The Ultimate in ICP-OES
ULTIMA 2
High Performance in ICP-OES
High Quality Spectrometer
Analyst Software
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Ult
ima 2
High performance in ICP-OES
performance in ICP-OES.ULTIMA 2 is the only instrument able to provide an analytical answer for almost any matrix.
range and less than 10 picometers in the 320-800 nm range. Resolution shortens the time needed for method development, even for difficult matrices.
The highest performance is offered with an easy to use
instrument
ULTIMA 2 is based on a versatile platform to match actual and future needs of your laboratory. The knowledge of HORIBA Scientific in manufacturing ICP-OES and high quality optics were combined to provide the highest
The one meter focal length monochromator associated with the high density holographic grating and advanced PMT detection offers the best resolution achievable. Less than 5 picometers are achieved in the 160-320 nm
ULTIMA 2 ICP Optical Emission Spectrometer combines simplicity and high performance
RESOLUTION
228.756 228.779 228.802 228.825 228.840
Cd
228.802 228.823228.791 228.813
Cd
As
324.776 324.797324.754324.732324.711
Cu
Cd 228.802 nm & As 228.812 nm in soils
Cu 324.754 nm in Co 10 g/L
Cd 228.802 nm in Co 10 g/LULTIM
A 2
highest performance due to low matrix effects and enhanced sensitivity. Radial viewing reduces matrix effects, simplifying the analysis and improving detection limits in real samples.
High resolution can be extended to 430 nm using the dual back-to-back gratings option. Upgrade with a polychromator is also available, providing simultaneous measurement for unattended productivity and performance.
The total plasma view concept, using a verticaltorch and radial viewing with the measurement of the whole Normal Analytical Zone allows running the most difficult matrices with the
ULTIMA 2 can be tailored to your specific needs.The Far UV kit allows measuring wavelengths down to 120 nm, offering halogens analysis capability and the use of alternative wavelengthsfor many elements.
SENSITIVITY
VERSATILITY
134.694 134.724134.664134.634134.604
Cl
Cl 134.664nm in oil
401.230 401.250401.210
Nd
Nd in Pt 20 g/L
Au
Gd
PtIrOs
Pm
Np Pu Am Cm Bk Cf EsUTh PaAc
La Ce Pr Nd Sm Eu Tb Dy Ho Er Tm Yb Lu
Po At Rn
Xe
Kr
Ar
He
C N O F NeB
In Sn Sb Te I
Ga Ge As Se Br
Al Si P S Cl
Hg Tl Pb Bi
FeMnCr Co Ni Cu Zn
RuTcMo Rh Pd Ag CdRb
BaCs
Sr Y Zr Nb
K
MgNa
Ca Sc Ti V
BeLi
RaFr
H
Hf Ta W Re
0.15 0.8 0.9 0.060.30.5 0.35 0.7 0.081.7 0.9 1.20.6 1.5
1.9 1.4
0.05
0.030.6
0.5
1.5 0.03 0.09 0.2 0.2 0.2
6 0.03 0.2 0.3 0.9 0.2
0.05 0.2 0.2 0.3 0.2 0.2
3.2* 0.04 1 0.9 2
1.5 3 1.1 0.6 0.1 1.4
0.9 2 1.3 0.6 1.3
1.3 1.5 2.2 10
0.3
0.2 1.3 1.5 1.5 200
2.6 2.5 1.2 1.1 100
1 1.5 2.60.13
* concentration in mg/L
Detection limits in µg/L
High quality ICP-OES SpectrometerExcellence in ICP-OES design with attentionon every component• Spacious sample introduction area with
corrosion resistant sample tray for the analysis of all types of samples and for the use of a wide variety of sample introduction systems.
• Quick release and quick mount torch design in a large plasma compartment with no adjustment required. Multi-user operation is thus facilitated, providing excellent reproducibility.
• Vertical torch and Total Plasma View concept providing optimum sensitivity and reduced matrix effects, for both aqueous and organic matrices. The original sheath gas device and the large 3 mm i.d. injector tube gives unique high dissolved solids capability, up to 30% NaCl, with excellent long-term stability, minimized memory effects and with no compromise in performance.
• High efficiency 40.68 MHz solid state generator enhancing ability to handle a large range of applications and improving the limits of detection. Water cooling ensures improved reliability, stability and a reduced warm-up time, usually less than 15 minutes.
• The 2400 g/mm holographic grating used in the 1st and the 2nd orders offers constant spectral resolution and full wavelength coverage over the spectral range. The optical resolution is less than 5 pm in the 160-320 nm range and less than 10 pm in the 320-800 nm range. Using the optional dual back-to-back gratings (4320 g/mm and 2400 g/mm used in the 1st order) allows an optical resolution of less than 6 pm in the 160-430 nm range and less than 10 pm in the 430-800 nm range.
• The dual PMT detection system offers optimum sensitivity according to the wavelength range. Optional Far UV detector allows reaching high sensitivity down to 120 nm.
User oriented design for ease of use and high
technology for unrivaledperformance
ULTIM
A 2
Unique PMT technology dedicated to ICP-OESULTIMA 2 is equipped with the patented HighDynamic Detection system, exclusively available from HORIBA Scientific. The dynamic range is enhanced, with up to 10 orders of magnitude. The adjustment of the gain is done within milliseconds without hysteresis, allowing full spectrum acquisition in less than 3 minutes. Measurement of trace and major elements is possible in a single run for qualitative and semi-quantitative analysis purposes using optional Image Navigator.The use of PMT detection provides unique advantages such as UV sensitivity without any coating of the detector that can reduces lifetime. Detection of halogens and alternative lines in the Far UV has never been so easy. The high sensitivity of PMT detectors reduces analysis time by using short integration times, even for trace analysis.
High precision can be obtained using the truesimultaneous measurement of an internal standard, only available with PMT detectors.This measurement can be done on a dedicatedreference monochromator or on the optionalpolychromator.
0.001 0.01 0.1 1 10 100 1000
1 000
100 000
10 000 000
1 000 000 000
Concentration (mg/L)
Inte
nsity
(c/
s)
Cd from 0.001 to 1000 mg/L
Classical PMT: To see the signal of a major element at high concentrations, gain is lower and trade concentration are non-detectable.
Classical PMT: To see the signal of a trace concentration, gain is raised and high concentrations saturate.
HDD: Tailored sensitivity to the signal present, allowing the detection of trace and high concentrations in the same acquisition without saturation or loss of sensitivity
ULTIMA 2 offers productivity and unrivaled performanceThe design of ULTIMA 2 allows reduced matrixeffects, high sensitivity and enhanced stability,even with difficult matrices. To obtain this high level of performance, every component has been optimized to its best. The original sheath gas device, the 3 mm i.d. injector, the vertical torch with radial viewing and Total Plasma View concept, the size and quality of optical components and the detection system. Each component is integral to the high performance offered by the ULTIMA 2.Productivity is ensured by short integration timedue to high sensitivity, by stability avoiding frequent periodic recalibrations and by high dynamic range avoiding dilution of the samples.
Al 167.020 Ca 393.366 K 766.49 M, 257.610 Si 251.611
V 292.402Sr 407.771
Time (hours)0 1 2 3 4 5
0.90
0.94
0.96
1.02
1.06
1.10
Nor
mal
ized
Inte
nsity
NaCI 30 % over 5 hours
Measurement of high concentrations
Poor sensitivity, traceelement non-detected
Saturation of high concentrations
Sensitivity for trace analysis
Measurement of high concentrationwith no saturation
Sensitivity for trace analysis
Rel
ativ
e in
tens
ity
Rel
ativ
e in
tens
ity
Rel
ativ
e in
tens
ity
Analyst SoftwareAnalyst software extends instrument capability andensures traceability
Qualitative and semi-quantitative analysis with Image Navigator
• Analyst provides a data audit trail for users and instrument operation. 21 CFR Part 11 compliance is obtained through a powerful SQL Server database ensuring integrity of raw data and traceability of operations.
• User rights management is available for enhanced security and management of access levels for each analyst.
• Automatic start up and shutdown afford flexibility of use and reduces argon usage.
• Enhanced productivity with automated analysis thanks to multiple methods sequence, programmable recalibration and automated QC checks with user defined actions, in combination with the autosampler.
• Import and export of data from LIMS with a large variety of report and exports formats for results.
• Semi-quantitative analysis using full spectrum acquisition and Image Navigator.
• Statistical Process Control included for X, R, SD and histogram charts for user-selected samples.
Image Navigator is used to display the full spectrum acquired on the ULTIMA 2 and offers unique features for high resolution ICP spectrometers thanks to its library containing over 25 000 lines.The display of spectra is possible, allowing careful visual inspection, line selection according to spectral interferences and comparison of thefingerprint between several samples.• Qualitative analysis based on the identification
of the most sensitive lines for each element.• Semi-quantitative analysis using the library
or a reference spectrum.
As the full spectrum is stored in a file, retrospective analysis is always possible to confirm a result or to find the result for other elements.
Advanced tools areprovided by Analyst,
Image Navigator and CLIP
Multi-method sequences automate the analysis. Automatic tasks such as QC, recalibration, standard additions and blanck substraction can be inserted into the sequence with the click on a button.
ULTIM
A 2
CLIP: Collection of Line Intensity ProfilesLine selection is the crucial part of method development. As high resolution ICP-OES are often dedicated to the analysis of complex matrices with more risk of spectral interferences, this step can be difficult and time consuming. Using the CLIP will shorten the time needed for line selection and enhance the reliability of the resulting method.
CLIP stands for Collection of Line Intensity Profiles. The CLIP is dedicated to the PMT-based instruments of the ULTIMA 2 Family and can be used with older instruments.Using the proprietary ICP-based S3-base wavelength database, containing wavelengths and detection limits, allows the analyst to ensure that lines, sensitivity and relative intensities are really close to what will be observed on the instrument. Profiles of each line are calculated according to the instrument settings (focal length, slit combinations, grating(s), order used) and are displayed.
As the display allows the analyst to look at eachindividual spectrum and also at the total spectrum, he can easily validate a line for the analysis.More-over, the display of the various slit combinations can validate the best combination that can be used. The CLIP, based on theoretical calculations of the profiles reduces the need to prepare various solutions and to perform many profiles.
The benefits of CLIP are:
` Help for line selectionThis is an efficient tool to select lines for analysis in complex matrices and to select the optimum slit combination.
` Save timeIt reduces the time needed for method development due to reduced solutions preparation and reduced time for profiling lines.
` Allows you access to new marketsThe method development for new applications is easy and fast
Zoom of lines listin green: validatedin red: rejected
Line proposition with CLIP
Line zoom
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TECHNICAL SPECIFICATIONSGenerator Radio frequency, solid-state 40.68 MHz, water cooledCooling system GenCo water chiller for the generator and the coilExhaust Direct exhaust connection for plasma compartmentPlasma Fully demountable torch, 3 mm i.d. injector, 12 L/min plasma gas, 0.2 L/min sheath gas Sample introduction Concentric glass nebulizer and glass c y -
clonic spray chamber, 3-channel peristaltic pump (4-channel optional)
Optical system Thermo-regulated, 1 meter focal length, 2400 g/mm grating used in the 1st and 2nd order with optic resolution < 5 pm for 160-320 nm and < 10 pm for 320 - 800 nm.
Wavelength range 160-800 nm (optional 120-800 nm with far UV kit)
Detection Dual PMT detection with High Dynamic Detec-tion system (HDD®)
PHYSICAL DATARefer to ULTIMA 2 Pre-installation Guide for more details.
Depth 698 mm (27.5 in)Width 1696 mm (66.8 in)Height 604 mm (23.8 in)Weight 205 kg (452 lb)Power Single phase, 220-240 V, 50/60 Hz, 4 kVACooling water 2 to 3 L/min, 2 barsArgon 99.995% purityNitrogen 160 to 190 nm, 99.999% purity 120 to 160 nm, 99.9995% purityExhaust 250 m3/h (150 cfm)Environmental 20 to 80% humidity, 18-24 ± 2°C
Options• Dual back-to-back gratings (4320 g/mm and 2400 g/mm) used in the 1st
order offering resolution < 6 pm for 160-430 nm and < 10 pm for 430-800 nm.
• Far UV kit for sensitive measurement of wavelength down to 120 nm• AS-500 Autosampler with optional rinse station • Ar humidifier• Micro/high dissolved solids/inert material/iorganic nebulizers• Scott/HF resistant/cooled spray chambers• Ultrasonic nebulizer• CMA for simultaneous measurement of hydride forming elements and other
elements• Oxygen kit for organic samples• Laser ablation system
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www.horiba.com/scientific
France: HORIBA Jobin Yvon S.A.S., 16-18 rue du Canal, 91165 Longjumeau cedex - Tel: +33 (0)1 69 74 72 00 - Fax: +33 (0)1 69 09 07 21 - Email: [email protected]: HORIBA Instruments Inc., 3880 Park Avenue, Edison, NJ 08820-3012 - Toll-free: +1-866-562-4698 - Tel: +1 732 494 8660 - Fax: +1 732 549 5125 - Email: [email protected]: HORIBA Ltd., Tokyo Branch Office, 2-6, KandaAwaji-cho, Chiyoda-ku, Tokyo 101-0063, Japan - Tel: +81-(0)3 6206 4721 - Fax: +81 (0)3 6206 4730 - Email: [email protected]: HORIBA Jobin Yvon GmbH, Hauptstrasse 1, 82008 Unterhaching - Tel: +49 (0)89 4623 17-0 - Fax: +49 (0)89 4623 17-99 - Email: [email protected]: HORIBA Jobin Yvon Srl., Via Cesare Pavese 21, 20090 Opera (Milano) - Tel: +39 2 5760 3050 - Fax: +39 2 5760 0876 - Email: [email protected]: HORIBA UK Ltd., 2 Dalston Gardens, Stanmore, Middlesex HA7 1BQ - Tel: +44 (0)20 8204 8142 - Fax: +44 (0)20 8204 6142 - Email: [email protected]: HORIBA (China) Trading Co. Ltd., Unit D 1F, Bldg A, Srynnex International Park, No. 1068 West Tianshan Road, Shanghai 200335 - Tel: +86 (0)21 6289 6060 - Fax: +86 (0)21 6289 5553 Email: [email protected]: HORIBA Instruments do Brasil Ltda., Av. das Nações Unidas, 21.735, Bairro Jurubatuba, São Paulo CEP 04795-100 - Tel: +55 (0)11 5545 1500 - Fax: +55 (0)11 5545 1570 Email: [email protected]: Tel: +33 (0)1 69 74 72 00 - Email: [email protected]
