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The Dew Point Specialists Humidity Measurement in Fuel Cell Technologies Background Investment in alternative fuel technologies for motor vehicles continues to gather pace, as commercial viability becomes a reality. One of the leading technologies is fuel cells which represents a huge step forward in fundamental technology (even though it has been in existence for at least fifty years). Moisture plays an important part in determining efficiency, quality and safety issues relating to delivery and performance of the technologies. "I believe fuel cell vehicles will finally end the hundred-year reign of the internal combustion engine as the dominant source of power for personal transportation. It's going to be a winning situation all the way around - consumers will get an efficient power source, communities will get zero emissions, and automakers will get another major business opportunity - a growth opportunity." William C. Ford, Jr., Ford Chairman, International Auto Show, January 2000. Every major auto manufacturer has been researching and developing some type of fuel cell vehicle. Projections made by car companies themselves and energy and automotive experts concur that around 2010, and perhaps earlier, car manufacturers will have mass production capabilities for fuel cell vehicles, signifying the time they would be economically available to the average consumer. The Technology There are several different types of fuel cell. Because of its low operating temperature the fuel cell used to power motor vehicles is the Proton Exchange/ Polymer Electrolyte Membrane (PEM) fuel cell. In principle, a fuel cell operates like a battery. Unlike a bat- tery, a fuel cell does not run down or require recharging. It will produce energy in the form of electricity and heat as long as fuel is supplied. A fuel cell consists of two electrodes sandwiched around an electrolyte. Oxygen pass- es over one electrode and hydrogen over the other, generating electricity, water and heat. Hydrogen fuel is fed into the "anode" of the fuel cell. Oxygen (or air) enters the fuel cell through the cathode. Encouraged by a catalyst, the hydrogen atom splits into a proton and an electron, which take different paths to the cathode. The proton passes through the electrolyte. The electrons create a separate current that can be utilized before they return to the cathode, to be reunited with the hydrogen and oxygen in a molecule of water. A fuel cell system which includes a "fuel reformer" can utilise the hydrogen from any hydrocarbon fuel - from natural gas to methanol, and even gasoline. Since the fuel cell relies on chemistry and not combustion, emissions from this type of a system would still be much smaller than emissions from the cleanest fuel combustion processes. Typical process efficiency of 80% can be achieved, which is more than double that of an internal combustion engine. Michell Instruments Ltd 48 Lancaster Way Business Park Ely, Cambs, CB6 3NW Tel: +44 (0)1353 658000 Fax: +44 (0)1353 658199 e-mail: [email protected] www.michell-instruments.com Q6284 (UK) 0179 (UK) Heat Exchanger Fuel Source (Hydrogen) Oxidant Source (Oxygen) Coolant Humidifier/Heater Humidifier/Heater Fuel Cell Test System Exhaust 89.6 93.2 Dew Point Dew Point Power Output = Gas/Liquid Flow = Process Signals Key PEM fuel cell test station layout Application Notes
Transcript
Page 1: Humidity Measurement in Fuel Cell Technologies · The Dew Point Specialists Humidity Measurement in Fuel Cell Technologies Background Investment in alternative fuel technologies for

The Dew Point Specialists

Humidity Measurement in FuelCell Technologies

BackgroundInvestment in alternative fuel technologies for motor vehicles continues to gatherpace, as commercial viability becomes a reality. One of the leading technologies isfuel cells which represents a huge step forward in fundamental technology (eventhough it has been in existence for at least fifty years). Moisture plays an importantpart in determining efficiency, quality and safety issues relating to delivery andperformance of the technologies.

"I believe fuel cell vehicles will finally end the hundred-year reign of the internalcombustion engine as the dominant source of power for personal transportation. It'sgoing to be a winning situation all the way around - consumers will get an efficientpower source, communities will get zero emissions, and automakers will get anothermajor business opportunity - a growth opportunity." William C. Ford, Jr., FordChairman, International Auto Show, January 2000.

Every major auto manufacturer has been researching and developing some type offuel cell vehicle. Projections made by car companies themselves and energy andautomotive experts concur that around 2010, and perhaps earlier, car manufacturerswill have mass production capabilities for fuel cell vehicles, signifying the time theywould be economically available to the average consumer.

The TechnologyThere are several different types of fuel cell. Because of its low operating temperaturethe fuel cell used to power motor vehicles is the Proton Exchange/ Polymer ElectrolyteMembrane (PEM) fuel cell. In principle, a fuel cell operates like a battery. Unlike a bat-tery, a fuel cell does not run down or require recharging. It will produce energy in theform of electricity and heat as long as fuel is supplied.

A fuel cell consists of two electrodes sandwiched around an electrolyte. Oxygen pass-es over one electrode and hydrogen over the other, generating electricity, water andheat.

Hydrogen fuel is fed into the "anode" of the fuel cell. Oxygen (or air) enters the fuel cellthrough the cathode. Encouraged by a catalyst, the hydrogen atom splits into a protonand an electron, which take different paths to the cathode. The proton passes throughthe electrolyte. The electrons create a separate current that can be utilized before theyreturn to the cathode, to be reunited with the hydrogen and oxygen in a molecule ofwater.

A fuel cell system which includes a "fuel reformer" can utilise the hydrogen from anyhydrocarbon fuel - from natural gas to methanol, and even gasoline. Since the fuel cellrelies on chemistry and not combustion, emissions from this type of a system would stillbe much smaller than emissions from the cleanest fuel combustion processes.

Typical process efficiency of 80% can be achieved, which is more than double that ofan internal combustion engine.

Michell Instruments Ltd48 Lancaster Way Business ParkEly, Cambs, CB6 3NWTel: +44 (0)1353 658000 Fax: +44 (0)1353 658199e-mail: [email protected] www.michell-instruments.com

Q6284 (UK) 0179 (UK)

Heat Exchanger

Fuel Source (Hydrogen)

Oxidant Source (Oxygen)

Coolant

Humidifier/Heater

Humidifier/Heater

Fuel Cell

Test System

Exhaust

89.6

93.2

Dew Point

Dew Point

Power Output

= Gas/Liquid Flow

= Process Signals

Key

PEM fuel cell test station layout

Application Notes

Page 2: Humidity Measurement in Fuel Cell Technologies · The Dew Point Specialists Humidity Measurement in Fuel Cell Technologies Background Investment in alternative fuel technologies for

The Dew Point Specialists

Michell Instruments Ltd48 Lancaster Way Business ParkEly, Cambs, CB6 3NWTel: +44 (0)1353 658000 Fax: +44 (0)1353 658199e-mail: [email protected] www.michell-instruments.com

Moisture MeasurementHigh moisture content within the hydrogen fuel yields greater processefficiency. This is related to the effectiveness of the catalytic action ofsplitting the hydrogen molecule into two hydrogen ions and twoelectrons - the driver of the process. It is clear in any case that in boththe development of fuel cells, with complex and sophisticated fuel celltest stations; and also in production fuel cells, the hydrogen must besaturated with moisture at temperatures up to 80 - 90 oC to gain bestperformance. Hence the need, in the development phase, for accurateand reliable measurement of hydrogen gas dew point within theprocess. Many developers benefit from using Michell Instruments'Optidew Cooled Mirror Hygrometer with High Temperature sensor forthese determinations. Once optimum operating conditions for theparticular fuel cell have been determined, the production units can bebuilt with an appropriate humidifier for the hydrogen fuel.

Fuel Cell technologies hold promise for a greener future in theautomotive industry and Michell Instruments is in a strong position tobe able to provide a humidity measurement solution to suit theapplications of either industry.

Optidew

Reference UsersOpel, DVGW, Ballard Power, TH Aachen, Johnson Mathey

High Temperature Sensor

Ref

: HM

FCT-

AP

N 1


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