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Overview of IgneousRocks
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Igneous rocks crystallize from magmasan most magmas are s cate magmas
(containing 40 to 75 wt.% SiO2)
Felsic (silicic or sialic) magmas are high in
Intermediate magmas are between Felsic
Mafic magmas contain less than 50 wt.%
2 an g er g , e an e2 3 Ultramafic magmas are even more SiO2
poor and MgO/FeO rich
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Igneous Rocks
Based on Felsic Mineral Content or rec e sen agram
For fine-grained volcanic rocks, naming isase on c em ca compos t on p otNa2O+K2O vs. SiO2)
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Streckeisen
(QAPF)
PlutonicIgneous Rock
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IUGS Volcanic Classification is Graphical
Alkaline
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How to plot on the Streckeisen Diagram
Note that several fields
+A+P
,
which do you use?
Q/ or e as . . an
Na-rich plagioclase with
An35 andCa-rich plagioclase with
>+A+P Anorthosite has >90%
plagioclase (
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Shows order in which minerals crystallizerom a yp ca ma c or asa c magma
Left side is called Discontinuous Side Mafic minerals change abruptly
Right side is called Continuous Side Plagioclase changes composition gradually
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Bowens Reaction Series
olivine Ca plagioclase
T
orthopyroxeneclinopyroxene NaCa plagioclase
amphibole (Hb)erature
biotite Na plagioclase
coolingtem
muscoviteresidual
phases
low T
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,
An Isolated Tetrahedral Silicate
complete solid solution with two end-mem ers:
2 4 Fe SiO Fa alite Fa
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Vitreous luster-
No ood cleava es H=6.5 G=3.2
Optical: high relief, moderately
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Olivine in thin section
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Pyroxenes Common in mafic and intermediate igneous rocks,
typically crystallize from basalt after Olivine (BRS)
Single Chain Silicates General Formula: Ca2+ M 2+ Fe2+ Si O
Two kinds:
Ortho roxenes O x M Fe Si O are orthorhombicand have perpendicular axes, low birefringence, // ext.
Enstatite
Clinopyroxenes (Cpx) Ca(Mg,Fe)Si2O6 are monoclinicand have one inclined axis, higher biref., inclined ext.
Augite and Diopside
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PyroxeneRelief, Color
PPL
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Orthopyroxene Properties
Orthopyroxenes (enstatite, hypersthene,
Color gray, bronze, brown Colorless to tan in thin section
High relief
Low birefringence
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Clinopyroxene Properties
Diopside (more likely in metamorphic rocks)
a~1 g~1 2 6 Color light green
Colorless in thin section
Moderate birefrin ence inclined extinction Augite Ca~1(Mg,Fe)~1Si2O6 (typical igneous Cpx)
Tan, light brown or green in thin section
Moderate birefringence, inclined extinction
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Augite (moderate birefringence, twinningand cleavage)
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Hornblende (Hb)
is the main amphibole in igneous rocks
from mafic magmas, and at lowertemperature
is most common in intermediatecomposition igneous rocks
ou e-c a n s ca e
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General Amphibole Formula:
(Na,K)0-1(Ca,Na,Fe,Mg)2(Mg,Fe,Al)5(Si,Al)8O22(OH)2 large medium small tetrahedral cations
Simple Amphibole (Tremolite):
_ a2 g5 8 22 2
Hornblende Formula:
(Ca,Na)2-3(Mg,Fe,Al)5Si6(Si,Al)2O22(OH)2 Substitution of (Alvi, Aliv) for (Mgvi, Siiv) of tremolite
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Black or dark green
Vitreous luster, translucent = - = -. .
two perfect prismatic cleavages at about 60o and ,
commonly in prisms with flattened hexagonal
cross-sect ons
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Various shades of brown, red-brown, green,
ue-green or tan n t n sect on
Moderate to strong pleochroism is typical
Moderate birefringence, commonly
obscured by its color Two good cleavages at ~60o and 120o toeachother
You have to be looking down the prism tosee 2 crossing sets of cleavages, in manyv ews you w see on y one se o c eavages
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Igneous Amphiboles
B g Horn en e Crysta s n t s ne-gra ne
volcanic rock are called Phenocrysts
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Hb cleavage, color & pleochroism
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Kaersutite Na Ti-rich i neous am hibole
w t strong re - rown p eoc ro sm
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Biotite is the lowest Mafic Mineral on
scon nuous e o owen s er es
t crysta zes very ate rom ract onate ma cmagmas and is only common in intermediate toe s c magmas, 2 must e present or ot te
to crystallize Biotite is a trioctahedral, t-o-t (or 2:1) sheetsilicate
Biotites properties: its strongly pleochroic,has cleava e arallel extinction birds-e eextinction and pleochroic haloes around zircon
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H2O in the liquid
biotite, except for color and pleochroism
ommon n ran tes an egmat tes
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Felsic Minerals on BRS
olivine Ca plagioclase
T
orthopyroxene
clinopyroxene NaCa plagioclase
amphibole (Hb)
e
rature
biotite Na plagioclase
coolingtem
muscovite residualphases
low T
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= =, .
Generally clear and glassy, may have avar e y o co ors c ear, smo y, rown, rose;its allochromatic)
Conc o a racture, no c eavage
Habit: hexagonal (6-sided prisms) or
massive O tical: low relief and low birefrin ence
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Quartz in Granite Thin Section
From Atlas of Rocks & Minerals in Thin Section
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The Feldspar Ternarya 2 2 8
AnorthiteAll naturale spars
No feldspars
NaAlSi3O8 KAlSi3O8
r oc ase
alkali feldspars
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.Properties
H=6, G=2.56 ,
or flesh-colored
Habit: stubby prisms, simple twins common
Optical: low relief and low birefringence Commonl Perthitic micro and macro
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Alkali Felds ars have Perthites
What do Perthites look like?
Thinsection
in XPL
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Alkali Feldspars have Perthites
What do Perthites look like?
1mm
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What causes Perthites?
Caused by un-mixing, exsolution orse aration of Na+ diameter~1.1 and K+
(diameter~1.6) as the feldspar cools
At low temperatures, there is a miscibility
3 8 3 8
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plaid twinning
1mm
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= - = - = =. , . . , .
Luster pearly, vitreous/translucent Co or w te to gray
One perfect, one good cleavage Optical: low relief and low birefringence
Not Perthitic!
Common y zone
Pl i l F ld h
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Plagioclase Feldspars have
po ysyn e c, ame ar e w ns
- blein
n
han
y
visi
L
)
siblei
usual
n(XP
bev
i
imen
,
secti
M
a
s
pe
thin
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Large crystals ofQuartz,
Muscovite(which are low on Bowens
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Elements and Volatiles
Incompatible Elements those elements
minerals (Li, B, Be)
o at es t ose e ements t at ave astrong preference for the gaseous phase
2 , 2, , ,
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Phase Diagrams tell MUCH moreabout Crystallization and Melting
What follows is just a quick preview of
some of the things phase diagrams can beused for
H d thi di t t ll
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How do we use this diagram to tell
Diopside-richqu
80% CaMgSi2O6 (Di)20% CaAl Si O An
X
Draw isopleth=
line of constantcomposition
What happens as
liquid cools?Anorthite-rich li uid Y65% CaAl2Si2O8 (An)
35% CaMgSi2O6 (Di)
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Textures of rocks in Di-An System
2 component system with
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2-component system with
Crystallization ofPlagioclase inBasalts (realgneous p ag oc ase
is not pure An like-
system)
P C iti d th
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Pyroxene Compositions and the
yroxene ua r atera
CaFeSi2O6CaMgSi2O6
ops e e en erg e
Augite
Ortho roxene
Mg2Si2O6 Fe2Si2O6
FerrosiliteEnstatite orthopyroxenes