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Igneous Overview

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    Overview of IgneousRocks

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    Igneous rocks crystallize from magmasan most magmas are s cate magmas

    (containing 40 to 75 wt.% SiO2)

    Felsic (silicic or sialic) magmas are high in

    Intermediate magmas are between Felsic

    Mafic magmas contain less than 50 wt.%

    2 an g er g , e an e2 3 Ultramafic magmas are even more SiO2

    poor and MgO/FeO rich

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    Igneous Rocks

    Based on Felsic Mineral Content or rec e sen agram

    For fine-grained volcanic rocks, naming isase on c em ca compos t on p otNa2O+K2O vs. SiO2)

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    Streckeisen

    (QAPF)

    PlutonicIgneous Rock

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    IUGS Volcanic Classification is Graphical

    Alkaline

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    How to plot on the Streckeisen Diagram

    Note that several fields

    +A+P

    ,

    which do you use?

    Q/ or e as . . an

    Na-rich plagioclase with

    An35 andCa-rich plagioclase with

    >+A+P Anorthosite has >90%

    plagioclase (

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    Shows order in which minerals crystallizerom a yp ca ma c or asa c magma

    Left side is called Discontinuous Side Mafic minerals change abruptly

    Right side is called Continuous Side Plagioclase changes composition gradually

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    Bowens Reaction Series

    olivine Ca plagioclase

    T

    orthopyroxeneclinopyroxene NaCa plagioclase

    amphibole (Hb)erature

    biotite Na plagioclase

    coolingtem

    muscoviteresidual

    phases

    low T

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    ,

    An Isolated Tetrahedral Silicate

    complete solid solution with two end-mem ers:

    2 4 Fe SiO Fa alite Fa

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    Vitreous luster-

    No ood cleava es H=6.5 G=3.2

    Optical: high relief, moderately

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    Olivine in thin section

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    Pyroxenes Common in mafic and intermediate igneous rocks,

    typically crystallize from basalt after Olivine (BRS)

    Single Chain Silicates General Formula: Ca2+ M 2+ Fe2+ Si O

    Two kinds:

    Ortho roxenes O x M Fe Si O are orthorhombicand have perpendicular axes, low birefringence, // ext.

    Enstatite

    Clinopyroxenes (Cpx) Ca(Mg,Fe)Si2O6 are monoclinicand have one inclined axis, higher biref., inclined ext.

    Augite and Diopside

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    PyroxeneRelief, Color

    PPL

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    Orthopyroxene Properties

    Orthopyroxenes (enstatite, hypersthene,

    Color gray, bronze, brown Colorless to tan in thin section

    High relief

    Low birefringence

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    Clinopyroxene Properties

    Diopside (more likely in metamorphic rocks)

    a~1 g~1 2 6 Color light green

    Colorless in thin section

    Moderate birefrin ence inclined extinction Augite Ca~1(Mg,Fe)~1Si2O6 (typical igneous Cpx)

    Tan, light brown or green in thin section

    Moderate birefringence, inclined extinction

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    Augite (moderate birefringence, twinningand cleavage)

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    Hornblende (Hb)

    is the main amphibole in igneous rocks

    from mafic magmas, and at lowertemperature

    is most common in intermediatecomposition igneous rocks

    ou e-c a n s ca e

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    General Amphibole Formula:

    (Na,K)0-1(Ca,Na,Fe,Mg)2(Mg,Fe,Al)5(Si,Al)8O22(OH)2 large medium small tetrahedral cations

    Simple Amphibole (Tremolite):

    _ a2 g5 8 22 2

    Hornblende Formula:

    (Ca,Na)2-3(Mg,Fe,Al)5Si6(Si,Al)2O22(OH)2 Substitution of (Alvi, Aliv) for (Mgvi, Siiv) of tremolite

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    Black or dark green

    Vitreous luster, translucent = - = -. .

    two perfect prismatic cleavages at about 60o and ,

    commonly in prisms with flattened hexagonal

    cross-sect ons

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    Various shades of brown, red-brown, green,

    ue-green or tan n t n sect on

    Moderate to strong pleochroism is typical

    Moderate birefringence, commonly

    obscured by its color Two good cleavages at ~60o and 120o toeachother

    You have to be looking down the prism tosee 2 crossing sets of cleavages, in manyv ews you w see on y one se o c eavages

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    Igneous Amphiboles

    B g Horn en e Crysta s n t s ne-gra ne

    volcanic rock are called Phenocrysts

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    Hb cleavage, color & pleochroism

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    Kaersutite Na Ti-rich i neous am hibole

    w t strong re - rown p eoc ro sm

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    Biotite is the lowest Mafic Mineral on

    scon nuous e o owen s er es

    t crysta zes very ate rom ract onate ma cmagmas and is only common in intermediate toe s c magmas, 2 must e present or ot te

    to crystallize Biotite is a trioctahedral, t-o-t (or 2:1) sheetsilicate

    Biotites properties: its strongly pleochroic,has cleava e arallel extinction birds-e eextinction and pleochroic haloes around zircon

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    H2O in the liquid

    biotite, except for color and pleochroism

    ommon n ran tes an egmat tes

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    Felsic Minerals on BRS

    olivine Ca plagioclase

    T

    orthopyroxene

    clinopyroxene NaCa plagioclase

    amphibole (Hb)

    e

    rature

    biotite Na plagioclase

    coolingtem

    muscovite residualphases

    low T

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    = =, .

    Generally clear and glassy, may have avar e y o co ors c ear, smo y, rown, rose;its allochromatic)

    Conc o a racture, no c eavage

    Habit: hexagonal (6-sided prisms) or

    massive O tical: low relief and low birefrin ence

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    Quartz in Granite Thin Section

    From Atlas of Rocks & Minerals in Thin Section

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    The Feldspar Ternarya 2 2 8

    AnorthiteAll naturale spars

    No feldspars

    NaAlSi3O8 KAlSi3O8

    r oc ase

    alkali feldspars

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    .Properties

    H=6, G=2.56 ,

    or flesh-colored

    Habit: stubby prisms, simple twins common

    Optical: low relief and low birefringence Commonl Perthitic micro and macro

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    Alkali Felds ars have Perthites

    What do Perthites look like?

    Thinsection

    in XPL

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    Alkali Feldspars have Perthites

    What do Perthites look like?

    1mm

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    What causes Perthites?

    Caused by un-mixing, exsolution orse aration of Na+ diameter~1.1 and K+

    (diameter~1.6) as the feldspar cools

    At low temperatures, there is a miscibility

    3 8 3 8

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    plaid twinning

    1mm

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    = - = - = =. , . . , .

    Luster pearly, vitreous/translucent Co or w te to gray

    One perfect, one good cleavage Optical: low relief and low birefringence

    Not Perthitic!

    Common y zone

    Pl i l F ld h

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    Plagioclase Feldspars have

    po ysyn e c, ame ar e w ns

    - blein

    n

    han

    y

    visi

    L

    )

    siblei

    usual

    n(XP

    bev

    i

    imen

    ,

    secti

    M

    a

    s

    pe

    thin

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    Large crystals ofQuartz,

    Muscovite(which are low on Bowens

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    Elements and Volatiles

    Incompatible Elements those elements

    minerals (Li, B, Be)

    o at es t ose e ements t at ave astrong preference for the gaseous phase

    2 , 2, , ,

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    Phase Diagrams tell MUCH moreabout Crystallization and Melting

    What follows is just a quick preview of

    some of the things phase diagrams can beused for

    H d thi di t t ll

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    How do we use this diagram to tell

    Diopside-richqu

    80% CaMgSi2O6 (Di)20% CaAl Si O An

    X

    Draw isopleth=

    line of constantcomposition

    What happens as

    liquid cools?Anorthite-rich li uid Y65% CaAl2Si2O8 (An)

    35% CaMgSi2O6 (Di)

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    Textures of rocks in Di-An System

    2 component system with

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    2-component system with

    Crystallization ofPlagioclase inBasalts (realgneous p ag oc ase

    is not pure An like-

    system)

    P C iti d th

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    Pyroxene Compositions and the

    yroxene ua r atera

    CaFeSi2O6CaMgSi2O6

    ops e e en erg e

    Augite

    Ortho roxene

    Mg2Si2O6 Fe2Si2O6

    FerrosiliteEnstatite orthopyroxenes


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