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© NERC All rights reserved Environmental Protection Scotland: 24 th March 2014 P otential shale gas/oil resources in Scotland Hugh Barron Responsive Surveys Scotland
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Page 1: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reserved Environmental Protection Scotland: 24th March 2014

Potential shale gas/oil resources in Scotland

Hugh Barron

Responsive Surveys Scotland

Page 2: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

The British Geological Survey (BGS)

− world's oldest national geological survey (1835)

− public sector organisation

− the UK’s No.1 centre for geoscience information & expertise

− geoscience advisors to UK Government (and Scottish Govt)

− impartial geological advice to industry, academia & the public

− part of NERC, which reports to BIS

− 50% funded (c. £45m) from NERC, rest from public and private commissioned research

Page 3: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

BGS Edinburgh office

Murchison House

Page 4: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

BGS expertise on shale gas issues− 3D geological modelling

− Hydrocarbon prospectivity

− Organic geochemistry

− Groundwater sustainability and quality

− Seismicity, earthquake hazard & rock stress

Page 5: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

What is shale?

− Grey or black, soft

− Fine grained

− Low porosity and permeability

− 70% of the world’s surface rocks are sedimentary; 50% of those are shale

− Contain ~95 % of the organic matter in sedimentary rocks

P521295

Lower Devonian shale, Margie Burn, Edzell

Page 6: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

P219686Shales, siltstones and thin sandstones in the Gullane Formation, Linhouse Water, Mid Calder, West Lothian

What is shale?

Page 7: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Land plant material and seawater algae collect in mud

Older, deeper shale layer

Where does the organic material come from?

Page 8: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

500 m

0 mOld deep shale layer

Burial over millions of years

− Shale buried

− Biological decay –biogenic methane

− Organic matter ‘cooked’ – thermogenic methane

Shale formation

Page 9: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Page 10: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Oil and gas maturation

Geothermal gradient in Scotland = 30 to 45oC/km

Page 11: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Kerogen types and their hydrocarbon potentialEnvironment Kerogen

typeKerogen form Origin HC potential

Aquatic

I

Alginite Algal bodiesOil

Amorphous Kerogen

Structureless debris of algal origin

Oil

IIStructureless planktonic material,primarily of marine origin

Terrestrial

II

Exinite Skins of spores and pollen, cuticle of leaves and herbaceous plants

Oil

III

Vitrinite Fibrous and woody plant fragments and structurelesscolloidal humic matter

Gas, some oil

Mainly gas

IVInertinite Oxidised, recycled woody debris

None

Page 12: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Petroleum accumulates instructural closure

Cap rock

Oil

Gas

Water

Reservoir

rock

Source

rock

www.aapg.org

Cap Rock

Reservoir

Source

Conventional Petroleum System

Page 13: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

PERMEABLE

RESERVOIR

ROCKS

What is a Gas Shale ?

LOMPOC Quarry Sample

Monterey Formation, CA

10 cm

It´s all together:

the source

the reservoir

the seal

and:

it is rich in organic carbon

!! Shale gas is self-contained HC system !

Unconventional Petroleum System− Regionally extensive

− Dry holes are rare

− No HC/H2O contacts

− Poor reservoir

− Production difficult

− Performance unpredictable

− High OPEX

Page 14: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Sand grain

Sand grain

gas

gas

0.25mm

shalesandstone

Conventional − Unconventional

Page 15: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

iMethane gas is stored……

In sorbedstate

On the surface of the organic fraction

On the surface of clay minerals

As free gas

Matrix porosity (blue)

Fracture porosity

− Fracture gas is produced immediately

− Adsorbed gas is released as pressure declines

Page 16: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

PERMEABLE

RESERVOIR

ROCKS

Unconventional Petroleum Systems

− Shale gas

− Shale oil

− Tight gas sands

− Heavy oil

− Coalbed methane

− Gas hydrates

− Oil shale

Page 17: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Oil shale

− Organic rich

− Immature for oil & gas

− Produces oil and gas when pyrolyzed at around 500°C

P528095Oil-shale from West Lothian

Page 18: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

From: frontispiece of Bibliotheca Chemica (Volume 2), 1906, edited by John Ferguson

Scotland − birthplace of the oil industryJames “Paraffin” Young

1811 − 1883− 1850 Patent: distillation of

oil and paraffin wax from cannel coal

− 1851, Bathgate: first commercial oil-works in the world

− Initially torbanite & cannel coal, then oil shale used

− Scotland was the worlds largest oil-producing nation for a few years!

− In production until 1960

Page 19: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

P000194

West Lothian oil-shale works

Retorts, distillation plant and condensers in 1927

− Estimated total oil production = 75m barrels (10m tonnes)

− 37m barrels remaining (5m tonnes)

Page 20: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Oil-shale products

P528115

Page 21: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

P000199

Spent shale…

Westwood Bing 'The Five Sisters', West Calder, West Lothian

Page 22: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

What makes a successful shale play?

− Conventional oil & gas production

− Depth range: 1000 – 3500 m

− TOC; Tmax; HI (maturity)

− Kerogen type (I & II)

− Target unit thickness/volume

− Overpressured zones

− Maturity within the gas/oil window

− Petrography: non-clay minerals

− Good geophysical data

Page 23: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Risk Period Target Basin/setting

Lower

Carboniferous Bowland Shale Pennine

Jurassic Kimmeridge Clay Weald

Higher

Carboniferous Dinantian shales Pennine

Jurassic Lias Weald

Carboniferous Oil Shale Group Midland Valley, Scotland

Cambrian Upper Cambrian Midland Microcraton

UK exploration targets

Page 24: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Conventional oil & gas wells

Page 25: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Midland Valley PEDL licences

Page 26: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Page 27: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Resources and reserves ‒ definitions

Resources refers to an estimate of the amounts of oil and gas that are believed to be physically contained in the source rock

Reserves refer to an estimate of the amount of oil or gas that can technically and economically be expected to be produced from a geological formation. Estimates of reserves will develop and improve with increasing exploration drilling

Page 28: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

SPE Oil & Gas Reserves Committee (OGRC)

Resources and reserves

Page 29: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

ResourceTechnically recoverableresource

Economic reserve ?

Resources and reserves

Page 30: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Resources and reserves

Bowland Shale resources

Total Gas in Place (GIP)

= 1,329 tcf (2013)

Midland Valley resources

= ? (2014)

Page 31: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

− Bottom-up – In place figure based on geological model, volumetrics and gas contents-BGS approach

− Top-down – Technically recoverable estimate based on well technology, well density, well performance* USGS approach

*more reliable figure but requires production data that we don’t have in the UK

How to estimate

Page 32: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Core and cuttings for:Mineralogy

Organic geochemistry

Vitrinite reflectance

Porosity and permeability

Subsurface models:of shale thicknesses

of underground stress

Downhole data:Geophysical log: Natural/spectral gamma;

resistivity; sonic, nuclear, image etc.

Geothermal gradient

Interpreted 2D/3D seismic

Datasets to aid resource estimations

Page 33: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Workflow

Page 34: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Page 35: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

Bowland Shale (lower unit)

Page 36: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

− Correlation and dating: establish a geological framework

− Variations in TOC and kerogen types

− Variations in shale mineralogy

− Geological controls on variables:

• Depositional

• Diagenetic

• Basin evolution; Maturation, inversion

− Resource assessment‒ resource to reserve

Geological challenges

Page 37: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

− Cracks the shale

− High pressure water or nitrogen, 350-700 bar (350 to 700 atmospheres)

Fracking basics

Page 38: Hugh Barron Responsive Surveys Scotland · Oil Amorphous Kerogen Structureless debris of algal origin Oil II Structureless planktonic material, primarily of marine origin Terrestrial

© NERC All rights reservedEnvironmental Protection Scotland: 24th March 2014

[email protected]

www.bgs.ac.uk/research/ukgeology/scotland.html


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