Hazardous Waste Management - The Voice of the Flexible · PDF file ·...

Hazardous Waste Hazardous Waste ManagementManagement

Environmental Resource CenterEnvironmental Resource Center

Flexible Packaging AssociationFlexible Packaging Association

INTRODUCTIONINTRODUCTION

llBrian KarnofskyBrian Karnofsky

––Environmental Resource CenterEnvironmental Resource Center

llbrianbrian@@ercwebercweb.com.com

ll919919--469469--15851585

llhttp://www.ercweb.comhttp://www.ercweb.com

Material to Be CoveredMaterial to Be Covered

llWhat is Hazardous WasteWhat is Hazardous Waste

llWaste Management OnWaste Management On--sitesite

llPrePre--Transport RequirementsTransport Requirements

llEmergency ResponseEmergency Response

llCommon ProblemsCommon Problems

What IsWhat Is

Hazardous WasteHazardous Waste

Hazardous Waste Hazardous Waste 40 CFR 261

llCharacteristic Characteristic wastewastellListed wasteListed wastellHazardous waste Hazardous waste

mixturesmixturesllTreatment Treatment

residuesresidues

ListedF003

CharacteristicD001

Characteristic WasteCharacteristic Waste

Ignitable Reactive

Corrosive Toxic

Ignitable D001Ignitable D001

ll Liquid with flashpoint less than 140°Liquid with flashpoint less than 140°(except aqueous solutions containing < 24% (except aqueous solutions containing < 24% alcohol)alcohol)

ll NonNon--liquid, capable under standard liquid, capable under standard temperature and pressure, of causing fire temperature and pressure, of causing fire through friction, absorption of moisture or through friction, absorption of moisture or spontaneous chemical change and when spontaneous chemical change and when ignited burns so vigorously and ignited burns so vigorously and persistently it creates a hazardpersistently it creates a hazard

ll Ignitable compressed gases and oxidizers Ignitable compressed gases and oxidizers as defined by DOTas defined by DOT 55--55

IGNITABLE HAZARDOUS WASTE

ENVIRONMENTAL RESOURCE CENTER

COMBUSTIBLE

FLAMMABLE

200° F200° F

60.5°° C (141° F° F)

100° F100° F

140° F140° F

EPAEPA DOTDOT

llAn aqueous material with a An aqueous material with a pH pH << 2 or 2 or >> to 12.5to 12.5

llOr…Or…

Characteristic Hazardous WasteCharacteristic Hazardous Waste

CorrosiveCorrosive D002D002

A liquid that can corrode steel A liquid that can corrode steel at a rate greater than 0.25 at a rate greater than 0.25 inch per year at a inch per year at a temperature of 55temperature of 55°° C (130C (130°° F)F)

Characteristic Hazardous Waste

CorrosiveCorrosive D002D002


llNormally unstable and reacts Normally unstable and reacts violently without detonatingviolently without detonatingllReacts violently with waterReacts violently with waterllForms an explosive mixture with Forms an explosive mixture with

waterwaterllGenerates toxic gases, vapors, or Generates toxic gases, vapors, or

fumes when mixed with waterfumes when mixed with water

ReactiveReactive D003D003


ll Contains cyanide or sulfide and generates Contains cyanide or sulfide and generates toxic gases, vapors, or fumes at a pH of toxic gases, vapors, or fumes at a pH of between 2 and 12.5between 2 and 12.5

ll Capable of detonation if heated under Capable of detonation if heated under confinement or subjected to a strong initiating confinement or subjected to a strong initiating sourcesource

ll Capable of detonation at standard Capable of detonation at standard temperature and pressuretemperature and pressure

ll Listed by DOT as 1.1 Listed by DOT as 1.1 –– 1.3 explosive1.3 explosive

ReactiveReactive D003D003

Characteristic Hazardous WastesCharacteristic Hazardous WastesToxicity CharacteristicToxicity Characteristic

EPA HW Regulatory EPA HW RegulatoryNumber Contaminant Level (mg/l) Number Contaminant Level (mg/l)

D004 Arsenic 5.0 D032 Hexachlorobenzene 0.13D005 Barium 100.0 D033 Hexachlorobutadiene 0.5D018 Benzene 0.5 D034 Hexachloroethane 3.0D006 Cadmium 1.0 D008 Lead 5.0D019 Carbon Tetrachloride 0.5 D013 Lindane 0.4D020 Chlordane 0.03 D009 Mercury 0.2D021 Chlorobenzene 100.0 D014 Methoxychlor 10.0D022 Chloroform 6.0 D035 Methyl Ethyl Ketone 200.0D007 Chromium 5.0 D036 Nitrobenzene 2.0D023 o-Cresol 200.0 D037 Pentachlorophenol 100.0D024 m-Cresol 200.0 D038 Pyridine 5.0D025 p-Cresol 200.0 D010 Selenium 1.0D026 Cresol 200.0 D011 Silver 5.0D016 2,4-D 10.0 D039 Tetrachlorethylene 0.7D027 1,4-Dichlorobenzene 7.5 D015 Toxaphene 0.5D028 1,2-Dichloroethane 0.5 D040 Trichloroethylene 0.5D029 1,1-Dichloroethylene 0.7 D041 2,4,5-Trichlorophenol 400.0D030 2,4-Dinitrotolene 0.13 D042 2,4,6-Trichlorophenol 2.0D012 Endrin 0.02 D017 2,4,5-TP (Silvex) 1.0D031 Heptachlor (& its hydroxide) 0.008 D043 Vinyl Chloride 0.2

Listed WasteListed WasteListed Waste

• Spent solvents

• Electroplating

• Wood preserving wastes

• Petroleum refining waste

• Chlorinated aliphatic hydrocarbons

• Dioxin-bearing wastes, pesticide production

•• Spent solventsSpent solvents

•• ElectroplatingElectroplating

•• Wood preserving wastesWood preserving wastes

•• Petroleum refining wastePetroleum refining waste

•• Chlorinated aliphatic Chlorinated aliphatic hydrocarbonshydrocarbons

•• DioxinDioxin--bearing wastes, bearing wastes, pesticide productionpesticide production

Non-Specific Source WastesNonNon--Specific Source WastesSpecific Source Wastes

F List261.30F List

261.30

Degreasing F001Degreasing F001

TetrachloroethyleneTetrachloroethyleneTrichloroethyleneTrichloroethyleneMethyleneMethylene chloridechloride1,1,11,1,1--TrichloroethaneTrichloroethaneCarbon tetrachlorideCarbon tetrachlorideChlorinated fluorocarbonsChlorinated fluorocarbons

Solvents F002Solvents F002

TetrachloroethyleneTetrachloroethyleneMethyleneMethylene chloridechlorideTrichloroethyleneTrichloroethylene1,1,11,1,1--TrichloroethaneTrichloroethaneChlorobenzeneChlorobenzene1,1,21,1,2--TrichloroTrichloro--1,2,21,2,2--trifluoroethanetrifluoroethaneOrthodichlorobenzeneOrthodichlorobenzeneTrichlorofluoromethaneTrichlorofluoromethane1,1,21,1,2--TrichloroethaneTrichloroethane


XyleneXylene Methyl isobutyl Methyl isobutyl ketoneketoneAcetoneAcetone nn--Butyl alcoholButyl alcoholEthyl acetateEthyl acetate CyclohexanoneCyclohexanoneEthyl benzeneEthyl benzene MethanolMethanolEthyl etherEthyl ether


CresolsCresolsCresylicCresylic acidacidNitrobenzeneNitrobenzene


TolueneTolueneMethyl ethyl Methyl ethyl ketoneketoneCarbon disulfideCarbon disulfideIsobutanolIsobutanolPyridinePyridineBenzeneBenzene22--ethoxyethanolethoxyethanol22--nitropropanenitropropane

KK--ListListSpecific Source WastesSpecific Source Wastes

Wood PreservationInorganic PigmentsOrganic ChemicalsInorganic ChemicalsPesticidesExplosivesPetroleum RefiningVeterinary PharmaceuticalsInk Formulation

Wood PreservationInorganic PigmentsOrganic ChemicalsInorganic ChemicalsPesticidesExplosivesPetroleum RefiningVeterinary PharmaceuticalsInk Formulation

Iron and SteelPrimary CopperPrimary LeadPrimary ZincPrimary AluminumFerroalloysSecondary LeadCoking

Iron and SteelPrimary CopperPrimary LeadPrimary ZincPrimary AluminumFerroalloysSecondary LeadCoking

Commercial Chemical Commercial Chemical ProductsProducts

llThe commercial chemical The commercial chemical productproductllOffOff--specification speciesspecification speciesllContainer residueContainer residuellSpill residueSpill residuellWhen used as fuelWhen used as fuelllWhen applied to landWhen applied to land

P LIST

U LIST

PP--LISTLIST


Haz-ardous waste No.

Chemical abstracts No. Substance

P023 107-20-0 Acetaldehyde, chloroP002 591-08-2 Acetamide, N-aminoP057 640-19-7 Acetamide, 2-fluoroP058 62-74-8 Acetic acid, fluoro-,sodium saltP002 591-08-2 1-Acetyl-2-thioureaP003 107-02-8 AcroleinP070 116-06-03 AldicarbP004 309-00-2 AldrinP005 107-18-6 Allyl alcoholP006 20859-73-6 Alluminum phosphate (R,T)

Regulated Hazardous Waste Regulated Hazardous Waste

llListed wastesListed wastes

llCharacteristic wastesCharacteristic wastes

llWaste mixturesWaste mixtures

llWaste residuesWaste residues

Hazardous Waste MixturesHazardous Waste Mixtures

Listed hazardous waste Listed hazardous waste + “Solid waste” + “Solid waste” = Listed hazardous waste= Listed hazardous waste

Characteristic waste Characteristic waste + “Solid waste” + “Solid waste” = ?= ?

Derived From RuleDerived From Rule

Residue derived from Residue derived from the treatment, storage, the treatment, storage, or disposal of listed or disposal of listed wastewaste


How to How to Accumulate Accumulate

Hazardous WasteHazardous Waste


SatelliteSatelliteAccumulationAccumulationPointPoint

AccumulationAccumulationPointPoint

•• Up to 90 DaysUp to 90 Days•• 180 days if SQG180 days if SQG

•• No Volume LimitNo Volume Limit•• No Time LimitNo Time Limit

•• 55 Gallon Limit55 Gallon Limit

Satellite Accumulation PointSatellite Accumulation Point

l An area at or near the point where the waste is initially accumulatedl Under the control of the

operator of the process generating the waste

Satellite Satellite Accumulation PointAccumulation Point

ll 55 gal/1qt of waste in containers55 gal/1qt of waste in containers

llUnlimited timeUnlimited time

Satellite Accumulation PointSatellite Accumulation Point

llIn good conditionIn good conditionllCompatible with the wasteCompatible with the wastellClosedClosedllMarked to identify the contents or Marked to identify the contents or

with the words, “HAZARDOUS with the words, “HAZARDOUS WASTE”WASTE”

Containers Must beContainers Must beContainers Must be

Satellite Accumulation Point Satellite Accumulation Point RequirementsRequirements

llContainers holding Containers holding in in excess of 55 excess of 55 gallonsgallons must be must be marked with the marked with the date the excess date the excess accumulation beganaccumulation began

llRemove excess Remove excess within within three daysthree days


Satellite Satellite Accumulation PointAccumulation Point


Accumulation PointAccumulation Point

Accumulation PointAccumulation Point

ll Any volume of waste in tanks Any volume of waste in tanks

or containers or containers

ll Up to 90 days (180 for SQG)Up to 90 days (180 for SQG)


SatelliteSatellitePointPointAccumulationAccumulation

•• Containers in good Containers in good conditioncondition

•• Compatible w/wasteCompatible w/waste•• Container closedContainer closed•• Mark w/contents or Mark w/contents or ""Hazardous WasteHazardous Waste""

•• No time limitNo time limit•• 55 gallon limit (1 qt 55 gallon limit (1 qt acute)acute)

•• Containers in good Containers in good conditioncondition

•• Compatible w/wasteCompatible w/waste•• Container closedContainer closed••Mark "Hazardous Mark "Hazardous Waste"Waste"

••90 day time limit90 day time limit••Plus...Plus...

Accumulation PointsAccumulation Points

llHandle in a manner to avoid ruptures Handle in a manner to avoid ruptures or releasesor releases

llInspect weeklyInspect weekly

llIgnitable or reactive must be 50 ft. Ignitable or reactive must be 50 ft. inside property boundaryinside property boundary

llSeparate incompatiblesSeparate incompatibles

Regulatory RequirementsRegulatory Requirements

Accumulation PointsAccumulation Points

llDate each containerDate each container

llEmergency equipmentEmergency equipment

llContingency planContingency plan

llTrain personnel exposed to or who Train personnel exposed to or who handle hazardous wastehandle hazardous waste

Regulatory RequirementsRegulatory Requirements


FIRE

CLAY Absorbent

Accumulation points must be Accumulation points must be equipped withequipped with

llEmergency communication Emergency communication equipmentequipment

ll Fire control equipmentFire control equipment

llSpill control equipmentSpill control equipment

InspectionsInspections

•Inspected by

•Date

•Leaks

•Deterioration

Personnel occupationally Personnel occupationally exposed to or who handle exposed to or who handle

hazardous waste must hazardous waste must receive annual trainingreceive annual training

Hazardous

waste

training

Hazardous

waste

training

llHow to comply with How to comply with regulationsregulations

llHow to implement How to implement emergency response emergency response proceduresprocedures

Training Training RecordsRecords

ll Job titleJob title

ll Job descriptionJob description

ll Training descriptionTraining description

ll Training documentationTraining documentation

PrePre--TransportationTransportation

HazardousWaste

Hazardous Waste Manifest

Placard

MarkingMarking

LabelingLabeling


Basic DescriptionBasic Description11. US DOT Description

a.

b.

c.

d.

Waste Toxic liquids, n.o.s., 6, UN 2810, PG II (contains 1,1,1-trichloroethane, phenol) ERG 123

(Including Proper Shipping Name, Hazard Class, and ID Number)

Manifest Basic DescriptionManifest Basic DescriptionBlock 11Block 11

llSShipping name (hipping name (colcol 2 of HMT)2 of HMT)

llHHazaz class division or number (class division or number (colcol 3)3)

llIIdentification number (UN/NA: dentification number (UN/NA: colcol 4)4)

llPPacking Group (if any) (acking Group (if any) (colcol 5)5)

–– Example: Waste Acetone, 3, Example: Waste Acetone, 3, UN1090, PGIIUN1090, PGII


Uniform Hazardous Uniform Hazardous Waste ManifestWaste Manifest

GENERATOR'S CERTIFICATION: I hereby declare that the contents of this consignmentare fully and accurately described above by proper shipping name and are classified,packed, marked, and labeled, and are in all respects in proper condition fortransportation by highway according to applicable international and nationalgovernment regulations.

If I am a large quantity generator, I certify that I have a program in place to reduce thevolume and toxicity of waste generated to the degree I have determined to beeconomically practicable and that I have selected the practicable method of treatment,storage, or disposal currently available to me which minimizes the present and futurethreat to human health and the environment; OR, if I am a small quantity generator, Ihave made a good faith effort to minimize my waste generation and select the best waste management method that is available to me and that I can afford.

16.

Print/Type Name Signature Month Day Year

On or Accompanying ManifestOn or Accompanying Manifest

lEmergency response telephone number

lEmergency response information


Friday June 1, 1995Friday June 1, 1995

Environmental Protection AgencyEnvironmental Protection Agency

Phase II - Land Disposal Restrictions

Phase II - Land Disposal Restrictions

40 CFR Part 268 et al.40 CFR Part 268 et al.

Land Disposal Land Disposal RestrictionsRestrictions

Emergency RequirementsEmergency Requirements

llContingency planContingency plan–– TSD facilitiesTSD facilities–– Large quantity generatorsLarge quantity generators

llPreparedness and preventionPreparedness and prevention–– TSD facilitiesTSD facilities–– Large quantity generatorsLarge quantity generators–– Small quantity generatorsSmall quantity generators

Preparedness and PreventionPreparedness and Prevention

ll Internal communication Internal communication equipmentequipmentllMeans of summoning Means of summoning

outside assistanceoutside assistancell Emergency response Emergency response

equipmentequipmentll Decontamination equipmentDecontamination equipmentllWater (vol. and pressure) for Water (vol. and pressure) for

above equipmentabove equipment

Mike F

Preparedness and Preparedness and PreventionPrevention

llAccess to emergency equipmentAccess to emergency equipmentllAisle space for emergency Aisle space for emergency

equipmentequipment

•• Make and document Make and document emergency assistance emergency assistance agreementsagreements


FIRE

CLAY Absorbent

Emergency equipment Emergency equipment must be periodically must be periodically tested and maintained tested and maintained to ensure to ensure proper proper operation in the event operation in the event of an emergencyof an emergency


Contingency Contingency Plan must listPlan must listlName, lAddress, and lPhone number of

each Emergency Coordinator

Emergency CoordinatorsName Address Phone

1. Jack G Forest Ave. 543-11232. Joe K Lane Dr. 210-12343. Blake M First St. 987-22334. Tracy H Easy St 789-1111


Describe Describe arrangements arrangements

with with organizations organizations that may be that may be

called upon to called upon to assist in an assist in an emergencyemergency

HOSPITAL

AMBULANCE

ContingencyPlan

GovernmentResponseAgencies


Emergency Emergency Equipment ListEquipment List

Emergency Equipment

Type of equipmentType of equipment

LocationLocation

DescriptionDescription

CapabilitiesCapabilities

What

Where

Capabilities

Evacuation PlanEvacuation Plan

llEvacuation signalsEvacuation signalsllPrimary evacuation Primary evacuation

routesroutesllAlternate evacuation Alternate evacuation

routesroutes

Emergency ProceduresEmergency Procedures

llHow you will respond to a HW spill, How you will respond to a HW spill, fire or explosionfire or explosionllWho will respond?Who will respond?llWhat procedures will they follow?What procedures will they follow?llWill they respond differently for Will they respond differently for

different wastes or in different different wastes or in different waste accumulation or waste accumulation or management areas?management areas?

Universal WasteUniversal Waste

llBatteriesBatteries

llThermostatsThermostats

llPesticidesPesticides

llLampsLamps

40 CFR 273 Applies to40 CFR 273 Applies to

llGenerators, transporters, Generators, transporters, TSDsTSDs

llDo not count universal wastes Do not count universal wastes in generator statusin generator status

SQHUWsSQHUWs

llSmall quantity handler of Small quantity handler of universal wasteuniversal waste

llUp to 5,000 kg at any timeUp to 5,000 kg at any time

ll§273 Subpart B§273 Subpart B

LQHUWsLQHUWs

llLarge quantity handler of Large quantity handler of universal wasteuniversal waste

ll> 5,000 kg at any time> 5,000 kg at any time

ll§273 Subpart C§273 Subpart C

Destination FacilityDestination Facility

llHW TSD facilityHW TSD facilityllPermit or interim statusPermit or interim status

Handler Requirements Handler Requirements (L and S)(L and S)

llMay not treat or disposeMay not treat or disposellShip toShip to

––S or LQHUWS or LQHUW––TSDTSD––Foreign destinationForeign destination

Handler Requirements Handler Requirements (L and S)(L and S)

ll Label units or containersLabel units or containers–– Universal waste Universal waste -- batteriesbatteries–– Waste batteriesWaste batteries–– Used batteriesUsed batteries

ll Replace “batteries” with Replace “batteries” with –– Thermostats, lampsThermostats, lamps

ll Label pesticidesLabel pesticides–– Original label, DOT label, or Original label, DOT label, or

label approved by pesticide label approved by pesticide collection programcollection program

Handler StorageHandler Storage

llUp to 1 year from Up to 1 year from date it becomes UWdate it becomes UWllProve you store for Prove you store for

less than 1 yearless than 1 year–– LabelLabel–– MarkMark–– Other methodOther method

Handler RequirementsHandler Requirements

llMinimize releases to environmentMinimize releases to environment

llKeep containers Keep containers closedclosed, good , good conditioncondition

llContain releasesContain releases

ll If releases are HW, manage per §260If releases are HW, manage per §260--272272

LQHUW RequirementsLQHUW Requirements

llRegister with EPARegister with EPA

llReceive ID number prior to storing Receive ID number prior to storing 5,000 kg5,000 kg

–– Ensure employees are “thoroughly Ensure employees are “thoroughly familiar with waste handling and familiar with waste handling and emergency procedures relative to emergency procedures relative to their responsibilities during normal their responsibilities during normal facility operations and facility operations and emergencies”emergencies”

SQHUW Training SQHUW Training RequirementRequirement

llInform of waste handling Inform of waste handling and emergency proceduresand emergency procedures

Questions?Questions?

llbrianbrian@@ercwebercweb.com.com

llhttp://www.http://www.ercwebercweb.com.com

ll919919--469469--1585 x 2391585 x 239

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