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Fire Station, GIDC, Ankleshwar- 2
Ph. No. !"2#$#% 22"22&, #'()")
Disaster Pre*ention + anaement Centre
Hazard Assessment and Risk Hazard Assessment and Risk
Management Techniques for Management Techniques for
Industries Industries
Prepared / 0Prepared / 0 1IA3 ASA41IA3 ASA4Chief Co-ordinator,
DPMC
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Disaster Risk Management
5he s/stematic process o6 7sin
administrati*e decisions,
oranisation, operational skills and
capacities to implement policies,strateies and copin capacities o6
the societies and comm7nities to
lessen the impacts o6en*ironmental and technoloical
disasters.
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Disaster Risk Reduction
5he concept7al 6ramework o6
elements considered with the
possiilities to minimi8e
*7lnerailitiies and disaster riskthro7ho7t a societ/, to a*oid
!pre*ention% or to limit !mitiation
and preparedness% the ad*erseimpacts o6 ha8ards.
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What is system safety? What is system safety?
The system safety concept is the application of
special technical and managerial skills to the
systematic, forward-looking identification and
control of hazards throughout the life cycle of a
project, program, or activity The concept calls for
safety analyses and hazard control actions,
!eginning with the conceptual phase of a systemand continuing through the design, production,
testing, use, and disposal phases, until the activity
is retired
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Chemical hazards Chemical hazards 5/pe o6 chemical ha8ards
aterial ha8ard 0 "azardous nature of chemicals
like #nflamma!le, e$plosive, to$ic, corrosive, reactive,
radioactive, reducing, o$idizing, decomposing or
incompati!le.
Process ha8ards 0 #n process, chemical and
physical change, chemical reaction, pressure,
temperature, level, flow, %uantity and other
parameters create
1essel ha8ards 0 The vessels and e%uipments in
which the chemicals are stored, handled or reacted
pose.
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Chemical hazards Chemical hazards 5/pe o6 chemical ha8ards
Control ha8ards 0 The inade%uate, defective, under
design or wrongly modified control devices or their of
failure cause.
Fire ha8ards 0 Fire or e9plosion
5o9ic ha8ards 0 &ffluent disposal and gaseous
emissions !ring pollution and to$ic hazards
:andlin ha8ards 0 'eaks, spills and splashes
cause
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Chemical hazards Chemical hazards
Ph/sical ha8ards or health ha8ards
Ph/sical :a8ards 0 Corrosives, ($plosives
etc
:ealth :a8ards 0 To$ic, #rritants and )$ides
Accident an emerenc/ ha8ard
&!sence, nonuse or failure of fire fighting
e%uipments, personal protective
e%uipments, emergency control devices
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The Hazard The Hazard
A potential condition or set o6 conditions, either
internal and;or e9ternal to a s/stem, prod7ct,
6acilit/, or operation. <hich, when acti*ated
trans6orms the ha8ard into a series o6 e*ents that
c7lminate in loss !an accident%. A simpler and
more 67ndamental de6inition o6 ha8ard is a
condition that can ca7se in=7r/ or death, damaeto or loss o6 e>7ipment or propert/, or
en*ironmental harm.
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Hazard Analysis at various stagesHazard Analysis at various stages
of Project Execution of Project Execution
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Process Hazard Management Process Hazard Management
Process :a8ard anaement incl7des0 "azard identification
"azard &ssessment
&ccidental vapour cloud release *flamma!le and+or
to$ic
(ngineering approaches to mitigation
Design features for emergency control
Process afety Management *PM
Planning for counter measures
(mergency response planning *(.P-onsite
&lerting local authorities and pu!lic
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Some important elements o6 PS.0
(mployee Participation Process afety #nformation *P#
Process "azard &nalysis *P"&
)perating Procedure
Training Contractor afety
Pre-tartup afety .eview
Mechanical #ntegrity
"ot /ork Program
Management of Change *M)C
#ncident #nvestigation
(mergency Planning 0 .esponse Compliance
&udits
Process Hazard Management Process Hazard Management
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#nitial startup
1ormal, temporary 0 emergency operations
1ormal shutdown
tartup following a turnaround or after an
emergency shutdown
)perating limits
Conse%uences of deviation steps re%uired to
correct or to avoid such deviation
).). ?peratin Proced7res
Process Hazard Management Process Hazard Management
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afety 0 "ealth considerations
Precautions necessary to prevent e$posure,
including engineering controls
&dministrative controls 0 personal protective
e%uipment
Controls measure to !e taken if physical
contact or air!orne e$posure occurs 2uality control for raw materials 0 control of
hazardous chemical inventory levels
afety systems 0 their functions
).). ?peratin Proced7res
Process Hazard Management Process Hazard Management
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Construction 0 e%uipment is in accordance
with design specifications
afety, operating, maintenance 0emergency procedures are in place 0 are
ade%uate
Modified facilities meet the re%uirementscontained in Management of Change
Training of each employee involved in
operating a process has !een completed
2.2. Pre-Start7p Sa6et/ 4e*iew
Process Hazard Management Process Hazard Management
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The technical !asis for the proposed
change
#mpact of change on safety and health Modifications to operating procedures
1ecessary time period for the change
&uthorization re%uirements for theproposed change
3p-date of Process afety information
*P#, P"& 0 )perating procedures
(.(. anaement o6 Chane !?C%
Process Hazard Management Process Hazard Management
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(ngineering 0 administrative controls
Detection methods for providing early
warning of releases Conse%uences of failure of engineering
and administrative controls
4acility site
"uman factors 2ualitative evaluation of a range of the
possi!le safety and health effects of failureof controls on employees and others
$.$. Process :a8ard Anal/sis !P:A%
Process Hazard Management Process Hazard Management
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"&5#D is an automated hazard identification tool
for continuous process plants and principle
features of
ectionalizing the process plant into several units
6eneration of hazardous incident scenarios
3se of models to distinguish !etween the feasi!le
and infeasi!le scenarios
3se rules to detect plant configuration pro!lem
HA!" Techni#ue HA!" Techni#ue
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HA!" Techni#ue HA!" Techni#ue :AID Process
Divide the Process Plant into smallersection
6enerate "azardous #ncident cenarios
#dentify the feasi!le cenarios only
#dentify plant configuration pro!lem
6enerate output in "&5)P ta!le
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The Hazard The Hazard
:a8ard se*erit/
Cateor/ Name Characteristics
I Catastrophic Death
oss o6 s/stem
II Critical Se*ere in=7r/ or moridit/
a=or damae to s/stem
III arinal inor in=7r/ or moridit/inor damae to s/stem
I1 Neliile No in=7r/ or moridit/
No damae to s/stem
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The Hazard The Hazard Possile ha8ard likelihood
Description Level Speci6ic Indi*id7al Item Fleet or In*entor/
Fre>7ent A ikel/ to occ7r 6re>7entl/ Contin7o7sl/e9perienced
Proale B <ill occ7r se*eral times inli6e o6 an item
<ill occ7r 6re>7entl/
?ccasional C ikel/ to occ7r sometimein li6e o6 an item
<ill occ7r se*eral times
4emote D nlikel/ 7t possile toocc7r in li6e o6 an item nlikel/ 7t canreasonal/ e e9pectedto occ7r
improale So 7nlikel/, it can eass7med occ7rrence ma/not e e9perienced
nlikel/ to occ7r, 7tpossile
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The Hazard The Hazard :a8ard Assessment atri9
Fre>7enc/ o6?cc7rrence
:AA4D CA5G?4IS
ICatastrophic
IICritical
IIIarinal
I1Neliile
!A% Fre>7ent 2 3 4
!B% Proale B 2B 3B 4B
!C% ?ccasional C 2C 3C 4C
!D% 4emote D 2D 3D 4D
!% improale D 2E 3E 4E
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The Hazard The Hazard :a8ard Assessment atri9
"azard .isk #nde$ ".#
7&, 78, 7C, 9&, 98, :& #
7D, 9C, 9D, :8, :C ##7(, 9(, :(, :(, ;&, ;8 ###
;C, ;D, ;( #<
S7ested Criteria
nacceptale
ndesirale !anaement decision re>7ired%
Acceptale with re*iew / manaement
Acceptale witho7t re*iew
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The Hazard The Hazard 4elationship o6 >7alitati*e proailit/
rankin to >7antitati*e *al7es
Description e*elFre>7enc/ o6occ7rrence
Potential relationshipto E7antitati*e 1al7e
Fre>7ent A :ih )"-)
Proale B
?ccasional C edi7m )"-(
4emote D )"-$
Improale ow )"-#
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The Conce$t of %is& The Conce$t of %is&
4isk0 Chances or possiilit/ o6 accidental lossesor 7ndesired conse>7ences.H
The pro!a!ility of a dangerous event posed !y a
hazard, over a definite time period of e$posure or
The fre%uency at which such events will occur
and results in fatalities to certain num!er of
people and
The conse%uence of such events in terms of
e$pected num!er of fatalities per year
4isk !Proailit/% 9 !Conse>7ences%
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Consequence Analysis or
Semi Quantitative Risk AnalysisAssessment o6 possiilities
--- B/ 7se o6 *ario7s ha8ardidenti6ication techni>7es like
J Preliminar/ :a8ard Anal/sis!P:A%
J :a8ard + ?perailit/ St7d/
J Sa6et/ A7dit J Fa7lt tre anal/sis
J *ent tree anal/sis, etc.
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EFFECT MODELS
Concei*in a credile scenario /
ha8ard identi6ication techni>7es
= Comp7tation o6 ph/sical e66ects o6 the scenario/ s7itale models like0
-- ?7t6low model -- Dispersion model
-- ncon6ined *apo7r clo7d e9plosion models
-- et 6ire dimensions
-- Damae 6rom shock wa*e on B1
-- Fire all radiation damaes
-- Pool 6ire radiation damaes etc.
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TEC!"Q#ES A$A"LA%LE
o Fire + 9plosion Inde9 !Dow Inde9% and
5o9icit/ Inde9
o Calc7lation o6 damaes likel/ 6rom the
6ires,e9plosions and to9ic releases andcominin the damaes with
proailities o6 occ7rrence in terms o6
Indi*id7al 4isk and Societal 4isk.
! 5he later is more o=ecti*e 6orestimatin the distances likel/ to e
a66ected%
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T&e Mat&ematical Models
Availa'le to Com(ute t&e E))ects-- 4elease rate o6 li>7ids 7nder press7re.
-- Distance o6 ower 9plosi*e imit in the windwarddirection.
-- Conto7rs o6 concentrations at the ro7ndle*el.
-- ass o6 as within e9plosi*e rane !For7ncon6ined *apo7r clo7d%
-- Shockwa*e damae on inition o6 7ncon6ined*apo7r clo7d e9plosion.
-- ass o6 as in e9plosi*e rane on B1.
-- Fire Ball 4adi7s.-- Fire all d7ration.
-- 4adiati*e 6l79.
-- 5hermal Dose.
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8oth the methods are closely related and as such
Mond #nde$ was developed as an e$tension of
D)/ inde$ Primarily, Dow inde$ calculates the
4ire 0 ($plosion inde$ for a process unit taking
into consideration the flamma!ility and reactivity
of the material handled in the process units under
the general and special process condition Mond#nde$ on the other hand uses specifically the
material to$icity in addition to the other aspects
"o' and Mond !ndices "o' and Mond !ndices
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Fire + 9plosion inde9 0!F + )% F 9 !GP:% !SP:%
5o9icit/ Inde9 0 5h K 5s !)KGP:KSP:%
)""
<here, F aterial Factor
SP: Special Process :a8ard
GP: General Process :a8ard
5h 5o9icit/ 6actor ased on the NFPA ha8ardinde9 !" $%
5s Correction 6actor !additional penalt/% 6or
to9icit/ ased on a9im7m Allowale
Concentration !AC% *al7e in ppm
"o' and Mond !ndices "o' and Mond !ndices
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"o' and Mond !ndices "o' and Mond !ndices 5o9icit/ Factors and Correction Factor
6or AC *al7esNFPA Inde9
N7mer 5o9icit/ Factor/
!5h%
" "
) '"2 )2'
( 2'"
$ (2'
AC !in ppm% 5S
' and low )2'
Between ' and '" L'
'" and more '"
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6P" includes processes eg e$othermic reaction,
endothermic reactions, hydrogenation, alkylation,
isomerisation, sulphurization, neutralization,esterification, o$idation, polymerization,
condensation, halogenation, nitration, loading-
unloading operation, enclosed process units,
inade%uate drainage and proper access etc
different penalties are assigned for different
processes
General Process :a8ard !GP:%
Process Hazard Management Process Hazard Management
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P" includes special hazards posed due to
process parameters like temp, pressure,
flamma!ility ranges *3(', '(' of material andissues like internal and e$ternal corrosion, leakage
from joints etc additional penalties are assigned
for special process hazards election of the
process units which may contri!ute to a fire or
e$plosion or to$ic release
Special Process :a8ard !SP:%
Process Hazard Management Process Hazard Management
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5he material 6actor which are the 67nctionso6 6lammale and reacti*it/ can e
calc7lated / the 6ollowin wa/ M
4ind out flash point of a material or "C< !y
multiplying heat of com!ustion !y the vapour
pressure of that su!stance at 9>? C
4ind out flamma!ility factor from the ne$t ta!le
from the flash point data or "C< value
4ind out the adia!atic decomposition temp of the
su!stance
4ind out the reactivity factor from the ta!le from
decomposition temp value
Process Hazard Management Process Hazard Management
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"o' and Mond !ndices "o' and Mond !ndices
5ale 6or 6indin o7t aterial Factor !6% 6rom the tale
Calc7late 6 6rom 6ollowin 5ale 6rom e6t to 4iht
Decompositiontemp. 5d De
O (" (" -&('
&(' -)")"
)")" -)""
)""
Flash :C1 4eacti*it/ QQQQQQQ
Pt. k ar; mol F
" ) 2 ( $
None O $ 9 )"-' A " " )$ 2$ 2& $"
)"" $ 9 )"-' 2.' ) $ )$ 2$ 2& $"
$"-)"" 2.' - $" A 2 )" )$ 2$ 2& $"
2"-$" $" #"" B ( )# )# 2$ 2& $"
O -2" #"" I $ 2) 2) 2$ 2& $"
aterial Factor F
I53
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Procedure for Calculating theProcedure for Calculating the
!ndices !ndices #dentify the most process units for risk
point of view
Determine the material factor *M4 foreach process units *flamma!ility 0
reactivity of material
Determine the 4ire 0 ($plosion #nde$
*40(# and the pro!lem e$posure area foreach process unit from the formula
Calculate the Ma$imum Pro!a!le Property
Damage *MPPD
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Indices and the 9tent o6 :a8ard
F + inde9 5o9icit/ Inde9 Deree o6 :a8ard
) #" ) # iht
#) &# # )" oderate
&L )2L )" Intermediate
)2 )' )" :ea*/
)'& )" Se*ere
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%is& Analysis %is& Analysis
General Principles o6 4isk Anal/sis
). All rele*ant risks are s/stematicall/
addressed #dentify major, don?t concentrate on minor
Consider those aspects of work which arehazardous
Take into account 0 critically assess e$isting safety
controls 0 measures provided
2. Address what act7all/ happens &ctual practice, not instruction
Consider non-routine operations
Pay attention to changes+interruptions
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%is& Analysis %is& Analysis
General Principles o6 4isk Anal/sis
: #nclude all who could !e affected, including
visitors, contractors, and general pu!lic
; Take into account, and o!jectively assess,
control measures
@ The level of protection measures should
match the level of risk *ie risk within the
&'&.P regionA #n most cases, make a rough assessment
first, find out the need for detailed assessment
and carry out the same, if needed
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%is& Analysis %is& Analysis se o6 Proailities in 4isk
Anal/sisThe risk of operational activity with hazardous
materials consists of two elements
The conse%uence of certain unwanted event
The pro!a!ility of certain conse%uences that will occur
& distinction is made !etween : types ofpro!a!ilities
The pro!a!ility of the initiating event The pro!a!ility that designed counter measures may
function
The pro!a!ility of certain conse%uences of an accident
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%is& Analysis %is& Analysis a/ers o6 Protection Anal/sis
?66site merenc/ eas7res Comm7nit/ Alertin + *ac7ation, i6 necessar/
?nsite merenc/ eas7res ?nsite *ac7ation
Protecti*e eas7res + Control Sa6et/ Instr7mented
itiation
Protecti*e Control + onitorin Process alarms +Sa6et/ Instr7mented Control
Process Control + S7per*ision
:a8ardo7s Process
!omogram o) Risk Assessment
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P .RR
!omogram o) Risk Assessment
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%is& Analysis %is& Analysis
Conse>7ence B1 odel 6or Di66erent
Static and oile Press7re 1essels
B1 Scenarios and Conse>7ence Distances
Storae t/pe In*entor/!5% )"" 6atalit/Distance ) Fatalit/Distance
.oad tanker 79 7:> M @BB M
--Do--- 9B 7A9 M ABB M
.ail /agon @B 97 M >BB M
"orton phere 7;B :B@ M ;B M
---Do--- 77@B A9; M 7:; M
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*ilometer
Conse#uence Analysis Conse#uence Analysis
Conse>7ence Anal/sis 6or a Ammonia 5ank eak
Scenario 0 2" dia. 5ank ha*in leak o6 N:( 6rom )" pipe
Conse>7ence 0 Distance to ID: is .& m
+ ,
,
,
,-
. /+0
-
+
-
* i l o m e t e r
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*ilometer
Conse#uence Analysis Conse#uence Analysis
So7r !containin :2S% Nat7ral Gas pipeline leak scenario
Scenario 0 67ll ore r7pt7re o6 a $2 pipeline
Conse>7ence 0 Distance to ID: is (.& m
+ ,
+12
+12
/ / 3 -
/12
+
/12
* i l o m e t e r
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%is& Analysis %is& Analysis
4isk control techni>7es ; 4isk anaement
#nherent safe design *!uilt-in safety
4ault tolerant measures *single or multiple
failures
Protective measures
&de%uate information on the residual risk
&dministration controls *eg allocation of task
to the human operator, training etc )ther .isk .eduction measures
Corrective and preventive actions
Document control
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%is& Analysis %is& Analysis
ist o6 So6twareTs A*ailale 6or 4isk
Anal/sis and ?ther St7dies
Sl.No.
Item Description Application
7 &4(T# )nshore .isk &nalysis
9 43 )ffshore .isk &nalysis
: C&4T&1 4ault Tree &nalysis
; (T.& (vent Tree &nalysis
@ "&5(C "&5)P tudy
A "&5T.&C "&5)P .ecommendation Tracking
> P"&T Conse%uence &nalysis
/"&5&1 Conse%uence &nalysis
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%is& Analysis %is& Analysis
ist o6 So6twareTs A*ailale 6or 4isk
Anal/sis and ?ther St7diesSl.No.
Item Description Application
(44(CT Conse%uence *(ffects Modeling
7B D&M&6( Conse%uence *Damage Modeling
77 PC-4&CT 4ailure 0 &ccident Data!ank
79 &&P (vent Tree &nalysis
7: 4M(C& 4ailure Mode (ffects 0 Criticality &nalysis
7; &1(E 'ife Time &nalysis 0 4ailure (stimation
7@ (0P 4).3M "ydrocar!on 'eak 0 #gnition Data!ase
7A &')"& Conse%uence &nalysis
& l
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%is& Analysis %is& Analysis
ist o6 So6twareTs A*ailale 6or 4isk
Anal/sis and ?ther St7diesSl.No.
Item Description Application
7> C'& "azardous &rea .isk 0 Classifications
7 .#F C3.<( T1) #ndividual 0 6roup .isk computations
7 .#F& T .isk &nalysis model of "ealth 0 afety
($ecutives, 3F
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Risk Communication
Seven Cardinal Rules
). Accept and in*ol*e the p7lic as a leitimatepartner.
2. Plan care67ll/ and e*al7ate /o7r e66orts.
(. isten to the p7licUs speci6ic concerns
!Comm7nication is two wa/ acti*it/%$. Be honest, 6rank and open !5r7st and crediilit/
are most precio7s assets%
'. Coordinate and collaorate with other credileso7rces
#. eet the needs o6 edia ! pro*ide risk in6ormationtailored to the needs o6 each t/pe o6 media%
L. Speak clearl/ and with compassion ! se simplenon technical lan7ae with eneral p7lic%