0614E-07

.5680E-07

.6970E-07

.5370E-07

.1540E-07

.0614E-07

.4180E-08

.2226E-07

.5370E-07

.4180E-08

.5370E-07

.4180E-08

.4180E-08

.4180E-08

.5667E-08

.2788E-15

.5370E-07

.1475E-16

.5370E-07

.5680E-07

.4060E-16

.2509E-19

.6187E-07

.2588E-21

.0384E-21

.9036E-17-5.1354E-143-27-7-6-9-9-23

.7509E-07

.1123E-18

.2884E-09

.2978E-07

.1964E-17

.3369E-14

.3336E-20

.4221E-07

.7509E-07

E

2.7134E-15-1.5856E-11-1.5856E-11-1.2435E-11-1.7032E-16-9.6188E-218.7092E-24-2.3673E-17-8.9635E-11-8.1524E-11-1.8111E-11

—-7.2792E-12-5.6419E-11-5.8565E-11-5.6419E-11-5.8565E-11-5.6419E-11-5.6419E-11-8.9635E-11-4.9404E-11-5.2003E-11-5.2003E-11-3.4933E-11-1.1902E-11-1.1902E-11-1.1961E-11-1.1902E-11-2.3863E-11-2.3863E-11-1.6955E-11-2.3863E-114.6291E-11O.OOOOE+00-8.9635E-11-4.9404E-11-2.3863E-111.8348E-11-5.6419E-11-8.9635E-111.8348E-11-8.9635E-111.8348E-111.8348E-111.8348E-11-1.8682E-11-3.2746E-18-8.9635E-114.2727E-19-8.9635E-114.6291E-112.3117E-201.5174E-22-4.3754E-119.9371E-253.3152E-251.4440E-203.2239E-17-8.1524E-117.2113E-22-5.1766E-133.7871E-103.0195E-206.3394E-172.0665E-238.2396E-11-8.1524E-11

TMIN

273298298298298273298273100100100--298298298298298298298100100100100298100100298100298298298298100100100100298100298100100100100100100298298100298100100298298298298298273298100298100298298298298298100

TMAX

3681500150020004448461673423150015002000

--16851500150015001500150015001500150015001500150015001500150015001500150015001500150084815001500150015001500150015001500150015001500119050515005201500150041886212703269247372349715001155600050773343819009411500

PHASE

solidgasgasgassolidsolidsolidsolidgasgasgassolidsolidgasgasgasgasgasgasgasgasgasgasgasgasgasgasgasgasgasgasgasgassolidgasgasgasgasgasgasgasgasgasgasgassolidsolidgassolidgasgassolidsolidsolidsolidsolidsolidsolidgassolidgassolidsolidsolidsolidsolidgas

** A computer program, containing data for all compounds, Is available for a nominal fee (Carl L. Yaws, Box 10053, LamarUniversity, Beaumont, TX 77710, phone/FAX 409-880-8787). The computer program is in ASCII which can be accessed by other software.

361

<CP - joule/g-mol K, T - K)

NO FORMULA NAME TMIN TMAX PHASE

327328329330331332333334335336337338339340341342343

VVC14VOC13WWF6XeYbYtZnZnCl2ZnF2ZnOZnS04ZrZrBr4ZrCUZrl4

VANADIUMVANADIUM TETRACHLORIDEVANADIUM OXYTRICHLORIDETUNGSTENTUNGSTEN FLUORIDEXENONYTTERBIUMYTTRIUMZINCZINC CHLORIDEZINC FLUORIDEZINC OXIDEZINC SULFATEZIRCONIUMZIRCONIUM BROMIDEZIRCONIUM CHLORIDEZIRCONIUM IODIDE

223529223520

.898

.481

.050

.912

.463

.78622.63523226062-57121704492

.932

.384

.668

.300

.070

.427

.974

.795

.472

.902

33344084121281352

.6997E-03

.4358E-01

.2969E-01

.6861E-03

.3695E-01

.OOOOE+00

. 2843 E- 03

.1840E-03

.0042E-02

.3012E-02

.1360E-02

.8610E-01

.7015E-02

.1632E-02

.5625E-01

.0671E-01

.0270E-01

7.8595E-06-6.0413E-04-5.2847E-041.4921E-17-6.4406E-040. OOOOE+006.3018E-16-9.4660E-17-5.3572E-147.6380E-13-5.2291E-15-5.7750E-040. OOOOE+00-2.1446E-15-8.1803E-04-1.1887E-03-4.6822E-04

-3.7455E-094.4984E-073.6323E-07-7.3117E-214.3271E-070. OOOOE+00-6.4801E-196.6643E-207.3244E-17-1.1605E-155.0388E-184.3300E-070. OOOOE+002.0750E-188.8208E-071.2934E-065.1226E-07

6.4469E-13-1.1924E-10-8.9429E-111.2276E-24-1.0794E-100. OOOOE+002.3706E-22-1.6156E-23-3.6627E-206.4990E-19-1.7239E-210. OOOOE+000. OOOOE+00-7.1349E-22-3.6360E-10-5.3834E-10-2.1446E-10

29850502982985029829829829829840300298298298298

2190 solid1500 gas1600 gas2500 solid1500 gas1500 gas1071 solid1773 solid693 solid591 solid1145 solid473 solid953 solid1135 solid720 solid710 solid704 solid


NOTE:

1. Sources for the property data are:

1. Daubert, T. E. and R. P. Danner, DATA COMPILATION OF PROPERTIES OF PURE COMPOUNDS. Parts 1, 2, 3 and 4, Supplements1 and 2, DIPPR Project, AIChE, New York, NY (1985-1992).

2. Stull, D. R. and H. Prophet, JANAF THERMOCHEMICAL TABLES. 2nd edition, NSRDS-NBS 37, US Government Printing Office,Washington, DC (June, 1971).

3. Wagman, D. D. and others, NBS TABLES OF CHEMICAL THERMODYNAMIC PROPERTIES. J. Phys. Chem. Ref. Data, H, SupplementNo. 2 (1982).

4. Chase, M. W. and others, JANAF THERMOCHEMICAL TABLES. 3rd edition, Parts 1 (Al-Co) and 2 (Cr-Zr), J. Phys. Chem. Ref.Data, U, Supplement No. 1 (1985).

5. Kelley, K. K., CONTRIBUTIONS TO THE DATA ON THEORETICAL METALLURGY. Bureau of Mines Bulletin 584, US GovernmentPrinting Office, Washington, DC (1960).

6. Wicks, C. E. and F. E. Block, THERMODYNAMIC PROPERTIES OF 65 ELEMENTS - THEIR OXIDES. HAL1DES. CARBIDES. AND NITRIDES.Bureau of Mines Bulletin 605, US Government Printing Office, Washington, DC (1963).

7. Barin, I. and 0. Knacke, THERMOCHEMICAL PROPERTIES OF INORGANIC SUBSTANCES. Springer-Verlag, New York, NY (1973).8. PERRY'S CHEMICAL ENGINEERING HANDBOOK. 6th ed., McGraw-Hill, New York, NY (1984).9. CRC HANDBOOK OF CHEMISTRY AND PHYSICS. 66th - 75th eds., CRC Press, Inc., Boca Raton, FL (1985-1994).

CONDENSED CHEMICAL DICTIONARY. 10th (G. G. Hawley) and 11th eds. (N. I. Sax and R. J. Lewis, Jr.), Van NostrandReinhold Co., New York, NY (1981,1987).LANGE'S HANDBOOK OF CHEMISTRY. 13th and 14th eds., McGraw-Hill, New York, NY (1985, 1992).Reid, R. C., J. M. Prausnitz and B. E. Poling, THE PROPERTIES OF GASES AND LIQUIDS. 3rd ed. (R. C.Sherwood), 4th ed., McGraw-Hill, New York, NY (1977, 1987).Rabinovich, V. A., editor, THERMOPHYSICAL PROPERTIES OF GASES AND LIQUIDS, translated from Russian, U. S. Dept.Commerce, Springfield, VA (1970).

Reid and T. K.

14.15.16.17.18.19.20.21.22.23.24.25.

Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,Yaws,

C.C.C.C.C.C.C.C.C.C.C.C.

LLLLLLLLLLLL

and others, Solid State Technology, 16. No.and others, Solid State Technology, 17. No.and others, Solid State Technology, 17. No.

1, 39 (1973).I, 47 (1974).II, 31 (1974).1, 35 (1975).1, 43 (1978).

87 (1981).

and others, Solid State Technology, 18. No. 1,and others, Solid State Technology, 21_, No. 1,and others, Solid State Technology, 24, No. 1,and others, J. Ch. I. Ch. E., 12, 33 (1981).and others, J. Ch. I. Ch. E., 14, 205 (1983).and others, Ind. Eng. Chem. Process Des. Dev., 23, 48 (1984).

, PHYSICAL PROPERTIES. McGraw-Hill, New York, NY (1977)., THERMODYNAMIC AND PHYSICAL PROPERTY DATA. Gulf Publishing Co., Houston, TX (1992).and R. W. Gallant, PHYSICAL PROPERTIES OF HYDROCARBONS. Vols. 1 (2nd ed.), 2 (3rd ed.), 3, and 4, Gulf

Publishing Co., Houston, TX (1992, 1993, 1993, 1995).26. Estimated.

2. Very limited experimental data for heat capacity are available for inorganic compounds as compared to the more abundantexperimental data which are available for organic compounds. Thus, the estimates for these substances should be considered roughapproximations in the absence of experimental data. The estimates are noted by the * following the compound name.

362

Appendix F

COMPOUND LIST BY FORMULA

Ag SILVER 1 CdF2AgCl SILVER CHLORIDE 2 Cdl2Agl SILVER IODIDE 3 CdOAl ALUMINUM 4 ClFAIB3H12 ALUMINUM BOROHYDRIDE 5 CIF03AlBr3 ALUMINUM BROMIDE 6 CIF3AIC13 ALUMINUM CHLORIDE 7 CtF5AIF3 ALUMINUM FLUORIDE 8 CIH03SAU3 ALUMINUM IODIDE 9 CIH04A1203 ALUMINUM OXIDE 10 C102AI2S3012 ALUMINUM SULFATE 11 C12Ar ARGON 12 C120As ARSENIC 13 C1207AsBr3 ARSENIC TRI BROMIDE 14 CoAsCl3 ARSENIC TRICHLORIDE 15 CoCl2AsF3 ARSENIC TRIFLUORIDE 16 CoNC304AsF5 ARSENIC PENTAFLUORIDE 17 CrAsH3 ARSINE 18 CrC606Asl3 ARSENIC TRIIODIDE 19 Cr02Cl2As203 ARSENIC TRIOXIDE 20 CsAt ASTATINE 21 CsBrAu GOLD 22 CsClB BORON 23 CsFBBr3 BORON TRIBROMIDE 24 CslBC13 BORON TRICHLORIDE 25 CuBF3 BORON TRI FLUORIDE 26 CuBrBH2CO BORINE CARBONYL 27 CuClBH303 BORIC ACID 28 CuCt2B2D6 DEUTERODIBORANE 29 CulB2H5Br DIBORANE HYDROBROMIDE 30 DCNB2H6 DIBORANE 31 02B3N3H6 BORINE TRIAMINE 32 D20B4H10 TETRABORANE 33 EuB5H9 PENTABORANE 34 F2B5H11 TETRAHYDROPENTABORANE 35 F20B10H14 DECABORANE 36 FeBa BARIUM 37 FeC505Be BERYLLIUM 38 FeCl2BeB2H8 BERYLLIUM BOROHYDRIDE 39 FeCl3BeBr2 BERYLLIUM BROMIDE 40 FrBeCl2 BERYLLIUM CHLORIDE 41 GaBeF2 BERYLLIUM FLUORIDE 42 GaCl3BeI2 BERYLLIUM IODIDE 43 GdBi BISMUTH 44 GeBiBr3 BISMUTH TRIBROMIDE 45 GeBr4BiCl3 BISMUTH TRICHLORIDE 46 GeCl4BrF5 BROMINE PENTAFLUORIDE 47 GeHCl3Br2 BROMINE 48 GeH4C CARBON 49 Ge2H6CC120 PHOSGENE 50 Ge3H8CF20 CARBONYL FLUORIDE 51 HBrCH4N20 UREA 52 HCNCH4N2S THIOUREA 53 HClCNBr CYANOGEN BROMIDE 54 HFCNCl CYANOGEN CHLORIDE 55 HICNF CYANOGEN FLUORIDE 56 HN03CO CARBON MONOXIDE 57 H2COS CARBONYL SULFIDE 58 H20COSe CARBON OXYSELENIDE 59 H202C02 CARBON DIOXIDE 60 H2SCS2 CARBON DISULFIDE 61 H2S04CSeS CARBON SELENOSULFIDE 62 H2S2C2N2 CYANOGEN 63 H2SeC3S2 CARBON SUBSULFIDE 64 H2TeCa CALCIUM 65 H3N03SCaF2 CALCIUM FLUORIDE 66 HeCbF5 COLUMBIUM FLUORIDE 67 HeCd CADMIUM 68 HfCdCl2 CADMIUM CHLORIDE 69 Hg

CADMIUM FLUORIDE 70CADMIUM IODIDE 71CADMIUM OXIDE 72CHLORINE MONOFLUORIDE 73PERCHLORYL FLUORIDE 74CHLORINE TRIFLUORIDE 75CHLORINE PENTAFLUORIDE 76CHLOROSULFONIC ACID 77PERCHLORIC ACID 78CHLORINE DIOXIDE 79CHLORINE 80CHLORINE MONOXIDE 81CHLORINE HEPTOXIDE 82COBALT 83COBALT CHLORIDE 84COBALT NITROSYL TRICARBONYL 85CHROMIUM 86CHROMIUM CARBONYL 87CHROMIUM OXYCHLORIDE 88CESIUM 89CESIUM BROMIDE 90CESIUM CHLORIDE 91CESIUM FLUORIDE 92CESIUM IODIDE 93COPPER 94CUPROUS BROMIDE 95CUPROUS CHLORIDE 96CUPRIC CHLORIDE 97COPPER IODIDE 98DEUTERIUM CYANIDE 99DEUTERIUM 100DEUTERIUM OXIDE 101EUROPIUM 102FLUORINE 103FLUORINE OXIDE 104IRON 105IRON PENTACARBONYL 106FERROUS CHLORIDE 107FERRIC CHLORIDE 108FRANCIUM 109GALLIUM 110GALLIUM TRICHLORIDE 111GADOLINIUM 112GERMAN IUM 113GERMANIUM BROMIDE 114GERMANIUM CHLORIDE 115TR ICHLORO GERMANE 116GERMANE 117DIGERMANE 118TRI GERMANE 119HYDROGEN BROMIDE 120HYDROGEN CYAN IDE 121HYDROGEN CHLORIDE 122HYDROGEN FLUOR IDE 123HYDROGEN IODIDE 124NITRIC ACID 125HYDROGEN 126WATER 127HYDROGEN PEROXIDE 128HYDROGEN SULFIDE 129SULFURIC ACID 130HYDROGEN DISULFIDE 131HYDROGEN SELENIDE 132HYDROGEN TELLURIDE 133SULFAMIC ACID 134HELIUM-3 135HELIUM-4 136HAFNIUM 137MERCURY 138

363

HgBrZ MERCURIC BROMIDE 139 PC13HgClZ MERCURIC CHLORIDE 140 PC15Hgl2 MERCURIC IODIDE 141 PH3IF7 IODINE HEPTAFLUORIDE 142 PH4Br12 IODINE 143 PH4CIIn INDIUM 144 PH4IIr IRIDIUM 145 POC13K POTASSIUM 146 PSBr3KBr POTASSIUM BROMIDE 147 PSC13KCl POTASSIUM CHLORIDE 148 P406KF POTASSIUM FLUORIDE 149 P4010KI POTASSIUM IODIDE 150 P4S10KOH POTASSIUM HYDROXIDE 151 PbKr KRYPTON 152 PbBr2La LANTHANUM 153 PbCl2Li LITHIUM 154 PbF2LiBr LITHIUM BROMIDE 155 PbI2LiCl LITHIUM CHLORIDE 156 PbOLiF LITHIUM FLUORIDE 157 PbSLil LITHIUM IODIDE 158 PdLu LUTETIUM 159 PoMg MAGNESIUM 160 PtMgCl2 MAGNESIUM CHLORIDE 161 RaMgO MAGNESIUM OXIDE 162 RbMn MANGANESE 163 RbBrMnCl2 MANGANESE CHLORIDE 164 RbClMo MOLYBDENUM 165 RbFMoF6 MOLYBDENUM FLUORIDE 166 RblMo03 MOLYBDENUM OXIDE 167 ReNC13 NITROGEN TRICHLORIDE 168 Re207ND3 HEAVY AMMONIA 169 RhNF3 NITROGEN TRIFLUORIDE 170 RnNH3 AMMONIA 171 RuNH30 HYDROXYLAMINE 172 RuF5NH4Br AMMONIUM BROMIDE 173 SNH4CI AMMONIUM CHLORIDE 174 SF4NH4I AMMONIUM IODIDE 175 SF6NH50 AMMONIUM HYDROXIDE 176 SOBr2NH5S AMMONIUM HYDROGENSULFIDE 177 SOC12NO NITRIC OXIDE 178 SOF2NOCl NITROSYL CHLORIDE 179 S02NOF NITROSYL FLUORIDE 180 S02C12N02 NITROGEN DIOXIDE 181 S03N2 NITROGEN 182 S2C12N2F4 TETRAFLUOROHYDRAZINE 183 SbN2H4 HYDRAZINE 184 SbBr3N2H4C AMMONIUM CYANIDE 185 SbCl3N2H6C02 AMMONIUM CARBAMATE 186 SbCISN20 NITROUS OXIDE 187 SbH3N203 NITROGEN TRIOXIDE 188 Sbl3N204 NITROGEN TETRAOXIDE 189 Sb203N205 NITROGEN PENTOXIDE 190 ScNa SODIUM 191 SeNaBr SODIUM BROMIDE 192 SeCl4NaCN SODIUM CYANIDE 193 SeF6NaCl SODIUM CHLORIDE 194 SeOCl2NaF SODIUM FLUORIDE 195 Se02Nal SODIUM IODIDE 196 SiNaOH SODIUM HYDROXIDE 197 SiBrCl2FNa2S04 SODIUM SULFATE 198 SiBrF3Nb NIOBIUM 199 SiBr2ClFNd NEODYMIUM 200 SiClF3Ne NEON 201 SiCl2F2Ni NICKEL 202 SiCl3FNiC404 NICKEL CARBONYL 203 SiCl4NiF2 NICKEL FLUORIDE 204 SiF4Np NEPTUNIUM 205 SiHBr302 OXYGEN 206 SiHCl303 OZONE 207 SiHF3Os OSMIUM 208 SiH2Br2OsOFS OSMIUM OXIDE PENTAFLUORIDE 209 SiH2Cl2Os04 OSMIUM TETROXIDE - YELLOW 210 SiH2F2Os04 OSMIUM TETROXIDE - WHITE 211 SiH2l2P PHOSPHORUS - WHITE 212 SiH3BrPBr3 PHOSPHORUS TRIBROMIDE 213 SiH3ClPC12F3 PHOSPHORUS DICHLORIDE TRIFLUORIDE 214 SiH3F

PHOSPHORUS TRICHLORIDE 215PHOSPHORUS PENTACHLORIDE 216PHOSPHINE 217PHOSPHONIUM BROMIDE 218PHOSPHONIUM CHLORIDE 219PHOSPHONIUM IODIDE 220PHOSPHORUS OXYCHLORIDE 221PHOSPHORUS THIOBROMIDE 222PHOSPHORUS THIOCHLORIDE 223PHOSPHORUS TRIOXIDE 224PHOSPHORUS PENTOXIDE 225PHOSPHORUS PENTASULFIDE 226LEAD 227LEADLEADLEADLEAD

BROMIDE 228CHLORIDE 229FLUORIDE 230IODIDE 231

LEAD OXIDE 232LEAD SULFIDE 233PALLADIUM 234POLONIUM 235PLATINUM 236RADIUM 237RUBIDIUM 238RUBIDIUM BROMIDE 239RUBIDIUM CHLORIDE 240RUBIDIUM FLUORIDE 241RUBIDIUM IODIDE 242RHENIUM 243RHENIUM HEPTOXIDE 244RHODIUM 245RADON 246RUTHENIUM 247RUTHENIUM PENTAFLUORIDE 248SULFUR 249SULFUR TETRAFLUORIDE 250SULFUR HEXAFLUORIDE 251THIONYL BROMIDE 252THIONYL CHLORIDE 253SULFUROUS OXYFLUORIDE 254SULFUR DIOXIDE 255SULFURYL CHLORIDE 256SULFUR TRIOXIDE 257SULFUR MONOCHLORIDE 258ANTIMONY 259ANTIMONY TRIBROMIDE 260ANTIMONY TRICHLORIDE 261ANTIMONY PENTACHLORIDE 262STIBINE 263ANTIMONY TRI IODIDE 264ANTIMONY TRIOXIDE 265SCANDIUM 266SELENIUM 267SELENIUM TETRACHLORIDE 268SELENIUM HEXAFLUORIDE 269SELENIUM OXYCHLORIDE 270SELENIUM DIOXIDE 271SILICON 272BROMODICHLOROFLUOROSILANE 273TRIFLUOROBROMOSI LANE 274DIBROMOCHLOROFLUOROSI LANE 275TRIFLUOROCHLOROSILANE 276DICHLORODIFLUOROSILANE 277TR1CHLOROFLUOROSILANE 278SI LI CON TETRACHLOR IDE 279SILICON TETRAFLUORIDE 280TRIBROMOSILANE 281TRICHLOROSILANE 282TR IFLUOROSI LANE 283DIBROMOSI LANE 284DICHLOROSI LANE 285DIFLUOROSI LANE 286DIIODOSILANE 287MONOBROMOSI LANE 288MONOCHLOROSILANE 289MONOFLUOROSILANE 290

364

SiH3I IODOSILANE 291Si H4 SI LANE 292Si02 SILICON DIOXIDE 293Si2Cl6 HEXACHLORODISILANE 294S i 2F6 HEXAFLUORODISI LANE 295Si2H5Cl DISILANYL CHLORIDE 296Si2H6 DISILANE 297Si20Cl3F3 TRICHLOROTRIFLUORODISILOXANE 298Si20Cl6 HEXACHLORODISILOXANE 299Si 20H6 DI SI LOXANE 300Si3Cl8 OCTACHLOROTRISILANE 301Si3H8 TRISILANE 302Si3H9N TRISILAZANE 303Si4H10 TETRASILANE 304Sm SAMARIUM 305Sn TIN 306SnBr4 STANNIC BROMIDE 307SnCl2 STANNOUS CHLORIDE 308SnCl4 STANNIC CHLORIDE 309SnH4 STANNIC HYDRIDE 310Snl4 STANNIC IODIDE 311Sr STRONTIUM 312SrO STRONTIUM OXIDE 313Ta TANTALUM 314Tc TECHNETIUM 315Te TELLURIUM 316TeCl4 TELLURIUM TETRACHLORIDE 317TeF6 TELLURIUM HEXAFLUORIDE 318Ti TITANIUM 319TiCl4 TITANIUM TETRACHLORIDE .' 320Tl THALLIUM 321TlBr THALLOUS BROMIDE 322TU THALLOUS IODIDE 323Tm THULIUM 324U URANIUM 325UF6 URANIUM FLUORIDE 326V VANADIUM 327VC14 VANADIUM TETRACHLORIDE 328VOC13 VANADIUM OXYTRICHLORIDE 329W TUNGSTEN 330WF6 TUNGSTEN FLUORIDE 331Xe XENON 332Yb YTTERBIUM 333Yt YTTRIUM 334Zn ZINC 335ZnCl2 ZINC CHLORIDE 336ZnF2 ZINC FLUORIDE 337ZnO ZINC OXIDE 338ZnS04 ZINC SULFATE 339Zr ZIRCONIUM 340ZrBr4 ZIRCONIUM BROMIDE 341ZrCl4 ZIRCONIUM CHLORIDE 342Zrl4 ZIRCONIUM IODIDE 343

365

Appendix G

COMPOUND LIST BY NAME

ALUMINUM 4ALUMINUM BOROHYDRIDE 5ALUMINUM BROMIDE 6ALUMINUM CHLORIDE 7ALUMINUM FLUORIDE 8ALUMINUM IODIDE 9ALUMINUM OXIDE 10ALUMINUM SULFATE 11AMMONIA 171AMMONIUM BROMIDE 173AMMONIUM CARBAMATE 186AMMONIUM CHLORIDE 174AMMONIUM CYANIDE 185AMMONIUM HYDROGENSULFIDE 177AMMONIUM HYDROXIDE 176AMMONIUM IODIDE 175ANTIMONY 259ANTIMONY PENTACHLORIDE 262ANTIMONY TRI BROMIDE 260ANTIMONY TRICHLORIDE 261ANTIMONY TRI IODIDE 264ANTIMONY TRIOXIDE 265ARGON 12ARSENIC 13ARSENIC PENTAFLUORIDE 17ARSENIC TRIBROMIDE 14ARSENIC TRICHLORIDE 15ARSENIC TRIFLUORIDE 16ARSENIC TRI IODIDE 19ARSENIC TRIOXIDE 20ARSINE 18ASTATINE 21BARIUM 37BERYLLIUM 38BERYLLIUM BOROHYDRIDE 39BERYLLIUM BROMIDE 40BERYLLIUM CHLORIDE 41BERYLLIUM FLUORIDE 42BERYLLIUM IODIDE 43BISMUTH 44BISMUTH TRIBROMIDE 45BISMUTH TRICHLORIDE 46BORIC ACID 28BORINE CARBONYL 27BORINE TRIAMINE 32BORON 23BORON TRIBROMIDE 24BORON TRICHLORIDE 25BORON TRIFLUORIDE 26BROMINE 48BROMINE PENTAFLUORIDE 47BROMODICHLOROFLUOROSILANE 273CALCIUM 65CALCIUM FLUORIDE 66CADMIUM 68CADMIUM CHLORIDE 69CADMIUM FLUORIDE 70CADMIUM IODIDE 71CADMIUM OXIDE 72CARBON 49CARBON DIOXIDE 60CARBON DISULFIDE 61CARBON MONOXIDE 57CARBON OXYSELENIDE 59CARBON SELENOSULFIDE 62CARBON SUBSULFIDE 64CARBONYL FLUORIDE 51CARBONYL SULFIDE 58CESIUM 89

CESIUM BROMIDE 90CESIUM CHLORIDE 91CESIUM FLUORIDE 92CESIUM IODIDE 93CHLORINE 80CHLORINE DIOXIDE 79CHLORINE HEPTOXIDE 82CHLORINE MONOFLUORIDE 73CHLORINE MONOXIDE 81CHLORINE PENTAFLUORIDE 76CHLORINE TRIFLUORIDE 75CHLOROSULFONIC ACID 77CHROMIUM 86CHROMIUM CARBONYL 87CHROMIUM OXYCHLORIDE 88COBALT 83COBALT CHLORIDE 84COBALT NITROSYL TRICARBONYL 85COLUMBIUM FLUORIDE 67COPPER 94COPPER IODIDE 98CUPRIC CHLORIDE- 97CUPROUS BROMIDE 95CUPROUS CHLORIDE 96CYANOGEN 63CYANOGEN BROMIDE 54CYANOGEN CHLORIDE 55CYANOGEN FLUORIDE 56DECABORANE 36DEUTERIUM 100DEUTERIUM CYANIDE 99DEUTERIUM OXIDE 101DEUTERODIBORANE 29DIBORANE 31DIBORANE HYDROBROMIDE 30DIBROMOCHLOROFLUOROSI LANE 275DIBROMOSI LANE 284DICHLORODIFLUOROSILANE 277DICHLOROSILANE 285DIFLUOROSILANE 286DIGERMANE 118D11ODOSI LANE 287DISI LANE 297DISILANYL CHLORIDE 296DISILOXANE 300EUROPIUM 102FERRIC CHLORIDE 108FERROUS CHLORIDE 107FLUORINE 103FLUORINE OXIDE 104FRANCIUM 109GADOLINIUM 112GALLIUM 110GALLIUM TRICHLORIDE 111GERMANE 117GERMAN IUM 113GERMANIUM BROMIDE 114GERMANIUM CHLORIDE 115GOLD 22HAFNIUM 137HEAVY AMMONIA 169HELIUM-3 135HELIUM-4 136HEXACHLORODI SI LANE 294HEXACHLORODI SI LOXANE 299HEXAFLUORODI SI LANE 295HYDRAZI NE 184HYDROGEN 126HYDROGEN BROMIDE 120

366

HYDROGEN CHLORIDE 122HYDROGEN CYANIDE 121HYDROGEN DISULFIDE 131HYDROGEN FLUORIDE 123HYDROGEN IODIDE 124HYDROGEN PEROXIDE 128HYDROGEN SELENIDE 132HYDROGEN SULFIDE 129HYDROGEN TELLURIDE 133HYDROXYLAMINE 172INDIUM 144IODINE 143IODINE HEPTAFLUORIDE 142IODOSILANE 291IRIDIUM 145IRON 105IRON PENTACARBONYL 106KRYPTON 152LANTHANUM 153LEAD 227LEAD BROMIDE 228LEAD CHLORIDE 229LEAD FLUORIDE 230LEAD IODIDE 231LEAD OXIDE 232LEAD SULFIDE 233LITHIUM 154LITHIUM BROMIDE 155LITHIUM CHLORIDE 156LITHIUM FLUORIDE 157LITHIUM IODIDE 158LUTETIUM 159MAGNESIUM 160MAGNESIUM CHLORIDE 161MAGNESIUM OXIDE 162MANGANESE 163MANGANESE CHLORIDE 164MERCURIC BROMIDE 139MERCURIC CHLORIDE 140MERCURIC IODIDE 141MERCURY 138MOLYBDENUM 165MOLYBDENUM FLUOR IDE 166MOLYBDENUM OXIDE 167MONOBROMOSILANE 288MONOCHLOROSI LANE 289MONOFLUOROSILANE 290NEODYMIUM 200NEON 201NEPTUNIUM 205NICKEL 202NICKEL CARBONYL 203NICKEL FLUORIDE 204NIOBIUM 199NITRIC ACID 125NITRIC OXIDE 178NITROGEN 182NITROGEN DIOXIDE 181NITROGEN PENTOXIDE 190NITROGEN TETRAOXIDE 189NITROGEN TRICHLORIDE 168NITROGEN TRIFLUORIDE 170NITROGEN TRIOXIDE 188NITROSYL CHLORIDE 179NITROSYL FLUORIDE 180NITROUS OXIDE 187OCTACHLOROTRISILANE 301OSMIUM 208OSMIUM OXIDE PENTAFLUORIDE 209OSMIUM TETROXIDE - WHITE 211OSMIUM TETROXIDE - YELLOW 210OXYGEN 206OZONE 207PALLADIUM 234PENTABORANE 34PERCHLORIC ACID 78

PERCHLORYL FLUORIDE 74PHOSGENE 50PHOSPHINE 217PHOSPHONIUM BROMIDE 218PHOSPHONIUM CHLORIDE 219PHOSPHONIUM IODIDE 220PHOSPHORUS - WHITE 212PHOSPHORUS DICHLORIDE TRIFLUORIDE 214PHOSPHORUS OXYCHLORIDE 221PHOSPHORUS PENTACHLORIDE 216PHOSPHORUS PENTASULFIDE 226PHOSPHORUS PENTOXIDE 225PHOSPHORUS THIOBROMIDE 222PHOSPHORUS THIOCHLORIDE 223PHOSPHORUS TRI BROMIDE 213PHOSPHORUS TRICHLORIDE 215PHOSPHORUS TRIOXIDE 224PLATINUM 236POLONIUM 235POTASSIUM 146POTASSIUM BROMIDE 147POTASSIUM CHLORIDE 148POTASSIUM FLUORIDE 149POTASSIUM HYDROXIDE 151POTASSIUM IODIDE 150RADIUM 237RADON 246RHENIUM 243RHENIUM HEPTOXIDE 244RHODIUM 245RUBIDIUM 238RUBIDIUM BROMIDE 239RUBIDIUM CHLORIDE 240RUBIDIUM FLUORIDE 241RUBIDIUM IODIDE 242RUTHENIUM 247RUTHENIUM PENTAFLUORIDE 248SAMARIUM 305SCANDIUM 266SELENIUM 267SELENIUM DIOXIDE 271SELENIUM HEXAFLUORIDE 269SELENIUM OXYCHLORIDE 270SELENIUM TETRACHLORIDE 268SI LANE 292SILICON 272SILICON DIOXIDE 293SILICON TETRACHLORIDE 279SILICON TETRAFLUORIDE 280SILVER 1SILVER CHLORIDE 2SILVER IODIDE 3SODIUM 191SODIUM BROMIDE 192SODIUM CHLORIDE 194SOD IUM CYAN IDE 193SODIUM FLUORIDE 195SODIUM HYDROXIDE 197SODIUM IODIDE 196SODIUM SULFATE 198STANNIC BROMIDE 307STANNIC CHLORIDE 309STANNIC HYDRIDE 310STANNIC IODIDE 311STANNOUS CHLOR IDE 308STIBINE 263STRONTIUM 312STRONTIUM OXIDE 313SULFAMIC ACID 134SULFUR 249SULFUR DIOXIDE 255SULFUR HEXAFLUORIDE 251SULFUR MONOCHLORIDE 258SULFUR TETRAFLUORIDE 250SULFUR TRIOXIDE 257SULFURIC ACID 130

367

SULFUROUS OXYFLUORIDE 254SULFURYL CHLORIDE 256TANTALUM 314TECHNETIUM 315TELLURIUM 316TELLURIUM HEXAFLUORIDE 318TELLURIUM TETRACHLORIDE 317TETRABORANE 33TETRAFLUOROHYDRAZINE 183TETRAHYDROPENTABORANE 35TETRASI LANE 304THALLIUM 321THALLOUS BROMIDE 322T HAL LOUS IODIDE 323THIONYL BROMIDE 252THIONYL CHLORIDE 253THIOUREA 53THULIUM 324TIN 306TITANIUM 319TI TAN IUM TETRACHLORIDE 320TRIBROMOSILANE 281TRICHLORO GERMANE 116TRICHLOROFLUOROSI LANE 278TRICHLOROSILANE 282TRICHLOROTRIFLUORODISILOXANE 298TRI FLUOROBROMOSILANE 274TRI FLUOROCHLOROSILANE 276TRIFLUOROSI LANE 283TRI GERMANE 119TRISILANE 302TR ISILAZANE 303TUNGSTEN 330TUNGSTEN FLUORIDE 331URANIUM 325URANIUM FLUORIDE 326UREA 52VANADIUM 327VANADIUM OXYTRICHLORIDE 329VANADIUM TETRACHLORIDE 328WATER 127XENON 332YTTERBIUM 333YTTRIUM 334ZINC 335ZINC CHLORIDE 336ZINC FLUORIDE 337ZINC OXIDE 338ZINC SULFATE 339ZIRCONIUM 340ZIRCONIUM BROMIDE 341ZIRCONIUM CHLORIDE 342ZIRCONIUM IODIDE 343

368

Appendix H

Computer Program for Thermodynamic Properties

A computer program for calculation of thermodynamic properties using the Peng-Robinson equation of stateis available for a nominal fee (Carl L. Yaws, Box 10053, Lamar University, Beaumont, TX 77710, phone/FAX409-880-8787). The computer program is executable and complete with data files. The program calculatesthermodynamic properties at pressures and temperatures that are input by the user. Representative results are shownbelow:

COMPOUND: 1534 N2 NITROGEN

reference state: datum of ideal gas @ 77 F (25 C)

ppsia

500.0500.0500.0500.0500.0500.0500.0500.03000.03000.03000.03000.03000.03000.03000.03000.010000.010000.010000.010000.010000.010000.010000.010000.0

TF

-300.000.00

100.00200.00300.00400.00500.001000.00-300.00

0.00100.00200.00300.00400.00500.001000.00-300.00

0.00100.00200.00300.00400.00500.001000.00

Z

0.1520.9700.9931.0031.0081.0101.0121.0110.8550.9881.0401.0651.0761.0801.0811.0682.6361.5071.4441.4021.3691.3421.3181.234

VftA3/lb

0.0190.3420.4260.5070.5870.6660.7441.1310.0170.0580.0740.0900.1040.1190.1320.1990.0160.0270.0310.0350.0400.0440.0480.069

HBTU/lb

-174.07-24.31

2.2228.2153.9879.70105.49237.14-169.89-41.19-8.8620.9549.4577.22104.59240.67-154.48-43.69-10.2521.5552.1381.84110.95253.15

SBTU/lb F

-0.892-0.297-0.245-0.202-0.166-0.134-0.1060.004-0.917-0.456-0.392-0.343-0.303-0.268-0.238-0.124-0.956-0.562-0.496-0.444-0.401-0.364-0.332-0.212

369

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Handbook of Thermodynamic Diagrams VOLUME4

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